Having Particle Size Of 100 Millimicrons Or Less, E.g., Lippmann Type, Etc. Patents (Class 430/568)
  • Patent number: 4614707
    Abstract: A color reversal photographic light-sensitive materials comprising a base having thereon (a) at least one light-sensitive silver halide emulsion layer containing a dye forming coupler and (b) a silver halide emulsion layer substantially without light-sensitivity provided adjacent to said light-sensitive layer, or (a) at least one light-sensitive silver halide emulsion layer containing a dye forming coupler, (b) a silver halide emulsion layer substantially without light-sensitivity to light, and (c) an intermediate layer therebetween, wherein said intermediate layer or said silver halide emulsion layer substantially without light-sensitivity, or both said intermediate layer and said silver halide emulsion layer substantially without light-sensitivity contain at least one compound represented by the following formula (I): ##STR1## wherein R.sup.1 and R.sup.2, which may be the same or different, each represents a hydrogen atom or a group having 1 to 10 carbon atoms capable of being hydrolyzed with alkali, R.sup.
    Type: Grant
    Filed: February 19, 1985
    Date of Patent: September 30, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Munehisa Fujita, Yasuhiro Hayashi, Takashi Ozawa, Nobutaka Ohki
  • Patent number: 4603103
    Abstract: A heat-developable light-sensitive material comprising, on a support, a thermally decomposable organic silver salt. The heat-developable light-sensitive materials have high density and low fog.
    Type: Grant
    Filed: November 26, 1984
    Date of Patent: July 29, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Hirai, Kozo Sato, Hiroshi Hara
  • Patent number: 4599302
    Abstract: In most highly sensitive recording materials containing silver halide, the graininess may be improved by the addition of a virtually insensitive silver halide-emulsion to a most highly sensitive light-sensitive silver halide emulsion layer.
    Type: Grant
    Filed: May 20, 1985
    Date of Patent: July 8, 1986
    Assignee: Agfa-Gevaert Aktiengesellschaft
    Inventor: Rainer Scheerer
  • Patent number: 4596764
    Abstract: A method of processing an image-wise exposed silver halide color photographic material is described, having on a support at least one red-sensitive silver halide emulsion layer, at least one green-sensitive silver halide emulsion layer, and at least one blue-sensitive silver halide emulsion layer, the total amount of silver iodide contained in the light-senstive silver halides in said light-sensitive silver halide emulsion layers being higher than 4.0.times.10.sup.-3 mole/m.sup.2, which comprises processing the color photographic material further containing in a protective layer thereof a super fine grain silver halide, having a mean grain size of less than 0.2 .mu.
    Type: Grant
    Filed: July 3, 1985
    Date of Patent: June 24, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Shingo Ishimaru
  • Patent number: 4552838
    Abstract: A process is disclosed of producing photographically useful radiation sensitive silver halide emulsions the grains of which are of a predetermined size distribution, including selection of maximum and minimum grain diameters and selection of the distribution of grains of maximum, minimum, and intervening diameters. This is achieved by modifying a double jet precipitation to introduce during the run stable silver halide grains capable of acting as host grains for the deposition of additional silver and halide ions. The degree to which the host grains initially introduced are grown determines the maximum grain diameter of the emulsion. The minimum diameter of the grains in the emulsion produced can be determined by the diameter of the stable silver halide grains introduced at the end of the run. The rate at which the stable host grains are introduced during the run controls the distribution of intervening grain sizes.
    Type: Grant
    Filed: May 18, 1984
    Date of Patent: November 12, 1985
    Assignee: Eastman Kodak Company
    Inventors: Jong-Shinn Wey, Thomas E. Whiteley, James M. Hamlin
  • Patent number: 4536472
    Abstract: A silver halide color photographic light-sensitive material comprising a support having thereon a blue-sensitive silver halide emulsion layer, a green-sensitive silver halide emulsion layer and a red-sensitive silver halide emulsion layer, at least one of these silver halide emulsion layers containing a non-diffusible coupler which forms a properly smearing diffusible dye upon reaction with the oxidation product of a color developing agent together with a monodispersed silver halide emulsion. The silver halide color photographic light-sensitive material provides color images having not only an improved RMS granularity but also an improved visual sensation of graininess.
    Type: Grant
    Filed: January 19, 1984
    Date of Patent: August 20, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hirohiko Kato, Seiji Ichijima, Keiichi Adachi, Toshiyuki Watanabe
  • Patent number: 4510234
    Abstract: A silver halide photographic emulsion, which comprises (i) a mono-dispersed silver halide emulsion comprising 3 to 50 mole % of silver chloride, 1 mole % or less of silver iodide and 50 to 97 mole % of silver bromide having a grain size distribution of 0.
    Type: Grant
    Filed: September 7, 1983
    Date of Patent: April 9, 1985
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Syoji Matsuzaka, Makoto Kajiwara, Masanobu Miyoshi, Kiyoshi Yamashita
  • Patent number: 4467029
    Abstract: A silver halide light-sensitive photographic material comprises a support and a Lippmann emulsion layer on the support containing a silver halide and at least one compound of the following formula in a quantity of at least 3.5.times.10.sup.-3 mole per mole of the silver halide of the Lippmann emulsion layer: ##STR1## wherein Z represents an atomic group necessary to form a heterocyclic ring; Y is a hydrogen atom or --S--R.sub.1 group; R and R.sub.1 are each a hydrogen atom, an alkali-metal atom, ammonium or an alkyl group; X and X.sub.1 are each a divalent organic group; m and m.sub.1 are each 0 or 1; and n is an integer of up to 3, provided if n is 0, Y is --S--R.sub.1 group.The silver halide light-sensitive photographic material is developed in a developer containing at least 0.6 mole per liter of sulfurous ions.
    Type: Grant
    Filed: March 8, 1983
    Date of Patent: August 21, 1984
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Toshikazu Nishide, Akio Kobayashi, Tamio Kitahata
  • Patent number: 4451560
    Abstract: A method for forming a photosensitive element which comprises contacting silver halide in a plurality of spaced depressions in a surface with a mixture of a silver halide solvent and preformed sensitivity centers.
    Type: Grant
    Filed: November 15, 1982
    Date of Patent: May 29, 1984
    Assignee: Polaroid Corporation
    Inventors: Arthur M. Gerber, Judith Loucks
  • Patent number: 4450225
    Abstract: New silver halide emulsions are prepared at least partly by converting a silver phosphate with a water soluble halide.
    Type: Grant
    Filed: June 2, 1982
    Date of Patent: May 22, 1984
    Assignee: Agfa-Gevaert Aktiengesellschaft
    Inventors: Edith Weyde, Harald von Rintelen, Wilhelm Saleck, Heinz-Horst Teitscheid
  • Patent number: 4444877
    Abstract: A light-sensitive silver halide emulsion is disclosed, which comprises cores composed of silver halide grains and shells covering the cores. The cores consist essentially of silver halide containing silver iodide, and the shells consist essentially of silver bromide, silver chloride or silver chlorobromide excluding silver iodide. The shells have a thickness of from 0.01 to 0.1.mu.. This light-sensitive silver halide emulsion has high sensitivity and superior covering power.
    Type: Grant
    Filed: February 9, 1982
    Date of Patent: April 24, 1984
    Assignee: Konishiroku Photo Ind. Co., Ltd.
    Inventors: Takeo Koitabashi, Yoshihiro Haga, Syoji Matsuzaka
  • Patent number: 4414304
    Abstract: Forehardened photographic elements, particularly radiographic elements, intended to produce silver images are disclosed including among hydrophilic colloid layers at least one emulsion layer containing thin tabular silver halide grains. When developed in less than 1 minute to produce a viewable silver image, these photographic elements exhibit increased covering power.
    Type: Grant
    Filed: September 30, 1982
    Date of Patent: November 8, 1983
    Assignee: Eastman Kodak Company
    Inventor: Robert E. Dickerson
  • Patent number: 4413055
    Abstract: Silver halide emulsion with an average grain size of at most 0.6 .mu.m containing Co-, Ce- or Cu-salts are suitable for the production of vesicular images.
    Type: Grant
    Filed: September 28, 1981
    Date of Patent: November 1, 1983
    Assignee: Agfa-Gevaert Aktiengesellschaft
    Inventors: Edith Weyde, Harald von Rintelen, Wilhelm Saleck, Heinz-Horst Teitscheid
  • Patent number: 4379837
    Abstract: Silver halide emulsions are prepared by precipitating a silver halide emulsion I on a more sparingly soluble silver halide emulsion II in the presence of a silver halide solvent wherein the emulsion I has been prepared in the presence of a compound inhibiting grain growth.
    Type: Grant
    Filed: May 20, 1981
    Date of Patent: April 12, 1983
    Assignee: Agfa-Gevaert Aktiengesellschaft
    Inventors: Otto Lapp, Harald von Rintelen, Franz Moll, Lothar Endres
  • Patent number: 4366235
    Abstract: A photosensitive element comprising a support carrying photosensitive silver halide grains in a substantially predetermined spaced array and methods for forming such photosensitive elements.
    Type: Grant
    Filed: February 17, 1981
    Date of Patent: December 28, 1982
    Assignee: Polaroid Corporation
    Inventor: Edwin H. Land
  • Patent number: 4359526
    Abstract: A method for forming a photosensitive element comprising a plurality of single effective silver halide grains in a predetermined spaced array which comprises coalescing a fine-grain silver halide emulsion in a plurality of predetermined spaced depressions in a surface, wherein said coalescence is carried out by contacting said fine-grain emulsion with a silver halide solvent in the vapor phase.
    Type: Grant
    Filed: September 2, 1981
    Date of Patent: November 16, 1982
    Assignee: Polaroid Corporation
    Inventor: Vivian K. Walworth
  • Patent number: 4356257
    Abstract: A method for forming a photosensitive element comprising a plurality of single effective siler halide grains in a predetermined spaced array which comprises coalescing fine-grain silver halide in a plurality of predetermined spaced depressions in a surface, thereby forming in situ a single effective silver halide grain in each of said depressions and a photosensitive element comprising coalesced single effective silver halide grains in a predetermined spaced array.
    Type: Grant
    Filed: September 2, 1981
    Date of Patent: October 26, 1982
    Assignee: Polaroid Corporation
    Inventor: Arthur M. Gerber
  • Patent number: 4353977
    Abstract: A photosensitive silver halide element comprising a support carrying photosensitive silver halide grains in a predetermined spaced array is prepared by a method which comprises at least partially coalescing fine-grain silver halide in a plurality of spaced depressions in a hydrophobic layer, superposing said layer with a hydrophilic layer during or subsequent to said coalescence, and then separating said hydrophilic layer and said hydrophobic layer whereby said coalesced silver halide grains are retained on said hydrophilic layer in a pattern corresponding substantially to the pattern of said spaced depressions.
    Type: Grant
    Filed: September 2, 1981
    Date of Patent: October 12, 1982
    Assignee: Polaroid Corporation
    Inventors: Arthur M. Gerber, Warren D. Slafer, Vivian K. Walworth
  • Patent number: 4352874
    Abstract: A fine-grain emulsion in a plurality of predetermined spaced depressions is coalesced to form, in situ, a plurality of single effective silver halide grains in a predetermined spaced array by the action of a solution of a silver halide solvent containing a dissolved silver salt.
    Type: Grant
    Filed: September 2, 1981
    Date of Patent: October 5, 1982
    Assignee: Polaroid Corporation
    Inventors: Edwin H. Land, Vivian K. Walworth
  • Patent number: 4349622
    Abstract: There are provided a photographic silver halide emulsion which comprises composite silver halide crystals consisting essentially of multi-faceted silver iodobromide crystals containing 15-40 mole % of silver iodide and silver halide crystals containing not more than 10 mole % of silver iodide, said silver halide crystals being combined as epitaxial silver halide crystals with said multi-faceted silver iodobromide crystals, at least half of the facetes of said multi-faceted crystals being substantially free of said epitaxial crystals and the amount of said epitaxial crystals being limited to not more than 75 mole % based on the total silver halide forming said composite crystals, a silver halide emulsion comprising silver halide grains consisting essentially of silver iodobromide containing 15-40 mole % of silver iodide substantially homogeneously distributed therein, and a process for preparing the same.
    Type: Grant
    Filed: May 29, 1980
    Date of Patent: September 14, 1982
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Takeo Koitabashi, Syozi Matsuzaka, Tashifumi Iijima
  • Patent number: 4309501
    Abstract: Fine crystals characterized by improved morphological homogeneity and a narrow size distribution are prepared by introducing a solution of a crystallizable solute in a solvent into a bed of small inert continuously moving solid particles and initiating crystallization within the solution while it is in contact with the moving particles. The process finds application in the manufacture of diverse crystalline products such as, for example, in the formation of metal oxalates, phosphorescent compounds, and silver halide crystals, as well as in the purification of both organic and inorganic materials.
    Type: Grant
    Filed: July 9, 1980
    Date of Patent: January 5, 1982
    Assignee: Eastman Kodak Company
    Inventors: Albert P. Huguenard, Michel J. Favre
  • Patent number: 4260674
    Abstract: A photographic material for the production of an image in a dry process by forming a vesicle image upon the decomposition of a peroxide compound at image nuclei of silver by providing a layer containing a silver salt which forms upon exposure to light, in imagewise distribution, image nuclei. The silver salt has a grain size of less than 0.3 .mu.m and is present in the layer in an amount of from 1-500 mg/m.sup.2.
    Type: Grant
    Filed: December 14, 1979
    Date of Patent: April 7, 1981
    Assignee: Agfa-Gevaert Aktiengesellschaft
    Inventors: Edith Weyde, Anita von Konig, Werner Liebe
  • Patent number: 4232116
    Abstract: Ultraviolet radiation sensitive photographic film material comprising a silver halide emulsion of at least 50 mole % silver chloride and a yellow filter dye over said silver halide emulsion layer.
    Type: Grant
    Filed: January 31, 1979
    Date of Patent: November 4, 1980
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Peter B. Jamieson
  • Patent number: 4229525
    Abstract: A photographic silver halide emulsion containing silver halide grains having an average grain size of from 0.3 to 3.0 microns in diameter as a light sensitive element in a dispersing medium and additionally containing super fine grains of silver halide having an average grain size of less than 0.2 microns in diameter is disclosed.
    Type: Grant
    Filed: November 29, 1976
    Date of Patent: October 21, 1980
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Hirozo Ueda
  • Patent number: 4210715
    Abstract: Light-sensitive silver halide photographic materials to be treated with a hydroquinones-containing developing solution which material comprises a support and at least one hydrophilic colloidal layer coated thereon which contains silver halide grains having an average grain size of 0.05 to 1.5.mu., a tetrazolium compound and a sensitizing dye.
    Type: Grant
    Filed: March 2, 1979
    Date of Patent: July 1, 1980
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Mitsuto Fujiwhara, Syunji Matsuo, Toyoaki Masukawa, Yutaka Kaneko, Mikio Kawasaki
  • Patent number: 4202695
    Abstract: Fine-grain silver halide emulsions of the Lippmann-type are described which comprise derivatives of heterocyclic mercaptans corresponding to the formulae: ##STR1## wherein: each of Z.sub.1 and Z.sub.2 represents the atoms necessary to complete a 5- or 6-membered heterocyclic ring system,n is 0 or 1,X is --CO-- or --CS--,R is an alkyl group or an aryl group, andY is --CO--, --COO--, --CS--, --SO.sub.2 --, --CON(R.sub.1)-- or --CSN(R.sub.1)--, R.sub.1 being hydrogen, alkyl or aryl.Both in reversal and negative processing sharpness of fine detail is improved and the distortion of image-details is reduced. Upon reversal processing yellow staining is also reduced.
    Type: Grant
    Filed: January 30, 1975
    Date of Patent: May 13, 1980
    Assignee: AGFA-GEVAERT N.V.
    Inventors: Herman A. Philippaerts, Robert J. Pollet, Wolfgang Muller-Bardorff, Wilhelm Saleck, Anita von Konig, Walter Gauss, Franz Moll, Theofiel H. Ghys