Polymer Of Unsaturated Monomer Patents (Class 430/536)
  • Patent number: 4362812
    Abstract: Static property in a photographic material is effectively prevented by incorporating a specific copolymer formed from, as the copolymerizable components, a betaine-containing polymerizable monomer and a fluorine-containing polymerizable monomer, in the protective layer, backing layer, or an overcoat of the photographic material without exhibiting adverse influences on the photographic properties of the photographic material.
    Type: Grant
    Filed: July 10, 1981
    Date of Patent: December 7, 1982
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Junji Minamizono, Shinzo Kishimoto, Shigeki Yokoyama, Takayuki Inayama
  • Patent number: 4358533
    Abstract: A silver halide photographic material having a hydrophilic colloid layer comprising fine polymer particles loaded with a hydrophobic photographic addenda provided on a support wherein the polymer has repeating units formed from a nonionic hydrophobic monomer. The nonionic hydrophobic monomer has the formula ##STR1## R.sub.1 and R.sub.2 individually are a hydrogen atom or methyl group, R.sub.3 is a hydrogen atom, an alkyl or aryl group, and m and n are integers of from 2 to 100 individually.
    Type: Grant
    Filed: March 11, 1981
    Date of Patent: November 9, 1982
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Kouji Tokitou, Tsuneo Wada
  • Patent number: 4356249
    Abstract: Photographic assemblages, elements, receiving elements and cover sheets comprise a combination of two timing layers and two neutralizing layers for use with negative-working silver halide emulsions and positive-working redox dye-releasers. The outermost timing layer has a negative temperature coefficient while the innermost timing layer has either a positive or negative temperature coefficient and has a penetration time by alkaline processing composition that is greater than the penetration time of the outermost timing layer. An auxiliary neutralizing layer is located between the two timing layers. Dye release is restricted more at low temperatures than at high temperatures so that the temperature latitude of the system is thereby increased.
    Type: Grant
    Filed: October 30, 1981
    Date of Patent: October 26, 1982
    Assignee: Eastman Kodak Company
    Inventors: Edward P. Abel, Edward Weissberger
  • Patent number: 4355099
    Abstract: For the production of positive photographic prints a composite material in strip form is used as an intermediary to form the print images and is then adhered in a continuous procedure to a main support strip such as paper. The resultant strip is then cut to separate the individual prints. The composite material has a transparent film of biaxially-oriented plastics film not more than 50.mu. thick and water-resistant and to which photosensitive emulsions are applied, and a further layer overlying the emulsions to protect them, the further layer being adhered to the main support. This layer is reflective, as by incorporation of a white pigment, so that the image is seen through the transparent film against the background of this layer rather than the main support. The reflective layer may contain other chemicals relevant to processing.
    Type: Grant
    Filed: November 29, 1981
    Date of Patent: October 19, 1982
    Assignee: Ciba-Geigy AG
    Inventor: Franz Trautweiler
  • Patent number: 4353981
    Abstract: A silver halides photographic material with improved keeping quality, said material having a substrate formed by coating a base web with a film-forming resin, preferably a polyolefin resin, said base web being composed principally of natural pulp or a mixture of two or more different types of natural pulp having a post color number of 2 or below, said post color number being defined by the following formula: ##EQU1## [wherein Ro is brightness (%).times.(1)/(100) before fading treatment, R is brightness (%).times.(1)/(100) after 18-hour fading treatment at 85.degree. C. and 95% RH, and P is post color (PC) number which indicates the degree (nondimensional number) of fading].
    Type: Grant
    Filed: September 5, 1980
    Date of Patent: October 12, 1982
    Assignee: Mitsubishi Paper Mills, Ltd.
    Inventors: Toru Noda, Yoshinobu Ichihashi, Massashi Kubbota
  • Patent number: 4353980
    Abstract: An improved abrasion and scratch resistance and resistance to chemicals of photographic materials is achieved by applying a coating composition comprising an irradiation-hardening binder, a multifunctional acrylic monomer, optionally a diiso- or polyisocyanate and a photoinitiator to the photographic material and subsequently irradiating the coating composition with light from the ultra-violet region of the spectrum.
    Type: Grant
    Filed: November 25, 1980
    Date of Patent: October 12, 1982
    Assignee: AGFA-Gevaert AG
    Inventors: Gunter Helling, Karl Fuhr
  • Patent number: 4353973
    Abstract: Photographic assemblages, elements, receiving elements and cover sheets are described employing a neutralizing layer comprising about 75 to about 150 meq. of acid/m.sup.2 of element for neutralizing an alkaline processing composition. The neutralizing layer, timing layer or layer adjacent thereto also contains about 1 to about 10 meq./m.sup.2 of oxalic acid, or an acid salt thereof, to minimize sensitometric changes that occur with keeping.
    Type: Grant
    Filed: June 29, 1981
    Date of Patent: October 12, 1982
    Assignee: Eastman Kodak Company
    Inventor: Richard W. Wheeler
  • Patent number: 4340655
    Abstract: Improved thermal and mechanical barrier layers coated on the recording layer of an optical recording element are disclosed. The improved layers comprise water-soluble polymers having a glass transition temperature when dry of at least 100.degree. C. and preferably at least 150.degree. C. These barrier layers are easily coated and do not significantly degrade the performance of the element. Optional layers such as spacer layers and topcoat layers coated on the barrier layers are also disclosed.
    Type: Grant
    Filed: June 18, 1980
    Date of Patent: July 20, 1982
    Assignee: Eastman Kodak Company
    Inventors: Kenneth R. Hollister, Harold T. Thomas
  • Patent number: 4333998
    Abstract: Radiation-curable compositions useful for restorative and/or protective treatment of photographic elements are comprised of an acrylated urethane, an aliphatic ethylenically-unsaturated carboxylic acid, a multifunctional acrylate, and a siloxy-containing polycarbinol. Photographic elements, such as still films, motion picture films, paper prints, microfiche, and the like, are provided with a protective overcoat layer which is permanently bonded to the element, and serves to protect it from abrasion and scratches, by coating the element with the radiation-curable composition and irradiating the coating to bond it to the element and cure it to form a transparent, flexible, scratch-resistant, cross-linked polymeric layer. The protective overcoat layer can be applied to the image-bearing side of the element or to the support side of the element or to both sides.
    Type: Grant
    Filed: November 24, 1980
    Date of Patent: June 8, 1982
    Assignee: Eastman Kodak Company
    Inventor: Gerald M. Leszyk
  • Patent number: 4331508
    Abstract: A photographic support comprises a paper coated on both sides with polyethylene resin film. To impart the paper a desirable stiffness and improved cutting property, polyvinyl alcohol fibers which are neither heat-treated nor acetalized, in 5-20 parts by weight, are mixed to 100 parts by weight of woodpulp fibers when the paper is formed.
    Type: Grant
    Filed: July 6, 1981
    Date of Patent: May 25, 1982
    Assignee: Mitsubishi Paper Mills, Ltd.
    Inventors: Masao Miyama, You Kusama
  • Patent number: 4330618
    Abstract: A photographic light-sensitive material containing a copolymer comprising a betaine group-containing monomer and a fluorine atom-containing monomer in at least one photographic layer thereof, whereby the material is improved in the antistatic properties without adversely affecting its photographic properties.
    Type: Grant
    Filed: December 3, 1980
    Date of Patent: May 18, 1982
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Junji Minamizono, Shinzo Kishimoto, Takayuki Inayama
  • Patent number: 4329423
    Abstract: Improvements in coated film bases. Photobase comprising a film support, e.g. a polyethylene terephthalate film, having a copolymeric subbing layer comprising a copolymer of acrylic acid or an alkyl ester thereof/methacrylic acid or an alkyl ester thereof/itaconic acid or itaconic anhydride, e.g. an ethyl acrylate/methyl methacrylate/itaconic acid copolymer, and containing free itaconic acid, half ester or anhydride which is directly adherent to light-sensitive photographic emulsions.
    Type: Grant
    Filed: October 22, 1980
    Date of Patent: May 11, 1982
    Assignee: Imperial Chemical Industries Limited
    Inventors: Cyril J. Ealding, Graham Jarrett
  • Patent number: 4328283
    Abstract: A photographic polyester support having an adjacent subbing layer which comprises a copolymer of (1) glycidyl acrylate and/or glycidyl methacrylate and (2) hydroxylalkyl acrylate with the alkyl groups of 2-4 carbon atoms and/or hydroxyalkyl methacrylate wherein 0-67 wt % of a copolymerizable vinyl monomer may be present and the method of subbing said support with an aqueous composition of the acrylate copolymer.
    Type: Grant
    Filed: November 13, 1979
    Date of Patent: May 4, 1982
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Takanori Nakadate, Naoto Abe, Kenichi Kitahara, Hironobu Nakao
  • Patent number: 4323644
    Abstract: A photographic material having at least one layer containing a polymer having a repeating unit of the formula (I): ##STR1## wherein A is a monomer unit copolymerized with a copolymerizable ethylenically unsaturated monomer; R is a hydrogen atom or a lower alkyl group having 1 to about 6 carbon atoms; L is a bivalent linking group having 1 to about 20 carbon atoms; X is an active ester group; x and y each represents molar percent, x being between 0 and 95 and y being between 5 and 100; m is 0 or 1.
    Type: Grant
    Filed: November 5, 1980
    Date of Patent: April 6, 1982
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Taku Nakamura, Masasi Ogawa, Kunio Ishigaki
  • Patent number: 4317123
    Abstract: A thermal recording material possessing high sensitivity which comprises a support having thereon in sequence a subbing layer, a recording layer and optionally, a protecting layer in which the subbing layer contains a composition comprising (A) 100 parts by weight of chlorinated polyolefin having a chlorine content of about 30% by weight or more and (B) 1 part to 100 parts by weight of aminoalkylalkoxysilane compound represented by the following general formula (I): ##STR1## wherein R.sup.1 represents an amino group or a H.sub.2 N--R.sup.5 --NH-- group; R.sup.2 and R.sup.5 each represents a polymethylene group having 1 to 2 carbon atoms or a straight or branched chain alkylene (alkanediyl) group having 3 to 5 carbon atoms, and may be the same or different; R.sup.3 represents a straight or branched chain alkyl group having 1 to 5 carbon atoms; m represents 2 or 3; R.sup.4 represents a straight or branched chain alkyl group having 1 to 5 carbon atoms or an R.sup.1 --R.sup.
    Type: Grant
    Filed: October 25, 1979
    Date of Patent: February 23, 1982
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tomizo Namiki, Osamu Seshimoto, Fumiaki Shinozaki, Akira Nahara, Tomoaki Ikeda
  • Patent number: 4314020
    Abstract: Photographic assemblages, elements, receiving elements and cover sheets comprise a combination of two timing layers and a neutralizing layer. The outermost timing layer contains photographic addenda, such as development inhibitors, for substantially terminating development of the silver halide emulsion. The timing layer next to the neutralizing layer has a much longer breakdown time so that it is permeated by the alkaline processing composition only after silver halide development has been substantially terminated.
    Type: Grant
    Filed: August 4, 1980
    Date of Patent: February 2, 1982
    Assignee: Eastman Kodak Company
    Inventors: Kenneth J. Reed, Patrick H. Saturno, Gerald L. Ducharme
  • Patent number: 4312940
    Abstract: A photographic light-sensitive material comprising at least one layer containing a polymer dispersion of the following formula (I) or (II) as a mordant ##STR1## wherein A represents a monomer unit obtained from at least one monomer having at least two copolymerizable ethylenically unsaturated groups at least one of which is in the side chain; B represents a monomer unit obtained from at least one copolymerizable monoethylenically unsaturated monomer; D.sup..sym. represents a 5- or 6-membered heterocyclic group containing one or two nitrogen atoms one of which is positively charged and D may contain one or more substituents; R.sub.1 represents a hydrogen atom or a lower alkyl group; R.sub.2 and R.sub.3, which may be the same or different, each represents an alkyl group or an aralkyl group, or R.sub.2 and R.sub.3 may combine together with the nitrogen atom to which they are attached and form a 5- or 6-membered ring; X.sup..crclbar.
    Type: Grant
    Filed: July 7, 1980
    Date of Patent: January 26, 1982
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Taku Nakamura, Shigeru Nagatomo
  • Patent number: 4312937
    Abstract: This disclosure relates to production of a photographic film assembly substantially free of optical pinholes for use as a base for negatives in self-developing film packs. The assembly comprises a paper layer and first and second layers of polyolefin adhered to opposite sides of the paper layer. The paper layer has a caliper of about 2 mils to about 4.5 mils and a basis weight of about 55 g/m.sup.2 to about 125 g/m.sup.2. The first and second polyolefin layers each have a layer weight of about 10 g/m.sup.2 to about 48 g/m.sup.2. Carbon black is uniformly dispersed in at least two out of the three layers. The total amount of carbon black in the assembly is about 2.5 g/m.sup.2 to about 4.0 g/m.sup.2.
    Type: Grant
    Filed: April 11, 1980
    Date of Patent: January 26, 1982
    Assignee: Schoeller Technical Papers, Inc.
    Inventors: Klaus B. Kasper, William L. Quartz, William H. Myers
  • Patent number: 4309713
    Abstract: A thermal recording element comprising a support, a recording layer formed thereon and a chlorinated polyolefin layer formed on said recording layer.
    Type: Grant
    Filed: June 26, 1979
    Date of Patent: January 5, 1982
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Fumiaki Shinozaki, Tomizo Namiki, Masao Kitajima, Tomoaki Ikeda, Yuzo Mizobuchi
  • Patent number: 4301240
    Abstract: Photographic silverhalide containing materials having improved mechanical and electrostatic properties are obtained by adding to at least one of the layers of the material a cross-linked polymer of acrylic acid and/or methacrylic acid which is prepared either (a) by inverse emulsion polymerization of acrylic and/or methacrylic acid monomers in the presence of polyfunctional cross-linking monomers and an emulsifier and breaking of the emulsion and redispersion of the polymer particles in water; or (3) by emulsion polymerization of aliphatic esters of acrylic and/or methacrylic acid in water in the presence of polyfunctional cross-linking monomers and of an emulsifier, followed by saponification of the polymer.
    Type: Grant
    Filed: December 28, 1978
    Date of Patent: November 17, 1981
    Assignee: Agfa-Gevaert Aktiengesellschaft
    Inventors: Rolf Bruck, Erich Wolff
  • Patent number: 4301239
    Abstract: Dimensionally stable energy-treated polyester film is coated with an opaque antistatic backing layer of carbon-filled polyacrylate containing an aziridine cross-linking agent.
    Type: Grant
    Filed: December 5, 1979
    Date of Patent: November 17, 1981
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Conrad E. Miller
  • Patent number: 4301230
    Abstract: A process for producing an image which comprises the steps of:(1) applying to the surface of a substrate the surface of a photosensitive layer, the other surface of the photosensitive layer being adhered to a substantially transparent film support which is soluble or dispersible in a developer consisting essentially of a liquid capable of substantially dissolving or dispersing therein the areas of the layer other than those having a polymeric image produced by imagewise exposure in the step (2) below;(2) exposing the photosensitive layer, imagewise, to actinic radiation to form a polymeric image in the layer; and(3) washing away with the developer the film support and the areas of the layer other than those having the polymeric image to form an image of a polymeric material on the substrate.
    Type: Grant
    Filed: December 18, 1979
    Date of Patent: November 17, 1981
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Tadashi Taguchi, Noboru Fujikawa, Mitsuo Kohno, Katsumi Yoshitake, Kunio Satake
  • Patent number: 4297431
    Abstract: A diffusion control layer comprising a polymerization product of a monomer capable of undergoing .beta.-elimination in an alkaline environment is disclosed for use in diffusion transfer film units, as an interlayer or overcoat in photosensitive elements, or as a timing layer or overcoat in image-receiving elements.
    Type: Grant
    Filed: March 14, 1980
    Date of Patent: October 27, 1981
    Assignee: Polaroid Corporation
    Inventor: Charles I. Sullivan
  • Patent number: 4297432
    Abstract: Photographic elements, two-sheet diffusion transfer assemblages containing such elements, and dye image-receiving elements are described. The photographic element comprises a support, a neutralizing layer, a timing layer, a vinylidene chloride polymeric layer, a polymeric primer layer, and at least one silver halide emulsion layer having a dye image-providing material associated therewith. The vinylidene chloride polymeric layer and the polymeric primer layer prevent unwanted transfer of portions of the emulsion layer to a receiver when the receiver and photographic element are peeled apart. The polymeric primer layer can be either a particular ionic vinyl polymer or a particular ionic polyester.
    Type: Grant
    Filed: August 1, 1980
    Date of Patent: October 27, 1981
    Assignee: Eastman Kodak Company
    Inventors: Wayne A. Bowman, John F. Bishop, John M. Noonan
  • Patent number: 4296195
    Abstract: Two-sheet diffusion transfer assemblages and photographic elements are described which contain a primer layer located between a polymeric acid layer and a timing layer. The primer layer prevents unwanted transfer of portions of the emulsion layer to the receiver when the receiver and photographic element are peeled apart. The primer layer comprises:(a) a mixture of gelatin and cellulose nitrate, or(b) a mixture of an acrylic acid copolymer and a particular acrylic acid terpolymer, or(c) an acrylic acid copolymer as described herein.
    Type: Grant
    Filed: August 1, 1980
    Date of Patent: October 20, 1981
    Assignee: Eastman Kodak Company
    Inventors: John F. Bishop, Wayne A. Bowman
  • Patent number: 4292402
    Abstract: Fluorine-containing surfactants according to formula (Rf--X).sub.n --A--L--Z wherein Rf is a short-chain fluorine-containing group derived from hexafluoropropylene or trifluorochloroethylene, X is --O--, --S--, or --SO.sub.2 --, n is at least 2, the Rf groups being same or different, L is a monovalent bond or a bivalent bridging group such as --COO--alkylene, --CONR.sup.1 --alkylene, or --SO.sub.2 NR.sup.1 --alkylene, wherein R.sup.1 is hydrogen or C.sub.1 -C.sub.5 alkyl, and Z represents a hydrophilic polyoxyethylene group or a hydrophilic group such as ##STR1## wherein M is hydrogen, an alkali metal, ammonium, or organic ammonium, and R.sup.3 is alkyl; A is an aliphatic, aromatic, or aliphatic-aromatic group. These surfactants can be used in hydrophilic colloid layers, which may form part of light-sensitive silver halide materials.
    Type: Grant
    Filed: February 8, 1980
    Date of Patent: September 29, 1981
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Robert J. Pollet, Hendrik E. Kokelenberg, Rafael P. Samijn, Francis J. Sels, Frans J. Ville, Nikolaas C. de Jaeger
  • Patent number: 4291120
    Abstract: A heat developable photosensitive material having two or more layers superimposed on a support and containing at least (a) an organic silver salt, (b) a photocatalyst and (c) a reducing agent in one or more such layers, at least one said layers containing (d) a polymer having a repeating unit of the formula: ##STR1## wherein R is a hydrogen atom or a lower alkyl group; and X is a hydrogen atom, or one to three groups selected from the group consisting of a halogen atom, a nitro group, a cyano group, an alkyl group, an alkoxy group, an alkoxycarbonyl group, an alkylsulfonyl group, an aryloxy group, an acyl group, an acyloxy group and an acylamido group.
    Type: Grant
    Filed: February 15, 1980
    Date of Patent: September 22, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tomoyuki Kobayashi, Toshimasa Usami, Hiroshi Misu, Hidefumi Sera
  • Patent number: 4288531
    Abstract: An imaging element which relies upon an aromatic dialdehyde to produce a dye provides improved maximum neutral densities when certain polymers are superimposed over the element. Such polymers seal the element to reduce loss of the dialdehyde during development. An imaging method is also disclosed.
    Type: Grant
    Filed: September 26, 1979
    Date of Patent: September 8, 1981
    Assignee: Eastman Kodak Company
    Inventors: Anthony Adin, Richard C. Sutton, Joseph A. Verdone
  • Patent number: 4288287
    Abstract: A photographic support comprises a paper coated on both sides with polyethylene resin film. For providing improved cutting property of the paper when it is used for a photographic paper and subjected to an automatic printer/cutter, strength reinforcing and sizing agents contained in the support are made such that amount ratio of the former to the latter is at least 1.8. To impart the paper a desirable stiffness and further improved cutting property, polyvinyl alcohol fibers which are neither heat-treated nor acetalized, in 5-25 parts by weight, are mixed to 100 parts by weight of woodpulp fibers when the paper is formed. This allows to make the paper as light as 160 g/m.sup.2 or less but having stiffness property pertaining to photographic papers.
    Type: Grant
    Filed: January 11, 1980
    Date of Patent: September 8, 1981
    Assignee: Mitsubishi Paper Mills, Ltd.
    Inventors: Masao Miyama, You Kusama
  • Patent number: 4288523
    Abstract: Novel polymers comprising recurring units capable of undergoing .beta.-elimination in an alkaline environment are disclosed for use in diffusion control layers in diffusion transfer film units.
    Type: Grant
    Filed: March 14, 1980
    Date of Patent: September 8, 1981
    Assignee: Polaroid Corporation
    Inventor: Lloyd D. Taylor
  • Patent number: 4287293
    Abstract: A photographic element having a photographic layer such as silver halide emulsion layer, protective layer, intermediate layer, subcoat layer, diffusion transfer image-receiving layer, antihalation layer and backing layer, can be improved in the adhesion between the layer and support, little curling on drying, and flexibility of the layer, by incorporating into the photographic layer a conversion mixture of a polyvinyl alcohol having a saponification degree of 96% or more and an ethylene-maleic anhydride copolymer.
    Type: Grant
    Filed: January 8, 1980
    Date of Patent: September 1, 1981
    Assignee: Mitsubishi Paper Mills, Ltd.
    Inventors: Tamotsu Iwata, Shigeru Iguchi
  • Patent number: 4283504
    Abstract: Copolymers containing an acrylamidophenol as a crosslinking site and the corresponding crosslinked polymers are disclosed. The acrylamidophenol unit can be copolymerized with a wide variety of other monomers to provide crosslinkable and crosslinked polymers with useful properties. The acrylamidophenol unit provides for crosslinking at low pH with conventional crosslinking agents. The acrylamidophenol monomer unit is present in the copolymer from about 0.5 to 50 percent by weight and has the formula: ##STR1## wherein: x is 1 or 0,L is a linking group,R represents hydrogen or methyl, andR.sup.1 through R.sup.5 are independently selected from the group consisting of hydrogen, hydroxy, alkyl from 1 to 6 carbon atoms and aryl from 6 to 10 carbon atoms; with the proviso that at least one of R.sup.1 through R.sup.5 is hydroxy and at least one of the positions ortho or para to said hydroxy has a hydrogen atom attached thereto. The remainder of the polymer can comprise from 50 to 99.
    Type: Grant
    Filed: October 11, 1979
    Date of Patent: August 11, 1981
    Assignee: Eastman Kodak Company
    Inventors: Gerald A. Campbell, Kenneth R. Hollister, Richard C. Sutton
  • Patent number: 4271256
    Abstract: A method for forming images which comprises imagewise exposing a recording element comprising a support having directly or on a subbing layer thereon, as a recording layer, a vacuum deposited layer containing at least about 20% by volume of an organic substance, adhering a strippable film on the surface of the recording layer prior to or after the imagewise exposure, and peeling apart the strippable film from the recording layer after the imagewise exposure, whereby the exposed areas of the recording layer remain on the support and the non-exposed areas are transferred onto the strippable film.
    Type: Grant
    Filed: June 20, 1980
    Date of Patent: June 2, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Keishiro Kido, Minoru Wada, Tomoaki Ikeda
  • Patent number: 4269937
    Abstract: In a base for a photographic sensitive material comprising a polyolefin coated paper, the improvement which comprises a layer of an ionomer of an .alpha.-olefin and an .alpha.,.beta.-ethylenically unsaturated carboxylic acid between the surface of the paper and the polyolefin coating.
    Type: Grant
    Filed: June 25, 1979
    Date of Patent: May 26, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoshimasa Asanuma, Taiichi Nishimura
  • Patent number: 4268601
    Abstract: A photosensitive image forming material which comprises a transparent support having thereon, in order, a poly(vinyl alcohol) layer, an alcohol soluble polyamide layer and a photosensitive resin composition layer with at least one of the poly(vinyl alcohol) layer and the photosensitive resin composition layer containing a colorant therein; and an image forming method using the image-forming material. Such a layer structure ensures sufficiently layer good adhesion as well as strippability of the developed image on demand.
    Type: Grant
    Filed: July 17, 1978
    Date of Patent: May 19, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tomizo Namiki, Fumiaki Shinozaki, Tomoaki Ikeda
  • Patent number: 4267262
    Abstract: In a photographic element for the color diffusion transfer process having a neutralizing system comprising a neutralizing layer and a timing layer, the improvement which comprises said timing layer containing a mixture of acetyl cellulose and a polymer represented by the general formula (I): ##STR1## wherein A represents a repeating unit represented by the general formula (II): ##STR2## wherein R.sub.2 represents a hydrogen atom, a halogen atom, or a methyl group; R.sub.3 represents a hydrogen atom, a halogen atom, an alkyl group, an aryl group, ##STR3## R.sub.4 represents an alkyl group or an aralkyl group; R.sub.5 and R.sub.6, which may be the same or different, each represents an alkyl group, an aryl group, or an aralkyl group; and a represents 0 or 1; R.sub.
    Type: Grant
    Filed: April 3, 1979
    Date of Patent: May 12, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yukio Karino, Shinji Sakaguchi, Yoshio Sakakibara
  • Patent number: 4266015
    Abstract: Light sensitive elements containing silver halide emulsions can be desensitized to static charge marking by the addition of fluorine-containing polymers of a defined class.
    Type: Grant
    Filed: September 13, 1977
    Date of Patent: May 5, 1981
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Louis Butler, Paul H. Ogden
  • Patent number: 4247627
    Abstract: This invention is directed to photographic elements having hydrophilic colloid layers containing loaded particles of from 0.02 to 0.2 micron in average diameter consisting essentially of a loadable polymer, with greater than 2 percent by weight of the polymer being derived from monomers capable of forming water soluble homopolymers. A hydrophobic photographic dye, coupler, developing agent or ultraviolet absorbing compound is loaded into and distributed through the particles. The weight ratio of the hydrophobic photographic dye, coupler, developing agent or ultraviolet absorbing compound to the loadable polymer is from about 1:4 to 3:1.
    Type: Grant
    Filed: October 10, 1979
    Date of Patent: January 27, 1981
    Assignee: Eastman Kodak Company
    Inventor: Tsang J. Chen
  • Patent number: 4247625
    Abstract: An imaging composition and element are disclosed wherein an aromatic dialdehyde reacts with amines generated in response to activating radiation. Improved binders are used to insure sufficient retention of the volatile dialdehyde prior to imaging.
    Type: Grant
    Filed: December 20, 1978
    Date of Patent: January 27, 1981
    Assignee: Eastman Kodak Company
    Inventors: George L. Fletcher, Wojciech M. Przezdziecki, John C. Wilson, Paul D. Yacobucci, Richard C. Van Hanehem
  • Patent number: 4245036
    Abstract: A latex is formed of a copolymer of 90 to 98% by weight of ethyl acrylate and 2 to 10% by weight of an ionogenic comonomer. The latter comprises in its structure a polymerizable ethylenically unsaturated bond, a hydrophobic chain comprising at least 8 carbon atoms, and a strong hydrophilic group taken from a sulpho group, a sulphato group or a phosphono group in acid or salt form.Photographic layers are described wherein the above latex is used as plasticizer for gelatin.
    Type: Grant
    Filed: October 19, 1979
    Date of Patent: January 13, 1981
    Assignee: AGFA-GEVAERT N.V.
    Inventors: Walter F. De Winter, Marcel J. Monbaliu, August M. Marien, Antoine R. Van Rossen
  • Patent number: 4229524
    Abstract: A photographic light sensitive material which contains, in at least one layer, a copolymer having a repeating unit represented by the following general formula (I): ##STR1## wherein R.sub.f represents a perfluoroalkyl group having 2 to 12 carbon atoms which may contain one hydrogen atom at the .omega.-position or a perfluoroalkenyl group; R represents a hydrogen atom or a methyl group; p represents an integer of 1 to 5; m represents an integer of 5 to 50; n represents zero or an integer of 1 to 20; and Y represents a hydrogen atom, an alkyl group having 1 to 24 carbon atoms, an alkenyl group, a phenyl group, an alkylphenyl group or one of the groups represented by R.sub.f ; whereby antistatic property (even under low humidity) and adhesion resisting property are improved without adversely affecting photographic characteristics.
    Type: Grant
    Filed: June 4, 1979
    Date of Patent: October 21, 1980
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masakazu Yoneyama, Shinzo Kishimoto
  • Patent number: 4221862
    Abstract: One can obtain finely divided polymer particles by dissolving a polymer in a water immiscible volatile solvent which has a boiling point lower than that of water, then dispersing the solution into an aqueous medium, and removing the solvent from the dispersed oil phase droplets.
    Type: Grant
    Filed: June 28, 1976
    Date of Patent: September 9, 1980
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kenji Naito, Keitaro Ohe, Nobuo Tsuji
  • Patent number: 4217409
    Abstract: There is provided an image-forming material of a laminar structure comprising:a substrate;an image-forming layer provided on at least one surface of the substrate and containing an image-forming agent selected from the group consisting of polyacids of molybdenum and tungsten and salts and complexes of these polyacids; anda transparent polymer film provided on the image-forming layer,at least one of the image-forming layer and the transparent polymer film containing a reducing agent.The image-forming material may be used in a one-stage image-forming process comprising irradiation thereof with image-wise light-rays including ultraviolet and visible and/or infrared rays or a two-stage image-forming process comprising irradiation thereof with image-wise ultra-violet rays and then with visible and/or infrared rays.
    Type: Grant
    Filed: January 15, 1979
    Date of Patent: August 12, 1980
    Assignee: Dai Nippon Insatsu Kabushiki Kaisha
    Inventors: Eiichi Inoue, Misturu Takeda
  • Patent number: 4214047
    Abstract: This invention is directed to photographic elements having hydrophilic colloid layers containing loaded particles of from 0.02 to 0.2 micron in average diameter consisting essentially of a loadable polymer, with greater than 2 percent by weight of the polymer being derived from monomers capable of forming water soluble homopolymers. A hydrophobic photographic dye, coupler, developing agent or ultraviolet absorbing compound is loaded into and distributed through the particles. The weight ratio of the hydrophobic photographic dye, coupler, developing agent or ultraviolet absorbing compound to the loadable polymer is from about 1:4 to 3:1.
    Type: Grant
    Filed: May 4, 1979
    Date of Patent: July 22, 1980
    Assignee: Eastman Kodak Company
    Inventor: Tsang J. Chen
  • Patent number: 4207106
    Abstract: A light-sensitive copying material comprising at least two organic coating layers on a support, at least one of the coating layers being a light-sensitive layer which comprises an O-quinone diazide compound whose alkali solubility is increased by irradiation with active rays.
    Type: Grant
    Filed: May 10, 1978
    Date of Patent: June 10, 1980
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masaru Odawara, Tadao Yoyama, Azusa Ohashi
  • Patent number: 4207109
    Abstract: Copolymers containing an acrylamidophenol as a crosslinking site and the corresponding crosslinked polymers are disclosed. The acrylamidophenol unit can be copolymerized with a wide variety of other monomers to provide crosslinkable and crosslinked polymers with useful properties. The acrylamidophenol unit provides for crosslinking at low pH with conventional crosslinking agents. The acrylamidophenol monomer unit is present in the copolymer from about 0.5 to 50 percent by weight and has the formula: ##STR1## wherein: x is 1 or 0,L is a linking group,R represents hydrogen or methyl, andR.sup.1 through R.sup.5 are independently selected from the group consisting of hydrogen, hydroxy, alkyl from 1 to 6 carbon atoms and aryl from 6 to 10 carbon atoms; with the proviso that at least one of R.sup.1 through R.sup.5 is hydroxy and at least one of the positions ortho or para to said hydroxy has a hydrogen atom attached thereto. The remainder of the polymer can comprise from 50 to 99.
    Type: Grant
    Filed: April 5, 1978
    Date of Patent: June 10, 1980
    Assignee: Eastman Kodak Company
    Inventors: Gerald A. Campbell, Kenneth R. Hollister, Richard C. Sutton
  • Patent number: 4192683
    Abstract: A photographic light-sensitive material comprising a layer which contains a compound represented by the following Formula I ##STR1## wherein R.sub.1 is an alkyl group having 1 to 18 carbon atoms, R.sub.2 is a hydrogen atom or an alkyl group having 1 to 18 carbon atoms with a proviso that when R.sub.2 is a hydrogen atom, R.sub.1 is an alkyl group having 1 to 7 carbon atoms, M is a cation and n is a number of 1 to 50.
    Type: Grant
    Filed: October 18, 1977
    Date of Patent: March 11, 1980
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Eiichi Sakamoto, Masao Ishihara, Kazuo Nakazato, Hiroshi Yamada, Sadatugu Terada, Kenichi Kitahara, Naoto Abe, Mamoru Komiya, Masaru Kanbe
  • Patent number: 4188220
    Abstract: A support for photographic paper coated with a resin composition comprising 100 parts by weight of a polyolefin resin and about 5 to about 25 parts by weight of a low molecular weight polyolefin having a number average molecular weight of about 1,500 to about 10,000. A photographic light-sensitive material comprising such a support is also disclosed.
    Type: Grant
    Filed: March 31, 1976
    Date of Patent: February 12, 1980
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tsuneo Kasugai, Keishi Kitagawa
  • Patent number: 4179541
    Abstract: An embossed photographic support material is produced by extrusion coating a polyolefin resin over a pattern embossed on a base paper material and pressing the polyolefin resin onto the embossed paper with a cooling roll. The cooling roll has a surface finish to impart the desired amount of gloss to the embossed surface.
    Type: Grant
    Filed: August 12, 1977
    Date of Patent: December 18, 1979
    Assignee: Mitsubishi Paper Mills, Ltd.
    Inventors: Masao Miyama, Sakan Yamaguti, You Kusama
  • Patent number: 4173480
    Abstract: Sheet material having a polymeric surface for receiving a photographic image, the material comprising an antistatic agent which is a synthetic hectorite clay having a layered structure the layers of which are electrically charged.
    Type: Grant
    Filed: April 11, 1978
    Date of Patent: November 6, 1979
    Assignee: Wiggins Teape Limited
    Inventor: Antony I. Woodward