Positive Image Formation From Radiation Sensitive Dye Former Patents (Class 430/334)
  • Patent number: 4888266
    Abstract: The invention relates to a process for producing supports intended for the optical recording and reading of information. A layer containing a diazo compound is deposited onto a metallized substrate. Recording is obtained by exposing the support to light through a mask, the exposed zones of the layer of diazo compound being decomposed. Dry development in ammonia vapors shows up transparent zones and opaque zones corresponding to the information.
    Type: Grant
    Filed: March 13, 1987
    Date of Patent: December 19, 1989
    Assignee: Thomson Brandt
    Inventors: Jean-Pierre Lacotte, Claude Puech
  • Patent number: 4663275
    Abstract: Photolithographic methods employing a photoresist layer and a contrast enhancing photobleachable layer deposited thereon have certain disadvantages including compatibility and the tendency toward scum formation during stripping of the photobleachable layer. These problems are alleviated by the deposition of an aqueous alkali-soluble polymeric barrier layer such as poly(vinyl alcohol), which is removed simultaneously with the alkaline development step for the photoresist. In a preferred embodiment, the polymeric binder for the photobleachable layer is also water-soluble and is also removed simultaneously with development.
    Type: Grant
    Filed: September 4, 1984
    Date of Patent: May 5, 1987
    Assignee: General Electric Company
    Inventors: Paul R. West, Gary C. Davis
  • Patent number: 4613553
    Abstract: Metallic salts of organic charge-transfer agents, such as TCNQ, TNAP, TCNE and DDQ and their derivatives, can be processed by an electron beam for a variety of useful electronic and optical applications. The metallic charge transfer salts can be used to deposit high resolution conductive lines directly without developing solutions or subsequent metallization steps. The compounds can also be employed in the conventional manner as resists for doping (i.e., ion diffusion or implantation) and to diffuse metals into substrates. In particular, electronic devices, optical devices and image-storage devices are disclosed which can be formed by simple electron beam processed of metal charge-transfer salt films deposited on substrates.
    Type: Grant
    Filed: May 31, 1985
    Date of Patent: September 23, 1986
    Assignee: Brown University Research Foundation
    Inventors: William M. Risen, Jr., Efstratios I. Kamitsos
  • Patent number: 4394433
    Abstract: A novel light sensitive, heat developable imaging system incorporating a diazonium salt and a leuco dye in a binder is disclosed.
    Type: Grant
    Filed: July 23, 1981
    Date of Patent: July 19, 1983
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Kenneth G. Gatzke
  • Patent number: 4334005
    Abstract: A radiation-sensitive element is disclosed including a radiation-sensitive layer comprised of a cobalt(III)complex and a photoreductant. A process is disclosed in which the photoreductant is converted to a reducing agent by exposure to electromagnetic radiation longer than 300 nanometers. The reducing agent is then reacted with a cobalt(III)complex. Images can be recorded directly within the radiation-sensitive layer or in a separate image-recording element or layer by use of the residual cobalt(III)complex not exposed or one or more of the reaction products produced by exposure. By using the ammonia liberated from ammine ligand containing cobalt(III)complexes on exposure in combination with imagewise and uniform exposures, positive or negative images can be formed in diazo image-recording layers or elements associated with the radiation-sensitive layer. By the selection of amine-responsive reducing agent precursors, the amines released by the cobalt(III)complexes cause an amplified image.
    Type: Grant
    Filed: March 15, 1979
    Date of Patent: June 8, 1982
    Assignee: Eastman Kodak Company
    Inventors: Anthony Adin, James C. Fleming
  • Patent number: 4311783
    Abstract: Photoimaging compositions comprising (A) 2,4,5-triphenylimidazolyl dimer having selected substituents on the 2,4 and 5 phenyl rings and an extinction coefficient determined in methylene chloride at 10.sup.-5 to 10.sup.-3 mol/liter at 350 nm of at least 4000 liters/mol-cm and at 400 nm of at least 250 liters/mol-cm; and at least one of (B1) leuco dye or (B2) addition polymerizable ethylenically unsaturated monomeric compound. The new imaging compositions are useful in preparing dual response photoimaging products such as proofing papers, printout paper, overlay films and photopolymerizable elements. Improved imaging speed is achieved at equal concentration levels when compared with conventional 2,4,5-triphenylimidazolyl dimers.
    Type: Grant
    Filed: July 17, 1980
    Date of Patent: January 19, 1982
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Rolf Dessauer
  • Patent number: 4309047
    Abstract: A pressure-sensitive or heat-sensitive recording material which contains in its color reactant system, as developer for the color former, at least one compound of the formula ##STR1## wherein X is the direct bond or ##STR2## each of R.sub.1, R.sub.2 and R.sub.3 independently is hydrogen or unsubstituted or substituted alkyl, aryl or aralkyl, or R.sub.1 and R.sub.3, together with the nitrogen atom to which they are attached, are a 5- or 6-membered heterocyclic radical, Q is carbon or an unsubstituted or substituted hydrocarbon radical, Y is halogen, and m is 1 to 3. The grouping --Q--Y.sub.m is preferably --C(Hal).sub.3, wherein Hal is halogen.
    Type: Grant
    Filed: September 30, 1980
    Date of Patent: January 5, 1982
    Assignee: Ciba-Geigy Corporation
    Inventor: Jean C. Petitpierre
  • Patent number: 4273860
    Abstract: There is disclosed a cobalt(III) complex-containing photographic composition, element and process which can be made negative-working or positive-working. Featured are an exposure activatible image precursor composition and a photoinhibitor composition capable of inhibiting image formation in the image precursor composition.
    Type: Grant
    Filed: December 20, 1978
    Date of Patent: June 16, 1981
    Assignee: Eastman Kodak Company
    Inventor: Anthony Adin
  • Patent number: 4262074
    Abstract: An imaged development process and materials wherein use is made of a photographic medium sensitive to ultraviolet radiations and formulated of an alkyl cellulose derivative and 7,7,8,8-tetracyanoquinodimethane.
    Type: Grant
    Filed: November 19, 1979
    Date of Patent: April 14, 1981
    Assignee: A. B. Dick Company
    Inventor: James M. Halm
  • Patent number: 4245027
    Abstract: A light-sensitive image recording material comprising, as a self-supporting film or in one or more layers on a support, at least(a) a heat sensitive coloring element comprising at least one polyvinyl pyridine and at least one polyvinylidene halide, and(b) a light sensitizing element comprising at least one of(1) a compound which, on exposure to actinic radiation, is capable of complexing the polyvinyl pyridine of element (a) or is capable of forming a quaternary salt with the polyvinyl pyridine of element (a), or(2) a compound which, on exposure to actinic radiation, is capable of releasing a precursor which is capable of complexing the polyvinyl pyridine of element (a) or is capable of forming a quaternary salt with the polyvinyl pyridine of element (a) under heating,and a dry process for recording a light image comprising(1) imagewise exposing to actinic radiation the light-sensitive image recording material described above, and(2) uniformly heating the imagewise exposed light-sensitive image recording mate
    Type: Grant
    Filed: July 11, 1978
    Date of Patent: January 13, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Keiji Takeda, Masayoshi Nagata, Kenji Matsumoto
  • Patent number: 4237207
    Abstract: A photochromic spiropyran compound is uniformly dispersed in a vinyl chloride homopolymer or copolymer resin binder. The resulting photosensitive composition provides an image which is highly stable against exposure to light, darkness, and heat when the composition is exposed to a light source emitting radiation of wavelength which includes the absorption band of the spiropyran compound.
    Type: Grant
    Filed: July 20, 1979
    Date of Patent: December 2, 1980
    Assignee: La Cellophane
    Inventor: Claude G. Ceintrey