Merocyanine Compound Patents (Class 430/577)
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Patent number: 8445857Abstract: A flame sensor is provided with a focusing member. Ultraviolet light emitted from a light source is reflected by an inner surface of the focusing member to be focused on an electrode of an electrode pair, to increase the sensitivity.Type: GrantFiled: March 11, 2011Date of Patent: May 21, 2013Assignee: Azbil CorporationInventors: Yoshihide Sugino, Keisuke Sumiyoshi, Nanako Yanada, Yuuichi Nakajima
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Patent number: 7351523Abstract: The use of a red-sensitising trinuclear merocyanine dye and an osmium dopant according to formula (I): [Os(NZ)L5]r wherein Z is sulphur or oxygen, L is a ligand and r is 0, ?1, ?2 or ?3, in photographic silver halide emulsions for use in photographic materials, result in a reduction and/or prevention of speed gain in the emulsion over time without significant speed loss.Type: GrantFiled: November 14, 2004Date of Patent: April 1, 2008Assignee: Eastman Kodak CompanyInventors: Nicholas E. Grzeskowiak, Colin J. Gray
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Patent number: 7303851Abstract: Disclosed is a silver halide photographic light-sensitive material wherein a silver halide emulsion layer and/or a hydrophilic colloid layer contains at least one hydrazine derivative, and a silver halide emulsion is spectrally sensitized with a particular dye, and which contains a benzotriazol compound. There is provided a silver halide photographic light-sensitive material that exhibits superior residual color property and can provide stable photographic performance even after a long term running with a reduced silver amount.Type: GrantFiled: September 29, 2003Date of Patent: December 4, 2007Assignee: Fujifilm CorporationInventors: Mitsunori Hirano, Kunio Ishigaki, Tokuju Oikawa
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Patent number: 7291449Abstract: Disclosed is a silver halide photographic material which comprises at least one methine dye represented by the following formula (I): wherein Y represents a furan ring or a pyrrole ring, and Y may further be condensed with other 5- or 6-membered carbocyclic ring or heterocyclic ring, or may have a substituent; the bond between two carbon atoms in which Y is condensed may be a single bond or a double bond; Z represents an atomic group necessary to form a 5- or 6-membered nitrogen-containing heterocyclic ring, and Z may further be condensed with other 5- or 6-membered carbocyclic ring or heterocyclic ring; R represents a substituted or unsubstituted alkyl group, aryl group, or heterocyclic group; D represents a group necessary to form a methine dye; L1 and L2 each represents a methine group; p represents 0 or 1; M represents a counter ion; and m represents a number of 0 or higher necessary to neutralize the charge in the molecule.Type: GrantFiled: August 17, 2001Date of Patent: November 6, 2007Assignee: Fujifilm CorporationInventors: Tetsuo Nakamura, Takanori Hioki, Katsuhisa Ohzeki, Naoyuki Hanaki
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Patent number: 7083906Abstract: A heat-developable photosensitive material having on a support at least one light-sensitive layer comprising an organic silver salt, a light-sensitive silver halide and a reducing agent and at least one light-insensitive layer, which comprises an antihalation dye causing no decoloration by heat and provides tone represented by an inequality L*?92 on the CIELAB space in a background after heat development.Type: GrantFiled: March 7, 2003Date of Patent: August 1, 2006Assignee: Fuji Photo Film Co., Ltd.Inventors: Keiichi Suzuki, Hideyasu Ishibashi
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Patent number: 7067243Abstract: A process for preparing a photothermographic material with increased photosensitivity, the photothermographic material comprising a support and a photo-addressable thermally developable element, exclusive of a compound R—S(M)n wherein R is an aliphatic hydrocarbon, aryl or heterocyclic group, M is a hydrogen atom, or cation, and letter n is a number determined so as to render the molecule neutral and also exclusive of a compound capable of releasing a mobile dye corresponding to or inversely corresponding to the reduction of silver halide to silver at elevated temperatures, the photo-addressable thermally developable element containing a photosensitive agent in catalytic association with a light-insensitive organic silver salt, a reducing agent for the light-insensitive organic silver salt in thermal working relationship therewith and a binder, comprising the steps of: (i) increasing the photosensitivity of a photosensitive silver halide by chemical sensitisation with a chemical sensitising merocyanine dye coType: GrantFiled: March 7, 2003Date of Patent: June 27, 2006Assignee: Agfa GevaertInventors: Herman Uytterhoeven, Paul Callant
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Patent number: 7052827Abstract: A silver halide photographic material including at least one methine dye represented by the following general formula (I) and at least one coupler represented by the following general formula (XX): wherein X1 and X2 each represents an oxygen atom, a sulfur atom, a selenium atom, a tellurium atom, or a nitrogen atom; Y1 represents a furan, pyrrole or thiophene ring which may be condensed with another 5- or 6-membered carbon ring or heterocycle or may have a substituent group; Y2 represents an atomic group necessary for forming a benzene ring or a 5- or 6-membered unsaturated heterocycle, which may be further condensed with another 5- or 6-membered carbon ring or heterocycle or may have a substituent group; a bond between two carbon atoms by which Y1 and Y2 are each condensed with the carbon ring or the heterocycle may be a single bond or a double bond; R1 and R2 each represents a substituted or unsubstituted alkyl, aryl or heterocyclic group; L1, L2 and L3 each represents a methine group; n1 represents 0 oType: GrantFiled: August 27, 2004Date of Patent: May 30, 2006Assignee: Fuji Photo Film Co., Ltd.Inventor: Tetsuo Nakamura
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Patent number: 6908730Abstract: This invention relates to a silver halide photographic material comprising at least one silver halide emulsion comprising silver halide grains having associated therewith: (a) a first dye (Dye 1) that is a cyanine dye capable of spectrally sensitizing a silver halide emulsion and that has at least one anionic substituent; and (b) a second dye (Dye 2) that is not a cyanine dye and that has at least one cationic substituent. Dye 2 has a log P, excluding any counterion, of less than 4.00 and greater than 1.00 or Dye 2 is represented by a dye of formula II as described herein.Type: GrantFiled: January 17, 2003Date of Patent: June 21, 2005Assignee: Eastman Kodak CompanyInventors: Richard L. Parton, Thomas L. Penner, David R. Foster, Stephen A. Hershey
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Patent number: 6875562Abstract: A silver halide photographic emulsion which contains silver halide grains having light absorption strength of 100 or more.Type: GrantFiled: January 28, 2003Date of Patent: April 5, 2005Assignee: Fuji Photo Film Co., Ltd.Inventors: Katsuhiro Yamashita, Katsumi Kobayashi
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Patent number: 6875859Abstract: The invention concerns compounds of the general formula (I) in which the residues R1 to R7 have the meanings given in the application as well as methods for their preparation.Type: GrantFiled: March 11, 2002Date of Patent: April 5, 2005Assignee: Roche Diagnostics GmbHInventors: Klaus Mühlegger, Herbert Von Der Eltz
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Patent number: 6828087Abstract: A silver halide photographic material comprising at least one methine dye of formula (I) and at least one coupler of formula (X): wherein X1 and X2 each represents O, S, Se, Te, N or C; Y1 represents a furan, pyrrole or thiophene ring which may be condensed and substituted with the specific ring; Y2 represents an atomic group necessary for forming a benzene ring or a 5- or 6-membered unsaturated heterocycle; R1 and R2 each represents a substituted or unsubstituted alkyl, aryl or heterocyclic group; L1, L2 and L3 each represents a methine group; n1 represents 0 or 1; M1 represents a counter ion; and m1 represents a number of 0 or more necessary for neutralizing a charge in a molecule; wherein Z1 and Z2 each represents —C(Q3)═ or —N═; Q1 and Q3 each represents a hydrogen atom or a monovalent substituent group; Q2 represents a hydrogen atom or a coupling release group.Type: GrantFiled: September 23, 2002Date of Patent: December 7, 2004Assignee: Fuji Photo Film Co., Ltd.Inventor: Tetsuo Nakamura
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Patent number: 6794122Abstract: A silver halide photographic material comprising a support having thereon at least one silver halide photographic emulsion layer, wherein the emulsion layer contains at least one compound of formulae (Ia), (Ib) and (Ic) and at least one compound of formula (II): wherein Z1 represents S, O, Se, Te, N or C; R, R31 and R32 each are an alkyl, aryl or heterocyclic group; D is a group necessary for forming a methine dye; V1 to V4 represent H or a monovalent substituent; M and M3 each are a charge-balancing counter ion; m and m3 each are a number or 0 or more necessary for neutralizing the charge of the molecule; Z31 and Z32 each are an atomic group necessary for forming the nitrogen-containing hetero-ring; L31 to L37 each represent a methine group; p31 and p32 each are 0 or 1; n3 is 0, 1, 2, 3 or 4, but the compound of formula (II) does not include the compounds of formulae (Ia), (Ib) and (Ic).Type: GrantFiled: December 4, 2002Date of Patent: September 21, 2004Assignee: Fuji Photo Film Co., Ltd.Inventors: Takanori Hioki, Tetsuo Nakamura
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Patent number: 6794121Abstract: This invention relates to a method of spectrally sensitizing a silver halide emulsion comprising the following steps in the following order a) providing a silver halide emulsion comprising tabular silver halide grains having an inner dye layer adjacent to the silver halide grain, said dye layer comprising at least one dye (Dye 1) that is capable of spectrally sensitizing silver halide, b) adding to the emulsion at least one dye (Dye 2) capable of providing a second dye layer adjacent to the inner dye layer, and c) adding to the emulsion a non-cationic surfactant or a scavenger for oxidized developer, or a combination of the two, to form a silver halide emulsion comprising silver halide grains having associated therewith two dye layers, wherein the dye layers are held together by non-covalent forces or by in situ bond formation; the outer dye layer adsorbs light at equal or higher energy than the inner dye layer; and the energy emission wavelength of the outer dye layer overlaps with the energy absorptionType: GrantFiled: January 17, 2003Date of Patent: September 21, 2004Assignee: Eastman Kodak CompanyInventors: David R. Foster, Stephen P. Singer, William J. Harrison, Alan R. Pitt
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Patent number: 6770433Abstract: A high-sensitive silver halide photographic light-sensitive material is provided. A silver halide photographic light-sensitive material comprising a dye having a plurality of dye chromophores, which contains at least one dye where at least one of the dye chromophores is a methine dye chromophore containing a basic nucleus comprising a monocyclic heterocyclic ring.Type: GrantFiled: January 11, 2002Date of Patent: August 3, 2004Assignee: Fuji Photo Film Co., Ltd.Inventor: Takanori Hioki
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Publication number: 20040126721Abstract: Disclosed is a silver halide photographic light-sensitive material wherein a silver halide emulsion layer and/or a hydrophilic colloid layer contains at least one hydrazine derivative, and a silver halide emulsion is spectrally sensitized with a particular dye, and which contains a benzotriazol compound. There is provided a silver halide photographic light-sensitive material that exhibits superior residual color property and can provide stable photographic performance even after a long term running with a reduced silver amount.Type: ApplicationFiled: September 29, 2003Publication date: July 1, 2004Inventors: Mitsunori Hirano, Kunio Ishigaki, Tokuju Oikawa
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Patent number: 6756191Abstract: A silver halide photographic light-sensitive emulsion comprising a silver halide and a compound represented by the following Formula (I): wherein each X3 and X4 represents independently N, P, S, Se or Te; each Y1 and Y2 represents independently a group of carbon atoms necessary to complete a 6 to 12 membered heterocyclic ring with X3 and X4.Type: GrantFiled: July 19, 2002Date of Patent: June 29, 2004Assignee: Konica CorporationInventors: Tatsuo Tanaka, Nobuaki Kagawa, Yoshiko Iwai, Tomohiro Oshiyama
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Patent number: 6730461Abstract: A photothermographic material that comprises a support having thereon one or more thermally-developable imaging layers comprising a binder and in reactive association, a photosensitive silver halide, a non-photosensitive source of reducible silver ions, and a reducing composition for the non-photosensitive source reducible silver ions. The thermally-developable layers further comprises one or more radiation absorbing compounds that provide a total absorbance of greater than 0.6 and up to and including 3 in the thermally-developable imaging layer(s). These photothermographic materials are independently coated and dried while the material is conveyed at a rate of at least 5 meters per minute.Type: GrantFiled: October 26, 2001Date of Patent: May 4, 2004Assignee: Eastman Kodak CompanyInventors: Bryan V. Hunt, Steven H. Kong, William D. Ramsden, Gary E. Labelle
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Patent number: 6686142Abstract: A chemically and spectrally-sensitized emulsion has been described, wherein said emulsion comprising (100) cubic silver halide grains with an average edge length of from 0.2 up to 1.5 &mgr;m, has been spectrally sensitized by addition at least three trimethine dyes: a main spectral sensitizer added in an amount of at least 85 mole % of all spectral sensitizers added, followed by adding a second spectral sensitizer in an amount of not more than 10 mole % and a third spectral sensitizer in an amount of at most 1 mole % wherein at least said main spectral sensitizer has two benzoxazole rings in its chemical structure, at least said third spectral sensitizer has two benzimidazole rings in its chemical structure and wherein the said second spectral sensitizer has a structure more sterically hindered than the structure of the other spectral sensitizers. A light-sensitive silver halide photographic film material coated with such emulsion and a radiographic screen/film combination has been described.Type: GrantFiled: March 4, 2002Date of Patent: February 3, 2004Assignee: Agfa-GevaertInventors: Kathy Elst, Paul Callant
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Patent number: 6649336Abstract: A silver halide photographic light-sensitive material is disclosed, including at least one silver halide emulsion layer, wherein the silver halide grain contained in the emulsion layer is silver chloroiodide or silver chloroiodobromide having a silver chloride content of 90 mol % or more and a silver iodide content of 0.01 to 1.0 mol %, at least one hexacyano complex is doped in an amount of at least 1×10−7 mol % based on the total silver amount, and the emulsion layer contains a methine dye represented by the formula (I) as defined.Type: GrantFiled: September 25, 2001Date of Patent: November 18, 2003Assignee: Fuji Photo Film Co., LTDInventors: Katsuhisa Ohzeki, Tetsuo Nakamura
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Patent number: 6649335Abstract: A cyanine dye of formula (II) wherein X1 is C(R5, R6), NR7, O, S or Se, X2 is O, S, Se or NR13, R2 with R3, or R3 with R4, are the remaining members for the completion of a condensed furano ring system, and the other R2 or R4 radical, is H, a halogen, SH, CN, CF3, alkyl, aryl, heterocyclyl, alkoxy, aryloxy, alkylthio or arylthio, R10 to R12, are H, a halogen, SH, CN, CF3, alkyl, aryl, heterocyclyl, alkoxy, aryloxy, alkylthio or arylthio, or R10 with R11, or R11 with R12, are the remaining members for the completion of a ring system, R5 to R7 and R13 are alkyl, alkylene-SO3Z1 or alkylene-CO2Z1, R8 and R9 are alkyl, alkylene-SO3Z1, alkylene-CO2Z1 or alkylene-Y2—N(Z1)—Y3-alkyl, Z1 is H or a negative charge, Y2 and Y3 are —S(═O)2— or —C(═O)—, M1 is a counterion, L1, L2 and L3 are a methine group and n is 0, 1, 2 or 3.Type: GrantFiled: November 5, 2001Date of Patent: November 18, 2003Assignee: AGFA-GevaertInventor: Michael Missfeldt
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Publication number: 20030190564Abstract: A silver halide photographic material comprising a support having thereon at least one silver halide photographic emulsion layer, wherein the emulsion layer contains at least one compound of formulae (Ia), (Ib) and (Ic) and at least one compound of formula (II): 1Type: ApplicationFiled: December 4, 2002Publication date: October 9, 2003Applicant: FUJI PHOTO FILM CO., LTD.Inventors: Takanori Hioki, Tetsuo Nakamura
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Patent number: 6620581Abstract: This invention comprises a silver halide photographic material comprising at least one silver halide emulsion comprising silver halide grains having associated therewith at least two dyes: (a) a first dye that has at least one anionic substituent and that is capable of spectrally sensitizing a silver halide emulsion; and (b) a second dye that absorbs light at an equal or shorter wavelength than the first dye and that has at least one cationic substituent and that is highly fluorescent.Type: GrantFiled: October 16, 2000Date of Patent: September 16, 2003Assignee: Eastman Kodak CompanyInventors: Richard L. Parton, Joseph C. Deaton, William J. Harrison, Margaret J. Helber
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Patent number: 6610468Abstract: A silver halide photographic material having high sensitivity, low fog and good shelf life (i.e., storage stability), which comprises at least one kind of merocyanine dye represented by formula (I): wherein Z1 represents an atomic group necessary for forming a naphthoxazole ring, R1 and R2 each represents an unsubstituted or substituted alkyl group, an aryl group or a heterocyclic group, L1, L2, L3 and L4 each represents a methine group, M1 represents a charge neutralizing counter ion, and m1 is a number of 0 or more necessary for neutralizing a charge in a molecule.Type: GrantFiled: April 10, 2001Date of Patent: August 26, 2003Assignee: Fuji Photo Film Co., Ltd.Inventors: Takashi Katoh, Tomoyuki Ohzeki, Katsutoshi Yamane, Takanori Hioki
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Patent number: 6582892Abstract: A black-and-white photothermographic material that is sensitive at a wavelength greater than 700 nm, and comprises a support having thereon one or more thermally-developable imaging layers comprising a binder and in reactive association, a photosensitive silver halide, a non-photosensitive source of reducible silver ions, and a reducing composition for the non-photosensitive source reducible silver ions. The thermally-developable layers further comprises one or more indolenine dyes as post-processing stabilizing compounds and one or more merocyanine dyes or cyanine spectral sensitizing dyes that comprise one or more thioalkyl, thioaryl, or thioether groups.Type: GrantFiled: June 29, 2001Date of Patent: June 24, 2003Assignee: Eastman Kodak CompanyInventors: Steven H. Kong, Bryan V. Hunt, William D. Ramsden
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Patent number: 6582894Abstract: A silver halide photographic emulsion is disclosed, comprising a silver halide grain having a spectral absorption maximum wavelength of less than 500 nm and a light absorption intensity of 60 or more or having a spectral absorption maximum wavelength of 500 nm or more and a light absorption intensity of 100 or more, wherein assuming that a maximum value of the spectral absorption factor of said emulsion by a sensitizing dye is Amax, the distance between the shortest wavelength showing 80% of Amax and the longest wavelength showing 80% of Amax is 20 nm or more and the distance between the shortest wavelength showing 50% of Amax and the longest wavelength showing 50% of Amax is 120 nm or less.Type: GrantFiled: March 10, 2000Date of Patent: June 24, 2003Assignee: Fuji Photo Film Co., Ltd.Inventors: Takanori Hioki, Katsuhiro Yamashita, Katsumi Kobayashi, Takashi Katoh
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Patent number: 6566044Abstract: The present invention provides a silver halide photographic material that is excellent in photographic speed as well as image graininess and exhibits low residual color even after rapid processing. The silver halide photographic material contains a compound represented by formula (I) and a compound represented by formula (II), as defined.Type: GrantFiled: March 26, 2001Date of Patent: May 20, 2003Assignee: Fuji Photo Film Co., Ltd.Inventors: Katsuhisa Ohzeki, Tetsuo Nakamura, Takanori Hioki
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Patent number: 6562557Abstract: A color photographic material comprising a transparent support, at least one blue-sensitive, predominantly yellow-coupling silver halide emulsion layer, at least one green-sensitive, predominantly magenta-coupling silver halide emulsion layer (PP-1) and at least one red-sensitive, predominantly cyan-coupling silver halide emulsion layer (BG-1), characterised in that the spectral sensitivity distribution of BG-1 is characterised in that 605≦&lgr;max≦630 nm, 0.1≦&Dgr;lgE640≦0.6 and 1.Type: GrantFiled: July 19, 2001Date of Patent: May 13, 2003Assignee: Agfa-GevaertInventors: Klaus Wagner, Heinz Schütz, Peter Bell, Lothar Endres, Detlev Kapitza, Thomas Stetzer
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Patent number: 6514677Abstract: Photothermographic materials comprise heat-bleachable antihalation compositions in antihalation layers. These compositions comprise a hexaarybiimidazole and one or more infrared radiation absorbing compounds that are represented by the following Structure I: A1—L1—A2 I wherein A1 represents a group derived from a dye base, a heterocyclic group, or an electron-donating aromatic group, A2 represents a group derived from a dye base, a heterocyclic group, a group derived from a dye acid, or an electron-donating aromatic group, and L1 represents a conjugated linking group that maintains electron delocalization between A1 and A2 to provide infrared absorbance. The antihalation composition is typically bleached when subjected to a temperature of at least 90° C. for at least 0.5 seconds.Type: GrantFiled: August 31, 2001Date of Patent: February 4, 2003Assignee: Eastman Kodak CompanyInventors: William D. Ramsden, David G. Baird
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Patent number: 6509144Abstract: This invention comprises a photographic element comprising a support and at least one blue sensitive silver halide emulsion layer containing a tabular grain silver halide emulsion, or an emulsion in which the halide content is at least 50% chloride and no more than 5% iodide, wherein the emulsion is spectrally sensitized with at least one dye providing a peak sensitization between 446 and 500 nm and at least one dye providing a peak sensitization between 400 and 445 nm and additionally sensitized with a fragmentable electron donor of the formula: X—Y′. or an electron donor which contains an —XY′ moiety; wherein X is an electron donor moiety, Y′ is a leaving proton H or a leaving group Y, with the proviso that if Y′ is H a base, &bgr;−, is covalently linked directly or indirectly to X. and wherein: 1) X—Y′ has an oxidation potential between 0 and about 1.Type: GrantFiled: January 25, 1999Date of Patent: January 21, 2003Assignee: Eastman Kodak CompanyInventors: Kenneth J. Reed, Joseph P. Pepe, James A. Friday, Jon N. Eikenberry, Yun C. Chang, Annabel A. Muenter, Jerome R. Lenhard
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Patent number: 6479220Abstract: A method of imaging comprising: providing a photothermographic material having at least one photothermographic medium and exposing said material to a source of narrow band radiation, wherein said material comprises one or more non-sensitizing acutance or antihalation dyes associated with said photothermographic medium providing an absorption maximum (&lgr;max) within 10 nm of the wavelength of maximum output of said narrow band source and an optical density of at least 0.05 at a wavelength (&lgr;max+50) nm.Type: GrantFiled: October 25, 1995Date of Patent: November 12, 2002Assignee: Eastman Kodak CompanyInventors: Michael L. Parkinson, Duncan McL A. Grieve
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Patent number: 6403276Abstract: A film material has been provided with emulsions comprising {111} tabular silver halide grains rich in silver bromide, spectrally sensitive to irradiation in the wavelength range shorter than 420 nm by the presence of at least one blue spectral sensitizer and of at least one azacyanine dye, the formula of which has been given in the description and in the claims. A radiographic screen/film combination or system has also been provided comprising a duplitized film sandwiched between a pair of supporting or self-supporting X-ray intensifying screens, characterized in that i) said pair of supported or self-supporting X-ray intensifying screens essentially consists of luminescent phosphor particles emitting at least 50% and more preferably at least 80% of their emitted radiation in the wavelength range shorter than 420 nm, ii) said film corresponds with the film material disclosed hereinbefore.Type: GrantFiled: April 7, 2000Date of Patent: June 11, 2002Assignee: Agfa-GevaertInventors: Kathy Elst, Paul Callant, Ann Verbeeck
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Publication number: 20020061483Abstract: A black and white graphic arts film comprising a support having thereon at least one emulsion layer, said emulsion layer comprising:Type: ApplicationFiled: August 10, 2001Publication date: May 23, 2002Applicant: Eastman Kodak CompanyInventor: Julie Baker
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Patent number: 6361932Abstract: This invention comprises a silver halide photographic material comprising at least one silver halide emulsion comprising silver halide grains having associated therewith at least two dye layers comprising (a) an inner dye layer adjacent to the silver halide grain and comprising at least one dye, Dye 1, that is capable of spectrally sensitizing silver halide and (b) an outer dye layer adjacent to the inner dye layer and comprising at least one dye, Dye 2, wherein Dye 2 is other than a cyanine dye, wherein the dye layers are held together by non-covalent forces; the outer dye layer adsorbs light at equal or higher energy than the inner dye layer; and the energy emission wavelength of the outer dye layer overlaps with the energy absorption wavelength of the inner dye layer.Type: GrantFiled: September 11, 1998Date of Patent: March 26, 2002Assignee: Eastman Kodak CompanyInventors: Richard L. Parton, Thomas L. Penner, William J. Harrison, Margaret J. Helber
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Patent number: 6348307Abstract: An object of the present invention is to provide a silver halide photographic light-sensitive material which exhibits a high sensitivity and less residual color.Type: GrantFiled: July 25, 2000Date of Patent: February 19, 2002Assignee: Fuji Photo Film Co., Ltd.Inventor: Takanori Hioki
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Patent number: 6338941Abstract: A silver halide light sensitive photographic material is disclosed, comprising a support and at least one hydrophilic colloid layer including a silver halide emulsion layer, wherein the hydrophilic colloid layer comprises a compound represented by the following formula. An image forming method by use thereof is also disclosed.Type: GrantFiled: July 6, 2000Date of Patent: January 15, 2002Assignee: Konica CorporationInventors: Toshiyuki Takabayashi, Takeo Arai
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Patent number: 6333146Abstract: Disclosed is a compound represented by the following formula (I): wherein Z1 represents an atomic group necessary to form a 5- or 6-membered nitrogen-containing heterocyclic ring; Z2 represents an atomic group necessary to form a 5- or 6-membered heterocyclic ring, Z2 may further be substituted, or may be condensed with a hetero ring or a benzene ring; R1 represents a hydrogen atom, a halogen atom, a mercapto group, an alkyl group, an alkenyl group, an aryl group, an alkylthio group, an alkenylthio group, or an arylthio group; L1 and L2 each represents a methine group; p1 represents 0 or 1; V1 represents a substituent; and n represents 0, 1 or 2, and when n represents 2, a plurality of V1 may be the same or different.Type: GrantFiled: March 10, 2000Date of Patent: December 25, 2001Assignee: Fuji Photo Film Co., Ltd.Inventors: Katsumi Kobayashi, Takashi Katoh, Junji Nishigaki
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Patent number: 6331385Abstract: This invention comprises a silver halide photographic material comprising at least one silver halide emulsion comprising tabular silver halide grains having associated therewith at least two dye layers comprising (a) an inner dye layer adjacent to the silver halide grain and comprising at least one dye that is capable of spectrally sensitizing silver halide and (b) an outer dye layer adjacent to the inner dye layer and comprising at least one dye, wherein the dye layers are held together by non-covalent forces or by in situ bond formation; the outer dye layer adsorbs light at equal or higher energy than the inner dye layer; and the energy emission wavelength of the outer dye layer overlaps with the energy absorption wavelength of the inner dye layer.Type: GrantFiled: September 11, 1998Date of Patent: December 18, 2001Assignee: Eastman Kodak CompanyInventors: Joseph C. Deaton, Richard L. Parton, Thomas L. Penner, William J. Harrison, David E. Fenton
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Patent number: 6329133Abstract: This invention comprises a silver halide photographic material comprising at least one silver halide emulsion comprising silver halide grains having associated therewith a combination of two or more dyes wherein (b) (a) a dye having at least one substituent that has a negative charge is present, a dye having at least one substituent that has a positive charge is present, wherein at least one of the dyes is further substituted with at least one hydrogen bonding donor substituent. In a preferred embodiment, at least one of the dyes is substituted with at least two hydrogen bonding donor substituents. In another preferred embodiment a silver halide photographic material comprises at least one silver halide emulsion comprising silver halide grains having associated therewith a dye substituted with at least one guanidinium, amidinium, or imine of urea substituent.Type: GrantFiled: September 13, 1999Date of Patent: December 11, 2001Assignee: Eastman Kodak CompanyInventors: Andrei Andrievsky, Richard L. Parton, Thomas L. Penner, William J. Harrison
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Patent number: 6329135Abstract: A silver halide photothermographic material is disclosed, comprising a support having thereon a light-sensitive layer and light-insensitive layer, wherein the light-sensitive layer or the light-insensitive layer comprises a heteroatom-containing macrocyclic compound, and the light-sensitive layer comprising a sensitizing dye exhibiting maximum sensitivity at a wavelength of 600 nm or more.Type: GrantFiled: June 2, 2000Date of Patent: December 11, 2001Assignee: Konica CorporationInventor: Hiroshi Kashiwagi
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Patent number: 6312883Abstract: A silver halide photographic material comprises at least one silver halide emulsion comprising silver halide grains having associated therewith at least two dyes: (a) a first dye that has at least one anionic substituent and that is capable of spectrally sensitizing a silver halide emulsion; and (b) a second dye of formula II wherein: R1 is a substituted or unsubstituted alkyl or aryl group; E3 represents the atoms necessary to complete a substituted or unsubstituted 5- or 6-membered heterocyclic nucleus; Ar1 represents an electron-withdrawing substituted aryl, or a substituted or unsubstituted electron-withdrawing heteroaryl group; L11 through L14 are substituted or unsubstituted methine groups; s is 0 or 1; G1 is an electron-withdrawing group; G2 is O or dicyanovinyl (C(CN)2); W1 is a counterion if necessary.Type: GrantFiled: June 22, 2000Date of Patent: November 6, 2001Assignee: Eastman Kodak CompanyInventors: Richard L. Parton, Thomas L. Penner, Stephen A. Hershey
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Patent number: 6306570Abstract: A photographic element comprising at least one silver halide emulsion layer in which the silver halide is sensitized with a compound of the formula: wherein A is a silver halide adsorptive group that contains at least one atom of N, S, Se, or Te that promotes adsorption to silver halide, and Z is a light absorbing group including for example cyanine dyes, complex cyanine dyes, merocyanine dyes, complex merocyanine dyes, homopolar cyanine dyes, styryl dyes, oxonol dyes, hemioxonol dyes, and hemicyanine dyes, and XY is an fragmentable electron donor moiety in which X is an electron donor group and Y is a leaving group other than hydrogen, and wherein: 1) XY has an oxidation potential between 0 and about 1.4 V; and 2) the oxidized form of XY undergoes a bond cleavage reaction to give the radical X• and the leaving fragment Y. In a preferred embodiment of the invention, the radical X• has an oxidation potential ≦−0.7 V.Type: GrantFiled: March 27, 2000Date of Patent: October 23, 2001Assignee: Eastman Kodak CompanyInventors: Anthony Adin, Jerome J. Looker, Samir Y. Farid, Ian R. Gould, Stephen A. Godleski, Jerome R. Lenhard, Annabel A. Muenter, Lal C. Vishwakarma, Paul A. Zielinski
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Patent number: 6300051Abstract: A method has been disclosed for preparing a tabular silver halide emulsion wherein tabular silver halide grains having an average aspect ratio of at least 2:1, an average crystal diameter from 0.3 &mgr;m to 3.0 &mgr;m and an average thickness of less than 0.50 &mgr;m account for at least 50% of the total projective surface area of said grains, said method comprising the steps of precipitating, spectrally sensitizing and chemically ripening said grains, characterized by spectrally sensitizing by adding to the emulsion grains before chemically ripening at least one J-band aggregating spectrally sensitizing dye and at least one non-J-band aggregating dye.Type: GrantFiled: March 18, 1999Date of Patent: October 9, 2001Assignee: Agfa-GevaertInventors: Marc Van den Zegel, Kathy Elst
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Patent number: 6245499Abstract: In a photothermographic material comprising an organic silver salt, a silver halide, and a reducing agent, a hydrazine compound of a special structure and a sensitizing dye of a special structure are contained. The photothermographic material shows high Dmax and ultrahigh contrast.Type: GrantFiled: August 21, 1998Date of Patent: June 12, 2001Assignee: Fuji Photo Film Co., Ltd.Inventors: Keiichi Suzuki, Toshiaki Kubo, Yoshio Inagaki, Tsutomu Arai
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Patent number: 6187525Abstract: A photographic recording element is disclosed containing in at least one dye image forming layer unit (a) a radiation-sensitive silver halide grains include tabular grains (1) having {111} major faces, (2) containing greater than 50 mole percent bromide, based on silver, and (3) accounting for greater than 50 percent total grain projected area, (b) a fragmentable electron donating sensitizer, (c) a water dispersible cationic starch peptizer, and (d) a one equivalent dye image providing coupler. Increased photographic speed is realized.Type: GrantFiled: December 17, 1998Date of Patent: February 13, 2001Assignee: Eastman Kodak CompanyInventors: Joe E. Maskasky, Kenneth J. Reed, Victor P. Scaccia, James A. Friday
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Patent number: 6153371Abstract: This invention comprises a photographic element comprising a support and at least one silver halide emulsion layer in which the silver halide is sensitized with a compound of the formula:Q-XYwherein Q represents the atoms necessary to form a chromophore comprising an amidinium-ion, a carboxyl-ion or dipolar-amidic chromophoric system when conjugated with XY, and XY is a fragmentable electron donor moiety in which X is an electron donor group and Y is a leaving group other than hydrogen, and wherein:1) XY has an oxidation potential between 0 and about 1.4 V;2) the oxidized form of XY undergoes a bond cleavage reaction to give the radical X.sup..cndot. and the leaving fragment Y.In a preferred embodiment of the invention, the radical X.cndot. has an oxidation potential <-0.7V.Type: GrantFiled: July 17, 1998Date of Patent: November 28, 2000Assignee: Eastman Kodak CompanyInventors: Samir Y. Farid, Ian R. Gould, Stephen A. Godleski, Jerome R. Lenhard, Annabel A. Muenter, Paul A. Zielinski
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Patent number: 6124085Abstract: A silver halide photographic light-sensitive material is disclosed, comprising at least one compound represented by the following formula (I): ##STR1## wherein A represents a divalent linking group containing at least one atom other than a carbon atom, Z.sub.1 represents an atomic group necessary for forming a 5- or 6-membered nitrogen-containing heterocyclic ring, provided that the ring may further be condensed with an aromatic ring, L.sub.1 and L.sub.2 each represents a methine group, p.sub.1 represents 0 or 1, M.sub.1 represents a charge balancing counter ion, m.sub.1 represents a number of from 0 to 10 necessary for neutralizing the charge of the molecule, and Q represents a group necessary for forming a methine dye.Type: GrantFiled: January 14, 1999Date of Patent: September 26, 2000Assignee: Fuji Photo Film Co., Ltd.Inventor: Takanori Hioki
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Patent number: 6010842Abstract: A silver halide photographic light-sensitive material has at least one light-sensitive silver halide emulsion layer on a support, wherein a light-sensitive silver halide emulsion in the emulsion layer contains a compound represented by formula (I) below and a compound represented by formula (II) below. ##STR1## In formula (I), each of R.sub.1 to R.sub.3 represents a hydrogen atom, an alkyl group, or an aryl group. ##STR2## In formula (II), R represents a specific alkyl group, each of L.sub.1 and L.sub.2 represents a methine group, p.sub.1 represents 0 or 1, Z.sub.1 represents atoms required to form a 5- or 6-membered nitrogen-containing heterocyclic ring, M.sub.1 represents a charge-balancing counter ion, m.sub.1 represents a number from 0 to 10 required to neutralize electric charge of a molecule, and Q represents a methine group or a polymethine group substituted by a heterocyclic group or an aromatic group.Type: GrantFiled: August 29, 1997Date of Patent: January 4, 2000Assignee: Fuji Photo Film Co., Ltd.Inventors: Yoichi Suga, Masato Taniguchi
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Patent number: 5989795Abstract: This invention relates to a photographic recording material comprising a support and a photosensitive chemically sensitized silver halide emulsion layer, containing a sensitizing dye selected from the group consisting of oxonal dyes, merocyanine dyes, and cyanine dyes having a net negative charge, and which has a pH value between about 2 to about 5 and a pAg value between about 1 to about 4.7.Type: GrantFiled: May 21, 1992Date of Patent: November 23, 1999Assignee: Eastman Kodak CompanyInventors: Francis John Evans, Arthur Herman Herz
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Patent number: 5965346Abstract: A photothermographic material is disclosed, comprising a support having on at least one surface thereof a light-sensitive silver halide grain, an organic salt, a reducing agent for silver ion and a binder, wherein the heat-developable light-sensitive material contains a methine dye represented by formula (I).Type: GrantFiled: July 31, 1997Date of Patent: October 12, 1999Assignee: Fuji Photo Film Co., Ltd.Inventors: Yoshio Inagaki, Naoyuki Hanaki, Hirohiko Tsuzuki
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Patent number: 5965345Abstract: A method of sensitizing a silver halide emulsion comprises the steps of:a) forming a co-dispersion of a first sensitizing dye and a second sensitizing dye in an aqueous medium, wherein the peak absorptance of the second dye is at least 10 nm different from the peak absorptance of the first dye, and wherein the ratio of the first dye to the second dye is from about 0.1 to 20; andb) incorporating the resulting co-dispersion in a silver halide emulsion.Type: GrantFiled: December 12, 1995Date of Patent: October 12, 1999Assignee: Eastman Kodak CompanyInventors: Steven George Link, John William Boettcher, Frederick Charles Derks, Heidi Melissa Viterise