Developing Inhibitor Or Processing Ingredient Containing Patents (Class 430/505)
  • Patent number: 5415989
    Abstract: Magenta dye images with excellent stability to light are obtained with a color photographic recording material which contains, associated with a light-sensitive silver halide emulsion layer, at least one magenta coupler corresponding to formula I and at least one compound corresponding to formula II.
    Type: Grant
    Filed: February 22, 1994
    Date of Patent: May 16, 1995
    Assignee: Agfa-Givaert AG
    Inventors: Erich Wolff, Dieter Lowski
  • Patent number: 5413902
    Abstract: A color light-sensitive material comprising at least three light-sensitive layers having different color-sensitivity from one another provided on a support. Each layer comprises a combination of at least a light-sensitive silver halide, a binder and a dye-providing compound. At least one layer thereof has a spectral sensitization peak in at least two wavelength regions, the peaks in the at least two wavelength regions being at least 50 nm away from each other and at least one spectral sensitization peak thereof exists in the wavelength region of 700 nm or above.
    Type: Grant
    Filed: December 2, 1992
    Date of Patent: May 9, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroshi Hara, Takanori Hioki, Keiichi Adachi
  • Patent number: 5411839
    Abstract: An improved color reversal element comprising: a support having thereon at least two light-sensitive silver halide emulsion layers and a compound capable of releasing a development inhibitor, the element comprising a compound having the structural formulaCAR--(TIME).sub.n --INHwherein:CAR is a carrier moiety from which --(TIME).sub.n --INH is released during color development;TIME is a timing group; INH is comprised of a development inhibitor moiety selected from the group consisting of oxazole, thiazole, diazole, oxathiazole, triazole, thiatriazole, benzotriazole, tetrazole, benzimidazole, indazole, isoindazole, mercaptotriazole, mercaptothiadiazole, mercaptotetrazole, selenotetrazole, mercaptothiazole, selenobenzothiazole, mercaptobenzoxazole, selenobenzoxazole, mercaptobenzimidazole, mercaptobenzothiazole, selenobenzimidazole, benzodiazole, mercaptooxadiazole, or benzisodiazole, the INH havina an inhibitor strength greater than 1 (one), andn is 0, 1 or 2.
    Type: Grant
    Filed: January 15, 1993
    Date of Patent: May 2, 1995
    Assignee: Eastman Kodak Company
    Inventors: John W. Harder, Paul A. Burns, J. Ramon Vargas, Arlyce T. Bowne, Philip D. Knight, William J. Begley, Hans G. Ling
  • Patent number: 5409806
    Abstract: There is disclosed a color photographic material and a method for forming a color image using the said photographic material. The color photographic material has at least three dye-forming coupler-containing layers and comprises a reflective support covered with a water-resistant resin composition containing a white pigment and a thermoplastic resin, an emulsion layer that has a silver chloride content of 95 mol % or more and contains silver chlorobromide grains or silver chloride grains containing specified metal ions, and the color photographic material being hardened by a specified compound.
    Type: Grant
    Filed: November 30, 1993
    Date of Patent: April 25, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Shigeaki Otani
  • Patent number: 5405969
    Abstract: The invention provides a process for making a thioether compound having the formula:A--S--Rcomprising reacting:(1) Compound I having the formula:A--H (I)where A comprises a carbon atom bonded to H where that carbon is either capable of ionizing to a nucleophilic state or is conjugated to such an atom, with(2) Compound II having the formula:H--SR or RSSR (II)wherein R is selected from the group consisting of:(a) a substituted or-unsubstituted aryl group or alicyclic group, said groups being carbocyclic or heterocyclic, and(b) a thiocarbonyl group,in the presence of a base and an oxidizing agent that is free of reactive halogen and that is capable of oxidizing H--SR to RSSR.
    Type: Grant
    Filed: December 10, 1993
    Date of Patent: April 11, 1995
    Assignee: Eastman Kodak Company
    Inventors: Charles W. Wright, Joan C. Potenza, John E. Leary, Jr., Chang K. Kim
  • Patent number: 5405735
    Abstract: A silver halide color photographic material light-sensitive having a photographic layer constitution on a support is provided. The photographic layer constitution is comprised of at least one yellow coupler-containing silver halide emulsion layer, at least one magenta coupler-containing silver halide emulsion layer and at least one cyan coupler-containing silver halide emulsion layer formed on the support in this order. The magenta coupler is a 2-equivalent 5-pyrazolone coupler or a 2-equivalent pyrazoloazole coupler. A non-light-sensitive layer is provided between the yellow coupler-containing silver halide emulsion layer and the magenta coupler-containing silver halide emulsion layer and it contains a compound of formula (I) in an amount of from 2.75.times.10.sup.-4 to 1.5.times.10.sup.-3 mol/m.sup.2. The molar ratio of the silver halide in the yellow coupler-containing silver halide emulsion layer to the yellow coupler therein is from 1.5 to 3.5.
    Type: Grant
    Filed: September 20, 1993
    Date of Patent: April 11, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Tadashi Ogawa
  • Patent number: 5403704
    Abstract: A silver halide color photographic material which contains at least one pyrrolotriazole cyan coupler having two electron attracting groups and at least one non-color forming, nondiffusing compound.
    Type: Grant
    Filed: February 22, 1993
    Date of Patent: April 4, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yasuhiro Yoshioka, Shigeo Hirano, Makoto Suzuki
  • Patent number: 5399466
    Abstract: Photographic reversal elements, preferably color reversal elements, and methods of processing them, which elements use both an inhibitor releasing compound in a causer layer and fogged grains in the receiver layer to obtain a high interimage effect. The elements can be processed by standard processing (which provides for exhaustive color development). The elements have at least a first and a second layer, the first layer containing latent image forming iodide containing silver halide grains and the second layer containing latent image forming silver halide grains. An inhibitor releasing compound is provided in the first layer or a non-imaging layer associated with the first and second layers, the inhibitor releasing compound having the structural formulaCAR-(TIME).sub.n -INHwherein:CAR is a carrier moiety from which -(TIME).sub.n -INH is released during-color development;TIME is a timing group;INH is comprised of a development inhibitor moiety; andn is 0, 1 or 2.
    Type: Grant
    Filed: January 15, 1993
    Date of Patent: March 21, 1995
    Assignee: Eastman Kodak Company
    Inventor: John W. Hamer
  • Patent number: 5399465
    Abstract: A reversal photographic element, preferably a color reversal element, is provided with development inhibitors of a defined class, and an absorber dye. The combination improves acutance. The element has a light sensitive layer containing latent image forming silver halide grains, and an inhibitor containing compound in the light sensitive layer or a non-imaging record associated with the light sensitve layer, the compound having the structural formulaCAR-(TIME).sub.n -INHwherein:CAR is a carrier moiety from which -(TIME).sub.n -INH is released during color development;TIME is a timing group;INH is comprised of a development inhibitor moiety selected from the group defined in the specification, the INH having an inhibitor strength greater than 1. The element is further provided with a dye which absorbs light to which the light sensitive layer is sensitive. Elements of the present invention are preferably processed in a standard reversal process.
    Type: Grant
    Filed: January 15, 1993
    Date of Patent: March 21, 1995
    Assignee: Eastman Kodak Company
    Inventor: John D. Baloga
  • Patent number: 5399468
    Abstract: A color photographic silver halide negative working duplicating element and process comprising (A) a magenta colored masking coupler in at least one blue-sensitive photographic silver halide emulsion layer; and (B) a combination of (i) masking couplers and (ii) color contamination of at least one photographic silver halide emulsion layer enables upon exposure and processing of the element formation of a duplicate image that enables formation of a print image that is visually indistinguishable from the original image. The color photographic silver halide duplicating element is useful in forming duplicate images, especially for color motion picture films.
    Type: Grant
    Filed: August 17, 1993
    Date of Patent: March 21, 1995
    Assignee: Eastman Kodak Company
    Inventors: John F. Sawyer, David E. Fenton
  • Patent number: 5399475
    Abstract: A silver halide photographic material having at least one light-sensitive silver halide emulsion layer coated on a support, wherein the silver halide emulsion layer contains silver chlorobromide grains comprising silver chlorobromide containing 90 mol % or more of silver chloride, having at least one region in which the silver bromide content is high at the vicinity of the corner of the grains, and with not more than 15 mol % of average silver bromide content at the surface of the grains. A method producing the silver halide photographic materials is also disclosed.
    Type: Grant
    Filed: December 11, 1992
    Date of Patent: March 21, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kazunori Hasebe, Osami Tanabe, Masahiro Asami, Naoto Ohshima, Keisuke Shiba, Toshihiro Nishikawa
  • Patent number: 5399469
    Abstract: This invention relates to color photographic elements and processes and especially to color photographic elements comprising two or more image forming layers sensitized to the same region of the electromagnetic spectrum where a more sensitive layer is positioned closer to an exposure source than a less sensitive layer and the less sensitive layer additionally comprises a spatially fixed absorber dye. The combination provides improved image sharpness without compromising photographic sensitivity.
    Type: Grant
    Filed: October 13, 1993
    Date of Patent: March 21, 1995
    Assignee: Eastman Kodak Company
    Inventor: Richard P. Szajewski
  • Patent number: 5395744
    Abstract: The invention relates to a color negative photographic recording material comprising a support bearing:at least one photographic layer comprising a sensitized tabular grain silver halide emulsion having an average aspect ratio greater than about 8;an image dye forming coupler;at least one color dye forming development inhibitor releasing coupler; andat least one distributed dye that absorbs light in the region of the spectrum to which said sensitized tabular grain silver halide emulsion having an aspect ratio greater than about 8 is sensitized wherein;the quantity of said at least one distributed dye is such as to reduce the sensitivity of the color record containing said sensitized tabular grain silver halide emulsion having an aspect ratio greater than about 8 by at least 20%; andthe quantity of said at least one development inhibitor releasing compound being greater than about 0.07 mole percent relative to the total quantity of sensitized silver halide emulsion in said at least one photographic layer.
    Type: Grant
    Filed: October 13, 1993
    Date of Patent: March 7, 1995
    Assignee: Eastman Kodak Company
    Inventors: Allan F. Sowinski, Richard P. Szajewski, James P. Merrill
  • Patent number: 5385815
    Abstract: A photographic element comprising a UV absorbing polymer latex which is loaded with a non-polymeric UV absorbing compound. The polymer is a homopolymer or heteropolymer comprising monomeric units containing a 2-hydroxybenzotriazole. The benzotriazole preferably is of the formula I: ##STR1## wherein: the phenyl ring and benzo ring are optionally additionally substituted; and one of m and n is 1, and M and N have the formula: ##STR2## wherein R3 is H or an alkyl group; L is a bivalent linking group; and p is 0 or 1. The elements may additionally have a polmer present (which is preferably different from the UV absorbing polymer) which has a glass transition temperature (T.sub.g) of less than 5.degree. C.
    Type: Grant
    Filed: December 29, 1993
    Date of Patent: January 31, 1995
    Assignee: Eastman Kodak Company
    Inventors: Edward Schofield, Richard P. Szajewski
  • Patent number: 5384235
    Abstract: A photographic element with particular polymeric ultraviolet absorbers. The ultraviolet absorbers have repeating units of the formula: ##STR1## wherein: X is O or NH;Y is H or halogen;R.sub.1 is selected from the group consisting of H, halogen, alkoxy , straight chain or branched alkyl group of 1 to 8 carbons;R.sub.2 is C.sub.2 -C.sub.10 alkylene which may be straight chain or branched; andR.sub.3 is H or CH.sub.3.Elements of the invention have good fresh Dmin and image dye stability, and the ultraviolet absorbers therein are highly light stable.
    Type: Grant
    Filed: July 1, 1992
    Date of Patent: January 24, 1995
    Assignee: Eastman Kodak Company
    Inventors: Tien-Teh Chen, Edward Schofield, Hwei-Ling Yau, Lal C. Vishwakarma
  • Patent number: 5384234
    Abstract: The present invention provides a silver halide color photographic photosensitive material which has high saturation, excellent color reproduction and excellent graininess, the material comprising a silver halide emulsion layer which imparts an interlayer effect to a red sensitive silver halide emulsion layer is spectrally sensitized with a sensitizing dye represented by formula (I) and contains a development inhibitor releasing compound represented by formula (II).
    Type: Grant
    Filed: July 2, 1993
    Date of Patent: January 24, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Fumitaka Ueda, Junji Nishigaki, Akihiko Ikegawa
  • Patent number: 5382500
    Abstract: Disclosed is a silver halide color photographic light-sensitive material comprising a support and thereon a blue-sensitive silver halide emulsion layer, a green-sensitive silver emulsion layer and a red-sensitive silver halide emulsion layer, wherein said green-sensitive emulsion layer contains at least one coupler represented by Formula M-I and at least one of a non-color-forming compound represented by Formula A-1 or A-2: ##STR1## wherein R represents a hydrogen atom or a substituent; X represents a hydrogen atom or a substituent capable of splitting upon making a reaction with an oxidized product of a color developing agent; and Z represents a group consisting of metal atoms necessary to form a nitrogen-containing heterocyclic ring:Formula (A-1)R.sub.21 --NHSO.sub.2 --R.sub.22wherein R.sub.21 and R.sub.
    Type: Grant
    Filed: December 27, 1993
    Date of Patent: January 17, 1995
    Assignee: Konica Corporation
    Inventors: Shuichi Sugita, Hidenobu Ohya, Masakazu Tonishi
  • Patent number: 5382506
    Abstract: A silver halide color photographic light sensitive material comprising a support which is both side coated with a polyolefin resin is disclosed. A hydrophilic colloidal layer containing a white pigment and a silver halide emulsion layer are provided on the support and the silver halide emulsion layer contains at least one of the compounds represented by the following Formula I, ##STR1## wherein R.sub.1 represents an alkyl group, a cycloalkyl group or an aryl group; R.sub.2 represents a fluorine atom, an alkyl group, an aryl group, an alkoxy group, an aryloxy group, a dialkylamino group, an alkylthio group or an arylthio group; R.sub.3 represents a group substitutable to a benzene ring; n is an integer of 0 or 1; Z represents a hydrogen atom or a group capable of splitting off when coupling it to the oxidized product of a developing agent; and Y represents a monovalent organic group including a ballast group.
    Type: Grant
    Filed: August 20, 1993
    Date of Patent: January 17, 1995
    Assignee: Konica Corporation
    Inventors: Yasuo Tosaka, Masayuki Sasagawa
  • Patent number: 5380631
    Abstract: A silver halide color photographic light-sensitive material having at least one negative silver halide emulsion layer on a support, wherein the silver halide color photographic light-sensitive material contains at least one type of a compound which reacts with the oxidized form of a developing agent to release a development inhibitor or a precursor of a development inhibitor and/or at least one type of a compound which cleaves after reacting with the oxidized form of a color developing agent, the cleaved compound of which in turn reacts with another molecule of the oxidized form of a color developing agent to cleave a development inhibitor, and contains at least one type of a compound selected from Formulas (A) and (B) below. In Formulas (A) and (B), each of R.sub.a1 to R.sub.a5 and R.sub.b1 to R.sub.b5 represents a hydrogen atom, an alkyl group or other groups. R.sub.a1 to R.sub.a5 are not simultaneously hydrogen atoms, and one or two of R.sub.b2 to R.sub.b5 are hydroxyl groups.
    Type: Grant
    Filed: January 8, 1993
    Date of Patent: January 10, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yasushi Nozawa, Nobuo Seto, Nobutaka Ohki, Masayoshi Toyoda
  • Patent number: 5380639
    Abstract: A silver halide color photographic material containing a compound capable of the timed release of photographically useful groups is disclosed. The material contains at least one compound of the formula (I): ##STR1## wherein R.sub.1 is an alkyl group; R.sub.2 is an alkyl or aryl group; R.sub.3 is an oxycarbonyl, sulfonamido, carbamoyl, acylamino, ureido, oxycarbonylamino, sulfonyloxy, carbonyloxy or sulfamoyl group; R.sub.4 is a substituent; n is 0, 1, 2 or 3; and X is a group, preferably of the formula (II) or (III), which, when eliminated upon coupling with the oxidation product of a developing agent, forms an o-quinonemethide or p-quinonemethide to release a development inhibitor or a precursor thereof.
    Type: Grant
    Filed: August 5, 1992
    Date of Patent: January 10, 1995
    Assignee: Konica Corporation
    Inventors: Osamu Ishige, Eisaku Katoh, Hiroko Fujiwara, Shigeto Hirabayashi, Shuichi Sugita
  • Patent number: 5380633
    Abstract: An improved color reversal element is disclosed capable of development in black and white developer, and of development in a color developer comprising:a support having thereon at least two light-sensitive silver halide emulsion layers and a combination of compounds (A) and (B)Compound (A) capable of releasing a development modifier having the structural formulaM(Time).sub.n --INH(1)whereinM is a carrier, moiety from which --(Time).sub.n --INH(1) is released during black and white development to provide a weak inhibitor;Compound (B) having the structural formulaCAR--(TIME).sub.n --INH(2)wherein:CAR is a carrier moiety from which --(TIME).sub.n --INH(2) is released during color development to provide a strong inhibitor.
    Type: Grant
    Filed: January 15, 1993
    Date of Patent: January 10, 1995
    Assignee: Eastman Kodak Company
    Inventors: John W. Harder, John D. Baloga
  • Patent number: 5380632
    Abstract: A photosensitive photographic silver halide colour material comprising at least two dye image-forming units each separated from its neighbouring units by a layer containing a scavenger for oxidised developing agent, each unit comprising at least one silver halide emulsion layer and at least one dye image-forming colour coupler, the material comprising a total silver halide coating weight of less than 300 mg/m.sup.2 (as silver) characterised in that at least one image-forming unit contains extra gelatin either in a layer adjacent to the coupler-containing layer or in the coupler-containing layer itself such that the gelatin content of the unit is more than 800 mg/m.sup.2, in order to decrease the band width of the dye formed from said coupler.
    Type: Grant
    Filed: March 19, 1993
    Date of Patent: January 10, 1995
    Assignee: Eastman Kodak Company
    Inventors: Peter D. Marsden, John K. C. Kempster, John A. Bee
  • Patent number: 5378590
    Abstract: A color reversal photographic element comprises a support bearing a red-sensitive, cyan dye-forming unit, a green-sensitive, magenta dye-forming unit, and a blue-sensitive, yellow dye-forming unit, each unit comprising a photosensitive silver halide layer and an image-dye forming coupler; the element contains an interimage effect-controlling means which is characterized as having the capability of simultaneously forming a red image of high relative chroma and a yellow-red tint image of substantially lower relative chroma when the element is exposed to a red color standard object having CIELab values for D.sub.55 reference white a*=30.46, b*=19.16, C*=35.98, L*=40.12 and a yellow-red tint color standard object having CIELab values for D.sub.55 reference white a*=17.26, b*=18.01, C*=24.95, L*=66.98; the resulting images have a red reproduction coefficient equal to or greater than 0.88 and a ratio of red reproduction coefficient to yellow-red tint reproduction coefficient equal to or greater than 1.15.
    Type: Grant
    Filed: January 15, 1993
    Date of Patent: January 3, 1995
    Assignee: Eastman Kodak Company
    Inventors: Frederick E. Ford, Arlyce T. Bowne, Carl Kotlarchik, Jr.
  • Patent number: 5376513
    Abstract: A silver halide color photographic light-sensitive material comprising a support having thereon at least one light-sensitive silver halide emulsion layer, wherein the light-sensitive material contains a yellow colored cyan coupler and an acylacetamide yellow dye forming coupler having an acyl moiety represented by the general formula (A): ##STR1## wherein R.sub.1 represents a univalent group, Q represents a group of non-metal atoms required to form, together with C, a three to five membered hydrocarbon ring or a three to five membered heterocyclic ring which has within the ring at least one hetero atom selected from among N, O, S and P, with the proviso that R.sub.1 is not a hydrogen atom and it does not join with Q to form a ring.
    Type: Grant
    Filed: November 9, 1993
    Date of Patent: December 27, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Keiji Mihayashi
  • Patent number: 5376515
    Abstract: A silver halide color photographic light-sensitive material has, on a support, at least one green-sensitive silver halide emulsion layer containing a magenta coupler, at least one blue-sensitive silver halide emulsion layer containing a yellow coupler, and at least two red-sensitive silver emulsion layers containing a cyan coupler and having different sensitivities. The highest sensitivity layer of the red-sensitive silver halide emulsion layers contains a yellow coupler, and a red-sensitive emulsion layer having a lower sensitivity contains a yellow-colored cyan coupler.
    Type: Grant
    Filed: June 17, 1993
    Date of Patent: December 27, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Yuji Kume
  • Patent number: 5376514
    Abstract: A silver halide photosensitive photographic material comprising a support and provided thereon, photographic component layers including at least one silver halide emulsion layer is disclosed, wherein the photosensitive silver halide grains contained in all the silver halide emulsion layers have an average silver iodide content ranging from 0 to 3 mol % and contain at least silver bromide; and at least one of the silver halide emulsion layers contain a diequivalent phenolic cyan dye-forming coupler having a ureido group in a 2-position of a phenolic nucleus.
    Type: Grant
    Filed: March 4, 1994
    Date of Patent: December 27, 1994
    Assignee: Konica Corporation
    Inventors: Satoru Shinba, Toshihiko Kimura, Fumio Ishii
  • Patent number: 5374507
    Abstract: A silver halide color photographic light-sensitive material capable of providing a dye image having excellent color reproducibility, sharpness and image fastness.
    Type: Grant
    Filed: July 8, 1993
    Date of Patent: December 20, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Yasuhiro Yoshioka
  • Patent number: 5372920
    Abstract: A multilayered color photographic element contains a support having coated thereon photographic silver halide emulsion layers including at least one blue-sensitive and at least three red-sensitive silver halide emulsion layers, said red-sensitive layers respectively being most, mid, and least red-sensitive relative to each other, said most and mid red-sensitive layers being contiguous, and the most red-sensitive layer being a coupler starved layer, which element comprises:(a) a yellow image dye-forming coupler and substantially no development inhibitor releasing coupler in the most red-sensitive layer; and(b) at least one development inhibitor releasing coupler in the mid red-sensitive layer.
    Type: Grant
    Filed: June 11, 1993
    Date of Patent: December 13, 1994
    Assignee: Eastman Kodak Company
    Inventor: Larry D. Edwards
  • Patent number: 5370967
    Abstract: A photographic element for processing in moderate to large volume photofinishing baths and comprising one and only one dimensionally stable coating support, and coated thereon in reactive association an imaging layer containing radiation sensitive silver halide, a diffusible-dye forming layer containing a diffusible-dye forming compound, and a barrier layer overlaying said diffusible-dye forming layer is disclosed. This coating support is selected from reflection base and transparent base materials, and this diffusible-dye forming layer may be the same or different than this imaging layer. This barrier layer contains a polymer that allows the passage of solutions for processing when this element is contacted with an external processing bath, and impedes the diffusion out of this element of the diffusible dye formed from this diffusible-dye forming compound.
    Type: Grant
    Filed: September 28, 1992
    Date of Patent: December 6, 1994
    Assignee: Eastman Kodak Company
    Inventors: John Texter, Wayne A. Bowman, Glenn T. Pearce
  • Patent number: 5370978
    Abstract: Disclosed is a silver halide color photographic material which contains the combination of a pyrroloazole type cyan coupler and a carboxylic acid ester type high boiling organic solvent having a dielectric constant of at most 6.0 in a cyan color-forming silver halide emulsion layer and further contains a pyrazoloazole type magenta coupler in a magenta color-forming silver halide emulsion layer, thereby acquiring high color formability, excellent color reproducibility and preventing stains from generating in the white area after photographic processing.
    Type: Grant
    Filed: May 18, 1993
    Date of Patent: December 6, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Osamu Takahashi
  • Patent number: 5364748
    Abstract: There is disclosed a silver halide color photo-graphic light-sensitive material capable of providing a dye image having excellent color reproducibility, sharpness and image fastness. The light-sensitive material comprises a support having provided thereon a photographic constituent layer comprising a light-sensitive silver halide emulsion layer containing a yellow dye-forming coupler, a light-sensitive silver halide emulsion layer containing a magenta dye-forming coupler, and a light-sensitive silver halide emulsion layer containing a cyan dye-forming coupler, and non-light-sensitive hydrophilic colloid layers.
    Type: Grant
    Filed: July 8, 1993
    Date of Patent: November 15, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Hiroyuki Yoneyama
  • Patent number: 5362616
    Abstract: The invention is accomplished by forming balanced cyan, magenta, and yellow coupler and emulsion mixes. There is at least one layer in which silver halide emulsion has been sensitized to blue light or silver halide emulsion sensitive to green light. Regardless of the color sensitivity of the silver halide layer that contains silver contains a mix of cyan, magenta, and yellow dye-forming couplers. Further, in order to have a black-and-white image that has a lightness such as observed by the human eye in a scene, it is preferred that the ratios of red sensitive emulsion to green sensitive emulsion to blue sensitive emulsion in the photographic element is about 2:3:1.
    Type: Grant
    Filed: November 25, 1992
    Date of Patent: November 8, 1994
    Assignee: Eastman Kodak Company
    Inventors: James L. Edwards, Paul T. Hahm, Mitchell J. Bogdanowicz, Joseph E. LaBarca
  • Patent number: 5360702
    Abstract: Melt crystallization of a photographic composition containing dispersed particles of a filter dye and dispersed particles of oxidized developer scavenger, in particular a hydrazide or a disulfonamidophenol oxidized developer scavenger, is inhibited by dispersing the oxidized developer scavenger in the composition in the form of particles comprising the oxidized developer scavenger dispersed or dissolved in an organic solvent selected such that the following relationship is satisfied:6.65+10.0 A-1.53 B+0.11 B.sup.2 -0.99 AB<4.0wherein A is the weight ratio of organic solvent to oxidized developer scavenger; and B is the log P of the organic solvent.
    Type: Grant
    Filed: January 26, 1993
    Date of Patent: November 1, 1994
    Assignee: Eastman Kodak Company
    Inventors: Paul L. Zengerle, Glenn M. Brown, John B. Rieger
  • Patent number: 5356763
    Abstract: A silver halide color photographic material enables rapid processing, provides a high quality image and has excellent light fastness under extensive conditions, even under high humidity comprises a support, provided thereon at least three silver halide emulsion layers each containing at least one different coupler for forming a different dye by a coupling reaction with the oxidation product of an aromatic primary amine developing agent and each having a different light sensitivity, and at least one anti-color mixing layer provided between each of the emulsion layers and comprising a light-insensitive layer, wherein at least one of the above silver halide emulsion layers contains silver halide grains having a silver chloride content of 90 mole % or more and a magenta coupler represented by the following formula (I) and at least two of the anti-color mixing layers contain at least one anti-color mixing agent having a molecular weight of 350 or more and at least one high boiling organic solvent having the dielec
    Type: Grant
    Filed: March 1, 1993
    Date of Patent: October 18, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Osamu Takahashi, Nobutaka Ohki
  • Patent number: 5356764
    Abstract: A color photographic element having a support bearing at least one radiation sensitive emulsion layer comprising dispersing medium and silver halide grains is disclosed. The emulsion layer is a tabular grain silver halide emulsion layer Wherein at least 50 percent of total grain projected area is accounted for by tabular grains (a) bounded by {100} major faces having adjacent edge ratios of less than 10, (b) each having an aspect ratio of at least 2, and (c) internally at their nucleation site, containing iodide and at least 50 mole percent chloride. The emulsion layer has in reactive association an image dye-forming compound and a compound that contains a photographically useful group and is capable of reacting with oxidized developing agent to thereby release such group. A process for preparing the radiation sensitive tabular grain silver halide emulsions is also described.
    Type: Grant
    Filed: June 1, 1993
    Date of Patent: October 18, 1994
    Assignee: Eastman Kodak Company
    Inventors: Richard P. Szajewski, Gary L. House, Thomas B. Brust, Debra L. Hartsell, Donald L. Black, Anne E. Bohan, James P. Merrill
  • Patent number: 5342748
    Abstract: A color photographic light-sensitive material for printing use comprising a reflection type support bearing thereon a blue-sensitive silver halide emulsion layer, a green-sensitive silver halide emulsion layer and a red-sensitive silver halide emulsion layer; wherein a silver halide emulsion contained in said green-sensitive silver halide emulsion layer is a monodispersed silver halide emulsion and a coupler combined with said monodispersed silver halide emulsion is a magneta coupler represented by the following formula I ##STR1## wherein Z represents a group of non-metal atoms necessary for forming a nitrogen-containing heterocyclic ring, and the ring formed by the Z is allowed to have substituents; X represents a substituent capable of splitting off through the reaction thereof on the oxidation products of a color developing agent; and R represents hydrogen or a substituent.
    Type: Grant
    Filed: November 23, 1993
    Date of Patent: August 30, 1994
    Assignee: Konica Corporation
    Inventors: Masanobu Miyoshi, Makoto Kajiwara, Makoto Onodera
  • Patent number: 5340706
    Abstract: A silver halide color photographic light-sensitive material capable of providing a dye image having excellent color reproducibility, less fading of cyan, magenta and yellow colors and a dye image fastness with a good balance of the three colors, comprise a support and provided thereon a silver halide light-sensitive layer containing a cyan coupler, a silver halide light-sensitive layer containing a magenta coupler, and a silver halide light-sensitive layer containing a yellow coupler, wherein the silver halide light-sensitive layer containing the cyan coupler contains at least one pyrrolotriazole cyan couplers represented by the following Formula (I) or (II) as a cyan coupler and the silver halide light-sensitive layer containing the magenta coupler contains a pyrazoloazole magenta coupler represented by the following Formula (M) as a magenta coupler: ##STR1## with the substituents as defined in the specification.
    Type: Grant
    Filed: November 27, 1992
    Date of Patent: August 23, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hideaki Naruse, Makoto Suzuki
  • Patent number: 5338651
    Abstract: A silver halide color photographic light-sensitive material which provides a good color developability and an excellent color reproducibility in every hue comprises at least a cyan dye-forming emulsion layer, a magenta dye-forming emulsion layer and a yellow dye-forming emulsion layer, wherein the cyan dye-forming emulsion layer contains at least one cyan dye-forming coupler represented by the following Formula (I) or (II) and the yellow dye-forming emulsion layer contains at least one yellow dye-forming coupler represented by the following Formula (III) or (IV): ##STR1## to form a homopolymer or a copolymer; ##STR2## wherein X.sub.3 represents ##STR3## with the substituents as defined herein the specification.
    Type: Grant
    Filed: November 27, 1992
    Date of Patent: August 16, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hideaki Naruse, Makoto Suzuki, Takehiko Sato
  • Patent number: 5330886
    Abstract: A color photographic recording material having a support, at least one light-sensitive silver halide emulsion layer containing a pyrazoloazole magenta coupler, at least one other layer which is arranged closer to the source of light and at least one other layer arranged further away from the source of light than the silver halide emulsion layer containing the pyrazoloazole magenta coupler, these other layers containing gelatine and a randomly or alternatingly structured copolymer of vinyl alcohol and an unsaturated carboxylic acid or a graft polymer of vinyl acetate on polyalkylene oxide followed by saponification of the acetate groups is distinguished by improved stability to light of the magenta dye obtained after processing.
    Type: Grant
    Filed: January 27, 1993
    Date of Patent: July 19, 1994
    Assignee: AGFA-Gevaert AG
    Inventors: Gunter Helling, Gunter Renner
  • Patent number: 5328818
    Abstract: A silver halide color photographic light-sensitive material includes red-, green- and blue-sensitive silver halide emulsion layers, and a non-light-sensitive layer, and contains a dye of the following formula (I). The emulsion layer or the non-light-sensitive layer contains a yellow coupler of the following formula (1) or (2), or an acylacetamide type yellow coupler having an acyl group of the following formula (Y): ##STR1## where X and Y represent an electron attractive group, or when coupled with each other, XY represents an acidic nucleus, Ar represents a phenyl group or a heterocyclic group, and L.sup.1, L.sup.2 and L.sup.3 represent a methine group, ##STR2## where X.sub.1 and X.sub.2 represent an alkyl group, an aryl group, or a heterocyclic group, X.sub.3 represents an organic group which forms a nitrogen-containing heterocyclic group together with >N--, Y represents an aryl group or a heterocyclic group, and Z represents a split-off group, ##STR3## where D.sup.
    Type: Grant
    Filed: September 17, 1992
    Date of Patent: July 12, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroshi Fukuzawa, Kohzaburoh Yamada, Keiji Mihayashi, Koji Tamoto, Shigeru Shibayama, Minoru Sato, Kiyoshi Nakazyo
  • Patent number: 5322758
    Abstract: In accordance with this invention a photographic color diffusion transfer element is provided wherein said element comprises a single dimensionally stable transparent support and coated thereon in reactive association and in sequence (1) a mordant layer for binding diffusible dyes, (2) a light reflecting layer, (3) imaging layers comprising a radiation sensitive layer comprising silver halide and a diffusible dye forming layer comprising a diffusible dye forming compound, and (4) a barrier layer comprising a polymer that allows the passage of solutions for processing said element when said element is contacted with an external processing bath, and wherein said barrier layer impedes the diffusion out of said element of the diffusible dye formed from said diffusible dye forming compound.
    Type: Grant
    Filed: September 28, 1992
    Date of Patent: June 21, 1994
    Assignee: Eastman Kodak Company
    Inventors: John Texter, Wayne A. Bowman, Glenn T. Pearce, Douglas E. Corbin
  • Patent number: 5322766
    Abstract: A color negative photographic recording material is described in which low emulsion coverage tabular grain silver halide emulsion imaging units are employed. The silver halide emulsion in at least one of the units comprises grains having a tabularity of between about 50 and 25,000. The imaging unit thickness is less than about 4.0 .mu.m, using a total of no more than 2.0 parts by weight of silver per part of coupler. The imaging unit yields a density of at least 2.0 when exposed and processed.
    Type: Grant
    Filed: January 19, 1993
    Date of Patent: June 21, 1994
    Assignee: Eastman Kodak Company
    Inventors: Allan F. Sowinski, George F. Wu, Thomas B. Brust, James T. Kofron, Gary L. House
  • Patent number: 5322767
    Abstract: A silver halide color photographic material having at least three light-sensitive silver halide emulsion layers, each sensitive in a different wavelength region. At least one of the silver halide emulsion layers contains at least one adsorbable reducing compound represented by a hydroquinone containing a group capable of promoting adsorption to silver halide grains and a silver halide emulsion having a silver chloride content of at least 90 mol %. The photographic material is well adapted for rapid processing and maintains constant sensitivity with a change in humidity upon exposure and when stored for a long period of time prior to use.
    Type: Grant
    Filed: June 18, 1992
    Date of Patent: June 21, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Naoto Ohshima, Morio Yagihara
  • Patent number: 5320920
    Abstract: The method for producing a color filter of the present invention comprises the following steps: an inorganic active layer is formed on a transparent substrate, a first color is dyed on said inorganic active layer, a resist is formed on portions of the inorganic active layer other than portions where a second color is dyed, a decoloring treatment is conducted, the second color is dyed on the exposed inorganic active layer, the resist is removed, a resist is formed on portions of the inorganic active layer other than portions where a third color is dyed, a decoloring treatment is conducted, the third color is dyed on the exposed inorganic active layer, and then the resist is removed.
    Type: Grant
    Filed: March 29, 1990
    Date of Patent: June 14, 1994
    Assignee: Nissha Printing Co., Ltd.
    Inventors: Tenri Isoda, Masahiro Nishida, Takao Hashimoto, Kanji Suyama, Kenji Kishi, Yoshihide Inako, Yosuke Matsukawa
  • Patent number: 5320937
    Abstract: A silver halide photographic emulsion contains silver halide grains comprising at least two portions, i.e., a core and an outermost shell with different silver halide compositions and having an average aspect ratio of less than 8. The core consists of silver iodobromide, silver chloroiodobromide, silver chlorobromide, or silver bromide. An average silver iodide content of the outermost shell is higher than that of the core and is 6 mol % or more. The silver halide grains are subjected to all of selenium sensitization, gold sensitization, and sulfur sensitization.
    Type: Grant
    Filed: December 10, 1992
    Date of Patent: June 14, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Mikio Ihama
  • Patent number: 5314792
    Abstract: A photographic element and process useful therewith comprises at least two light sensitive silver halide layers sensitized to green light and having differing degrees of light sensitivity, comprising in association with a higher sensitivity layer a yellow dye forming DIR coupler which releases a development inhibitor containing a weak inhibitor fragment, and further comprising in association with the lower sensitivity layer a cyan dye forming DIR coupler with a timing group containing a strong inhibitor fragment which releases a precursor of the development inhibitor fragment.
    Type: Grant
    Filed: January 29, 1993
    Date of Patent: May 24, 1994
    Assignee: Eastman Kodak Company
    Inventor: James P. Merrill
  • Patent number: 5310630
    Abstract: A silver halide color photographic photosensitive material which has been spectrally sensitized to light of wavelengths greater than of about 670 nm in which are highly sensitive to light of wavelength greater than about 670 nm and sufficiently insensitive to visible light having a shorter wavelength. The photosensitive materials comprises a silver halide photosensitive layer containing the yellow coupler, a silver halide photosensitive layer containing a magenta coupler, a silver halide photosensitive layer containing a cyan coupler and at least one non-photosensitive hydrophilic layer. Each of the photosensitive layers are spectrally sensitized such that they have different peak spectral sensitivities at light wavelengths greater than about 670 nm.
    Type: Grant
    Filed: May 6, 1992
    Date of Patent: May 10, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Yoshio Inagaki
  • Patent number: 5310638
    Abstract: A silver halide color photographic material comprises a support, a blue sensitive layer, a green sensitive layer and a red sensitive layer. The total silver content of the photographic material is not more than 1.0 g/m.sup.2. The photographic material further contains a compound represented by the formula (1a) or (1b): ##STR1## in which R.sup.12 is an aliphatic group, an aromatic group or a heterocyclic group; M is --CO--, --SO.sub.2 --, --N(R.sup.15)CO--, --OCO-- or --N(R.sup.15)SO.sub.2 --; each of R.sup.14, R.sup.15 and R.sup.24 independently is hydrogen, an alkyl group or an aryl group; L is a divalent linking group necessary for forming a 5, 6 or 7-membered ring; each of R.sup.11, R.sup.13 and R.sup.21 independently is hydrogen or a substituent group of the hydroquinone nucleus; Time is a group which is released from the oxidation product of the hydroquinone nucleus to further release X; X is a development inhibitor; and t is 0 or 1. M preferably is --SO.sub.2 --, --N(R.sup.15)CO--, --OCO-- or --N(R.sup.
    Type: Grant
    Filed: October 25, 1991
    Date of Patent: May 10, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Sadanobu Shuto, Takashi Ozawa
  • Patent number: 5306608
    Abstract: A direct positive photographic light-sensitive material comprises a support and a light-sensitive emulsion layer provided thereon which contains non-pre-fogged internal latent image type silver halide grains of a core/shell structure. The cores of the silver halide grains are treated with a spectral sensitizing dye and a chemical sensitizer.
    Type: Grant
    Filed: October 19, 1992
    Date of Patent: April 26, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Kiyokatsu Kato
  • Patent number: RE34697
    Abstract: A silver halide light-sensitive material having a support and at least one silver halide emulsion is provided. The silver halide emulsion layer contains in combination at least one cyan coupler of Formula (I) and at least one cyan coupler of Formula (II).
    Type: Grant
    Filed: May 29, 1990
    Date of Patent: August 16, 1994
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Shun Takada, Kaoru Onodera, Takashi Kadowaki