Abstract: A method of forming a photoresist mask on a light emitting device is disclosed. A portion of the light emitting device is coated with photoresist. A portion of the photoresist is exposed by light impinging on the interface of the light emitting device and the photoresist from inside the light emitting device. The photoresist is developed, removing either the exposed photoresist or the unexposed photoresist. In one embodiment, the photoresist mask may be used to form a phosphor coating. After the photoresist is developed to remove the exposed photoresist, a phosphor layer is deposited overlying the light emitting device. The unexposed portion of photoresist is stripped. In some embodiments, the light exposing the photoresist is produced by electrically biasing the light emitting device, or by shining light into the light emitting device through an aperture or by a focussed laser.

Abstract: Disclosed are a phosphor pattern which comprises a calcination product of a phosphor pattern precursor containing

Abstract: Disclosed are a process for preparing a phosphor pattern for a field emission display panel which comprises the steps of: (I) forming (A) a photosensitive resin composition layer containing a phosphor on a substrate to which a conductive layer is formed; (II) irradiating active light to (A) the photosensitive resin composition layer containing a phosphor imagewisely; (III) selectively removing (A) the photosensitive resin composition layer to which active light has been imagewisely irradiated by development to form a pattern; and (IV) calcining the pattern to remove unnecessary portion to form a phosphor pattern, a photosensitive element for a FED display panel, phosphor pattern for a FED display panel, and a FED display panel.

Abstract: Disclosed are a phosphor pattern which comprises a calcination product of a phosphor pattern precursor containing (A) an organic material containing at least one selected from the group consisting of an alkali metal and an alkaline earth metal; and (B) a phosphor wherein an amount of the alkali metal or the alkaline earth metal is 2% by weight or less based on the amount of (B) the phosphor, a process for preparing the same, an organic alkali developing solution for forming the same, an emulsion developing solution for forming the same and a back plate for plasma display using the same.

Abstract: A partition of a plasma display device is fabricated by forming a dielectric layer on the surface of a rear substrate having an address electrode; forming a conductive layer and a photoconductive layer in order on the surface of said dielectric layer; charging the surface of said photoconductive layer; exposing aid photoconductive layer covered with a mask of a predetermined pattern to ultraviolet rays so that an electrostatic latent image can be formed on said photoconductive layer; developing the electrostatic latent image by allowing said photoconductive layer, on which the electrostatic latent image is formed, to be in contact with a charged liquid toner layer so that liquid toner can stick to the electrostatic latent image; drying the toner stuck to the electrostatic latent image and absorbing the toner remaining an area other than the electrostatic latent image; repeating three times the steps from said step of charging the surface of said photoconductive layer through to said step of drying and absorbi

Abstract: A method of electrophotographically manufacturing a viewing screen including a filter layer of pigment particles for a cathode-ray tube (CRT), which comprises the steps of first-coating of volatilizable conductive layer, second-coating the conductive layer with a volatilizable photoconductive layer, first-establishing a uniform electrostatic charge over the whole surface of the photoconductive layer, first-exposing selected areas of the photoconductive layer to a light source, first-developing the discharged, exposed areas with one kind of charged pigment particles, and fixing the developed pigment particles to the photoconductive layer to form a filter layer beneath one of first to third color-emitting phosphor particles. Then, the one of first to third color-emitting phosphor particles is formed on the filter layer by a electrophotographically manufacturing method.

Abstract: The present invention provides with a black matrix, a phosphor screen, and a method of manufacturing thereof. For a method of manufacturing the black matrix formed on the inner surface of a panel of a color CRT, a photoresist is not used, but a wet electrophotographic method was employed, using graphite for a main component of the black matrix materials, and forming a phosphor screen by a dry electrophotographic method to improve the quality of a color cathode-ray-tube.

Abstract: There is disclosed a display screen obtained such that a first pigment layer and a resist layer are exposed and developed, then a second pigment layer is formed on the photoresist pattern, and the resultant structure is coated with a resist decomposition agent to remove the photoresist pattern and the second pigment layer formed on the photoresist pattern.

Abstract: A method of forming a fluorescent screen, such as a black matrix or a color filter, on a front panel of a cathode ray tube is described. The method comprises the steps of forming a photosensitive adhesion layer on an inner surface of the front panel, exposing the photosensitive adhesion layer through a color selecting electrode having a plurality of slots for reducing adhesion level of exposed area of the photosensitive adhesion layer, bringing a pigment layer provided on a supporting sheet into intimate contact with the photosensitive adhesion layer, applying pressure to the pigment layer and the photosensitive layer, and peeling off the supporting sheet from the pigment layer. Alternatively, a pigment may be dispersed in the photosensitive adhesion pigment layer.

Abstract: In accordance with the present invention, shown in FIG. 3, a method of electrophotographically manufacturing a phosphor screen, comprises the steps of coating 44 an interior surface of a viewing faceplate panel to form a volatilizable organic conductive (OC) layer and overcoating 46 the OC layer to form a volatilizable organic photoconductive (OPC) layer. The OPC layer is electrostatically charged 48 and selected areas of the OPC layer are exposed to light to form a charge image 50. The charge image is developed with at least one phosphor material 52 which is fixed 58 to the OPC layer by spraying a fixing solution comprising two solvents, having substantially different rates of evaporation onto the phosphor material on the OPC layer to affect the solubility thereof and to make the OPC layer tacky. At least a portion or all of the solvent with the higher rate of evaporation is allowed to evaporate while the solvent with the lower rate of evaporation retains the tackiness of the OPC layer.

Abstract: There is disclosed a salt of a polymer having charged anionic functionalities used as a dispersant in a dispersion solution containing a pigment and used for forming a first pigment layer. A substance which forms a salt with a polymer having charged anionic functionalities is mixed into a solution applied on the pigment layer, and/or mixed into a developing solution. The formed layers are patterned and thus a display screen is obtained.

Abstract: The black matrix of the faceplate panel is deposited by a wet-layer photoconductive manner. An organic conductive layer is initially deposited on the faceplate panel, on which an organic photoconductive material is formed to form an organic photoconductive layer. The photoconductive layer is charged to positive or negative potential and a selective area of the organic photoconductive layer is exposed to light radiated from an exposure device, such that the potential can be left on the unexposed area, where the black matrix will be deposited, of the organic photoconductive layer. Then, As novel steps, deposition of the conductive black matrix is achieved according to the following steps. First, a conductive black matrix material is charged having the opposite potential to that left on the unexposed area of the organic photoconductive layer.

Abstract: A light fixing layer is deposited on the panel during the screening process of a panel. The light fixing layer can be softened when it is subjected to light so as to allow the phosphor layers to be fixed on the panel. That is, the light fixing layer shows adhesive characteristics when subjected to light. Therefore, after developing all phosphor layers on the panel, when the light is radiated to the light fixing layer, the light fixing layer is softened, thereby fixing the phosphor layers.

Abstract: Items of material are patterned on a substrate by forming a layer of photoresist on the substrate and a layer of metal on the photoresist. The photoresist is patterned to define an opening exposing a portion of the substrate and the metal is patterned to define an aperture smaller than the opening so as to divide the exposed surface of the substrate into shadow areas and a non-shadow area. A first material system is evaporated generally perpendicular to the aperture to form a first organic light emitting diode on the surface of the substrate in the non-shadow area and second and third material systems are evaporated at angles to the aperture to form second and third organic light emitting diodes in the shadow areas. Passivation material is evaporated perpendicularly onto the first diode and at the angle onto the second diode.

Abstract: A process for preparing a black matrix comprising the steps of producing a developed substrate by coating, drying, exposing and developing a photoresist on the inside of a substrate, producing a dried substrate by drying the developed substrate several times, coating a dye on the dried substrate and then drying the board, coating graphite on the dried substrate, and etching the graphite-coated substrate. This method makes it possible to perfectly etch the black matrix dot and increase volatility in fluorescent coating.

Abstract: The present invention relates to a method for manufacturing a shadow mask, which is satisfactory in terms of shape, linearity and dimensional accuracy of an etching hole when thickness of an electrode base material is about 20-80 .mu.m. According to the invention, resist is coated on both sides of a base material, and patterning is performed only on the resist on one side, the resist with electrode pattern is developed, and patterning is performed.

Abstract: In accordance with the present invention, a method of electrophotographically manufacturing a luminescent screen assembly on a photoreceptor disposed on an interior surface of a faceplate panel for a color CRT includes the steps of: charging the photoreceptor to establish a substantially uniform electrostatic voltage thereon; positioning the panel on an exposure device having a light source therein; exposing selected areas of the photoreceptor to visible light from the light source to affect the voltage thereon, without affecting the voltage on the unexposed area of the photoreceptor; and depositing a triboelectrically charged, first color-emitting phosphor onto the selected areas of the photoreceptor. The charging, positioning, exposing and depositing steps are repeated for a second and a third triboelectrically charged, color-emitting phosphor.

Abstract: A method for fabricating a phosphor screen of a cathode ray tube which includes the steps of forming a light absorbing pattern on an inner surface of a panel of the cathode ray tube, applying a slurry of first phosphor on the inner surface of the panel, rotating the panel for drying the slurry of first phosphor around a first axis of rotation, exposing the first phosphor selectively so as to form a first phosphor pattern, applying a slurry of second phosphor on the inner surface of the panel, rotating the panel for drying the slurry of second phosphor around a second axis of rotation, exposing the second phosphor selectively so as to form a second phosphor pattern, applying a slurry of third phosphor on the inner surface of the panel, rotating the panel for drying the slurry of third phosphor around a third axis of rotation, and exposing the third phosphor selectively so as to form a third phosphor pattern, wherein the first, second and third axes of rotation are parallel to one another.

Abstract: The method of electrophotographically manufacturing a screen assembly on an interior surface of a faceplate panel for a color CRT, according to the present invention includes the step of forming a photoreceptor by sequentially coating the surface of the panel with a conductive solution to form a volatilizable conductive layer and then overcoating the conductive layer with an organic photoconductive solution comprising a suitable resin, an electron donor material, an electron acceptor material, a surfactant and an organic solvent to form a volatilizable photoconductive layer.

Abstract: The method of electrophotographically manufacturing a screen assembly on an interior surface of a viewing faceplate of a panel for a color CRT, according to the present invention, includes the steps of forming a volatilisable organic conductive layer on the interior surface of the viewing faceplate and overcoating the organic conductive layer with an organic photoconductive solution to form a volatilizable organic photoconductive layer. The conductive solution, comprising a polyelectrolyte and a diluent, is applied to the interior surface of the viewing faceplate by spraying, to form the conductive layer.

Abstract: At least partly overlapping patterns are formed on a substrate. The substrate is provided with a photosensitive layer which becomes tacky under the influence of light. The layer is exposed according to a pattern. A powder is provided on the exposed portions of the layer. The powder adheres to the exposed portions. Subsequently, the layer is again exposed according to a pattern which at least partly overlaps the first pattern. It has been found that a second powder adheres to the powder which has been provided first. In this manner, several powder layers can be provided on top or: each other on one photosensitive layer. This saves time.

Abstract: The method of electrophotographically manufacturing a screen assembly on an interior surface of a faceplate panel for a color CRT, according to the present invention, includes the steps of sequentially coating the surface of the panel with a conductive solution to form a volatilizable organic conductive layer and then overcoating the conductive layer with a photoconductive solution to form a volatilizable organic photoconductive layer. The conductive layer, comprising a quaternary ammonium polyelectrolyte and a surfactant, provides an electrode for the photoconductive layer and has improved electrical and physical properties compared to prior conductive layers.

Abstract: A luminescent screen assembly for a CRT is made by first coating the interior surface of a faceplate panel with a photoconductive layer which overlies a conductive layer. A multiplicity of red-, green- and blue-emitting phosphor screen elements are then deposited in color groups, in a cyclic order, onto the interior surface of the panel. A negative charge is then established on the photoconductive layer. The charge is weakened in the areas where the photoconductive layer underlies the phosphor screen elements, but unaffected in the open areas separating the phosphor screen elements. The charged, open areas of the photoconductive layer are discharged by flood illumination and reversal developed by depositing thereon particles of light-absorptive matrix material having a triboelectric charge of the same polarity as the charge established on the photoconductive layer. The novel process provides a high opacity matrix.

Abstract: A method for fabricating a cathode ray tube is described. The method comprises the steps of selectively forming a resist layer corresponding to a pattern of a fluorescent material on an inner surface of the panel of a cathode ray tube, and applying a slurry of a light-absorbing material on the entire inner surface of the panel including the resist layer to form a light-absorbing layer. An inorganic pigment slurry is applied over the entire inner surface of the panel to form an inorganic pigment layer on the light-absorbing layer and then subjected to reverse development to selectively remove the resist layer along with the light-absorbing layer and the white pigment layer, thereby forming a matrix pattern. Finally, a fluorescent material is applied to individual removed portions of the matrix pattern to form a fluorescent pattern. Monochromatic or color cathode ray tubes are obtained with an improved luminance and a colorimetric purity by a simple procedure.

Abstract: An apparatus for fusing a polymer powder deposited on a surface of a faceplate panel of a cathode-ray tube comprises a housing having a faceplate support surface and enclosing a chamber. A shutter adjacent to the panel support surface separates the faceplate panel from the chamber. A reservoir for holding a solvent is within the chamber and at least one piezoelectric transducer communicates with the reservoir for atomizing the solvent to create a fog. A fan within the chamber distributes the fog onto the polymer powder. A method for fusing the polymer powder onto the faceplate panel also is described.

Abstract: In an electrophotographic process for manufacturing a luminescent screen assembly on an interior surface of a faceplate panel of a CRT, the panel is first coated with a conductive layer and then overcoated with a photoconductive layer. A substantially uniform charge is established on the photoconductive layer. Selected areas of the photoconductive layer are exposed to actinic radiation, through a shadow mask, to affect the charge on the layer. The unexposed areas of the photoconductive layer are developed with triboelectrically-charged, dry-powdered, light-absorptive screen structure material. The photoconductive layer is reexposed to further discharge those open areas free of the light absorptive material while retaining the charge on those areas having light absorptive matrix material thereon. The reexposure increases the voltage contrast between the exposed and the unexposed areas of the photoconductive layer.

Abstract: A color reference CRT of the type employing a screen of a pattern of individual phosphor elements of different color components, is produced by adjusting the screen weights of the different color components to achieve the desired reference color when the screen is scanned by an electron beam of predetermined beam current and anode potential.

Abstract: The method of electrophotographically manufacturing a luminescent screen on a substrate of a color CRT, according to the present invention, includes the steps of forming a photoreceptor by sequentially coating the substrate to form a conductive layer and an overcoating of a photoconductive layer, establishing an electrostatic charge on the photoconductive layer, and exposing selected areas of the photoconductive layer to visible light to affect the charge thereon. Then the photoconductive layer is developed by the application of suitable triboelectrically charged, dry-powdered screen structure materials. The improved process provides at least one wear-resistant, conductive contact patch on a peripheral portion of a surface of the substrate. The contact patch has a first portion which underlies at least one of the layers of the photoreceptor and is in electrical contact with the conductive layer, and a second portion which extends from the photoreceptor.

Abstract: The present invention relates to a method for making a viewing screen structure for a cathode-ray tube. The method includes the steps of coating a support surface with a film of a polymeric material, a suitable dichromate and a sensitizer therefor which is a chromium ion migration enhancer having a reduced sensitivity to thermal and dark hardening; exposing the film to an image in the form of radiant energy until the solubility of the irradiated regions thereof is selectively altered, thereby producing in the film regions of greater solubility and regions of lesser solubility; removing those regions of the film with greater solubility to bare portions of the underlying support surface while retaining those regions of the film with lesser solubility. The bare portions of the support surface and the retained film regions are overcoated with a composition of light-absorbing material which is adherent to the support surface.

Abstract: In accordance with the present invention, a method of manufacturing a luminescent screen assembly on a substrate of a CRT includes the steps of providing a coating of a non-luminescent screen structure material in a predetermined pattern on the substrate and depositing a plurality of color-emitting screen structure materials on the substrate. The color-emitting screen structure materials are surrounded by the non-luminescent material. An electrostatically-charged dry-powdered resin is deposited onto the aforementioned color-emitting and non-luminescent screen structure materials and fused to form a substantially continuous film.

Abstract: Photoresist for forming the phosphor screen of color cathode-ray tube made up of the composition rate of pure water 10-50%, polyvinyl alcohol 5-30%, dichromate potassium salt 0.5-5%, diethylene glycol 0.5-10%, ethylene glycol 0.5-5%, urea 0.5-10%, acetamide 0.5-5%, butanediol 0.5-10%, paraaldehyde 0.5-5%, dioxane 0.5-5%, a surfactant 0.5-5%.

Abstract: The method of electrophotographically manufacturing a screen assembly on a substrate for use within a CRT, according to the present invention, includes the steps of sequentially coating a substrate with a conductive layer and an overcoating of a photoconductive layer, establishing an electrostatic charge on the photoconductive layer, and exposing selected areas of the photoconductive layer to visible light to affect the charge thereon. Then the photoconductive layer is developed with a charged screen structure material. The improved process utilizes a dry-powdered screen structure material having at least a surface charge control agent thereon to control the triboelectrical charging of the screen structure material.

Abstract: The method of electrophotographically manufacturing a luminescent screen assembly on a substrate of a CRT, according to the present invention, includes the steps of coating the substrate with a conductive layer and overcoating the conductive layer with a photoconductive layer, establishing an electrostatic charge on the photoconductive layer, and exposing selected areas of the photoconductive layer to visible light to affect the charge thereon. Then, the selected areas of the photoconductive layer are developed with triboelectrically charged, dry-powdered, surface-treated screen structure materials. The improved process increases the adherence of the surface-treated materials to the photoconductive layer by contacting the surface-treated materials with a solvent to render the photoconductive layer and the materials tacky.

Abstract: During the formation of a black-matrix layer on the inside surface of a faceplate of a color picture tube, the development of the photoresist coating takes place in an atmosphere with a relative humidity of between about 80-100% and at a temperature of between about 30.degree.-50.degree. C.

Abstract: An optical contact of a patternwise powdery coating layer is improved by permeating a substantially transparent inorganic material having a refractive index of 1.2 to 2.0 into a paternwise powdery coating layer formed on a substrate, thereby forming a mixture layer of the transparent inorganic material and the powdery coating layer between the patternwise powdery coating layer and the substrate.

Abstract: A method for manufacturing a color cathode ray tube, and in particular, for conditioning the surface of a panel of a color cathode ray tube to prepare it for the application of a pattern of color phosphors while minimizing the effects of reflections from interfaces in the panel.

Abstract: A fluorescent screen of a color picture tube is manufactured by the steps of forming a film of substance which becomes sticky when exposed to light on an inner surface of a panel of the tube, exposing predetermined portion of the film through a shadow mask to render sticky the exposed portions, repeatedly applying powders of phosphors of respective colors onto the portions which became sticky so as to form phosphor picture elements of respective colors, exposing portions of the film other than the predetermined portions to render them sticky, and applying a powder of graphite to the portions other than the predetermined portions to form a black matrix film.

Abstract: A method of forming a color picture tube fluorescent screen by so-called dry process. After a photosticky substance mainly containing a diazonium compound is coated on a panel inner face, phosphor is adhered to portions of the compound which have been exposed to light through a color selection electrode and rendered sticky, and surplus phosphor applied on unexposed portions of the compound is removed, the above steps being consecutively repeated for phosphors of three colors to form picture elements of triads of three color phosphors on the panel inner face. The panel inner face is then treated with an aqueous solution containing at least polymer coagulant.

Abstract: A water-soluble, positive-working photoresist composition is disclosed which comprises water-soluble aromatic diazonium salt, water-soluble phenolic compound, and water-soluble polymeric compound. When the film of this composition is irradiated with a pattern of actinic ray and then brought into contact with an alkaline gas or solution, the coating of unexposed areas hardens to become water-insoluble. Preferably, when the film is brought into contact with a suspension of powder or dry powder after being hardened, a positive pattern of powder is obtained by the development with water.

Abstract: A method for forming a pattern of a non-light-emitting black material on the inner surface of a faceplate of a color cathode ray tube is provided, which comprises the steps of:forming a photoresist layer of a photoresist containing a water-soluble bisazidocompound, a water-soluble diazocompound, and a water-soluble polymeric material, on an inner surface of a faceplate of a color cathode ray tube;selectively exposing parts of the photoresist layer using a shadow mask so as to photocure the exposed parts;developing the photoresist layer to remove unexposed parts of the photoresist layer, thereby forming dots of the photoresist;forming a film of a non-light-emitting black material on the inner surface of the faceplate including the dots; andremoving the dots and the non-light-emitting black material on the dots so as to form holes in the film of the non-light-emitting black material.

Abstract: In a method for preparing a mosaic luminescent screen, islands of dry precoating material are adhered to a glass support surface at the sites of the mosaic parts of the screen. Then, the mosaic parts of the screen are deposited on the islands by the slurry-direct photographic method, including development with a turbulent aqueous developing medium. The use of islands provides the necessary adherence during development of the mosaic parts with a substantial reduction in the amount of precoating that must later be removed.

Abstract: A photosensitive composition improved in sensitivity by adding a salt of a compound represented by the general formula: ##STR1## (wherein R.sub.1 and R.sub.2 each represents a straight chain alkyl group, and X, Y and Z each represents H, a straight chain alkyl group or an alkoxy group, but two or more of X, Y and Z can not be H at the same time) to an aromatic diazonium salt which gets sticky upon exposure to light.

Abstract: A process for forming a fluorescent screen, where polychroic patterns are successively formed from at least two kinds of phosphors having different color emission or black powder by means of a photosensitive substance capable of turning tacky by light irradiation, which comprises bringing a finer particulate filling material than particles of the phosphors in contact with tackified parts when or after the particles of the phosphors are applied to the tackified parts in the individual steps of forming patterns each of the individual phosphors. The filling material saturates the tackiness of the phosphor pattern in question in advance to formation of a phosphor pattern in the successive step, and a cause for contamination of the pattern of the preceding step with the phosphor of the successive step can be eliminated thereby.

Abstract: In forming a fluorescent screen of a black matrix type color picture tube, a light absorptive film is first formed on the inner surface of a face plate of the color picture tube. Formed on the light absorptive film is a light-hardenable photosensitive resin film which in turn is exposed to light through a shadow mask at portions corresponding to phosphor applying portions. The unexposed portion of the light-hardenable photosensitive film is then developed. Finally, the exposed portion of the light-hardenable photosensitive film and portion of the light absorptive film therebeneath are removed to partly perforate the light absorptive film so that in the light absorptive film, openings are formed into which the phosphor is applied.

Abstract: For improving the contrast of information displayed on the screen, there is placed in front of this latter a filter comprising a matrix of channels pierced in a photosensitive glass plate. The pierced plate is covered over the whole of its surface with a blackened deposit so as to reduce to the maximum its coefficient of reflection. Thus filters can be formed readily on request, according to the direction of observation in particular, with a good coefficient of transmission and improved contrast.

Abstract: Disclosed are a photosensitive composition comprising a copolymer comprising acrylamide, diacetone-acrylamide and a sulfonated vinyl monomer, such as sodium p-styrenesulfonate, and a water-soluble aromatic bisazide compound, and a pattern-forming method using this photosensitive composition.This photosensitive composition has a reciprocity law failure, and when this photosensitive composition is used, the development after light exposure is completed in a short time.

Abstract: A process for forming a phosphor screen of a color picture tube comprising forming a thin layer using a photosensitive composition which contains an aromatic diazonium salt as a photosensitive component and produces tackiness by exposure to actinic light on the surface of the substrate and contacting the tackified thin layer after exposure to light with phosphor particles to form each phosphor layer for emitting color is improved by using as the phosphor particles those coated with at least one surface coating material selected from the group consisting of Zn(OH).sub.2, Zn.sub.3 (PO.sub.4).sub.2 and AlPO.sub.4 in shortening the contact time between the thin layer and the phosphor particles.

Abstract: A patternwise coated powder layer can be formed by a process comprising the steps of coating a photosensitive composition, which contains an aromatic diazonium salt as a photosensitive component and becomes sticky by exposure, onto the surface of a substrate to form a thin layer, subjecting the thin layer to patternwise exposure with actinic radiation to produce stickiness at the exposed area, and then contacting powder particles with the thin layer after exposure to make the thin layer to accept the powder particles according to the powder acceptability of the thin layer. According to this process, for example, the phosphor screen of a color picture tube can simply be produced.LIST OF PRIOR ART (37 CFR 1.56 (a))The following reference is cited to show the state of the art:Japanese Patent Laid-Open Publication No.

Abstract: A method of manufacturing a fluorescent screen for color picture tubes comprises applying to the tube front plate a continuous sensitized filter layer and exposing it, applying a continuous sensitized fluorescent layer and exposing it through a mask and removing the unexposed parts of the fluorescent layer and the filter layer therebeneath by washing.

Abstract: A photosensitive film applied onto the inner surface of a faceplate of color picture tube is exposed to light through a shadow mask. The exposed portions of the photosensitive film are further hardened by the photo-cross linking property until they exhibit hydrophobic property. Since these further hardened portions repel a light absorbing material, for example graphite, the graphite adheres to only the portions of the faceplate between the exposed portions. The surplus light absorbing material deposited on the further hardened portions is removed by development, whereby a black matrix surface can be obtained having a pattern of the light absorbing material adhered to the faceplate.