Substituted At Coupling Position With Other Than Hydrogen Patents (Class 430/557)
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Patent number: 8481252Abstract: Silver halide photographic photosensitive materials are disclosed. A silver halide photographic photosensitive material has a support, and on or above the support, a red-sensitive silver halide emulsion layer, a first interlayer, a green-sensitive silver halide emulsion layer, a second interlayer, and a blue-sensitive silver halide emulsion layer in this order from the support, wherein the first interlayer includes a chelating agent and another silver halide photographic photosensitive material has, in the following order, a support, and provided on or above the support, a first interlayer containing a chelating agent, a blue-sensitive silver halide emulsion layer, a second interlayer, a red-sensitive silver halide emulsion layer, a third interlayer, a green-sensitive silver halide emulsion layer, and a protective layer.Type: GrantFiled: November 27, 2009Date of Patent: July 9, 2013Assignee: FUJIFILM CorporationInventors: Hiroya Yoshioka, Hidekazu Sakai, Shigeru Shibayama
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Patent number: 7687229Abstract: A silver halide color photographic light-sensitive material having, on a support, at least each one light-sensitive silver halide emulsion layers containing yellow-, magenta-, or cyan-dye-forming-coupler, and at least one light-insensitive hydrophilic colloid layer, wherein at least one of the dye-forming couplers is a dye-forming coupler that forms an azomethine dye having a solubility of 1×10?8 mol/L to 5×10?3 mol/L in ethyl acetate; and an image forming method using the light-sensitive material.Type: GrantFiled: August 23, 2005Date of Patent: March 30, 2010Assignee: FUJIFILM CorporationInventors: Yasuaki Deguchi, Kiyoshi Takeuchi, Mamoru Sakurazawa, Makoto Yamada, Takehiko Satou
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Patent number: 7556918Abstract: A silver halide color photographic light-sensitive material, having at least one each of blue-, green-, and red-sensitive emulsion layers containing yellow, magenta, and cyan couplers, respectively, on a support; wherein said blue-sensitive emulsion layer contains at least one coupler of formula (I); and wherein the light-sensitive material satisfies expression a-1) and/or b-1): wherein, Q forms a 5- to 7-membered ring with the —N?C—N(R1)-; R1 and R2 each are a substituent; m is 0 to 5; and X is a hydrogen atom, or a coupling split-off group; 0.5?Dmax(UV)/Dmin(UV)?1.1??a-1) wherein Dmax(UV)/Dmin(UV) is the smallest of the value in a wavelength range of 340 to 450 nm; 1300?(B?C)/A?20000??b-1) wherein B is yellow Dmax, C is yellow Dmin; and A is an amount mol/m2 of the coupler of formula (I).Type: GrantFiled: December 31, 2007Date of Patent: July 7, 2009Assignee: FUJIFILM CorporationInventors: Hiroyuki Yoneyama, Akira Ikeda, Shin Soejima, Kiyoshi Takeuchi, Naoto Matsuda
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Patent number: 7527922Abstract: A silver halide color photographic light-sensitive material having, on a support, at least one red-sensitive silver halide emulsion layer, at least one green-sensitive silver halide emulsion layer and at least one blue-sensitive silver halide emulsion layer, characterized in that at least one of the silver halide emulsion layers contains a silver halide emulsion having a silver chloride content of 90 mole % or above, the silver halide emulsion contains at least one kind of selenium compound, and the silver halide emulsion layer containing the silver halide emulsion has a characteristic curve satisfying the following relation (1); 2.0??H/?L?0.5??Relation (1) wherein ? represents a gradient of the characteristic curve, ?H represents a gradient in the case of 1×10?6-second exposure and ?L represents a gradient in the case of 100-second exposure.Type: GrantFiled: March 10, 2005Date of Patent: May 5, 2009Assignee: FUJIFILM CorporationInventors: Shigeru Shibayama, Toshihiro Kariya, Akito Yokozawa, Kenji Naoi, Katsuhisa Ohzeki, Hiroyuki Suzuki
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Patent number: 7425408Abstract: A silver halide color photographic light-sensitive material, having at least one each of blue-, green-, and red-sensitive emulsion layers containing yellow, magenta, and cyan couplers, respectively, on a support; wherein said blue-sensitive emulsion layer contains at least one coupler of formula (I); and wherein the light-sensitive material satisfies expression a-1) and/or b-1): wherein, Q forms a 5- to 7-membered ring with the —N?C—N(R1)—; R1 and R2 each are a substituent; m is 0 to 5; and X is a hydrogen atom, or a coupling split-off group; 0.5?Dmax(UV)/Dmin(UV)?1.1: ??a-1) wherein Dmax(UV)/Dmin(UV) is the smallest of the value in a wavelength range of 340 to 450 nm; 1300?(B?C)/A?20000: ??b-1) wherein B is yellow Dmax, C is yellow Dmin; and A is an amount mol/m2 of the coupler of formula (I).Type: GrantFiled: November 9, 2006Date of Patent: September 16, 2008Assignee: FUJIFILM CorporationInventors: Hiroyuki Yoneyama, Akira Ikeda, Shin Soejima, Kiyoshi Takeuchi, Naoto Matsuda
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Patent number: 7279271Abstract: The present invention provides a color material and a silver halide color photographic light-sensitive material, particularly, a color material and a silver halide color photographic light-sensitive material which are excellent in a coloring capability, processing stability, dye image fastness and a white background.Type: GrantFiled: March 25, 2003Date of Patent: October 9, 2007Assignee: Konica Minolta Photo Imaging Inc.Inventor: Takeshi Hakii
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Patent number: 7244551Abstract: A silver halide color photosensitive material comprising a support and, superimposed thereon, a blue-sensitive layer unit, a green-sensitive layer unit and a red-sensitive layer unit, each of these light-sensitive layer units composed of at least one silver halide emulsion layer, together with at least one non-sensitive layer, wherein compound (A) is contained in at least one layer in the silver halide color photosensitive material, compound (A) being a compound capable of releasing compound (Ac1) by oxidation coupling reaction with a color developing agent, compound (Ac1) being a heterocyclic compound which when added, is capable of enhancing the sensitivity of the photosensitive material as compared with that exhibited when not added, provided that the heterocyclic ring of the heterocyclic compound has 1 or 2 hetero atoms.Type: GrantFiled: December 23, 2005Date of Patent: July 17, 2007Assignee: Fujifilm CorporationInventors: Junichiro Hosokawa, Naoharu Kiyoto, Ryoji Nishimura, Takashi Hoshimiya, Tadashi Inaba
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Patent number: 7189501Abstract: A silver halide color photographic photosensitive material that has, on a support, at least one yellow color-forming photosensitive silver halide emulsion layer, at least one magenta color-forming photosensitive silver halide emulsion layer, and at least one cyan color-forming photosensitive silver halide emulsion layer, wherein at least one specific yellow or magenta dye-forming coupler and at least one compound represented by formula (Ph) are contained in the same layer: wherein Rb1 represents a specific functional group; and Rb2 to Rb5 each independently represent a hydrogen or halogen atom, or a specific functional group.Type: GrantFiled: December 29, 2003Date of Patent: March 13, 2007Assignee: Fuji Photo Film Co., Ltd.Inventors: Toshiyuki Makuta, Hiroyuki Yoneyama, Nobuo Seto, Kiyoshi Takeuchi
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Patent number: 7175976Abstract: A silver halide color photographic light-sensitive material comprising at least one yellow color developable light-sensitive silver halide emulsion layer, at least one magenta color developable light-sensitive silver halide emulsion layer, and at least one cyan color developable light-sensitive silver halide emulsion layer, each of which is provided on a support: which comprises at least one yellow coupler of formula (I) and at least one cyan coupler of formula (A); wherein Q represents a group of non-metal atoms that form a 5- to 7-membered ring in combination with —N?C—N(R1)-, each of R1 and R2 represents a substituent, m represents an integer of 0 to 5, and X represents a hydrogen atom or a group capable of being split-off upon a coupling reaction; wherein R11 and R12 each represent an alkyl group or an aryl group, J represents an alkylene group, and X represents a hydrogen atom or a group that can split off upon a coupling reaction.Type: GrantFiled: October 21, 2004Date of Patent: February 13, 2007Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroyuki Yoneyama, Yasuaki Deguchi, Naoto Ohshima, Kiyoshi Takeuchi, Akira Ikeda, Naoto Matsuda
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Patent number: 7153639Abstract: Disclosed is a silver halide color photographic lightsensitive material comprising a support and, superimposed thereon, a blue-sensitive layer unit, a green-sensitive layer unit and a red-sensitive layer unit, each of these layers comprising at least two silver halide emulsion layers with different photographic speeds, together with at least one antihalation layer, wherein couplers capable of color formation are contained in a total coating amount of 0.02 mmol/m2 to 2 mmol/m2.Type: GrantFiled: December 5, 2002Date of Patent: December 26, 2006Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroshi Tamaoki, Yoichi Suga, Yoshio Ishii, Mitsuhiro Uchida
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Patent number: 7144691Abstract: A color photographic material which contains on a support at least one blue-sensitive silver halide emulsion layer containing at least one yellow coupler, at least one green-sensitive silver halide emulsion layer containing at least one magenta coupler, at least one red-sensitive silver halide emulsion layer containing at least one cyan coupler, together with customary non-light-sensitive layers, characterized in that at least one layer contains a compound of formula (I) or (II) wherein the R1-radicals and R2-radicals are preferably methyl; and wherein the compounds of formula (II) are preferably (III) R3 is a radical —CH(CH3)—X—D, wherein X is phenylene.Type: GrantFiled: February 25, 2003Date of Patent: December 5, 2006Assignee: Ciba Specialty Chemicals CorporationInventors: Stéphane Biry, Francesco Fuso, Andreas Kramer
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Patent number: 7115357Abstract: A silver halide color reversal photosensitive material comprising a blue-sensitive emulsion layer unit containing a yellow color-forming coupler, a green-sensitive emulsion layer unit containing a magenta color-forming coupler and a red-sensitive emulsion layer unit containing a cyan color-forming coupler, on a transparent support, wherein the material includes at least one interimage effect-donating layer substantially forms no image; the wavelength, ?rmax, at which the maximum sensitivity of the spectral sensitivity distribution of the red-sensitive layer unit is given, satisfies the relation: 620 nm??rmax?680 nm; and the sensitivities of the red-sensitive layer unit satisfy the following relationships: Sr(610) is ? of Sr(?rmax) or more; Sr(680) is 1/10 of Sr(?rmax) or more; and/or Sr(690) is 1/50 of Sr(?rmax) or more wherein Sr(610), Sr(680) and Sr(690) are the sensitivities of the red-sensitive unit at 610 nm, 680 nm and 690 nm, respectively, and Sr(?rmax) is the maximum sensitivity at ?rmax.Type: GrantFiled: April 20, 2004Date of Patent: October 3, 2006Assignee: Fuji Photo Film Co., Ltd.Inventors: Nobuyuki Haraguchi, Masayuki Kuramitsu, Naoto Matsuda
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Patent number: 7108963Abstract: A photographic element comprises a silver halide emulsion layer having associated therewith a dye forming coupler and a combination of a carbonamide compound, a phenolic compound, and an electron-rich compound. Such a combination provides improved dye stability.Type: GrantFiled: April 6, 2005Date of Patent: September 19, 2006Assignee: Eastman Kodak CompanyInventors: Albert J. Mura, Jr., Gary M. Russo, Shari L. Eiff, Brian Thomas
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Patent number: 7090969Abstract: A photographic element comprises a silver halide emulsion layer having associated therewith a dye forming coupler and a compound of the following Formula I1: wherein L is a linking moiety; X is a heteroatom group selected from O, S, or NR? where R? is H or a substituent; w is 0 or 1; R is hydrogen or a substituent group; n is an integer from 0 to 5; and ST represents a stabilizer selected from the group consisting of: A. a thiomorpholine dioxide; B. a dialkoxy aromatic group linked through a phenolic oxygen; C. a dialkoxy aromatic group linked through the aromatic ring; D. a sulfonamido group; E. a hydroxyphenyl benzotriazole group; and F. a phenolic group.Type: GrantFiled: March 15, 2005Date of Patent: August 15, 2006Assignee: Eastman Kodak CompanyInventors: Albert J. Mura, Shari L. Eiff, Gary M. Russo
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Patent number: 6927020Abstract: A silver halide color photographic material is disclosed, comprising on a support a silver halide emulsion layer comprising an yellow dye forming coupler represented by formula (I): A—B??formula (I) wherein A is represented by formula (Ia), (Ia?), (Ia?), (Ib), (Ic), (Id), (Id?), (Ie), (Ie?), (Ie?), (If) or (If?); and B is represented by formula (II) described in the specification.Type: GrantFiled: February 5, 2004Date of Patent: August 9, 2005Assignee: Konica Minolta Holdings, Inc.Inventors: Rie Sakuragi, Satoru Ikesu, Takatugu Suzuki
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Patent number: 6887657Abstract: A silver halide color photographic photosensitive material, which containes at least one specific compound containing at least one alkenylcarbonyl group, in at least one layer on a support; and an image-forming method using the same.Type: GrantFiled: May 11, 2004Date of Patent: May 3, 2005Assignee: Fuji Photo Film Co., Ltd.Inventors: Nobuo Seto, Toshiyuki Makuta, Hidekazu Sakai, Hiroyuki Yoneyama, Tomonori Ichinose
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Publication number: 20040161713Abstract: Disclosed is a silver halide color photographic lightsensitive material comprising a support and, superimposed thereon, a blue-sensitive layer unit, a green-sensitive layer unit and a red-sensitive layer unit, each of these layers comprising at least two silver halide emulsion layers with different photographic speeds, together with at least one antihalation layer, wherein couplers capable of color formation are contained in a total coating amount of 0.02 mmol/m2 to 2 mmol/m2.Type: ApplicationFiled: August 19, 2003Publication date: August 19, 2004Inventors: Hiroshi Tamaoki, Yoichi Suga, Yoshio Ishii, Mitsuhiro Uchida
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Publication number: 20040157173Abstract: A silver halide color photographic material is disclosed, comprising on a support a silver halide emulsion layer comprising an yellow dye forming coupler represented by formula (I):Type: ApplicationFiled: February 5, 2004Publication date: August 12, 2004Applicant: KONICA MINOLTA HOLDINGS, INC.Inventors: Rie Sakuragi, Satoru Ikesu, Takatugu Suzuki
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Dye-forming coupler, silver halide photographic light-sensitive material and azomethine dye compound
Publication number: 20040096787Abstract: A dye-forming coupler of formula (I), a silver halide photographic light-sensitive material containing the coupler, and an azomethine dye that can be derived from the dye-forming coupler: 1Type: ApplicationFiled: October 7, 2003Publication date: May 20, 2004Applicant: Fuji Photo Film Co., Ltd.Inventors: Kiyoshi Takeuchi, Shigeki Uehira, Mario Aoki -
Publication number: 20040091825Abstract: A silver halide color photographic light-sensitive material comprising at least one yellow color developable light-sensitive silver halide emulsion layer, at least one magenta color developable light-sensitive silver halide emulsion layer, and at least one cyan color developable light-sensitive silver halide emulsion layer, each of which is provided on a support: which comprises at least one yellow coupler of formula (I) and at least one cyan coupler of formula (A); 1Type: ApplicationFiled: February 26, 2003Publication date: May 13, 2004Applicant: FUJI PHOTO FILM CO., LTD.Inventors: Hiroyuki Yoneyama, Yasuaki Deguchi, Naoto Ohshima, Kiyoshi Takeuchi, Akira Ikeda, Naoto Matsuda
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Dye-forming coupler, silver halide photographic light-sensitive material and azomethine dye compound
Patent number: 6727053Abstract: A dye-forming coupler of formula (I), a silver halide photographic light-sensitive material containing the coupler, and an azomethine dye that can be derived from the dye-forming coupler: wherein Q is a group —C(—R11)═C(—R12)—SO2—; R11 and R12 bond with each other to form, together with the —C═C— moiety, a 5- to 7-membered ring, or they each represent a hydrogen atom or a substituent; R1, R3 and R4 each represent a substituent; m is an integer of 0 to 4; and X represents a hydrogen atom or a group that splits off upon a coupling reaction with an oxidized product of a developing agent; with the proviso that the following compound (I-A) is excluded from the dye-forming coupler of formula (I).Type: GrantFiled: March 27, 2002Date of Patent: April 27, 2004Assignee: Fuji Photo Film Co., Ltd.Inventors: Kiyoshi Takeuchi, Shigeki Uehira, Mario Aoki, Jun Ogasawara, Yasuhiro Shimada, Seiji Ichijima, Yasuaki Deguchi, Naoto Matsuda, Akira Ikeda, Hisashi Mikoshiba, Masaharu Sugai, Taiji Katsumata -
Publication number: 20040058284Abstract: A silver halide color photographic light-sensitive material, having at least one each of blue-, green-, and red-sensitive emulsion layers containing yellow, magenta, and cyan couplers, respectively, on a support;Type: ApplicationFiled: February 28, 2003Publication date: March 25, 2004Applicant: FUJI PHOTO FILM CO., LTD.Inventors: Hiroyuki Yoneyama, Akira Ikeda, Shin Soejima, Kiyoshi Takeuchi, Naoto Matsuda
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Patent number: 6677110Abstract: A dye-forming coupler of formula (I): wherein Q represents a residue that forms, together with —N—C═N—, a nitrogen-containing 6-membered ring; RA represents an aryl, heterocyclic, or —(R1)r—(R4)m group; X represents an aryl group; Y represents a hydrogen atom, or a group capable of being split-off upon a coupling reaction with an oxidized product of a developing agent: wherein, when RA represents an —(R1)r—(R4)m group, R1 represents a methylene group, a methine group, or a carbon atom; r is 1 to 30; R4 represents a substituent except for a hydrogen atom; m is 1 to 30; and the —(R1)r—(R4)m group does not represent a straight-chain alkyl group. A silver halide photographic light-sensitive material which contains at least one of the coupler. An azomethine dye compound derived from the coupler.Type: GrantFiled: March 27, 2002Date of Patent: January 13, 2004Assignee: Fuji Photo Film Co., Ltd.Inventors: Kiyoshi Takeuchi, Shigeki Uehira, Mario Aoki
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Patent number: 6660465Abstract: A compound represented by the following formula (I) to (VII): In the formulas, R1 represents an acyl group, cyano group, nitro group, aryl group, heterocyclic residue, alkoxycarbonyl group, aryloxycarbonyl group, carbamoyl group, sulfamoyl group, alkylsulfonyl group, or arylsulfonyl group, which may be substituted, or a cyano or nitro group; R2 represents an alkyl group, aryl group or heterocyclic residue, which may be substituted; R3 represents an aryl group or heterocyclic residue, each of which may be substituted; R4, R6 and R9 represent a substituent; R5, R7 and R8 represent a hydrogen atom or substituent; n represents an integer of 0 to 2, wherein when n is 2, a plurality of R4's may be the same or different; L represents a divalent linking group; and k represents an integer of 0 or more, wherein when k is 2 or more, a plurality of L's may be the same or different.Type: GrantFiled: May 30, 2002Date of Patent: December 9, 2003Assignee: Fuji Photo Film Co., Ltd.Inventors: Shigeki Uehira, Kiyoshi Takeuchi
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Patent number: 6653061Abstract: The invention relates to a photographic label comprising a pragmatic polymer sheet, at least one layer comprising at least one image forming layer comprising photosensitive silver halide grains and dye forming coupler above said pragmatic polymer sheet, wherein said at least one image forming layer has an exposure time to obtain a usable Dmax of 1.5 of less than 0.01 seconds, wherein said at least one image forming layer is substantially free of image dye stabilizers, and wherein said polymer sheet has an L* of greater than 95.Type: GrantFiled: December 21, 2001Date of Patent: November 25, 2003Assignee: Eastman Kodak CompanyInventors: John B. Rieger, Robert P. Bourdelais
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Patent number: 6649329Abstract: The present application relates to a photothermographic material comprising, on a side of a support, (a) a photosensitive silver halide, (b) a reducible silver salt, (c) a phenol derivative having the specific structure as reducing compound, (d) a binder, (e) a coupler compound, and (f) a compound represented by Q1—NHNH—V6 wherein Q1 is a 5- to 7-membered unsaturated ring and V6 is a carbamoyl group, etc.Type: GrantFiled: August 3, 2001Date of Patent: November 18, 2003Assignee: Fuji Photo Film Co., Ltd.Inventors: Toyohisa Oya, Kazunobu Katoh
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Patent number: 6641988Abstract: A photographic element is disclosed, comprising a yellow dye forming coupler, a magenta dye forming coupler and a cyan dye forming coupler, wherein spectral reflection absorption characteristics of a yellow dye, a magenta dye and a cyan dye which are formed of the yellow dye forming coupler, the magenta dye forming coupler and the cyan dye forming coupler, respectively, meet the following requirements: 110≧&lgr;max(M)−&lgr;max(Y)≧95, 80≧&lgr;max(C)−&lgr;max(M)≧70, 0.43≧Abs600(M)≧0.38, and 0.48≧Abs550(C)≧0.35.Type: GrantFiled: January 31, 2002Date of Patent: November 4, 2003Assignee: Konica CorporationInventor: Takeshi Hakii
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Patent number: 6620580Abstract: Disclosed is a photographic element comprising a support bearing a blue light sensitive record containing at least three layers having different levels of light sensitivity arranged in the order slowest to fastest with the slowest layer closest to the support and the fastest layer closest to the light exposure source, wherein (a) all of the blue-sensitive layers are closer to the light exposure source than the layers sensitive to any other color; (b) the slowest blue light sensitive layer is at least 1.0 log E slower than the next fastest blue light sensitive layer when measured at a density of 0.15 above Dmin, and contains a particular type of cyan dye-forming development inhibitor releasing (DIR) coupler; and (c) all of the blue light sensitive layers other than the slowest blue light sensitive layer independently contain a certain type of yellow dye-forming DIR coupler. Embodiments of the invention provide improved color rendition without sacrificing blue density.Type: GrantFiled: November 14, 2001Date of Patent: September 16, 2003Assignee: Eastman Kodak CompanyInventors: Norma B. Platt, Drake M. Michno
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Publication number: 20030170574Abstract: The invention relates to a photographic label comprising a pragmatic polymer sheet, at least one layer comprising at least one image forming layer comprising photosensitive silver halide grains and dye forming coupler above said pragmatic polymer sheet, wherein said at least one image forming layer has an exposure time to obtain a usable Dmax of 1.5 of less than 0.01 seconds, wherein said at least one image forming layer is substantially free of image dye stabilizers, and wherein said polymer sheet has an L* of greater than 95.Type: ApplicationFiled: December 21, 2001Publication date: September 11, 2003Applicant: Eastman Kodak CompanyInventors: John B. Rieger, Robert P. Bourdelais
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Patent number: 6610466Abstract: A silver halide photographic lightsensitive material comprising at least one silver halide photographic emulsion layer containing a silver halide photographic emulsion prepared by mixing a dispersion of silver halide grains, the silver halide grains exhibiting such spectral absorption maximum wavelength and light absorption intensity that, when the spectral absorption maximum wavelength is less than 500 nm, the light absorption intensity is 60 or more, while when the spectral absorption maximum wavelength is 500 nm or more, the light absorption intensity is 100 or more, with an emulsified dispersion, wherein the silver halide photographic emulsion, when agitated at 40° C. for 30 min, exhibits a variation of absorption spectrum integrated intensity ranging from 400 nm to 700 nm of 10% or less.Type: GrantFiled: August 28, 2001Date of Patent: August 26, 2003Assignee: Fuji Photo Film Co., Ltd.Inventors: Masami Sakurada, Kiyoshi Morimoto, Fumitaka Ueda, Toru Yamada
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Patent number: 6602777Abstract: The present invention relates to a method for controlling the formation of the intermetallic compounds in solder joints, The types of the intermetallic compounds between the SnAgCu solders and the Ni-bearing substrate can be controlled by adjusting the copper concentration in the SnAgCu solders. If the SnAgCu solder has a copper concentration higher than or equivalent to 0.6 wt. %, the soldering intermetallic compound includes a continuous (Cu1−xNix)6Sn5 layer. If the copper concentration of the SnAgCu solders is lower than or equivalent to 0.4 wt. %, the soldering intermetallic compound includes a continuous (Ni1−yCuy)3Sn4 layer and a non-continuous (Cu1−xNix)6Sn5 layer. If the copper concentration of the SnAgCu solders is between 0.4 wt. % to 0.6 wt. %, the soldering intermetallic compound includes the continuous (Cu1−xNix)6Sn5.Type: GrantFiled: March 20, 2002Date of Patent: August 5, 2003Assignee: National Central UniversityInventors: Cheng-Heng Kao, Cheng-En Ho
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Patent number: 6593069Abstract: A photothermographic material comprising at least (a) a photosensitive silver halide, (b) a reducible silver salt, (c) a reducing compound represented by the following formula (1) or (2), (d) a binder and (e) a coupler compound on the same side of a support: wherein, in the formula (1), V1 to V4 each independently represent hydrogen atom or a substituent, and V5 represents a substituted or unsubstituted alkyl group, aryl group or heterocyclic group: Q1—NHNH—V6 (2) wherein, in the formula (2), Q1 represents a 5- to 7-membered unsaturated ring bonding to NHNH—V6 at a carbon atom, and V6 represents a carbamoyl group, an acyl group, an alkoxycarbonyl group, an aryloxycarbonyl group, a sulfonyl group or a sulfamoyl group.Type: GrantFiled: March 16, 2001Date of Patent: July 15, 2003Assignee: Fuji Photo Film Co., Ltd.Inventors: Toyohisa Oya, Kazunobu Katoh, Shigeo Hirano
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Publication number: 20030104324Abstract: A compound represented by the following formula (I) to (VII): 1Type: ApplicationFiled: May 30, 2002Publication date: June 5, 2003Applicant: FUJI PHOTO FILM CO., LTD.Inventors: Shigeki Uehira, Kiyoshi Takeuchi
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Patent number: 6569612Abstract: A color photographic element is disclosed comprising at least three light-sensitive units which have their individual sensitivities in different wavelength regions, comprising at least one imaging layer comprising a light-sensitive silver-halide emulsion, binder, and a yellow coupler represented by the following structure: Wherein COUP is a photographic coupler residue capable of coupling with oxidized color developer to form a first yellow dye L is a linking group selected from the group consisting of —OC(═O)—, —OC(═S)—, —SC(═O)—, and —SC(═S)—, and —DYE is a releasable second yellow dye or yellow dye precursor, wherein COUP is an acetanilide compound that contains one or more electron-withdrawing groups such that the pKa at the coupling site is less than 8.7. Such yellow couplers improve activity and enhance dye densities.Type: GrantFiled: August 30, 2001Date of Patent: May 27, 2003Assignee: Eastman Kodak CompanyInventors: Lelia Cosimbescu, Jared B. Mooberry, David T. Southby, Louis E. Friedrich
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Patent number: 6555306Abstract: Photographic elements are disclosed comprising a silver halide emulsion layer having associated therewith a dye forming coupler and a compound of the following Formula I: wherein n=0-6 and each R is independently hydrogen, an aromatic, cyclic, linear or branched chain hydrocarbon group, NR′R″, or OR′; where R′ is an aromatic, cyclic, linear or branched chain hydrocarbon group and R″ is hydrogen or an aromatic, cyclic, linear or branched chain hydrocarbon group. Photographic elements of the present invention upon exposure and photographic processing exhibit good activity and yield dye images that have unexpected and substantial improvements in the stability of the formed image dyes.Type: GrantFiled: December 21, 2001Date of Patent: April 29, 2003Assignee: Eastman Kodak CompanyInventors: J. Ramon Vargas, Gary M. Russo
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Dye-forming coupler, silver halide photographic light-sensitive material and azomethine dye compound
Publication number: 20030073047Abstract: A dye-forming coupler of formula (I), a silver halide photographic light-sensitive material containing the coupler, and an azomethine dye that can be derived from the dye-forming coupler: 1Type: ApplicationFiled: March 27, 2002Publication date: April 17, 2003Inventors: Kiyoshi Takeuchi, Shigeki Uehira, Mario Aoki, Jun Ogasawara, Yasuhiro Shimada, Seiji Ichijima, Yasuaki Deguchi, Naoto Matsuda, Akira Ikeda, Hisashi Mikoshiba, Masahara Sugai, Taiji Katsumata -
Patent number: 6548238Abstract: The stability of the dyes which are obtained after processing a color photographic material is improved by the addition of a polyvinylcaprolactam.Type: GrantFiled: July 20, 2001Date of Patent: April 15, 2003Assignee: AGFA-GevaertInventors: Beate Weber, Bernd Spachmann, Heinz Wiesen
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Publication number: 20030064331Abstract: A color photographic silver halide material which can be developed to form a negative, at least 95 mol % of the silver halides of which consist of AgCl, and which contains at least one light-sensitive silver halide emulsion layer, the silver halide of which contains at least one compound of formulae (I), (II) and (III):Type: ApplicationFiled: November 5, 2001Publication date: April 3, 2003Inventors: Cuong Ly, Edgar Draber, Matthias Feigl, Gunter Helling, Thomas Kaluschke, Michael Missfeldt, Maria Nietgen, Heinz-Horst Teitscheid, Ralf Weimann, Heinz Wiesen
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Patent number: 6531269Abstract: A color photographic silver halide material, which has a support which comprises at least one blue-sensitive, yellow-coupling silver halide emulsion layer nearest the light source and at least one green-sensitive, magenta-coupling silver halide emulsion layer and at least one red-sensitive, cyan-coupling silver halide emulsion layer which are further from the light source than is the at least one blue-sensitive layer, and which contains at least one cyan masking coupler which has its maximum absorption above 650 mn, the red-sensitive layers have their maximum sensitivity at 620±20 nm and the absorption of the masking coupler at the maximum sensitivity of the red-sensitive layers is at most 70% of its absorption at 690 mn, is distinguished by improved color reproduction and color saturation in the magenta layer without loss of sensitivity.Type: GrantFiled: March 12, 2001Date of Patent: March 11, 2003Assignee: Agfa-Gevaert N.V.Inventors: Ralf Wirowski, Jan Haller, Stefan Herrmann, Jürgen Jung
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Patent number: 6518006Abstract: The present invention provides a silver halide color photographic photosensitive material having superior image sharpness and film strength. Disclosed is a silver halide color photographic photosensitive material in which a yellow-developing photosensitive silver halide emulsion layer on a support contains at least one dye-forming coupler represented by the following general formula (Y-1), and at least one layer of the non-photosensitive hydrophilic colloid layers on the support contains a dispersion of solid particles of a dye represented by the following general formula [I]. In the general formula (Y-1), Y represents a nitrogen-containing heterocycle; Z represents a substituted aryl group; X represents a hydrogen atom, or a group that leaves by the reaction with an oxidized form of a developing solution. In the general formula [I], D represents a residue of a compound having a chromophoric group; X represents a dissociative hydrogen atom or a group having a dissociative hydrogen atom.Type: GrantFiled: March 12, 2001Date of Patent: February 11, 2003Assignee: Fuji Photo Film Co., Ltd.Inventors: Hidekazu Sakai, Yasuhiro Shimada
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Publication number: 20020187443Abstract: A photographic element is disclosed, comprising a yellow dye forming coupler, a magenta dye forming coupler and a cyan dye forming coupler, wherein spectral reflection absorption characteristics of a yellow dye, a magenta dye and a cyan dye which are formed of the yellow dye forming coupler, the magenta dye forming coupler and the cyan dye forming coupler, respectively, meet the following requirements:Type: ApplicationFiled: January 31, 2002Publication date: December 12, 2002Inventor: Takeshi Hakii
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Publication number: 20020172900Abstract: A color photographic silver halide material having a support, which material comprises at last one blue-sensitive, yellow-coupling silver halide emulsion layer and at least one geen-sensitive, magenta-coupling silver halide emulsion layer and at least one red-sensitive, cyan-coupling silver halide emulsion layer, and which contains at least one masking coupler which has two chromophores which absorb in the wavelength range from 420 to 750 nm and are eliminable or decolorisable by coupling with the developer oxidation product, is distinguished by improved sensitivity associated with undiminished color purity.Type: ApplicationFiled: January 10, 2002Publication date: November 21, 2002Inventors: Jan Haller, Ralf Wirowski
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Patent number: 6479225Abstract: A silver halide photographic element for forming a sepia image comprising a support and an image forming layer which contains a cyan dye forming coupler, a magenta dye forming coupler and a yellow dye forming coupler, wherein the support has CIELAB a* and b* values within the following ranges at L*>90:0<b*<6.0, 0<a*<1.Type: GrantFiled: July 30, 2001Date of Patent: November 12, 2002Assignee: Eastman Kodak CompanyInventors: David J. Valvo, Kurt M. Schroeder, Michael R. Roberts
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Patent number: 6458521Abstract: The invention provides a color photographic element that contains a coupler useful for forming a neutral silver-based image. Such couplers are particularly useful to provide an auxiliary silver-based image for optically recording a sound track in color motion picture films.Type: GrantFiled: November 14, 2000Date of Patent: October 1, 2002Assignee: Eastman Kodak CompanyInventors: Philip T. Lau, Stephen P. Singer, Janet N. Younathan, Jerrold N. Poslusny, Susan D. Hill, Anabisdally I. Bodden
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Patent number: 6455241Abstract: Disclosed is a photographic element comprising a light sensitive silver halide emulsion layer having associated therewith a coupler represented by formula F-1, wherein: R1, R3 and R5 are independently selected from hydrogen or a substituent group and two of them may join to form a ring; X is hydrogen or a coupling-off group, B is hydrogen or a substituent group; Z is a substituent group, and n varies from 0-4. The element exhibits improved dye-forming activity and an improved combination of dye hue and dye stability.Type: GrantFiled: April 27, 2001Date of Patent: September 24, 2002Assignee: Eastman Kodak CompanyInventors: Thomas R. Welter, Frank D. Coms
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Patent number: 6444412Abstract: The invention relates to a photographic element comprising a light sensitive silver halide emulsion layer having associated therewith one or more dye-forming couplers and a stabilizer compound of formula (I): wherein R1 and R2 are independently selected from hydrogen or an unsubstituted or substituted alkyl, aryl, alkoxy, aryloxy or amino group or may combine to complete a 5-10 membered heterocyclic ring which may contain in addition to the silicon atom one or more heteroatoms selected from nitrogen, oxygen and sulfur, which ring is unsubstituted or substituted; each Z independently represents the atoms necessary to complete a substituted or unsubstituted arene or heteroaromatic ring system; X is a single bond or a linking group having a single atom which connects the arene rings or heteroaromatic ring systems; or X forms, together with substituents ortho to X on the arene rings or heteroaromatic ring systems, a fused unsubstituted or substituted 5-, 6- or 7-membered ring, which may contType: GrantFiled: August 21, 2001Date of Patent: September 3, 2002Assignee: Eastman Kodak CompanyInventors: David Clarke, Llewellyn J. Leyshon, Christopher P. Moore
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Patent number: 6426178Abstract: The invention relates to a photographic element for forming neutral images comprising a cyan dye-forming coupler, a magenta dye-forming coupler of formula wherein Ra and Rb represents H or a substituent; X is hydrogen or a coupling-off group; Za, Zb, and Zc are a substituted methine group, ═N—, ═C—, or —NH—; and yellow dye-forming coupler of formula, wherein R5 is an alkoxy group with more than one carbon atom, aryloxy, anilino, arylthio, alkylthio, or dialkylamino groups linked to the anilide phenyl ring by oxygen, sulfur or nitrogen; R6 is selected from hydrogen, halogen, alkoxycarbonyl(—CO2R), carbamoyl(—CONRR′), carbonamido(—NRCOR′), sulfonate(—OSO2R), sulfamoyl (—SO2NRR′), sulfonamido(—NRSO2R′), or sulfonyl(—SO2R); R and R′ may be hydrogen, alkyl or aryl groups; q is 1 to 4; R7 is alkyl, cyclic, or multicyclic alky, aryl, heterocyclic, heteroaromatic, andType: GrantFiled: August 7, 2000Date of Patent: July 30, 2002Assignee: Eastman Kodak CompanyInventors: Michael R. Roberts, Kurt M. Schroeder, Frank D. Coms
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Publication number: 20020098449Abstract: A photothermographic material comprising at least (a) a photosensitive silver halide, (b) a reducible silver salt, (c) a reducing compound represented by the following formula (1) or (2), (d) a binder and (e) a coupler compound on the same side of a support: 1Type: ApplicationFiled: March 16, 2001Publication date: July 25, 2002Inventors: Toyohisa Oya, Kazunobu Katoh, Shigeo Hirano
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Patent number: 6416941Abstract: A color photographic element comprises a support and at least one dye image forming layer unit comprising gelatin-peptized radiation-sensitive silver halide grains, a fragmentable electron donating compound; and an electron transfer agent releasing compound.Type: GrantFiled: December 20, 1999Date of Patent: July 9, 2002Assignee: Eastman Kodak CompanyInventors: Kenneth J. Reed, Annabel A. Muenter, Sharon R. Lunt, David T. Southby
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Patent number: 6416943Abstract: The invention provides a color photographic element suitable for forming both a colored dye image and a neutral silver-based image, comprising a support bearing at least one light-sensitive silver halide emulsion layer containing a coupler capable of forming a colored dye upon development, and bearing a further light-sensitive silver halide emulsion layer containing a coupler which is capable of releasing a thiovinyl group upon development that is capable of reacting to form a neutral silver-based image.Type: GrantFiled: November 14, 2000Date of Patent: July 9, 2002Assignee: Eastman Kodak CompanyInventors: Robert F. Romanet, Susan D. Hill, Stephen P. Singer, Anabisdally I. Bodden