Having Particle Size Of 100 Millimicrons Or Less, E.g., Lippmann Type, Etc. Patents (Class 430/568)
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Patent number: 4614707Abstract: A color reversal photographic light-sensitive materials comprising a base having thereon (a) at least one light-sensitive silver halide emulsion layer containing a dye forming coupler and (b) a silver halide emulsion layer substantially without light-sensitivity provided adjacent to said light-sensitive layer, or (a) at least one light-sensitive silver halide emulsion layer containing a dye forming coupler, (b) a silver halide emulsion layer substantially without light-sensitivity to light, and (c) an intermediate layer therebetween, wherein said intermediate layer or said silver halide emulsion layer substantially without light-sensitivity, or both said intermediate layer and said silver halide emulsion layer substantially without light-sensitivity contain at least one compound represented by the following formula (I): ##STR1## wherein R.sup.1 and R.sup.2, which may be the same or different, each represents a hydrogen atom or a group having 1 to 10 carbon atoms capable of being hydrolyzed with alkali, R.sup.Type: GrantFiled: February 19, 1985Date of Patent: September 30, 1986Assignee: Fuji Photo Film Co., Ltd.Inventors: Munehisa Fujita, Yasuhiro Hayashi, Takashi Ozawa, Nobutaka Ohki
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Patent number: 4603103Abstract: A heat-developable light-sensitive material comprising, on a support, a thermally decomposable organic silver salt. The heat-developable light-sensitive materials have high density and low fog.Type: GrantFiled: November 26, 1984Date of Patent: July 29, 1986Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroyuki Hirai, Kozo Sato, Hiroshi Hara
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Patent number: 4599302Abstract: In most highly sensitive recording materials containing silver halide, the graininess may be improved by the addition of a virtually insensitive silver halide-emulsion to a most highly sensitive light-sensitive silver halide emulsion layer.Type: GrantFiled: May 20, 1985Date of Patent: July 8, 1986Assignee: Agfa-Gevaert AktiengesellschaftInventor: Rainer Scheerer
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Patent number: 4596764Abstract: A method of processing an image-wise exposed silver halide color photographic material is described, having on a support at least one red-sensitive silver halide emulsion layer, at least one green-sensitive silver halide emulsion layer, and at least one blue-sensitive silver halide emulsion layer, the total amount of silver iodide contained in the light-senstive silver halides in said light-sensitive silver halide emulsion layers being higher than 4.0.times.10.sup.-3 mole/m.sup.2, which comprises processing the color photographic material further containing in a protective layer thereof a super fine grain silver halide, having a mean grain size of less than 0.2 .mu.Type: GrantFiled: July 3, 1985Date of Patent: June 24, 1986Assignee: Fuji Photo Film Co., Ltd.Inventor: Shingo Ishimaru
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Patent number: 4552838Abstract: A process is disclosed of producing photographically useful radiation sensitive silver halide emulsions the grains of which are of a predetermined size distribution, including selection of maximum and minimum grain diameters and selection of the distribution of grains of maximum, minimum, and intervening diameters. This is achieved by modifying a double jet precipitation to introduce during the run stable silver halide grains capable of acting as host grains for the deposition of additional silver and halide ions. The degree to which the host grains initially introduced are grown determines the maximum grain diameter of the emulsion. The minimum diameter of the grains in the emulsion produced can be determined by the diameter of the stable silver halide grains introduced at the end of the run. The rate at which the stable host grains are introduced during the run controls the distribution of intervening grain sizes.Type: GrantFiled: May 18, 1984Date of Patent: November 12, 1985Assignee: Eastman Kodak CompanyInventors: Jong-Shinn Wey, Thomas E. Whiteley, James M. Hamlin
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Patent number: 4536472Abstract: A silver halide color photographic light-sensitive material comprising a support having thereon a blue-sensitive silver halide emulsion layer, a green-sensitive silver halide emulsion layer and a red-sensitive silver halide emulsion layer, at least one of these silver halide emulsion layers containing a non-diffusible coupler which forms a properly smearing diffusible dye upon reaction with the oxidation product of a color developing agent together with a monodispersed silver halide emulsion. The silver halide color photographic light-sensitive material provides color images having not only an improved RMS granularity but also an improved visual sensation of graininess.Type: GrantFiled: January 19, 1984Date of Patent: August 20, 1985Assignee: Fuji Photo Film Co., Ltd.Inventors: Hirohiko Kato, Seiji Ichijima, Keiichi Adachi, Toshiyuki Watanabe
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Patent number: 4510234Abstract: A silver halide photographic emulsion, which comprises (i) a mono-dispersed silver halide emulsion comprising 3 to 50 mole % of silver chloride, 1 mole % or less of silver iodide and 50 to 97 mole % of silver bromide having a grain size distribution of 0.Type: GrantFiled: September 7, 1983Date of Patent: April 9, 1985Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Syoji Matsuzaka, Makoto Kajiwara, Masanobu Miyoshi, Kiyoshi Yamashita
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Patent number: 4467029Abstract: A silver halide light-sensitive photographic material comprises a support and a Lippmann emulsion layer on the support containing a silver halide and at least one compound of the following formula in a quantity of at least 3.5.times.10.sup.-3 mole per mole of the silver halide of the Lippmann emulsion layer: ##STR1## wherein Z represents an atomic group necessary to form a heterocyclic ring; Y is a hydrogen atom or --S--R.sub.1 group; R and R.sub.1 are each a hydrogen atom, an alkali-metal atom, ammonium or an alkyl group; X and X.sub.1 are each a divalent organic group; m and m.sub.1 are each 0 or 1; and n is an integer of up to 3, provided if n is 0, Y is --S--R.sub.1 group.The silver halide light-sensitive photographic material is developed in a developer containing at least 0.6 mole per liter of sulfurous ions.Type: GrantFiled: March 8, 1983Date of Patent: August 21, 1984Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Toshikazu Nishide, Akio Kobayashi, Tamio Kitahata
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Patent number: 4451560Abstract: A method for forming a photosensitive element which comprises contacting silver halide in a plurality of spaced depressions in a surface with a mixture of a silver halide solvent and preformed sensitivity centers.Type: GrantFiled: November 15, 1982Date of Patent: May 29, 1984Assignee: Polaroid CorporationInventors: Arthur M. Gerber, Judith Loucks
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Patent number: 4450225Abstract: New silver halide emulsions are prepared at least partly by converting a silver phosphate with a water soluble halide.Type: GrantFiled: June 2, 1982Date of Patent: May 22, 1984Assignee: Agfa-Gevaert AktiengesellschaftInventors: Edith Weyde, Harald von Rintelen, Wilhelm Saleck, Heinz-Horst Teitscheid
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Patent number: 4444877Abstract: A light-sensitive silver halide emulsion is disclosed, which comprises cores composed of silver halide grains and shells covering the cores. The cores consist essentially of silver halide containing silver iodide, and the shells consist essentially of silver bromide, silver chloride or silver chlorobromide excluding silver iodide. The shells have a thickness of from 0.01 to 0.1.mu.. This light-sensitive silver halide emulsion has high sensitivity and superior covering power.Type: GrantFiled: February 9, 1982Date of Patent: April 24, 1984Assignee: Konishiroku Photo Ind. Co., Ltd.Inventors: Takeo Koitabashi, Yoshihiro Haga, Syoji Matsuzaka
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Patent number: 4414304Abstract: Forehardened photographic elements, particularly radiographic elements, intended to produce silver images are disclosed including among hydrophilic colloid layers at least one emulsion layer containing thin tabular silver halide grains. When developed in less than 1 minute to produce a viewable silver image, these photographic elements exhibit increased covering power.Type: GrantFiled: September 30, 1982Date of Patent: November 8, 1983Assignee: Eastman Kodak CompanyInventor: Robert E. Dickerson
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Patent number: 4413055Abstract: Silver halide emulsion with an average grain size of at most 0.6 .mu.m containing Co-, Ce- or Cu-salts are suitable for the production of vesicular images.Type: GrantFiled: September 28, 1981Date of Patent: November 1, 1983Assignee: Agfa-Gevaert AktiengesellschaftInventors: Edith Weyde, Harald von Rintelen, Wilhelm Saleck, Heinz-Horst Teitscheid
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Patent number: 4379837Abstract: Silver halide emulsions are prepared by precipitating a silver halide emulsion I on a more sparingly soluble silver halide emulsion II in the presence of a silver halide solvent wherein the emulsion I has been prepared in the presence of a compound inhibiting grain growth.Type: GrantFiled: May 20, 1981Date of Patent: April 12, 1983Assignee: Agfa-Gevaert AktiengesellschaftInventors: Otto Lapp, Harald von Rintelen, Franz Moll, Lothar Endres
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Patent number: 4366235Abstract: A photosensitive element comprising a support carrying photosensitive silver halide grains in a substantially predetermined spaced array and methods for forming such photosensitive elements.Type: GrantFiled: February 17, 1981Date of Patent: December 28, 1982Assignee: Polaroid CorporationInventor: Edwin H. Land
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Patent number: 4359526Abstract: A method for forming a photosensitive element comprising a plurality of single effective silver halide grains in a predetermined spaced array which comprises coalescing a fine-grain silver halide emulsion in a plurality of predetermined spaced depressions in a surface, wherein said coalescence is carried out by contacting said fine-grain emulsion with a silver halide solvent in the vapor phase.Type: GrantFiled: September 2, 1981Date of Patent: November 16, 1982Assignee: Polaroid CorporationInventor: Vivian K. Walworth
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Patent number: 4356257Abstract: A method for forming a photosensitive element comprising a plurality of single effective siler halide grains in a predetermined spaced array which comprises coalescing fine-grain silver halide in a plurality of predetermined spaced depressions in a surface, thereby forming in situ a single effective silver halide grain in each of said depressions and a photosensitive element comprising coalesced single effective silver halide grains in a predetermined spaced array.Type: GrantFiled: September 2, 1981Date of Patent: October 26, 1982Assignee: Polaroid CorporationInventor: Arthur M. Gerber
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Patent number: 4353977Abstract: A photosensitive silver halide element comprising a support carrying photosensitive silver halide grains in a predetermined spaced array is prepared by a method which comprises at least partially coalescing fine-grain silver halide in a plurality of spaced depressions in a hydrophobic layer, superposing said layer with a hydrophilic layer during or subsequent to said coalescence, and then separating said hydrophilic layer and said hydrophobic layer whereby said coalesced silver halide grains are retained on said hydrophilic layer in a pattern corresponding substantially to the pattern of said spaced depressions.Type: GrantFiled: September 2, 1981Date of Patent: October 12, 1982Assignee: Polaroid CorporationInventors: Arthur M. Gerber, Warren D. Slafer, Vivian K. Walworth
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Patent number: 4352874Abstract: A fine-grain emulsion in a plurality of predetermined spaced depressions is coalesced to form, in situ, a plurality of single effective silver halide grains in a predetermined spaced array by the action of a solution of a silver halide solvent containing a dissolved silver salt.Type: GrantFiled: September 2, 1981Date of Patent: October 5, 1982Assignee: Polaroid CorporationInventors: Edwin H. Land, Vivian K. Walworth
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Patent number: 4349622Abstract: There are provided a photographic silver halide emulsion which comprises composite silver halide crystals consisting essentially of multi-faceted silver iodobromide crystals containing 15-40 mole % of silver iodide and silver halide crystals containing not more than 10 mole % of silver iodide, said silver halide crystals being combined as epitaxial silver halide crystals with said multi-faceted silver iodobromide crystals, at least half of the facetes of said multi-faceted crystals being substantially free of said epitaxial crystals and the amount of said epitaxial crystals being limited to not more than 75 mole % based on the total silver halide forming said composite crystals, a silver halide emulsion comprising silver halide grains consisting essentially of silver iodobromide containing 15-40 mole % of silver iodide substantially homogeneously distributed therein, and a process for preparing the same.Type: GrantFiled: May 29, 1980Date of Patent: September 14, 1982Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Takeo Koitabashi, Syozi Matsuzaka, Tashifumi Iijima
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Patent number: 4309501Abstract: Fine crystals characterized by improved morphological homogeneity and a narrow size distribution are prepared by introducing a solution of a crystallizable solute in a solvent into a bed of small inert continuously moving solid particles and initiating crystallization within the solution while it is in contact with the moving particles. The process finds application in the manufacture of diverse crystalline products such as, for example, in the formation of metal oxalates, phosphorescent compounds, and silver halide crystals, as well as in the purification of both organic and inorganic materials.Type: GrantFiled: July 9, 1980Date of Patent: January 5, 1982Assignee: Eastman Kodak CompanyInventors: Albert P. Huguenard, Michel J. Favre
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Patent number: 4260674Abstract: A photographic material for the production of an image in a dry process by forming a vesicle image upon the decomposition of a peroxide compound at image nuclei of silver by providing a layer containing a silver salt which forms upon exposure to light, in imagewise distribution, image nuclei. The silver salt has a grain size of less than 0.3 .mu.m and is present in the layer in an amount of from 1-500 mg/m.sup.2.Type: GrantFiled: December 14, 1979Date of Patent: April 7, 1981Assignee: Agfa-Gevaert AktiengesellschaftInventors: Edith Weyde, Anita von Konig, Werner Liebe
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Patent number: 4232116Abstract: Ultraviolet radiation sensitive photographic film material comprising a silver halide emulsion of at least 50 mole % silver chloride and a yellow filter dye over said silver halide emulsion layer.Type: GrantFiled: January 31, 1979Date of Patent: November 4, 1980Assignee: Minnesota Mining and Manufacturing CompanyInventor: Peter B. Jamieson
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Patent number: 4229525Abstract: A photographic silver halide emulsion containing silver halide grains having an average grain size of from 0.3 to 3.0 microns in diameter as a light sensitive element in a dispersing medium and additionally containing super fine grains of silver halide having an average grain size of less than 0.2 microns in diameter is disclosed.Type: GrantFiled: November 29, 1976Date of Patent: October 21, 1980Assignee: Fuji Photo Film Co., Ltd.Inventor: Hirozo Ueda
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Patent number: 4210715Abstract: Light-sensitive silver halide photographic materials to be treated with a hydroquinones-containing developing solution which material comprises a support and at least one hydrophilic colloidal layer coated thereon which contains silver halide grains having an average grain size of 0.05 to 1.5.mu., a tetrazolium compound and a sensitizing dye.Type: GrantFiled: March 2, 1979Date of Patent: July 1, 1980Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Mitsuto Fujiwhara, Syunji Matsuo, Toyoaki Masukawa, Yutaka Kaneko, Mikio Kawasaki
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Patent number: 4202695Abstract: Fine-grain silver halide emulsions of the Lippmann-type are described which comprise derivatives of heterocyclic mercaptans corresponding to the formulae: ##STR1## wherein: each of Z.sub.1 and Z.sub.2 represents the atoms necessary to complete a 5- or 6-membered heterocyclic ring system,n is 0 or 1,X is --CO-- or --CS--,R is an alkyl group or an aryl group, andY is --CO--, --COO--, --CS--, --SO.sub.2 --, --CON(R.sub.1)-- or --CSN(R.sub.1)--, R.sub.1 being hydrogen, alkyl or aryl.Both in reversal and negative processing sharpness of fine detail is improved and the distortion of image-details is reduced. Upon reversal processing yellow staining is also reduced.Type: GrantFiled: January 30, 1975Date of Patent: May 13, 1980Assignee: AGFA-GEVAERT N.V.Inventors: Herman A. Philippaerts, Robert J. Pollet, Wolfgang Muller-Bardorff, Wilhelm Saleck, Anita von Konig, Walter Gauss, Franz Moll, Theofiel H. Ghys