Color Correcting Patents (Class 430/359)
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Patent number: 4948698Abstract: A heat-processible color photographic material having on a base support at least a light-sensitive silver halide, a reducing agent, a binder and a dye-providing material represented by the following general formula (1) in disclosed. where A is a coupler site capable of dye formation by entering into a coupling reaction with the oxidized product of the reducing agent; L is a divalent linkage grop binding to A at the active point of the coupler site represented by A; B is a ballast group having a sufficient molecular size or shape to render the dye-providing material of the general formula (1) substantially immobile during thermal development; Dye is a dye site, n is 1, 2 or 3, part of the coupler site A optionally serving as part of the dye site Dye.Type: GrantFiled: October 10, 1989Date of Patent: August 14, 1990Assignee: Konica CorporationInventor: Tawara Komamura
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Patent number: 4942114Abstract: A silver halide photographic material having at least one silver halide emulsion layer on a support, comprising a compound of formula (I):PWR--(Time).sub.t --FWA (I)in which PWR represents a group capable of releasing (Time).sub.t --FWA upon reduction; FWA represents a group which functions as a brightening agent; Time represents a group capable of releasing FWA through a reaction which follows the release of (Time).sub.t --FWA from PWR; and t represents an integer of 0 or 1.Type: GrantFiled: May 2, 1988Date of Patent: July 17, 1990Assignee: Fuji Photo Film Co., Ltd.Inventors: Keisuke Shiba, Keizo Koya
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Patent number: 4935321Abstract: This invention relates to a color photographic silver halide recording material containing a dye image-forming coupler compound and a carbonamide compound which is capable of altering the spectral absorption properties of a dye formed by reaction of the coupler compound with oxidized developing agent.Type: GrantFiled: November 14, 1989Date of Patent: June 19, 1990Assignee: Eastman Kodak CompanyInventor: Paul B. Merkel
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Patent number: 4886736Abstract: A silver halide color photographic material comprising (1) at least one coupler and (2) at least one compound represented by formula (I) ##STR1## wherein EAG represents a group capable of accepting an electron from a reducing substance; R.sup.1 and R.sup.2 each represents a chemical bond or a divalent substituent, or R.sup.1 and R.sup.2 are linked together to form a cyclic structure when linked with (Time).sub.t PUG; or R.sup.1 and R.sup.2 each represents a substituent, or R.sup.1 and R.sup.2 are linked together to form a cyclic structure when not linked with (Time).sub.t PUG; Time represents a group capable of releasing PUG, which is released by the cleavage of the single bond between the oxygen atom and the nitrogen atom in the compound; t represents 0 or 1; PUG represents a photographically useful group; and the dotted lines mean that at least one of them forms a chemical bond, and a method for forming an image using the material.Type: GrantFiled: June 12, 1987Date of Patent: December 12, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Koki Nakamura, Kei Sakanoue, Seiji Ichijima
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Patent number: 4883746Abstract: A novel silver halide color photographic material is provided which comprises at least one colored coupler represented by the general formula (I) and at least one cyan coupler represented by the general formula (II), (III), (IV) or (V): ##STR1## wherein R.sub.1 represents an aromatic or heterocyclic group; R.sub.2 represents a group capable of being substituted on a naphthol ring; R.sub.3 represents an aliphatic, heterocyclic or aromatic group; R.sub.4 represents an aromatic group excluding p-cyanophenyl group; R.sub.5 represents an aromatic or heterocyclic group; R.sub.6 represents an aliphatic group; n represents an integer of 0 to 4; m represents an integer of 0 to 3; A--B--N.dbd.Type: GrantFiled: February 13, 1989Date of Patent: November 28, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Yasuhiro Shimada, Hiroshi Fukuzawa, Seiji Ichijima
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Patent number: 4879203Abstract: A process for producing masked positive color images by the silver dye bleach process using a developer solution which contains 0.3 to 1.0 mol/l of a bromide.Type: GrantFiled: April 4, 1988Date of Patent: November 7, 1989Assignee: Ciba-Geigy AGInventor: Urs J. Furholz
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Patent number: 4871655Abstract: A light-sensitive silver halide color photographic material, comprising at least one photographic constituent layer containing a multi-functional dye which becomes substantially colorless in the presence of the oxidized product of a color developing agent through the reaction with the oxidized product, and becomes substantially colorless in the absence of the oxidized product of the color developing agent during the color-photographic processing step.According to the present invention, a color light-sensitive material containing a multi-functional compound having excellent sharpness, good color reproducibility and further excellent graininess can be obtained.Type: GrantFiled: December 30, 1987Date of Patent: October 3, 1989Assignee: Konica CorporationInventors: Mitsuto Fujiwhara, Takashi Uchida, Toshihiko Kimura
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Patent number: 4810603Abstract: The tonality of a produced color image transferred to an image receiving material is measured. The differences between equivalent neutral shades of a reference color image and equivalent neutral shades of the reproduced color image are compared to calculate tonal correction values for corrected equivalent neutral shades. Tonality correction means is controlled on the basis of said tonal correction values.Type: GrantFiled: February 5, 1988Date of Patent: March 7, 1989Assignee: Fuji Photo Film Co., Ltd.Inventor: Yoshiharu Okino
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Patent number: 4808502Abstract: This invention relates to a color photographic silver halide recording material containing a dye image-forming coupler compound and a compound which is capable of altering the spectral absorption properties of a dye formed by reaction of the coupler compound with oxidized developing agent.Type: GrantFiled: July 25, 1988Date of Patent: February 28, 1989Assignee: Eastman Kodak CompanyInventor: Paul B. Merkel
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Patent number: 4783385Abstract: Process for production of photographic masks for tonal correction by dry dot etching comprising exposing a mask film, e.g., positive film, behind a film combination of half-tone positives and negatives that contains at least one pair of a positive and a negative of the same color separation, said pair being separated from one another by a spacer film, e.g., transparent, matt film, etc. The half-tone values at the points to be corrected are in the range of 30-70%.Type: GrantFiled: March 31, 1987Date of Patent: November 8, 1988Assignee: E. I. Du Pont de Nemours and CompanyInventor: Gerhard F. Duesdieker
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Patent number: 4777120Abstract: A photographic masking coupler containing in the coupling position a coupling-off group that is capable of reacting with oxidized color developing agent to form a water-insoluble dye in non-image areas and a water-soluble compound in image areas of a color photographic element enables formation of a colored integral mask for color correction upon exposure and processing of the element. The masking couplers are essentially colorless in a color photographic element. Such a photographic masking coupler is advantageous in a color photographic element and process.Type: GrantFiled: May 18, 1987Date of Patent: October 11, 1988Assignee: Eastman Kodak CompanyInventor: Philip T. S. Lau
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Patent number: 4774181Abstract: An imaging element is described which comprises a dye image-forming coupler compound and a compound capable of releasing a fluorescent dye as a function of silver halide development. The released dye is capable of fluorescence which optically compensates for unwanted absorption of an image dye thereby resulting in color correction of the image.Type: GrantFiled: June 25, 1987Date of Patent: September 27, 1988Assignee: Eastman Kodak CompanyInventors: Nair N. Ravindran, Ramanuj Goswami
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Patent number: 4764454Abstract: A novel silver halide color photographic material is provided comprising a compound of the general formula (I):LIG-A-LVG (I)wherein A represents a group which reacts with an oxidation product of a developing agent to cleave the bond to LVG; LVG represents a coupling-off group; and LIG represents a group which reacts with metal ions to form a complex compound.A novel method of processing the instant silver halide color photographic material is provided including a processing step using a processing solution of an iron (II) ion concentration of 1.times.10.sup.-6 to 1 mol/l. In the processing step, the potential of a bath having a bleaching capacity containing an aminopolycarboxylic acid-iron (III) complex salt is 150 mV or less.Type: GrantFiled: December 18, 1986Date of Patent: August 16, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Seiji Ichijima, Kei Sakanoue
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Patent number: 4749641Abstract: An imaging element is described which comprises a colorless coupler compound which contains an oxidizable lueco dye moiety and optionally a colorless dye image-forming coupler compound. Following color development a masking dye is obtained by oxidation of the leuco dye moiety in areas where no photographic development occurs.Type: GrantFiled: September 15, 1986Date of Patent: June 7, 1988Assignee: Eastman Kodak CompanyInventors: John E. Kaufman, Max H. Stern
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Patent number: 4746592Abstract: Color correction of negative images resulting from diffusion transfer photographic recording materials is obtained through use of two dye image-providing compounds, each of which is capable of releasing a diffusible dye. One of the dye image-providing compounds releases a diffusible dye as a result of silver halide development whereas the other compound releases dye in areas where no development occurs.Type: GrantFiled: August 27, 1986Date of Patent: May 24, 1988Assignee: Eastman Kodak CompanyInventor: Kin K. Lum
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Patent number: 4717646Abstract: A method and system are provided for enabling amateurs and non-professionals to restore faded or discolored color photographs and snapshots to their original condition by treating the faded or discolored color photographs and snapshots to clean areas with a remover of anhydrous acetone-free diacetone and coating or coloring the cleaned areas with a color corrective restorer comprising a powdered dye embedded or dispersed in anhydrous diacetone preferably in the relative proportions of 40 grains dye: 30 ml anhydrous diacetone or by using wax cube compositions of alcoholic paraffin or other suitable wax with acetone-free diacetone in the relative proportions of 100 grams wax in alcohol: 1-3 grams powdered dye therein in the optional presence of liquid glycerin and/or lecithin. Procedure and equipment as described for carrying out the invention which is characterized by the slower evaporation rate of diacetone as compared to denatured alcohol to provide adequate time to carry out the process steps.Type: GrantFiled: September 5, 1986Date of Patent: January 5, 1988Inventor: Lewis A. Giorgi
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Patent number: 4690888Abstract: A photosensitive silver halide colored photographic material having (1) ballasted couplers combined with photosensitive silver halide emulsions and (2) colored compounds capable of reacting with oxidized developing agent, wherein the colored compounds are capable of diffusing in the photographic material during developing treatments and have their principal absorption in the main absorption wavelength region of the dye produced by the reaction of the coupler with the developing agent.Type: GrantFiled: September 10, 1985Date of Patent: September 1, 1987Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Mitsuto Fujiwhara, Takao Nimura, Yasumasa Numata, Yasuko Matsubara
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Patent number: 4678740Abstract: A photographic matte for use in traveling matte photography is formed by recording a separation of a first screen-color separation of an image on a first film layer and recording a separation of a different second color on a second layer. Preferably, the second color is complementary to the screen color. One layer is developed to form a positive image and the other to form a negative image, these images reinforcing each other. One image is formed by black dye, using a coupler and a color developer and the other is formed by a black dye destruct technique in which the developed portion of the silver halide emulsion is removed. According to another aspect of the invention, a matte of increased density can be formed without commensurate image growth by combining a black dye image with a silver image.Type: GrantFiled: April 29, 1985Date of Patent: July 7, 1987Inventor: James N. Catania
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Patent number: 4647527Abstract: A silver halide color photographic light-sensitive material is described, which is of ultra-high-sensitivity and is characterized by having the following light-sensitive layer unit (I), (II) or (III):Unit (I): a light-sensitive layer unit comprising: (a) a blue- and green-sensitive layer containing (a-1) a yellow image-forming coupler, (a-2) a magenta image-forming coupler, and (a-3) a cyan colored coupler; and (b) a green- and red-sensitive layer containing (b-1) a cyan image-forming coupler, (b-2) a magenta image-forming coupler, and (b-3) a yellow colored coupler.Unit (II): a light-sensitive layer unit comprising: (a) a blue- and red-sensitive layer containing (a-1) a yellow image-forming coupler, (a-2) a cyan image-forming coupler, and (a-3) a magenta colored coupler; and (b) a green- and red-sensitive layer containing (b-1) a magenta image-forming coupler, (b-2) a cyan image-forming coupler, and (b-3) a yellow colored coupler.Type: GrantFiled: May 22, 1984Date of Patent: March 3, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Shinpei Ikenoue, Akikazu Mikawa, Seiji Ichijima
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Patent number: 4571373Abstract: The exposure latitude of positive-acting, color pre-press proofing photosensitive articles can be improved by positioning an optical filter between the separation half-tone positive and the photosensitive article.Type: GrantFiled: June 11, 1984Date of Patent: February 18, 1986Assignee: Minnesota Mining and Manufacturing CompanyInventors: Arlene K. Musser, Peter M. Koelsch
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Patent number: 4557998Abstract: Essentially colorless, hydrophilic ligand-releasing polymers are prepared from ethylenically unsaturated polymerizable monomers represented by the structure: ##STR1## wherein R' is hydrogen or lower alkyl, COUP is a photographic color coupling moiety, LINK is a coupling-off group which can be cleaved by an oxidized developer composition, and LIG is a ligand capable of complexing with metal ions, while joined to the polymer, to form a dye. These polymers also have recurring units which impart hydrophilicity to the polymer. These polymers form metal complex dyes in unexposed areas of photographic elements only, while the ligand is cleaved from the polymer in the exposed areas and washed out of the element.Type: GrantFiled: January 2, 1985Date of Patent: December 10, 1985Assignee: Eastman Kodak CompanyInventors: William N. Washburn, Kenneth R. Hollister
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Patent number: 4555477Abstract: A process of obtaining highly stable color masking dyes comprises use of an element which has a support having thereon at least one silver halide emulsion layer having associated therewith an essentially colorless, immobile, ligand-releasing compound of the structure LIG-X. In this structure, X is a group which, as a function of silver halide development, is cleaved from LIG, and LIG is a ligand capable of complexing with metal ions while joined to X to form a color masking dye. A color masking dye is formed by developing the imagewise exposed areas of the described element with a developing agent to cleave LIG from X and washing substantially all of the cleaved LIG moieties in those areas out of the element, and treating the element with metal ions to form a masking dye complex with LIG-X in unexposed areas.Type: GrantFiled: January 2, 1985Date of Patent: November 26, 1985Assignee: Eastman Kodak CompanyInventor: William N. Washburn
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Patent number: 4497893Abstract: A silver halide color reversal photographic material comprising a backing layer containing both gelatin of an isoelectric point of 5.5 or more and a cationic polymer is disclosed. By utilizing the particular backing layer the color reversal photographic material has increased retouchability.Type: GrantFiled: January 31, 1984Date of Patent: February 5, 1985Assignee: Fuji Photo Film Co., Ltd.Inventors: Naoyasu Deguchi, Koji Kameyama, Taku Nakamura
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Patent number: 4483916Abstract: Method of improving the color balance of a multicolor reversal image obtained in a photographic material itself or obtained by a diffusion transfer reversal process in an image receiving material is provided, wherein said method comprises, as illustrated in FIG. 3, the steps of:(1) providing a photographic silver halide material (4) capable of yielding in said material or in an image receiving layer a multicolor reversal image of average gradient of at least 1.8;(2) image-wise exposing said photographic material to or through a multi-color continuous tone original (2) while keeping in the optical path between the original and the photographic material a light-distribution means (3) dividing the light in line-like or dot-like portions over the exposed area of the photographic material,(3) developing and reversal-processing said photographic material, e.g. by dye diffusion transfer-processing, hereby producing a reversal image with average gradient of at most 1.50 and reduced color point spreading.Type: GrantFiled: February 2, 1983Date of Patent: November 20, 1984Assignee: Agfa-Gevaert, N.V.Inventor: Christiaan G. Thiers
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Patent number: 4458002Abstract: A process for the production of a multicolor reversal image with improved color balance is provided which process comprises the steps of directing incident image light dot- or linewise modulated by a light-distributing means onto a multicolor photographic silver halide emulsion material containing a blue-, a green- and a red-sensitive silver halide emulsion layer and processing said silver halide emulsion layers to form a color reversal image.In the maximum density part of the dots or lines of said light distributing means e.g. a contact screen the ratio of the absorption density for the light corresponding with the spectral sensitivity region of the silver halide emulsion layer being during the exposure most remote from the light-distributing means to the absorption density for the light of the whole visible spectrum (400-700 nm) is higher than the said ratio in any other density part of the dots or lines (see FIG. 1).Type: GrantFiled: May 17, 1983Date of Patent: July 3, 1984Assignee: AGFA-Gevaert, N.V.Inventors: Wilhelmus Janssens, Christiaan G. Thiers, Wilfried F. Liekens
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Patent number: 4427763Abstract: A color photographic recording material, in which a precursor compound for a yellow mask coupler is contained in a green-sensitive layer or in a layer adjacent thereto and in which a blue-sensitive layer is arranged between this layer and the layer support, permits very good sharpness with satisfactory speed.Type: GrantFiled: August 30, 1982Date of Patent: January 24, 1984Assignee: Agfa-Gevaert AktiengesellschaftInventors: Joachim W. Lohmann, Gunter Renner, Wolfgang Sauerteig
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Patent number: 4416971Abstract: In one embodiment, the present invention is concerned with novel xanthene compounds of the formula ##STR1## wherein each R.sup.1 is the same and is selected from ##STR2## R.sup.2 is alkyl, R.sup.3 is an electron-withdrawing group positioned ortho, meta or para to said N atom, R.sup.4 is hydrogen, alkyl or an electron-withdrawing group positioned ortho, meta or para to said N atom; R.sup.5 is alkyl; X is hydrogen, an electron-withdrawing group or an electron-donating group; and A is an anion. In another embodiment, the present invention is concerned with photographic products and processes employing these xanthene compounds, e.g., as photographic light-screening dyes.Type: GrantFiled: December 28, 1982Date of Patent: November 22, 1983Assignee: Polaroid CorporationInventors: Alan L. Borror, Louis Cincotta, John W. Lee, Jr.
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Patent number: 4410613Abstract: The invention relates to a process and an equipment for making color enlaments in additive method, where the device can be fitted onto the traditional enlargers. By using the solution according to the invention the arrangement of the additive color filters under the lens of the enlarger can be solved in a stable but not containing manner, simultaneously ensuring easy and alternating actuating and integration of the colors of the negative. By means of the comparative process, by using the color-analyzer mask and the properly dark colored reference standards belong to the equipment, the color and density balance of the prints to be enlarged can be adjusted by the way of one single trial development, independent of the individual subjective color perceptional ability.Type: GrantFiled: September 14, 1981Date of Patent: October 18, 1983Assignee: Ofotert Optikai Finommechanikai es Fotocikkeket Ertekesito VallalatInventor: Miklos Soskuthy
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Patent number: 4368256Abstract: Production of masked positive color images by the silver dye bleach process, by exposure of a photographic material for the silver dye bleach process, silver developing, dye bleaching, silver bleaching and fixing, optionally the silver bleaching is carried out simultaneously with the dye bleaching and/or the fixing, in a single processing bath.Type: GrantFiled: July 13, 1981Date of Patent: January 11, 1983Assignee: Ciba-Geigy AGInventors: Herbert Mollet, Dieter Wyrsch
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Patent number: 4339517Abstract: Color correction is conducted in a color printing system for negatives having undesirable color balance. The negatives are classified into groups, namely a group consisting of under-exposed negatives, a group consisting of over-exposed negatives, a group consisting of negatives exposed under tungsten light, a group consisting of negatives exposed under fluorescent light, a group consisting of negatives susceptible to color failure, a group consisting of negatives having high color temperature, a group consisting of negatives having low color temperature and a group consisting of aged negatives. In the color printing system, color correction is conducted in accordance with the group to which the negative to be printed belongs. The classification is carried out by measuring various characteristics such as large area transmission density (LATD), red, green and blue large area transmission densities, hue of the maximum density point, and ratio of area of particular colors.Type: GrantFiled: April 15, 1980Date of Patent: July 13, 1982Assignee: Fuji Photo Film Co., Ltd.Inventor: Taizo Akimoto
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Patent number: 4329411Abstract: The sensitometric properties of multicolor diffusion transfer film units may be modified after the photosensitive element has been coated. Sensitometric modification is effected by a photoexposure through a layer of a color correction dye(s). In a preferred embodiment, the color correction dye(s) is bleachable and is contained in a layer over the image-receiving layer.Type: GrantFiled: March 21, 1980Date of Patent: May 11, 1982Assignee: Polaroid CorporationInventor: Edwin H. Land
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Patent number: 4310617Abstract: Production of masked positive color images by the silver dye bleach process, by exposing a photographic material for the silver dye bleach process, silver developing, dye-bleaching, silver-bleaching and fixing, optionally, the step of silver-bleaching is carried out in a combined treatment bath together with dye-bleaching and/or fixing.Type: GrantFiled: August 1, 1980Date of Patent: January 12, 1982Assignee: Ciba-Geigy AGInventors: Herbert Mollet, Alfred Oetiker, Carlo Boragine
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Patent number: 4294900Abstract: A process for producing a multicolor optical filter by exposing a multilayer color photographic material comprising:(1) a silver halide emulsion layer containing a colored coupler (1b) which has one of cyan, magenta or yellow colors and which forms a dye of one of the other two colors than the color of the colored coupler by a coupling reaction with the oxidation product of an aromatic primary amine color developing agent, and(2) a silver halide emulsion layer containing (i) a silver halide emulsion having a sufficiently high sensitivity that it can be exposed without exposing emulsion layer (1) and without increasing the color density in emulsion layer (1) and (ii) a colored coupler (2b) which has the same color as that of the dye formed by the coupling reaction of the colored coupler (1b) and which forms a cyan, magenta or yellow dye but not the color of the colored coupler (1b) or the color of the dye formed by the coupling reaction of the colored coupler (1b); the exposure is through a stripe or mosaic fiType: GrantFiled: February 22, 1980Date of Patent: October 13, 1981Assignee: Fuji Photo Film Co., Ltd.Inventor: Toshiaki Aono
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Patent number: 4293641Abstract: A photographic light-sensitive material is described comprising a support having thereon at least two silver halide photographic emulsion layers capable of forming a silver image upon treatment with an alkaline processing solution in the presence of a developing agent for silver halide after exposure, said material containing an interlayer positioned between said emulsion layers, wherein the improvement comprises said interlayer containing a complex which is formed from a mixture of hydroquinone derivatives having a solidifying point of 100.degree. C. or less, and which are different compounds from the developing agent for silver halide used in the treatment of the material, and a homopolymer or copolymer containing a recurring unit represented by formula (I): ##STR1## wherein R.sub.1 represents a hydrogen atom or a methyl group; Q represents of chemical bond, --COOR.sub.2 -- or --CONHR.sub.2 --; A represents a chemical bond or an oxygen atom; B represents a chemical bond or ##STR2## D represents --CH=CH).Type: GrantFiled: April 24, 1980Date of Patent: October 6, 1981Assignee: Fuji Photo Film Co., Ltd.Inventors: Osamu Takahashi, Shinji Sakaguchi
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Patent number: 4259423Abstract: A color photography printing process prints, a test print on the basis of color intensities of three color ranges transmitted through a small selected area of a test print. The exposure times for the three ranges are recorded besides the print in machine readable code. In the making of the final print the machine readable code controls the printing time. The times determined by the machine readable code may be corrected during the making of the final print by corrections determined by an expert observer of the test print.Type: GrantFiled: January 23, 1979Date of Patent: March 31, 1981Assignees: Armando M. Merlo, Angelo BalsamoInventor: Armando M. Merlo
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Patent number: 4211558Abstract: In a color printing method, a color photosensitive material is exposed in the photographing step to object illuminating light, which is recorded thereon as an optical density by photographic treatments. In the printing step, the optical density is detected to determine blue, green and red exposures, which cause the object illuminating light to be reproduced on a color positive photosensitive material so as to have neutal gray or to be colored to a standard color. An object image on the color/photosensitive material is printed on the color positive photosensitive material with the most suitable color reproduction with the same three-color component exposures as those determined in printing the object illuminating light.Type: GrantFiled: May 22, 1978Date of Patent: July 8, 1980Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Masanobu Oguchi, Hidehiko Ishikawa, Haruyoshi Okuyama, Yasuo Uchida, Kiyoshi Izawa