Developing Or Fixing Agents Containing For Liquid Processing Patents (Class 430/566)
  • Patent number: 6534226
    Abstract: This invention comprises an imaging element comprising an imaging layer having associated therewith a compound of Structure I: In the above Structure I, the substituents are as defined in the application. Such compounds have good reactivity and can by used to block photographically useful compounds such as developing agents until thermally activated under preselected conditions. Compounds according to the present invention are especially useful in color photothermographic imaging elements.
    Type: Grant
    Filed: November 20, 2000
    Date of Patent: March 18, 2003
    Assignee: Eastman Kodak Company
    Inventors: Zbyslaw R. Owczarczyk, David T. Southby, Xiqiang Yang
  • Patent number: 6531270
    Abstract: This invention involves the use of ionic liquids as coupler solvents in a color or monochrome photothermographic system. The presence of an ionic liquid can increase the amount of density or dye formed. The ionic liquid may be combined with other coupler solvents.
    Type: Grant
    Filed: November 21, 2001
    Date of Patent: March 11, 2003
    Assignee: Eastman Kodak Company
    Inventors: Leif P. Olson, James H. Reynolds
  • Patent number: 6531271
    Abstract: A light-sensitive silver-halide color photographic element comprising at least two different chromogenic couplers including, in reactive association, a multifunctional coupler and a developer precursor that liberates a developing agent enabling cyan color from the multifunctional coupler on development, wherein the multifunctional coupler has the property that it is capable of forming a distinctly colored dye with an oxidized form of the developer 4-(N-ethyl-N-2-hydroxyethyl)-2-methylphenylenediamine. In one embodiment, the multifunctional coupler has the property that it is capable of forming a distinctly colored magenta dye with an oxidized form of the developer 4-(N-ethyl-N-2-hydroxyethyl)-2-methylphenylenediamine. By means of the present invention, light-sensitive color photothermographic elements can form yellow, magenta and cyan dye records of consistent density forming ability and consistent stability in all three color records.
    Type: Grant
    Filed: August 16, 2001
    Date of Patent: March 11, 2003
    Assignee: Eastman Kodak Company
    Inventors: Richard P. Szajewski, Lyn M. Irving
  • Patent number: 6531273
    Abstract: This invention involves dispersions comprising ionic liquids and a non-ionic surfactant, optionally further comprising a photographically useful compound such as a dye-forming coupler. Such dispersions form coatings that are relatively free of physical defects, and show reduced problems such as crystallization of components like the couplers or ion pairs.
    Type: Grant
    Filed: November 21, 2001
    Date of Patent: March 11, 2003
    Assignee: Eastman Kodak Company
    Inventors: Leif P. Olson, John W. Boettcher, James H. Reynolds
  • Patent number: 6528241
    Abstract: A light-sensitive silver-halide color photographic element comprising a multifunctional coupler enabling formation of an infrared dye on development, wherein the multifunctional coupler has the property that it is capable of forming a distinctly colored cyan dye with an oxidized form of the developer 4-(N-ethyl-N-2-hydroxyethyl)-2-methylphenylenediamine.
    Type: Grant
    Filed: August 13, 2001
    Date of Patent: March 4, 2003
    Assignee: Eastman Kodak Company
    Inventor: Richard P. Szajewski
  • Patent number: 6521384
    Abstract: The present invention is directed to a photothermographic element in which the density formed in a thermally processed photothermographic element is limited for the purpose of scanning the element prior to removal of silver halide, metallic silver, and/or any organic silver salts. In one embodiment of the invention, this is accomplished by employing limited quantities of sensitized silver halide in a photothermographic element.
    Type: Grant
    Filed: May 14, 2001
    Date of Patent: February 18, 2003
    Assignee: Eastman Kodak Company
    Inventor: Richard P. Szajewski
  • Patent number: 6517981
    Abstract: A light-sensitive silver-halide color photothermographic element comprises a typically magenta dye-forming pyrazolone coupler in the cyan record by rendering the hue of the resultant dye a cyan hue. The use of certain para-phenylenediamine developers, for example, containing a substituent group in both the 2- and 6-positions (ortho, ortho') relative to the coupling nitrogen, along with selected magenta dye-forming couplers, when oxidized, yield cyan dyes with certain couplers, resulting in the superior non-hue characteristics of magenta couplers in the cyan layer. By means of the present invention, light sensitive color photothermographic elements can form image dye records of consistent density forming ability and consistent stability in all three color records. Also disclosed is a method of processing such a color photographic element.
    Type: Grant
    Filed: August 16, 2001
    Date of Patent: February 11, 2003
    Assignee: Eastman Kodak Company
    Inventors: Leif P. Olson, Wojciech K. Slusarek, James H. Reynolds, Richard P. Szajewski
  • Patent number: 6509126
    Abstract: The present invention is directed to a photothermographic imaging element comprising at least one silver halide imaging layer containing a fluorophore. The imaging element can be exposed and then processed by heating to form an image in which the intensity of the fluorescence from the element is modulated imagewise to yield a fluorescent image of the light intensities to which the element was exposed. The present invention is also directed to a method of processing photothermographic film that has been imagewise exposed in a camera, which method in order comprises thermally developing the film step without any externally applied developing agent, comprising heating said film to a temperature greater than 80° C.
    Type: Grant
    Filed: December 28, 2001
    Date of Patent: January 21, 2003
    Assignee: Eastman Kodak Company
    Inventors: Thomas H. Whitesides, John H. Hone
  • Patent number: 6506528
    Abstract: This invention relates to a photothermographic color element containing a mixture of blocked developers in the same emulsion layer, which blocked developers having different onset temperatures. Such a mixture has been found to allow for lower film processing temperatures and/or shorter times of development with respect to the blocked developer having a higher onset temperature. Conversely, improved discrimination can be obtained with respect to the blocked developer having the lower onset temperature.
    Type: Grant
    Filed: November 20, 2000
    Date of Patent: January 14, 2003
    Assignee: Eastman Kodak Company
    Inventors: Zbyslaw R. Owczarczyk, David T. Southby, Xiqiang Yang
  • Patent number: 6506546
    Abstract: This invention comprises an imaging element comprising an imaging layer having associated therewith a compound of Structure I: wherein PUG is a photographically useful group; LINK 1 and LINK 2 are linking groups; TIME is a timing group; T represents t independently selected substituted or unsubstituted alkyl or aryl groups, t is 0, 1, or 2 and if t is 2, the T groups can form a ring; HET is a heterocyclic group which optionally can form a ring with a T group; R12 is hydrogen, substituted or unsubstituted alkyl or substituted or unsubstituted aryl, or R12 can form a ring with a T group or with HET; 1 is 0 or 1; m is 0, 1, or 2; and n is 0 or 1.
    Type: Grant
    Filed: December 30, 1999
    Date of Patent: January 14, 2003
    Assignee: Eastman Kodak Company
    Inventors: Zbyslaw R. Owozarczyk, Xiqiang Yang, David T. Southby
  • Publication number: 20030008248
    Abstract: This invention comprises a photographic element comprising at least one light-sensitive silver halide emulsion layer containing a fragmentable electron donating compound of the formula: X—Y′ or a compound which contains a moiety of the formula —X—Y′; wherein
    Type: Application
    Filed: January 5, 2001
    Publication date: January 9, 2003
    Applicant: Eastman Kodak Company
    Inventors: Annabel A. Muenter, Steven P. Szatynski, Sharon G. Johnston
  • Patent number: 6500590
    Abstract: The present invention is directed to a method of processing color photographic film that has been imagewise exposed in a camera, said film having at least three light-sensitive units which have their individual sensitivities in different wavelength regions, each of the units comprising at least one light-sensitive silver-halide emulsion, binder, and dye-providing coupler, which method in order comprises: (a) thermally developing the film step without any externally applied developing agent, comprising heating said film to a temperature greater than 80° C.
    Type: Grant
    Filed: May 23, 2001
    Date of Patent: December 31, 2002
    Assignee: Eastman Kodak Company
    Inventors: Mark E. Irving, David T. Southby
  • Patent number: 6497999
    Abstract: The invention is directed to a color photothermographic film in which particles comprising an organic silver salt is treated with a passivating agent. In particular, the present invention involves passivating the organic silver salts with an organic adsorbate that blocks the surface of the organic silver salt or ligand, resulting in a reduction of speed loss. The invention is also directed to a method of making a photothermographic element to improve raw stock keeping.
    Type: Grant
    Filed: November 21, 2001
    Date of Patent: December 24, 2002
    Assignee: Eastman Kodak Company
    Inventors: Gregg P. Bryant, JoAnn D. Hanna, Nancy B. Liebert, Mark E. Irving
  • Patent number: 6498001
    Abstract: A spectrally sensitized photographic silver halide emulsion, characterized in that after precipitation at least one compound of formula is added to the emulsion, wherein R1 denotes alkyl, aryl, aralkyl, alkenyl or heterocyclyl; R2 denotes H, alkyl, aryl, heterocyclyl, amino or alkoxy; R3 denotes H, alkyl, aryl, aralkyl or heterocyclyl; D denotes —OH or —NR4R5; X denotes O or N—R6; R4 denotes H, alkyl, aryl, aralkyl, alkenyl or heterocyclyl; R5: denotes H, alkyl, aryl, aralkyl, alkenyl or heterocyclyl; R6: denotes H, alkyl, aryl, aralkyl, alkenyl, acyl, alkoxycarbonyl, carbamoyl or heterocyclyl, the aforementioned alkyl, aryl, aralkyl, alkenyl, heterocyclyl, amino, alkoxy, acyl, alkoxycarbonyl and carbamoyl groups can be substituted, and any two of the radicals R1 to R6 can together form a heterocyclic ring, such as a pyrrolidine, piperidine, perhydroazepine, piperazine, morpholine or thiomorpholine ring, for example; as well as a photographic material comprising a
    Type: Grant
    Filed: July 24, 2001
    Date of Patent: December 24, 2002
    Assignee: AGFA-Gevaert
    Inventors: Peter Bergthaller, Jörg Siegel, Hans-Ulrich Borst, Ralf Büscher, Ulrich Nickel
  • Patent number: 6498002
    Abstract: A photographic material comprising a support and at least one at least one layer which comprises at least one spectrally sensitized silver halide emulsion, characterized in that the material contains at least one compound of formula wherein X denotes sulphur or selenium, R1 denotes aryl or heterocyclyl, R2 denotes alkyl, alkenyl, alkynyl, aralkyl or hetarylalkyl, R3 denotes alkyl, alkenyl, aryl, aralkyl, hetaryl or hetarylalkyl, and R4 denotes H, alkyl, alkenyl, aryl, aralkyl, hetaryl or hetaralkyl, or R3, together with R4, denotes the remaining atoms of a carbocyclic or heterocyclic ring, is distinguished by increased spectral sensitivity, a high sensitivity/fogging ratio and a good shelf life under humid conditions.
    Type: Grant
    Filed: July 25, 2001
    Date of Patent: December 24, 2002
    Assignee: AGFA-Gevaert
    Inventors: Peter Bergthaller, Jörg Siegel, Hans-Ulrich Borst
  • Patent number: 6498003
    Abstract: A photographic material comprising a support and at least one layer which comprises at least one spectrally sensitised silver halide emulsion, characterised in that the material contains at least one compound of formula and/or wherein R1 denotes H, alkyl, aryl, aralkyl, alkenyl, heterocyclyl, R2 denotes OH, NH2, NHR7, NR8R9 or R1 together with R2, denotes the atoms necessary for the completion of a heteroaliphatic ring, R3 denotes OH, NH2, NHR7, NR8R9, R4 denotes H, alkyl, aryl, aralkyl, alkenyl, heterocyclyl, R5, R6 independently of each other, denote OH, NH2, NHR10, NR11R12, or R4 together with R5, or R4 together with R6, denote the atoms necessary for the completion of a heteroaliphatic ring, and the R5 or R6 radical, which is not part of a ring, denotes OH, NH2, NHR10 or NR11R12, R7, R10 denote alkyl, aryl, aralkyl, heterocyclyl, R8, R9 independently of each other, denote alkyl, aryl, aralkyl, heterocyclyl, or R8 together with R9, denotes the atoms necessary f
    Type: Grant
    Filed: July 26, 2001
    Date of Patent: December 24, 2002
    Assignee: Agfa-Gevaert
    Inventors: Peter Bergthaller, Jörg Siegel, Hans-Ulrich Borst
  • Patent number: 6492076
    Abstract: This invention relates to a color photothermographic element comprising a support, at least one photothermographic imaging layer, and at least one antihalation layer or filter layer, wherein the antihalation or filer layer comprises an aqueous heat-bleachable composition comprising at least one zwitterionic 1-aminopyridinium dye having a methine linkage terminated by a substituted or unsubstituted heterocyclic nucleus.
    Type: Grant
    Filed: August 27, 2001
    Date of Patent: December 10, 2002
    Assignee: Eastman Kodak Company
    Inventors: Ramanuj Goswami, Mark E. Irving, David H. Levy
  • Patent number: 6489086
    Abstract: Disclosed are an improved silver halide color photographic photosensitive material comprising a support having thereon a photosensitive layer containing at least one kind of photosensitive silver halide grain, a color developing agent, a coupler and a binder, and a non-photosensitive layer, wherein a one dye is contained as a dispersion of solid fine particles at least one of the layers the dye being represented by general formula (I) as follows: D−(X)y  General formula (I) wherein D represents a compound having a chromophore; X represents a dissociative proton or a group having a dissociative proton which is linked to D directly or via a divalent linking group; and y represents an integer of 1 to 7.
    Type: Grant
    Filed: March 17, 2000
    Date of Patent: December 3, 2002
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tetsu Kamosaki, Keizo Kimura, Masashi Ogiyama
  • Patent number: 6482582
    Abstract: Disclosed in an image recording material comprising, on a support, a photosensitive silver halide, a reducing agent, a binder and a compound represented by the following Formula (1): wherein, in Formula (1), R1 and R2 each independently represent a substituent, R1 and R2 may be bonded to each other to form a ring, X represents a halogen atom, L represents a methylene group, m represents an integer of 0-7, Y represents a divalent bridging group, n represents 0 or 1 and Z represents a residue derived from a photographically useful compound. This image recording material exhibits high sensitivity, low fog and good storage stability, and is stable against fluctuation of development conditions.
    Type: Grant
    Filed: July 24, 2001
    Date of Patent: November 19, 2002
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Katsuyuki Watanabe, Masaru Takasaki
  • Publication number: 20020168595
    Abstract: A silver halide color photographic light-sensitive material containing at least one kind of a compound represented by formula (I): 1
    Type: Application
    Filed: February 4, 2002
    Publication date: November 14, 2002
    Applicant: FUJI PHOTO FILM CO., LTD.
    Inventors: Masahiko Taniguchi, Naoto Matsuda
  • Patent number: 6479198
    Abstract: A silver halide light-sensitive material comprises a support and a silver halide gelatin emulsion layer. The silver halide gelatin emulsion layer or an optionally provided hydrophilic layer contains a tanning developing agent. According to the first embodiment of the present invention, the tanning developing agent has a molecular structure in which two to six benzenediol or benzenetriol rings are connected with a linking group. According to the second embodiment of the invention, the tanning developing agent consists of a polymer having side chains containing benzenediol or benzenetriol rings. According to the third embodiment of the invention, the tanning developing agent consists of a benzenediol or benzenetriol ring having an aliphatic substituent group having 5 to 40 carbon atoms or an aromatic substituent group having 7 to 40 carbon atoms. A tanning developing solution and a lithographic printing plate are also disclosed.
    Type: Grant
    Filed: February 1, 2001
    Date of Patent: November 12, 2002
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Naonori Makino, Kaku Sakata
  • Patent number: 6472111
    Abstract: This invention relates to a photothermographic color element containing a mixture of blocked developers in the same emulsion layers. By having different blocked developers or mixtures of at least two blocked developers in different color layers, it is possible to manipulate the image discrimination (at the processing temperature) in each layer and to balance the density formation or color in the different color layers. Different mixtures of blocked developers can be used in different imaging layers, to balance the Gamma, the Dmin and the Latitude in different imaging layers or color units.
    Type: Grant
    Filed: November 20, 2000
    Date of Patent: October 29, 2002
    Assignee: Eastmank Kodak Company
    Inventors: James H. Reynolds, David H. Levy, David T. Southby
  • Publication number: 20020146651
    Abstract: A color-developing agent of the formula (1-1): 1
    Type: Application
    Filed: July 25, 2001
    Publication date: October 10, 2002
    Inventors: Osamu Uchida, Yasuhiro Ishiwata, Takayuki Ito, Nobutaka Fukagawa
  • Publication number: 20020136995
    Abstract: There is disclosed a silver halide photographic emulsion comprising silver halide grains, wherein 50% or more of the projected area of the silver halide grains to be contained is occupied by tabular grains having an aspect ratio of 2 or more and a grain thickness of 0.2 &mgr;m or less, with the tabular grains each having a phase with the content of silver bromide being 10% or more, and wherein in the phase, the tabular grains each contain a metal complex dopant in an amount necessary to increase the density of a dislocation. This emulsion produces high contrast and better granularity while it has high sensitivity. Further, there is also disclosed a silver halide photographic emulsion, wherein the average equivalent-circle diameter of the total tabular grains among the silver halide grains contained is 2.0 to 4.0 &mgr;m, and the tabular grains contain at least one metal complex having, as a ligand, a heterocyclic compound in a number more than half of the coordination number of the metal atom.
    Type: Application
    Filed: September 17, 2001
    Publication date: September 26, 2002
    Applicant: FUJI PHOTO FILM CO., LTD.
    Inventors: Masahiro Asami, Makoto Kikuchi, Tadanobu Sato
  • Publication number: 20020132175
    Abstract: The present invention is directed to a method of scanning silver-halide-containing color photographic and photothermographic film. In particular, the present invention comprises record shifting by means by employing at least one infrared dye in a color unit of the film, thereby forming at least one image record in the infrared. This expedient leads to the formation of high quality images, especially when scanning photothermographic elements in which the silver halide, metallic silver, and/or any organic silver salts have not been removed.
    Type: Application
    Filed: March 6, 2002
    Publication date: September 19, 2002
    Applicant: Eastman Kodak Company
    Inventor: Richard P. Szajewski
  • Patent number: 6451516
    Abstract: This invention relates to a photothermographic element comprising a support, at least one photothermographic imaging layer, and at least one antihalation layer or a filter layer, wherein the antihalation or filer layer comprises an aqueous heat-bleachable composition comprising a 1-aminopyridinium filter dye having a methine linkage terminated by a substituted or unsubstituted heterocyclic nucleus of the type contained in cyanine dyes, which filter dye is in the presence of an effective amount of a thermal solvent.
    Type: Grant
    Filed: August 27, 2001
    Date of Patent: September 17, 2002
    Assignee: Eastman Kodak Company
    Inventors: Mark E. Irving, Ramanuj Goswami
  • Patent number: 6440618
    Abstract: This invention relates to an imaging element comprising an imaging layer having associated therewith a compound of Structure I: In the above Structure I, the substituents are as defined in the application, wherein B is a six-membered heteroaromatic ring. Such compounds have good reactivity and can by used to block photographically useful compounds such as developing agents until thermally activated under preselected conditions. Compounds according to the present invention are especially useful in color photothermographic imaging elements.
    Type: Grant
    Filed: November 13, 2000
    Date of Patent: August 27, 2002
    Assignee: Eastman Kodak Company
    Inventors: Wojciech K. Slusarek, Xiqiang Yang, David H. Levy
  • Publication number: 20020110763
    Abstract: A heat-developable light-sensitive material, which at least contains:
    Type: Application
    Filed: November 27, 2001
    Publication date: August 15, 2002
    Inventors: Kazuhiko Matsumoto, Toshio Kawagishi
  • Publication number: 20020102489
    Abstract: There is disclosed a novel color-developing agent of a 1,2,4-thiadiazol-5-yl hydrazine type. There is also disclosed a silver halide photographic light-sensitive material which gives sufficient color formation by development and forms an image excellent in image quality and image storability, by using the color-developing agent. Further, there is disclosed an image-forming method using the light-sensitive material.
    Type: Application
    Filed: June 25, 2001
    Publication date: August 1, 2002
    Inventors: Osamu Uchida, Yasuhiro Ishiwata, Kiyoshi Takeuchi, Taiji Katsumata, Takashi Nakamura
  • Patent number: 6426179
    Abstract: This invention relates to an imaging element, such as a photographic or photothermographic element comprising a silver halide emulsion layer, wherein the element also comprises a compound of Structure I: wherein the substituents are as defined in the specification.
    Type: Grant
    Filed: December 30, 1999
    Date of Patent: July 30, 2002
    Assignee: Eastman Kodak Company
    Inventors: Wojciech K. Slusarek, Xiqiang Yang, Mark E. Irving, David H. Levy
  • Patent number: 6423485
    Abstract: A heat developing color photosensitive material including a substrate carrying thereon a photosensitive silver halide, binder, a developing agent having specific structure classified into an aminophenol derivative or a phenylenediamine derivative and a compound which forms or releases a diffusive dye by reaction with an oxidized product of the developing agent, in which the material further comprises at least one of the specific naphtol derivatives, phenol derivatives, pyrazolone derivatives, aminophenol derivatives, and the like. These compounds each preferably contain an organic ballasting group which allows the compound. There is also disclosed a silver halide photographic light-sensitive material which includes at least a compound of the formula (1) or (2): This light-sensitive material is excellent in discrimination and raw stock storability.
    Type: Grant
    Filed: June 21, 2000
    Date of Patent: July 23, 2002
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Makoto Yamada, Hideaki Naruse
  • Patent number: 6413708
    Abstract: This invention relates to an imaging element comprising an imaging layer having associated therewith a compound of Structure I: In the above Structure I, the substituents are as defined in the application. Such compounds have good reactivity and can by used to block photographically useful compounds such as developing agents until thermally activated under preselected conditions. Compounds according to the present invention are especially useful in color photothermographic imaging elements.
    Type: Grant
    Filed: November 9, 2000
    Date of Patent: July 2, 2002
    Assignee: Eastman Kodak Company
    Inventors: Wojciech K. Slusarek, Xiqiang Yang, David H. Levy
  • Patent number: 6410216
    Abstract: Method of forming a photographic color image which comprises imagewise exposing a photographic silver halide color material and processing it with an alkaline processing solution in the presence of a sulphonhydrazide color developing agent and a 3-pyridinol color coupler optionally containing in the 2-position a ballasting group of such size and configuration as to render the coupler non-diffusible in photographic materials thus forming a dye image by reaction of the oxidized color developing agent and the color coupler.
    Type: Grant
    Filed: July 14, 1994
    Date of Patent: June 25, 2002
    Assignee: Eastman Kodak Company
    Inventors: David Clarke, Paul Louis Reginald Stanley
  • Publication number: 20020055070
    Abstract: A silver halide photographic light-sensitive material comprising, on a support, at least one light-sensitive silver halide emulsion layer and at least one non-light-sensitive layer, wherein 60% or more of the total projected area of silver halide grains contained in said at least one light-sensitive silver halide emulsion layer are tabular silver halide grains having an average aspect ratio of 5 or more, and a film pAg on the light-sensitive silver halide emulsion layer side of said material falls within 4.0 to 8.5.
    Type: Application
    Filed: June 8, 2001
    Publication date: May 9, 2002
    Applicant: FUJI PHOTO FILM CO., LTD.
    Inventor: Minoru Uchida
  • Patent number: 6368780
    Abstract: A silver halide photographic material excellent in color generation, color reproduction and image fastness, which comprises at least one coupler represented by the following formula: wherein R1 represents an alkyl group which may be optionally substituted, with the proviso that an alkyl group substituted by a halogen atom alone and an alkyl group substituted by a halogen atom and an aryl group are excluded from R1; R2 and R3, which may be the same or different, each represents a hydrogen atom or a substituent; and X1 represents a group which can leave by coupling with an oxidation product of a color developing agent; and an image formation method using the same.
    Type: Grant
    Filed: July 28, 2000
    Date of Patent: April 9, 2002
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kiyoshi Takeuchi, Taiji Katsumata, Satoshi Sano, Yuki Mizukawa
  • Publication number: 20020031731
    Abstract: A method for processing a silver halide color photographic light-sensitive material. The material has, on a support, at least one light-sensitive silver halide emulsion layer comprising a light-sensitive silver halide emulsion, a compound that forms a dye by a coupling reaction with a developing agent in an oxidized form, and a binder. The method comprises processing the light-sensitive material such that a silver density of the at least one light-sensitive silver halide emulsion layer during development is 4×105 g/m3 or more.
    Type: Application
    Filed: June 8, 2001
    Publication date: March 14, 2002
    Inventor: Junichiro Hosokawa
  • Patent number: 6350564
    Abstract: Disclosed is a color silver halide photographic element comprising a support bearing: (1) a light sensitive silver halide emulsion layer; (2) a nitrogen heterocycle with a minimum of three heteroatoms that does not react with oxidized developer, does not contain free thiol substituents, and has a ClogP sufficient to increase the photographic speed of said element compared to the same element without the compound, said heterocycle compound located either in said light sensitive layer or in a layer adjacent to it; and (3) a light reflecting silver halide material; provided that the heterocycle compound and the light reflecting material are located either (a) in different layers of the element located close enough to each other so that a super-additive speed increase is realized or (b) in the same light sensitive layer. The invention provides improved light sensitivity.
    Type: Grant
    Filed: October 17, 2000
    Date of Patent: February 26, 2002
    Assignee: Eastman Kodak Company
    Inventors: Joseph F. Bringley, James A. Friday, Stephen P. Singer, Marcello Vitale
  • Patent number: 6350566
    Abstract: This invention relates to packaged photographic film that is capable of being alternately processed, according to individual consumer choice, by either (1) a traditional wet-chemistry process with a phenylenediamine-containing developer solution followed by desilvering in one or more subsequent solutions to obtain a color negative film, or (2) a thermal process involving the use of a relatively minor amount of an aqueous solution containing a liberating agent such as alkaline base to activate (unblock) a blocked phenylenediamine developing agent located within the photographic element, followed by electronic scanning of the developed film without desilvering. This invention enables a single film stock to be developed in both a conventional deep tank process and in an apparently dry process.
    Type: Grant
    Filed: January 11, 2001
    Date of Patent: February 26, 2002
    Assignee: Eastman Kodak Company
    Inventors: Mark E. Irving, Richard P. Szajewski, Lyn M. Irving
  • Publication number: 20020019571
    Abstract: This invention relates to an imaging element comprising an imaging layer having associated therewith a compound of Structure I: 1
    Type: Application
    Filed: July 13, 2001
    Publication date: February 14, 2002
    Inventors: Wojciech K. Slusarek, Xiqiang Yang, David H. Levy
  • Publication number: 20020012886
    Abstract: The present invention relates to a novel blocked phenylenediamine developer useful, in reactive association, for enabling, on development, a non-magenta color, for example a cyan color, from a dye-forming coupler. In one embodiment, the developer has the property that the dye color formed with the coupler is distinctly different from the color formed by the same coupler with an oxidized form of the conventional developer 4-(N-ethyl-N-2-hydroxyethyl)-2-methylphenylenediamine. The invention is also directed to a light-sensitive silver-halide color photographic element comprising the blocked developing agent according to the present invention.
    Type: Application
    Filed: May 31, 2001
    Publication date: January 31, 2002
    Applicant: Eastman Kodak Company
    Inventors: Richard P. Szajewski, Lyn M. Irving
  • Patent number: 6337177
    Abstract: Disclosed is a silver halide color photographic material comprising a support, photosensitive silver halide emulsion layers grouped into at least three units according to their color sensitivities, each of which comprises a blue-sensitive, green-sensitive or red-sensitive silver halide emulsion, a color developing agent and a coupler, and a light-insensitive layer, wherein the photographic material has a total silver coverage of at most 5.0 g/m2, and at least one emulsion comprised in the highest-speed emulsion layer of at least one of each unit is a tabular silver halide emulsion that comprises tabular silver halide grains having an average thickness of from 0.05 to 0.20 &mgr;m.
    Type: Grant
    Filed: September 3, 1999
    Date of Patent: January 8, 2002
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Makoto Kikuchi
  • Patent number: 6335154
    Abstract: There is disclosed a silver halide photographic emulsion comprising silver halide grains, wherein 50% or more of the projected area of the silver halide grains to be contained is occupied by tabular grains having an aspect ratio of 2 or more and a grain thickness of 0.2 &mgr;m or less, with the tabular grains each having a phase with the content of silver bromide being 10% or more, and wherein in the phase, the tabular grains each contain a metal complex dopant in an amount necessary to increase the density of a dislocation. This emulsion produces high contrast and better granularity while it has high sensitivity. Further, there is also disclosed a silver halide photographic emulsion, wherein the average equivalent-circle diameter of the total tabular grains among the silver halide grains contained is 2.0 to 4.0 &mgr;m, and the tabular grains contain at least one metal complex having, as a ligand, a heterocyclic compound in a number more than half of the coordination number of the metal atom.
    Type: Grant
    Filed: March 22, 2000
    Date of Patent: January 1, 2002
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masahiro Asami, Makoto Kikuchi, Tadanobu Sato
  • Publication number: 20010044067
    Abstract: A silver halide color photographic light-sensitive material comprising, a photographic structural layer coated on a support, which structural layer includes at least one photographic light-sensitive layer containing a light-sensitive silver halide, a compound that forms a dye by a coupling reaction with an oxidized product of a developing agent, and a binder, wherein at least one photographic light-sensitive layer of the light-sensitive material contains a silver halide emulsion comprising a tabular silver halide grain that has principal faces composed of (111) planes, an average equivalent circle diameter of at least 0.70 &mgr;m, and an average thickness of less than 0.20 &mgr;m, and the emulsion is chemically sensitized by a tellurium sensitizer.
    Type: Application
    Filed: February 28, 2001
    Publication date: November 22, 2001
    Inventor: Tomoyuki Koide
  • Patent number: 6319640
    Abstract: This invention relates to an imaging element comprising an imaging layer having associated therewith a compound of Structure I: In the above Structure I, the substituents are as defined in the application. Such compounds have good reactivity and can by used to block photographically useful compounds such as developing agents until thermally activated under preselected conditions. Compounds according to the present invention are especially useful in color photothermographic imaging elements.
    Type: Grant
    Filed: November 13, 2000
    Date of Patent: November 20, 2001
    Assignee: Eastman Kodak Company
    Inventors: Wojciech K. Slusarek, Xiqiang Yang, David H. Levy
  • Patent number: 6312879
    Abstract: This invention relates to an imaging element, such as a photographic or photothermographic element comprising a silver halide emulsion layer, wherein the element also comprises a compound of Structure I: wherein the substituents are as defined in the specification.
    Type: Grant
    Filed: December 30, 1999
    Date of Patent: November 6, 2001
    Assignee: Eastman Kodak Company
    Inventors: Wojciech K. Slusarek, Xiqiang Yang, Mark E. Irving, James H. Reynolds, David H. Levy, Lyn M. Irving
  • Patent number: 6306551
    Abstract: This invention relates to an imaging element comprising an imaging layer having associated therewith a compound of Structure I: wherein the substituents are as defined in the specification.
    Type: Grant
    Filed: December 30, 1999
    Date of Patent: October 23, 2001
    Assignee: Eastman Kodak Company
    Inventors: Zbyslaw R. Owczarczyk, Xiqiang Yang, David H. Levy, Mark E. Irving
  • Publication number: 20010024771
    Abstract: This invention relates to packaged photographic film that is capable of being alternately processed, according to individual consumer choice, by either (1) a traditional wet-chemistry process with a phenylenediamine-containing developer solution followed by desilvering in one or more subsequent solutions to obtain a color negative film, or (2) a thermal process involving the use of a relatively minor amount of an aqueous solution containing a liberating agent such as alkaline base to activate (unblock) a blocked phenylenediamine developing agent located within the photographic element, followed by electronic scanning of the developed film without desilvering. This invention enables a single film stock to be developed in both a conventional deep tank process and in an apparently dry process.
    Type: Application
    Filed: January 11, 2001
    Publication date: September 27, 2001
    Inventors: Mark E. Irving, Richard P. Szajewski, Lyn M. Irving
  • Publication number: 20010014434
    Abstract: A silver halide color photographic light-sensitive material comprising, a photographic structural layer coated on a support, which structural layer includes at least one photographic light-sensitive layer containing a light-sensitive silver halide, a compound that forms a dye by a coupling reaction with an oxidized product of a developing agent, and a binder, wherein at least one photographic light-sensitive layer of the light-sensitive material contains a silver halide emulsion comprising a tabular silver halide grain that has principal faces composed of (111) planes, an average equivalent circle diameter of at least 0.70 &mgr;m, and an average thickness of less than 0.20 &mgr;m, and the emulsion is chemically sensitized by a tellurium sensitizer is disclosed. The light-sensitive material is a color photographic light-sensitive material improved in the relation of sensitivity and granularity.
    Type: Application
    Filed: December 22, 2000
    Publication date: August 16, 2001
    Inventor: Tomoyuki Koide
  • Patent number: 6261757
    Abstract: A photographic element comprises at least one light-sensitive layer on a support wherein the photographic element also comprises a particulate ion exchange material having an average particle size of about 0.01 to about 10 &mgr;m and comprising at least one reducing agent ionically bound to an ion exchange matrix.
    Type: Grant
    Filed: June 13, 2000
    Date of Patent: July 17, 2001
    Assignee: Eastman Kodak Company
    Inventors: Lyn M. Irving, John M. Noonan, Mark E. Irving
  • Patent number: 6251576
    Abstract: A heat developing color photosensitive material including a substrate carrying thereon a photosensitive silver halide, binder, a developing agent having specific structure classified into an aminophenol derivative or a phenylenediamine derivative and a compound which forms or releases a diffusive dye by reaction with an oxidized product of the developing agent, in which the material further comprises at least one of the specific naphtol derivatives, phenol derivatives, pyrazolone derivatives, aminophenol derivatives, and the like. These compounds each preferably contain an organic ballasting group which allows the compound. There is also disclosed a silver halide photographic light-sensitive material which includes at least a compound of the formula (1) or (2): This light-sensitive material is excellent in discrimination and raw stock storability.
    Type: Grant
    Filed: January 10, 2000
    Date of Patent: June 26, 2001
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toshiki Taguchi, Masaaki Tukase, Makoto Yamada, Hideaki Naruse