Direct Positive Patents (Class 430/589)
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Patent number: 7052827Abstract: A silver halide photographic material including at least one methine dye represented by the following general formula (I) and at least one coupler represented by the following general formula (XX): wherein X1 and X2 each represents an oxygen atom, a sulfur atom, a selenium atom, a tellurium atom, or a nitrogen atom; Y1 represents a furan, pyrrole or thiophene ring which may be condensed with another 5- or 6-membered carbon ring or heterocycle or may have a substituent group; Y2 represents an atomic group necessary for forming a benzene ring or a 5- or 6-membered unsaturated heterocycle, which may be further condensed with another 5- or 6-membered carbon ring or heterocycle or may have a substituent group; a bond between two carbon atoms by which Y1 and Y2 are each condensed with the carbon ring or the heterocycle may be a single bond or a double bond; R1 and R2 each represents a substituted or unsubstituted alkyl, aryl or heterocyclic group; L1, L2 and L3 each represents a methine group; n1 represents 0 oType: GrantFiled: August 27, 2004Date of Patent: May 30, 2006Assignee: Fuji Photo Film Co., Ltd.Inventor: Tetsuo Nakamura
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Patent number: 6828087Abstract: A silver halide photographic material comprising at least one methine dye of formula (I) and at least one coupler of formula (X): wherein X1 and X2 each represents O, S, Se, Te, N or C; Y1 represents a furan, pyrrole or thiophene ring which may be condensed and substituted with the specific ring; Y2 represents an atomic group necessary for forming a benzene ring or a 5- or 6-membered unsaturated heterocycle; R1 and R2 each represents a substituted or unsubstituted alkyl, aryl or heterocyclic group; L1, L2 and L3 each represents a methine group; n1 represents 0 or 1; M1 represents a counter ion; and m1 represents a number of 0 or more necessary for neutralizing a charge in a molecule; wherein Z1 and Z2 each represents —C(Q3)═ or —N═; Q1 and Q3 each represents a hydrogen atom or a monovalent substituent group; Q2 represents a hydrogen atom or a coupling release group.Type: GrantFiled: September 23, 2002Date of Patent: December 7, 2004Assignee: Fuji Photo Film Co., Ltd.Inventor: Tetsuo Nakamura
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Patent number: 6770433Abstract: A high-sensitive silver halide photographic light-sensitive material is provided. A silver halide photographic light-sensitive material comprising a dye having a plurality of dye chromophores, which contains at least one dye where at least one of the dye chromophores is a methine dye chromophore containing a basic nucleus comprising a monocyclic heterocyclic ring.Type: GrantFiled: January 11, 2002Date of Patent: August 3, 2004Assignee: Fuji Photo Film Co., Ltd.Inventor: Takanori Hioki
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Patent number: 6582894Abstract: A silver halide photographic emulsion is disclosed, comprising a silver halide grain having a spectral absorption maximum wavelength of less than 500 nm and a light absorption intensity of 60 or more or having a spectral absorption maximum wavelength of 500 nm or more and a light absorption intensity of 100 or more, wherein assuming that a maximum value of the spectral absorption factor of said emulsion by a sensitizing dye is Amax, the distance between the shortest wavelength showing 80% of Amax and the longest wavelength showing 80% of Amax is 20 nm or more and the distance between the shortest wavelength showing 50% of Amax and the longest wavelength showing 50% of Amax is 120 nm or less.Type: GrantFiled: March 10, 2000Date of Patent: June 24, 2003Assignee: Fuji Photo Film Co., Ltd.Inventors: Takanori Hioki, Katsuhiro Yamashita, Katsumi Kobayashi, Takashi Katoh
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Patent number: 6566044Abstract: The present invention provides a silver halide photographic material that is excellent in photographic speed as well as image graininess and exhibits low residual color even after rapid processing. The silver halide photographic material contains a compound represented by formula (I) and a compound represented by formula (II), as defined.Type: GrantFiled: March 26, 2001Date of Patent: May 20, 2003Assignee: Fuji Photo Film Co., Ltd.Inventors: Katsuhisa Ohzeki, Tetsuo Nakamura, Takanori Hioki
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Patent number: 6329132Abstract: In a method of preparing a silver halide photographic emulsion by performing spectral sensitization by adding a cyanine dye during or before chemical sensitization, a substantially insoluble silver iodobromide fine-grain emulsion is added during or after chemical sensitization of the silver halide photographic emulsion.Type: GrantFiled: December 12, 1995Date of Patent: December 11, 2001Assignee: Fuji Photo Film Co., Ltd.Inventor: Mikio Ihama
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Patent number: 5534402Abstract: A direct-positive silver halide photographic material is disclosed, which comprises a support having thereon at least one prefogged light-sensitive silver halide emulsion layer, wherein said silver halide emulsion is an emulsion which has been previously fogged with a gold compound and a tellurium compound.Type: GrantFiled: December 13, 1994Date of Patent: July 9, 1996Assignee: Fuji Photo Film Co., Ltd.Inventors: Koichi Kuno, Hiroyuki Mifune
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Patent number: 5523197Abstract: In order to provide a direct-positive material having low contrast and extended latitude that can be manufactured in a consistent and reproducable way a multilayer direct-positive photographic material is disclosed as well as the process to provide it, characterized by the steps of coating on one side of a support at least two layers of direct positive silver halide emulsions of the externally fogged type, at least one layer of which comprises a mixture of direct positive silver halide emulsions of the externally fogged type and at least one layer of which comprises one or more filter dyes; overcoating said emulsion layers with at least one protective layer; coating on the other side of the support at least one backing layer.Type: GrantFiled: April 12, 1995Date of Patent: June 4, 1996Assignee: Agfa-Gevaert, N.V.Inventor: Luc Heremans
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Patent number: 5472839Abstract: A photographic recording material having a photosensitive silver halide emulsion layer which is spectrally sensitized with a sensitizing dye of one of the formulae I and II ##STR1## in which R.sup.1, R.sup.2 denote sulfoalkyl;R.sup.3 denotes alkyl;R.sup.4 denotes H, F, Cl, --CN, alkoxycarbonyl, carbamoyl;R.sup.5 denotes Cl, --CN;M.sup..sym. denotes a counter ion (cation) which is optionally necessary to balance the charge exhibits a high degree of sensitivity which is stable under warm, humid conditions.Type: GrantFiled: June 22, 1994Date of Patent: December 5, 1995Assignee: Agfa-Gevaert AGInventor: Michael Missfeldt
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Patent number: 5449595Abstract: The present invention relates to a method for making direct-positive photographic images by developing light-sensitive materials in the presence of development nucleators which do not cause loss of sensitivity during exposure or unevenness of development. More specifically the invention relates to the formation of direct-positive images having a high maximum density and high exposure latitude and to photographic materials for use in said formation, which is accomplished by a method for making direct-positive images comprising:image-wise exposing a photographic light-sensitive silver halide material comprising a support and a layer of an internal latent image-type silver halide emulsion, the pAg of which has been adjusted to a pAg-value between 9.0 and 10.5 inclusive before coating, anddeveloping said exposed photographic silver halide material in a surface developer in the presence of a development nucleator with a group promoting adsorption to silver halide.Type: GrantFiled: June 29, 1994Date of Patent: September 12, 1995Assignee: Agfa-Gevaert, N.V.Inventors: Jean-Marie Dewanckele, David Terrell, Kris Viaene
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Patent number: 5336590Abstract: A silver halide color photographic photosensitive material is disclosed which comprises a transparent support on which there are provided at least one cyan color forming coupler containing layer, at least one magenta color forming coupler containing layer, and at least one yellow color forming coupler containing layer, and at least one light-insensitive layer, wherein a compound represented by formula (I), a compound represented by formula (IIa) or (IIb) or both, and an internal latent image forming silver halide grain are contained in the photographic material: ##STR1## wherein Z.sup.11 represents a group of non-metal atoms which is required to form a five or six membered heterocyclic ring, and Z.sup.11 may be substituted with substituent groups; R.sup.11 is an aliphatic group; and R.sup.12 is a hydrogen atom, an aliphatic group or an aromatic group; R.sup.11 and R.sup.12 may be substituted with substituent groups; R.sup.12 may be joined to the heterocyclic ring completed by Z.sup.Type: GrantFiled: September 28, 1992Date of Patent: August 9, 1994Assignee: Fuji Photo Film Co., Ltd.Inventor: Akio Mitsui
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Patent number: 5266448Abstract: A method for color reversal processing of an imagewise exposed silver halide color photographic material comprising first developing in a black-and-white developing bath, next color developing in a color developing bath, and then desilvering in a bath having a bleaching ability. The black-and-white developing bath has a bromide concentration in the range of 0.025 to 0.1 mol/l and is used for the black-and-white development. Furthermore, in a preferred embodiment, the photographic material comprises at least one silver halide emulsion layer containing a silver halide emulsion comprising silver halide grains having an average grain size of 0.3 .mu.m or less. In accordance with the invention, the maximum densities of the developed color images are increased without lowering of the sensitivity and contrast.Type: GrantFiled: March 27, 1992Date of Patent: November 30, 1993Assignee: Fuji Photo Film Co., Ltd.Inventors: Sadanobu Shuto, Takatoshi Ishikawa
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Patent number: 5032500Abstract: A process or the preparation of a silver halide photographic emulsion is provided which comprises the addition of at least one pendant type spectral sensitizing dye containing as a substituent a compound having the effect of inhibiting fog at any time after the formation of silver halide grains, but before the completion of the chemical ripening process. In a preferred embodiment, the addition of said pendant type spectral sensitizing dyes is effected at any time after the formation of silver halide grains, but before former one second of the total time of the chemical ripening process. The pendant type spectral sensitizing dyes are compounds represented by the general formula (III) or (IV): ##STR1## wherein SSD represents a sensitizing dye portion; AF represents a compound portion containing a saturated or unsaturated 5- to 7-membered ring containing at least one nitrogen atom; L.sup.1 represents a divalent connecting group containing at least one of C, N, S and O; L.sup.2 has the same meaning at L.sup.Type: GrantFiled: January 14, 1990Date of Patent: July 16, 1991Assignee: Fuji Photo Film Co., Ltd.Inventors: Tadashi Ikeda, Mitsuo Saitou, Yoshio Inagaki, Toshinao Ukai
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Patent number: 4857445Abstract: A direct positive photo-sensitive material is described, wherein the material comprises at least one internal latent image-type silver halide emulsion layer containing core/shell-type silver halide grains consisting of substantially cubic or tetradecahedral grains mainly of the face (100) and being spectrally-sensitized with at least one sensitizing dye having the following formula: ##STR1## wherein R.sup.1 and R.sup.2 represent each a lower alkyl group substituted with a sulfonato, carboxyl or hydroxyl group, at least one of R.sup.1 and R.sup.2 being a sulfonatoalkyl group, R.sup.3 represents a hydrogen atom or a lower alkyl or substituted or unsubstituted phenethyl group, R.sup.4 represents a chlorine atom, a methoxy or ethoxy group or a hydrogen atom, R.sup.5 represents a chlorine atom or a phenyl, alkoxy or alkyl group, M.sup.+1 represents a cationic residue, m represents 0 or 1 with the proviso that when an inner salt is formed, m is 0.Type: GrantFiled: February 19, 1987Date of Patent: August 15, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Tetsuo Yoshida, Tatsuo Heki
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Patent number: 4830958Abstract: A photographic material having an excellent rapid processability, a high sensitivity and a less sensitivity variation due to a change of standing of the silver halide emulsion in the course of preparation of the light-sensitive material, and its preparation process are disclosed. The silver halide photographic light-sensitive material comprises a support bearing at least one silver halide emulsion layer thereon, and at least one silver halide emulsion layer contains highly chloride-containing silver halide grains having a silver chloride content of not less than 90 mol %, a water-soluble bromide of from 0.05 mol % to 2 mol % per mol of silver halide and a high boiling organic solvent having a dielectric constant of not higher than 6.0.Type: GrantFiled: January 25, 1988Date of Patent: May 16, 1989Assignee: Konica CorporationInventors: Mitsuhiro Okumura, Keiji Ohbayashi, Shigeo Tanaka
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Patent number: 4801523Abstract: Process for preparing photographic emulsion comprising bringing aqueous silver and chloride-containing halide salt solutions into contact in the presence of a dispersing medium to form octahedral silver halide grains having a halide content of at least 50 mole percent chloride, based on total moles of silver present, the improvement forming the grains in the presence of a crystal modifying amount of an aminoazapyridine as described in pH range of 2.5 to 9, pCl range of 0 to 3, the aminoazapyridine compound being added after at least about 6% to about 45% of the silver salt solution has been added.The photographic emulsion is useful in x-ray, laser scanner films, as color separation elements and inverse transfer systems, etc.Type: GrantFiled: August 28, 1987Date of Patent: January 31, 1989Assignee: E. I. Du Pont de Nemours and CompanyInventor: Thomas P. Tufano
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Patent number: 4800154Abstract: A silver halide photographic emulsion comprising at least one spectral sensitizing dye having the following general formula (I):Dye--J.sup.1 --CONH--J.sup.2 --NHNHG--R (I)wherein Dye represents a dye residue capable of becoming a spectral sensitizing dye; J.sup.1 represents a substituted or unsubstituted alkylene group, a substituted or unsubstituted arylene group, a substituted or unsubstituted aralkylene group, or a substituted or unsubstituted alkarylene group; J.sup.2 represents a substituted or unsubstituted arylene group; R represents hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted alkoxy group, or a substituted or unsubstituted aryloxy group; and G represents a carbonyl group, a sulfonyl group, a sulfoxy group, a phosphoryl group, or a substituted or unsubstituted iminomethylene group.Type: GrantFiled: October 16, 1986Date of Patent: January 24, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Masaki Okazaki, Haruo Takei
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Patent number: 4792518Abstract: A silver halide color reversal reflection print photosensitive material comprises at least one blue-sensitive layer, at least one green-sensitive layer and at least one red-sensitive layer on a support. In the characteristic curves of the color sensitive layers, a fluctuation width of point-gammas and absolute values of point-gammas are defined. The distribution of the grain size of the silver halide grains in silver halide emulsions contained in the color sensitive layer can be controlled by forming the grains in the presence of a silver halide solvent.Type: GrantFiled: April 22, 1988Date of Patent: December 20, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Shigeru Kuwashima, Akio Mitsui, Masaru Sano
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Patent number: 4769316Abstract: A restraining method for restraining the formation of a re-reversal negative image is described, comprising incorporating a cyanine dye or a merocyanine dye which is electron donative and is adsorbable on silver halide in at least one hydrophilic colloid layer of an internal latent image type direct positive silver halide photographic material as a re-reversal restrainer.Type: GrantFiled: June 18, 1986Date of Patent: September 6, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Tsutomu Miyasaki, Shigeo Hirano, Kiyoshi Morimoto
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Patent number: 4576905Abstract: Compounds containing an aromatic ring portion fused with a tellurazolium or derivative tellurazole, tellurazoline (including tellurazolinylidene), or tellurazolinium ring portion are disclosed together with processes and intermediates for their preparation. With properly selected pendant groups these tellurazolium and derivative compounds can be usefully employed as dyes, antifoggants or stabilizers, nucleating agents, latent image keeping addenda, or speed or contrast altering addenda in silver halide photographic systems.Type: GrantFiled: October 12, 1984Date of Patent: March 18, 1986Assignee: Eastman Kodak CompanyInventors: Wolfgang H. H. Gunther, Ronald E. Leone, Rosemary Przyklek
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Patent number: 4571380Abstract: An inner latent image type silver halide photographic emulsion which is spectrally sensitized by adding at least one cyanine dye represented by general formula (II) to a direct positive inner latent image type silver halide photographic emulsion and thereafter adding additionally at least one cyanine dye represented by general formula (I) to said emulsion ##STR1## (the symbols are as defined in the appended claims). A remarkable increase of spectral sensitivity, an increase of maximum density and a decrease of minimum density can be obtained by this silver halide photographic emulsion.Type: GrantFiled: October 27, 1983Date of Patent: February 18, 1986Assignee: Fuji Photo Film Co., Ltd.Inventors: Yasuhiro Noguchi, Yuji Mihara
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Patent number: 4555481Abstract: A silver halide photographic emulsion is disclosed which contains at least one of benzimidazolocarbocyanine dyes represented by the general formula (I) or (II): ##STR1## wherein a represents an integer of 1 to 8, R.sub.1, R.sub.2 and which may be identical with or different from one another, represent each --CH.sub.2 (CF.sub.2).sub.b H or a substituted or unsubstituted alkyl group, but at least one of R.sub.1, R.sub.2 and R.sub.3 contains an acid group-containing alkyl group, wherein b, which may be identical with or different from a, represents an integer of 1 to 8, l represents 0 or an integer of 1 to 8, and m represents 0 or an integer of 1 to 8, but l+m>0; R.sub.4, R.sub.5 and R.sub.6, which may be identical or different from one another, represent each --(CH.sub.2).sub.j (CF.sub.2).sub.k F or a substituted or unsubstituted alkyl group, but at least one of R.sub.4, R.sub.5 and R.sub.6 represents an acid group (for example, sulfo group or carboxyl group, etc.Type: GrantFiled: January 25, 1984Date of Patent: November 26, 1985Assignee: Fuji Photo Film Co., Ltd.Inventors: Toshinao Ukai, Masaki Okazaki, Haruo Takei, Ichizo Toya
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Patent number: 4504570Abstract: High aspect ratio tabular grain direct reversal silver halide emulsions are disclosed. The emulsions can be incorporated in photographic elements, such as multicolor photographic elements. Image transfer film units incorporating these direct reversal emulsions are specifically disclosed.Type: GrantFiled: December 23, 1983Date of Patent: March 12, 1985Assignee: Eastman Kodak CompanyInventors: Francis J. Evans, Richard L. Daubendiek, Ronald G. Raleigh
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Patent number: 4376817Abstract: Direct-positive photographic material having at least one layer which contains a silver halide emulsion surface-fogged by chemical means or by exposure and a tri-nuclear cyanine dye, which has the formula ##EQU1## in which A.sub.1 is .dbd.CH-- or .dbd.CH--CH.dbd.CH--, Z.sub.1 is a monocyclic or polycyclic heterocyclic radical which is linked by a double bond to the adjacent methine group, Z.sup..sym. is a positively charged radical which is mesomeric to Z.sub.1 and is linked by a single bond to the adjacent methine group, Z.sub.2 --is a nitrogen-heterocyclic radical which has its single positive charge on the nitrogen atom and Z.sub.3 .dbd. is a radical which has no charge on the nitrogen atom and is mesomeric to Z.sub.2, at least one of the radicals Z.sub.Type: GrantFiled: July 27, 1981Date of Patent: March 15, 1983Assignee: Ciba-Geigy AGInventors: Rolf Steiger, Jean F. Reber
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Patent number: 4355098Abstract: Direct positive photographic elements with improved spectral sensitivity in the green and red portion of the visible spectrum are obtained from emulsions containing a supersensitizing amount of a spectral sensitizing dye (a) having a solution absorption maximum less than 495 nm and the lowest vacant energy band less than -3.7 eV, and a sensitizing amount of a spectral sensitizing dye (b) having a lowest vacant energy band between -3.7 eV and 0.3 eV below the lowest vacant energy band of said spectral sensitizing dye (a) and with the highest occupied energy band between -5.9 eV and 0.3 eV above the highest occupied energy level of dye (a).Type: GrantFiled: February 11, 1981Date of Patent: October 19, 1982Assignee: E. I. Du Pont de Nemours and CompanyInventor: James W. Wheeler
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Patent number: 4306016Abstract: Silver halide emulsions are disclosed containing silver halide grains capable of forming an internal latent image. Incorporated in the emulsions as a nucleating agent is a heterocyclic compound having an arylaminovinylene or aryloxyvinylene substituent, thereby permitting a direct-positive image to be formed on imagewise exposure and photographic processing.Type: GrantFiled: November 17, 1980Date of Patent: December 15, 1981Assignee: Eastman Kodak CompanyInventors: Roger M. Baralle, Marcel A. Compere, Maurice E. Pfaff, Frederic X. Jordi, Claude G. Goumont
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Patent number: 4306017Abstract: Silver halide emulsions are disclosed containing silver halide grains capable of forming an internal latent image. Incorporated in the emulsions as a nucleating agent is a dihydrospiropyran bis-condensation product of salicylic aldehyde and at least one heterocyclic ammonium salt, thereby permitting a direct-positive image to be formed on imagewise exposure and photographic processing.Type: GrantFiled: November 17, 1980Date of Patent: December 15, 1981Assignee: Eastman Kodak CompanyInventors: Roger M. Baralle, Marcel A. Compere, Maurice E. Pfaff, Frederic X. Jordi, Claude G. Goumont
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Patent number: 4294919Abstract: A direct positive silver halide photographic light-sensitive material is described, comprising a support having coated thereon a light-sensitive silver halide photographic emulsion layer and a hydrophilic colloid layer, at least one of said layers containing a compound represented by the formula (I): ##STR1## wherein R.sup.1 represents R.sup.6 or R.sup.6 CO--; and R.sup.6 represents an aliphatic group, an aromatic group, a heterocyclic aromatic group or hydrogen; R.sup.2 and R.sup.4, which may be the same or different, each represents an aliphatic group, an aromatic group, a heterocyclic aromatic group or a hydrogen atom; or R.sup.1 and R.sup.2 together can form a ring; R.sup.3 represents hydrogen or an aliphatic group; R.sup.5 represents Y or X--A--Y wherein X and Y, which may be the same or different, each represents a divalent aromatic group; and A represents a divalent group selected from --CONH--, --NHCONH--, --SO.sub.2 NH--, --B--CONH-- and --B--SO.sub.Type: GrantFiled: June 6, 1980Date of Patent: October 13, 1981Assignee: Fuji Photo Film Co., Ltd.Inventors: Nobuyuki Tsujino, Shigeo Hirano
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Patent number: 4273862Abstract: Direct-positive silver halide photographic sensitive materials of high sensitivity and capable of forming a high-contrast image are obtained by incorporating anion-type cyanine dyes having a polarographic oxidation halfwave potential not less positive than +0.4 V in externally fogged direct-positive silver halide emulsions containing not less than 70 mole-% of bromide. Additional incorporation of a development accelerator such as 2-mercaptoimidazoline improves developability.Type: GrantFiled: September 24, 1979Date of Patent: June 16, 1981Assignee: Mitsubishi Paper Mills, Ltd.Inventors: Akio Yoshida, Seigo Ebato
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Patent number: 4245037Abstract: A direct positive light-sensitive silver halide photographic material comprising a support having thereon a layer containing a compound represented by the formula (I): ##STR1## wherein R.sub.1 represents an aliphatic residue or an aromatic residue; R.sub.2 represents a hydrogen atom, an aliphatic residue, or an aromatic residue; X.sub.1 and X.sub.2, which may be the same or different, each represents a divalent aromatic residue; and Y represents ##STR2## or a direct bond wherein the O or S is bonded to X.sub.1 ; R represents a divalent aliphatic residue and R.sub.3 represents an aliphatic residue or an aromatic residue. The compound is particularly effective in combination with a diffusible dye releasing dye image providing compound having an o-hydroxyarylsulfamoyl group.Type: GrantFiled: October 25, 1979Date of Patent: January 13, 1981Assignee: Fuji Photo Film Co., Ltd.Inventors: Nobuyuki Tsujino, Shigeo Hirano, Keiichi Adachi
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Patent number: 4210715Abstract: Light-sensitive silver halide photographic materials to be treated with a hydroquinones-containing developing solution which material comprises a support and at least one hydrophilic colloidal layer coated thereon which contains silver halide grains having an average grain size of 0.05 to 1.5.mu., a tetrazolium compound and a sensitizing dye.Type: GrantFiled: March 2, 1979Date of Patent: July 1, 1980Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Mitsuto Fujiwhara, Syunji Matsuo, Toyoaki Masukawa, Yutaka Kaneko, Mikio Kawasaki