Achromatic Image Forming Organic Compound Patents (Class 430/565)
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Publication number: 20080206688Abstract: Incorporation of certain compounds into photothermographic materials provides materials with reduced initial image Dmin and improved Raw Stock Keeping film stability without unacceptable loss in sensitometric properties. These compounds include certain e-i) zinc salts of an aryl sulfonic acid or of a fluorinated C2-C6 carboxylic acid, e-ii) non-encapsulated alkali metal salts of an aryl sulfonic acid or of a fluorinated C2-C6 carboxylic acid, and e-iii) fluorinated C2-C6 carboxylic acids.Type: ApplicationFiled: February 26, 2007Publication date: August 28, 2008Inventors: Kui Chen-Ho, William D. Ramsden
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Patent number: 7323294Abstract: A color photographic material is disclosed comprising a black image forming coupler substituted in the 2, 4 and/or 6 position shown by formula (I) or formula (II), where in LINK represents a divalent linking group, BALL represents a group that prevents the coupler from diffusing away from the layer containing it. X and Y each represent a hydrogen atom or a coupling-off group capable of being released upon an oxidative coupling reaction with a developing agent. The material has a good color reproduction and excellent light stability.Type: GrantFiled: October 11, 2005Date of Patent: January 29, 2008Assignee: Fuji Photo Film Co., Ltd.Inventors: Huibert Albertus van Boxtel, Akira Kase, Yasuo Iwasa, Yuzo Toda
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Publication number: 20020098449Abstract: A photothermographic material comprising at least (a) a photosensitive silver halide, (b) a reducible silver salt, (c) a reducing compound represented by the following formula (1) or (2), (d) a binder and (e) a coupler compound on the same side of a support: 1Type: ApplicationFiled: March 16, 2001Publication date: July 25, 2002Inventors: Toyohisa Oya, Kazunobu Katoh, Shigeo Hirano
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Patent number: 6368759Abstract: The invention relates to an imaging element comprising a transparent polymer sheet, and at least one photosensitive dye forming coupler containing layer is on each side of said transparent sheet, wherein there are at least four separate photosensitive layers and the photosensitive layers comprise at least four dye forming couplers that form at least four spectrally distinct colors, and wherein said imaging element is adhered to a transmissive polymer sheet that has a spectral transmissiveness of greater than 15 and less than 90%.Type: GrantFiled: September 18, 2000Date of Patent: April 9, 2002Assignee: Eastman Kodak CompanyInventors: Robert P. Bourdelais, Peter T. Aylward, Alphonse D. Camp, James L. Edwards
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Patent number: 6303282Abstract: The present invention discloses a color photographic photosensitive material for heat development, which material is characterized in that the color photographic photosensitive material produces superior discrimination with reduced color muddiness in rapid processing. The color photographic photosensitive material for heat development of the present invention comprises a support having thereon a photosensitive silver halide, a binder, a dye-releasable compound, a compound represented by the general formula (I) or (II), and a compound represented by the general formula (III) or (IV).Type: GrantFiled: December 15, 1999Date of Patent: October 16, 2001Assignee: Fuji Photo Film Co., Ltd.Inventors: Hideaki Naruse, Toshio Kawagishi, Takeshi Shibata
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Patent number: 6013428Abstract: A colour photographic recording material having at least one red-sensitive silver halide emulsion layer which is associated with a cyan coupler, at least one green-sensitive silver halide emulsion layer which is associated with a magenta coupler, at least one blue-sensitive silver halide emulsion layer which is associated with a yellow coupler contains in at least one green-sensitive silver halide emulsion layer a 2-equivalent pyrazolone coupler and in a photosensitive or non-photosensitive layer a white coupler of the formula (I) ##STR1## in which X.sup.1 means an acyl residue derived from an aliphatic, cycloaliphatic or aromatic carboxylic or sulphonic acid, a carbonic acid semi-ester or a carbamic acid,Z means the residue required to complete a saturated or partially unsaturated 5- or 6-membered carbocyclic ring which is optionally substituted and/or provided with a further fused ring or ring system.Type: GrantFiled: July 11, 1997Date of Patent: January 11, 2000Assignee: Agfa-Gevaert AGInventors: Hans Langen, Heinrich Odenwalder, Uwe Dahlhaus
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Patent number: 5989801Abstract: The present invention provides a silver halide photographic material and an image forming method for obtaining a monochrome image using a dye image even if it is treated with a color developer free of benzyl alcohol; a photographic property of the monochrome image is less deteriorated by a toxic gas such as formaldehyde and an increase in sensitization and fog with time is improved.Type: GrantFiled: August 26, 1998Date of Patent: November 23, 1999Assignee: Oriental Photo Industrial Co., Ltd.Inventors: Toshio Hirosawa, Kouji Katsube, Toshiko Nakamura, Yoshiro Hayafuchi, Katsuyuki Arasawa
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Patent number: 5885760Abstract: A color photographic recording material having at least one silver halide emulsion layer unit containing color coupler, which unit comprises at least two adjacent silver halide emulsion partial layers of the spectral sensitivity concerned, one of which is more sensitive and one less sensitive, contains in a reactive association with at least one more sensitive silver halide emulsion partial layer having a comparatively low color coupler content relative to the silver halide content, a compound (or a precursor compound thereof), which is capable under chromogenic development conditions of forming a substantially colorless, diffusible coupling product with the color developer oxidation product, which coupling product is capable under chromogenic development conditions in the presence of an oxidising agent of forming a dye with a color coupler, with transfer of the residue originating from the color developer.On chromogenic development, color images having improved grain are obtained.Type: GrantFiled: August 5, 1997Date of Patent: March 23, 1999Assignee: Agfa-Gevaert AGInventors: Peter Bergthaller, Jurgen Strobach
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Patent number: 5874206Abstract: A silver halide photographic light sensitive material is disclosed, comprising a support having thereon a silver halide emulsion layer, wherein the silver halide emulsion layer contains tabular silver halide grains having an average iodide content of 1.Type: GrantFiled: March 27, 1997Date of Patent: February 23, 1999Assignee: Konica CorporationInventors: Yoko Kimura, Taketoshi Yamada, Norio Miura
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Patent number: 5871893Abstract: A silver halide photographic light-sensitive material is disclosed. The light-sensitive material comprises a transparent support having thereon a hydrophilic colloid layer comprising a silver halide emulsion layer and an electric conductive layer, in which the electric conductive layer contains colloidal particles of a kind of metal oxide and at least one layer of the hydrophilic colloid layer contains a leucocompound of a blue dye.Type: GrantFiled: July 25, 1997Date of Patent: February 16, 1999Assignee: Konica CorporationInventor: Tsuyoshi Mitsuhashi
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Patent number: 5856072Abstract: A color photographic element which comprises a light sensitive silver halide emulsion layer and a non-light sensitive interlayer containing a ballasted 5-carbamoyl-1,3-dihydroxybenzene compound. The element exhibits an improved ability to prevent oxidized developer from diffusing away from the imaging layer in which it formed and into other color records where it can form the wrong color dye.Type: GrantFiled: June 2, 1997Date of Patent: January 5, 1999Assignee: Eastman Kodak CompanyInventors: Ronald E. Leone, Stephen P. Singer
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Patent number: 5851751Abstract: A silver halide emulsion of average grain size 0.2 .mu.m or less comprising silver halide grains having a core and an outer shell, the core comprising at least 85 mol % of the total silver halide content of the grain and at least 50 mol % of the silver halide in the core being silver bromide, and the outer shell comprising silver halide of which greater than 50 mol % is silver chloride; the emulsion either containing no rhodium dopant, or containing rhodium dopant such that the concentration of said dopant is at least as great in the core as in the shell.Type: GrantFiled: January 21, 1997Date of Patent: December 22, 1998Assignee: Imation Corp.Inventors: Julian M. Wallis, Robert J. D. Nairne, Alexis Zinn-Warner
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Patent number: 5817452Abstract: A heat developable color light-sensitive material provided on a support, which is for use in an image forming process comprising using a dye fixing element provided on a support separate from the support for the light-sensitive material, superposing one on another, heat developing to form a diffusible dye in the light sensitive material, and transferring the diffusible dye to the dye fixing element to form an image, is disclosed.Type: GrantFiled: September 19, 1997Date of Patent: October 6, 1998Assignee: Fuji Photo Film Co., Ltd.Inventor: Tetsu Kamosaki
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Patent number: 5728511Abstract: A silver halide photographic material is provided which exhibits nearly equal sensitivities and gamma values with respect to yellow, magenta and cyan to form a black-and-white image of neutral black or sepia tone, even when it is processed with a color developer free from benzyl alcohol.The silver halide photographic material is made up of a substrate and at least one silver halide emulsion layer formed on the substrate. The silver chloride content of silver halide grains constituting the silver halide emulsion layer is 95 mole % or above, the silver halide emulsion is spectrally sensitized by a specific sensitizing dye, and the silver halide emulsion layer contains a yellow coupler, a magenta coupler and a cyan coupler. The image-forming process is characterized by developing the silver halide photographic material with a color developer substantially free from benzyl alcohol.Type: GrantFiled: March 5, 1997Date of Patent: March 17, 1998Assignee: Oriental Photo Industrial Co., Ltd.Inventors: Toshio Hirosawa, Kouji Katsube, Junichi Komiyama, Yoshiro Hayafuchi, Toshiko Nakamura
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Patent number: 5716773Abstract: Blue-black color favored in medical imaging is imparted to black and white photographic emulsions by the addition of a compound of formula I or II: ##STR1## wherein: R.sup.1 and R.sup.2 independently represent one or more carbon atoms necessary to complete a 5, 6 or 7 membered ring;R.sup.3 and R.sup.4 independently represent H, alkyl or aryl groups or together represent the atoms selected from C, N, O and S necessary to complete a 5, 6 or 7 membered cyclic ring but are not both H;R.sup.5 and R.sup.6 independently represent H or alkyl or together represent the atoms selected from C, N, O and S necessary to complete a 5, 6 or 7 membered ring;X represents a bond or a divalent linking group,each Y may be the same or different and is selected from S, Se, O, and NR.sup.7, where R.sup.7 is H or alkyl of up to 5 carbon atoms, andZ is S or Se.Type: GrantFiled: June 10, 1996Date of Patent: February 10, 1998Assignee: Minnesota Mining and Manufacturing CompanyInventors: Robert James Domett Nairne, Julian Mark Wallis, Alexis Sarah Zinn-Warner
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Patent number: 5599647Abstract: Toning agents are provided for use in thermographic and photothermographic materials, either on their own or in combination with at least one other toning agent, with improved compatibility with hydrophobic media as shown by reduced crystallization and reduced diffusion through the material, which properties enabling an improved imaging performance to be achieved and in particular a more neutral image tone after storage.Type: GrantFiled: June 20, 1996Date of Patent: February 4, 1997Assignee: Agfa-Gevaert N.V.Inventors: Geert Defieuw, Marcel Monbaliu, Jean-Marie Dewanckele
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Patent number: 5536629Abstract: The invention relates to a photographic element comprising a Formula I class yellow coupler comprising ##STR1## wherein R.sub.1 represents a substituent;X is hydrogen or a coupling-off group;Y represents an aryl group or a heterocyclic group;a Formula II class cyan coupler comprising ##STR2## wherein R.sub.2 represents a substituent;R.sub.3 represents a substituent;X represents a hydrogen or a coupling-off group;m is from 1-3; anda Formula III class magenta coupler comprising ##STR3## wherein R.sub.4 is a substituent;R.sub.5 is a substituent;X is hydrogen or a coupling-off group;and which provides a relative fixed upper scale contrast between 1.1 and 1.8.An alternative form of the invention relates to a photographic element comprising a Formula I class yellow coupler comprising ##STR4## wherein R.sub.1 represents a substituent;X is hydrogen or a coupling-off group;Y represents an aryl group or a heterocyclic group;a Formula IV class cyan coupler comprising ##STR5## wherein R.sub.Type: GrantFiled: October 31, 1995Date of Patent: July 16, 1996Assignee: Eastman Kodak CompanyInventors: Gary N. Barber, Patricia R. Greco, Mitchell J. Bogdanowicz, Elizabeth L. Kelly
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Patent number: 5491053Abstract: The invention relates to a photographic element comprising a Formula I class yellow coupler comprising ##STR1## wherein R.sub.1 represents a substituent;X is hydrogen or a coupling-off group;Y represents an aryl group or a heterocyclic group;a Formula II class cyan coupler comprising ##STR2## wherein R.sub.2 represents a substituent;R.sub.3 represents a substituent;X represents a hydrogen or a coupling-off group;m is from 1-3; anda Formula III class magenta coupler comprising ##STR3## wherein R.sub.4 is a substituent;R.sub.5 is a substituent;X is hydrogen or a coupling-off group;and which provides a relative fixed upper scale contrast between 1.1 and 1.8.An alternative form of the invention relates to a photographic element comprising a Formula I class yellow coupler comprising ##STR4## wherein R.sub.1 represents a substituent;X is hydrogen or a coupling-off group;Y represents an aryl group or a heterocyclic group;a Formula IV class cyan coupler comprising ##STR5## wherein R.sub.Type: GrantFiled: December 23, 1994Date of Patent: February 13, 1996Assignee: Eastman Kodak CompanyInventors: Gary N. Barber, Patricia R. Greco, Mitchell J. Bogdanowicz, Elizabeth L. Kelly
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Patent number: 5364747Abstract: The invention is accomplished by forming balanced cyan, magenta, and yellow coupler and emulsion mixes. There is at least one layer in which silver halide emulsion has been sensitized to blue light or silver halide emulsion sensitive to green light. Regardless of the color sensitivity of the silver halide layer that contains silver contains a mix of cyan, magenta, and yellow dye-forming couplers. Further, in order to have a black-and-white image that has a lightness such as observed by the human eye in a scene, it is preferred that the ratios of red sensitive emulsion to green sensitive emulsion to blue sensitive emulsion in the photographic element is about 2:3:1.Type: GrantFiled: November 25, 1992Date of Patent: November 15, 1994Assignee: Eastman Kodak CompanyInventors: James L. Edwards, Paul T. Hahm, Joseph E. LaBarca
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Patent number: 5362616Abstract: The invention is accomplished by forming balanced cyan, magenta, and yellow coupler and emulsion mixes. There is at least one layer in which silver halide emulsion has been sensitized to blue light or silver halide emulsion sensitive to green light. Regardless of the color sensitivity of the silver halide layer that contains silver contains a mix of cyan, magenta, and yellow dye-forming couplers. Further, in order to have a black-and-white image that has a lightness such as observed by the human eye in a scene, it is preferred that the ratios of red sensitive emulsion to green sensitive emulsion to blue sensitive emulsion in the photographic element is about 2:3:1.Type: GrantFiled: November 25, 1992Date of Patent: November 8, 1994Assignee: Eastman Kodak CompanyInventors: James L. Edwards, Paul T. Hahm, Mitchell J. Bogdanowicz, Joseph E. LaBarca
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Patent number: 5356760Abstract: A silver halide photographic light-sensitive material forming a black and white image is disclosed. The silver halide in the silver halide emulsion layer is silver chlorobromide having a silver chloride content of not less than 90 mol % and containing virtually no silver iodide; the emulsion layer contains a coupler selected from resorcinol-based dye-forming couplers and aminophenol-based dye-forming couplers, and gelatin in a coating weight of 1.0 to 1.5 g/m.sup.2. The silver halide photographic light-sensitive material is processed by color development to form a black and white image.Type: GrantFiled: February 11, 1993Date of Patent: October 18, 1994Assignee: Konica CorporationInventors: Mitsuhiro Okumura, Shigeo Tanaka
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Patent number: 5314790Abstract: Monocyclic and polycyclic azoles having the following formula modify the tone of a silver image formed from a fine grain radiation sensitive silver chlorobromide emulsion layer in which the silver chlorobromide grains have a mean equivalent circular diameter of less than 0.3 .mu.m. The azoles have the formula: ##STR1## wherein Z is --N.dbd. or --C(R.sup.5).dbd. where R.sup.5 is hydrogen, --NH.sub.2, aliphatic of 1 to 8 carbon atoms or aromatic of 1 to 8 carbon atoms;R.sup.4 is hydrogen, aliphatic of 1 to 8 carbon atoms or aromatic of 1 to 8 carbon atoms;R.sup.4 and R.sup.5 together complete a 5 or 6 membered heterocyclic nucleus containing 1 to 3 ring nitrogen atoms;L is a divalent aliphatic linking group containing 1 to 8 carbon atoms;T is an aliphatic terminal group containing 1 to 8 carbon atoms;m is 0 or 1;n is an integer of 1 to 4; andp is an integer of 2 to 4.Type: GrantFiled: June 3, 1992Date of Patent: May 24, 1994Assignee: Eastman Kodak CompanyInventors: Stephen A. Hershey, J. Ramon Vargas, Paul A. Burns
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Patent number: 5292627Abstract: Monocyclic and polycyclic azoles having the following formula modify the tone of a silver image formed from a fine grain radiation sensitive silver bromide or silver bromoiodide emulsion layer in which the silver bromide or silver bromoiodide grains have a mean equivalent circular diameter of less than 0.3 .mu.m. The azoles have the formula: ##STR1## wherein Z is --N.dbd. or --C(R.sup.5).dbd. where R.sup.5 is hydrogen, --NH.sub.2, aliphatic of 1 to 8 carbon atoms or aromatic of 1 to 8 carbon atoms;R.sup.4 is hydrogen, aliphatic of 1 to 8 carbon atoms or aromatic of 1 to 8 carbon atoms;R.sup.4 and R.sup.5 together complete a 5 or 6 membered heterocyclic nucleus containing 1 to 3 ring nitrogen atoms;L is a divalent aliphatic linking group containing 1 to 8 carbon atoms;T is an aliphatic terminal group containing 1 to 10 carbon atoms;m is 0 or 1;n is an integer of 1 to 4; andp is an integer of 2 to 4.Type: GrantFiled: June 3, 1992Date of Patent: March 8, 1994Assignee: Eastman Kodak CompanyInventors: Stephen A. Hershey, J. Ramon Vargas, Paul A. Burns
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Patent number: 5256519Abstract: Silver halide photographic elements which are capable of high contrast development and are especially useful in the field of graphic arts have incorporated therein a hydrazine compound which functions as a nucleator, an amino compound which functions as an incorporated booster, and a 2-substituted-4-hydroxy-1,3,3a,7-tetraazaindene which functions to inhibit pepper fog.Type: GrantFiled: March 2, 1992Date of Patent: October 26, 1993Assignee: Eastman Kodak CompanyInventor: Anthony Adin
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Patent number: 5185231Abstract: Certain fluoran dyes have been found to be effective reducing agents for silver ion in dry silver constructions. The fluoran dyes have the following structure: ##STR1## wherein: R.sup.1 represents methyl or n-butyl;R.sup.2 represents n-butyl or cyclohexyl;R.sup.3 represents hydrogen, methyl, or methoxy; andR.sup.4 represents ##STR2## where X represents halogen (preferably chlorine); and a binder.Type: GrantFiled: August 26, 1991Date of Patent: February 9, 1993Assignee: Minnesota Mining and Manufacturing CompanyInventor: David C. Weigel
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Patent number: 5141844Abstract: Photographic elements are described containing polymeric dye-forming couplers in which the polymer contains coupler moieties that upon reaction with oxidized color developing agent yield dyes of a least two different hues. In one embodiment a neutral dye is formed. In another embodiment a minor proportion of one coupler moiety is used to modify or current the spectral absorption characteristics of another coupler moiety.Type: GrantFiled: May 7, 1990Date of Patent: August 25, 1992Assignee: Eastman Kodak CompanyInventor: Philip T. S. Lau
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Patent number: 5087554Abstract: The invention provides stable dispersions of couplers and methods of their formation. The stable dispersions are formed by the use of a nonionic water soluble polymer in combination with an anionic surfactant having a sulfate or sulfonate head group and a hydrophobic group of 8 to 20 carbons. The preferred nonionic water soluble polymers are polyethyleneoxide and polyvinylpyrrolidene. It is preferred that the dispersions have a pH of between about 5 and 5.5.Type: GrantFiled: June 27, 1990Date of Patent: February 11, 1992Assignee: Eastman Kodak CompanyInventors: Krishnan Chari, James T. Beck
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Patent number: 4917995Abstract: A silver halide photographic material for obtaining silver images is described, comprising at least one silver halide emulsion layer on a support having a white reflection layer, wherein at least one compound represented by formula (I) is contained in at least one of the constituent layers: ##STR1## wherein X.sup.1 represents a divalent bonding group bonded by way of a hetero atom to a carbon atom; A represents a group capable of controlling the tone of silver images, which is bonded to X.sup.1 by way of the hetero atom of A; R.sup.1, R.sup.2 and R.sup.3 each represents a hydrogen atom or a group that can be substituted, in which R.sup.1 and R.sup.2, or R.sup.1 and R.sup.3 may further be bonded together to form a carbocyclic ring or a heterocyclic ring; Y represents: ##STR2## a cyano group or a nitro group, in which R.sup.4, R.sup.5, R.sup.6, R.sup.7 R.sup.Type: GrantFiled: June 28, 1988Date of Patent: April 17, 1990Assignee: Fuji Photo Film Co., Ltd.Inventors: Tetsuro Kojima, Tetsunori Matsushita, Ichizo Toya, Kazuhiko Takeuchi
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Patent number: 4865958Abstract: A photographic recording material is described which comprises a leuco dye which is capable of generating a blue tone in a developed silver image.Type: GrantFiled: August 18, 1988Date of Patent: September 12, 1989Assignee: Eastman Kodak CompanyInventors: Thomas I. Abbott, Robert E. Dickerson, Michael P. Youngblood
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Patent number: 4814827Abstract: A radiation-sensitive element for half tone color proofing adapted to be exposed by scanning with four independently modulated sources of radiation emitting at different wavelengths within the range 550 to 900 nm, the element comprising a substrate bearing at least four separate imaging media coated thereon, said imaging media including:(1) an imaging medium capable of forming a yellow image upon imagewise exposure and processing,(2) an imaging medium capable of forming a magenta image upon imagewise exposure and processing,(3) an imaging medium capable of forming a cyan image upon imagewise exposure and processing, and(4) an imaging medium capable of forming a black or a balancing black image upon imagewise exposure and processing,each imaging medium having a maximum spectral sensitivity at a wavelength different from that of the maximum sensitivity of the other imaging media such that after exposure and processing super-imposed yellow, magenta, cyan and black or balancing black images are formed, each imageType: GrantFiled: August 13, 1987Date of Patent: March 21, 1989Assignee: Minnesota Mining and Manufacturing CompanyInventors: Jonathan P. Kitchin, Stephen R. Powers, Keith A. Penfound, Peter J. Finn, Michael G. Fisher
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Patent number: 4728601Abstract: Tetra-aza indene compounds of the formula ##STR1## wherein R.sub.1 is alkyl or a ring system and R.sub.2 and R.sub.3 are hydrogen or alkyl.These compounds are of use as image toners in photographic materials.Type: GrantFiled: April 1, 1986Date of Patent: March 1, 1988Assignee: Ciba-Geigy AGInventors: David Rowland, Michael E. Dale, Geoffrey E. Ficken, William E. Long, Andrew W. Yates
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Patent number: 4705745Abstract: A radiation-sensitive element for half tone color proofing adapted to be exposed by scanning with four independently modulated sources of radiation emitting at different wavelengths within the range 550 to 900 nm, the element comprising a substrate bearing at least four separate imaging media coated thereon, said imaging media including:(1) an imaging medium capable of forming a yellow image upon imagewise exposure and processing,(2) an imaging medium capable of forming a magenta image upon imagewise exposure and processing,(3) an imaging medium capable of forming a cyan image upon imagewise exposure and processing, and(4) an imaging medium capable of forming a black or a balancing black image upon imagewise exposure and processing,each imaging medium having a maximum spectral sensitivity at a wavelength different from that of the maximum sensitivity of the other imaging media such that after exposure and processing super-imposed yellow, magenta, cyan and black or balancing black images are formed, each imageType: GrantFiled: March 3, 1986Date of Patent: November 10, 1987Assignee: Minnesota Mining and Manufacturing CompanyInventors: Jonathan P. Kitchin, Stephen R. Powers, Keith A. Penfound, Peter J. Finn, Michael G. Fisher
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Patent number: 4565777Abstract: A silver halide color photographic light-sensitive material is described, comprising a coupler represented by formula (I): ##STR1## wherein A represents the residue of a coupler, R.sub.1 represents an alkyl group having from 4 to 15 carbon atoms, R.sub.2 represents an alkyl group having from 1 to 20 carbon atoms, with the total number of carbon atoms of R.sub.1 and R.sub.2 being from 8 to 27.Type: GrantFiled: July 20, 1984Date of Patent: January 21, 1986Assignee: Fuji Photo Film Co., Ltd.Inventors: Akira Ogawa, Kozo Aoki, Osami Tanabe, Makoto Umemoto
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Patent number: 4525450Abstract: A silver halide color photographic light-sensitive material containing a coupler having at least one of a sulfamoylphenylenesulfonyl group, a sulfamoylaminophenylenesulfonyl group and a sulfonamidophenylenesulfonyl group as a substituent. Preferred couplers are represented by the formula: ##STR1## wherein all moieties are defined in the specification wherein Cp is a coupler residue, L is a divalent linking group and X represents --NHSO.sub.2 --, ##STR2## or --SO.sub.2 NH, and n represents 0-4. Groups R.sup.1, R.sup.2 and R.sup.3 are defined in the specification.Type: GrantFiled: March 23, 1984Date of Patent: June 25, 1985Inventors: Isamu Itoh, Takeshi Hirose
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Patent number: 4514494Abstract: A photographic material suited for the production of (an) azine dye image(s), and having at least one silver halide emulsion layer and/or a separate layer in water-permeable relationship with such an emulsion layer which contains:(1) a heterocyclic hydrazone compound,(2) a phenol, naphthol or active methylene coupler compound capable of forming on oxidative coupling with compound (1) an azine dye,(3) an electron transfer agent or ETA-compound capable of forming a positively charged semiquinone on oxidation with exposed silver halide,(4) a reducing agent capable of reducing the thus-formed semiquinone in acidic medium, and having in the pH range of 2-5, a polarographic half-wave potential (E 1/2) which is at least 40 mV more negative (according to the European Convention) than the polarographic half-wave potential of the ETA-compound in the same pH range, said material being suited for processing with a simple aqueous alkaline liquid, and(5) an acidic medium.Type: GrantFiled: November 4, 1983Date of Patent: April 30, 1985Assignee: Agfa-Gevaert N.V.Inventors: Raymond G. Lemahieu, Wilhelmus Janssens
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Patent number: 4513082Abstract: A silver halide color photographic light-sensitive material containing at least one coupler having a ballast group represented by the following general formula (I): ##STR1## wherein X represents a halogen atom, an alkyl group, an aryl group, a heterocyclic group, a hydroxy group, an alkoxy group, an aryloxy group, an acylamino group, a sulfonamido group, a carbamoyl group, a sulfamoyl group, a ureido group, an alkoxycarbonyl group, an alkoxycarbonylamino group, a sulfonyl group, an alkylthio group, a cyano group, a nitro group or a carboxyl group, l represents an integer of 1 to 4, and m represents an integer of 1 or 2, with the proviso that when X represents a hydroxyl group, a substituent other than a hydroxy group is also present on the phenyl ring.Type: GrantFiled: March 23, 1984Date of Patent: April 23, 1985Assignee: Fuji Photo Film Co., Ltd.Inventors: Nobuo Furutachi, Takeshi Hirose
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Patent number: 4503141Abstract: A silver halide color photographic light-sensitive material containing at least one coupler having a ballast group represented by the following general formula (I): ##STR1## wherein ##STR2## represents a substituted or unsubstituted aromatic heterocyclic ring, and m represents an integer of 1 or 2.Type: GrantFiled: March 23, 1984Date of Patent: March 5, 1985Assignee: Fuji Photo Film Co., Ltd.Inventors: Nobuo Furutachi, Takeshi Hirose
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Patent number: 4489155Abstract: In a silver halide color photographic material is disclosed. The material is comprised of a blue-sensitive silver halide emulsion layer, a green-sensitive silver halide emulsion layer, and a red-sensitive silver halide emulsion layer. The granularity of the material is improved by incorporating a non-diffusible coupler capable of forming a properly smearing diffusible dye by causing a reaction with the oxidation product of a color developing agent and a colorless competing compound capable of capturing the oxidation product of a color developing agent in at least one of the foregoing silver halide emulsion layers.Type: GrantFiled: July 5, 1983Date of Patent: December 18, 1984Assignee: Fuji Photo Film Co., Ltd.Inventors: Kei Sakanoue, Shigeo Hirano, Keiichi Adachi
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Patent number: 4439518Abstract: Process for the production of a photographic black dye image which comprises(a) imagewise exposing photographic silver halide material comprising at least one silver halide emulsion layer coated on a support, there being present in the silver halide emulsion layer(s) or in a layer in operative contact with at least one silver halide emulsion layer a resorcinol compound of the formula ##STR1## where each of W, Y and Z is hydrogen, chlorine or bromine, a nitrogen-linked heterocycle, --SR.sub.1 where R.sub.1 is alkyl, aryl or a heterocycle or W, Y or Z is acylamino or --R.sub.3 where --R.sub.3 is alkyl, cycloalkyl or aralkyl or Z alone is --CO--R.sub.1 where R.sub.1 is as just defined but at least one of W, Y and Z must be --R.sub.3, and X which is the coupling position is hydrogen, chlorine or bromine, a nitrogen-linked heterocycle or --SR.sub.Type: GrantFiled: June 18, 1982Date of Patent: March 27, 1984Assignee: Ciba-Geigy A.G.Inventor: Stephen R. Postle
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Patent number: 4436798Abstract: Method of treating a dye image in photographic material which dye image has been formed by the color coupling reaction of a primary aromatic amine color developing agent with a phenolic color coupler of the formula ##STR1## where T is hydroxy or amino, one of R.sub.1 and R.sub.3 is the coupling position and if it is the coupling position the substituent group is hydrogen or halogen, a nitrogen-linked heterocycle or a mercapto group, the other of R.sub.1 and R.sub.3 and R.sub.2 and R.sub.4 are each hydrogen or halogen or optionally substituted organic groups, or one or R.sub.1 and R.sub.2 together or R.sub.2 and R.sub.3 together may represent the atoms necessary to complete a benzannelated ring, which treatment method comprises treating the dye image with an aqueous solution which comprises a salt of a transition (b-sub group) metal, the concentration of the metal ion in the aqueous solution being at least 10.sup.-4 M.Type: GrantFiled: June 28, 1982Date of Patent: March 13, 1984Assignee: Ciba-Geigy AGInventors: Christopher D. Shennan, Michael W. Fry
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Patent number: 4429035Abstract: A black and white photographic material is disclosed. The material contains a black image-forming coupler shown by formula (I) or (II) ##STR1## wherein R represents ##STR2## Y.sub.1 represents a group which prevents the coupler from diffusing away from the layer containing it. Examples of such groups include an aliphatic group, an aryl group, an aralkyl group, or a heterocyclic group. X.sub.1 and X.sub.2 each represents a hydrogen atom or a coupling-off group capable of being released upon oxidative coupling reaction with a developing agent. The material is capable of producing an excellent black image by development after image exposure. In the photographic material, the amount of silver can be effectively reduced and the photographic material give black images even after bleaching the black image formed.Type: GrantFiled: June 20, 1983Date of Patent: January 31, 1984Assignee: Fuji Photo Film Co., Ltd.Inventors: Eiichi Kato, Nobutaka Ohki, Junkichi Ogawa
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Patent number: 4387158Abstract: Photographic silver halide material which comprises at least one silver halide emulsion layer coated on a support, there being present in the silver halide emulsion layer(s), or in a layer in operative contact with at least one silver halide emulsion layer, a compound of the formula ##STR1## wherein W is hydrogen, alkyl, --NHCOR.sup.1 or --COR.sup.1, wherein R.sup.1 is alkyl or alkenyl, cycloalkyl, aralkyl, aryl, phenoxymethylamino or halogen; X is a substituent in the coupling position and is a leaving group selected from hydrogen, chlorine, bromine, --SR.sup.11 wherein R.sup.11 is alkyl, aryl or a heterocyclic group, or X is a nitrogen-containing heterocyclic residue attached at a ring nitrogen atom; Y is a group having the formula ##STR2## wherein Q is selected from the residues: (a) --COOR.sup.4 or --CONR.sup.4 R.sup.5 where R.sup.4 is hydrogen, alkyl optionally interrupted by 1 or more oxygen atoms, alkenyl, cycloalkyl, aralkyl or aryl, and R.sup.5 is hydrogen or alkyl or R.sup.4 and R.sup.Type: GrantFiled: June 18, 1982Date of Patent: June 7, 1983Assignee: Ciba-Geigy AGInventor: Stephen R. Postle
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Patent number: 4374914Abstract: Negative color images are produced by the silver dye bleach process, by exposure of a photographic silver dye bleach material, silver developing, dye bleaching, silver bleaching and fixing, the silver bleaching being optionally carried out simultaneously with the dye bleaching and/or the fixing, in a single treatment bath.Type: GrantFiled: July 13, 1981Date of Patent: February 22, 1983Assignee: Ciba-Geigy Ltd.Inventors: Herbert Mollet, Dieter Wyrsch
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Patent number: 4324856Abstract: A photographic silver halide material is disclosed which contains a precursor of photographic chemicals.Type: GrantFiled: October 7, 1980Date of Patent: April 13, 1982Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Satoshi Kawakatsu, Shigeto Hirabayashi, Hidetaka Ninomiya, Yutaka Kaneko
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Patent number: 4284714Abstract: A method is described for forming a black-and-white photographic image consisting essentially of a silver image and a coextensive dye image, in which the maximum density of the image and the fastness of the image to light are greatly improved, by processing a silver halide photosensitive material which contains silver halide in a reduced amount (compared with conventional materials) that has been imagewise exposed to light in the presence of a naphthalene compound containing at least two hydroxy substituents groups on the nucleus thereof and a p-phenylenediamine type developing agent or a precursor of the p-phenylenediamine compound.Type: GrantFiled: May 9, 1980Date of Patent: August 18, 1981Assignee: Fuji Photo Film Co., Ltd.Inventors: Junkichi Ogawa, Mitsugu Tanaka, Minoru Yamada
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Patent number: 4269923Abstract: Novel photographic imaging process and materials suitable therefor are provided, which can find their application in multi-color motion picture and simultaneous sound recording, in direct-positive image formation, in image-intensification processes, etc. A photographic silver image is formed in at least one hydrophilic colloid layer of a light-sensitive photographic material incorporating silver halide, by means of exposure and alkaline development steps, followed by bleaching of quantities of silver which are present in areas of said layer extraneous to those where imaging silver is required.Type: GrantFiled: January 22, 1980Date of Patent: May 26, 1981Assignee: AGFA-GEVAERT N.V.Inventors: Raymond A. Roosen, Robert J. Pollet, Antoon L. Vandenberghe
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Patent number: 4268616Abstract: A process for forming photographic images comprising a silver image and a dye image, which comprises development processing an imagewise exposed silver halide photographic light-sensitive material in the presence of a carboxy- and sulfo-free naphthalene compound wherein at least two hydrogen atoms in the naphthalene nucleus are substituted at specific positions thereof as indicated in formula (I) below, and a 3-pyrazolidone compound.Type: GrantFiled: January 18, 1980Date of Patent: May 19, 1981Assignee: Fuji Photo Film Co., Ltd.Inventors: Junkichi Ogawa, Tsutomu Hamanka
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Patent number: 4254213Abstract: A process for forming a dye image is disclosed which comprises processing an image-wise exposed silver halide photographic emulsion with an aromatic primary amine color developing agent in the presence of bis pyrazolines obtained by reacting 3-acylamino-5-pyrazolones with para-hydroxybenzaldehydes having at least one of the ortho positions to the hydroxy group substituted with a member selected from halogen, alkyl, aryl, amino or amido groups. The invention includes the present dye forming coupler alone and combined with the silver halide emulsion layer.Type: GrantFiled: January 28, 1980Date of Patent: March 3, 1981Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Kosaku Masuda, Hajime Wada, Kiyoshi Yamashita
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Patent number: 4221860Abstract: A process for forming color photographic images having improved granularity, sharpness, and gradation by applying, after image exposure, a color reversal process including a step of performing color development in the presence of a competing coupler. The element processed is a multilayer reversal color photographic material comprising a support having coated thereon at least three differently sensitive photographic silver halide emulsion layers, the outermost layer of the color photographic material being blue-sensitive and containing a nondiffusible coupler forming a yellow dye by a coupling reaction with an oxidized primary aromatic amino color developing agent and represented by the following general formula (I) ##STR1## wherein R.sub.1 represents an alkyl group or an aryl group; R.sub.Type: GrantFiled: May 20, 1977Date of Patent: September 9, 1980Assignee: Fuji Photo Film Co., Ltd.Inventors: Takeshi Hirose, Akia Okumura
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Patent number: H1127Abstract: A silver halide photographic material that contains a polymer including a repeating unit represented by the following general formula (I) and having a weight average molecular weight of no more than 30,000: ##STR1## wherein R.sup.1 is a hydrogen atom or an alkyl group; Z represents the atomic group necessary to form a lactam ring, an oxazolidone ring or a pyrrolidone ring; A is a simple linkage, --CO--, --COO(CH.sub.2).sub.n or --CONR.sup.2 (CH.sub.2).sub.n where R.sup.2 is a hydrogen atom or an alkyl group, and n is an integer of 1-6. This photographic material experiences a minimum level of increase in fogging during rapid processing and produces image having improved sharpness and granularity.Type: GrantFiled: October 3, 1990Date of Patent: January 5, 1993Assignee: Konica CorporationInventors: Hiroshi Shimazaki, Fumie Fukazawa, Masayuki Kurematsu, Kenjiro Ushiyama, Satoru Shimba