Developing Or Fixing Agents Containing For Liquid Processing Patents (Class 430/566)
  • Patent number: 4458009
    Abstract: Color photographic images are produced by decomposing hydrogen peroxide on nuclei present in imagewise distribution and bleaching out a dye by the hydrogen peroxide on those parts of the image where no such nuclei are present.
    Type: Grant
    Filed: January 10, 1983
    Date of Patent: July 3, 1984
    Assignee: Agfa-Gevaert Aktiengesellschaft
    Inventors: Edith Weyde, Wilhelm Saleck, Hubertus Psaar, Anita von Konig, Hans hlschlager
  • Patent number: 4458010
    Abstract: A process for bleaching color photographic sensitive materials and color photographic sensitive materials are disclosed. The process comprises bleaching the silver halide color photographic sensitive materials which are comprised of a support base, a silver halide emulsion layer, and a compound represented by the general formula (I) or strong acid salts thereof in a layer which does not substantially form silver salts of said compounds with a treating solution containing persulfate after being exposed to the light and carrying out color development: ##STR1## wherein M represents a hydrogen atom, an alkali metal atom, an alkaline earth metal, a quaternary ammonium group, a quaternary phosphonium group, an amidino group or ##STR2## R.sup.1 and R.sup.2 each represents a hydrogen atom or an aliphatic group, and m represents an integer of 2 to 4. The bleaching process effectively bleaches color sensitive materials having a high silver content and/or a colloidal silver layer without creating a bad odor.
    Type: Grant
    Filed: November 12, 1982
    Date of Patent: July 3, 1984
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kiyohiko Yamamuro, Shigeo Hirano, Yasuo Iwasa
  • Patent number: 4456682
    Abstract: A silver halide color photographic material is disclosed. The material has improved developing characteristics which are obtained by containing both a substantially light-insensitive silver halide and at least one specific 3-pyrazolidone compound. The substantially light-insensitive silver halide includes a halogen composition consisting of 0 to 100 percent of bromide, 0 to 2 percent of iodine and the residual percent of chlorine, a mean grain size of 0.01 to 0.3.mu., and a coverage of 5 to 500 mg/m.sup.2. The 3-pyrazolidone compound has the following general formula (I): ##STR1## wherein X represents a hydrogen atom or an acetyl group; R represents an aryl group; and R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each represents a hydrogen atom, an alkyl group or an aryl group, and they may be the same as or different from one another. The material can be developed at an increased speed and is not accompanied by undesirable photographic effects such as fogging.
    Type: Grant
    Filed: September 21, 1982
    Date of Patent: June 26, 1984
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takatoshi Ishikawa, Akio Mitsui, Masakazu Morigaki, Takashi Nakamura
  • Patent number: 4450223
    Abstract: A photographic silver halide material comprising a compound which is capable of being reduced by a silver halide developing agent at a rate slower than that of image-wise developable silver halide and in reduced state is capable of releasing a photographically useful group, characterized in that said compound corresponds to the following formula: ##STR1## wherein: R.sup.10 and R.sup.20 (same or different)(1) represent an alkyl group, a cycloalkyl group, an alkenyl group, a cycloalkenyl group or an aralkyl group including said groups in substituted form,(2) represent an aryl group including a substituted aryl group, or(3) represent a heterocyclic ring residue including such residue in substituted form, orR.sup.10 and R.sup.20 are ringclosed, either R.sup.10 or R.sup.20 containing a ballasting group conferring diffusion resistance to the compound in hydrophilic colloid media when penetrated by an aqueous alkaline liquid;L.sup.1 and L.sup.2 (same or different) represent a ##STR2## --SO.sub.
    Type: Grant
    Filed: February 14, 1983
    Date of Patent: May 22, 1984
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Raphael K. Van Poucke, Christian C. Van de Sande, Andree Verhecken
  • Patent number: 4448850
    Abstract: Polymers having excellent adherence to film supports such as cellulose acetate are disclosed. The polymers comprise random recurring units having the structure--A).sub.w, --B).sub.x, --C).sub.y and --D).sub.zwherein;A represents polymerized vinyl acetate;B represents a polymerized acrylate or methacrylate monomer capable of copolymerization with vinyl acetate;C represents a polymerized monomer selected from the group consisting of methacrylic acid, itaconic acid and vinylbenzoic acid;D represents a polymerized cationically charged copolymerizable monomer;w represents from 20 to 85 weight percent;x represents from 5 to 65 weight percent;y represents from 5 to 50 weight percent and;z represents from 0 to 15 weight percent.
    Type: Grant
    Filed: July 23, 1982
    Date of Patent: May 15, 1984
    Assignee: Eastman Kodak Company
    Inventors: Donald A. Upson, David J. Steklenski
  • Patent number: 4447522
    Abstract: A method of forming a photographic image which comprises development processing with an alkaline activator solution a silver halide photographic light-sensitive material comprising a support having thereon at least one surface latent image type silver halide emulsion layer, and containing in at least one layer selected from the silver halide emulsion layer and another hydrophilic colloid layer(1) a developing agents;(2) an acylhydrazine compound represented by formula (I):R.sup.1 NHNHCOR.sup.2 (I)wherein R.sup.1 represents an unsubstituted or substituted aryl group or alkyl group; and R.sup.2 represents a hydrogen atom, or an unsubstituted or substituted aryl group or alkyl group; and(3) at least one compound represented by formula (II): ##STR1## wherein each of W.sup.1 and W.sup.2 can represent a hydrogen atom or an aliphatic group or W.sup.1 and W.sup.2 are bonded each other to form a ring; W.sup.3 represents a divalent aliphatic group; Q.sup.
    Type: Grant
    Filed: April 18, 1983
    Date of Patent: May 8, 1984
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shigeo Hirano, Yoshihiro Takagi
  • Patent number: 4446216
    Abstract: Photographic material which comprises in at least one silver halide emulsion layer or a layer or layers adjacent thereto at least one substituted hydroquinone compound of the formula ##STR1## where R is hydrogen or optionally substituted alkyl, aryl or a heterocyclic group, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 are each hydrogen, halogen or optionally substituted alkyl,x is 0 or 1,y is 0 or 1,and R.sub.1 is hydrogen or a group of the formula ##STR2## where R, x and y are as just defined.
    Type: Grant
    Filed: November 23, 1982
    Date of Patent: May 1, 1984
    Inventors: Norman A. Smith, Stephen R. Postle, William E. Long
  • Patent number: 4444867
    Abstract: Sulfilimine compounds of formula I ##STR1## wherein X is the integrating residue of a photographically active compound H.sub.2 N--A--X andA is a linking member between X and N consisting of a benzene ring having at least two electron-attracting groupsare suitable compounds for photographic recording materials. The compounds can be split reductively to release the photographically active compound. Where the photographically active compound is a dye or dye precursor the sulfilimine compounds are suitable dye releasers for color diffusion transfer processes.
    Type: Grant
    Filed: April 18, 1983
    Date of Patent: April 24, 1984
    Assignee: Agfa-Gevaert Aktiengesellschaft
    Inventor: Hans-Heinrich Credner
  • Patent number: 4443537
    Abstract: Substituted hydroquinone compounds of the formula ##STR1## wherein R.sub.1 to R.sub.4 are hydrogen or alkyl and Z is an aromatic ring or a group of the formula --X--Y--X--, wherein X is an aromatic ring and Y is an electron withdrawing group, are incorporated as developers into photographic materials. These materials are suitable for activation processings.
    Type: Grant
    Filed: September 24, 1982
    Date of Patent: April 17, 1984
    Assignee: Ciba-Geigy AG
    Inventors: Stephen R. Postle, Patrick D. P. Thomas, Brian R. D. Whitear
  • Patent number: 4439519
    Abstract: A silver halide photographic light-sensitive material containing a diffusion resistant coupler, a light-sensitive silver halide and at least one compound represented by the following general formula (I) in the same layer or different layers on a support. ##STR1## wherein R.sup.1 and R.sup.2 independently represent an alkyl group having from 1 to 5 carbon atoms, a hydroxyalkyl group having from 1 to 5 carbon atoms, an alkoxyalkyl group having from 2 to 10 carbon atoms or an alkylsulfonamidoalkyl group having from 2 to 10 carbon atoms; R.sup.3 represents a hydrogen atom, an alkyl group having from 1 to 5 carbon atoms or an alkoxy group having from 1 to 5 carbon atoms; X represents a hydrogen atom or a group capable of being removed with alkali; Y represents ##STR2## and Z represents an alkyl group, an alkenyl group, an aryl group or a heterocyclic group.
    Type: Grant
    Filed: May 5, 1983
    Date of Patent: March 27, 1984
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Nobutaka Ohki, Ken Kawata, Isamu Itoh
  • Patent number: 4438195
    Abstract: Silver halide developer compounds containing amino groups and attached in the form of a salt to ion exchangers are embedded in layers of photographic recording material comprising at least one silver halide emulsion layer. In color photographic recording materials, the silver halide emulsion layers may have color-providing compounds associated with them.
    Type: Grant
    Filed: November 3, 1982
    Date of Patent: March 20, 1984
    Assignee: Agfa-Gevaert Aktiengesellschaft
    Inventors: Friedrich-Wilhelm Kunitz, Karl-Wilhelm Schranz
  • Patent number: 4436810
    Abstract: Compounds corresponding to the formula: ##STR1## wherein Z represents a radical which completes a condensed aromatic ring system;R.sup.1 represents an n-valent aliphatic or aromatic radical;R.sup.2 represents H, alkyl or aryl,R.sup.3 represents one or more radicals to control the diffusion properties and the activation pH;andn represents 1 or 2,are suitable ED precursor compounds for use in color-photographic recording materials. They are preferably used in a combination with reducible dye-releasers. They are also suitable as so-called scavengers.
    Type: Grant
    Filed: April 29, 1983
    Date of Patent: March 13, 1984
    Assignee: Agfa-Gevaert Aktiengesellschaft
    Inventors: Karl Kuffner, Paul Marx, Wolfgang Lassig
  • Patent number: 4435499
    Abstract: Photosensitive silver halide grains that are thin tabular grains having an average grain thickness of less than 0.3 microns provide advantages, including improved spectral sensitization and image tone, in a photothermographic material comprising photosensitive silver halide and a photosensitive silver halide processing agent. An image is developed in such an exposed photothermographic material by heating the material, such as to a temperature within the range of about 90.degree. C. to about 180.degree. C.
    Type: Grant
    Filed: January 31, 1983
    Date of Patent: March 6, 1984
    Assignee: Eastman Kodak Company
    Inventor: John W. Reeves
  • Patent number: 4430424
    Abstract: The invention relates to a color photographic light-sensitive material comprising a support and a hydrophilic colloid layer coated thereon, said layer comprising a non-diffusible coupler and a hydrophilic colloid layer having an aromatic primary amine developing agent and/or its precursor and a polymer layer coated thereon wherein said polymer is permeable to an alkaline processing liquid but less permeable to said aromatic primary amine developing agent and/or its precursor, and the diffusion rate of said aromatic primary amine developing agent and/or its precursor, when dissolved in the alkaline processing liquid, in the polymer layer is not greater than 5.times.10.sup.-8 cm.sup.2 /sec per second at room temperature.
    Type: Grant
    Filed: September 1, 1982
    Date of Patent: February 7, 1984
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Ken Okauchi, Tatsuhiko Kobayashi
  • Patent number: 4429036
    Abstract: A method of forming a photographic image which comprises development processing with an alkaline aqueous activator solution a silver halide photographic light-sensitive material comprising a support having thereon at least one surface latent image type silver halide emulsion layer, and containing in at least one layer selected from a silver halide emulsion layer and another hydrophilic colloid-layer (1) a hydroquinone series developing agent and (2) an acylhydrazine compound represented by formula (I):R.sup.1 NHNHCOR.sup.2 (I)wherein R.sup.1 represents an unsubstituted or substituted aryl group or alkyl group; and R.sup.2 represents a hydrogen atom, or an unsubstituted or substituted aryl group or alkyl group,wherein the aqueous activator solution or a prebath thereof contains at least one compound represented by formula (II): ##STR1## wherein each of W.sup.1, W.sup.2, W.sup.3, and W.sup.
    Type: Grant
    Filed: March 31, 1983
    Date of Patent: January 31, 1984
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shigeo Hirano, Yoshihiro Takagi
  • Patent number: 4429050
    Abstract: A method for the simultaneous immunochemical assay of trace components in a sample involving competitively reacting the antigens or antibodies in a sample and labeled antigens or labeled antibodies for limited binding sites. The labels are spectral sensitizing dyes. The reaction products are contacted with silver halide and exposed to light having wavelengths corresponding to the absorption spectra of the spectral sensitizing dyes.
    Type: Grant
    Filed: September 2, 1981
    Date of Patent: January 31, 1984
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yukio Yasuda, Nobuhito Masuda, Yuji Mihara, Masaki Okazaki, Nobuo Hiratsuka
  • Patent number: 4427757
    Abstract: A tannable photographic element and method therefore, the element comprising a uniquely treated opaque, translucent, or transparent base support and having at least one pigment in reactive association with the silver halide emulsion layer is useful in the graphic arts. The base support comprises an extremely thin gelatin subbing layer substantially free of hardener, or no subbing at all, on a primed base support.
    Type: Grant
    Filed: May 18, 1983
    Date of Patent: January 24, 1984
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: George W. Beebe, Michael T. Macioch
  • Patent number: 4426441
    Abstract: In a dye-forming imaging material comprising (a) a dye-forming coupler, and (b) an organic reducing agent that is capable in its oxidized form of reacting with the dye-forming coupler to form a dye, improvements are provided by a reducing agent that is a ureidoaniline silver halide developing agent free of strong electron withdrawing groups. Such an imaging material can be a photographic silver halide material. The imaging material can be a photothermographic material for producing a dye image comprising, in reactive association, (a) photographic silver halide, (b) a dye-forming coupler, and (c) an oxidation-reduction image forming combination comprising (1) an organic silver salt oxidizing agent, and (2) an organic reducing agent for the organic silver salt oxidizing agent, wherein the reducing agent is a ureidoaniline which is capable in its oxidized form of reacting with the dye-forming coupler to form a dye.
    Type: Grant
    Filed: December 3, 1982
    Date of Patent: January 17, 1984
    Assignee: Eastman Kodak Company
    Inventors: Anthony Adin, Roy C. DeSelms
  • Patent number: 4426444
    Abstract: Compounds of the formula ##STR1## wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are hydrogen or alkyl, X represents the atoms to complete an aromatic heterocyclic ring system and Y is hydrogen or the group ##STR2## where X is defined as above, are readily cleaved in alkaline solutions to release a hydroquinone derivative.The compounds can be incorporated into photographic materials used for activation processing.
    Type: Grant
    Filed: September 17, 1982
    Date of Patent: January 17, 1984
    Assignee: Ciba Geigy AG
    Inventors: Stephen R. Postle, Patrick D. P. Thomas
  • Patent number: 4423126
    Abstract: A new color-forming 4-(4'-secondary or tertiary-amino)anilino-1-carboxamidonaphthalene dye precursor in a photographic material and process enables formation of a dye image by means of cross-oxidation without the need for a coupling reaction. The color-forming 4-(4'-secondary or tertiary-amino)anilino-1-carboxamidonaphthalene dye precursor is useful in a photographic silver halide material for producing (i) a dye image, or (ii) a dye image and silver image. The exposed photographic material is processed to produce (a) a positive dye image, (b) a negative dye and negative silver image, (c) a negative dye image or (d) a positive dye image and a positive silver image. New naphthoquinoneimide dyes are also described.
    Type: Grant
    Filed: May 27, 1982
    Date of Patent: December 27, 1983
    Assignee: Eastman Kodak Company
    Inventors: James E. Klijanowicz, Csaba A. Kovacs
  • Patent number: 4421845
    Abstract: A silver halide photographic light-sensitive material which comprises at least one of those pyrazole compounds represented by the following general formula: ##STR1## wherein A is a group which can be eliminated in a photographic process condition; X is ##STR2## wherein R.sub.5 is a hydrogen atom or an alkyl, an aryl, an acyl or a sulfone group, which R.sub.5 group may combine together with R.sub.1 to form a condensed ring; R.sub.1 is a hydrogen atom or an alkyl, an aryl, an acyl, a sulfone, an alkoxy, or a heterocyclic residue; R.sub.2 is a hydrogen atom or an alkyl, an aryl, an alkoxy, an amino, an acid amide, a sulfonamide, a carboxyl, an alkoxycarbonyl, a carbamoyl, a cyano, or a halogenated alkyl group, R.sub.3 and R.sub.
    Type: Grant
    Filed: March 11, 1982
    Date of Patent: December 20, 1983
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Morito Uemura, Kenichi Kishi, Satoshi Nakagawa, Shuji Kida, Hiroshi Sugita
  • Patent number: 4421846
    Abstract: A photographic element containing a nondiffusible metal complex capable of releasing a diffusible photographically useful group. The complex contains at least one poly-dentate ligand which contains the photographically useful group. The complex may be activated when reduced under alkaline conditions to release the photographically useful group.
    Type: Grant
    Filed: December 23, 1981
    Date of Patent: December 20, 1983
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Satoru Ikeuchi, Masaru Kanbe, Jiro Takahashi, Ryuichiro Kobayashi, Shunji Suginaka, Noboru Mizukura
  • Patent number: 4420557
    Abstract: Compounds corresponding to the formula: ##STR1## wherein R.sup.1 represents an aromatic group, andR.sup.2 represents H, alkyl, alkenyl, aryl or acyl, are suitable ED precursor compounds for use in color photographic recording materials. They are preferably used in combination with reducible dye releasers. They are also suitable as so-called scavengers.
    Type: Grant
    Filed: October 25, 1982
    Date of Patent: December 13, 1983
    Assignee: Agfa-Gevaert Aktiengesellschaft
    Inventors: Heinrich Odenwalder, Paul Marx
  • Patent number: 4420551
    Abstract: This application relates to the use of certain dihydro-benzotriazine compounds as photographic silver halide developing agents and to photographic processes, products and compositions which utilize the same. The compounds are effective developers in acid environment as well as in basic environment. Also described are novel dihydro-benzotriazine compounds.
    Type: Grant
    Filed: January 31, 1983
    Date of Patent: December 13, 1983
    Assignee: Polaroid Corporation
    Inventor: Emmett S. McCaskill
  • Patent number: 4419439
    Abstract: A process for forming a photographic image comprising imagewise exposing a silver halide photographic light-sensitive material to light and processing the silver halide photographic light-sensitive material with an alkaline processing solution, wherein the improvement comprises the silver halide photographic light-sensitive material contains a compound represented by formula (I) ##STR1## wherein R represents an alkyl group having from 6 to 22 carbon atoms, a substituted alkyl group having from 6 to 22 carbon atoms, an aryl group having from 6 to 22 carbon atoms, a substituted aryl group having from 6 to 22 carbon atoms, an alkenyl group having from 6 to 22 carbon atoms, a substituted alkenyl group having from 6 to 22 carbon atoms or an aralkyl group having from 7 to 22 carbon atoms; X represents an alkyl group having from 1 to 4 carbon atoms, an alkoxy group having from 1 to 6 carbon atoms, or a halogen atom; and n represents an integer from 1 to 3.
    Type: Grant
    Filed: November 16, 1981
    Date of Patent: December 6, 1983
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shigeru Kuwazima, Eiichi Kato, Minoru Yamada
  • Patent number: 4419433
    Abstract: The present invention relates to a photographic material containing at least one kind of silver halogenide developer in at least one stratum of photograph-constructing layer provided on a support prepared by coating a paper base material with a film-formable resin wherein said paper base material for support is treated with at least one member selected from the group consisting of aminomethanesulfonic acid and its salts. When it is used, the discoloration in said photographic material can be prevented.
    Type: Grant
    Filed: September 27, 1982
    Date of Patent: December 6, 1983
    Assignee: Mitsubishi Paper Mills, Ltd.
    Inventors: Massashi Kubbota, Touru Noda
  • Patent number: 4410618
    Abstract: .alpha.-Ketoimidomethyl blocked photographic reagents are useful in photographic elements, film units and processes. The blocked photographic reagents have the structure: ##STR1## wherein J represents ##STR2## X represents the atoms to complete a 5- or 6-membered ring or ring system; R represents alkyl of 1 to 30 carbon atoms or aryl of 6 to 30 carbon atoms; andPR represents the residue of an organic photographic reagent containing a heteroatom through which it is joined to the blocking group.
    Type: Grant
    Filed: June 11, 1982
    Date of Patent: October 18, 1983
    Assignee: Eastman Kodak Company
    Inventors: James P. Vanmeter, Chin H. Chen
  • Patent number: 4410619
    Abstract: In a photographic material, comprising a photographic constitution layer or layers containing a silver halide developer on a support obtained by coating base paper with a film-forming resin, the use of the base paper treated with a sulfinic acid or a salt thereof prevents the discoloration of the photographic material by the influence of the silver halide developer.
    Type: Grant
    Filed: April 8, 1982
    Date of Patent: October 18, 1983
    Assignee: Mitsubishi Paper Mills, Ltd.
    Inventors: Massashi Kubbota, Touru Noda
  • Patent number: 4409324
    Abstract: A multilayer color photographic sensitive material is disclosed. The material is comprised of a support base and a silver halide emulsion layer. The material contains at least one layer containing a high boiling solvent and an oil-soluble coupler, wherein the volume ratio of solvent to coupler is 1/2 or less, and a compound represented by the general formula (I): ##STR1## wherein X is a hydrogen atom or an acetyl group, R is an aryl group, and R.sub.1, R.sub.2, R.sub.3 and R.sub.4, which may be the same or different, each represents a hydrogen atom, an alkyl group or an aryl group. The material produces sharp images even though it contains a low oil/coupler ratio. Furthermore, there is no retardation of development.
    Type: Grant
    Filed: September 21, 1982
    Date of Patent: October 11, 1983
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takatoshi Ishikawa, Akio Mitsui, Masakazu Morigaki, Takashi Nakamura
  • Patent number: 4407941
    Abstract: A photographic element comprising a support provided thereon with at least one light-sensitive silver halide emulsion layer containing a nondiffusible compound which receives at least one electron in an alkaline condition to release a photographically useful material and a nondiffusible electron donor or a precursor thereof having the following formula (I) or (II): ##STR1## wherein R.sup.1 represents hydrogen, an alkyl, an aryl or a heterocyclic group, R.sup.2 represents hydrogen, an alkyl, an aryl, a heterocyclic, an amino, a carbamide, a sulfonamide, a sulfamoyl, a carbamoyl or a ureido group, R.sup.3 and R.sup.4 each is hydrogen, --COR.sup.5, --SO.sub.2 R.sup.6 or --CSR.sup.7 wherein R.sup.5 and R.sup.6 each is a substituted or unsubstituted, respectively, alkyl, alkenyl, aryl, heterocyclic, alkylamino, alkyloxy, aryloxy, alkylthio, arylthio, alkyloxycarbonyl or aryloxycarbonyl group, and R.sup.7 is a substituted or unsubstituted alkyllamino or arylamino group, said R.sup.
    Type: Grant
    Filed: March 8, 1982
    Date of Patent: October 4, 1983
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Shunji Suginaka, Ryuichiro Kobayashi, Satoru Ikeuchi, Noboru Mizukura, Noriko Fujita
  • Patent number: 4404390
    Abstract: Mesoionic 1,2,4-triazolium-3-thiolate silver halide stabilizer precursors are novel compounds useful in a heat developable and heat stabilizable photographic silver halide materials and processes. After imagewise exposure of the photographic material, a developed and stabilized silver image is produced by heating the element. Mesoionic stabilizer precursors are also useful in photographic silver halide processing compositions.
    Type: Grant
    Filed: November 9, 1981
    Date of Patent: September 13, 1983
    Assignee: Eastman Kodak Company
    Inventors: Henry W. Altland, Daniel D. Shiao
  • Patent number: 4404289
    Abstract: In an immunochemical measurement method of an antigen or antibody which comprises competitively reacting an antigen or antibody labelled with spectral sensitizer and an antigen or antibody to be measured, bringing either the reaction product of immune reaction or the unreacted component into contact with silver halide, exposing the same to light having a wavelength which the spectral sensitizer absorbs, developing the exposed silver, and, measuring optical density of the thus formed silver image and/or colored dye, the contact with silver halide is performed in the presence of a specific hydrazine compound. Thus, detection sensitivity is markedly improved.
    Type: Grant
    Filed: September 2, 1981
    Date of Patent: September 13, 1983
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Nobuhito Masuda, Shigeru Nagatomo, Yuji Mihara
  • Patent number: 4390617
    Abstract: The present invention is directed towards a silver halide photographic material which has a reducing agent for silver halide or a precursor thereof and a compound M.sub.1 H.sub.m (PO.sub.n).sub.i.jH.sub.2 O which generates base when heat is applied. M is a metal from the Groups IA and IIA of the Periodic Table, 1 and i are individually integers from 1 to 3, m is an integer from 0 to 4, n is 3 or 4, and j is an integer from 0 to 12.
    Type: Grant
    Filed: March 5, 1981
    Date of Patent: June 28, 1983
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Kenichiro Okaniwa, Toyoaki Masukawa, Kiyoshi Yamashita, Wataru Ishikawa
  • Patent number: 4388398
    Abstract: This invention relates to photographic products and processes employing silver halide solvent precursors of the formula ##STR1## wherein R.sup.1 is a monovalent organic radical; R.sup.2 is hydrogen or a monovalent organic radical; Z is a moiety that undergoes .beta.-elimination in aqueous alkaline solution and preferably is a moiety that undergoes .beta.-elimination in aqueous alkaline solution to release a photographically useful reagent; and n is an integer 3, 4 or 5.
    Type: Grant
    Filed: March 23, 1982
    Date of Patent: June 14, 1983
    Assignee: Polaroid Corporation
    Inventors: Alan L. Borror, Ernest W. Ellis
  • Patent number: 4382119
    Abstract: This invention relates to photographic products and processes employing silver halide solvent precursors of the formulae ##STR1## wherein R.sup.1 and R.sup.2, the same or different, each are hydrogen, alkyl, phenalkyl, phenyl or phenyl substituted with an electron-donating or electron-withdrawing group; R.sup.3 is alkyl, phenalkyl, phenyl or substituted phenyl; Z is --CN or --SO.sub.2 R.sup.4 wherein R.sup.4 is branched-chain alkyl, phenalkyl, phenyl or substituted phenyl; and n is an integer 3, 4 or 5.
    Type: Grant
    Filed: May 27, 1982
    Date of Patent: May 3, 1983
    Assignee: Polaroid Corporation
    Inventors: Alan L. Borror, Ernest W. Ellis
  • Patent number: 4378424
    Abstract: Mesoionic 1,2,4-triazolium-3-thiolates are silver halide stabilizers and fixing agents. They are useful in heat developable and heat stabilizable photographic silver halide materials and processes. After imagewise exposure of the photographic materials, developed and stabilized silver images are produced by heating the materials. The mesoionic 1,2,4-triazolium-3-thiolates are also silver halide stabilizers and fixing agents in photographic silver halide processing compositions.
    Type: Grant
    Filed: November 24, 1981
    Date of Patent: March 29, 1983
    Assignee: Eastman Kodak Company
    Inventors: Henry W. Altland, Edward L. Dedio, Gary J. McSweeney
  • Patent number: 4371603
    Abstract: This invention relates to amino hydroxy cyclohexenones of the formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each are alkyl, usually containing 1 to 20 carbon atoms.In another embodiment, the present invention is directed to the use of the above-denoted compounds as photographic silver halide developing agents and to photographic processes, products and compositions employing the same.
    Type: Grant
    Filed: December 30, 1980
    Date of Patent: February 1, 1983
    Assignee: Polaroid Corporation
    Inventors: James R. Bartels-Keith, Eva R. Karger
  • Patent number: 4371604
    Abstract: A photographic material for diffusion transfer photography containing a quinonoid compound, which is capable in reduced state and under alkaline conditions of releasing a photographically useful group and corresponds to one of the following general formulae: ##STR1## wherein: each of (Nuox).sup.1 and (Nuox).sup.2 (same or different) represents an oxidized nucleophilic group,Z represents a bivalent atom or bivalent atomic group, which is electro-negative,Q together with the group Z represents a releasable photographically useful group,Y.sup.1 and Y.sup.2 together represent the necessary atoms to close a p-quinonoid ring substituted with (a) directly linked monovalent organic ring or ring system substituent(s) having aromatic character,Y.sup.3 represents the necessary atoms to close a o-quinonoid ring substituted with (a) directly linked monovalent organic ring or ring system substituent(s) having aromatic character, andeach of R.sup.1 and R.sup.
    Type: Grant
    Filed: March 31, 1981
    Date of Patent: February 1, 1983
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Christian C. Van de Sande, Wilhelmus Janssens, Wolfgang Lassig, Ernst Meier
  • Patent number: 4369245
    Abstract: A photographic element for tanning development which comprises a support, a layer of silver halide emulsion in non-hardened gelatin including a tanning developer dispersed therein, and over said emulsion layer, a layer of non-hardened gelatin comprising at least one colored pigment dispersed therein, characterized by the silver in said silver halide emulsion layer being present in a quantity of less than 0.6 g/m.sup.2 with a silver/gelatin ratio of less than 0.4. A method for obtaining a colored relief image in such an element is shown.
    Type: Grant
    Filed: September 8, 1981
    Date of Patent: January 18, 1983
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Marco Beruto, Piero Ramello
  • Patent number: 4368258
    Abstract: In the process for preparing impregnated polymer latex compositions by impregnating a hydrophobic substance in dispersed polymer particles in an aqueous polymer latex, the improvement comprises impregnating said hydrophobic substance, wherein the impregnation is effected by mixing said hydrophobic substance which is solid state, a water-miscible organic solvent and aqueous polymer latex wherein a polymer of the polymer latex is prepared from ethene monomers and containing at least one hydrophilic group.
    Type: Grant
    Filed: March 11, 1981
    Date of Patent: January 11, 1983
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Mitsuto Fujiwhara, Syunji Matsuo, Tsuneo Wada, Naoto Abe, Toyoaki Masukawa, Akio Iijima, Keiji Oishi
  • Patent number: 4358532
    Abstract: A photographic element containing a compound represented by formula (I) ##STR1## wherein G represents --OR.sup.1 or --NHR.sup.2, R.sup.1 represents hydrogen or a hydrolyzable moiety, R.sup.2 represents hydrogen or an alkyl group containing from 1 to 50 carbon atoms, Z represents a photographically useful group, A represents an atomic group forming an aromatic ring, Ball represents an organic immobilizing group on the aromatic ring, which cntains from 8 to 50 carbon atoms, m represents an integer of 1 or 2, X represents a divalent organic group, Nu represents a nucleophilic group, and n represents an integer of 1 or 2, and X with the nucleophilic group Nu is capable of forming a 5- to 12-membered ring by oxidation having an electrophilic center at the carbon atom substituted by the --NHSO.sub.2 Z group.
    Type: Grant
    Filed: July 15, 1981
    Date of Patent: November 9, 1982
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Koichi Koyama, Shinsaku Fujita
  • Patent number: 4358525
    Abstract: Photographically useful compounds such as photographic reagents and photographic dyes are blocked with a grouping which, under alkaline conditions, is cleaved from the compound by an intramolecular nucleophilic displacement reaction. The compounds are resistant to unblocking under storage conditions, but are uniformly unblocked under conditions encountered during photographic processing.
    Type: Grant
    Filed: August 12, 1981
    Date of Patent: November 9, 1982
    Assignee: Eastman Kodak Company
    Inventors: Jared B. Mooberry, William C. Archie, Jr.
  • Patent number: 4358533
    Abstract: A silver halide photographic material having a hydrophilic colloid layer comprising fine polymer particles loaded with a hydrophobic photographic addenda provided on a support wherein the polymer has repeating units formed from a nonionic hydrophobic monomer. The nonionic hydrophobic monomer has the formula ##STR1## R.sub.1 and R.sub.2 individually are a hydrogen atom or methyl group, R.sub.3 is a hydrogen atom, an alkyl or aryl group, and m and n are integers of from 2 to 100 individually.
    Type: Grant
    Filed: March 11, 1981
    Date of Patent: November 9, 1982
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Kouji Tokitou, Tsuneo Wada
  • Patent number: 4351896
    Abstract: Mesoionic 1,2,4-triazolium-3-thiolate silver halide stabilizer precursors are novel compounds useful in a heat developable and heat stabilizable photographic silver halide materials and processes. After imagewise exposure of the photographic material, a developed and stabilized silver image is produced by heating the element. Mesoionic stabilizer precursors are also useful in photographic silver halide processing compositions.
    Type: Grant
    Filed: November 9, 1981
    Date of Patent: September 28, 1982
    Assignee: Eastman Kodak Company
    Inventors: Henry W. Altland, Daniel D. Shiao
  • Patent number: 4350752
    Abstract: Imidomethyl blocked photographic reagents are useful in photographic elements, film units and processes. The blocked photographic reagents have the structure: ##STR1## wherein: J represents ##STR2## X represents the atoms to complete a 5- or 6-membered ring or ring system; R represents hydrogen, alkyl or 1 to 4 carbon atoms or aryl of 6 to 12 carbon atoms; andPR represents the residue of an organic photographic reagent containing a heteroatom through which it is joined to the imidomethyl blocking group.
    Type: Grant
    Filed: December 29, 1980
    Date of Patent: September 21, 1982
    Assignee: Eastman Kodak Company
    Inventors: James A. Reczek, Thomas R. Welter
  • Patent number: 4346154
    Abstract: A stain retarding concentration of a phosphine antistain agent or phosphine antistain agent precursor in the undercoat layer of a photographic silver halide element comprising a support having thereon (a) a photographic silver halide gelatino emulsion layer, and (b) an undercoat layer between the emulsion layer and the support, provides reduced stain in the element upon exposure and processing. The photographic element preferably comprises a silver halide developing agent. The photographic element, after exposure, is preferably processed by means of an aqueous alkaline activator bath and then an aqueous thiosulfate stabilizer bath.
    Type: Grant
    Filed: June 22, 1981
    Date of Patent: August 24, 1982
    Assignee: Eastman Kodak Company
    Inventors: Donald F. McLaen, Arthur H. Herz
  • Patent number: 4345019
    Abstract: Transfer silver images high in maximum density, contrast and sharpness and small in dependency on developing temperatures are obtained by image wise exposing and developing a diffusion transfer light sensitive material which comprises a support having thereon at least a carbon black-containing layer and a silver halide emulsion layer present on said carbon black containing layer, said carbon black-containing layer and/or layer adjacent thereto containing 3-pyrazolidone compound represented by the following general formula: ##STR1## wherein R.sub.1 and R.sub.2 are hydroxyalkyl or alkyl group of 1-4 carbon atoms, at least one of R.sub.1 and R.sub.2 being hydroxyalkyl group and R.sub.3 is an aryl group.
    Type: Grant
    Filed: April 17, 1981
    Date of Patent: August 17, 1982
    Assignee: Mitsubishi Paper Mills, Ltd.
    Inventor: Isao Kohmura
  • Patent number: 4336321
    Abstract: In a silver halide photographic material, at least one mercapto complexing agent for silver salt is contained in at least one photographic constituting layer and at least one anion or betaine type cyanine sensitizing dye is contained in silver halide emulsion layer to improve photographic defects such as reduction of sensitivity, softening in tone, etc.
    Type: Grant
    Filed: February 4, 1981
    Date of Patent: June 22, 1982
    Assignee: Mitsubishi Paper Mills, Ltd.
    Inventors: Eiji Kanada, Yasuo Tsubai, Shoji Yamada, Yoshikazu Takaya, Takao Senga
  • Patent number: 4330617
    Abstract: The compounds represented by the general formula (I) or (II) as defined in the specification are novel and useful developing agent precursors in silver halide photographic light sensitive materials.
    Type: Grant
    Filed: February 4, 1981
    Date of Patent: May 18, 1982
    Assignee: Mitsubishi Paper Mills, Ltd.
    Inventors: Minoru Ohashi, Katsuaki Iwaosa
  • Patent number: 4324856
    Abstract: A photographic silver halide material is disclosed which contains a precursor of photographic chemicals.
    Type: Grant
    Filed: October 7, 1980
    Date of Patent: April 13, 1982
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Satoshi Kawakatsu, Shigeto Hirabayashi, Hidetaka Ninomiya, Yutaka Kaneko