Developing Or Fixing Agents Containing For Liquid Processing Patents (Class 430/566)
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Patent number: 4458009Abstract: Color photographic images are produced by decomposing hydrogen peroxide on nuclei present in imagewise distribution and bleaching out a dye by the hydrogen peroxide on those parts of the image where no such nuclei are present.Type: GrantFiled: January 10, 1983Date of Patent: July 3, 1984Assignee: Agfa-Gevaert AktiengesellschaftInventors: Edith Weyde, Wilhelm Saleck, Hubertus Psaar, Anita von Konig, Hans hlschlager
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Patent number: 4458010Abstract: A process for bleaching color photographic sensitive materials and color photographic sensitive materials are disclosed. The process comprises bleaching the silver halide color photographic sensitive materials which are comprised of a support base, a silver halide emulsion layer, and a compound represented by the general formula (I) or strong acid salts thereof in a layer which does not substantially form silver salts of said compounds with a treating solution containing persulfate after being exposed to the light and carrying out color development: ##STR1## wherein M represents a hydrogen atom, an alkali metal atom, an alkaline earth metal, a quaternary ammonium group, a quaternary phosphonium group, an amidino group or ##STR2## R.sup.1 and R.sup.2 each represents a hydrogen atom or an aliphatic group, and m represents an integer of 2 to 4. The bleaching process effectively bleaches color sensitive materials having a high silver content and/or a colloidal silver layer without creating a bad odor.Type: GrantFiled: November 12, 1982Date of Patent: July 3, 1984Assignee: Fuji Photo Film Co., Ltd.Inventors: Kiyohiko Yamamuro, Shigeo Hirano, Yasuo Iwasa
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Patent number: 4456682Abstract: A silver halide color photographic material is disclosed. The material has improved developing characteristics which are obtained by containing both a substantially light-insensitive silver halide and at least one specific 3-pyrazolidone compound. The substantially light-insensitive silver halide includes a halogen composition consisting of 0 to 100 percent of bromide, 0 to 2 percent of iodine and the residual percent of chlorine, a mean grain size of 0.01 to 0.3.mu., and a coverage of 5 to 500 mg/m.sup.2. The 3-pyrazolidone compound has the following general formula (I): ##STR1## wherein X represents a hydrogen atom or an acetyl group; R represents an aryl group; and R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each represents a hydrogen atom, an alkyl group or an aryl group, and they may be the same as or different from one another. The material can be developed at an increased speed and is not accompanied by undesirable photographic effects such as fogging.Type: GrantFiled: September 21, 1982Date of Patent: June 26, 1984Assignee: Fuji Photo Film Co., Ltd.Inventors: Takatoshi Ishikawa, Akio Mitsui, Masakazu Morigaki, Takashi Nakamura
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Patent number: 4450223Abstract: A photographic silver halide material comprising a compound which is capable of being reduced by a silver halide developing agent at a rate slower than that of image-wise developable silver halide and in reduced state is capable of releasing a photographically useful group, characterized in that said compound corresponds to the following formula: ##STR1## wherein: R.sup.10 and R.sup.20 (same or different)(1) represent an alkyl group, a cycloalkyl group, an alkenyl group, a cycloalkenyl group or an aralkyl group including said groups in substituted form,(2) represent an aryl group including a substituted aryl group, or(3) represent a heterocyclic ring residue including such residue in substituted form, orR.sup.10 and R.sup.20 are ringclosed, either R.sup.10 or R.sup.20 containing a ballasting group conferring diffusion resistance to the compound in hydrophilic colloid media when penetrated by an aqueous alkaline liquid;L.sup.1 and L.sup.2 (same or different) represent a ##STR2## --SO.sub.Type: GrantFiled: February 14, 1983Date of Patent: May 22, 1984Assignee: AGFA-Gevaert, N.V.Inventors: Raphael K. Van Poucke, Christian C. Van de Sande, Andree Verhecken
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Patent number: 4448850Abstract: Polymers having excellent adherence to film supports such as cellulose acetate are disclosed. The polymers comprise random recurring units having the structure--A).sub.w, --B).sub.x, --C).sub.y and --D).sub.zwherein;A represents polymerized vinyl acetate;B represents a polymerized acrylate or methacrylate monomer capable of copolymerization with vinyl acetate;C represents a polymerized monomer selected from the group consisting of methacrylic acid, itaconic acid and vinylbenzoic acid;D represents a polymerized cationically charged copolymerizable monomer;w represents from 20 to 85 weight percent;x represents from 5 to 65 weight percent;y represents from 5 to 50 weight percent and;z represents from 0 to 15 weight percent.Type: GrantFiled: July 23, 1982Date of Patent: May 15, 1984Assignee: Eastman Kodak CompanyInventors: Donald A. Upson, David J. Steklenski
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Patent number: 4447522Abstract: A method of forming a photographic image which comprises development processing with an alkaline activator solution a silver halide photographic light-sensitive material comprising a support having thereon at least one surface latent image type silver halide emulsion layer, and containing in at least one layer selected from the silver halide emulsion layer and another hydrophilic colloid layer(1) a developing agents;(2) an acylhydrazine compound represented by formula (I):R.sup.1 NHNHCOR.sup.2 (I)wherein R.sup.1 represents an unsubstituted or substituted aryl group or alkyl group; and R.sup.2 represents a hydrogen atom, or an unsubstituted or substituted aryl group or alkyl group; and(3) at least one compound represented by formula (II): ##STR1## wherein each of W.sup.1 and W.sup.2 can represent a hydrogen atom or an aliphatic group or W.sup.1 and W.sup.2 are bonded each other to form a ring; W.sup.3 represents a divalent aliphatic group; Q.sup.Type: GrantFiled: April 18, 1983Date of Patent: May 8, 1984Assignee: Fuji Photo Film Co., Ltd.Inventors: Shigeo Hirano, Yoshihiro Takagi
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Patent number: 4446216Abstract: Photographic material which comprises in at least one silver halide emulsion layer or a layer or layers adjacent thereto at least one substituted hydroquinone compound of the formula ##STR1## where R is hydrogen or optionally substituted alkyl, aryl or a heterocyclic group, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 are each hydrogen, halogen or optionally substituted alkyl,x is 0 or 1,y is 0 or 1,and R.sub.1 is hydrogen or a group of the formula ##STR2## where R, x and y are as just defined.Type: GrantFiled: November 23, 1982Date of Patent: May 1, 1984Inventors: Norman A. Smith, Stephen R. Postle, William E. Long
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Patent number: 4444867Abstract: Sulfilimine compounds of formula I ##STR1## wherein X is the integrating residue of a photographically active compound H.sub.2 N--A--X andA is a linking member between X and N consisting of a benzene ring having at least two electron-attracting groupsare suitable compounds for photographic recording materials. The compounds can be split reductively to release the photographically active compound. Where the photographically active compound is a dye or dye precursor the sulfilimine compounds are suitable dye releasers for color diffusion transfer processes.Type: GrantFiled: April 18, 1983Date of Patent: April 24, 1984Assignee: Agfa-Gevaert AktiengesellschaftInventor: Hans-Heinrich Credner
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Patent number: 4443537Abstract: Substituted hydroquinone compounds of the formula ##STR1## wherein R.sub.1 to R.sub.4 are hydrogen or alkyl and Z is an aromatic ring or a group of the formula --X--Y--X--, wherein X is an aromatic ring and Y is an electron withdrawing group, are incorporated as developers into photographic materials. These materials are suitable for activation processings.Type: GrantFiled: September 24, 1982Date of Patent: April 17, 1984Assignee: Ciba-Geigy AGInventors: Stephen R. Postle, Patrick D. P. Thomas, Brian R. D. Whitear
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Patent number: 4439519Abstract: A silver halide photographic light-sensitive material containing a diffusion resistant coupler, a light-sensitive silver halide and at least one compound represented by the following general formula (I) in the same layer or different layers on a support. ##STR1## wherein R.sup.1 and R.sup.2 independently represent an alkyl group having from 1 to 5 carbon atoms, a hydroxyalkyl group having from 1 to 5 carbon atoms, an alkoxyalkyl group having from 2 to 10 carbon atoms or an alkylsulfonamidoalkyl group having from 2 to 10 carbon atoms; R.sup.3 represents a hydrogen atom, an alkyl group having from 1 to 5 carbon atoms or an alkoxy group having from 1 to 5 carbon atoms; X represents a hydrogen atom or a group capable of being removed with alkali; Y represents ##STR2## and Z represents an alkyl group, an alkenyl group, an aryl group or a heterocyclic group.Type: GrantFiled: May 5, 1983Date of Patent: March 27, 1984Assignee: Fuji Photo Film Co., Ltd.Inventors: Nobutaka Ohki, Ken Kawata, Isamu Itoh
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Patent number: 4438195Abstract: Silver halide developer compounds containing amino groups and attached in the form of a salt to ion exchangers are embedded in layers of photographic recording material comprising at least one silver halide emulsion layer. In color photographic recording materials, the silver halide emulsion layers may have color-providing compounds associated with them.Type: GrantFiled: November 3, 1982Date of Patent: March 20, 1984Assignee: Agfa-Gevaert AktiengesellschaftInventors: Friedrich-Wilhelm Kunitz, Karl-Wilhelm Schranz
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Patent number: 4436810Abstract: Compounds corresponding to the formula: ##STR1## wherein Z represents a radical which completes a condensed aromatic ring system;R.sup.1 represents an n-valent aliphatic or aromatic radical;R.sup.2 represents H, alkyl or aryl,R.sup.3 represents one or more radicals to control the diffusion properties and the activation pH;andn represents 1 or 2,are suitable ED precursor compounds for use in color-photographic recording materials. They are preferably used in a combination with reducible dye-releasers. They are also suitable as so-called scavengers.Type: GrantFiled: April 29, 1983Date of Patent: March 13, 1984Assignee: Agfa-Gevaert AktiengesellschaftInventors: Karl Kuffner, Paul Marx, Wolfgang Lassig
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Patent number: 4435499Abstract: Photosensitive silver halide grains that are thin tabular grains having an average grain thickness of less than 0.3 microns provide advantages, including improved spectral sensitization and image tone, in a photothermographic material comprising photosensitive silver halide and a photosensitive silver halide processing agent. An image is developed in such an exposed photothermographic material by heating the material, such as to a temperature within the range of about 90.degree. C. to about 180.degree. C.Type: GrantFiled: January 31, 1983Date of Patent: March 6, 1984Assignee: Eastman Kodak CompanyInventor: John W. Reeves
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Patent number: 4430424Abstract: The invention relates to a color photographic light-sensitive material comprising a support and a hydrophilic colloid layer coated thereon, said layer comprising a non-diffusible coupler and a hydrophilic colloid layer having an aromatic primary amine developing agent and/or its precursor and a polymer layer coated thereon wherein said polymer is permeable to an alkaline processing liquid but less permeable to said aromatic primary amine developing agent and/or its precursor, and the diffusion rate of said aromatic primary amine developing agent and/or its precursor, when dissolved in the alkaline processing liquid, in the polymer layer is not greater than 5.times.10.sup.-8 cm.sup.2 /sec per second at room temperature.Type: GrantFiled: September 1, 1982Date of Patent: February 7, 1984Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Ken Okauchi, Tatsuhiko Kobayashi
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Patent number: 4429036Abstract: A method of forming a photographic image which comprises development processing with an alkaline aqueous activator solution a silver halide photographic light-sensitive material comprising a support having thereon at least one surface latent image type silver halide emulsion layer, and containing in at least one layer selected from a silver halide emulsion layer and another hydrophilic colloid-layer (1) a hydroquinone series developing agent and (2) an acylhydrazine compound represented by formula (I):R.sup.1 NHNHCOR.sup.2 (I)wherein R.sup.1 represents an unsubstituted or substituted aryl group or alkyl group; and R.sup.2 represents a hydrogen atom, or an unsubstituted or substituted aryl group or alkyl group,wherein the aqueous activator solution or a prebath thereof contains at least one compound represented by formula (II): ##STR1## wherein each of W.sup.1, W.sup.2, W.sup.3, and W.sup.Type: GrantFiled: March 31, 1983Date of Patent: January 31, 1984Assignee: Fuji Photo Film Co., Ltd.Inventors: Shigeo Hirano, Yoshihiro Takagi
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Patent number: 4429050Abstract: A method for the simultaneous immunochemical assay of trace components in a sample involving competitively reacting the antigens or antibodies in a sample and labeled antigens or labeled antibodies for limited binding sites. The labels are spectral sensitizing dyes. The reaction products are contacted with silver halide and exposed to light having wavelengths corresponding to the absorption spectra of the spectral sensitizing dyes.Type: GrantFiled: September 2, 1981Date of Patent: January 31, 1984Assignee: Fuji Photo Film Co., Ltd.Inventors: Yukio Yasuda, Nobuhito Masuda, Yuji Mihara, Masaki Okazaki, Nobuo Hiratsuka
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Patent number: 4427757Abstract: A tannable photographic element and method therefore, the element comprising a uniquely treated opaque, translucent, or transparent base support and having at least one pigment in reactive association with the silver halide emulsion layer is useful in the graphic arts. The base support comprises an extremely thin gelatin subbing layer substantially free of hardener, or no subbing at all, on a primed base support.Type: GrantFiled: May 18, 1983Date of Patent: January 24, 1984Assignee: Minnesota Mining and Manufacturing CompanyInventors: George W. Beebe, Michael T. Macioch
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Patent number: 4426441Abstract: In a dye-forming imaging material comprising (a) a dye-forming coupler, and (b) an organic reducing agent that is capable in its oxidized form of reacting with the dye-forming coupler to form a dye, improvements are provided by a reducing agent that is a ureidoaniline silver halide developing agent free of strong electron withdrawing groups. Such an imaging material can be a photographic silver halide material. The imaging material can be a photothermographic material for producing a dye image comprising, in reactive association, (a) photographic silver halide, (b) a dye-forming coupler, and (c) an oxidation-reduction image forming combination comprising (1) an organic silver salt oxidizing agent, and (2) an organic reducing agent for the organic silver salt oxidizing agent, wherein the reducing agent is a ureidoaniline which is capable in its oxidized form of reacting with the dye-forming coupler to form a dye.Type: GrantFiled: December 3, 1982Date of Patent: January 17, 1984Assignee: Eastman Kodak CompanyInventors: Anthony Adin, Roy C. DeSelms
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Patent number: 4426444Abstract: Compounds of the formula ##STR1## wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are hydrogen or alkyl, X represents the atoms to complete an aromatic heterocyclic ring system and Y is hydrogen or the group ##STR2## where X is defined as above, are readily cleaved in alkaline solutions to release a hydroquinone derivative.The compounds can be incorporated into photographic materials used for activation processing.Type: GrantFiled: September 17, 1982Date of Patent: January 17, 1984Assignee: Ciba Geigy AGInventors: Stephen R. Postle, Patrick D. P. Thomas
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Patent number: 4423126Abstract: A new color-forming 4-(4'-secondary or tertiary-amino)anilino-1-carboxamidonaphthalene dye precursor in a photographic material and process enables formation of a dye image by means of cross-oxidation without the need for a coupling reaction. The color-forming 4-(4'-secondary or tertiary-amino)anilino-1-carboxamidonaphthalene dye precursor is useful in a photographic silver halide material for producing (i) a dye image, or (ii) a dye image and silver image. The exposed photographic material is processed to produce (a) a positive dye image, (b) a negative dye and negative silver image, (c) a negative dye image or (d) a positive dye image and a positive silver image. New naphthoquinoneimide dyes are also described.Type: GrantFiled: May 27, 1982Date of Patent: December 27, 1983Assignee: Eastman Kodak CompanyInventors: James E. Klijanowicz, Csaba A. Kovacs
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Patent number: 4421845Abstract: A silver halide photographic light-sensitive material which comprises at least one of those pyrazole compounds represented by the following general formula: ##STR1## wherein A is a group which can be eliminated in a photographic process condition; X is ##STR2## wherein R.sub.5 is a hydrogen atom or an alkyl, an aryl, an acyl or a sulfone group, which R.sub.5 group may combine together with R.sub.1 to form a condensed ring; R.sub.1 is a hydrogen atom or an alkyl, an aryl, an acyl, a sulfone, an alkoxy, or a heterocyclic residue; R.sub.2 is a hydrogen atom or an alkyl, an aryl, an alkoxy, an amino, an acid amide, a sulfonamide, a carboxyl, an alkoxycarbonyl, a carbamoyl, a cyano, or a halogenated alkyl group, R.sub.3 and R.sub.Type: GrantFiled: March 11, 1982Date of Patent: December 20, 1983Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Morito Uemura, Kenichi Kishi, Satoshi Nakagawa, Shuji Kida, Hiroshi Sugita
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Patent number: 4421846Abstract: A photographic element containing a nondiffusible metal complex capable of releasing a diffusible photographically useful group. The complex contains at least one poly-dentate ligand which contains the photographically useful group. The complex may be activated when reduced under alkaline conditions to release the photographically useful group.Type: GrantFiled: December 23, 1981Date of Patent: December 20, 1983Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Satoru Ikeuchi, Masaru Kanbe, Jiro Takahashi, Ryuichiro Kobayashi, Shunji Suginaka, Noboru Mizukura
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Patent number: 4420557Abstract: Compounds corresponding to the formula: ##STR1## wherein R.sup.1 represents an aromatic group, andR.sup.2 represents H, alkyl, alkenyl, aryl or acyl, are suitable ED precursor compounds for use in color photographic recording materials. They are preferably used in combination with reducible dye releasers. They are also suitable as so-called scavengers.Type: GrantFiled: October 25, 1982Date of Patent: December 13, 1983Assignee: Agfa-Gevaert AktiengesellschaftInventors: Heinrich Odenwalder, Paul Marx
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Patent number: 4420551Abstract: This application relates to the use of certain dihydro-benzotriazine compounds as photographic silver halide developing agents and to photographic processes, products and compositions which utilize the same. The compounds are effective developers in acid environment as well as in basic environment. Also described are novel dihydro-benzotriazine compounds.Type: GrantFiled: January 31, 1983Date of Patent: December 13, 1983Assignee: Polaroid CorporationInventor: Emmett S. McCaskill
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Patent number: 4419439Abstract: A process for forming a photographic image comprising imagewise exposing a silver halide photographic light-sensitive material to light and processing the silver halide photographic light-sensitive material with an alkaline processing solution, wherein the improvement comprises the silver halide photographic light-sensitive material contains a compound represented by formula (I) ##STR1## wherein R represents an alkyl group having from 6 to 22 carbon atoms, a substituted alkyl group having from 6 to 22 carbon atoms, an aryl group having from 6 to 22 carbon atoms, a substituted aryl group having from 6 to 22 carbon atoms, an alkenyl group having from 6 to 22 carbon atoms, a substituted alkenyl group having from 6 to 22 carbon atoms or an aralkyl group having from 7 to 22 carbon atoms; X represents an alkyl group having from 1 to 4 carbon atoms, an alkoxy group having from 1 to 6 carbon atoms, or a halogen atom; and n represents an integer from 1 to 3.Type: GrantFiled: November 16, 1981Date of Patent: December 6, 1983Assignee: Fuji Photo Film Co., Ltd.Inventors: Shigeru Kuwazima, Eiichi Kato, Minoru Yamada
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Patent number: 4419433Abstract: The present invention relates to a photographic material containing at least one kind of silver halogenide developer in at least one stratum of photograph-constructing layer provided on a support prepared by coating a paper base material with a film-formable resin wherein said paper base material for support is treated with at least one member selected from the group consisting of aminomethanesulfonic acid and its salts. When it is used, the discoloration in said photographic material can be prevented.Type: GrantFiled: September 27, 1982Date of Patent: December 6, 1983Assignee: Mitsubishi Paper Mills, Ltd.Inventors: Massashi Kubbota, Touru Noda
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Patent number: 4410618Abstract: .alpha.-Ketoimidomethyl blocked photographic reagents are useful in photographic elements, film units and processes. The blocked photographic reagents have the structure: ##STR1## wherein J represents ##STR2## X represents the atoms to complete a 5- or 6-membered ring or ring system; R represents alkyl of 1 to 30 carbon atoms or aryl of 6 to 30 carbon atoms; andPR represents the residue of an organic photographic reagent containing a heteroatom through which it is joined to the blocking group.Type: GrantFiled: June 11, 1982Date of Patent: October 18, 1983Assignee: Eastman Kodak CompanyInventors: James P. Vanmeter, Chin H. Chen
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Patent number: 4410619Abstract: In a photographic material, comprising a photographic constitution layer or layers containing a silver halide developer on a support obtained by coating base paper with a film-forming resin, the use of the base paper treated with a sulfinic acid or a salt thereof prevents the discoloration of the photographic material by the influence of the silver halide developer.Type: GrantFiled: April 8, 1982Date of Patent: October 18, 1983Assignee: Mitsubishi Paper Mills, Ltd.Inventors: Massashi Kubbota, Touru Noda
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Patent number: 4409324Abstract: A multilayer color photographic sensitive material is disclosed. The material is comprised of a support base and a silver halide emulsion layer. The material contains at least one layer containing a high boiling solvent and an oil-soluble coupler, wherein the volume ratio of solvent to coupler is 1/2 or less, and a compound represented by the general formula (I): ##STR1## wherein X is a hydrogen atom or an acetyl group, R is an aryl group, and R.sub.1, R.sub.2, R.sub.3 and R.sub.4, which may be the same or different, each represents a hydrogen atom, an alkyl group or an aryl group. The material produces sharp images even though it contains a low oil/coupler ratio. Furthermore, there is no retardation of development.Type: GrantFiled: September 21, 1982Date of Patent: October 11, 1983Assignee: Fuji Photo Film Co., Ltd.Inventors: Takatoshi Ishikawa, Akio Mitsui, Masakazu Morigaki, Takashi Nakamura
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Patent number: 4407941Abstract: A photographic element comprising a support provided thereon with at least one light-sensitive silver halide emulsion layer containing a nondiffusible compound which receives at least one electron in an alkaline condition to release a photographically useful material and a nondiffusible electron donor or a precursor thereof having the following formula (I) or (II): ##STR1## wherein R.sup.1 represents hydrogen, an alkyl, an aryl or a heterocyclic group, R.sup.2 represents hydrogen, an alkyl, an aryl, a heterocyclic, an amino, a carbamide, a sulfonamide, a sulfamoyl, a carbamoyl or a ureido group, R.sup.3 and R.sup.4 each is hydrogen, --COR.sup.5, --SO.sub.2 R.sup.6 or --CSR.sup.7 wherein R.sup.5 and R.sup.6 each is a substituted or unsubstituted, respectively, alkyl, alkenyl, aryl, heterocyclic, alkylamino, alkyloxy, aryloxy, alkylthio, arylthio, alkyloxycarbonyl or aryloxycarbonyl group, and R.sup.7 is a substituted or unsubstituted alkyllamino or arylamino group, said R.sup.Type: GrantFiled: March 8, 1982Date of Patent: October 4, 1983Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Shunji Suginaka, Ryuichiro Kobayashi, Satoru Ikeuchi, Noboru Mizukura, Noriko Fujita
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Patent number: 4404390Abstract: Mesoionic 1,2,4-triazolium-3-thiolate silver halide stabilizer precursors are novel compounds useful in a heat developable and heat stabilizable photographic silver halide materials and processes. After imagewise exposure of the photographic material, a developed and stabilized silver image is produced by heating the element. Mesoionic stabilizer precursors are also useful in photographic silver halide processing compositions.Type: GrantFiled: November 9, 1981Date of Patent: September 13, 1983Assignee: Eastman Kodak CompanyInventors: Henry W. Altland, Daniel D. Shiao
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Patent number: 4404289Abstract: In an immunochemical measurement method of an antigen or antibody which comprises competitively reacting an antigen or antibody labelled with spectral sensitizer and an antigen or antibody to be measured, bringing either the reaction product of immune reaction or the unreacted component into contact with silver halide, exposing the same to light having a wavelength which the spectral sensitizer absorbs, developing the exposed silver, and, measuring optical density of the thus formed silver image and/or colored dye, the contact with silver halide is performed in the presence of a specific hydrazine compound. Thus, detection sensitivity is markedly improved.Type: GrantFiled: September 2, 1981Date of Patent: September 13, 1983Assignee: Fuji Photo Film Co., Ltd.Inventors: Nobuhito Masuda, Shigeru Nagatomo, Yuji Mihara
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Patent number: 4390617Abstract: The present invention is directed towards a silver halide photographic material which has a reducing agent for silver halide or a precursor thereof and a compound M.sub.1 H.sub.m (PO.sub.n).sub.i.jH.sub.2 O which generates base when heat is applied. M is a metal from the Groups IA and IIA of the Periodic Table, 1 and i are individually integers from 1 to 3, m is an integer from 0 to 4, n is 3 or 4, and j is an integer from 0 to 12.Type: GrantFiled: March 5, 1981Date of Patent: June 28, 1983Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Kenichiro Okaniwa, Toyoaki Masukawa, Kiyoshi Yamashita, Wataru Ishikawa
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Patent number: 4388398Abstract: This invention relates to photographic products and processes employing silver halide solvent precursors of the formula ##STR1## wherein R.sup.1 is a monovalent organic radical; R.sup.2 is hydrogen or a monovalent organic radical; Z is a moiety that undergoes .beta.-elimination in aqueous alkaline solution and preferably is a moiety that undergoes .beta.-elimination in aqueous alkaline solution to release a photographically useful reagent; and n is an integer 3, 4 or 5.Type: GrantFiled: March 23, 1982Date of Patent: June 14, 1983Assignee: Polaroid CorporationInventors: Alan L. Borror, Ernest W. Ellis
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Patent number: 4382119Abstract: This invention relates to photographic products and processes employing silver halide solvent precursors of the formulae ##STR1## wherein R.sup.1 and R.sup.2, the same or different, each are hydrogen, alkyl, phenalkyl, phenyl or phenyl substituted with an electron-donating or electron-withdrawing group; R.sup.3 is alkyl, phenalkyl, phenyl or substituted phenyl; Z is --CN or --SO.sub.2 R.sup.4 wherein R.sup.4 is branched-chain alkyl, phenalkyl, phenyl or substituted phenyl; and n is an integer 3, 4 or 5.Type: GrantFiled: May 27, 1982Date of Patent: May 3, 1983Assignee: Polaroid CorporationInventors: Alan L. Borror, Ernest W. Ellis
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Patent number: 4378424Abstract: Mesoionic 1,2,4-triazolium-3-thiolates are silver halide stabilizers and fixing agents. They are useful in heat developable and heat stabilizable photographic silver halide materials and processes. After imagewise exposure of the photographic materials, developed and stabilized silver images are produced by heating the materials. The mesoionic 1,2,4-triazolium-3-thiolates are also silver halide stabilizers and fixing agents in photographic silver halide processing compositions.Type: GrantFiled: November 24, 1981Date of Patent: March 29, 1983Assignee: Eastman Kodak CompanyInventors: Henry W. Altland, Edward L. Dedio, Gary J. McSweeney
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Patent number: 4371603Abstract: This invention relates to amino hydroxy cyclohexenones of the formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each are alkyl, usually containing 1 to 20 carbon atoms.In another embodiment, the present invention is directed to the use of the above-denoted compounds as photographic silver halide developing agents and to photographic processes, products and compositions employing the same.Type: GrantFiled: December 30, 1980Date of Patent: February 1, 1983Assignee: Polaroid CorporationInventors: James R. Bartels-Keith, Eva R. Karger
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Patent number: 4371604Abstract: A photographic material for diffusion transfer photography containing a quinonoid compound, which is capable in reduced state and under alkaline conditions of releasing a photographically useful group and corresponds to one of the following general formulae: ##STR1## wherein: each of (Nuox).sup.1 and (Nuox).sup.2 (same or different) represents an oxidized nucleophilic group,Z represents a bivalent atom or bivalent atomic group, which is electro-negative,Q together with the group Z represents a releasable photographically useful group,Y.sup.1 and Y.sup.2 together represent the necessary atoms to close a p-quinonoid ring substituted with (a) directly linked monovalent organic ring or ring system substituent(s) having aromatic character,Y.sup.3 represents the necessary atoms to close a o-quinonoid ring substituted with (a) directly linked monovalent organic ring or ring system substituent(s) having aromatic character, andeach of R.sup.1 and R.sup.Type: GrantFiled: March 31, 1981Date of Patent: February 1, 1983Assignee: Agfa-Gevaert, N.V.Inventors: Christian C. Van de Sande, Wilhelmus Janssens, Wolfgang Lassig, Ernst Meier
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Patent number: 4369245Abstract: A photographic element for tanning development which comprises a support, a layer of silver halide emulsion in non-hardened gelatin including a tanning developer dispersed therein, and over said emulsion layer, a layer of non-hardened gelatin comprising at least one colored pigment dispersed therein, characterized by the silver in said silver halide emulsion layer being present in a quantity of less than 0.6 g/m.sup.2 with a silver/gelatin ratio of less than 0.4. A method for obtaining a colored relief image in such an element is shown.Type: GrantFiled: September 8, 1981Date of Patent: January 18, 1983Assignee: Minnesota Mining and Manufacturing CompanyInventors: Marco Beruto, Piero Ramello
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Patent number: 4368258Abstract: In the process for preparing impregnated polymer latex compositions by impregnating a hydrophobic substance in dispersed polymer particles in an aqueous polymer latex, the improvement comprises impregnating said hydrophobic substance, wherein the impregnation is effected by mixing said hydrophobic substance which is solid state, a water-miscible organic solvent and aqueous polymer latex wherein a polymer of the polymer latex is prepared from ethene monomers and containing at least one hydrophilic group.Type: GrantFiled: March 11, 1981Date of Patent: January 11, 1983Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Mitsuto Fujiwhara, Syunji Matsuo, Tsuneo Wada, Naoto Abe, Toyoaki Masukawa, Akio Iijima, Keiji Oishi
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Patent number: 4358532Abstract: A photographic element containing a compound represented by formula (I) ##STR1## wherein G represents --OR.sup.1 or --NHR.sup.2, R.sup.1 represents hydrogen or a hydrolyzable moiety, R.sup.2 represents hydrogen or an alkyl group containing from 1 to 50 carbon atoms, Z represents a photographically useful group, A represents an atomic group forming an aromatic ring, Ball represents an organic immobilizing group on the aromatic ring, which cntains from 8 to 50 carbon atoms, m represents an integer of 1 or 2, X represents a divalent organic group, Nu represents a nucleophilic group, and n represents an integer of 1 or 2, and X with the nucleophilic group Nu is capable of forming a 5- to 12-membered ring by oxidation having an electrophilic center at the carbon atom substituted by the --NHSO.sub.2 Z group.Type: GrantFiled: July 15, 1981Date of Patent: November 9, 1982Assignee: Fuji Photo Film Co., Ltd.Inventors: Koichi Koyama, Shinsaku Fujita
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Patent number: 4358525Abstract: Photographically useful compounds such as photographic reagents and photographic dyes are blocked with a grouping which, under alkaline conditions, is cleaved from the compound by an intramolecular nucleophilic displacement reaction. The compounds are resistant to unblocking under storage conditions, but are uniformly unblocked under conditions encountered during photographic processing.Type: GrantFiled: August 12, 1981Date of Patent: November 9, 1982Assignee: Eastman Kodak CompanyInventors: Jared B. Mooberry, William C. Archie, Jr.
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Patent number: 4358533Abstract: A silver halide photographic material having a hydrophilic colloid layer comprising fine polymer particles loaded with a hydrophobic photographic addenda provided on a support wherein the polymer has repeating units formed from a nonionic hydrophobic monomer. The nonionic hydrophobic monomer has the formula ##STR1## R.sub.1 and R.sub.2 individually are a hydrogen atom or methyl group, R.sub.3 is a hydrogen atom, an alkyl or aryl group, and m and n are integers of from 2 to 100 individually.Type: GrantFiled: March 11, 1981Date of Patent: November 9, 1982Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Kouji Tokitou, Tsuneo Wada
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Patent number: 4351896Abstract: Mesoionic 1,2,4-triazolium-3-thiolate silver halide stabilizer precursors are novel compounds useful in a heat developable and heat stabilizable photographic silver halide materials and processes. After imagewise exposure of the photographic material, a developed and stabilized silver image is produced by heating the element. Mesoionic stabilizer precursors are also useful in photographic silver halide processing compositions.Type: GrantFiled: November 9, 1981Date of Patent: September 28, 1982Assignee: Eastman Kodak CompanyInventors: Henry W. Altland, Daniel D. Shiao
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Patent number: 4350752Abstract: Imidomethyl blocked photographic reagents are useful in photographic elements, film units and processes. The blocked photographic reagents have the structure: ##STR1## wherein: J represents ##STR2## X represents the atoms to complete a 5- or 6-membered ring or ring system; R represents hydrogen, alkyl or 1 to 4 carbon atoms or aryl of 6 to 12 carbon atoms; andPR represents the residue of an organic photographic reagent containing a heteroatom through which it is joined to the imidomethyl blocking group.Type: GrantFiled: December 29, 1980Date of Patent: September 21, 1982Assignee: Eastman Kodak CompanyInventors: James A. Reczek, Thomas R. Welter
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Patent number: 4346154Abstract: A stain retarding concentration of a phosphine antistain agent or phosphine antistain agent precursor in the undercoat layer of a photographic silver halide element comprising a support having thereon (a) a photographic silver halide gelatino emulsion layer, and (b) an undercoat layer between the emulsion layer and the support, provides reduced stain in the element upon exposure and processing. The photographic element preferably comprises a silver halide developing agent. The photographic element, after exposure, is preferably processed by means of an aqueous alkaline activator bath and then an aqueous thiosulfate stabilizer bath.Type: GrantFiled: June 22, 1981Date of Patent: August 24, 1982Assignee: Eastman Kodak CompanyInventors: Donald F. McLaen, Arthur H. Herz
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Patent number: 4345019Abstract: Transfer silver images high in maximum density, contrast and sharpness and small in dependency on developing temperatures are obtained by image wise exposing and developing a diffusion transfer light sensitive material which comprises a support having thereon at least a carbon black-containing layer and a silver halide emulsion layer present on said carbon black containing layer, said carbon black-containing layer and/or layer adjacent thereto containing 3-pyrazolidone compound represented by the following general formula: ##STR1## wherein R.sub.1 and R.sub.2 are hydroxyalkyl or alkyl group of 1-4 carbon atoms, at least one of R.sub.1 and R.sub.2 being hydroxyalkyl group and R.sub.3 is an aryl group.Type: GrantFiled: April 17, 1981Date of Patent: August 17, 1982Assignee: Mitsubishi Paper Mills, Ltd.Inventor: Isao Kohmura
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Patent number: 4336321Abstract: In a silver halide photographic material, at least one mercapto complexing agent for silver salt is contained in at least one photographic constituting layer and at least one anion or betaine type cyanine sensitizing dye is contained in silver halide emulsion layer to improve photographic defects such as reduction of sensitivity, softening in tone, etc.Type: GrantFiled: February 4, 1981Date of Patent: June 22, 1982Assignee: Mitsubishi Paper Mills, Ltd.Inventors: Eiji Kanada, Yasuo Tsubai, Shoji Yamada, Yoshikazu Takaya, Takao Senga
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Patent number: 4330617Abstract: The compounds represented by the general formula (I) or (II) as defined in the specification are novel and useful developing agent precursors in silver halide photographic light sensitive materials.Type: GrantFiled: February 4, 1981Date of Patent: May 18, 1982Assignee: Mitsubishi Paper Mills, Ltd.Inventors: Minoru Ohashi, Katsuaki Iwaosa
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Patent number: 4324856Abstract: A photographic silver halide material is disclosed which contains a precursor of photographic chemicals.Type: GrantFiled: October 7, 1980Date of Patent: April 13, 1982Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Satoshi Kawakatsu, Shigeto Hirabayashi, Hidetaka Ninomiya, Yutaka Kaneko