Charge Generator Layer Contains Compound Having An Acyclic Azo Group (i.e., -n=n-) Patents (Class 430/59.2)
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Patent number: 11825740Abstract: An organic light-emitting device and an amine compound, the organic light-emitting device including a first electrode; a second electrode facing the first electrode; and an organic layer between the first electrode and the second electrode and including an emission layer, wherein the organic layer includes at least one amine compound represented by Formula 1:Type: GrantFiled: May 16, 2019Date of Patent: November 21, 2023Assignee: Samsung Display Co., Ltd.Inventors: Sanghyun Han, Dongjun Kim, Youngkook Kim, Jongwoo Kim, Eunjae Jeong
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Patent number: 10532997Abstract: A photochromic compound is provided, which may be a pyran, an oxazine, or a fulgide. The photochromic compound has at least one substituent Q attached thereto, each Q independently being —N3, —CN, —COOR?, —CCR?, —C(R?)C(R?)R?, —OCOR?, —OCOOR?, —SR?, —OSO2R??, and/or CON(R?)R?, wherein each R? is hydrogen, an unsubstituted or substituted alkyl group having from 1 to 18 carbon atoms; an unsubstituted or substituted aryl group, an unsubstituted or substituted alkene or alkyne group having from 2 to 18 carbon atoms, wherein the substituents are halo or hydroxyl and R?? is —CF3 or a perfluorinated alkyl group having from 2 to 18 carbon atoms The number, locations and nature of the constituents Q are dependent upon the structure of the photochromic compound.Type: GrantFiled: June 14, 2018Date of Patent: January 14, 2020Assignee: Transitions Optical, Inc.Inventors: Meng He, Darrin R. Dabideen, Terry A. Kellar, II, Anil Kumar
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Patent number: 8877411Abstract: An electrophotographic photoconductor includes an electrically conductive base and a photosensitive layer disposed on the electrically conductive base. The photosensitive layer has a structure 1) in which a charge-generation layer including at least a charge-generating material and a charge-transport layer including at least a charge-transporting material and a binder resin are stacked in that order, or a structure 2) in which at least the charge-generating material, the charge-transporting material, and the binder resin are included in the same layer, and the binder resin is a terpolymer polycarbonate resin represented by general formula (I) below.Type: GrantFiled: August 17, 2011Date of Patent: November 4, 2014Assignee: KYOCERA Document Solutions Inc.Inventors: Azuma Jun, Maruo Keiji, Hamasaki Kazunari
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Patent number: 8765335Abstract: The electrophotographic photosensitive member includes a surface layer containing (?), (?) and (?).Type: GrantFiled: June 6, 2012Date of Patent: July 1, 2014Assignee: Canon Kabushiki KaishaInventors: Daisuke Tanaka, Kazumichi Sugiyama, Tsutomu Nishida
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Patent number: 8518615Abstract: A method of drying an organic pigment is provided which includes an under-depressurization microwave drying step of irradiating the organic pigment with microwaves under depressurization and drying the organic pigment. A method of processing a phthalocyanine pigment and a method of manufacturing an electrophotographic photosensitive member are also provided each of which utilizes the drying method.Type: GrantFiled: September 27, 2010Date of Patent: August 27, 2013Assignee: Canon Kabushiki KaishaInventor: Masato Tanaka
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Patent number: 8263297Abstract: An electrophotographic photoconductor including a conductive support and a photosensitive layer, wherein the photosensitive layer contains a charge generation agent, a charge transport agent and a binder resin, and wherein the charge generation agent contains an asymmetric disazo pigment represented by General Formula (I), the charge transport agent contains a triphenylamine compound represented General Formula (IX), and the mass ratio of the charge transport agent to the binder resin is 0.3 to 2.0, where R1 and R2 each represent a substituted or unsubstituted alkyl group, alkoxy group, aryl group or heterocyclic group, provided that R1 and R2 are different, where R3 to R5 each represent hydrogen, a halogen atom, an alkyl group having 1 to 6 carbon atoms, which may have a substituent, an alkoxy group having 1 to 6 carbon atoms, which may have a substituent, or a substituted or unsubstituted aryl group having 6 to 12 carbon atoms.Type: GrantFiled: November 25, 2008Date of Patent: September 11, 2012Assignees: Ricoh Company, Ltd., Yamanashi Electronics Co., Ltd.Inventors: Takaaki Ikegami, Takeshi Takada, Toshihiko Koizumi, Hideki Nakamura, Hajime Suzuki, Keisuke Shimoyama, Kohsuke Yamamoto, Eiji Kurimoto
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Patent number: 8206880Abstract: An electrophotographic photoreceptor, including an electroconductive substrate; and a photosensitive layer overlying the substrate, wherein the photosensitive layer comprises a complex azo pigment comprising an azo compound having the following formula (a): A(H)n??(a) wherein A represents a residue of an azo compound, bonded with n pieces of hydrogen atom through one or more heteroatom being N or O and forming a part of the residue A; H represents a hydrogen atom; and n represents an integer of from 1 to 9, and a pigment.Type: GrantFiled: June 2, 2010Date of Patent: June 26, 2012Assignee: Ricoh Company, Ltd.Inventors: Hiromi Tada, Masafumi Ohta, Tatsuya Niimi, Norio Nagayama, Yoshiki Yanagawa, Yuuji Tanaka
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Patent number: 8173338Abstract: An electrophotographic photoconductor system for use in an electrophotographic device and method of using the same. The electrophotoconductor system comprises an electroconductive support, a charge generation layer disposed on the electroconductive support, and a charge transport layer disposed on the charge generation layer. The charge generation layer includes a photosensitive material comprising titanyl phthalocyanine, and at least one oligomeric phenylene additive. The electrophotographic photoconductor system is capable of absorbing light having a wavelength of about 350 nm to about 850 nm.Type: GrantFiled: February 11, 2009Date of Patent: May 8, 2012Assignee: Lexmark International, Inc.Inventors: Mark Thomas Bellino, Weimel Luo, Scott Daniel Reeves, Tanya Yvonne Thames
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Patent number: 8137878Abstract: The invention relates to an electrophotographic photoreceptor in which protrusions from the surface of the photoreceptor are partly or completely covered by a resin. The effect of such resin covering is to reduce toner deposition, thereby reducing or eliminating spotting defects in images formed using the electrophotographic photoreceptor. The invention further relates to an image-forming apparatus incorporating such an electrophotographic photoreceptor.Type: GrantFiled: April 24, 2008Date of Patent: March 20, 2012Assignee: Kyocera CorporationInventor: Yoshiaki Fujiwara
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Patent number: 8088541Abstract: The present invention relates to a polyvinyl acetal resin having a specific repeating structural unit, an electrophotographic photosensitive member using the polyvinyl acetal resin, and a process cartridge and an electrophotographic apparatus each having the electrophotographic photosensitive member.Type: GrantFiled: December 5, 2006Date of Patent: January 3, 2012Assignee: Canon Kabushiki KaishaInventors: Masato Tanaka, Atsushi Fujii, Yuka Ishiduka, Masataka Kawahara, Masaki Nonaka
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Publication number: 20110091799Abstract: In an electrophotographic photoreceptor having a photosensitive layer on an electroconductive substrate, the photosensitive layer is a positive-charging laminate comprising at least a charge transport layer and a charge generating layer laminated in that order, with the charge generating layer containing at least a resin binder, a charge generating agent, a space filler and an electron transport agent, while the charge transport layer contains at least, as a resin binder, polystyrene and a hole transport agent, and mineral oil of the charge transport layer is in an amount of 1% by mass or less of an amount of polystyrene. Thus, a highly durable and economic positive-charging multilayer electrophotographic photoreceptor and a manufacturing method therefor may be achieved.Type: ApplicationFiled: May 28, 2009Publication date: April 21, 2011Inventors: Yoichi Nakamura, Seizo Kitagawa, Hiroshi Emori, Yasushi Tanaka, Hiroyuki Ichiyanagi
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Patent number: 7893185Abstract: A polycarbonate copolymer contains: 0.1 to 50 mol % of a monomer unit represented by the following formula (1); and a monomer unit represented by the following formula (2). In the polycarbonate copolymer, the content of biphenols having a structure represented by the following formula (3) is 90 mass ppm or less. In the formula, R1 and R2 each independently represent a hydrogen atom, an aliphatic hydrocarbon group having 1 to 6 carbon atoms, an aryl group having 6 to 12 carbon atoms or a halogen atom. In the formula: R3 and R4 each independently represent a hydrogen atom, an aliphatic hydrocarbon group having 1 to 6 carbon atoms, an aryl group having 6 to 12 carbon atoms or a halogen atom; and X represents any one of bonding groups represented by —O—, —S—, —SO—, —SO2—, —CO— and 9,9-fluorenylidene group. In the formula, R1 and R2 each independently represent a hydrogen atom, an aliphatic hydrocarbon group having 1 to 6 carbon atoms, an aryl group having 6 to 12 carbon atoms or a halogen atom.Type: GrantFiled: October 18, 2007Date of Patent: February 22, 2011Assignee: Idemitsu Kosan Co., Ltd.Inventors: Takaaki Hikosaka, Yasushi Hamada
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Patent number: 7851112Abstract: A photoconductor containing an optional supporting substrate, a thiophosphate containing photogenerating layer, and a charge transport layer which includes a polyhedral oligomeric silsesquioxane (POSS)-containing material and an optional thiophosphate.Type: GrantFiled: November 28, 2006Date of Patent: December 14, 2010Assignee: Xerox CorporationInventors: Jin Wu, Kenny-Tuan Dinh, Kathleen M. Carmichael, Michael S. Roetker, Liang-Bih Lin
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Publication number: 20090061339Abstract: A photoconductor comprising a supporting substrate, a photogenerating layer, and at least one charge transport layer comprised of at least one charge transport component, and where the photogenerating layer contains a triazole.Type: ApplicationFiled: August 31, 2007Publication date: March 5, 2009Applicant: XEROX CORPORATIONInventor: Jin Wu
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Patent number: 7442479Abstract: A photoreceptor including at least an electroconductive substrate, and a charge blocking layer, a moiré preventing layer, and a photosensitive layer, which are located overlying the electroconductive substrate in this order, wherein the photosensitive layer includes an azo pigment having a fluorenone skeleton. The photosensitive layer is preferably prepared by coating a coating liquid including a dispersion which is prepared by dispersing the azo pigment in a solvent to an extent such that the average particle diameter of the azo pigment is not greater than 0.3 ?m and the standard deviation of the particle diameter is not greater than 0.2 ?m, followed by filtering with a filter having an effective pore diameter not greater than 5 ?m. An image forming apparatus and a process cartridge including the photoreceptor.Type: GrantFiled: June 27, 2005Date of Patent: October 28, 2008Assignee: Ricoh Company, LimitedInventor: Tatsuya Niimi
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Patent number: 7403735Abstract: An image formation apparatus using an elecrophotographic process for obtaining a high quality image with tone value R2 of equal to or more than 0.98 is provided. The resolution for light-writing is equal to or more than 1200 dpi and/or light-writing is performed based on image data formed by applying halftone processing at a line frequency of equal to or more than 200 lpi. Light-writing means is accomplished with a laser light beam with a beam diameter equal to or less than 35 ?m. The photoconductor includes a charge generating layer containing a charge generating material and a charge transfer layer containing a charge transfer material laminated on a conductive support. The ionization potential of the charge generating material Ip(CG) and ionization potential of the charge transfer material Ip(CT) satisfy the relationship of Ip(CG)?Ip(CT).Type: GrantFiled: January 24, 2003Date of Patent: July 22, 2008Assignee: Ricoh Company, Ltd.Inventors: Kei Yasutomi, Yasuo Suzuki
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Patent number: 7341810Abstract: An electrophotographic photoreceptor comprising a conductive substrate, an undercoat layer located overlying the conductive substrate, a photosensitive layer located overlying the undercoat layer. The photosensitive layer has a charge generation layer located overlying the undercoat layer and a charge transport layer located overlying the charge generation layer. In addition, when the charge generation layer is irradiated in the absence of the charge transport layer with light in a range of from 360 nm to 740 nm having the highest reflectivity for the charge generation layer, the charge generation layer has a reflectivity of from 15 to 21%.Type: GrantFiled: September 17, 2004Date of Patent: March 11, 2008Assignee: Ricoh Company, Ltd.Inventors: Eiji Kurimoto, Yasuyuki Yamashita
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Patent number: 7333752Abstract: An electrophotographic apparatus is disclosed using an electrophotographic photosensitive member which employs light with a short wavelength (380 nm to 500 nm) as image exposure light and is good in photoelectric conversion efficiency on the whole at that wavelength. The electrophotographic photosensitive member is composed of a reflecting layer, a charge generation layer and a charge transport layer formed on a support. The total reflectance and specular reflectance of the reflecting layer are 30% or more (with respect to a standard white board) and less than 15%, respectively, at that short-wavelength light. The absorbance of the charge generation layer is 1.0 or less at that short-wavelength light.Type: GrantFiled: July 7, 2006Date of Patent: February 19, 2008Assignee: Canon Kabushiki KaishaInventors: Masataka Kawahara, Masato Tanaka, Atsushi Fujii, Yuka Ishizuka, Masaki Nonaka
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Patent number: 7276318Abstract: This invention relates to an electrophotographic photosensitive member having a support and a photosensitive layer.Type: GrantFiled: November 5, 2004Date of Patent: October 2, 2007Assignee: Canon Kabushiki KaishaInventors: Atsushi Fujii, Masato Tanaka
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Patent number: 7192677Abstract: An electrophotographic photoconductor including an electroconductive support and a photoconductive layer formed thereon, which contains a phthalocyanine pigment and a disazo pigment of formula (I): wherein A and B are coupler radicals having different structures.Type: GrantFiled: March 11, 2005Date of Patent: March 20, 2007Assignee: Ricoh Company, Ltd.Inventor: Yasuo Suzuki
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Patent number: 7135261Abstract: A multi-layered organic electrophotographic photoconductor exhibits superior stability in mass production and excellent adhesion ability with two layers contacting the charge generation layer and is free of contamination of the coating liquid for a charge transport layer during a dip-coating process due to dissolution of the charge generation layer. The multi-layered organic electrophotographic photoconductor includes a conductive substrate and layers including an undercoat layer containing a thermosetting resin, a charge generation layer containing a charge generation material and an organic binder resin, and a charge transport layer laminated sequentially on the substrate, wherein polydispersity defined by a ratio of a weight average molecular weight to a number average molecular weight of the organic binder resin is at least 4.0, and the weight average molecular weight is at least 7.0×104 in a distribution of a polystyrene-converted molecular weight obtained by gel permeation chromatography.Type: GrantFiled: August 22, 2003Date of Patent: November 14, 2006Assignee: Fuji Electric Imaging Device Co., Ltd.Inventor: Mikio Yamazaki
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Patent number: 6960417Abstract: An electrophotographic photoconductor including an electroconductive support and a photoconductive layer formed thereon, which contains a phthalocyanine pigment and a disazo pigment of formula (I): wherein A and B are coupler radicals having different structures.Type: GrantFiled: October 31, 1995Date of Patent: November 1, 2005Assignee: Ricoh Company, Ltd.Inventor: Yasuo Suzuki
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Patent number: 6946225Abstract: A multi-active electrophotographic charge generation element comprises a conductive support, a charge generation layer (CGL) disposed on the conductive support, and a charge transport layer (CTL) disposed on the charge generation layer. The charge generation layer (CGL) includes a charge-generation material comprising an aggregated or crystalline form of a first dye or pigment and a first polymeric binder. The charge transport layer (CTL) comprises at least one charge-transport agent, a second dye or pigment having absorption in a selected spectral region that at least partially overlaps the absorption of a dissolved non-aggregated or non-crystalline form of the first dye or pigment, and a second polymeric binder. The second dye or pigment in the charge transport layer absorbs radiation in the selected spectral region that is incident on the charge transport layer, thereby shielding the charge generation layer from that radiation and mitigating visible radiation-induced photofatigue.Type: GrantFiled: July 22, 2002Date of Patent: September 20, 2005Assignee: Eastman Kodak CompanyInventors: Albert V. Buettner, Dennis R. Fronheiser, Anne F. Lairmore, David S. Weiss, Jeffrey R. Murray, Marie B. O'Regan
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Publication number: 20040214101Abstract: An electrophotographic photoconductor including an electroconductive support and a photoconductive layer formed thereon, which contains a phthalocyanine pigment and a disazo pigment of formula (I): 1Type: ApplicationFiled: October 31, 1995Publication date: October 28, 2004Inventor: YASUO SUZUKI
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Patent number: 6777149Abstract: An image forming apparatus including at least an image irradiator configured to irradiate a photoreceptor with a coherent light beam while scanning to form pixel light spots thereon for forming an electrostatic latent image thereon, wherein the light spots overlap with adjacent light spots; and an image developer configured to develop the electrostatic latent image with a developer, wherein the photoreceptor comprises an intermediate layer located overlying an electroconductive substrate, a charge generation layer located overlying the intermediate layer and a charge transport layer located overlying the charge generation layer, wherein the charge generation layer satisfies the following relationship: T1≦3.5% wherein T1 represents a relative mirror reflectance of the charge generation layer against the coherent light beam when the coherent light beam irradiates the charge generation layer at an incident angle of 5°.Type: GrantFiled: March 25, 2002Date of Patent: August 17, 2004Assignee: Ricoh Company LimitedInventors: Takaaki Ikegami, Akihiro Sugino
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Patent number: 6773856Abstract: An electrophotographic photosensitive member has a support and a photosensitive layer provided thereon. The photosensitive layer contains a carixarene compound having specific structure. Also disclosed are a process cartridge and an electrophotographic apparatus which have the electrophotographic photosensitive member.Type: GrantFiled: November 1, 2002Date of Patent: August 10, 2004Assignee: Canon Kabushiki KaishaInventors: Masato Tanaka, Hideki Anayama, Hidetoshi Hirano, Atsushi Fujii, Ryuji Higashi
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Publication number: 20040126688Abstract: A multi-layered organic electrophotographic photoconductor exhibits superior stability in mass production and excellent adhesion ability with two layers contacting the charge generation layer and is free of contamination of the coating liquid for a charge transport layer during a dip-coating process due to dissolution of the charge generation layer. The multi-layered organic electrophotographic photoconductor includes a conductive substrate and layers including an undercoat layer containing a thermosetting resin, a charge generation layer containing a charge generation material and an organic binder resin, and a charge transport layer laminated sequentially on the substrate, wherein polydispersity defined by a ratio of a weight average molecular weight to a number average molecular weight of the organic binder resin is at least 4.0, and the weight average molecular weight is at least 7.0×104 in a distribution of a polystyrene-converted molecular weight obtained by gel permeation chromatography.Type: ApplicationFiled: August 22, 2003Publication date: July 1, 2004Applicant: Fuji Electric Imaging Device Co., Ltd.Inventor: Mikio Yamazaki
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Patent number: 6656652Abstract: An electrophotographic photosensitive member includes a support, and a charge generation layer and a charge transport layer provided on the support in this order. The charge generation layer contains a charge-generating material in an amount of more than 2 parts by weight and not more than 5 parts by weight based on 1 part by weight of a binder resin, and the support has a surface roughness in which a maximum height RmaxD, a 10-point average roughness Rz, an arithmetic-mean roughness Ra and an unevenness average distance Sm fulfill the following conditions: 1.2 &mgr;m≦RmaxD≦5.0 &mgr;m, 1.2 &mgr;m≦Rz≦3.0 &mgr;m, 0.15 &mgr;m≦Ra≦0.5 &mgr;m, 30 &mgr;m<Sm≦80 &mgr;m. Also disclosed are a process cartridge and an electrophotographic apparatus which have the electrophotographic photosensitive member.Type: GrantFiled: September 26, 2001Date of Patent: December 2, 2003Assignee: Canon Kabushiki KaishaInventors: Shuji Ishii, Kazushige Nakamura, Noriyuki Takagi
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Publication number: 20030215264Abstract: An image formation apparatus using an elecrophotographic process for obtaining a high quality image with tone value R2 of equal to or more than 0.98 is provided. The resolution for light-writing is equal to or more than 1200 dpi and/or light-writing is performed based on image data formed by applying halftone processing at a line frequency of equal to or more than 200 lpi. Light-writing means is accomplished with a laser light beam with a beam diameter equal to or more than 35 &mgr;m. The photoconductor includes a charge generating layer containing a charge generating material and a charge transfer layer containing a charge transfer material laminated on a conductive support. The ionization potential of the charge generating material Ip(CG) and ionization potential of the charge transfer material Ip(CT) satisfy the relationship of Ip(CG)≧Ip(CT).Type: ApplicationFiled: January 24, 2003Publication date: November 20, 2003Inventors: Kei Yasutomi, Yasuo Suzuki
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Publication number: 20030143475Abstract: An electrophotographic photosensitive member has a support and a photosensitive layer provided thereon. The photosensitive layer contains a carixarene compound having specific structure. Also disclosed are a process cartridge and an electrophotographic apparatus which have the electrophotographic photosensitive member.Type: ApplicationFiled: November 1, 2002Publication date: July 31, 2003Inventors: Masato Tanaka, Hideki Anayama, Hidetoshi Hirano, Atsushi Fujii, Ryuji Higashi
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Publication number: 20030104295Abstract: A photoreceptor that can be repeatedly used to produce high-quality images steadily is described, as well as an electrophotographic apparatus that can be used to producing high-quality images even after repeated use. The electrophotographic photoreceptor has a protective layer thereon, in which the grain size distribution of the fillers continuously or gradually increases from the photosensitive layer side to the surface side. Meanwhile, the electrophotographic photoreceptor is used in the electrophotographic apparatus.Type: ApplicationFiled: March 22, 2002Publication date: June 5, 2003Inventor: Tatsuya Niimi
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Publication number: 20030059693Abstract: An image forming apparatus including at least an image irradiator configured to irradiate a photoreceptor with a coherent light beam while scanning to form pixel light spots thereon for forming an electrostatic latent image thereon, wherein the light spots overlap with adjacent light spots; and an image developer configured to develop the electrostatic latent image with a developer, wherein the photoreceptor comprises an intermediate layer located overlying an electroconductive substrate, a charge generation layer located overlying the intermediate layer and a charge transport layer located overlying the charge generation layer, wherein the charge generation layer satisfies the following relationship:Type: ApplicationFiled: March 25, 2002Publication date: March 27, 2003Inventors: Takaaki Ikegami, Akihiro Sugino
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Publication number: 20030054270Abstract: A multi-active electrophotographic charge generation element comprises a conductive support, a charge generation layer (CGL) disposed on the conductive support, and a charge transport layer (CTL) disposed on the charge generation layer. The charge generation layer (CGL) includes a charge-generation material comprising an aggregated or crystalline form of a first dye or pigment and a first polymeric binder. The charge transport layer (CTL) comprises at least one charge-transport agent, a second dye or pigment having absorption in a selected spectral region that at least partially overlaps the absorption of a dissolved non-aggregated or non-crystalline form of the first dye or pigment, and a second polymeric binder. The second dye or pigment in the charge transport layer absorbs radiation in the selected spectral region that is incident on the charge transport layer, thereby shielding the charge generation layer from that radiation and mitigating visible radiation-induced photofatigue.Type: ApplicationFiled: July 22, 2002Publication date: March 20, 2003Inventors: Albert V. Buettner, Dennis R. Fronheiser, Anne F. Lairmore, David S. Weiss, Jeffrey R. Murray, Marie B. O'Regan
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Publication number: 20020127487Abstract: An electrophotographic photoconductor has an electroconductive support, and a photoconductive layer formed thereon which contains at least one bisazo compound of formula (I): 1Type: ApplicationFiled: September 4, 2001Publication date: September 12, 2002Applicant: Ricoh Company, Ltd.Inventor: Tomoyuki Shimada
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Publication number: 20020061454Abstract: An electrophotographic photosensitive member capable of forming images with less defects, such as ghost, while retaining a high photo-sensitivity, is provided.Type: ApplicationFiled: January 24, 2001Publication date: May 23, 2002Inventors: Masato Tanaka, Hideki Anayama, Hidetoshi Hirano, Kan Tanabe, Kazue Asakura, Atsushi Fujii