Organic Dye Or Pigment Containing Patents (Class 430/517)
  • Patent number: 5994431
    Abstract: An ultraviolet light absorbing material that resists blooming and migration is made up of a carboxyl functional polymer and an amide functional ultraviolet light absorbing compound, wherein the carboxyl functional polymer and the amide functional ultraviolet light absorbing compound are hydrogen bonded to one another. Polymeric films that contain a polyolefin and the ultraviolet light absorbing material are useful as the top layer in multilayer constructions such as retroreflective sheetings and conformable marking sheets.
    Type: Grant
    Filed: May 3, 1996
    Date of Patent: November 30, 1999
    Assignee: 3M Innovative Properties Company
    Inventors: David B. Olson, David M. Burns
  • Patent number: 5993958
    Abstract: There is disclosed a method of manufacturing a polyester-series photographic support, comprising the steps of: incorporating at least one anthraquinone-series dye into a polyester, which polyester is produced by a condensation polymerization reaction of a dicarboxylic acid component that comprises a dialkyl ester of naphthalene-2,6-dicarboxylic acid as a main component, with a diol component that comprises ethylene glycol as a main component, the polyester being produced by allowing manganese, magnesium, antimony, and phosphorus to be incorporated in specific amounts, whereby the polyester has melt electric resistance in terms of common logarithm (log R) in the melt state at 300.degree. C. in the range of from 7.0 to 9.5, and intrinsic viscosity, measured in a mixture solution of phenol/tetrachloroethane (6/4, weight ratio) at 25.degree. C., in the range of from 0.49 to 0.
    Type: Grant
    Filed: January 21, 1997
    Date of Patent: November 30, 1999
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Toshimitsu Okutsu
  • Patent number: 5994050
    Abstract: The invention relates to a method of improved burning and dodging comprising providing a color photographic element that prior to development has CIELAB coordinates such that L* is greater than 71, exposing said paper, wherein during exposure burning and dodging is carried out.
    Type: Grant
    Filed: October 3, 1997
    Date of Patent: November 30, 1999
    Assignee: Eastman Kodak Company
    Inventors: Roupen H. Maronian, Donald R. Diehl, Pamela M. Ferguson, Joseph E. LaBarca
  • Patent number: 5985537
    Abstract: A photothermographic element comprising a substrate having on at least one side thereof a photothermographic system comprising silver halide spectrally sensitized to the infrared region of the electromagnetic spectrum, a light insensitive silver source, a reducing agent for silver ion, and a binder, said element further comprising at least one layer which contains an infrared-absorbing dye having a central nucleus of the formula ##STR1## wherein n is an integer of 1 to 12,Q is an ionic acidic moiety,and M is a cation, in an amount sufficient as to provide a transmission optical density of at least 0.1 at the wavelength of maximum sensitivity of said sensitized silver halide.
    Type: Grant
    Filed: November 10, 1993
    Date of Patent: November 16, 1999
    Assignee: Minnesota, Mining & Manufacturing Co.
    Inventors: James B. Philip, Jr., Charles W. Gomez
  • Patent number: 5968707
    Abstract: A transfer material colored to a predetermined color is used when images are formed on a transfer material for use in thermal transfer comprising a substrate and a dye receiving layer by a thermal transfer process.When images are formed by an optional image forming method such as silver salt photographic process, ink jet process or thermal transfer process, a transfer material having sepia tone is used in each of the image forming processes thereby forming sepia tone images. Images having unique appearance can be formed easily upon forming images by a thermal transfer process. Images of sepia tone can be formed safely and conveniently.
    Type: Grant
    Filed: July 14, 1998
    Date of Patent: October 19, 1999
    Assignee: Sony Corporation
    Inventor: Satoru Shinohara
  • Patent number: 5962207
    Abstract: The present invention is a motion picture film including a support having on one side thereof an antihalation undercoat and at least one silver halide emulsion layer. The motion picture film has on the opposite side thereof an antistatic layer and a protective overcoat. The protective overcoat includes a layer of a polyurethane binder having a tensile elongation to break of at least 50% and a Young's modulus measured at a 2% elongation of at least 50000 lb/in.sup.2, and a topcoat farthest from said support. The topcoat is an interpolymer having repeating units of A and B wherein A is a fluorine containing acrylate or methacrylate monomer and B is an ethylenically unsaturated monomer containing hydratable groups.
    Type: Grant
    Filed: February 5, 1998
    Date of Patent: October 5, 1999
    Assignee: Eastman Kodak Company
    Inventors: Charles C. Anderson, Brian A. Schell, Debasis Majumdar, Mario D. DeLaura
  • Patent number: 5959105
    Abstract: A dihydroperimidine squarylium compound is represented by the formula (I): ##STR1## in which each of R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7, R.sup.8, R.sup.9, R.sup.10, R.sup.11 and R.sup.12 independently is hydrogen, an alkyl group, a cycloalkyl group, an aryl group, an aralkyl group, an alkenyl group, an alkynyl group or an acyl group; R.sup.1 and R.sup.2, R.sup.3 and R.sup.4, R.sup.5 and R.sup.6, R.sup.7 and R.sup.8, R.sup.9 and R.sup.10 or R.sup.11 and R.sup.12 may be combined with each other to form a five- or six-membered nitrogen-containing heterocyclic ring; R.sup.2 and R.sup.3, R.sup.6 and R.sup.7 or R.sup.10 and R.sup.11 may be combined with each other to form a five- or six-membered aliphatic ring; and n is an integer of 1 to 6. The specification further discloses a mixture of dihydroperimidine squarylium compounds, an infrared absorbing sheet and a silver halide photographic material.
    Type: Grant
    Filed: January 21, 1998
    Date of Patent: September 28, 1999
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toru Harada, Yoshiharu Yabuki
  • Patent number: 5952162
    Abstract: A silver halide film for reproducing digitally stored medical diagnostic images through exposure and processing, including development, fixing and drying, in 90 seconds or less is disclosed in which onto a film support transparent to exposing radiation are coated (1) a processing solution permeable front layer unit coated on the front major face of the support capable of absorbing up to 60 percent of the exposing radiation and containing less than 30 mg/dm.sup.2 of hydrophilic colloid and less than 20 mg/dm.sup.2 silver in the form of radiation-sensitive silver halide grains and (2) a processing solution permeable back layer unit coated on the back major face of the support containing less than 40 mg/dm.sup.2 of hydrophilic colloid, silver in the form of radiation-sensitive silver halide grains accounting for from 40 to 60 percent of the total radiation-sensitive silver halide present in the film, and a dye capable of providing an optical density of at least 0.
    Type: Grant
    Filed: November 18, 1997
    Date of Patent: September 14, 1999
    Assignee: Eastman Kodak Company
    Inventors: Robert E. Dickerson, Wray E. Paul
  • Patent number: 5952163
    Abstract: A direct X-ray dental film is disclosed that, following imagewise exposure, can be removed from its opaque package and processed in room light. The film is comprised of emulsion and protective layers that contain dye particles which can be decolorized during processing. The dye particles provide an average density of greater than 3.0 over a spectral range of above 320 nm over which the silver halide exhibits an absorption coefficient of at least 0.5 cm.sup.-1. For additional protection the emulsion layers contain desensitizer adsorbed to the silver halide grains to reduce their sensitivity to light without significantly reducing their sensitivity to X-radiation.
    Type: Grant
    Filed: January 14, 1998
    Date of Patent: September 14, 1999
    Assignee: Eastman Kodak Company
    Inventors: Jeffrey S. Baugher, Robert E. Dickerson, Alan S. Fitterman
  • Patent number: 5952165
    Abstract: This invention relates to a motion picture film having a support and having, in order, on one side thereof an antihalation undercoat and at least one silver halide emulsion layer and having, in order, on the opposite side thereof an antistatic layer, a protective overcoat; characterized in that said protective overcoat includes a polyurethane binder, the polyurethane binder has a tensile elongation to break of at least 50% and a Young's modulus measured at a 2% elongation of at least 50000 lb/in.sup.2, and a topcoat farthest from the support which comprises gelatin-coated, latex particles.
    Type: Grant
    Filed: June 4, 1998
    Date of Patent: September 14, 1999
    Assignee: Eastman Kodak Company
    Inventors: Charles C. Anderson, Brian A. Schell
  • Patent number: 5948600
    Abstract: The present invention relates to an infra-red laser sensitive thermographic material and to a process for forming a heat mode image using such a material.
    Type: Grant
    Filed: September 10, 1997
    Date of Patent: September 7, 1999
    Assignee: AGFA-Gevaert N.V.
    Inventors: Peter Roschger, Stephan Michaelis, Karin Hassenruck, Horst Berneth, Paul Callant, Herman Uytterhoeven, Luc Bastiaens, Guy Van Ackere
  • Patent number: 5945209
    Abstract: An anti-reflection film comprises a low refractive index layer provided on one surface of a transparent support. The low refractive index layer has a refractive index of not higher than 1.45. The low refractive index layer has a surface average reflectance of not higher than 1% within the visible region of 400 to 800 nm. According to the first embodiment of the present invention, an infrared absorbing layer is provided between the transparent support and the low refractive index layer. According to the second embodiment of the present invention, an infrared absorbing layer is provided on the other surface of the transparent support. The infrared absorbing layer contains an infrared absorbing dye. The infrared absorbing layer decreases a transmittance of the film to not higher than 40% at a wavelength within the infrared region of 800 to 1,100 nm. Plasma display panels using the anti-reflection films are also disclosed.
    Type: Grant
    Filed: November 7, 1997
    Date of Patent: August 31, 1999
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masaki Okazaki, Toru Harada, Tomokazu Yasuda
  • Patent number: 5945263
    Abstract: A photothermographic recording material comprising a support; a photo-addressable thermally developable element comprising a substantially light-insensitive organic silver salt, photosensitive silver halide in catalytic association with the substantially light-insensitive organic silver salt spectrally sensitized to the infrared region of the electromagnetic spectrum and a binder; and in a hydrophobic layer an antihalation dye according to the general formula (I): ##STR1## wherein R.sup.1 and R.sup.15 independently represent an alkyl group or an alkyl group substituted with at least one fluorine, chlorine, bromine or an alkoxy-, aryloxy- or ester-group; R.sup.2, R.sup.3, R.sup.16 and R.sup.17 independently represent an alkyl group; R.sup.4, R.sup.5, R.sup.6, R.sup.7, R.sup.18, R.sup.19, R.sup.20 and R.sup.
    Type: Grant
    Filed: May 30, 1997
    Date of Patent: August 31, 1999
    Assignee: Agfa-Gevaert N.V.
    Inventors: Geert Deroover, Etienne Van Thillo, Ivan Hoogmartens, Hans Strijckers
  • Patent number: 5932404
    Abstract: The present invention is a silver halide photographic material including at least one layer which contains; a polymer comprising as constituent components thereof a repeating unit having a photographically useful group and at least one repeating unit having an imidazole group; and a compound having at least one functional group which reacts with an imidazole group and at least one other functional group capable of reacting with an imidazole group and a primary amine group, the amount of the compound being sufficient to insure adequate fixation of said polymer.
    Type: Grant
    Filed: December 18, 1996
    Date of Patent: August 3, 1999
    Assignee: Eastman Kodak Company
    Inventors: Tienteh Chen, Hwei-ling Yau, Dorothy T. Java
  • Patent number: 5932402
    Abstract: A colour photographic recording material, comprising of a transparent film base, red-sensitive, green-sensitive and blue-sensitive silver halide emulsion layer units which are disposed thereon and which contain colour couplers, and optionally of further light-insensitive layers, wherein the green-sensitive silver halide emulsion layer unit comprises at least two green-sensitive partial layers, the partial layer of which which is furthest from the film base has the highest sensitivity and is situated further from the film base than is each partial layer of the red-sensitive silver halide emulsion layer unit, and wherein each partial layer of the blue-sensitive silver halide emulsion layer unit is situated further from the film base than is the highest-sensitivity partial layer of the green-sensitive silver halide emulsion layer unit, contains, in the highest-sensitivity partial layer of the green-sensitive silver halide emulsion layer unit, an organic yellow dye which can be decolorised during processing; the
    Type: Grant
    Filed: December 16, 1997
    Date of Patent: August 3, 1999
    Assignee: Agfa-Gevaert AG
    Inventors: Heinz Schutz, Rainer Scheerer, Klaus Sinzger
  • Patent number: 5928849
    Abstract: A black and white photographic element contains a filter dye of Formula (I): ##STR1## wherein each R.sup.1 is independently substituted or unsubstituted alkyl, substituted or unsubstituted alkoxy, cyano, hydroxy, carboxy, substituted or unsubstituted amido, or substituted or unsubstituted sulfonamido;n is 1-4;R.sup.2 is H, substituted or unsubstituted alkyl or amido;each of R.sup.3 and R.sup.4 is independently hydrogen or substituted or unsubstituted alkyl; andM is a cation.
    Type: Grant
    Filed: July 31, 1996
    Date of Patent: July 27, 1999
    Assignee: Eastman Kodak Company
    Inventors: Christopher Edwin Wheeler, Robert Bruce Bayley, Michael Kent Coil, Margaret Jones Helber
  • Patent number: 5925505
    Abstract: Direct X-ray films are disclosed capable of being handled in room light prior to and during processing. The films contain silver halide grains responsive to X-radiation that are sulfur sensitized. The films also contain a combination of processing solution bleachable dyes chosen to provide prior to processing (a) an average density of greater than 3.0 over a first, continuous spectral sensitivity range extending from a minimum wavlength of 320 nm over which the silver halide grains exhibit an absorption coefficient of at least 0.5 cm.sup.-1 and (b) a density of greater than 3.0 throughout a second spectral range including wavelengths of from 600 to 650 nm.
    Type: Grant
    Filed: May 29, 1998
    Date of Patent: July 20, 1999
    Assignee: Eastman Kodak Company
    Inventors: Jeffrey S. Baugher, Robert E. Dickerson, Alan S. Fitterman
  • Patent number: 5919609
    Abstract: The synthesis and the application of new dyes is described. In particular said new dyes can be incorporated in non-migratory state in hydrophilic colloid layers of photographic materials wherefrom they can be rapidly removed after being quickly decolourised in alkaline aqueous liquids used in the processing of said materials. In photographic applications dyes of the general formula (I) are provided with at least one ionisable group which permits solubilisation in aqueous and/or alkaline medium. ##STR1## The meanings of the symbols are as defined in the claims and in the description.
    Type: Grant
    Filed: May 20, 1998
    Date of Patent: July 6, 1999
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Eric Kiekens, Paul Callant
  • Patent number: 5919610
    Abstract: The synthesis and the application of new dyes is described. In particular said new dyes can be incorporated in non-migratory state in hydrophilic colloid layers of photographic materials wherefrom they can be rapidly removed after being quickly decolourised in alkaline aqueous liquids used in the processing of said materials. In photographic applications dyes of the general formula (I) are provided with at least one ionisable group which permits solubilisation in aqueous and/or alkaline medium. ##STR1## The meanings of the symbols are as defined in the claims and in the description.
    Type: Grant
    Filed: May 20, 1998
    Date of Patent: July 6, 1999
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Eric Kiekens, Paul Callant
  • Patent number: 5919598
    Abstract: A method for making multilayer resist structures for microlithographic processing using a thermosetting anti-reflective coating is disclosed for a broad range of exposure wavelengths, said coating containing an active curing catalyst, ether or ester linkages derived from epoxy functionality greater than 3.0, a dye-grafted hydroxyl-functional oligomer, and an alkylated aminoplast crosslinking agent, all present in a low-to-medium alcohol-containing solvent.
    Type: Grant
    Filed: August 6, 1996
    Date of Patent: July 6, 1999
    Assignee: Brewer Science, Inc.
    Inventors: Tony D. Flaim, Jim D. Meador, Xie Shao, Terry Lowell Brewer
  • Patent number: 5910399
    Abstract: The present invention is a motion picture film which includes a support having, in order, on one side thereof an antihalation undercoat and at least one silver halide emulsion layer and having, in order, on the opposite side thereof an antistatic layer and a protective overcoat. The protective overcoat includes a polyurethane binder having a tensile elongation to break of at least 50% and a Young's modulus measured at a 2% elongation of at least 50000 lb/in.sup.2, and a topcoat farthest from the support. The topcoat is formed by the coating and subsequent drying of a coating composition comprising gelatin-grafted polyurethane comprising gelatin covalently bound to a polyurethane through a grafting agent, wherein the ratio of gelatin to polyurethane is from 1:10 to 2:1.
    Type: Grant
    Filed: June 4, 1998
    Date of Patent: June 8, 1999
    Assignee: Eastman Kodak Company
    Inventors: Brian A. Schell, Charles C. Anderson
  • Patent number: 5910398
    Abstract: Photographic glass plates can be prepared by directly coating the appropriate layer formations onto a glass support. One element comprises a thin subbing layer (less than 2 .mu.m), an antihalation layer, a silver halide emulsion layer, and a protective overcoat layer that can also include a matting agent or lubricant. Another embodiment has the antihalation layer coated directly onto the support.
    Type: Grant
    Filed: June 13, 1996
    Date of Patent: June 8, 1999
    Assignee: Eastman Kodak Company
    Inventors: Ronald James Schmidt, Lawrence Annello Savino
  • Patent number: 5871897
    Abstract: A silver halide photographic material is disclosed, which contains a connected-dye compound having a fixed configuration in which one cyanine dye plane is in parallel with and lies over the other so that the connected-dye compound always shows an absorption assignable to a cyanine dye aggregate thereof. The silver halide photographic material has excellent storage stability.
    Type: Grant
    Filed: June 26, 1996
    Date of Patent: February 16, 1999
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Takashi Katoh
  • Patent number: 5863714
    Abstract: There is disclosed a silver halide light-sensitive material which contains a methine compound represented by general formula (1):General formula (1) ##STR1## wherein A1, A2, and A3 each represent a streptocyanine dye; L1, L2, L3, and L4 each represent a divalent linking group, and n1 represents an integer of not less than 0. The light-sensitive material exhibits high absorptivity.
    Type: Grant
    Filed: April 15, 1997
    Date of Patent: January 26, 1999
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takashi Kato, Takayoshi Oyamada
  • Patent number: 5858608
    Abstract: There are described diffusion transfer photosensitive film units which include a novel antihalation layer comprising an antihalation material, titanium dioxide and a binder. Diffusion transfer film units prepared according to the invention provide silver images of enhanced resolution, film speed and sharpness.
    Type: Grant
    Filed: October 16, 1997
    Date of Patent: January 12, 1999
    Assignee: Polaroid Corporation
    Inventors: Barry B. Corden, Fredric N. Cramer, Paul E. Nangeroni
  • Patent number: 5856520
    Abstract: A novel substituted benzenedithiol metal complex represented by the general formula (1) is provided. The substituted benzenedithiol metal complex is useful as a singlet oxygen quencher and as an optical data recording medium per se. ##STR1## wherein M is a transition metal; A.sup.+ is a quaternary ammonium group; and R is an organic group selected from the group consisting of organic groups represented by the formulae (i), (ii), (iii) and (iv): ##STR2## (wherein R.sup.1 is an alkyl group having 1 to 4 carbon atoms), ##STR3## (wherein n is 3, 4 or 5), ##STR4## (wherein R.sup.2 is one of a hydrogen atom and a substitutent having 1 to 4 carbon atoms).
    Type: Grant
    Filed: October 20, 1997
    Date of Patent: January 5, 1999
    Assignee: Sumitomo Seika Chemicals Co., Ltd.
    Inventors: Kazuyoshi Hirako, Satoshi Kimura, Michio Suzuki
  • Patent number: 5853951
    Abstract: A silver halide photographic material comprising a support having thereon at least one silver halide emulsion layer, wherein: the silver halide emulsion layer comprises a silver halide comprising silver chloride or silver chlorobromide having a silver chloride content of not less than 95 mol %; the silver halide emulsion comprises at least one transition metal selected from the group consisting of elements belonging to the groups V to VIII of the periodic table, which has one nitrosyl, thionitrosyl or aquo ligand per molecule; and the silver halide is chemically sensitized with a selenium compound selected from compounds represented by one of formulae SE-1 to SE-8 disclosed in the specification.
    Type: Grant
    Filed: October 3, 1996
    Date of Patent: December 29, 1998
    Assignee: Fuji Photo Film Co., LTD.
    Inventors: Shoji Yasuda, Tadashi Ito, Takahiro Goto, Hirotomo Sasaki, Seiichi Yamamoto
  • Patent number: 5853969
    Abstract: A silver halide photographic material comprises a support, at least one silver halide emulsion layer and at least one non-light-sensitive hydrophilic colloidal layer. The silver halide emulsion layer or the hydrophilic colloidal layer contains a colorant having the absorption maximum wavelength within the infrared region of 700 to 1,100 nm. The colorant is in the form of solid particles dispersed in the silver halide emulsion layer or in the hydrophilic colloidal layer. The solid particles cannot substantially be removed by a processing solution of the silver halide photographic material. An image forming process employing the silver halide photographic material is also disclosed.
    Type: Grant
    Filed: November 28, 1997
    Date of Patent: December 29, 1998
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toru Harada, Keiichi Suzuki, Shigeru Ohno, Koji Wariishi, Yoshiharu Yabuki
  • Patent number: 5853971
    Abstract: A color photographic silver halide material contains on a support at least one red-sensitive, cyan-coupling, at least one green-sensitive, magenta-coupling and at least one blue-sensitive, yellow-coupling silver halide emulsion layer together with interlayers between layers of different colour sensitivity, wherein at least one of the stated interlayers contains at least one masking coupler, the masking coupler having a reaction rate constant for the coupling reaction with the developer oxidation product of .gtoreq.5000 1-mol.sup.- .cndot.s.sup.-1, is distinguished improved sensitivity without increase of granularity.
    Type: Grant
    Filed: April 15, 1997
    Date of Patent: December 29, 1998
    Assignee: Agfa-Gevaert AG
    Inventors: Peter Bell, Hans-Ulrich Borst, Ralf Buscher, Johannes Willsau, Jorg Siegel
  • Patent number: 5851747
    Abstract: A silver halide photographic light sensitive material comprising a support having thereon photographic component layers including a light sensitive silver halide emulsion layer and a light insensitive hydrophilic colloid layer, wherein the silver halide emulsion layer comprises a silver halide emulsion which has been subjected to desalting by ultrafiltration, at least one of the component layers containing a composite material comprising a hydrophobic polymer and inorganic particles.
    Type: Grant
    Filed: May 20, 1996
    Date of Patent: December 22, 1998
    Assignee: Konica Corporation
    Inventor: Shigeaki Takahashi
  • Patent number: 5851720
    Abstract: A transfer material colored to a predetermined color is used when images are formed on a transfer material for use in thermal transfer comprising a substrate and a dye receiving layer by a thermal transfer process.When images are formed by an optional image forming method such as silver salt photographic process, ink jet process or thermal transfer process, a transfer material having sepia tone is used in each of the image forming processes thereby forming sepia tone images. Images having unique appearance can be formed easily upon forming images by a thermal transfer process. Images of sepia tone can be formed safely and conveniently.
    Type: Grant
    Filed: November 12, 1996
    Date of Patent: December 22, 1998
    Assignee: Sony Corporation
    Inventor: Satoru Shinohara
  • Patent number: 5851243
    Abstract: A radiographic element is disclosed capable of producing a maximum density of at least 3.0 when imagewise exposed and processed in less than 45 seconds. The element includes magenta dye or dyes, including a dye for spectrally sensitizing radiation-sensitive silver halide grains, that leave a residual density at 505 nm of greater than 0.1 when the element is processed. Transmission of red light through the radiographic element when imagewise exposed and processed to produce a viewable image is reduced by the incorporation in at least one of the hydrophilic colloid layers of at least one ionic linear condensation polymer containing a cyan phthalocyanine dye.
    Type: Grant
    Filed: April 30, 1997
    Date of Patent: December 22, 1998
    Assignee: Eastman Kodak Company
    Inventors: Robert E. Dickerson, Rickey J. Seyler
  • Patent number: 5834172
    Abstract: A photographic coating composition comprising an aqueous medium containing a hydrophilic colloid and having dispersed therein solid particles of a yellow filter dye also contains a oxidized developer scavenger of formula III ##STR1## wherein x.sup.1 =hydrogen or a process cleavable group;R.sup.14 =an electron withdrawing and aqueous solubilizing group;R.sup.15 =a substituent group;R.sup.16 =a ballasting group;R.sup.17 =a substituent group;i=1, 2, 3, or 4; andj=1, 2, 3, or 4.The coating composition is stable with regard to crystal growth of the dispersed solid particles of filter dye even when held at coating temperatures (about 45.degree. C.) for several hours.
    Type: Grant
    Filed: February 23, 1996
    Date of Patent: November 10, 1998
    Assignee: Eastman Kodak Company
    Inventors: Paul Leo Zengerle, John Victor Nelson, Mary Christine Brick
  • Patent number: 5834173
    Abstract: A photographic element contains a dye of Formula (I): ##STR1## wherein G represents O or dicyanovinyl (--C(CN).sub.2); E.sup.1 represents an electron withdrawing group; R.sup.1 represents a substituted or unsubstituted aryl group or a substituted or unsubstituted hetereoaryl group; L.sup.1, L.sup.2 and L.sup.3 each independently represent substituted or unsubstituted methine groups; Z represents non-metal atoms which may be assembled to form a five- or six-membered heterocyclic ring other than furan; and n represents 0 or 1; and wherein the dye comprises at least one ionizable group with a pKa value between 4 and 12.
    Type: Grant
    Filed: June 28, 1996
    Date of Patent: November 10, 1998
    Assignee: Eastman Kodak Company
    Inventors: Margaret Jones Helber, Donald Richard Diehl, Terrence Robert O'Toole
  • Patent number: 5811229
    Abstract: An image-forming film-screen system for medical diagnostic imaging is disclosed comprising a light-sensitive silver halide photographic film material in operative association with at least one intensifying screen comprising on a support a layer of a visible light emitting luminescent phosphor, the said film material comprising a support and on at least one side thereof a light-sensitive silver halide emulsion layer having spectrally sensitized tabular silver halide and a non-light-sensitive protective layer, wherein said protective layer contains a polymeric compound selected from the group consisting of gelatin, a synthetic, semi-synthetic or natural substitute for gelatin and latex (co)polymers, in an amount of at least 0.4 g per m.sup.2 ; characterized in that between a light-sensitive silver halide emulsion layer and said protective layer there is an intermediate layer comprising a blue colored pigment in dispersed form, having a solubility in isopropanol at 25.degree. C. of less than 10 mg per liter.
    Type: Grant
    Filed: January 22, 1997
    Date of Patent: September 22, 1998
    Assignee: AGFA-Gevaert, N.V.
    Inventor: Marc Van den Zegel
  • Patent number: 5800963
    Abstract: A composition and methods for the use and manufacture thereof are provided for a polymeric dye. The composition comprises one or more aminoaromatic chromophores in conjunction with polymers having an anhydride group or the reaction products thereof. The composition is particularly useful as an underlaying antireflective coating with microlithographic photoresists for the absorbtion of near or deep ultraviolet radiation.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: September 1, 1998
    Assignee: International Business Machines Corporation
    Inventors: Christopher John Knors, Elwood Herbert Macy, Wayne Martin Moreau
  • Patent number: 5800971
    Abstract: The invention provides a multilayer color negative photographic element comprising a support, at least one light-sensitive silver halide emulsion layer sensitive to each of the blue, green and red regions of the visible spectrum, one or more yellow or orange-yellow cyano benzoxazolyl or cyano benzothiazolyl arylidene type methine filter or density correction dyes of structure I, below, codispersed with one or more hydroquinone, catechol or sulfonamidophenol reducing agents, ##STR1## wherein: R.sub.1 is hydrogen or an alkyl group;R.sub.2 is an alkyl group or an aryl group;R.sub.3 is hydrogen, a halogen, an alkyl group, an alkoxy group or an aryloxy group;R.sub.4 is hydrogen or an alkyl group;R.sub.5 is hydrogen or an alkyl group;R.sub.6 is hydrogen or an alkyl group;X is oxygen or sulfur;each R.sub.
    Type: Grant
    Filed: January 5, 1996
    Date of Patent: September 1, 1998
    Assignee: Eastman Kodak Company
    Inventors: Paul Leo Zengerle, Paul Barrett Merkel
  • Patent number: 5795708
    Abstract: A heat processable film comprising:a base layer;a dichroic mirror layer; anda heat processable emulsion layer which is exposed by radiation having a predetermined range of wavelengths; wherein the dichroic mirror layer reflects radiation at least having the predetermined range of wavelengths to the emulsion layer and transmits radiation having wavelengths outside the predetermined range of wavelengths.
    Type: Grant
    Filed: August 16, 1996
    Date of Patent: August 18, 1998
    Assignee: Eastman Kodak Company
    Inventor: John Claude Boutet
  • Patent number: 5786134
    Abstract: This invention relates to a motion picture print film having a support and having, in order, on one side thereof an antihalation undercoat and at least one silver halide emulsion layer and having, in order, on the opposite side thereof an antistatic layer, a protective overcoat; characterized in that said protective overcoat includes a polyurethane binder and the polyurethane binder has a tensile elongation to break of at least 50% and a Young's modulus measured at a 2% elongation of at least 50000 lb/in, and a topcoat farthest from the support which includes a hydrophilic binder at a weight percent of at least 20.
    Type: Grant
    Filed: May 15, 1997
    Date of Patent: July 28, 1998
    Assignee: Eastman Kodak Company
    Inventors: Mridula Nair, Kenneth L. Tingler, Gustav R. Apai, II, Frank A. Pettrone
  • Patent number: 5783380
    Abstract: A thermally processable imaging element is comprised of:(1) a support;(2) a thermographic or photothermographic imaging layer on one side of the support;(3) a transparent protective layer comprising:(A) a film forming binder;(B) a dye in said protective layer in an amount sufficient to impart a pre-selected color thereto; and(C) matte particles, the color of which substantially matches the color of the protective layer.
    Type: Grant
    Filed: September 24, 1996
    Date of Patent: July 21, 1998
    Assignee: Eastman Kodak Company
    Inventors: Dennis Edward Smith, Sharon Marilyn Melpolder, John Leonard Muehlbauer
  • Patent number: 5776667
    Abstract: A color photographic recording material comprises in a yellow filter layer at least one dye of one of the formulae I and II ##STR1## in which R.sup.1, R.sup.3 and R.sup.5 (mutually independently) mean alkyl, cycloalkyl or aryl;R.sup.2 and R.sup.4 (mutually independently) mean hydrogen or alkyl;R.sup.21 means a residue as R.sup.1 ;R.sup.22 means a residue as R.sup.2 ;R.sup.23 means a residue as R.sup.1 ;provided that in formula I none of the residues R.sup.1 to R.sup.5 contains an alkyl chain of more than 3 carbon atoms.The dyes exhibit suitable absorption as yellow filter dyes and are completely decolored during processing.
    Type: Grant
    Filed: January 7, 1997
    Date of Patent: July 7, 1998
    Assignee: AGFA AG
    Inventors: Hans Ohlschlager, Hans Langen, Klaus Sinzger
  • Patent number: 5766820
    Abstract: A silver halide photographic light sensitive material is disclosed which comprises a support and provided thereon, a hydrophilic colloid layer comprising at least one silver halide emulsion layer and at least one non-light sensitive layer, the hydrophilic colloid layer being hardened with at least one hardener selected from the group consisting of a carboxyl active hardener, a vinylsulfone type hardener, an epoxy type hardener and a triazine type hardener, wherein a silver halide emulsion layer closest to the support of the silver halide emulsion layers contains a dye in the form of dispersed solid particles or a non-light sensitive layer closest to the support of the non-light sensitive hydrophilic colloid layers contains a dye in the form of dispersed solid particles, and the thickness swell percentage of the photographic component layer is 10 to 100%.
    Type: Grant
    Filed: December 12, 1996
    Date of Patent: June 16, 1998
    Assignee: Konica Corporation
    Inventors: Junichi Fukawa, Seiji Hidaka, Takeo Arai
  • Patent number: 5766828
    Abstract: An infrared laser addressable imaging element comprising a substrate bearing a first layer comprising a reducible light-insensitive silver salt and a binder; and a second layer comprising an infrared absorber, a reducing agent for said silver salt and a binder; wherein said binder of said first layer is a polymeric medium having a glass transition temperature of at least 80.degree. C.
    Type: Grant
    Filed: September 9, 1996
    Date of Patent: June 16, 1998
    Assignee: Imation Corp.
    Inventors: Ranjana C. Patel, Jonathan C. Vogel
  • Patent number: 5766834
    Abstract: This invention relates to a photographic element containing a polymeric ultraviolet absorbing polymer fromed from an ultraviolet absorbing monomer of formula (I): ##STR1## where X is a bivalent linking group, and Y contains an ethylenically unsaturated functional group.
    Type: Grant
    Filed: September 11, 1996
    Date of Patent: June 16, 1998
    Assignee: Eastman Kodak Company
    Inventors: Tienteh T Chen, Lal C Vishwakarma, Hwei-Ling Yau
  • Patent number: 5759754
    Abstract: A radiation-sensitive medical diagnostic film for soft tissue imaging, particularly mammography, is disclosed. The film allows more rapid processing than films currently available for mammographic imaging and maintains acceptably high levels of image sharpness and low levels of mottle. The radiographic film records medical diagnostic images of soft tissue through (a) exposure by a single intensifying screen located to receive an image bearing source of X-radiation and (b) processing, including development, fixing and drying, in 90 seconds or less comprised of a film support transparent to radiation emitted by the intensifying screen and having opposed front and back major faces and an image-forming portion for providing, when imagewise exposed by the intensifying screen and processed, an average contrast in the range of from 2.5 to 3.5, measured over a density above fog of from 0.25 to 2.5.
    Type: Grant
    Filed: July 31, 1996
    Date of Patent: June 2, 1998
    Assignee: Eastman Kodak Company
    Inventor: Robert Edward Dickerson
  • Patent number: 5756257
    Abstract: The present invention provides a photosensitive color proofing article incorporating an antihalation effective amount of one or more antihalation dyes of the general formula (I) shown below: ##STR1## wherein: Z is an oxygen atom, NH, or NR; R is an alkyl group of 1 to 12 carbon atoms or a hydrogen atom; R.sup.1 represents a perfluoroalkylsulfonyl group of 1 to 12 carbon atoms or an arylsulfonyl group; and R.sup.2 represents a perfluoroalkylsulfonyl group of from 1 to 12 carbon atoms; an arylsulfonyl group; or a cyano group. The antihalation dyes of formula (I) absorb radiation within the wavelength range of from about 325 to 700 nm and preferably, from about 325 to 450 nm.
    Type: Grant
    Filed: February 14, 1996
    Date of Patent: May 26, 1998
    Assignee: Imation Corp.
    Inventors: Kevin D. Landgrebe, Alice S. Mendelsohn
  • Patent number: 5753390
    Abstract: A method is described for preparing a concentrated dispersion of a photographically useful compound ready-for-use in coating solutions of hydrophilic colloid layers of a silver halide photographic material, wherein said compound has at least one ionisable acid site on its molecule, the said method comprising the steps of deprotonising and solubilising the said compound in alkaline medium; microprecipitating the said compound and milling the microprecipitated compound obtained, coating the said dispersion of a photographically useful compound in non-light-sensitive and/or light-sensitive hydrophilic layers of a silver halide photographic material, wherein milling proceeds during and/or after the microprecipitating step.
    Type: Grant
    Filed: July 17, 1996
    Date of Patent: May 19, 1998
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Pierre De Roo, Jan Gilleir
  • Patent number: 5750323
    Abstract: Solid particle dispersions of compounds useful in imaging elements can be made with substantially improved stability to particle growth by dispersing the compound of interest in the presence of a relatively small amount of a second compound that is structurally similar to the compound of interest. This second compound is combined with the compound of interest prior to dispersing the compound of interest, i.e., prior to milling in the case of milled dispersions, and prior to precipitation in the case of pH or solvent precipitated dispersions. While being distinct, the second compound has a similar chemical structure to the main compound.
    Type: Grant
    Filed: August 15, 1996
    Date of Patent: May 12, 1998
    Assignee: Eastman Kodak Company
    Inventors: Raymond Peter Scaringe, David Darrell Miller, Mary Christine Brick, Leslie Shuttleworth, Margaret Jones Helber, Steven Evans
  • Patent number: 5747237
    Abstract: A silver halide photographic material comprising a support having at least one pre-fogged direct positive emulsion layer provided on at least one side of the support, wherein silver halide grain formation of the emulsion is carried out in the presence of a silver halide solvent, the emulsion contains at least one of an Rh salt, an Ru salt or a polybromoiridium salt, and at least one compound selected from the group consisting of compounds represented by the following formula (I), (II) and (III) is added to the emulsion while the silver halide photographic material is prepared:R--SO.sub.2 S--M (I)R--SO.sub.2 S--R.sup.1 (II)R--SO.sub.2 S--L.sub.m --SSO.sub.2 --R.sup.2 (III)wherein R, R.sup.1 and R.sup.2 are the same or different, and each represents an aliphatic group, an aromatic group or a heterocyclic group; M represents a cation; L represents a divalent linking group; and m represents 0 or 1.
    Type: Grant
    Filed: May 15, 1996
    Date of Patent: May 5, 1998
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shinichiro Fukui, Koichi Kuno
  • Patent number: RE36174
    Abstract: Disclosed is a photographic element comprising an antihalation dye of formula: ##STR1## whereinX.sup.1 .?.,.!. .Iadd.and .Iaddend.X.sup.2 independently represent.?.s.!. --CR.sup.8 R.sup.9 --, --S--, --Se--, --NR.sup.10 --, --CH.dbd.CH-- or --O--;n is an integer of 2 or 3;R.sup.1 and R.sup.2 independently represent alkyl of 1 to 10 carbons or substituted alkyl of 1 to 10 carbons;R.sup.3 represents .?.a ring chosen from the set consisting of aryl, substituted aryl, and.!. a heterocyclic ring;R.sup.4, R.sup.5, R.sup.6 and R.sup.7 independently represent hydrogen, alkyl of 1-10 carbons, substituted alkyl of 1-10 carbons.?.,.!..Iadd.; or .Iaddend.R.sup.4 and R.sup.5 taken together or R.sup.6 and R.sup.7 taken together .?.may.!. represent the atoms necessary to form a 5 or 6-membered aliphatic ring, an aromatic six-membered ring, an aromatic 10-membered ring, a substituted aromatic .?.six-member.!. .Iadd.six-membered .Iaddend.ring or a substituted aromatic .?.10-member.!. .Iadd.10-membered .Iaddend.ring;R.sup.8 .?.
    Type: Grant
    Filed: May 1, 1997
    Date of Patent: March 30, 1999
    Assignee: Sterling Diagnostic Imaging, Inc.
    Inventors: Dietrich M. Fabricius, Thomas Schelhorn