Polyheteronuclear Sensitizer Patents (Class 430/573)
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Patent number: 11857457Abstract: A device for alleviating obstructive sleep apnea, comprising: a base fitted and fixed to an user's head and having a passage portion; an adjustment element extending into the passage portion and undergoing relative displacement therein; a locking element disposed at the passage portion, wherein an user uses the locking element to fix the adjustment element in place to limit the relative displacement of the adjustment element; a suction member undergoing relative displacement relative to the passage portion together with the adjustment element and having a channel, wherein the channel extends into the adjustment element, undergoes relative displacement in the adjustment element, and connects to a tongue fixing portion disposed at the front end of the user's tongue; and a negative pressure source being mounted on the base and in communication with the channel, providing a negative pressure to the user's tongue in contact with the tongue fixing portion.Type: GrantFiled: May 17, 2021Date of Patent: January 2, 2024Assignee: GOOD NEWS MEDICAL CO., LTD.Inventor: Chin-Chi Lin
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Patent number: 8226854Abstract: A photoelectric conversion device is provided and includes a photoelectric conversion layer containing a compound represented by the following formula (1). Formula (1): In the formula, Z1 represents an atomic group for forming a 5- or 6-membered nitrogen-containing heterocyclic ring; Za represents an atomic group for forming a 5- or 6-membered ring; R1 represents a hydrogen atom, an alkyl group, an alkenyl group, an aryl group or a heterocyclic group; L11 to L14 each represents a methine group which may have a substituent or may form a ring with another methine group; p1 represents 0 or 1; n1 represents an integer of 0 to 4 and when n1 is an integer of 2 or more, each L13 or L14 may be the same as or different from every other L13 or L14; M1 represents an ion for neutralizing the electric charge; and m1 represents a number necessary for neutralization of the electric charge; provided that a compound where Z1 is an atomic group forming a thiazoline nucleus or a thiazole nucleus is excluded.Type: GrantFiled: November 26, 2008Date of Patent: July 24, 2012Assignee: FUJIFILM CorporationInventors: Rui Shen, Kimiatsu Nomura, Hideyuki Suzuki
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Patent number: 7598025Abstract: The present invention is characterized to provide a hologram silver halide photographic material having high sensitivity and diffraction efficiency, providing an excellent image and having less color residue and noise in a transparent part, a hologram, a method for producing the same. In the present invention, a hologram silver halide photographic material having at least one silver halide emulsion layer formed on a support, wherein an average particle diameter of silver halide particles in a silver halide emulsion is 0.03 ?m to 0.07 ?m; a film thickness of the silver halide emulsion layer is 4 ?m to 9 ?m; a silver/gelatin ratio of the silver halide emulsion layer is 0.3 to 0.6; and the silver halide emulsion layer contains sensitizing dye of specific structure.Type: GrantFiled: January 17, 2007Date of Patent: October 6, 2009Assignees: Konica Minolta Opto Inc., Dia Nippon Printing Co., Ltd.Inventors: Kenji Michiue, Tomonobu Moriya, Masashi Iwasaki, Toshihiro Kubota, Masachika Watanabe, Tsuyoshi Yamauchi, Tomoko Kumasawa, Kenji Ueda
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Patent number: 6916601Abstract: An image-forming method comprising: employing a silver halide color photographic light-sensitive material, comprising, on a support, at least one silver halide emulsion layer containing a yellow dye-forming coupler, at least one silver halide emulsion layer containing a magenta dye-forming coupler, at least one silver halide emulsion layer containing a cyan dye-forming coupler, at least one color-mix preventing layer and at least one protective layer, wherein the said silver halide emulsion layer containing a yellow dye-forming coupler includes a blue-sensitive silver halide emulsion having a silver chloride content of 90 mole % or more and containing at least one specific blue-sensitive sensitizing dye; and exposing the said silver halide color photographic light-sensitive material to a blue semiconductor laser of a wavelength shorter by 30 nm to 60 nm than the wavelength at which the said blue-sensitive silver halide emulsion has the spectral sensitivity maximum.Type: GrantFiled: December 27, 2002Date of Patent: July 12, 2005Assignee: Fuji Photo Film Co., Ltd.Inventors: Akito Yokozawa, Tatsuya Ishizaka, Katsuyuki Takada, Yoshiro Ochiai, Tetsuo Nakamura
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Patent number: 6875562Abstract: A silver halide photographic emulsion which contains silver halide grains having light absorption strength of 100 or more.Type: GrantFiled: January 28, 2003Date of Patent: April 5, 2005Assignee: Fuji Photo Film Co., Ltd.Inventors: Katsuhiro Yamashita, Katsumi Kobayashi
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Patent number: 6780577Abstract: A silver halide photographic material containing silver halide grains onto which a sensitizing dye in the first layer and a sensitizing dye or dyes in the second or after layers are multilayer-adsorbed, wherein the fluorescence life time of the dye or dyes in the second or after layers on the silver halide grain surface measured at a maximum wavelength of fluorescence spectrum is shorter than the fluorescence life time of the dye or dyes in a gelatin dry film measured at a maximum wavelength of fluorescence spectrum when the sensitizing dyes are multilayer-adsorbed onto the silver halide grain surface.Type: GrantFiled: October 9, 2002Date of Patent: August 24, 2004Assignee: Fuji Photo Film Co., Ltd.Inventor: Hideo Furuuchi
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Patent number: 6566044Abstract: The present invention provides a silver halide photographic material that is excellent in photographic speed as well as image graininess and exhibits low residual color even after rapid processing. The silver halide photographic material contains a compound represented by formula (I) and a compound represented by formula (II), as defined.Type: GrantFiled: March 26, 2001Date of Patent: May 20, 2003Assignee: Fuji Photo Film Co., Ltd.Inventors: Katsuhisa Ohzeki, Tetsuo Nakamura, Takanori Hioki
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Patent number: 6498002Abstract: A photographic material comprising a support and at least one at least one layer which comprises at least one spectrally sensitized silver halide emulsion, characterized in that the material contains at least one compound of formula wherein X denotes sulphur or selenium, R1 denotes aryl or heterocyclyl, R2 denotes alkyl, alkenyl, alkynyl, aralkyl or hetarylalkyl, R3 denotes alkyl, alkenyl, aryl, aralkyl, hetaryl or hetarylalkyl, and R4 denotes H, alkyl, alkenyl, aryl, aralkyl, hetaryl or hetaralkyl, or R3, together with R4, denotes the remaining atoms of a carbocyclic or heterocyclic ring, is distinguished by increased spectral sensitivity, a high sensitivity/fogging ratio and a good shelf life under humid conditions.Type: GrantFiled: July 25, 2001Date of Patent: December 24, 2002Assignee: AGFA-GevaertInventors: Peter Bergthaller, Jörg Siegel, Hans-Ulrich Borst
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Patent number: 6498001Abstract: A spectrally sensitized photographic silver halide emulsion, characterized in that after precipitation at least one compound of formula is added to the emulsion, wherein R1 denotes alkyl, aryl, aralkyl, alkenyl or heterocyclyl; R2 denotes H, alkyl, aryl, heterocyclyl, amino or alkoxy; R3 denotes H, alkyl, aryl, aralkyl or heterocyclyl; D denotes —OH or —NR4R5; X denotes O or N—R6; R4 denotes H, alkyl, aryl, aralkyl, alkenyl or heterocyclyl; R5: denotes H, alkyl, aryl, aralkyl, alkenyl or heterocyclyl; R6: denotes H, alkyl, aryl, aralkyl, alkenyl, acyl, alkoxycarbonyl, carbamoyl or heterocyclyl, the aforementioned alkyl, aryl, aralkyl, alkenyl, heterocyclyl, amino, alkoxy, acyl, alkoxycarbonyl and carbamoyl groups can be substituted, and any two of the radicals R1 to R6 can together form a heterocyclic ring, such as a pyrrolidine, piperidine, perhydroazepine, piperazine, morpholine or thiomorpholine ring, for example; as well as a photographic material comprising aType: GrantFiled: July 24, 2001Date of Patent: December 24, 2002Assignee: AGFA-GevaertInventors: Peter Bergthaller, Jörg Siegel, Hans-Ulrich Borst, Ralf Büscher, Ulrich Nickel
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Patent number: 6498003Abstract: A photographic material comprising a support and at least one layer which comprises at least one spectrally sensitised silver halide emulsion, characterised in that the material contains at least one compound of formula and/or wherein R1 denotes H, alkyl, aryl, aralkyl, alkenyl, heterocyclyl, R2 denotes OH, NH2, NHR7, NR8R9 or R1 together with R2, denotes the atoms necessary for the completion of a heteroaliphatic ring, R3 denotes OH, NH2, NHR7, NR8R9, R4 denotes H, alkyl, aryl, aralkyl, alkenyl, heterocyclyl, R5, R6 independently of each other, denote OH, NH2, NHR10, NR11R12, or R4 together with R5, or R4 together with R6, denote the atoms necessary for the completion of a heteroaliphatic ring, and the R5 or R6 radical, which is not part of a ring, denotes OH, NH2, NHR10 or NR11R12, R7, R10 denote alkyl, aryl, aralkyl, heterocyclyl, R8, R9 independently of each other, denote alkyl, aryl, aralkyl, heterocyclyl, or R8 together with R9, denotes the atoms necessary fType: GrantFiled: July 26, 2001Date of Patent: December 24, 2002Assignee: Agfa-GevaertInventors: Peter Bergthaller, Jörg Siegel, Hans-Ulrich Borst
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Patent number: 6492102Abstract: A red or infrared sensitive silver halide emulsion is disclosed, comprising at least a compound represented by the following formula. A photographic material containing the emulsion is also disclosed.Type: GrantFiled: August 11, 2000Date of Patent: December 10, 2002Assignee: Konica CorporationInventors: Nobuaki Kagawa, Noriyasu Kita
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Patent number: 6444392Abstract: A black and white graphic arts film comprising a support having thereon at least one emulsion layer, said emulsion layer comprising: a trinuclear merocyanine spectral sensitising dye; 2-methylthio-4-hydroxy-6-methyl-1,3,3a,7-tetraazaindene (SMe-TAI); and a photosensitive silver halide.Type: GrantFiled: August 10, 2001Date of Patent: September 3, 2002Assignee: Eastman Kodak CompanyInventor: Julie Baker
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Publication number: 20020061483Abstract: A black and white graphic arts film comprising a support having thereon at least one emulsion layer, said emulsion layer comprising:Type: ApplicationFiled: August 10, 2001Publication date: May 23, 2002Applicant: Eastman Kodak CompanyInventor: Julie Baker
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Publication number: 20020037486Abstract: A photographic material comprising a support and at least one layer which comprises at least one spectrally sensitized silver halide emulsion, characterised in that the material contains at least one compound of formula 1Type: ApplicationFiled: July 26, 2001Publication date: March 28, 2002Inventors: Peter Bergthaller, Jorg Siegel, Hans-Ulrich Borst
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Publication number: 20020034712Abstract: A photographic material comprising a support and at least one at least one layer which comprises at least one spectrally sensitised silver halide emulsion, characterised in that the material contains at least one compound of formula 1Type: ApplicationFiled: July 25, 2001Publication date: March 21, 2002Inventors: Peter Bergthaller, Jorg Siegel, Hans-Ulrich Borst
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Patent number: 6338941Abstract: A silver halide light sensitive photographic material is disclosed, comprising a support and at least one hydrophilic colloid layer including a silver halide emulsion layer, wherein the hydrophilic colloid layer comprises a compound represented by the following formula. An image forming method by use thereof is also disclosed.Type: GrantFiled: July 6, 2000Date of Patent: January 15, 2002Assignee: Konica CorporationInventors: Toshiyuki Takabayashi, Takeo Arai
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Patent number: 6333146Abstract: Disclosed is a compound represented by the following formula (I): wherein Z1 represents an atomic group necessary to form a 5- or 6-membered nitrogen-containing heterocyclic ring; Z2 represents an atomic group necessary to form a 5- or 6-membered heterocyclic ring, Z2 may further be substituted, or may be condensed with a hetero ring or a benzene ring; R1 represents a hydrogen atom, a halogen atom, a mercapto group, an alkyl group, an alkenyl group, an aryl group, an alkylthio group, an alkenylthio group, or an arylthio group; L1 and L2 each represents a methine group; p1 represents 0 or 1; V1 represents a substituent; and n represents 0, 1 or 2, and when n represents 2, a plurality of V1 may be the same or different.Type: GrantFiled: March 10, 2000Date of Patent: December 25, 2001Assignee: Fuji Photo Film Co., Ltd.Inventors: Katsumi Kobayashi, Takashi Katoh, Junji Nishigaki
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Publication number: 20010031430Abstract: A photothermographic material is disclose, comprising a light-sensitive silver halide, an organic silver salt, a reducing agent, a thiuronium salt and a binder, wherein the photothermographic material further contains at least one of compounds represented by formulas such as 1Type: ApplicationFiled: January 17, 2001Publication date: October 18, 2001Inventors: Shinji Kudo, Keiko Chigusa, Hiroshi Kashiwagi
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Patent number: 6218096Abstract: A silver halide (AgX) color photosensitive material comprises, on a support, a AgX emulsion layer (BL) containing a yellow coupler and spectrally sensitized such that a spectral sensitivity region is 400 to 520 nm, a AgX emulsion layer (GL) containing a magenta coupler and spectrally sensitized such that a spectral sensitivity region is 470 to 600 nm, and a AgX emulsion layer (RL) containing a cyan coupler and spectrally sensitized such that a spectral sensitivity region is 540 to 700 nm, wherein barycentric sensitivity wavelength of a spectral sensitivity distribution of GL (&lgr;G), that of RL (&lgr;R), and that of BL (&lgr;B) are 520 to 580 nm, 590 to 650 nm, and 430 to 485 nm, respectively, the material further has an interlayer effect donor lay (DL) by which a barycentric wavelength (&lgr;−R) of a magnitude distribution of an interlayer effect given to at least one RL at a wavelength of 500 to 600 nm satisfies 500 nm≦&lgr;−R≦560 nm, and &lgr;G−&lgr;−R≧5 nm, DL is placed cType: GrantFiled: April 20, 1999Date of Patent: April 17, 2001Assignee: Fuji Photo Film Co., Ltd.Inventors: Yoshio Ishii, Akira Ikeda, Fumitaka Ueda, Hiroyuki Yamagami, Yoshiharu Yabuki
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Patent number: 6156466Abstract: The present invention relates to photoconductors which exhibit excellent electrical properties which are not appreciably affected by environmental changes or by repeated use. Having excellent durability during repeated printing, these photoconductors can be used to obtain large quantities of high-quality output images.The photoconductor according to the invention includes a conductive substrate and a photoconductive film on the conductive substrate. The photoconductive film includes a plurality of charge generation and transport layers, wherein each layer contains a phthalocyanine compound described in the specification by chemical formula (I) as a charge generation agent and a charge transport agent dispersed or dissolved into a binder. The concentration of the charge generation agent in an upper layer is higher than in a lower layer.Type: GrantFiled: July 8, 1998Date of Patent: December 5, 2000Assignee: Fuji Electric Co., Ltd.Inventors: Shinichi Tamura, Tadashi Mimura, Yoji Yamada, Tadashi Asakawa, Hiroshi Kimura
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Patent number: 6090511Abstract: An improved photoreceptor is disclosed which contains a multi-layered charge generation layer formed on a substrate and a charge transport layer formed on the multi-layered charge generation layer. The multi-layered charge generation member is formed by sequentially forming a plurality of charge generation sub-layers first on the substrate then on the charge generation sub-layer that was already formed, so as to create at least one interface between the charge generation layers. The charge generation materials in the plurality of charge generation layers must satisfy the following relationship:(IP).sub.CGL1 .gtoreq.(IP).sub.CGL2 .gtoreq.(IP).sub.CGL3 . . . .gtoreq.(IP).sub.CGLnwherein: (IP).sub.CGLi, i=1, 2, . . . , n, represents an ionization potential of the charge generation material in charge generation layer i; and (b) a lower value of i indicating closer proximity to the substrate, and a greater value i indicates further away from the substrate.Type: GrantFiled: August 21, 1998Date of Patent: July 18, 2000Assignee: Sinonar Corp.Inventors: Chen-Jen Yang, Kuo-Chu Yeh
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Patent number: 5965345Abstract: A method of sensitizing a silver halide emulsion comprises the steps of:a) forming a co-dispersion of a first sensitizing dye and a second sensitizing dye in an aqueous medium, wherein the peak absorptance of the second dye is at least 10 nm different from the peak absorptance of the first dye, and wherein the ratio of the first dye to the second dye is from about 0.1 to 20; andb) incorporating the resulting co-dispersion in a silver halide emulsion.Type: GrantFiled: December 12, 1995Date of Patent: October 12, 1999Assignee: Eastman Kodak CompanyInventors: Steven George Link, John William Boettcher, Frederick Charles Derks, Heidi Melissa Viterise
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Patent number: 5958667Abstract: A photothermographic recording material comprising a support and a photo-addressable thermally developable element containing a substantially light-insensitive organic silver salt, a reducing agent therefor in thermal working relationship therewith, photosensitive silver halide spectrally sensitized to wavelengths >700 nm with a dye and in catalytic association with the substantially light-insensitive organic silver salt and a water-soluble binder, a water-dispersible binder or a mixture of a water-soluble and a water-dispersible binder, characterized in that the photothermographic recording material has an infra-red sensitivity of less than 80 J/m.sup.2 and the dye satisfies the following test: an exposure required by a photothermographic recording material A, consisting of a polyester 100 .mu.Type: GrantFiled: July 8, 1997Date of Patent: September 28, 1999Assignee: Agfa-GevaertInventors: Geert Deroover, Paul Callant, Herman Uytterhoeven
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Patent number: 5928854Abstract: A silver halide photosensitive material is described, which comprises at least one of the compounds represented by the following formula (I) ##STR1## wherein Z.sub.1 and Z.sub.2 each represents an atomic group necessary for forming a five- or six-membered nitrogen-containing heterocyclic ring, R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each represents an alkyl group, an aryl group or a heterocyclic group, Q represents a divalent linking group or a single bond, with the proviso that at least one of R.sub.1, R.sub.2, R.sub.3, R.sub.4 and Q is substituted with a water-soluble group, L.sub.1, L.sub.2, L.sub.3, L.sub.4, L.sub.5, L.sub.6, L.sub.7 and L.sub.8 each represents a methine group, n.sub.1 and n.sub.2 each is 0, 1, 2, 3 or 4, p.sub.1 and p.sub.2 each is 0 or 1, M.sub.1 represents a charge equilibrium counter ion, and m.sub.1 is a number of from 0 to 10, which is necessary for neutralizing charge of the molecule.Type: GrantFiled: June 2, 1998Date of Patent: July 27, 1999Assignee: Fuji Photo Film Co., Ltd.Inventor: Takanori Hioki
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Patent number: 5863714Abstract: There is disclosed a silver halide light-sensitive material which contains a methine compound represented by general formula (1):General formula (1) ##STR1## wherein A1, A2, and A3 each represent a streptocyanine dye; L1, L2, L3, and L4 each represent a divalent linking group, and n1 represents an integer of not less than 0. The light-sensitive material exhibits high absorptivity.Type: GrantFiled: April 15, 1997Date of Patent: January 26, 1999Assignee: Fuji Photo Film Co., Ltd.Inventors: Takashi Kato, Takayoshi Oyamada
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Patent number: 5851752Abstract: Disclosed is a silver halide photographic material comprising a support having provided thereon at least one silver halide emulsion layer comprising a substantially surface-latent-image-type silver halide emulsion which comprises hole-injection-type sensitizing dye(s) in an amount of 4.times.10.sup.-4 mol or more per mol of silver in the emulsion and further comprises supersensitizing compound(s), wherein the hole-injection-type sensitizing dye and the supersensitizing compound satisfy the requirements defined herein. The photographic material, thus comprising at least one silver halide emulsion that has been spectrally sensitized with a large amount of sensitizing dyes in a wavelength range longer than 545 nm and has been further sensitized by reduction sensitization, has a much increased sensitivity, while being fogged poorly, and has excellent storage stability.Type: GrantFiled: July 7, 1995Date of Patent: December 22, 1998Assignee: Fuji Photo Film Co., Ltd.Inventors: Mitsuhiro Uchida, Shunji Takada
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Patent number: 5851755Abstract: A photothermographic recording material comprising a photo-addressable thermally developable element containing a substantially light-insensitive organic silver salt, photosensitive silver halide in catalytic association with the substantially light-insensitive organic silver salt and spectrally sensitized to infra-red light with a dye, a supersensitizer for the dye, a reducing agent in thermal working relationship with the substantially light-insensitive organic silver salt and a binder, wherein the binder includes a water soluble polymer, a water-dispersible polymer or a water soluble polymer and a water-dispersible polymer; the dye absorbs electromagnetic radiation in the wavelength range from 700 to 1100 nm; and the supersensitizer is a stilbene compound represented by general formula (I): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently hydrogen or alkyl, aryl, aralkyl, alkaryl, alkoxy or aryloxy groups; and R.sup.5, R.sup.6, R.sup.7, R.sup.8, R.sup.9, R.sup.10, R.sup.11 and R.Type: GrantFiled: July 8, 1997Date of Patent: December 22, 1998Assignee: Agfa-GevaertInventors: Herman Uytterhoeven, Johan Loccufier, Geert Deroover, Paul Callant
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Patent number: 5821044Abstract: A spectrally sensitised photographic silver halide emulsion which is super-sensitised with an aromatic complex having a central transition metal atom which is present in a valence state which is not the highest possible for the metal concerned and which complex contains at least one non-aromatic complex ligand, is distinguished by increased sensitivity.Type: GrantFiled: July 17, 1997Date of Patent: October 13, 1998Assignee: Agfa-Gevaert AktiengesellschaftInventors: Peter Bergthaller, Jorg Siegel, Hans-Ulrich Borst, Michael Missfeldt
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Patent number: 5804362Abstract: A silver halide photographic material is disclosed, comprising a support having thereon at least one silver halide photographic emulsion layer of a silver halide emulsion, wherein the emulsion layer comprises monodisperse cubic silver halide grains which contain at least one metal atom of group VIII in the Periodic Table, and the silver halide emulsion is spectrally sensitized so as to have a sensitization maximum at a wavelength of 750 nm or more and further contains at least one of compounds represented by the following formulae (I-a), (I-b) and (I-c): ##STR1## wherein Z represents an alkyl group containing 1 to 18 carbon atoms, an aryl group containing 6 to 18 carbon atoms, or a heterocyclic group; Y represents atoms necessary to complete an aromatic ring containing 6 to 18 carbon atoms, or a hetero ring; M represents a metal atom or an organic cation; and n represents an integer of from 2 to 10.Type: GrantFiled: March 21, 1997Date of Patent: September 8, 1998Assignee: Fuji Photo Film Co., Ltd.Inventors: Koichi Kuno, Yuji Mihara
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Patent number: 5580711Abstract: Disclosed is silver halide photographic light-sensitive material comprising a support and thereon at least one light-sensitive silver halide emulsion layer, wherein at least one layer of said light-sensitive silver halide emulsion layer contains silver halide grains spectrally sensitized with a dye selected from the group consisting of Formula S-I and Formula S-II: ##STR1##Type: GrantFiled: March 21, 1996Date of Patent: December 3, 1996Assignee: Konica CorporationInventors: Nobuaki Kagawa, Noriyasu Kita
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Patent number: 5518876Abstract: A photographic materials with a high silver chloride red sensitive layer which has a high sensitivity and exhibits reduced thermal sensitivity. In particular the material has a silver halide emulsion of at least 90% silver chloride and compounds of formula I and II below: ##STR1## Where A, Z, X1, X2, R1, R2, W1-W12, D, G1, G2, Y1, Y2 are as defined in the specification.Type: GrantFiled: March 29, 1995Date of Patent: May 21, 1996Assignee: Eastman Kodak CompanyInventors: Richard L. Parton, David A. Stegman, Pamela M. Ferguson
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Patent number: 5514533Abstract: A silver halide photographic photosensitive material comprises a silver halide photographic emulsion layer and a compound represented by general formula (I): ##STR1## wherein V.sub.1 and V.sub.2 each represents a hydrogen atom, an alkyl group or an alkoxy group; at least one of V.sub.1 and V.sub.2 is an alkyl group or an alkoxy group; Z.sub.1 represents a group of atoms which is required to form a five- or six-membered nitrogen-containing heterocyclic ring; Z.sub.2 represents a group of atoms which is required to form a five- or six-membered nitrogen-containing heterocyclic ring; Z.sub.3 represents an oxygen atom, a sulfur atom or a selenium atom; R.sub.1 and R.sub.3 each represents an alkyl group; R.sub.2 represents an alkyl group, an aryl group or a heterocyclic group; L.sub.1, L.sub.2 and L.sub.3 each represents a methine group; M.sub.1 represents a charge neutralizing counter-ion; and m.sub.1 is a number having a value zero or above which is required to neutralize the charge within the molecule.Type: GrantFiled: October 4, 1994Date of Patent: May 7, 1996Assignee: Fuji Photo Film Co., LTD.Inventors: Takanori Hioki, Tetsuo Yoshida
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Patent number: 5501946Abstract: A pre-fogged direct reversal silver halide photographic material comprises on a support at least an emulsion layer comprising a previously fogged silver halide emulsion for forming a direct positive image.Type: GrantFiled: July 27, 1994Date of Patent: March 26, 1996Assignee: Fuji Photo Film Co., Ltd.Inventors: Yoshihiro Takagi, Yoshio Inagaki
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Patent number: 5489505Abstract: A silver halide photographic material which contains methine dyes represented by formula (I) to obtain high sensitivity and excellent storage stability: ##STR1## wherein Z.sub.1 and Z.sub.2 each represents atoms necessary to complete a 5- or 6-membered nitrogen-containing hetero ring; Q represents atoms necessary to complete a 5- or 6-membered ring; R.sub.1 represents an alkyl group, an aryl group or a heterocyclyl group; R.sub.2 and R.sub.3 each represents an alkyl group; L.sub.1, L.sub.2, L.sub.3, L.sub.4, L.sub.5 and L.sub.6 each represents a methine group; n.sub.1 and n.sub.2 each represents 0 or 1; M represents an ion for neutralizing electric charges; and m is a number necessary for neutralization of electric charges in the dye molecule, including 0.Type: GrantFiled: March 2, 1995Date of Patent: February 6, 1996Assignee: Fuji Photo Film Co., Ltd.Inventors: Takashi Kato, Takanori Hioki, Tadashi Ikeda
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Patent number: 5478719Abstract: The present invention provides a high sensitivity silver halide photographic material which minimizes the formation of fog and exhibits a small sensitivity drop during storage. A silver halide photographic material is provided comprising a compound having a methine dye and a styryl base covalently connected to each other.Type: GrantFiled: September 15, 1994Date of Patent: December 26, 1995Assignee: Fuji Photo Film Co., Ltd.Inventors: Takanori Hioki, Hiroshi Kawakami
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Patent number: 5453353Abstract: Disclosed is a silver halide photographic light-sensitive material comprising a support and thereon at least one light-sensitive silver halide emulsion layer, wherein said silver halide emulsion layer contains a compound represented by Formula S-I and a compound represented by Formulas S-II or S-III: ##STR1##Type: GrantFiled: April 8, 1994Date of Patent: September 26, 1995Assignee: Konica CorporationInventors: Takeo Arai, Nobuaki Kagawa
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Patent number: 5348850Abstract: A silver halide photographic material has on a support at least one light-sensitive silver halide emulsion layer which comprises silver halide emulsion grains having a chloride content: of at least 50 mol % and containing a metal selected from rhodium, ruthenium and rhenium in an amount of at least 10.sup.-8 mole per mole of silver, said silver halide emulsion being spectrally sensitized with a compound of general formula (I) and being chemically sensitized with a selenium or tellurium compound: ##STR1## wherein Z and Z.sub.1 each represents a group of nonmetallic atoms necessary to complete a 5- or 6-membered nitrogen-containing heterocyclic nucleus; R and R.sub.1 each represents an unsubstituted or substituted alkyl group, or an unsubstituted aryl group; Q and Q.sub.1 each represents a group of atoms necessary to complete a 4-thiazolidinone, 5-thiazolidinone or 4-imidazolidinone nucleus; L, L.sub.1 and L.sub.2 each represents an unsubstituted or substituted methine group; n.sub.1 and n.sub.Type: GrantFiled: August 27, 1993Date of Patent: September 20, 1994Assignee: Fuji Photo Film Co., Ltd.Inventor: Tetsuo Yoshida
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Patent number: 5288738Abstract: A novel red-sensitizing dye compound has a structure which contains a pentamethine oxonol chromophore linked to one or two cyanine chromophores. A photographic element comprises a support upon which is coated a silver halide emulsion layer comprising cubic silver halide crystals and said red-sensitizing dye compound.Type: GrantFiled: April 8, 1992Date of Patent: February 22, 1994Assignee: Eastman Kodak CompanyInventors: Lal C. Vishwakarma, Thomas R. Dobles
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Patent number: 5260183Abstract: A novel silver halide photographic material comprising at least one silver halide emulsion layer on a support is provided, characterized in that said emulsion layer comprises (i) silver halide grains which are at least 80 mol % silver chloride, (ii) at least one thiocyanate, (iii) at least one cyanine dye represented by general formula (I) and (iv) at least one compound represented by general formula (II), (III) or (IV): ##STR1##Type: GrantFiled: January 28, 1992Date of Patent: November 9, 1993Assignee: Fuji Photo Film Co., Ltd.Inventors: Shoji Ishiguro, Tadashi Ikeda
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Patent number: 5234806Abstract: The present invention provides dyes markedly excellent as sensitizing dyes for silver halide photographic light-sensitive materials. Said dyes are represented by the following formula (I): ##STR1## wherein R.sub.1 and R.sub.2 may be identical or different and each represents an alkyl group, an aralkyl group, an alkenyl group or an aryl group, R.sub.3 represents a heterocyclic group, Z.sub.1 and Z.sub.2 may be identical or different and each represents a group of atoms necessary to form a 5- or 6-membered nitrogen-containing heterocyclic ring, X represents a counter ion, L.sub.1 to L.sub.5 each represents a methine group, and m and n each represents 0, 1 or 2.Type: GrantFiled: December 4, 1991Date of Patent: August 10, 1993Assignee: Mitsubishi Paper Mills LimitedInventors: Satoshi Kaneko, Akira Tanaka
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Patent number: 5192653Abstract: A method for spectrally sensitizing silver halide emulsions is disclosed, comprising the step of adding a cyanine dye, which provides a J-band when added to silver halide emulsions, to a silver halide emulsion followed by ripening with such conditions that the relative quantum yield .phi..sub.r of spectral sensitization assumes a value of 1/2 or less of the .phi..sub.r of spectral sensitization obtained when the dye is added to the emulsion under ripening conditions of 40.degree. C. and 20 minutes from the time of addition of the dye to the emulsion until the time of coating the emulsion, and then ripening the silver halide emulsions. In one embodiment of the disclosed method, a heterocyclic compound which contains a mercapto group is added to the emulsion before the addition of the dye in an amount sufficient to increase the .phi..sub.r.Type: GrantFiled: February 26, 1992Date of Patent: March 9, 1993Assignee: Fuji Photo Film Co., Ltd.Inventor: Tadaaki Tani
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Patent number: 5185236Abstract: A full color recording material which has, on a support, at least three silver halide photosensitive emulsion layers which have different color sensitivities and which contain a yellow coupler, magenta coupler and cyan coupler, respectively, and in which at least two of these layers are selectively spectrally sensitized to match semiconductor laser light beams of wavelengths greater than 670 nm, wherein said at least three silver halide photosensitive layers which have different color sensitivities each contains silver chlorobromide grains with a layer average silver chloride content of at least 96 mol %, and said silver chlorobromide grains have a silver bromide local phase of which the silver bromide content is higher than that of the surroundings and a method for forming color images wherein the recording material is imagewise exposed while being transported at a feed rate which matches the scanning rate with semiconductor light beams, and substantially continuously to the exposing, the material is subjectType: GrantFiled: July 15, 1991Date of Patent: February 9, 1993Assignee: Fuji Photo Film Co., Ltd.Inventors: Keisuke Shiba, Kiyoshi Kawai, Masaki Okazaki, Yoshiharu Okino
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Patent number: 5166047Abstract: Silver halide photographic materials containing methine compounds of general formulas Ia, Ib, Ic, IIa, and IIb are disclosed. The variables are as defined in the present specification.Type: GrantFiled: February 19, 1991Date of Patent: November 24, 1992Assignee: Fuji Photo Film Co. Ltd.Inventors: Takanori Hioki, Tadashi Ikeda
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Patent number: 5112731Abstract: A silver halide photographic material is disclosed, which comprises a support having coated thereon at least one silver halide emulsion layer, wherein the emulsion layer comprises tabular grains of silver chloride, silver bromide, silver chlorobromide or silver chloroiodobromide having an iodide content of 1 mol % or less, which have an average aspect ratio of 3 or more and which have been spectrally sensitized with at least one spectral sensitizing dyes described below.Type: GrantFiled: August 30, 1990Date of Patent: May 12, 1992Assignee: Fuji Photo Film Co., Ltd.Inventor: Nobuaki Miyasaka
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Patent number: 5093222Abstract: A negative silver halide photographic light-sensitive material comprising a support having thereon at least one silver halide emulsion layer, wherein said silver halide emulsion layer or another hydrophilic colloid layer provided on the support contains (i) a hydrazine derivative, (ii) at least one cationic dye selected from the group consisting of cyanine dyes, hemicyanine dyes and rhodacyanine dyes, and (iii) a compound represented by formula (I) and having substantially no absorption maximum at the visible region; ##STR1## wherein Z.sup.11, Z.sup.12, R.sup.11, R.sup.12, X and n are defined in the specification.Type: GrantFiled: October 26, 1988Date of Patent: March 3, 1992Assignee: Fuji Photo Film Co., Ltd.Inventor: Kazunobu Katoh
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Patent number: 5091293Abstract: A high-speed color negative photographic material which comprises, a support having provided thereon, at least one red-sensitive silver halide emulsion layer, at least one green-sensitive silver halide emulsion layer and at least one blue-sensitive emulsion layer, and is designated so as to acquire a specific photographic sensitivity (defined in detailed description of the invention) of 800 or above, and has a combined total of silver coverages ranging from 3.0 g/m.sup.2 to 9.0 g/m.sup.2 so as to minimize an increase in fog, a decrease in photographic speed and deterioration in granularity, which heretofore have occurred in high-speed photographic materials during long-range storage before used. In addition, the present photographic material enables enhancement of pressure resistance and processing efficiency.Type: GrantFiled: June 25, 1990Date of Patent: February 25, 1992Assignee: Fuji Photo Film Co., Ltd.Inventors: Yasushi Nozawa, Hideto Ikoma, Keiji Mihayashi, Yoshihiko Shibahara
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Patent number: 5061618Abstract: A photographic element is described comprising a support having thereon a silver halide emulsion layer where the silver halide is sensitized with a dye having the formula: ##STR1## wherein where Z.sub.1, Z.sub.2, Z.sub.3, R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, and X are as defined herein.Type: GrantFiled: March 28, 1990Date of Patent: October 29, 1991Assignee: Eastman Kodak CompanyInventors: Richard L. Parton, Annabel A. Muenter, David A. Stegman
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Patent number: 5059516Abstract: A silver halide photographic material that contains at least one compound represented by the general formula (2) shown below and at least one compound selected from the group consisting of the compounds represented by the general formulas (3) and (4) shown below: ##STR1## The constituents in the above formulas are clearly defined in the instant specification and claims.Type: GrantFiled: October 30, 1990Date of Patent: October 22, 1991Assignee: Konica CorporationInventors: Kiyoshi Sato, Kouji Ono
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Patent number: 5059508Abstract: The present invention provides a method of preparing a planographic printing plate comprising the steps of:(1) exposing a DTR mono-sheet material containing a silver halide emulsion layer and a nuclei containing surface layer in a laser beam containing device, e.g. a helium-neon laser, an argon laser, or a semiconductor laser, wherein the said emulsion layer contains at least one emulsion showing following characteristics:(a) the emulsion consists principally of silver chloride but contains bromide ranging from 5 mole % to 40 mole % and iodide ranging from 0 to 1 mole %;(b) the emulsion belongs to the core-shell type wherein substantially all the bromide is concentrated in the core;(c) the emulsion grains contain Rhodium and/or Iridium dopants;(2) processing the DTR material by means of a developing or activator solution, containing at least an alkali agent and a silver halide complexing agent, followed by a neutralization solution.Type: GrantFiled: October 11, 1990Date of Patent: October 22, 1991Assignee: Agfa-Gevaert, N.V.Inventors: Jos A. Vaes, Luc J. Wabbes
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Patent number: 5009992Abstract: Photographic silver halide emulsion, sensitized for infrared spectral region, containing an aromatic thiosulfonic acid or a salt of the acid. The emulsion is useful for preparing photographic elements having sensitivity in the infrared spectral region.Type: GrantFiled: December 20, 1989Date of Patent: April 23, 1991Assignee: E. I. DuPont de Nemours and CompanyInventors: Wolfgang Friedrich, Alfred Worsching