Developing Inhibitor Or Processing Ingredient Containing Patents (Class 430/505)
  • Patent number: 4672027
    Abstract: Moderate camera speed photographic elements for producing subtractive primary dye images are disclosed, including one emulsion layer comprised of silver bromide or bromoiodide grains having a mean diameter in the range of from 0.2 to 0.55 .mu.m including tabular grains having an aspect ratio of greater than 8:1 accounting for at least 50 percent of the total projected area of the grains in the emulsion layer and being positioned to receive imaging radiation prior to one or more blue recording emulsion layers. Enhancement of speed-granularity relationships, blue to minus blue speed separation, silver utilization, and image sharpness can all be realized.
    Type: Grant
    Filed: August 1, 1986
    Date of Patent: June 9, 1987
    Assignee: Eastman Kodak Company
    Inventors: Richard L. Daubendiek, Gary L. House, Timothy R. Gersey
  • Patent number: 4670374
    Abstract: A photothermographic construction comprises a light-sensitive color-forming element on a support base, the element comprising a silver source, optionally silver halide, a binder, and an oxidizable leuco phenazine, phenoxazine, or phenothiazine dye, and as development accelerator a carboxylic acid, Lewis acid, or Bronsted acid.
    Type: Grant
    Filed: February 12, 1986
    Date of Patent: June 2, 1987
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Peter A. Bellus, Robert A. Frenchik
  • Patent number: 4668611
    Abstract: A color photographic light-sensitive material comprising a support having thereon, in sequence:(1) a blue-sensitive silver halide emulsion layer containing, dispersed in the emulsion using a high-boiling organic solvent, a yellow coupler represented by the following general formula (I): ##STR1## with the weight ratio of the high-boiling organic solvent for dispensing the coupler to the yellow coupler being 1.0:1 or less;(2) a green-sensitive silver halide emulsion layer containing a magenta coupler represented by the following general formula (II): ##STR2## (3) a red-sensitive silver halide emulsion layer containing a cyan coupler represented by the following general formula (III): ##STR3## (4) an ultraviolet light absorbing layer containing an ultraviolet light absorbent represented by the following general formula (IV): ##STR4## in which the substituents X, Z, and R.sub.1 -R.sub.12 are as defined in the specification.
    Type: Grant
    Filed: October 8, 1986
    Date of Patent: May 26, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Kotaro Nakamura
  • Patent number: 4656122
    Abstract: Silver halide photographic elements are disclosed capable of producing reversal images including at least one emulsion layer comprised of a blend of tabular silver haloiodide grains and relatively fine grains consisting essentially of a silver salt more soluble than silver iodide.
    Type: Grant
    Filed: January 27, 1986
    Date of Patent: April 7, 1987
    Assignee: Eastman Kodak Company
    Inventors: Allan F. Sowinski, David C. Shuman
  • Patent number: 4656123
    Abstract: A silver halide light-sensitive material is described, comprising a support having provided thereon at least two silver halide emulsion layers differing in color sensitivity, wherein at least one of said layers contains at least one compound capable of releasing a fogging agent, a development accelerator, or a precursor thereof in proportion to the amount of silver developed, and a layer containing silver halide grains which are not substantially developed by the development processing of said material is provided between said two emulsion layers differing in color sensitivity. The material has improved color reproducibility.
    Type: Grant
    Filed: January 25, 1985
    Date of Patent: April 7, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Keiji Mihayashi, Hidetoshi Kobayashi
  • Patent number: 4652515
    Abstract: A silver halide color photographic material which comprises a support having thereon at least two silver halide light-sensitive layers having essentially the same color sensitivity but different speeds and a light-insensitive layer positioned adjacent to the highest-speed layer of said light-sensitive layers and containing a compound which reacts with the oxidation products of a color developing agent to form a diffusible development restraining compound or a precursor thereof. The photographic material provides a color image having excellent graininess and color reproduction and has excellent characteristics of development processing.
    Type: Grant
    Filed: August 5, 1985
    Date of Patent: March 24, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tadashi Ogawa, Jun Arakawa, Satoshi Nagaoka, Yuichi Ohashi, Koji Tamoto
  • Patent number: 4647527
    Abstract: A silver halide color photographic light-sensitive material is described, which is of ultra-high-sensitivity and is characterized by having the following light-sensitive layer unit (I), (II) or (III):Unit (I): a light-sensitive layer unit comprising: (a) a blue- and green-sensitive layer containing (a-1) a yellow image-forming coupler, (a-2) a magenta image-forming coupler, and (a-3) a cyan colored coupler; and (b) a green- and red-sensitive layer containing (b-1) a cyan image-forming coupler, (b-2) a magenta image-forming coupler, and (b-3) a yellow colored coupler.Unit (II): a light-sensitive layer unit comprising: (a) a blue- and red-sensitive layer containing (a-1) a yellow image-forming coupler, (a-2) a cyan image-forming coupler, and (a-3) a magenta colored coupler; and (b) a green- and red-sensitive layer containing (b-1) a magenta image-forming coupler, (b-2) a cyan image-forming coupler, and (b-3) a yellow colored coupler.
    Type: Grant
    Filed: May 22, 1984
    Date of Patent: March 3, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shinpei Ikenoue, Akikazu Mikawa, Seiji Ichijima
  • Patent number: 4645735
    Abstract: A silver halide photographic light-sensitive material is disclosed. The material is comprised of a support base having positioned thereon a light-sensitive silver halide emulsion layer, a light-insensitive layer and ultraviolet ray absorbing polymer latex of a polymer having a repeating unit derived from a monomer represented by the general formula (I): ##STR1## within general formula (I) the substituents are defined within the specification. The Q represents an ultraviolet ray absorbing group represented by a general formula (II) or (III): ##STR2## The substituents within the general formulae given above are defined in the specification. By including the particular ultraviolet ray absorbing polymer latex of the invention the resulting photographic material has improved antistatic properties and the photographic characteristics of the material are not deteriorated by the presence of the latex.
    Type: Grant
    Filed: March 13, 1985
    Date of Patent: February 24, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Naohiko Sugimoto, Tetsuro Kojima, Shingo Ishimaru
  • Patent number: 4640889
    Abstract: Disclosed is a light-sensitive silver halide multi-layer color photographic material having a light-sensitive silver halide emulsion layer combined with a non-diffusion coupler on a support, which comprises a light-sensitive silver halide emulsion layer farthest from the support which contains mono-dispersed silver halide grains comprising primarily (100) faces and having an average grain size of 0.2 to 0.8 .mu.m.The light-sensitive silver halide multi-layer color photographic material of the present invention has stable performance against fluctuations in developing processing conditions, has high sensitivity and low fogging.
    Type: Grant
    Filed: April 15, 1985
    Date of Patent: February 3, 1987
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Kazuo Komorita, Masanobu Miyoshi, Kaoru Onodera
  • Patent number: 4640890
    Abstract: A silver halide color photographic material is described comprising a support having thereon at least one red-sensitive silver halide emulsion layer, at least one green-sensitive silver halide emulsion layer, and at least one blue-sensitive silver halide emulsion layer, with at least one of said light-sensitive silver halide emulsion layers containing a mono-dispersed silver halide emulsion, said color photogrphic material further comprising at least one auxiliary layer containing silver halide grains having substantially light-insensitivity and containing more than 75 mole % silver chloride.The silver halide color photographic material is improved in dependence of photographic characteristics with respect to the extent of stirring of a processing solution during development processing.
    Type: Grant
    Filed: July 31, 1985
    Date of Patent: February 3, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Munehisa Fujita, Akio Mitsui
  • Patent number: 4639415
    Abstract: A silver halide color photographic material is disclosed which contains a magenta color image-forming coupler represented by the following formula (I) and a compound represented by the following formula (II): ##STR1## wherein Z represents the group of nonmetallic atoms necessary for forming a nitrogen-containing heterocyclic ring, provided that the ring to be formed by said Z may have a substitutent;X represents a hydrogen atom or a substituent capable of leaving upon reaction with the oxidized product of a color developing agent; andR represents a hydrogen atom or a substituent. ##STR2## wherein R.sub.1 is an aliphatic group, a cycloalkyl group or an aryl group; andY represents the group of nonmetallic atoms necessary for forming a 5- to 7-membered heterocyclic ring taken together with the nitrogen atom, provided that at least two hetero atoms among the heterocyclic ring-forming nonmetallic atoms including the nitrogen atom are not adjacent to each other.
    Type: Grant
    Filed: September 16, 1985
    Date of Patent: January 27, 1987
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Yutaka Kaneko, Toshihiko Kimura, Kenji Kadokura
  • Patent number: 4639413
    Abstract: A silver halide color photographic material is described, comprising a support having formed thereon at least one silver halide emulsion layer having dispersed therein, in a coexisting state, at least one magenta coupler represented by formula (I) and at least one high-boiling point organic solvent represented by the formula (II) ##STR1## wherein R.sup.1 and R.sup.2 each represents a hydrogen atom or a substituent and x represents a hydrogen atom or a group capable of being released by a coupling reaction with the oxidation product of an aromatic primary amine developing agent; andwherein R.sup.3, R.sup.4, and R.sup.5 each represents an alkyl group, a cycloalkyl group, or an alkenyl group, and the total number of carbon atom of the groups R.sup.3, R.sup.4 and R.sup.5 is from 12 to 60.
    Type: Grant
    Filed: August 14, 1985
    Date of Patent: January 27, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toshio Kawagishi, Kiyoshi Nakazyo
  • Patent number: 4639409
    Abstract: A silver halide color photographic material comprising a support having thereon, in succession, a 1st silver halide photographic light-sensitive emulsion layer, a photographic auxiliary layer, and a 2nd silver halide photographic light-sensitive emulsion layer, or comprising a support having on one side thereof a 1st silver halide light-sensitive layer and on the other side thereof a photographic auxiliary layer and a 2nd silver halide photographic light-sensitive layer, the photographic auxiliary layer having a spectral reflectance of higher than 20% in a wavelength range of 410 nm to 700 nm and a spectral transmittance of higher than 5% in the same wavelength range. The invention provides a color photographic material giving recorded images, etc., capable of viewing by both reflected light and transmitted light.
    Type: Grant
    Filed: April 19, 1985
    Date of Patent: January 27, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Soichiro Yamamoto, Takeo Shimada
  • Patent number: 4636457
    Abstract: Direct positive photographic elements are disclosed employing internal latent image silver halide emulsions associated with developer autoxidation promoter agents constituted by 5 or 6 membered nucleus-containing heterocyclic compounds comprising an azomethine group, whose methine group is substituted with a 5-amino-1,2,4-triazolyl group, and/or copper complex compounds thereof.Preferably said direct positive photographic elements are multi-layer elements comprising internal latent image type type silver halide emulsion layers sensitized to different regions of the visible light and associated with image-dye providing compounds (photographic color couplers).
    Type: Grant
    Filed: July 15, 1985
    Date of Patent: January 13, 1987
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Luigi Valbusa, Enzo Coraluppi, Andrea Quaglia, Mario Tavella
  • Patent number: 4628024
    Abstract: A silver halide color photographic light-sensitive material comprising a support having thereon a silver halide emulsion layer and a compound represented by the following general formula (I): ##STR1## wherein COUP represents a coupler residue capable of being subjected to a coupling reaction with an oxidation product of an aromatic primary amine developing agent; TIME represents a timing group which is released upon the coupling reaction and subsequently releases ##STR2## Z represents a monocyclic or condensed heterocyclic ring consisting of a nitrogen atom and a carbon atom; L represents a divalent linking group; R.sup.1 represents a hydrogen atom or an alkoxycarbonyl group; R.sup.2 represents a hydrogen atom, an alkyl group, an aryl group, a heterocyclic group, an acyl group, a sulfonyl group, an alkoxycarbonyl group, a carbamoyl group, a sulfamoyl group, a thioacyl group or a thiocarbamoyl group; R.sup.3 represents a hydrogen atom; R.sup.2 and R.sup.
    Type: Grant
    Filed: January 9, 1986
    Date of Patent: December 9, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hidetoshi Kobayashi, Keiji Mihayashi, Isamu Itoh
  • Patent number: 4626498
    Abstract: A color reversal photographic light-sensitive material is described having at least one light-sensitive silver halide emulsion layer, wherein at least one of said emulsion layer and a layer adjacent thereto contains a silver halide emulsion of silver halide grains containing internal fog centers.
    Type: Grant
    Filed: May 21, 1984
    Date of Patent: December 2, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Sadanobu Shuto, Yasuhiro Hayashi, Munehisa Fujita, Kazunori Hasebe
  • Patent number: 4622287
    Abstract: A silver halide color photographic light-sensitive material comprising a support and red-sensitive, green-sensitive and blue-sensitive light-sensitive layers formed on the support. The light-sensitive layers separately contain a coupler of formula (I), a coupler of formula (II) or (III), and a coupler of formula (IV). ##STR1## This novel combination of couplers leads to good color formability, improved color reproducibility, improved image preservability and good color balance.
    Type: Grant
    Filed: April 26, 1985
    Date of Patent: November 11, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Makoto Umemoto, Kozo Aoki
  • Patent number: 4619892
    Abstract: Full color photographic images are produced by exposure of a radiation-sensitive element comprising at least three silver halide emulsion layers. At least two silver halide emulsion layers are sensitized to infrared radiation. Selectively absorptive filter layers and/or differential sensitivities between emulsion layers are used to prevent exposure of other layers to radiation used to expose a single layer.
    Type: Grant
    Filed: November 7, 1985
    Date of Patent: October 28, 1986
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Sharon M. Simpson, John M. McQuade, John R. Boon
  • Patent number: 4619891
    Abstract: A photosensitive material having a widened temperature lattitude. The photosensitive material is described, comprising a support having thereon at least one silver halide emulsion layer associated with a dye-providing compound capable of forming an imagewise mobile dye as the result of exposure and development, wherein a hydroquinone derivative and a water-insoluble but organic solvent-soluble homopolymer or copolymer having a recurring unit containing a ##STR1## bond in the main chain or side chain are integrated and dispersed as individual particles in a hydrophilic colloid of the silver halide emulsion layer or layers or the dye providing compound containing layer or layers.
    Type: Grant
    Filed: May 10, 1985
    Date of Patent: October 28, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Osamu Takahashi
  • Patent number: 4618571
    Abstract: A silver halide color photographic light-sensitive material comprising a support having thereon at least one silver halide emulsion layer, the color photographic light-sensitive material containing a coupler which releases a compound after the coupling reaction with the oxidation product of a developing agent, the released compound being capable of releasing further a photographically useful group by an oxidation-reduction reaction with the oxidation product of another developing agent. The compound used in the present invention is chemically stable and can release a photographically useful group under control; therefore the silver halide color photographic light-sensitive material containing the compound has good stability during storage and high sensitivity and provides a color image having good image qualities such as sharpness, graininess, color reproducibility, etc.
    Type: Grant
    Filed: February 25, 1985
    Date of Patent: October 21, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Seiji Ichijima, Hideo Usui, Naoyasu Deguchi
  • Patent number: 4618570
    Abstract: A silver halide photographic material having at least one layer of silver halide emulsion layers containing a silver halide having a silver chloride content of not less than 25 molar %, characterized in that at least one of said silver halide emulsion layers contains a silver halide sensitized with a compound having the following formula (Ia), and/or a compound having the following formula (Ib) and is hardened with a compound having the following formula (II) and/or a compound having the formula (III); ##STR1## in the above formulae (Ia), (Ib), (II) and (III), R.sub.1 to R.sub.20, Z.sub.1 and Z.sub.2, n.sub.1 and n.sub.2, Q and Q', L, p and q are defined in the specification.The photographic material of the invention not only shows a higher sensitivity, a lower infrared sensor fogging, a superior sharpness or color reproductivity and a superior whiteness but also exerts a good storage property with time or a lower change in sensitivity after storage.
    Type: Grant
    Filed: March 15, 1985
    Date of Patent: October 21, 1986
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Takashi Kadowaki, Kaoru Onodera
  • Patent number: 4614709
    Abstract: A silver halide photographic light-sensitive material having a support with at least one silver halide emulsion layer is provided. The silver halide emulsion layer containing in combination at least one yellow dye image-forming coupler of Formula I and at least one high-boiling organic solvent of Formula II to reduce the light discoloration of a yellow dye image.
    Type: Grant
    Filed: December 20, 1983
    Date of Patent: September 30, 1986
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Masao Sasaki, Kaoru Onodera
  • Patent number: 4614707
    Abstract: A color reversal photographic light-sensitive materials comprising a base having thereon (a) at least one light-sensitive silver halide emulsion layer containing a dye forming coupler and (b) a silver halide emulsion layer substantially without light-sensitivity provided adjacent to said light-sensitive layer, or (a) at least one light-sensitive silver halide emulsion layer containing a dye forming coupler, (b) a silver halide emulsion layer substantially without light-sensitivity to light, and (c) an intermediate layer therebetween, wherein said intermediate layer or said silver halide emulsion layer substantially without light-sensitivity, or both said intermediate layer and said silver halide emulsion layer substantially without light-sensitivity contain at least one compound represented by the following formula (I): ##STR1## wherein R.sup.1 and R.sup.2, which may be the same or different, each represents a hydrogen atom or a group having 1 to 10 carbon atoms capable of being hydrolyzed with alkali, R.sup.
    Type: Grant
    Filed: February 19, 1985
    Date of Patent: September 30, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Munehisa Fujita, Yasuhiro Hayashi, Takashi Ozawa, Nobutaka Ohki
  • Patent number: 4614710
    Abstract: A silver halide photographic material having one or more silver halide emulsion layers formed on a support is disclosed, wherein at least one of said silver halide emulsion layers contains a cyan coupler of formula (I) in combination with a cyan coupler of formula (II): ##STR1## (wherein R.sub.1 is an alkyl group, an aryl group, a cycloalkyl group or a heterocyclic group; R.sub.2 is a halogen atom or a monovalent organic group; m is an integer of 0 to 4, provided that when m is 2 or more, R.sub.2 may be the same or different; R.sub.3 is a hydrogen atom, a halogen atom, an alkyl group or an alkoxy group; W is an alkylsulfonamido group, an arylsulfonamido group, an alkylsulfamoyl group or an arylsulfamoyl group; R.sub.4 is an alkylene group; X is a divalent group; l is 0 or a positive integer; Z.sub.1 is a hydrogen atom or a group capable of leaving upon reaction with the oxidized product of an aromatic primary amine color developing agent); ##STR2## (wherein R.sub.
    Type: Grant
    Filed: April 18, 1985
    Date of Patent: September 30, 1986
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Shun Takada, Takashi Kadowaki, Kaoru Onodera
  • Patent number: 4613565
    Abstract: A silver halide photographic material having one or more silver halide emulsion layers formed on a support is disclosed, wherein at least one of said silver halide emulsion layers contains a cyan coupler of formula (I) in combination with a cyan coupler of formula (II): ##STR1## (wherein R.sub.1 is a ballast group; R.sub.2 is a halogen atom or a monovalent organic group; R.sub.3 is a hydrogen atom, a halogen atom, an alkyl group or an alkoxy group; W is an alkyl-sulfonamido group, an arylsulfonamido group, an alkylsulfamoyl group or an arylsulfamoyl group; m is an integer of 0 to 4, provided that when m is 2 or more, R.sub.2 may be the same or different; and Z.sub.1 is a hydrogen atom or a group capable of leaving upon reaction with the oxidized product of an aromatic primary amine color developing agent); ##STR2## (wherein R.sub.4 is an alkyl or alkoxy group; n is an integer of 0 to 5, provided that when n is 2 or more, R.sub.4 may be the same or different; R.sub.5 is an alkylene group; R.sub.
    Type: Grant
    Filed: April 18, 1985
    Date of Patent: September 23, 1986
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Shun Takada, Takashi Kadowaki, Kaoru Onodera
  • Patent number: 4613564
    Abstract: A silver halide photographic material having one or more silver halide emulsion layers formed on a support is disclosed, wherein at least one of said silver halide emulsion layers contains a cyan coupler of formula (I) in combination with a cyan coupler of formula (II) ##STR1## (wherein R.sub.1 is a ballast group; R.sub.2 is a halogen atom or a monovalent organic group; m is an integer of 0 to 4, provided that when m is 2 or more, R.sub.2 may be the same or different; R.sub.3 is a hydrogen atom or a halogen atom; W is a halogen atom or an alkyl group; and Z.sub.1 is a hydrogen atom or a group capable of leaving upon reaction with the oxidized product of an aromatic primary amine color developing agent); ##STR2## (wherein R.sub.4 is an alkyl or alkoxy group; n is an integer of 0 to 5, provided that when n is 2 or more, R.sub.4 may be the same or different; R.sub.5 is an alkylene group; R.sub.6 is an alkyl group; R.sub.7 is a hydrogen atom, a halogen atom or an alkyl group; and Z.sub.
    Type: Grant
    Filed: April 18, 1985
    Date of Patent: September 23, 1986
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Shun Takada, Takashi Kadowaki, Kaoru Onodera
  • Patent number: 4610959
    Abstract: A direct positive silver halide photographic material is described, comprising a support having thereon at least an internal latent image-type direct positive silver halide emulsion layer containing a hydrazine series nucleating agent, wherein said silver halide emulsion layer or a layer adjacent to the silver halide emulsion layer contains a non-dye image-forming compound represented by following general formula (I) in an amount sufficient for accelerating nucleation; ##STR1## wherein Z.sub.1 and Z.sub.2, which may be the same or different, each represents an atomic group necessary for forming a benzene ring or a naphthalene ring; G.sub.1 and G.sub.2, which may be the same or different, each represents hydrogen or a substituent which does not adversely influence the image; A.sub.1, A.sub.2 and A.sub.3, which may be the same or different, each represents hydrogen or a substituent which does not adversely influence the image; B.sub.1, B.sub.2 and B.sub.
    Type: Grant
    Filed: February 20, 1985
    Date of Patent: September 9, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shigetoshi Ono, Shigeru Nakamura, Kazuhiko Matsumoto
  • Patent number: 4609620
    Abstract: Compounds of the formula ##STR1## where Y is a tertiary group, X is hydrogen or a leaving group, and Q is hydrogen, amidino, alkyl or aryl, there being present in Y or Q a ballasting group which comprises 10 to 30 carbon atoms, exhibit a high secondary absorption in the blue region of the visible spectrum and are useful couplers in chromogenic monochrome negative material.
    Type: Grant
    Filed: April 9, 1985
    Date of Patent: September 2, 1986
    Assignee: Ciba Geigy AG
    Inventors: Stephen R. Postle, William E. Long
  • Patent number: 4608334
    Abstract: A silver halide color light-sensitive material having improved graininess is described, comprising a support having provided thereon at least two emulsion layers that are sensitive to the same color light but have different sensitivities, wherein a light-insensitive intermediate layer comprising gelatin is provided between any two of said emulsion layers that are adjacent to each other and the higher sensitivity emulsion layer of said two layers has a smaller silver/coupler molar ratio than that of the lower sensitivity emulsion layer of said two emulsion layers.
    Type: Grant
    Filed: September 12, 1985
    Date of Patent: August 26, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Sadanobu Shuto, Munehisa Fujita, Kazunori Hasebe
  • Patent number: 4607002
    Abstract: A silver halide color photographic light-sensitive material comprising a reflective support bearing thereon a green light-sensitive silver halide emulsion layer containing a t-alkyl 1H-pyrazolo[3,2-C]-5-triazole magenta forming coupler represented by Formula (I) defined in the specification: a blue light-sensitive silver halide emulsion layer containing a t-butyl acylacetamide yellow-forming coupler represented by Formula (II) defined in the specification and a red light-sensitive silver halide emulsion layer containing a phenolic cyan-forming coupler represented by Formula (III) or (IV) defined in the specification.
    Type: Grant
    Filed: November 14, 1985
    Date of Patent: August 19, 1986
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Noritaka Nakayama, Satoshi Kawakatsu, Katsunori Katoh, Kaoru Shinozaki
  • Patent number: 4607004
    Abstract: A silver halide color photographic light-sensitive material is disclosed, comprising a support having provided thereon light-sensitive silver halide emulsion layers, wherein on the outside of the light-sensitive silver halide emulsion layer positioned farthest from the support, a layer containing silver halide fine grains of about 0.2.mu. or less in average grain size is provided, and in the silver halide color photographic light-sensitive material at least one compound represented by the following general formula (I) is present: ##STR1## wherein M represents a hydrogen atom, an alkali metal or a quaternary ammonium group, X represents COOM' or SO.sub.3 M' (wherein M' represents a hydrogen atom, an alkali metal or a quaternary ammonium group), n represents 1 or 2, R.sub.1 represents a group capable of substituting on the phenyl group, and m represents 0, 1 or 2.
    Type: Grant
    Filed: December 17, 1984
    Date of Patent: August 19, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shinpei Ikenoue, Haruhiko Iwano, Hiroyuki Mifune, Morio Yagihara
  • Patent number: 4600688
    Abstract: A silver halide color photographic light-sensitive material whose magenta dye-forming layer forms a magenta dye image having an absorption maximum from 550 nm to 560 nm and an advantageous absorption spectrum for color reproduction is provided by a silver halide color photographic light-sensitive material comprising a support having thereon at least one silver halide emulsion layer, wherein the at least one silver halide emulsion layer contains a 1H-pyrazolo[3,2-C]-s-triazole-type magenta coupler, and the above silver halide emulsion layer containing the magenta coupler and/or a silver halide emulsion layer having substantially the same color sensitivity as does the above silver halide emulsion layer containing the magenta coupler contains a pyrazolone-type magenta coupler.
    Type: Grant
    Filed: February 8, 1985
    Date of Patent: July 15, 1986
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Satoshi Kawakatsu, Noritaka Nakayama, Katsunori Katoh, Kaoru Shinozaki, Toshihiko Kimura
  • Patent number: 4599301
    Abstract: A silver halide color photographic material is described, comprising a support having thereon at least a cyan-color-forming red-sensitive emulsion layer, a magenta-color-forming green-sensitive emulsion layer, and a yellow-color-forming blue-sensitive emulsion layer; the weight-averaged wavelength (.lambda.) on the spectral sensitivity distribution determined by equi-energy spectrum of said red-sensitive emulsion layer being less than 640 nm; the longest wavelength in the wavelengths having the sensitivity of 1/2 of the maximum value of the above-described equi-energy spectrum being in a range of from 30 nm to 55 nm longer than the weight-averaged wavelength and the minimum wavelength thereof being in a range of from 30 nm to 55 nm shorter than the weight-averaged wavelength; in the above-described equi-energy spectrum, values A and B defined below satisfying the relation of A/B.gtoreq.0.
    Type: Grant
    Filed: August 8, 1985
    Date of Patent: July 8, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yuichi Ohashi, Tadashi Ogawa
  • Patent number: 4596764
    Abstract: A method of processing an image-wise exposed silver halide color photographic material is described, having on a support at least one red-sensitive silver halide emulsion layer, at least one green-sensitive silver halide emulsion layer, and at least one blue-sensitive silver halide emulsion layer, the total amount of silver iodide contained in the light-senstive silver halides in said light-sensitive silver halide emulsion layers being higher than 4.0.times.10.sup.-3 mole/m.sup.2, which comprises processing the color photographic material further containing in a protective layer thereof a super fine grain silver halide, having a mean grain size of less than 0.2 .mu.
    Type: Grant
    Filed: July 3, 1985
    Date of Patent: June 24, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Shingo Ishimaru
  • Patent number: 4595650
    Abstract: A silver halide color photographic light-sensitive material is described, comprising a support having coated thereon at least one silver halide emulsion layer, the color photographic light-sensitive material having a photographic layer containing at least one kind of magenta coupler of 5-pyrazolone type having an arylthio group at the coupling position thereof, the arylthio group having an alkoxy group or an aryloxy group at the ortho position to the sulfur atom thereof and the alkoxy group and the aryloxy group being substituted with a cyano group, a halogen atom, a sulfonyl group, a sulfinyl group, a phosphonyl group, or an ##STR1## group, wherein A represents a chemical bond, an alkylene group, an arylene group, an oxygen atom, a sulfur atom, or an imino group; and B represents a hydroxy group, an alkoxy group, an aryloxy group, a hydrogen atom, an alkyl group, an aryl group, a heterocyclic group, an acyclic amino group, or a hydrazino group.
    Type: Grant
    Filed: July 20, 1984
    Date of Patent: June 17, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Nobuo Furutachi, Masakazu Morigaki, Takeshi Hirose
  • Patent number: 4594314
    Abstract: A silver halide color photographic light-sensitive material comprising a support having thereon a lower-speed emulsion containing a phenol cyan coupler and a higher-speed emulsion containing a naphthol cyan coupler. Both the lower-speed emulsion and the higher-speed emulsion have the same color sensitivity.
    Type: Grant
    Filed: July 5, 1985
    Date of Patent: June 10, 1986
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Toshihiko Kimura, Takashi Sasaki, Yutaka Kaneko
  • Patent number: 4585728
    Abstract: A silver halide color photographic light-sensitive material comprising a support having coated thereon at least one silver halide emulsion layer is described, the color photographic light-sensitive material having at least one layer containing (1) at least one 2-equivalent magenta coupler represented by formula (I): ##STR1## wherein W represents a phenyl group substituted with at least one halogen atom, alkyl group, alkoxy group, alkoxycarbonyl group or cyano group; Y represents an acylamino group or an anilino group; and Z represents a group capable of being released upon coupling, and (2) at least one amine compound having at least two groups other than a hydrogen atom represented by formula (II): ##STR2##
    Type: Grant
    Filed: June 7, 1985
    Date of Patent: April 29, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Nobuo Furutachi, Takeshi Hirose
  • Patent number: 4585732
    Abstract: A silver halide photographic light-sensitive material comprising a support having thereon at least one silver halide emulsion layer, the photographic light-sensitive material containing a color image forming coupler comprising a nitrogen containing heterocyclic 5-membered ring-condensed-5-membered ring in which the coupling active position is substituted with the nitrogen atom of a carboxylic acid amido group containing at least one fluorine atom.The magenta color image forming coupler has good color forming property and provides a magenta color image having excellent spectral absorption property and good fastness to light.
    Type: Grant
    Filed: December 27, 1984
    Date of Patent: April 29, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toshio Kawagishi, Nobuo Furutachi
  • Patent number: 4584265
    Abstract: s-Triazine compounds which contain in their molecule at least one sterically hindered phenol group and at least one polyalkylpiperidine group are effective optical stabilizers for photographic dyes and precursors thereof.
    Type: Grant
    Filed: May 14, 1985
    Date of Patent: April 22, 1986
    Assignee: Ciba-Geigy AG
    Inventors: David G. Leppard, Jean Rody
  • Patent number: 4584266
    Abstract: A silver halide color photographic light-sensitive material comprising a support having coated thereon at least one silver halide emulsion layer, the color photographic light-sensitive material having a photographic layer containing at least one 2-equivalent 5-pyrazolone type magenta coupler represented by the general formula (I) described below and an amount of a calcium atom contained in the color photographic light-sensitive material being up to 10 mg/m.sup.2. ##STR1## wherein W represents an aryl group; X represents an aliphatic group, an aryl group or a heterocyclic group; and Y represents an acylamino group, a ureido group or an anilino group.The silver halide color photographic light-sensitive material containing the 2-equivalent 5-pyrazolone magenta coupler and the restricted amount of the calcium atom exhibits photographic properties which are not influenced by variations in the pH of the color developing bath and can provide color images fast to light and heat.
    Type: Grant
    Filed: January 30, 1985
    Date of Patent: April 22, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takeshi Hirose, Kotaro Nakamura, Nobuo Furutachi
  • Patent number: 4582780
    Abstract: Adjacency effects of a color photographic material may be increased by dividing a light-sensitive silver halide emulsion layer into three emulsion layers sensitive to the same spectral region of the visible light, the uppermost silver halide emulsion layer of which has the highest sensitivity and the lowermost silver halide emulsion layer has the lowest sensitivity, wherein the maximum color density of the uppermost silver halide emulsion layer, after color development, is lower than 0.60 and the maximum color density of both the intermediate and lowermost silver halide emulsion layers, after color development, are each higher than 0.60.
    Type: Grant
    Filed: September 24, 1984
    Date of Patent: April 15, 1986
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Giovanni Giusto, Elio de Saraca
  • Patent number: 4581324
    Abstract: Colored, reflection-viewed images having improved stability to light, heat and moisture and improved storage stability while retaining the original color character thereof are produced using color photographic recording materials containing, on a light-reflecting layer support, a red-sensitive, a green-sensitive and a blue-sensitive silver halide emulsion layer, each with spectrally associated color coupler, the yellow coupler being a 2-equivalent yellow coupler derived from pivaloyl acetanilide, the magenta coupler a 3-anilinopyrazolone coupler and the cyan coupler a coupler corresponding to the following general formula (I): ##STR1## wherein R.sup.1 represents H or halogen;R.sup.2 represents alkyl having at least 2 carbon atoms;R.sup.3 represents H or alkyl having up to 5 carbon atoms;R.sup.4 represents acyl; andX.sup.1 represents H or a group releasable in the process of color coupling.
    Type: Grant
    Filed: October 29, 1984
    Date of Patent: April 8, 1986
    Assignee: Agfa-Gevaert Aktiengesellschaft
    Inventors: Erich Wolff, Gunter Renner, Friedrich-Wilhelm Kunitz
  • Patent number: 4579813
    Abstract: A silver halide color photographic material comprising a support having thereon at least a silver halide emulsion layer is described, wherein the photographic material contains a cyan dye-forming coupler represented by formula (I) ##STR1## wherein R represents an unsubstituted or substituted alkyl, aryl, or heterocylic ring group; B represents --O-- or --NR.sub.1 --, wherein R.sub.1 represents a hydrogen atom or an unsubstituted or substituted alkyl or aryl group; Z represents an unsubstituted or substituted aryl group or an alkyl or aralkyl group substituted by a carboxy group or a hydroxy group; A represents a substituted aryl group, or a substituted or unsubstituted heterocyclic ring group; and m represents 0 or 1, provided that when m is 0 the substituent is not an alkoxy group, a halogen atom or a cyano group.
    Type: Grant
    Filed: August 28, 1984
    Date of Patent: April 1, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kozo Aoki, Takayoshi Kamio, Toshiyuki Watanabe
  • Patent number: 4578346
    Abstract: A silver halide color photographic light-sensitive material is disclosed. The material is comprised of a support having two layers thereon. One layer is comprised of a silver halide emulsion layer containing a non-diffusible coupler which couples with an oxidation product of a developing agent during development processing to form a dye of such mobility that controlled image smearing occurs. The other layer is comprised of a silver halide emulsion layer containing a polymer coupler latex which is adjacent to the emulsion layer containing the dye diffusion type coupler. By utilizing the silver halide color photographic light-sensitive material as disclosed within the application it is possible to obtain improved results with respect to the graininess and sharpness of the images produced with the material without having bad effects on other photographic properties of the material.
    Type: Grant
    Filed: January 30, 1985
    Date of Patent: March 25, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toshiyuki Watanabe, Morio Yagihara, Keiichi Adachi
  • Patent number: 4576907
    Abstract: Compounds corresponding to the following formula(MS--Het--(Ar).sub.m --NR.sup.1 --CO) .sub.n R.sup.2which are contained in a color-photographic recording material in a silver-free layer between a layer containing colloidal silver and a silver halide emulsion layer, improve the storage stability of the material.
    Type: Grant
    Filed: August 29, 1984
    Date of Patent: March 18, 1986
    Assignee: Agfa Gevaert Aktiengesellschaft
    Inventors: Helmut Kampfer, Hans Langen, Erwin Ranz
  • Patent number: 4571378
    Abstract: Improved photographic recording materials containing at least one silver halide emulsion layer with comparatively high sensitivity and at least one silver halide emulsion layer with comparatively low sensitivity. Color couplers and DIR compounds of differing reactivities are associated with these layers.
    Type: Grant
    Filed: December 10, 1984
    Date of Patent: February 18, 1986
    Assignee: Agfa-Gevaert Aktiengesellschaft
    Inventors: Wolfgang Sauerteig, Erwin Ranz, Heinz Schutz
  • Patent number: 4568635
    Abstract: A silver halide light-sensitive material comprising a support having provided thereon at least one silver halide emulsion layer is disclosed. The emulsion layer contains a silver halide prepared in the presence of a tetrasubstituted thiourea as a silver halide solvent and was hardened with a hardener containing a vinylsulfonyl group. Combined use of the tetrasubstituted thiourea and the hardener of the above-described kinds increases the storability of the light-sensitive material.
    Type: Grant
    Filed: January 27, 1984
    Date of Patent: February 4, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Yamagami, Kazunori Hasebe, Naoyasu Deguchi, Koki Nakamura, Hiroyuki Mifune
  • Patent number: 4567135
    Abstract: A silver halide color photographic light-sensitive material is disclosed. The material is comprised of a support base having thereon a silver halide emulsion layer and two distinct types of couplers. One coupler is a diffusing dye-forming coupler which can form a dye capable of having moderate diffusibility in an emulsion layer through coupling with an oxidation product of a color developing agent. The other coupler is a high reaction rate coupler which can form a dye of the same color as that of the diffusing dye-forming coupler and that, has a coupling speed higher than that of the diffusing dye-forming coupler by a factor of 1.3 to 15. By utilizing the two types of couplers in combination with each other the resulting material can provide images with improved graininess over the entire density region of the dye image.
    Type: Grant
    Filed: January 19, 1984
    Date of Patent: January 28, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Jun Arakawa, Toshiyuki Watanabe
  • Patent number: 4564590
    Abstract: A silver halide photographic material having one or more silver halide emulsion layers formed on a reflective support is disclosed, wherein at least one of the silver halide emulsion layers contains at least one cyan coupler of formula (I) dispersed therein with the aid of at least one high-boiling organic solvent having a dielectric constant of 6.1 or more, and wherein at least one photographic layer contains at least one dye of formula (II) and/or formula (III): ##STR1## wherein R.sub.1 is a straight- or branched-chain alkyl group having 2 to 4 carbon atoms; R.sub.2 is a ballast group; and X is a hydrogen atom or a group capable of leaving upon coupling reaction with the oxidized product of a color developing agent; ##STR2## wherein R.sub.3 and R.sub.5 are each a hydrogen atom, an alkyl group or an aryl group; R.sub.4 and R.sub.
    Type: Grant
    Filed: March 19, 1985
    Date of Patent: January 14, 1986
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Masao Sasaki, Toyoki Nishijima, Shun Takada, Takashi Kadowaki, Kaoru Onodera
  • Patent number: RE32195
    Abstract: Photographic silver halide emulsions are protected against latent image fading by aromatic latent image stabilizing compounds having the structure: ##STR1## wherein: R.sup.1 is hydrogen, alkyl, or aryl;R.sup.2 and R.sup.3 are each individually hydrogen, alkyl, alkoxy, carboxy, alkoxycarbonyl, or aminocarbonyl;X is a middle chalcogen.[.;.]. .Iadd.chosen from the class consisting of sulfur and selenium; .Iaddend.Z represents the atoms completing an aromatic nucleus;n is an integer of 1 or 2; andM.sup..sym.n is a cation of valence n chosen from the group consisting of an onium ion, an ion from Group IA or IIA, and a metal ion from Group IIB, VIIB, IVA, or VA.
    Type: Grant
    Filed: April 4, 1985
    Date of Patent: July 1, 1986
    Assignee: Eastman Kodak Company
    Inventor: Arthur H. Herz