Organic Dye Or Pigment Containing Patents (Class 430/517)
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Patent number: 4900653Abstract: Dyes according to the formula: ##STR1## are useful as filter dyes in photographic elements. In this formula, n is 1 or 2. R.sub.1 and R.sub.2 are each independently substituted or unsubstituted alkyl or substituted or unbsubstituted aryl, or together represent the atoms necessary to complete a substituted or unsubstituted 5- or 6-membered ring. Also, if R.sub.7 is substituted or unsubstituted alkyl, R.sub.1 is H.R.sub.3 is substituted or unsubstituted alkyl or aryl. R.sub.4 and R.sub.5 each independently represents H, substituted or unsubstituted alkyl, substituted or unsubstituted aryl, secondary or tertiary amino, CO.sub.2 H, or NHSO.sub.2 R.sub.6, with the proviso that at least one of R.sub.4, R.sub.5, or a substituent on an aryl ring in R.sub.3, on an aryl ring in R.sub.4 or R.sub.5, on an aryl ring in R.sub.1 or R.sub.2, or on an aryl ring formed by R.sub.1 and R.sub.2 is CO.sub.2 H or NHSO.sub.2 R.sub.6. R.sub.6 is substituted or unsubstituted alkyl or substituted or unsubstituted aryl. R.sub.Type: GrantFiled: December 23, 1988Date of Patent: February 13, 1990Assignee: Eastman Kodak CompanyInventors: Ronda E. Factor, Donald R. Diehl
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Patent number: 4898809Abstract: A silver halide photographic light-sensitive material is disclosed, which has high sensitivity and can be handled under bright safelight. The photographic material comprises a support bearing thereon photographic component layers including at least one silver halide emulsion layer containing a silver halide emulsion sensitized so as to have a maximum spectral sensitivity on the side of a wavelength shorter than at least 600 nm and at least one non-light-sensitive hydrophilic colloid layer arranged to the side of the silver halide emulsion layer opposite to the support. And at least one of the hydrophilic colloid layers contains a water-soluble dye having a maximum light-absorption within the wavelength region of not less than 700 nm.Type: GrantFiled: August 3, 1988Date of Patent: February 6, 1990Assignee: Konica CorporationInventor: Takeshi Sampei
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Patent number: 4895786Abstract: In a processing method for silver halide color photosensitive material in which silver halide color photosensitive material is treated to produce a color dye image with a processing solution that has a fixing ability, and subsequently is not washed but treated with a washless stabilizing solution, the improvement comprising treating said silver halide color photosensitive material with a washless stabilizing solution that contains a triazinylstilbene optical brightening agent in the presence of an amount sufficient to stabilize the dye image and reduce staining of the photosensitive material of at least one compound represented by General Formula (I), (II), (II') or (II"): ##STR1##Type: GrantFiled: May 11, 1989Date of Patent: January 23, 1990Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Masayuki Kurematsu, Shigeharu Koboshi
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Patent number: 4894313Abstract: Photosensitive recording elements which possess a photosensitive recording layer which is applied to a dimensionally stable base, if necessary via one or more intermediate layers, and have good photochemical properties and a long shelf life contain a compound of the general formula (I) ##STR1## where M is a hydrogen atom or proton, an alkali metal cation, the ammonium cation or an amine cation and R.sup.1 and R.sup.2 are identical or different and are each a substituted s-triazine ring, in the photosensitive recording layer and/or any intermediate layer present, in order to control the photochemical properties.Type: GrantFiled: May 12, 1987Date of Patent: January 16, 1990Assignee: BASF AktiengesellschaftInventors: Peter Neumann, Guenter Wallbillich
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Patent number: 4892808Abstract: A silver halide emulsion contained in a photographic element is protected against hydrogen cyanide gas, which may evolve from carbon black contained in a non-light sensitive material associated with the photographic element, by a scavenger for hydrogen cyanide gas in a location where it will intercept the hydrogen cyanide gas.Type: GrantFiled: May 12, 1989Date of Patent: January 9, 1990Assignee: Eastman Kodak CompanyInventors: Kenneth G. Harbison, Wilbur S. Gaugh
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Patent number: 4885224Abstract: A light-sensitive material comprising a light-sensitive layer which contains silver halide, a reducing agent, a polymerizable compound and a color image forming substance provided on a support (the silver halide, polymerizable compound and color image forming substance are contained in microcapsules which are dispersed in the light-sensitive layer), characterized in that the microcapsules further contain a dye having a property of being decolorized when it is heated or irradiated with light.Type: GrantFiled: October 14, 1987Date of Patent: December 5, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Soichiro Yamamoto, Ken Kawata
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Patent number: 4880730Abstract: A silver halide photographic light-sensitive material comprising a support having thereon at least one colored layer, and the layer can be decolored or lightened upon photographic processing of the photographic light-sensitive material,wherein the colored layer is formed by a process comprising the step of:color developing at least one colorless or light-colored leuco-dyestuff utilizing at least one metal salt of an organic acid.Type: GrantFiled: December 6, 1988Date of Patent: November 14, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Kozo Sato, Yoshisada Nakamura
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Patent number: 4877720Abstract: A silver halide photographic material comprising a support having thereon at least one silver halide emulsion layer, at least one layer of the silver halide photographic material comprising at least one compound represented by formula (I):PWR--Time--.sub.t --POL (I)wherein PWR represents a group capable of releasing (Time--.sub.t POL upon reduction; Time represents a divalent organic group capable of releasing POL via a subsequent reaction after (Time--.sub.t POL is released from PWR; t is 0 or 1; and POL represents a polymer group.The compound represented by formula (I) is a useful functional polymer whose properties are drastically changed upon reduction and reveal photographically useful function.Type: GrantFiled: April 29, 1988Date of Patent: October 31, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Kozo Sato, Shigeru Ohno, Sumito Yamada
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Patent number: 4877721Abstract: A methine oxonol dye having a bis-(2-pyrazolin-5-one nucleus) substituted with(a) acyl groups in the 3 and 3' position;(b) aryl groups in the 1 and 1' position; and(c) bearing from 4 to 6 acidic substituents, each of which are capable of forming a monovalent anion provided that at least two of such substituents are other than carboxyl, is disclosed for use as filter dyes in photographic elements.Type: GrantFiled: August 23, 1988Date of Patent: October 31, 1989Assignee: Eastman Kodak CompanyInventors: Donald R. Diehl, Ralph C. Reed
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Patent number: 4876181Abstract: A dye useful for absorbing infrared radiation in photographic elements, having the structure: ##STR1## is disclosed. In this formula R.sub.1 and R.sub.2 each independently represents sulfoalkyl, carboxyalkyl, or sulfatoalkyl of from 3 to 6 carbon atoms, having at least 3 carbon atoms in the alkyl chain between the nitrogen atom of each Z ring and the sulfo or sulfato group, and at least 2 carbon atoms in the alkyl chain between the nitrogen atom of each Z ring and the carboxy group.R.sub.3 and R.sub.5 are each hydrogen or together represent the atoms necessary to complete 5- or 6-membered carbocyclic ring, and R.sub.4 represents hydrogen, alkyl of 1 to 4 carbon atoms, aryl, cyano, halogen, or ##STR2## where R.sub.6 and R.sub.7 each independently represents alkyl of from 1 to 6 carbon atoms or aryl, or together represent the non-metallic atoms necessary to form a 5- or 6-membered ring.X.sym. represents a cation.Z.sub.1 and Z.sub.Type: GrantFiled: March 10, 1988Date of Patent: October 24, 1989Assignee: Eastman Kodak CompanyInventors: Gary S. Proehl, Anthony D. Gingello, David J. Collett, Richard L. Parton, David A. Stegman, Anthony Adin
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Patent number: 4871656Abstract: A dye useful for absorbing infrared radiation in photographic elements, having the structure: ##STR1## is disclosed. In this formula, R.sub.1 and R.sub.2 each independently represents sulfoalkyl, carboxyalkyl, or sulfatoalkyl, from 2 to 4 carbon atoms, having 2 carbon atoms in the alkyl chain linking the nitrogen atom of each Z ring and the sulfo or sulfato group, and 1 carbon atom in the alkyl chain linking the nitrogen atom of each Z ring and the carboxy group.R.sub.3 and R.sub.5 are each hydrogen or together represent the atoms necessary to complete a 5- or 6-membered carbocyclic ring, and R.sub.4 represents hydrogen, alkyl of 1 to 4 carbon atoms, halogen, cyano, or ##STR2## where R.sub.6 and R.sub.7 each independently represents alkyl of from 1 to 6 carbon atoms or aryl or together represent the non-metallic atoms necessary to form a 5- or 6-membered heterocyclic ring.X.sup..sym. represents a cation.Z.sub.1 and Z.sub.Type: GrantFiled: March 10, 1988Date of Patent: October 3, 1989Assignee: Eastman Kodak CompanyInventors: Richard L. Parton, ANthony D. Gingello, David J. Collett, David A. Stegman, ANthony Adin
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Patent number: 4868087Abstract: A light-sensitive material comprising a light-sensitive layer containing silver halide, a reducing agent and a polymerizable compound provided on a support (the polymerizable compound is contained in microcapsules which are dispersed in the light-sensitive layer), characterized in that the light-sensitive layer further contains a white pigment which is arranged outside of the microcapsules.Type: GrantFiled: July 23, 1987Date of Patent: September 19, 1989Assignee: Fuji Photo Film Co., Ltd.Inventor: Soichiro Yamamoto
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Patent number: 4861700Abstract: Photographic elements comprising filter dyes of the formula: ##STR1## wherein A is a pyrrole or indole nucleus, with the tricyanovinyl radical occupying the 2 or 3 position of the nucleus.Type: GrantFiled: November 19, 1987Date of Patent: August 29, 1989Assignee: Eastman Kodak CompanyInventors: Leslie Shuttleworth, Paul B. Merkel
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Patent number: 4859539Abstract: An improved photographic support, especially useful for color prints, is comprised of a paper base material having thereon a polyolefin coating containing a white pigment and a mixture of optical brighteners, such mixture comprising certain fluorescent bis(benzoxazolyl)stilbenes. The support exhibits improved brightness at low brightener concentration and unexpected resistance to brightener exudation.Type: GrantFiled: September 19, 1988Date of Patent: August 22, 1989Assignee: Eastman Kodak CompanyInventors: Donna L. Tomko, Kenneth G. Harbison
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Patent number: 4857446Abstract: Dyes having structure ##STR1## A represents a substituted or unsubstituted nucleus having a carboxyphenyl or sulfonamidophenyl substituent selected from the group consisting of 2-pryazolin-5-ones free of any substituent bonded thereto through a carboxyl group, rhodanines, hydantoins, 2-thiohydantoins, 4-thiohydantoins, 2,4-oxazolidindiones, 2-thio-2,4-oxazolidindiones, isoxazolinones, barbiturics, 2-thiobarbiturics, and indandiones,R represent hydrogen, substituted or unsubstituted alkyl of 1 to 4 carbon atoms, or benzyl,R.sup.1 and R.sup.2 each independently represents substituted or unsubstituted alkyl or aryl, or taken together with R.sup.5, R.sup.6, N and the carbon atoms to which they are attached, represent the atoms needed to complete a julolydyl ring,R.sup.3 represents H, or substituted or unsubstituted alkyl or aryl,R.sup.5 and R.sup.6 each independently represents H, or R.sup.5 taken together with R.sup.1, or R.sup.6 taken together with R.sup.Type: GrantFiled: December 23, 1987Date of Patent: August 15, 1989Assignee: Eastman Kodak CompanyInventors: Donald R. Diehl, Ronda E. Factor
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Patent number: 4855221Abstract: Photographic elements having oxonol dyes of the formula: ##STR1## R.sup.1 and R.sup.2 each independently represent alkyl of from 1 to 5 carbon atoms are disclosed. The dyes are particularly useful as filter dyes in the form of solid particle microcrystalline dispersions.Type: GrantFiled: July 13, 1987Date of Patent: August 8, 1989Assignee: Eastman Kodak CompanyInventors: Ronda E. Factor, Donald R. Diehl
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Patent number: 4851328Abstract: A peel-apart monochromatic instant film unit including two separate diffusion transfer sheets, namely, a negative or photosensitive in which a latent image is created as a result of exposure and a positive or image-receiving sheet where the positive image is formed. The photosensitive sheet has a carbon containing paper base support which is provided on its one side with a white paper layer, a titanium dioxide containing polyethylene layer and a photosensitive emulsion layer, in that order, and on the opposite side is optionally provided with a transparent polyethylene layer and a backing layer.Type: GrantFiled: April 11, 1988Date of Patent: July 25, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroyuki Kurabayashi, Minoru Ono
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Patent number: 4849326Abstract: UV-sensitive direct positive silver halide photographic elements for duplicating processes which can be safely handled under white light, said elements comprising a support base, a hydrophilic colloidal silver halide emulsion layer comprising fogged silver halide grains, and one or more hydrophilic colloidal layers, wherein said silver halide emulsion is reactively associated with a water-removable UV-absorbing compound having at least 80% of the absorption in the range from 350 to 400 .mu.m.Type: GrantFiled: July 8, 1988Date of Patent: July 18, 1989Assignee: Minnesota Mining and Manufacturing CompanyInventors: Mauro Besio, Alberto Vacca, Angelo Vallarino
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Patent number: 4818659Abstract: A silver halide photographic material for use in a bright room is disclosed comprising a support having thereon at least two silver halide emulsion layers, each of the emulsion layers having a different sensitivity and comprising silver chloride grains or silver chlorobromide grains having at least about 80 mol % silver chloride, each of the silver halide emulsions layers containing from about 1.times.10.sup.-7 mol to about 1.times.10.sup.-4 mol of a rhodium salt per mol of silver, wherein the sensitivity of the lower emulsion layer (the emulsion layer coated nearer to the support) is higher than the sensitivity of the upper emulsion layer (the emulsion layer coated farther from the support) and at least one of the silver halide emulsion layers or different hydrophilic colloid layers contains a hydrazine derivative and at least one of the silver halide emulsion layers of different hydrophilic colloid layers contains a dry compound having a .sup..lambda. max of from about 400 nm to about 550 nm.Type: GrantFiled: April 7, 1987Date of Patent: April 4, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Toshiro Takahashi, Ken-ichi Kuwabara, Kimitaka Kameoka, Masahiro Okada
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Patent number: 4801525Abstract: A silver halide light-sensitive material is disclosed, comprising a support having provided thereon a silver halide emulsion layer that has been infrared-sensitized so as to have a sensitivity maximum at a wavelength longer than 750 nm and at least one light-insensitive hydrophilic colloidal layer on said silver halide emulsion layer, wherein said light-insensitive hydrophilic colloidal layer contains at least one dye having an absorption maximum at a wavelength shorter than 750 nm. The material has high sensitivity to infrared light, but can be handled under bright safelight.Type: GrantFiled: July 31, 1987Date of Patent: January 31, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Yuji Mihara, Kunio Ishigaki
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Patent number: 4794071Abstract: An improved photographic support, especially useful for color prints, is comprised of a paper base material having thereon a polyolefin coating containing a white pigment and a mixture of optical brighteners, such mixture comprising certain fluorescent bis(benzoxazolyl)stilbenes. The support exhibits improved brightness at low brightener concentration and unexpected resistance to brightener exudation.Type: GrantFiled: March 23, 1987Date of Patent: December 27, 1988Assignee: Eastman Kodak CompanyInventors: Donna L. Tomko, Kenneth Harbison
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Patent number: 4770984Abstract: Color photographic motion picture projection film element comprising a transparent film support and coated thereon in succession, a blue-sensitive silver halide emulsion layer comprising a yellow-forming coupler, a red-sensitized silver halide emulsion layer comprising a cyan-forming coupler, an intermediate layer, a green-sensitized silver halide emulsion layer comprising a magenta-forming coupler, and an antistress layer, wherein between said support and said blue-sensitive silver halide emulsion layer a yellow antihalation undercoat is provided, which comprises at least one yellow non-diffusing dye that absorbs blue light and is removable and/or decolorizable in a processing bath and between said blue-sensitive silver halide emulsion layer and said red-sensitized silver halide emulsion layer a bluish antihalation intermediate layer is provided, which comprises at least one blue non-diffusing dye that absorbs red light and is removable and/or decolorizable in a processing bath.Type: GrantFiled: July 8, 1987Date of Patent: September 13, 1988Assignee: Agfa-Gevaert, N.V.Inventors: Marc W. Ailliet, Felix J. Moelants, Ronnie G. Mampaey
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Patent number: 4764455Abstract: A color image-forming process is described, for a silver halide color photographic material comprising a support having provided thereon at least one red-sensitive silver halide emulsion layer, at least one green-sensitive silver halide emulsion layer, and at least one blue-sensitive silver halide emulsion layer, which process comprises incorporating in the photographic material a yellow dye represented by formula (I) and processing the photographic material using a bleach-fixing solution containing a ferric complex of aminopolycarboxylic acid and a thiosulfate ##STR1## wherein R.sub.1 and R.sub.2 each represents a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, a hydroxy group, a carboxy group, a substituted amino group, a carbamoyl group, a sulfamoyl group, a nitro group or an alkoxycarbonyl group;R.sub.3 and R.sub.Type: GrantFiled: August 6, 1986Date of Patent: August 16, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Jun Arakawa, Masahiro Okada, Takatoshi Ishikawa
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Patent number: 4711838Abstract: Photographic elements which may be imaged by laser scanners emitting in the near infrared without the formation of interference fringes comprising a support bearing one or more layers of a silver halide emulsion having grains of an average diameter of no more than 0.4 micron, the element including one or more of:(i) a topcoat layer which is an outermost layer on the same side of the support as the photosensitive emulsion which topcoat layer is a diffuse transmitting layer with respect to near infrared radiation,(ii) a backing layer which is an outermost layer on the side of the support remote from the photosensitive emulsion which backing layer is a diffuse reflecting layer or absorbing layer with respect to near infrared radiation,(iii) a subbing layer which is positioned between the support and the photosensitive emulsion which subbing layer is a diffuse transmitting or absorbing layer with respect to near infrared radiation.Type: GrantFiled: August 26, 1985Date of Patent: December 8, 1987Assignee: Minnesota Mining and Manufacturing CompanyInventors: Nicholas E. Grzeskowiak, James B. Philip, Jr.
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Patent number: 4702996Abstract: The image of an object with opaque and transparent regions having a contrast lens than the contrast threshold of a layer of photoresist when light of a predetermined wavelength to which the photoresist is sensitive is passed through the object and onto the layer of photoresist is enhanced in contrast by the provision of a contrast enhancing layer contiguous to the surface of the photoresist to a value above the contrast threshold of the photoresist. The contrast enhancing layer is constituted of an aryl nitrone compound mixed with a suitable binder.Type: GrantFiled: May 17, 1985Date of Patent: October 27, 1987Assignee: General Electric CompanyInventors: Bruce F. Griffing, Paul R. West
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Patent number: 4684608Abstract: A latex composition having utility in articles such as photographic elements is disclosed. The composition comprises loadable polymer particles having recurring units a, b and c wherein:component a is 10 to 100 weight percent of a tetrahydrofurfuryl monomer having the structure: ##STR1## in which R.sub.1 represents O or NH; andR.sub.2 represents H or lower alkyl of about 1 to 6 carbon atoms;component b is 0 to 20 weight percent of a hydrophilic monomer andcomponent c is 0 to 90 weight percent of a hydrophobic monomer.Type: GrantFiled: November 21, 1985Date of Patent: August 4, 1987Assignee: Eastman Kodak CompanyInventors: James W. Brown, Tsang J. Chen, Michael A. Schen
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Patent number: 4678741Abstract: A silver halide photographic material having on a support at least one hydrophilic colloid layer and at least one silver halide emulsion layer containing tabular silver halide grains having a grain diameter of at least 5 times the thickness of the grains and at least one compound represented by general formula (I) ##STR1## wherein R.sup.1 represents a methyl group and R.sup.2 represents an alkyl group, a substituted alkyl group, an aryl group, or a substituted aryl group.Type: GrantFiled: April 14, 1986Date of Patent: July 7, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Sumito Yamada, Masaki Okazaki
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Patent number: 4677049Abstract: Spin castable mixtures having aryl nitrones are provided which are useful in making photobleachable layers for use in contrast enhanced photolithography.Type: GrantFiled: November 28, 1984Date of Patent: June 30, 1987Assignee: General Electric CompanyInventors: Bruce F. Griffing, Paul R. West
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Patent number: 4618565Abstract: Multilayer photoresist recording media containing an absorptive layer are improved by forming the absorptive layer from a composition comprising PMMA or a copolymer of methylmethacrylate and methacrylic acid, certain dyes such as hydroxyazobenzoic acid or Sudan Orange G and a suitable solvent. The dyes are insoluble in the solvent of an overlying photoresist layer. The media are substantially free of loss of resolution due to dissolution of the dye into the photoresist layer.Type: GrantFiled: June 5, 1985Date of Patent: October 21, 1986Assignee: RCA CorporationInventors: Lawrence K. White, Nancy A. Miszkowski, Aaron W. Levine
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Patent number: 4615966Abstract: This invention relates to diffusion transfer photographic processes adapted to be performed in the presence of ambient light and to diffusion transfer products useful in such processes wherein enhanced opacification particularly, in the green region of the visible spectrum is achieved by employing a 7-sulfonamido/5- or 6-sulfamoyl indole phthalein as the light-absorbing, pH-sensitive optical filter agent for the shorter wavelength region of the visible spectrum.Type: GrantFiled: January 21, 1986Date of Patent: October 7, 1986Assignee: Polaroid CorporationInventors: Alan L. Borror, Efthimios Chinoporos, Cheryl P. Petersen
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Patent number: 4614708Abstract: Method for the preparation of stable aqueous dispersions of finely divided solid spherical polymer beads having an average particle size between about 0.5 and about 5 .mu.m and having a glass transition temperature of at least 40.degree. C. by dissolving in an aqueous solvent mixture at least one .alpha.,.beta.-ethylenically unsaturated monomer capable of forming a polymer that is soluble in the monomer(s) present in said aqueous solvent mixture but which is insoluble in said aqueous solvent mixture, a free radical-forming polymerization initiator, and a graft-polymerizable polymer containing hydrophilic groups, heating the solution to a temperature from 50.degree. C. to the reflux temperature thereof with stirring so as to form said polymer beads. The polymer beads can be used in an antifriction surface layer, an antihalation surface layer, an antistatic surface layer, or in a protective surface layer of a photographic element or in a top layer of a drafting film containing a photosensitive layer.Type: GrantFiled: February 16, 1984Date of Patent: September 30, 1986Assignee: AGFA-Gevaert, N.V.Inventors: Daniel M. Timmerman, Jan J. Priem, Jan H. Janssens
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Patent number: 4594312Abstract: Photothermographic elements containing heat bleachable acutance/antihalation dyes and thermographic elements employing heat bleachable dyes of the formula: ##STR1## in which: n is 2, 3, 4 or 5,at least one of R.sup.1 to R.sup.4 represent hydrogen and the remainder of R.sup.1 to R.sup.4 independently represent a hydrogen atom, an optionally substituted cycloalkyl group, an optionally substituted alkenyl group, an optionally substituted alkyl group, an optionally substituted aryl group, an optionally substituted heterocyclic aromatic group, or R.sup.1 and R.sup.2 together or R.sup.3 and R.sup.4 together represent the necessary atoms selected from C, N, O and S to complete a non-aromatic type ring,X.sup..crclbar. is an anion.Type: GrantFiled: March 6, 1984Date of Patent: June 10, 1986Assignee: Minnesota Mining and Manufacturing CompanyInventors: Gebran J. Sabongi, Stephen S. C. Poon, Bernard A. Lea
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Patent number: 4588673Abstract: A retouchable mat film comprising a hydrophobic support which has formed thereon a mat layer containing silicon dioxide as a matting agent is disclosed. The mat layer further includes a mixture of poly(methyl methacrylate) or a copolymer containing at least 80 wt % of methyl methacrylate and a hydrophilic polymer as a binder. This mat film withstands several retouching operations in ink.Type: GrantFiled: February 22, 1985Date of Patent: May 13, 1986Assignee: Fuji Photo Film Co., Ltd.Inventors: Shinzi Kataoka, Yukio Shinagawa, Shinji Sakaguchi
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Patent number: 4587195Abstract: A method of processing a silver halide photographic material using a color developer containing at least two kinds of triazylstilbene brightening agents having maximum fluorescent wavelengths at least 4.mu. apart, said material containing a sensitizing dye and an antiirradiation dye.Type: GrantFiled: April 10, 1985Date of Patent: May 6, 1986Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Masao Ishikawa, Shigeharu Koboshi, Masayuki Kurematsu
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Patent number: 4581323Abstract: A photothermographic element comprising a reflective base having coated thereon one or more layers constituting a photothermographic imaging medium in which a bleachable antihalation medium is coated over said photothermographic imaging medium, the components of the antihalation medium being in non-reactive association with components in the photothermographic imaging medium. The topcoat antihalation layer allows a wide latitude in the selection of dye bleach systems and binders and surprisingly is at least as effective as the use of antihalation underlayers.Type: GrantFiled: March 12, 1984Date of Patent: April 8, 1986Assignee: Minnesota Mining and Manufacturing CompanyInventors: Michael G. Fisher, Gebran J. Sabongi, Stephen S. C. Poon
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Patent number: 4576905Abstract: Compounds containing an aromatic ring portion fused with a tellurazolium or derivative tellurazole, tellurazoline (including tellurazolinylidene), or tellurazolinium ring portion are disclosed together with processes and intermediates for their preparation. With properly selected pendant groups these tellurazolium and derivative compounds can be usefully employed as dyes, antifoggants or stabilizers, nucleating agents, latent image keeping addenda, or speed or contrast altering addenda in silver halide photographic systems.Type: GrantFiled: October 12, 1984Date of Patent: March 18, 1986Assignee: Eastman Kodak CompanyInventors: Wolfgang H. H. Gunther, Ronald E. Leone, Rosemary Przyklek
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Patent number: 4563406Abstract: There is disclosed a light-sensitive silver halide photographic material having a white pigment containing layer and at least one silver halide emulsion layer provided successively on a support, being characterized in that there is provided a colorant containing layer capable of being made substantially colorless by a photographic treatment between said support and said white pigment containing layer. The present invention provides a light-sensitive silver halide photographic material having a reflective support improved to a great extent in sharpness substantially without bringing about lowering in sensitivity.Type: GrantFiled: July 12, 1984Date of Patent: January 7, 1986Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Keiji Ohbayashi, Kaoru Onodera
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Patent number: 4548896Abstract: An imagewise bleachable composition is described comprising a dye in reactive association with a mesoionic compound. The composition may be bleached by radiation at wavelengths between 200 and 1000 nm.Type: GrantFiled: March 6, 1984Date of Patent: October 22, 1985Assignee: Minnesota Mining and Manufacturing CompanyInventors: Gebran J. Sabongi, Stephen S. C. Poon
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Patent number: 4546062Abstract: Polymeric optical filter agents and products and processes using same are disclosed. The polymeric optical filter agents are pH-sensitive materials comprising a polymeric backbone having a plurality of pendant moieties of the formula (I). ##STR1## wherein X is ##STR2## and R is alkyl, aryl, alkaryl or aralkyl; A is hydrogen, alkyl or the radical ##STR3## where each of Y.sup.1, Y.sup.2 and Y.sup.3 is hydrogen or an electron-withdrawing group; and each Z.sup.1, Z.sup.2 and Z.sup.3 is hydrogen or an electron-withdrawing group; with the proviso that, when each of Z.sup.1, Z.sup.2 and Z.sup.3 is hydrogen, said A is a radical ##STR4## wherein at least one of said Y.sup.1, Y.sup.2 and Y.sup.3 groups comprises an electron-withdrawing group. These agents upon contact with alkali are converted from a substantially non-light absorbing form to a highly colored light-absorbing form useful in photographic products.Type: GrantFiled: July 30, 1984Date of Patent: October 8, 1985Assignee: Polaroid CorporationInventors: Irena Y. Bronstein-Bonte, Edward P. Lindholm
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Patent number: 4506002Abstract: A diffusion transfer photographic element composed of a photosensitive sheet, a cover sheet, and a processing composition contained in a rupturable container in such a manner that the processing composition is spread between both sheets after exposing the photosensitive sheet is disclosed. The whiteness of highlights of images obtained is improved by incorporating a graft carbon black polymer prepared by graft polymerizing a monomer to carbon black in the photographic element, in particular, in the light-shielding layer of the photosensitive sheet.The graft carbon black polymer prepared by graft polymerizing a monomer to carbon black can be uniformly dispersed in an aqueous medium and thus the photographic properties of a diffusion transfer photographic element can be improved using the graft carbon black polymer.Type: GrantFiled: November 28, 1983Date of Patent: March 19, 1985Assignee: Fuji Photo Film Co., Ltd.Inventors: Hideki Takaki, Hiroshi Hayashi, Shigetoshi Ono, Hisashi Okamura
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Patent number: 4500631Abstract: A radiographic image forming process comprising imagewise exposing a negative type silver halide light-sensitive photographic material in combination with a fluorescent intensifying screen to radiation and then treating said material with a processing solution, said material comprising a support and constituent layers coated on both sides of said support, said layers containing(a) light sensitive silver halide particles,(b) metallic salt particles which are not light-sensitive and, when untreated, are more soluble in said processing solution than said silver halide particles, said metallic salt particles having been treated so that the surface thereof has been rendered less soluble than said silver halide by a dissolution retarder,(c) physical development nuclei, and(d) compounds selected from water soluble dyes having absorption maxima in an aqueous solution of from 400 to 600 nm or compounds selected from said water soluble dyes coupled to a non-diffusive mordant, andsaid processing solution containing at lType: GrantFiled: August 5, 1983Date of Patent: February 19, 1985Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Eiichi Sakamoto, Mikio Kawasaki, Kouji Ono, Kakujulo Fukuoji, Noboru Fujimori
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Patent number: 4500636Abstract: A silver halide photographic light-sensitive material which comprises a light-sensitive silver halide emulsion layer having associated therewith a blocked photographic agent, said blocked photographic agent being represented by the following general formula (I): ##STR1## wherein A represents a photographic agent moiety which is attached to a blocking moiety through a hetero atom; Z represents a divalent linkage group; p represents 0 or 1; X and Y each represents a substituent: m represents an integer of 0 to 4: and n represents an integer of 0 to 5.Type: GrantFiled: January 27, 1984Date of Patent: February 19, 1985Assignee: Fuji Photo Film Co., Ltd.Inventors: Mitsunori Ono, Isamu Itoh, Keiji Mihayashi, Yukio Karino
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Patent number: 4495273Abstract: Silver halide photographic elements comprising a support on which there is spread a plurality of photosensitive layers of gelatin incorporating silver halides and containing coupling agents, and further being associatd with auxiliary gelatin layers tend to suffer from brittleness. An improved element comprises, spread over said support and under said plurality of photosensitive layers, a layer of gelatin in which there is dispersed a fragility reducing quantity of droplets of a water-immiscible high boiling organic solvent, and an adhesion promoting quantity of a vinyl addition polymer latex.Type: GrantFiled: September 3, 1981Date of Patent: January 22, 1985Assignee: Minnesota Mining and Manufacturing CompanyInventor: Mario Pannocchia
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Patent number: 4489152Abstract: Diffusion transfer film units and processes are disclosed wherein a silver transfer image is formed in an image layer separated from the silver halide emulsion by a layer containing carbon black. Inclusion of polyvinylpyrrolidone in the carbon black layer provides increased silver transfer density.Type: GrantFiled: February 29, 1984Date of Patent: December 18, 1984Assignee: Polaroid CorporationInventors: David F. Oberhauser, Peter H. Roth
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Patent number: 4477562Abstract: A photothermographic element having a strippably-adhered, radiation-absorbing, antihalation layer is disclosed. The element comprises at least one imageable layer adhered to one surface of a support base, and an antihalation layer having a resistance greater than 1500 ohms per square, strippably adhered to any exposed surface of said element, said antihalation layer having a delaminating resistance in the range of 6 to 50 g/cm, a layer strength in g/cm greater than its delaminating resistance, and an optical density of at least 0.1.Type: GrantFiled: May 24, 1983Date of Patent: October 16, 1984Assignee: Minnesota Mining and Manufacturing CompanyInventor: Jeanine I. Zeller-Pendrey
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Patent number: 4477559Abstract: There is disclosed a photosensitive silver halide color photographic material comprising a support having on one side thereof, an antihalation layer, a red-sensitive silver halide emulsion layer, a green-sensitive silver halide emulsion layer and a blue-sensitive silver halide emulsion layer wherein each of said silver halide emulsion layers contains a non-diffusable coupler. The other surface of the support has thereon a dye-containing backing layer. The antihalation layer contains no more than 0.2 g/m.sup.2 of silver and the total amount of silver contained in the silver halide emulsion layers is at least 7.0 g/m.sup.2.Type: GrantFiled: February 22, 1983Date of Patent: October 16, 1984Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Masao Iwamuro, Kenji Kumashiro
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Patent number: 4456674Abstract: This invention relates to diffusion transfer processes and products wherein the transmission density of the pigmented processing composition layer is increased by employing an alkali earth metal salt to increase the light-absorbing ability of a carboxynaphthol phthalein optical filter agent within said processing composition layer. In another embodiment, a carboxyindole phthalein optical filter agent also is included in said processing composition layer, and a zinc or cadmium salt is employed to shift the spectral absorption of the carboxyindole phthalein into the green region of the visible spectrum. In a further embodiment, a calcium salt is employed in a viscous pigmented processing compositon comprising a light-reflecting pigment, colloidal silica and a metal chelating agent, e.g., an alkylene polyamine polyacetic acid to stabilize the spreading characteristics of the compositions.Type: GrantFiled: July 25, 1983Date of Patent: June 26, 1984Assignee: Polaroid CorporationInventors: Leon D. Cerankowski, Gary S. LaPointe, Neil C. Mattucci
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Patent number: 4452878Abstract: A class of quaternary nitrogen-containing polymeric materials, which upon contact with alkali provide substantial light-absorbing or opacifying properties, is disclosed. The polymeric materials comprise repeating units of the formula: ##STR1## wherein the cyclic quaternary nitrogen-containing moiety is a 2-, 3-, or 4-pyridinium moiety; R.sup.1 and R.sup.2 are independently hydrogen, alkyl, substituted alkyl, cycloalkyl, aryl, aralkyl, alkaryl, halo, or R.sup.1 and R.sup.2 together comprise the atoms necessary to complete a six-membered, substituted or unsubstituted benzenoid ring; R.sup.3 is hydrogen or alkyl; X is an anion; and Y is hydrogen, alkyl, substituted alkyl, cycloalkyl, aryl, aralkyl, alkaryl or halo.Type: GrantFiled: May 9, 1983Date of Patent: June 5, 1984Assignee: Polaroid CorporationInventors: Louis Locatell, Jr., Charles M. Zepp
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Patent number: 4450222Abstract: Image transfer photographic elements, assemblages, processes and compositions are described which employ carbon black in an opaque layer and/or alkaline processing composition, the carbon black having a deactivating compound adsorbed thereto so that dye image-providing material can diffuse through the opaque layer and/or processing composition without any substantial adsorption thereof to the carbon black, the deactivating compound being incapable of releasing any dye moiety therefrom.In a preferred embodiment, the deactivating compound has the following formula: ##STR1## wherein: (a) Ballast is an organic ballasting radical;(b) Z is ##STR2## or is part of Y; (c) G is OR.sup.1 or NHR.sup.2 wherein R.sup.1 is hydrogen or a hydrolyzable moiety and R.sup.Type: GrantFiled: December 20, 1982Date of Patent: May 22, 1984Assignee: Eastman Kodak CompanyInventors: Kenneth C. Mattes, Harold C. Warren
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Patent number: 4446227Abstract: The new compounds of the general formula ##STR1## where R.sub.1 is hydrogen, alkyl or cyclic alkyl, R.sub.2 and R.sub.3 are each hydrogen, alkyl, a carboxylic acid, ester or amide group or cyano, and R.sub.4, R.sub.5 and R.sub.6 are each alkyl or aryl, are useful as antihalation dyes and as image dyes in photographic materials for dye-bleaching processes.Type: GrantFiled: September 20, 1982Date of Patent: May 1, 1984Assignee: Ciba-Geigy AGInventor: William E. Long