And Dye Catalyst Patents (Class 430/392)
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Patent number: 4576885Abstract: A photographic silver dye bleach material which contains a compound of the formula ##STR1## in which R is a substituted alkyl, R.sub.1 is substituted or unsubstituted alkyl, p is 1 or 2, q is 0 or 1, p+q having to be 1 or 2, and n is 1 to 20, or a salt of this compound.The benzoquinones used deactivate bleach catalysts which diffuse beyond the silver image area produced by development of the exposed material. The silver dye bleach material containing these compounds is therefore distinguished by high contrast, high sharpness and good color reproduction.Type: GrantFiled: January 16, 1984Date of Patent: March 18, 1986Assignee: Ciba-Geigy AGInventors: Mario Fryberg, Heinrich Schaller, Rolf Steiger, Heinz Peter
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Patent number: 4565775Abstract: In a process for the production of photographic images by the silver dye bleach process, a photograph material is used which, on a base, comprises at least one silver halide-free gelatin layer, which contains a diffusion-resistant bleachable image dye, the gelatin/dye ratio being at most 10:1, and a silver halide emulsion layer which is arranged directly on top of the former layer on the side facing the light source and is free of image dye, and the exposed material is processed in a dye and silver bleach bath which contains a combination of oxidizing agents of the formula (1a) with bleach catalysts of the formulae (2a) and (3), or of the oxidizing agent of the formula (1b) with bleach catalysts of the formula (2b).Type: GrantFiled: January 9, 1985Date of Patent: January 21, 1986Assignee: Ciba-Geigy AGInventor: Eddy Forte
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Patent number: 4546069Abstract: The processing time of exposed photographic silver dye bleach materials is shortened by using a bleach preparation which contains a strong acid, a water-soluble iodide, a water-soluble organic nitro compound, an anti-oxidizing agent, a bleach catalyst, an organic photographic developing agent and/or a benzotriazole derivate.Type: GrantFiled: July 18, 1984Date of Patent: October 8, 1985Assignee: Ciba-Geigy AGInventors: Arnost Libicky, Meinrad Schar
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Patent number: 4391884Abstract: A process for the production of a photographic color image by the silver dye bleach process, using a photographic material which comprises, on a base, at least one light-sensitive silver halide emulsion layer, which can contain a diffusion-resistant bleachable image dye, and immediately above this layer, on the side facing the light source, a silver halide-free layer containing a diffusion-resistant, bleachable image dye.The process gives very sharp photographic color images.Type: GrantFiled: April 17, 1981Date of Patent: July 5, 1983Assignee: Ciba-Geigy AGInventors: Armin Meyer, Carlo Boragine
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Patent number: 4366232Abstract: A method for processing exposed and developed photographic silver dye-bleach materials, in which the exposed and developed material is treated with aqueous bleaching preparations which contain (a) an acid component, (b) a silver complexing agent, (c) one or more bleach catalysts, (d) optionally an antioxidant, (e) optionally a water-soluble oxidizing agent and (f) optionally a bleaching accelerator.A water-soluble and as a rule solid adduct of an acid amide or a lactam and a strong mineral acid is used as acid component (a).Type: GrantFiled: February 17, 1981Date of Patent: December 28, 1982Assignee: Ciba-Geigy Ltd.Inventors: Hansjorg Buser, Adolf Morand
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Patent number: 4357280Abstract: A method of processing photographic silver dye bleach materials which have been exposed imagewise is provided. The process steps are (1) silver developing, (2) dye bleaching, (3) silver bleaching and (4) fixing. The treatment baths for the process steps (2), (3) and (4), or the combined treatment baths useful for process step (3) with at least one the process steps (2) or (4) contain water-soluble tertiary phosphines as silver ligands. These phosphines effect an acceleration of the dye and silver bleaching and they are further suitable stabilizers and optionally antioxidants which yield stable treatment baths.Type: GrantFiled: May 29, 1981Date of Patent: November 2, 1982Assignee: Ciba-Geigy AGInventors: Christoph Chylewski, Gerald Jan, Roland Kurzen, Max Meier, Matthias Schellenberg
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Patent number: 4335245Abstract: New silver dye-bleach catalysts and the process for their manufacture are provided. These compounds have the general formula ##STR1## wherein A is an electron-withdrawing group and R.sub.1 and R.sub.2 are hydrogen, optionally substituted alkyl or optionally substituted aryl.Type: GrantFiled: February 26, 1981Date of Patent: June 15, 1982Assignee: Ciba-Geigy AGInventor: William E. Long
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Patent number: 4310612Abstract: Photographically useful compounds such as photographic reagents and photographic dyes are blocked with a grouping which, under alkaline conditions, is cleaved from the compound by an intramolecular nucleophilic displacement reaction. The compounds are resistant to unblocking under storage conditions, but are uniformly unblocked under conditions encountered during photographic processing.Type: GrantFiled: October 10, 1978Date of Patent: January 12, 1982Assignee: Eastman Kodak CompanyInventors: Jared B. Mooberry, William C. Archie, Jr.
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Patent number: 4304847Abstract: A color image forming process which comprises processing a photographic light-sensitive element comprising a support having thereon a layer containing imagewise distributed silver therein with an aqueous alkaline solution containing a stannous ion and in the presence of a dye and a bispyridinium compound represented by the following general formula: ##STR1## wherein R.sub.1 and R.sub.2 each represents a lower aliphatic hydrocarbon group or R.sub.1 and R.sub.2 are bonded each other to form a ring; n represents 0 or 1; and X.sup.- represents an anion; to bleach the dye in an imagewise manner. By the process of the present invention, color images which are stable to light, heat and moisture are formed using light-sensitive elements containing a reduced amount of silver salt and without using chemicals causing environmental pollution problems for the processing.Type: GrantFiled: November 13, 1979Date of Patent: December 8, 1981Assignee: Fuji Photo Film Co., Ltd.Inventors: Koichi Nakamura, Isao Shimamura, Yukio Maekawa, Koichi Koyama, Shigeki Yokoyama
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Patent number: 4304846Abstract: A method for processing exposed silver dye-bleach materials using novel preparations for combined dye bleaching and silver bleaching is described. In addition to a strong acid, a water-soluble iodide, a water-soluble oxidizing agent, an antioxidant and, if desired, a bleaching accelerator, these preparations also contain a mixture of 1,4- or 1,2-diazines as bleach catalysts. This mixture consists either of at least two bleach catalysts with redox potentials between +105 mV and -30 mV, the difference between the redox potentials of the catalysts being at least 15 mV, or of at least one bleach catalyst with a redox potential between +60 mV and -30 mV and at least one bleach catalyst with a redox potential between -30 mV and -100 mV, the difference between the redox potentials of the catalysts likewise being at least 15 mV.When exposed dye-bleach materials are processed using these preparations, images with improved color quality are obtained.Type: GrantFiled: February 4, 1980Date of Patent: December 8, 1981Assignee: Ciba-Geigy AGInventors: Max Marthaler, Gerald Jan
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Patent number: 4288598Abstract: New silver dye-bleach catalysts and the process for their manufacture are provided. These compounds have the general formula ##STR1## wherein A is an electron-withdrawing group and R.sub.1 and R.sub.2 are hydrogen, optionally substituted alkyl or optionally substituted aryl.Type: GrantFiled: February 22, 1980Date of Patent: September 8, 1981Assignee: Ciba-Geigy AGInventor: William E. Long
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Patent number: 4271254Abstract: A new method to produce photographic images is provided which comprises(a) imagewise exposing a photographic assembly which contains at least during the silver halide developing step, in order optionally a supercoat layer, at least one silver halide emulsion layer, a layer containing a modifiable image substance and a photobase, there being optionally one or more interlayers between each of said components(b) treating the exposed photographic assembly with an aqueous processing bath so as to provide in the silver halide emulsion layer or layers a solution or dispersion of an image substance modifying/silver halide developing compound (dymodev compound), thereby to develop the latent silver image in the silver halide emulsion(s), and(c) in the non-latent image areas allowing the dymodev compound to diffuse in a counter-imagewise manner from the silver halide emulsion layer(s) to the layer containing the modifiable image substance and there to modify reductively the image substance.Type: GrantFiled: December 31, 1979Date of Patent: June 2, 1981Assignee: Ciba-Geigy AGInventors: Leslie F. A. Mason, Robert S. Cook, David Kilcast, Matthias Schellenberg, Christoph Chylewski
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Patent number: 4269928Abstract: A photographic dye diffusion transfer process is provided which operates by imagwise release of a dye.The dye diffuses to a receiving layer and is mordanted there to give a dye image. The dyes are released from a compound of the formula D--E--F--BAL by reductive cleavage.D is a group which contains the residue of diffusible dye, BAL is a ballasting group which renders the compound containing it substantive to the layer in which it is present, D and E being joined by any type of chemical bond and E and F represent a single or double bond system which links D and BAL and which has a reduction potential above -200 mV measured against a standard hydrogen electrode at a pH of less than 3 and which bond can be reductively cleaved at a pH of less than 3 by a reducing agent which is able to act at a pH below 3.Type: GrantFiled: February 23, 1979Date of Patent: May 26, 1981Assignee: Ciba-Geigy AktiengesellschaftInventors: Leslie F. A. Mason, Rainer Kitzing, Brian R. D. Whitear, William E. Long, Glenn P. Wood, David L. R. Reeves
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Patent number: 4266011Abstract: A process for the production of colored photographic images by the silver dye-bleach process by image-wise exposure and subsequent processing by developing the silver image, dye-bleaching and silver bleaching, it being possible, optionally, for the last two steps to be combined, silver fixing and washing, in which process dye-bleaching and/or silver bleaching is carried out in the presence of at least one bleach catalyst of the formula ##STR1## In the formula, A and B are in each case the non-metallic atoms necessary to complete a benzene or pyridine ring, R.sub.1 and R.sub.3 are each hydrogen, hydroxyl, halogen, alkyl, carboxyl, carbalkoxy, carbalkoxyalkoxy, --CH.sub.2 OH, --O(CH.sub.2).sub.n OH, --O(CH.sub.2).sub.2 O(CH.sub.2).sub.2 OH, --CH.sub.2 Cl, --CH.sub.2 Br, --NR.sub.5 R.sub.6, --CH.sub.2 NR.sub.5 R.sub.6, --O(CH.sub.2).sub.n NR.sub.5 R.sub.6, --CH.sub.2 SO.sub.3 M, --O(CH.sub.2).sub.n SO.sub.3 M or --SO.sub.3 M, R.sub.2 and R.sub.4 are each hydrogen, hydroxyl, alkyl or alkoxy and R.sub.5 and R.sub.Type: GrantFiled: September 20, 1979Date of Patent: May 5, 1981Assignee: Ciba-Geigy AGInventor: Gerald Jan
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Patent number: RE42128Abstract: Compositions containing certain organic solvents and a fluorine source are capable of removing photoresist and etching residue.Type: GrantFiled: January 22, 2009Date of Patent: February 8, 2011Assignee: Air Products and Chemicals, Inc.Inventor: Matthew Egbe