Heat Applied After Imaging Patents (Class 430/350)
  • Patent number: 5759752
    Abstract: A thermosensitive recording material suited for use in direct thermal imaging by means of an information-wise energized heating element, said recording material containing a thermosensitive recording layer of which the optical density is changed by heat, characterized in that said recording layer is coated with a protective transparent resin layer essentially consisting of a polycarbonate or copolycarbonate derived from one or more bisphenols, wherein at least 25 mole % of said bisphenols consists of a bis-(hydroxyphenyl)-cycloalkane corresponding to following general formula (I): ##STR1## wherein: each of R.sup.1, R.sup.2 , R.sup.3, and R.sup.4 (same or different) represents hydrogen, halogen, a C.sub.1 -C.sub.8 alkyl group, a substituted C.sub.1 -C.sub.8 alkyl group, a C.sub.5 -C.sub.6 cycloalkyl group, a substituted C.sub.5 -C.sub.6 cycloalkyl group, a C.sub.6 -C.sub.10 aryl group, a substituted C.sub.6 -C.sub.10 aryl group, a C.sub.7 -C.sub.12 aralkyl group, or a substituted C.sub.7 -C.sub.
    Type: Grant
    Filed: November 29, 1995
    Date of Patent: June 2, 1998
    Assignee: AGFA-Gevaert N.V.
    Inventors: Carlo Uyttendaele, Geert Defieuw
  • Patent number: 5756268
    Abstract: If a color photographic material, which is processed by the process steps a) image-by-image exposure, b) color developing, c) bleaching, d) fixing, e) washing or stabilizing, and f) drying, wherein steps c) and d) may be combined to constitute bleach-fixing, is subjected to a temperature treatment of 0.01 to 30 seconds at 60 to 240.degree. C. between exposure and color developing, an increase of the contrast can thereby be obtained.
    Type: Grant
    Filed: April 21, 1997
    Date of Patent: May 26, 1998
    Assignee: Agfa-Gevaert AG
    Inventors: Edgar Draber, Rudolf Tromnau, Manfred Peters
  • Patent number: 5750292
    Abstract: A compound represented by the following general formula (1) and a photosensitive resin composition comprising the compound of formula (1): ##STR1## The compound of formula (1) normally has a low ultraviolet absorption, but has a high ultraviolet absorption when heat-treated. The present invention also provides a photosensitive resin layer composition which has a low ultraviolet absorption in an appropriate wavelength range such that ultraviolet rays reach sufficiently deep into the film to effect curing when exposed to light, but which has a high ultraviolet absorption when subsequently processed.
    Type: Grant
    Filed: July 8, 1996
    Date of Patent: May 12, 1998
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Morimasa Sato, Takekatsu Sugiyama
  • Patent number: 5747226
    Abstract: Provided are a processing material used for forming images on a heat-developable photosensitive material by heating the processing material and the photosensitive material in a condition that they are brought into face-to-face contact, with the processing material comprising a long web support, preferably having a thickness of from 4 to 40 .mu.m, provided thereon a processing layer, preferably comprising a base or a precursor of bases; and a method of forming images on a heat-developable photosensitive material, which comprises a step of supplying a fountain water to the photosensitive material, a step of bringing the dampened photosensitive material into face-to-face contact with the aforesaid processing material and a step of applying heat thereto.
    Type: Grant
    Filed: August 27, 1996
    Date of Patent: May 5, 1998
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoshisada Nakamura, Shun-ichi Ishikawa, Kazuhiko Matsumoto
  • Patent number: 5705323
    Abstract: Heat bleachable antihalation compositions are prepared using metallized or unmetallized formazan dyes, hexaarylbiimidzoles having alkoxy substituents and organic carboxylic acids. These compositions are rapidly bleached at relatively low temperatures and can be used in photothermographic elements.
    Type: Grant
    Filed: January 5, 1996
    Date of Patent: January 6, 1998
    Assignee: Eastman Kodak Company
    Inventors: Robert James Perry, Ramanuj Goswami, Paul Anthony Zielinski
  • Patent number: 5705324
    Abstract: 4-Substituted isoxazole compounds are useful as co-developers in combination with hindered phenol developers to produce high contrast black-and-white photothermographic and thermographic elements.The photothermographic and thermographic elements may be used as a photomask in a process where there is a subsequent exposure of an ultraviolet or short wavelength visible radiation-sensitive imageable medium.
    Type: Grant
    Filed: March 14, 1996
    Date of Patent: January 6, 1998
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Thomas J. Murray
  • Patent number: 5686228
    Abstract: Certain propenenitrile compounds have been found to function as antifoggants and serve to improve the initial minimum density of black and white photo-thermographic and thermographic elements.
    Type: Grant
    Filed: February 25, 1997
    Date of Patent: November 11, 1997
    Assignee: Imation Corp.
    Inventors: Thomas J. Murray, Paul G. Skoug
  • Patent number: 5654130
    Abstract: 2-Substituted malondialdehyde compounds are useful as co-developers in combination with hindered phenol developers to produce high contrast black-and-white photothermographic and thermographic elements.The photothermographic and thermographic elements may be used as a photomask in a process where there is a subsequent exposure of an ultraviolet or short wavelength visible radiation-sensitive imageable medium.
    Type: Grant
    Filed: March 14, 1996
    Date of Patent: August 5, 1997
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Thomas J. Murray
  • Patent number: 5635339
    Abstract: Nitrogen containing 3-heteroaromatic substituted acrylonitrile compounds are useful as co-developers in combination with hindered phenol developers to produce high contrast black-and-white photothermographic and thermographic elements.The photothermographic and thermographic elements may be used as a photomask in a process where there is a subsequent exposure of an ultraviolet or short wavelength visible radiation-sensitive imageable medium.
    Type: Grant
    Filed: May 16, 1996
    Date of Patent: June 3, 1997
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Thomas J. Murray
  • Patent number: 5627008
    Abstract: The present invention provides a donor for use in thermal transfer printing. The donor element comprises on a support a donor layer comprising a binder and a mixture of at least two thermotransferable reducing agents capable of reducing a silver source to metallic silver upon heating. The donor element is image-wise heated while being in contact with an image receiving material comprising a thermoreducible silver source. By using a mixture of reducing agents crystallization is reduced and the obtained images exhibit an increased density and a more neutral grey hue.
    Type: Grant
    Filed: March 19, 1996
    Date of Patent: May 6, 1997
    Assignee: Agfa-Gevaert N.V.
    Inventors: Geert Defieuw, Wilhelmus Janssens, Jean-Marie Dewanckele
  • Patent number: 5601962
    Abstract: A thermal imaging process is provided using (i) a donor element comprising on a support a donor layer comprising a binder, a thermotransferable reducing agent capable of reducing a silver source to metallic silver upon heating and a thermotransferable toning agent and (ii) a receiving element comprising on a support a receiving layer comprising a silver source capable of being reduced to metallic silver by means of heat in the presence of a reducing agent, said thermal imaging process comprising the steps ofbringing said donor layer of said donor element into face to face relationship with said receiving layer of said receiving element,image-wise heating a thus obtained assemblage preferably by means of a thermal head, thereby causing image-wise transfer of an amount of said thermotransferable reducing agent to said receiving element in accordance with the amount of heat supplied andseparating said donor element from said receiving element.
    Type: Grant
    Filed: April 16, 1996
    Date of Patent: February 11, 1997
    Assignee: Agfa-Gevaert N.V.
    Inventors: Geert Defieuw, Wilhelmus Janssens
  • Patent number: 5599648
    Abstract: Surface reforming of a polymeric article containing a polymerizable compound is effectively performed by polymerizing the polymeric article in contact with a surface reforming medium because the transfer of the material constituting the surface reforming medium to the polymeric article is enhanced by the polymerization. The surface reforming can be performed locally selectively, i.e., imagewise. The remaining un-polymerized part may be subjected to further surface reforming, e.g., by using another type of surface reforming medium or attachment of powder, to provide an enhanced contrast of surface property. Such an enhanced contrast of surface property can be effectively used, e.g., for production of a printing plate.
    Type: Grant
    Filed: November 26, 1993
    Date of Patent: February 4, 1997
    Assignee: Canon Kabushiki Kaisha
    Inventors: Yuji Kondo, Masato Katayama, Akihiro Mouri
  • Patent number: 5595853
    Abstract: An optical image forming material in which the background portions thereof are not color developed (not fogged) during storage in the dark after fixing, comprising a support having thereon at least a coating layer containing (1) microcapsules containing a leuco dye which is form color when it is oxidized and a photooxidizing agent, and (2) a reducing agent and a fixing accelerator present outside of the microcapsules. The reducing agent is a hydroquinone derivative substituted by an alkyl group at each of 2- and 5-positions thereof, and the fixing accelerator is 2,2-bis(4-hydroxy-phenyl)propane.
    Type: Grant
    Filed: September 14, 1995
    Date of Patent: January 21, 1997
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Makoto Ono, Naoto Yanagihara
  • Patent number: 5589317
    Abstract: The present invention provides a method for reproducing continuous tone images by means of a thermal head. The method involves the image-wise heat transfer of a reducing agent from a donor element to a receiving layer of a receiving element. The receiving element contains a thermoreducible silver source such as e.g. silver behenate. The process of the present invention provides high density images with multiple intermediate density levels.
    Type: Grant
    Filed: March 8, 1995
    Date of Patent: December 31, 1996
    Assignee: Agfa-Gevaert N.V.
    Inventors: Geert Defieuw, Wilhelmus Janssens, Herman Uytterhoeven, Bart Horsten, Jean-Marie Dewanckele, Jan Van den Bogaert
  • Patent number: 5589321
    Abstract: A method of and an apparatus for controlling drying of a photographic material in which, by controlling respective temperatures of a contact-heating device and warm air, temperatures can be controlled to the minimum temperature necessary to provide the photographic material with optimal effects so that the relative contributions of drying the photographic material by the contact-heating device and the warm air are always constant.
    Type: Grant
    Filed: July 19, 1994
    Date of Patent: December 31, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Shinichi Matsuda
  • Patent number: 5587269
    Abstract: The present invention provides a thermal imaging process using (i) a donor element comprising on a support having a thickness of 3-10 .mu.m a donor layer comprising a binder, a thermotransferable reducing agent capable of reducing a silver source to metallic silver upon heating and particles protruding from the surface of said donor layer and (ii) a receiving element comprising on a support a receiving layer comprising a silver source capable of being reduced by means of heat in the presence of a reducing agent, said thermal imaging process comprising the steps ofbringing said donor layer of said donor element into face to face relationship with said receiving layer of said receiving element,image-wise heating a thus obtained assemblage, thereby causing image-wise transfer of an amount of said thermotransferable reducing agent to said receiving element in accordance with the amount of heat supplied by said thermal head andseparating said donor element from said receiving element.
    Type: Grant
    Filed: March 8, 1995
    Date of Patent: December 24, 1996
    Assignee: Afga-Gevaert N.V.
    Inventor: Geert Defieuw
  • Patent number: 5580706
    Abstract: Disclosed is a method for processing a silver halide photographic material, having on one side of a support a hydrophobic polymer layer as the outermost layer and on the side opposite an emulsion layer, by means of an automatic developing apparatus. The apparatus has a drying operation part which is equipped with two or more hot rollers arranged so that the silver halide photographic material may be wrapped partly around each of the hot rollers in turn and the contact between the rollers and the material may alternate between the front surface and the back surface of the photographic material, whereby the moisture in the photographic material evaporates from the surface areas when they are not in contact with the hot rollers. This method results in improvements in the drying characteristics of the photographic material and the transportation characteristics of the automatic developing apparatus.
    Type: Grant
    Filed: July 6, 1995
    Date of Patent: December 3, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Kunio Ishigaki
  • Patent number: 5547831
    Abstract: A dry process silver salt photosensitive material has a support and provided thereon a photosensitive layer containing at least an organic silver salt, a reducing agent and a photosensitive silver halide or a photosensitive silver halide forming component. The photosensitive layer is incorporated with a compound selected from the compounds (i), (ii) and (iii).
    Type: Grant
    Filed: November 16, 1993
    Date of Patent: August 20, 1996
    Assignee: Canon Kabushiki Kaisha
    Inventors: Tetsuro Fukui, Motokazu Kobayashi, Takehiko Ohi, Kazunori Ueno, Kenji Kagami, Masao Suzuki, Katsuya Nishino
  • Patent number: 5545507
    Abstract: Hydroxamic acid compounds are useful as contrast enhancers when used in combination with (i) hindered phenol developers, and (ii) trityl hydrazide and/or formyl-phenyl hydrazine co-developers, to produce ultra-high contrast black-and-white photothermographic and thermographic elements.The photothermographic and thermographic elements may be used as a photomask in a process where there is a subsequent exposure of an ultraviolet or short wavelength visible radiation-sensitive imageable medium.
    Type: Grant
    Filed: September 19, 1995
    Date of Patent: August 13, 1996
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Sharon M. Simpson, Francis H. Sansbury
  • Patent number: 5545505
    Abstract: Hydroxylamine, alkanolamine, and ammonium phthalamate compounds are useful as contrast enhancers when used in combination with (i) hindered phenol developers, and (ii) trityl hydrazide and/or formyl-phenyl hydrazine co-developers, to produce ultra-high contrast black-and-white photothermographic and thermographic elements.The photothermographic and thermographic elements may be used as a photomask in a process where there is a subsequent exposure of an ultraviolet or short wavelength visible radiation-sensitive imageable medium.
    Type: Grant
    Filed: September 19, 1995
    Date of Patent: August 13, 1996
    Assignee: Minnesota Mining and manufacturing Company
    Inventor: Sharon M. Simpson
  • Patent number: 5536622
    Abstract: Trityl hydrazides and formyl-phenyl hydrazines are useful as co-developers with hindered phenols in phothothermographic and thermographic elements. These co-developers have the formula:R.sup.1 --(C.dbd.O).sub.n --NHNH--R.sup.2R.sup.1 represents hydrogen and R.sup.2 represents an aryl or substituted aryl group; or,R.sup.1 represents hydrogen, alkyl and alkenyl groups of up to 20 carbon atoms; alkoxy, thioalkoxy, or amido groups of up to 20 carbon atoms; aryl, alkaryl, or aralkyl groups of up to 20 carbon atoms; aryloxy, thioaryloxy, or anilino groups of up to 20 carbon atoms; aliphatic or aromatic heterocyclic ring groups containing up to 6 ring atoms; carbocyclic ring groups comprising up to 6 ring carbon atoms; or fused ring or bridging groups comprising up to 14 ring atoms; and R.sup.2 represents a trityl group.
    Type: Grant
    Filed: August 28, 1995
    Date of Patent: July 16, 1996
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Sharon M. Simpson, Lori S. Harring
  • Patent number: 5532121
    Abstract: Reduction of mottle and other surface anomalies in photothermographic and thermographic elements is reduced by the incorporation of a fluorinated polymer containing at least two different groups within the polymer chain derived from reactive monomers, the groups being: a fluorinated, ethylenically unsaturated monomer; and a polar, ethylenically unsaturated monomer.
    Type: Grant
    Filed: March 24, 1995
    Date of Patent: July 2, 1996
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Roger K. Yonkoski, Patricia M. Savu
  • Patent number: 5516627
    Abstract: A method for processing a silver halide photographic material. The method comprises the steps of (1) developing, fixing and washing a photographic light-sensitive material which comprises a support and a photographic layer including a silver halide emulsion layer being provided on the support in which the outermost surface of the photographic layer has a matting degree of 0 to 150 mmHg and the silver halide emulsion layer contains colloidal silica particles, (2) drying the silver halide photographic light-sensitive material by contacting with a heat conductive member having a surface temperature of 90.degree. C. to 150.degree. C. which installed in a drying zone of the automatic processing machine. In the above method, the photographic light-sensitive material has a moisture content of 3 g/m.sup.2 to 6.5 g/m.sup.
    Type: Grant
    Filed: February 23, 1995
    Date of Patent: May 14, 1996
    Assignee: Konica Corporation
    Inventor: Toshiyuki Marui
  • Patent number: 5512411
    Abstract: Sulfonyl hydrazides are used as developers in phothothermographic and thermographic elements. The sulfonyl hydrazides have the formula:R.sup.1 --CO--NHNH--SO.sub.2 --R.sup.2wherein R.sup.1 and R.sup.
    Type: Grant
    Filed: August 21, 1995
    Date of Patent: April 30, 1996
    Assignee: Minnesota Mining & Manufacturing Company
    Inventors: Doreen C. Lynch, Sharon M. Simpson, Paul G. Skoug
  • Patent number: 5508146
    Abstract: This invention relates to an imaging element for reductive laser-imaging comprising a support having thereon an imaging layer comprising:a) a reducible Co(III) ammine complex,b) a source of phthalaldehyde, andc) a reducing agent,the imaging layer having an infrared-absorbing material associated therewith in the amount of about 0.001 to about 0.5 g/m.sup.2 of element, and wherein the imaging element has a Lewis acid-containing overcoat layer thereon.
    Type: Grant
    Filed: January 30, 1995
    Date of Patent: April 16, 1996
    Assignee: Eastman Kodak Company
    Inventors: Sharon W. Weber, Lee W. Tutt, Mitchell S. Burberry, Charles D. DeBoer
  • Patent number: 5429907
    Abstract: The present invention provides an imaging element comprising a support, a porous layer, a photosensitive layer containing a photopolymerizable composition and optionally a stripping layer characterized in that there is provided a barrier layer between said photosensitive layer and said porous layer said barrier layer being impermeable for the photopolymerizable composition at ambient temperature and capable of increasing its permeability with increasing temperature.
    Type: Grant
    Filed: March 30, 1994
    Date of Patent: July 4, 1995
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Herman Uytterhoeven, Luc Bastiaens
  • Patent number: 5424174
    Abstract: A heat-developable photosensitive material is disclosed which has a support and a photosensitive layer containing at least an organic silver salt, a silver halide and a reducing agent, a water-soluble polymeric layer containing a water-soluble polymeric material, and a hydrophobic polymeric layer containing a hydrophobic polymeric material.
    Type: Grant
    Filed: September 15, 1994
    Date of Patent: June 13, 1995
    Assignee: Canon Kabushiki Kaisha
    Inventors: Kobayashi Motokazu, Tetsuro Fukui, Miki Tamura, Kenji Kagami, Masao Suzuki, Katsuya Nishino
  • Patent number: 5424164
    Abstract: A recording material which comprises a support having provided thereon capsules containing a photosensitive diazonium salt, and a polymerizable coupler. The recording material can give a predetermined hue when light, pressure, heat and the like are applied alone or in combination. The main advantages of the recording material are that a specific hue can be selected safely, mixing of colors can be avoided, desensitization problem does not occur and a fixed image can be obtained.
    Type: Grant
    Filed: November 10, 1994
    Date of Patent: June 13, 1995
    Assignee: Fuji Photo Film Co., Ltd
    Inventors: Masato Satomura, Ken Iwakura, Akira Igarashi
  • Patent number: 5411825
    Abstract: Disclosed is an apparatus for heat development of a migration imaging member containing migration marking material and a softenable material capable of softening upon exposure to heat at a development temperature, which apparatus comprises a heating source, a conveyance means for conveying the migration imaging member past the heating source, a first pinch roller in contact with the conveyance means, and a second pinch roller in contact with the conveyance means, wherein the imaging member passes through a nip between the conveyance means and the first pinch roller subsequent to entering the apparatus and prior to exposure to the heating source and passes through a nip between the conveyance means and the second pinch roller subsequent to exposure to the heating source and prior to exiting the apparatus, wherein the surface temperature of the first pinch roller is maintained at a temperature at least 20.degree. C.
    Type: Grant
    Filed: October 16, 1990
    Date of Patent: May 2, 1995
    Assignee: Xerox Corporation
    Inventor: Man C. Tam
  • Patent number: 5409797
    Abstract: A heat-sensitive recording material for laser recording is provided including a support having thereon a heat-sensitive layer including at least a first substantially colorless coloring component, a second substantially colorless coloring component which reacts with the first substantially colorless coloring component to develop a color, and an infrared-absorbing dye.
    Type: Grant
    Filed: September 7, 1993
    Date of Patent: April 25, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Noriyuki Hosoi, Masao Yabe, Naoto Yanagihara
  • Patent number: 5393638
    Abstract: An image is formed by subjecting to imagewise exposure an image forming medium containing at least a heat-diffusible coloring matter, a photosensitive silver halide, an organic silver salt, a reducing agent, a polymerizable polymer precursor and a photopolymerization initiator; heating the image forming medium thus treated; subjecting it to polymerization exposure to form a polymerized area and an unpolymerized area in the image forming medium; separating the polymerized area from the unpolymerized area; and superposing an image receiving medium onto the unpolymerized area to transfer the heat-diffusible coloring matter in the unpolymerized area to the image receiving medium.
    Type: Grant
    Filed: June 10, 1991
    Date of Patent: February 28, 1995
    Assignee: Canon Kabushiki Kaisha
    Inventors: Akihiro Mouri, Masato Katayama, Kazuo Isaka, Tetsuro Fukui
  • Patent number: 5364739
    Abstract: An X-Ray sensitive composition including one or several photopolymerizable monomer or photocrosslinkable polymer systems and thermochromic substances which can be used in a dry X-Ray reproduction process. The process is based on the different dielectric constants and dielectric losses exhibited by a monomer and the corresponding polymer or a polymer and the crosslinked polymer and the reaction of certain thermochromic substances which exhibits a specific threshold temperature above which these substances change from a colorless form to a color stable form. The X-Ray sensitive element is exposed according to a pattern of X-Ray with spatial modulation providing an X-Ray image to form a latent image of polymerized or crosslinked zones and unpolymerized or non crosslinked zones.
    Type: Grant
    Filed: February 13, 1992
    Date of Patent: November 15, 1994
    Assignee: Board of Regents, The University of Texas System
    Inventor: Jean J. Robillard
  • Patent number: 5316885
    Abstract: A powder ink having in the structure a heat-fusible core comprising a thermo-melting substance and a coloring matter and a shell covering the core surface and comprising a resin product obtained by reacting:(1) 0 to 30 mole % of a monovalent isocyanate compound and/or a monovalent isothiocyanate compound and(2) 100 to 70 mole % of at least divalent isocyanate and/or at least divalent isothiocyanate compound with(3) 0 to 30 mole % of a compound having an active hydrogen atom to react with the isocyanate and isothiocyanate groups of (1) ana (2) and(4) 100 to 70 mole % of a compound having at least two active hydrogen atoms to react with the isocyanate and isothiocyanate groups of (1) and (2); at a molar ratio of (1) and (2) to (3) and (4) in the range between 1:1 and 1:2. At least 30 percent of all the linkages involved in the isocyanates and the isothiocyanates in the resin product are thermally linkages.
    Type: Grant
    Filed: August 12, 1991
    Date of Patent: May 31, 1994
    Assignee: Kao Corporation
    Inventors: Mitsuhiro Sasaki, Kuniyasu Kawabe
  • Patent number: 5270145
    Abstract: A process for forming a dye image including the steps of: (a) exposing a photographic element comprising a light sensitive silver halide emulsion layer containing a color coupler compound capable of forming a heat transferable dye upon development; (b) developing the exposed element resulting from step (a) with a color developer solution to form a heat transferable dye image; (c) heating the exposed, developed element resulting from step (b) to thereby transfer the dye image from the emulsion layer to a dye receiving layer which is part of the photographic element or part of a separate dye receiving element brought into contact with the photographic element; and (d) separating the emulsion layer from the dye receiving layer containing the transferred dye image; wherein the color coupler compound is of the following formula (I):COUP--B (I)wherein COUP represents a coupler moiety capable of forming a heat transferable dye upon reaction of the coupler compound with an oxidized product of the developing solution
    Type: Grant
    Filed: December 6, 1991
    Date of Patent: December 14, 1993
    Assignee: Eastman Kodak Company
    Inventors: Roland G. Willis, John Texter
  • Patent number: 5246811
    Abstract: An image forming method uses a light-sensitive material and an image receiving material. The light-sensitive material comprises a support and a light-sensitive layer provided thereon. The light-sensitive layer contains silver halide, a reducing agent, pigment particles, an ethylenically unsaturated polymerizable compound and a base precursor. The silver halide, the reducing agent, the pigment particles, the polymerizable compound and the base precursor are contained in microcapsules dispersed in the light-sensitive layer. The image forming method comprises imagewise exposing the light-sensitive material, developing the light-sensitive material to polymerize the polymerizable compound, and pressing the light-sensitive material on the image receiving material to transfer the pigment particles to the image receiving material. In the present invention, the light-sensitive material is pressed at a pressure in the range of 20 kg/cm.sup.2 to 500 kg/cm.sup.2 while heating the light-sensitive material at 30.degree. C.
    Type: Grant
    Filed: January 17, 1992
    Date of Patent: September 21, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Manabu Higuchi
  • Patent number: 5227277
    Abstract: An imaging medium comprises a layer, depolymerizable by exposure to actinic radiation and substantially non-tacky prior to depolymerization but becoming tacky upon at least partial depolymerization, disposed adjacent a layer of an imaging material, which has a cohesive strength greater than the adhesive strength between the imaging material and the depolymerizable layer prior to depolymerization. This medium is imagewise exposed to radiation, thereby causing at least partial depolymerization of the polymer in the exposed areas, so rendering these exposed areas tacky and firmly attaching exposed areas of the imaging material layer to the depolymerizable layer. The unexposed areas of the imaging material are then removed from the depolymerizable layer.
    Type: Grant
    Filed: April 17, 1991
    Date of Patent: July 13, 1993
    Assignee: Polaroid Corporation
    Inventor: Kenneth C. Waterman
  • Patent number: 5225314
    Abstract: An imaging medium comprises a layer, depolymerizable by exposure to actinic radiation and undergoing a reduction in cohesivity upon at least partial depolymerization, disposed adjacent a layer of an imaging material, which has a cohesive strength greater than the cohesive strength of the depolymerizable layer after depolymerization. This medium is imagewise exposed to radiation, thereby causing at least partial depolymerization of the polymer in the exposed areas, so rendering these exposed areas lower in cohesivity than the unexposed areas. The exposed areas of the imaging material are then removed from the depolymerizable layer.
    Type: Grant
    Filed: April 17, 1991
    Date of Patent: July 6, 1993
    Assignee: Polaroid Corporation
    Inventors: Kenneth C. Waterman, Michael A. Young, Edward P. Lindholm
  • Patent number: 5213940
    Abstract: The present invention relates to an image recording method utilizing photosensitive microcapsules. These photosensitive microcapsules have characteristics of being rendered hardenable upon exposure. Further, only the hardenable photosensitive microcapsules can be hardened. In this image recording method, an optional image pattern is initially exposed to a photosensitive recording medium having thereon the photosensitive microcapsules for rendering only the exposed photosensitive microcapsules hardenable corresponding to the image pattern. Subsequently, the exposed photosensitive recording medium is heated to harden only the hardenable photosensitive microcapsules. Further, the photosensitive recording medium is entirely exposed again with light to render the unhardened photosensitive microcapsules hardenable.
    Type: Grant
    Filed: April 3, 1992
    Date of Patent: May 25, 1993
    Assignee: Brother Kogyo Kabushiki Kaisha
    Inventors: Kouji Inaishi, Naomichi Kobayashi
  • Patent number: 5204210
    Abstract: A method of forming a patterned, poly-crystalline diamond film on a substrate is disclosed. First, a photoresist layer is applied to a substrate. A diamond powder layer is formed on the photoresist layer either through spray-coating, dip-coating, spin-coating using a diamond-powder suspension, and the like. The photoresist layer is exposed to electromagnetic radiation through a mask either before or after the diamond powder layer is applied. Then, the photoresist layer is developed, after which the substrate is heated causing the photoresist layer to carbonize. The substrate is exposed to a mixture of hydrogen-containing and carbon-containing gases which are decomposed in a processing apparatus. Hydrogen in this gas mixture etches away at the carbonized photoresist layer leaving behind the patterned diamond powder layer. Carbon in these carbon-containing gases combines with the diamond particles in the diamond powder layer to form diamond structures on the substrate.
    Type: Grant
    Filed: December 7, 1990
    Date of Patent: April 20, 1993
    Assignee: Xerox Corporation
    Inventors: Frank Jansen, Mary A. Machonkin
  • Patent number: 5196297
    Abstract: This invention relates to novel recording materials which employ color-forming di- and triarylmethane compounds possessing certain S-containing ring-closing moieties, namely, or thiolactone, dithiolactone or thioether ring-closing moiety and to a method of forming color by contacting these dye precursor compounds with a Lewis acid material capable of opening the thiolactone, dithiolactone or thioether ring-closing moiety whereby the compound is rendered colored, that is, converted to its chromophore color.
    Type: Grant
    Filed: December 5, 1986
    Date of Patent: March 23, 1993
    Assignee: Polaroid Corporation
    Inventors: Edward J. Dombrowski, Jr., James R. Freedman, Patrick F. King
  • Patent number: 5196288
    Abstract: An image forming method of imagewise exposing and heating a light-sensitive material is disclosed. The light-sensitive material comprises a support and a light-sensitive layer provided thereon. The light-sensitive layer contains silver halide, a reducing agent, an ethylenically unsaturated polymerizable compound, a color image forming substance and a base precursor. The silver halide, the reducing agent, the polymerizable compound, the color image forming substance and the base precursor are contained in microcapsules which are dispersed in the light-sensitive layer. According to the present invention, the support is made of a thin polymer film having a thickness of not more than 75 .mu.m. The light-sensitive material is heated from the side of the support for 0.1 to 5 seconds.
    Type: Grant
    Filed: September 9, 1991
    Date of Patent: March 23, 1993
    Assignees: Fuji Photo Film Co., Ltd., Seiko Epson Corp., Seiko Instruments, Inc.
    Inventor: Taku Nakamura
  • Patent number: 5153112
    Abstract: The improved method of processing a silver halide photographic material that has at least one light-sensitive silver halide emulsion layer on one side of a support and which has at least one back coating layer on the other side of the support is characterized in that said silver halide photographic material contains at least one specific dye and at least one anionic surfactant and the development, fixing, washing and/or stabilizing steps are performed within a time period of 40 seconds and at a line speed of at least 1,500 mm/min. The method is capable of processing the silver halide photographic material without producing either substantial or uneven color remnant.
    Type: Grant
    Filed: October 31, 1990
    Date of Patent: October 6, 1992
    Assignee: Konica Corporation
    Inventors: Kazuhiro Yoshida, Syoji Nishio
  • Patent number: 5147743
    Abstract: A process for the preparation of a color filter is described utilizing an exposure step of a light-sensitive material, imagewise exposing, toning and heat treating.
    Type: Grant
    Filed: June 28, 1990
    Date of Patent: September 15, 1992
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Mario Grossa
  • Patent number: 5139818
    Abstract: Photochemical and electroless metallization techniques have been combined to create high resolution circuits with line widths and spaces of about one mil on alumina substrates. In this process, small amounts of a xylene-soluble platinum metallo-organic compound are first applied to the surface of the alumina substrate. A mask is then used to selectively expose the platinum metallo-organic compound to ultraviolet light in the areas that are to be metallized, so as to transform the platinum metallo-organic compound into a xylene-insoluble form. After a xylene rinse removes the original soluble platinum compound from the unexposed areas, the substrate is fired in air at about 450.degree. C. for about five minutes, so as to pyrolize the insoluble, irradiated platinum metallo-organic compound into catalytically active platinum. This is followed by electroless deposition of copper onto the ultraviolet-treated regions where the catalytically active platinum resides.
    Type: Grant
    Filed: June 6, 1991
    Date of Patent: August 18, 1992
    Assignee: General Motors Corporation
    Inventor: Andrew M. Mance
  • Patent number: 5120634
    Abstract: An improved method for forming a patterned resist layer on a semiconductor body, after an energy radiation has been projected on a desired region of the resist layer, wherein a layer of negative-working resist on the semiconductor body is heated in an atmosphere which is free from any oxidizing gases, so that post-polymerization of said negative-working resist is substantially accomplished. The exposed and the post-polymerized negative-working resist is then developed. This method provides a high accuracy of the resulting resist patterns and constant thickness of the resist coating remaining in the exposed area after developing. It additionally provides an increased percentage of the thickness of the residual resist coating to the initial coating thickness. Further, it enables straight-line processing of the resists.
    Type: Grant
    Filed: April 25, 1991
    Date of Patent: June 9, 1992
    Assignee: Fujitsu Limited
    Inventor: Koichi Kobayashi
  • Patent number: 5084372
    Abstract: A light-sensitive composition for the preparation of printing plates is described, which contains a water-insoluble binder which is soluble in aqueous-alkaline solutions; a light-sensitive component which is an o- or p-quinone diazide, a diazonium salt polycondensation product or a mixture ofa) a compound which eliminates an acid on exposure to light andb) a compound having at least one C--O--C group which can be split by acid; and a thermo-crosslinking compound which is a cyclical acid amide of the general formula: ##STR1## wherein R denotes a hydrogen atom or an alkyl group. The printing plates can be baked at lower temperatures than plates without a crosslinking agent, but nevertheless have a long shelf life.
    Type: Grant
    Filed: January 23, 1991
    Date of Patent: January 28, 1992
    Assignee: Hoechst Celanese Corporation
    Inventors: Shane Hsieh, Paul Stahlhofen
  • Patent number: 5047310
    Abstract: A photographic material is disclosed, which comprises a support having provided thereon at least one electrically conductive layer, said conductive layer comprising carbon black having a dibutyl phthalate absorption capability of at least 80 cc/100 g and a hydrophilic binder.
    Type: Grant
    Filed: December 16, 1986
    Date of Patent: September 10, 1991
    Inventors: Hiroyuki Ozaki, Hideki Naito, Satoru Sawada
  • Patent number: 5032493
    Abstract: A method of drying a photographic light-sensitive material after development-processing in an automatic processor comprising a dry-processing portion, wherein the method comprises drying steps (a) and (b):(a) drying the photographic light-sensitive material to an extent that 65% of the moisture content of the photographic material just after squeezing is dried out; and subsequently,(b) drying the photographic light-sensitive material at a temperature which is set based on temperature and humidity conditions of an area where the automatic processor is installed.
    Type: Grant
    Filed: September 14, 1990
    Date of Patent: July 16, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Mori, Kunio Ishigaki
  • Patent number: 4985346
    Abstract: A photo and heat sensitive recording medium has a front side coated with a layer of photo-curable composition which has photo-curability and heat fusibility in an uncured state. In an image recording method, the recording medium is exposed to light on the basis of image information, to photo-cure light-illuminated areas of the layer of photo-curable composition. Subsequently, the recording medium is superimposed upon a side of a subject being transferred. The superimposed recording medium and subject are heated to transfer an image corresponding to uncured areas on the recording medium, onto the side of the subject.
    Type: Grant
    Filed: February 23, 1989
    Date of Patent: January 15, 1991
    Assignee: Brother Kogyo Kabushiki Kaisha
    Inventor: Kouji Suzuki
  • Patent number: 4963459
    Abstract: The present invention provides a method of registering to an imaging web moving within an imaging web handling apparatus along an imaging web path. The imaging web comprises a support having a coating of photosensitive microcapsules on the surface thereof. The photosensitive microcapsules have an internal phase of a photosensitive composition and a color former. Exposure of the imaging web to actinic radiation defines an image area and a border area.A registration mark is formed on the web by exposing a portion of the web area to actinic radiation so that the portion undergoes a color or reflection change, or exposing all but a portion of the border area to actinic radiation so that the exposed area undergoes a color or reflection change. The registration mark is detected and in response to detection of the registration mark, an operation is performed on the imaging web.
    Type: Grant
    Filed: August 25, 1989
    Date of Patent: October 16, 1990
    Assignee: The Mead Corporation
    Inventors: Jack Beery, David A. Boyer