Titanium (ti) Or Vanadium (v) Phthalocyanine Containing Patents (Class 430/59.5)
  • Patent number: 7560206
    Abstract: A photoconductor containing an optional supporting substrate, a silanol containing photogenerating layer, and at least one charge transport layer.
    Type: Grant
    Filed: July 12, 2006
    Date of Patent: July 14, 2009
    Assignee: Xerox Corporation
    Inventors: Jin Wu, John S. Chambers, Satchidanand Mishra, Michael A. Morgan, Liang-Bih Lin
  • Patent number: 7560203
    Abstract: An electrophotographic photoconductor that is excellent in the stability of image quality and can realize high durability is provided. In an electrophotographic photoconductor in which an underlying layer, a photoconductive layer, and a crosslinked-type charge transportation layer are stacked on an electrically conductive support in order, the underlying layer is composed of at least two layers being a layer containing an inorganic pigment and a layer including no inorganic pigment, and the crosslinked-type charge transportation layer is formed by curing, at least, a three-or-more-functional radical-polymerizable monomer having no charge transporting structure and a radical-polymerizable compound having one-functional charge transporting structure.
    Type: Grant
    Filed: December 1, 2004
    Date of Patent: July 14, 2009
    Assignee: Ricoh Company, Ltd.
    Inventors: Nozomu Tamoto, Tatsuya Niimi, Tetsuro Suzuki, Katsuichi Ohta
  • Patent number: 7560204
    Abstract: The present invention provides a latent electrostatic image bearing member which includes a support, a charge generating layer, and a charge transporting layer, the charge generating layer and the charge transporting layer being arranged in this order on or above the support, wherein the charge transporting layer comprises at least a charge transporting material and a binder resin and has a thickness of 30 ?m to 50 ?m; and the distribution representing the relation between the absorbance ratio of the charge transporting material and the binder resin measured by infrared spectroscopy and the distance from the surface of the charge transporting layer toward the thickness direction thereof represents a generally linear shape without having inflection points within 20 ?m from the surface of the charge transporting layer toward the thickness thereof.
    Type: Grant
    Filed: September 12, 2006
    Date of Patent: July 14, 2009
    Assignee: Ricoh Company, Ltd.
    Inventors: Naohiro Toda, Yasuyuki Yamashita, Takeshi Orito
  • Patent number: 7553593
    Abstract: A photoconductor containing an optional supporting substrate, a photogenerating layer, and at least one charge transport layer, and wherein the photogenerating layer contains a titanyl phthalocyanine prepared, for example, by dissolving a Type I titanyl phthalocyanine in a solution comprising a trihaloacetic acid and an alkylene halide; adding the mixture comprising the dissolved Type I titanyl phthalocyanine to a solution comprising an alcohol and an alkylene halide thereby precipitating a Type Y titanyl phthalocyanine; and treating the Type Y titanyl phthalocyanine with a monohalobenzene.
    Type: Grant
    Filed: June 22, 2006
    Date of Patent: June 30, 2009
    Assignee: Xerox Corporation
    Inventors: Jin Wu, Satchidanand Mishra, Kathleen M. Carmichael, Anthony M. Horgan, Kent J. Evans, Geoffrey M T. Foley, Yonn K. Rasmussen, Edward F. Grabowski, Liang-Bih Lin
  • Patent number: 7550239
    Abstract: A photoconductor containing an optional supporting substrate, a photogenerating layer, and at least one charge transport layer, and wherein the photogenerating layer contains an alkyltriol, such as glycerol, and a photogenerating pigment, such as a Type V titanyl phthalocyanine prepared, for example, by dissolving a Type I titanyl phthalocyanine in a solution of a trihaloacetic acid and an alkylene halide; adding the mixture comprising the dissolved Type I titanyl phthalocyanine to a solution of an alcohol and an alkylene halide thereby precipitating a Type Y titanyl phthalocyanine; and treating the Type Y titanyl phthalocyanine with a monohalobenzene.
    Type: Grant
    Filed: January 23, 2007
    Date of Patent: June 23, 2009
    Assignee: Xerox Corporation
    Inventors: Cuong Vong, Ah-Mee Hor
  • Patent number: 7537872
    Abstract: An image bearing member including an electroconductive substrate, a charge blocking layer disposed overlying the electroconductive substrate, a moire prevention layer disposed overlying the charge blocking layer, and a photosensitive layer disposed overlying the moire prevention layer. The charge blocking layer contains N-alkoxymethylized nylon and optionally at least one of an aliphatic dicarboxylic acid and an aliphatic tricarboxylic acid. The moire prevention layer contains a titanium oxide having a purity not less than 99.0% and a cross-linking resin.
    Type: Grant
    Filed: April 13, 2006
    Date of Patent: May 26, 2009
    Assignee: Ricoh Company Limited
    Inventors: Naohiro Toda, Yasuyuki Yamashita, Takeshi Orito
  • Patent number: 7514191
    Abstract: An imaging member is disclosed with a charge transport layer comprising a dimethyl terphenyl diamine having the structure of Formula (I): wherein n is an integer from 0 to about 18. The resulting imaging member has enhanced performance properties.
    Type: Grant
    Filed: November 8, 2006
    Date of Patent: April 7, 2009
    Assignee: Xerox Corporation
    Inventors: John F. Yanus, Markus Silvestri
  • Patent number: 7507510
    Abstract: An imaging member containing an optional supporting substrate, a photogenerating layer, and at least one charge transport layer of at least one charge transport component, at least one polyphenyl ether of the formula wherein each R1, R2, and R3 is independently selected from the group consisting of hydrogen, alkyl, aryl, alkoxy, substituted alkyl, substituted aryl, substituted alkoxy, and halogen, and n is from about 1 to about 10, and a thiophosphate.
    Type: Grant
    Filed: June 15, 2006
    Date of Patent: March 24, 2009
    Assignee: Xerox Corporation
    Inventors: Jin Wu, Kenny-Tuan Dinh, Kathleen M. Carmichael, Michael S. Roetker, Kent J. Evans, Geoffrey M T. Foley, Anthony M. Horgan, Yonn K. Rasmussen, Satchidanand Mishra, Edward F. Grabowski, Liang-Bih Lin, Markus R. Silvestri
  • Publication number: 20090061336
    Abstract: A photoconductor comprising a supporting substrate, a photogenerating layer, and at least one charge transport layer comprised of at least one charge transport component, and wherein said photogenerating layer contains a light stabilizer.
    Type: Application
    Filed: August 31, 2007
    Publication date: March 5, 2009
    Applicant: XEROX CORPORATION
    Inventor: Jin Wu
  • Publication number: 20090061337
    Abstract: A photoconductor comprising a supporting substrate, a photogenerating layer, and at least one charge transport layer comprised of at least one charge transport component, and where the photogenerating layer contains a triazine.
    Type: Application
    Filed: August 31, 2007
    Publication date: March 5, 2009
    Applicant: XEROX CORPORATION
    Inventors: Jin Wu, Liang-Bih Lin, Daniel V. Levy, Marko D. Saban
  • Publication number: 20090061338
    Abstract: A photoconductor comprising a supporting substrate, a photogenerating layer, and at least one charge transport layer comprised of at least one charge transport component, and where the photogenerating layer contains a boron containing compound.
    Type: Application
    Filed: August 31, 2007
    Publication date: March 5, 2009
    Applicant: XEROX CORPORATION
    Inventor: Jin Wu
  • Publication number: 20090035676
    Abstract: A photoconductor that includes, for example, a substrate; an undercoat layer thereover wherein the undercoat layer contains a metal oxide and an iodonium containing compound; a photogenerating layer; and at least one charge transport layer.
    Type: Application
    Filed: July 31, 2007
    Publication date: February 5, 2009
    Applicant: XEROX CORPORATION
    Inventor: Jin Wu
  • Publication number: 20090035675
    Abstract: A photoconductor that includes, for example, a substrate; an undercoat layer thereover wherein the undercoat layer contains a metal oxide, and a copper containing compound; a photogenerating layer; and at least one charge transport layer.
    Type: Application
    Filed: July 31, 2007
    Publication date: February 5, 2009
    Applicant: XEROX CORPORATION
    Inventor: Jin Wu
  • Publication number: 20090035674
    Abstract: A photoconductor that includes a substrate; an undercoat layer thereover comprised of a metal oxide, and an ultraviolet light absorber component; a photogenerating layer; and at least one charge transport layer.
    Type: Application
    Filed: July 31, 2007
    Publication date: February 5, 2009
    Applicant: XEROX CORPORATION
    Inventor: Jin Wu
  • Publication number: 20090035673
    Abstract: A photoconductor that includes a substrate; an undercoat layer thereover wherein the undercoat layer contains, for example, a metal oxide, and an iron containing compound; a photogenerating layer; and at least one charge transport layer.
    Type: Application
    Filed: July 31, 2007
    Publication date: February 5, 2009
    Applicant: XEROX CORPORATION
    Inventor: Jin Wu
  • Patent number: 7485398
    Abstract: A photoconductor containing an optional supporting substrate, a photogenerating layer, and at least one charge transport layer comprised of at least one charge transport component wherein the at least one charge transport component is comprised of aryl amine molecules of the formula wherein X and Y are each independently alkyl, alkoxy, aryl, a halogen, and wherein the photogenerating layer contains a titanyl phthalocyanine prepared by dissolving a Type I titanyl phthalocyanine in a solution comprising a trihaloacetic acid and an alkylene halide; adding the mixture comprising the dissolved Type I titanyl phthalocyanine to a solution comprising an alcohol and an alkylene halide thereby precipitating a Type Y titanyl phthalocyanine; and treating the Type Y titanyl phthalocyanine with monohalobenzene.
    Type: Grant
    Filed: June 22, 2006
    Date of Patent: February 3, 2009
    Assignee: Xerox Corporation
    Inventors: Jin Wu, John F. Yanus, Satish R. Parikh, Anthony M. Horgan, Kent J Evans, Geoffrey M T. Foley, Satchidanand Mishra, Markus R. Silvestri, J. Robinson Cowdery-Corvan, David M. Skinner, Edward F. Grabowski, Kathleen M. Carmichael, Yonn K. Rasmussen, Donald J. Goodman, Liang-Bih Lin
  • Patent number: 7479358
    Abstract: An imaging member containing an optional supporting substrate, a photogenerating layer, and at least one charge transport layer of at least one charge transport component, at least one C-ether of the formula wherein R1, R2, R3 and R4 are independently selected from the group consisting of hydrogen, alkyl, aryl, alkoxy, substituted alkyl, substituted aryl, substituted alkoxy, and halogen, and the sum of n plus m (n+m) is from about 1 to about 10, and a thiophosphate.
    Type: Grant
    Filed: June 15, 2006
    Date of Patent: January 20, 2009
    Assignee: Xerox Corporation
    Inventors: Jin Wu, Kenny-Tuan Dinh, Kathleen M. Carmichael, Michael S. Roetker, Kent J. Evans, Geoffrey M T. Foley, Anthony M. Horgan, Yonn K. Rasmussen, Satchidanand Mishra, Edward F. Grabowski, Liang-Bih Lin, Markus R. Silvestri
  • Patent number: 7476478
    Abstract: An imaging member containing an optional supporting substrate, a photogenerating layer and at least one charge transport layer of at least one charge transport component, at least one polyphenyl thioether of the formula wherein R1, R2, and R3 are independently selected from the group consisting of hydrogen, alkyl, aryl, alkoxy, substituted alkyl, substituted aryl, substituted alkoxy, and halogen mixtures thereof, and n is a number of, for example, from about 1 to about 10.
    Type: Grant
    Filed: June 15, 2006
    Date of Patent: January 13, 2009
    Assignee: Xerox Corporation
    Inventors: Jin Wu, Kenny-Tuan Dinh, Kathleen M. Carmichael, Michael S. Roetker, Kent J. Evans, Geoffrey M T. Foley, Anthony M. Horgan, Yonn K. Rasmussen, Satchidanand Mishra, Edward F. Grabowski, Liang-Bih Lin
  • Patent number: 7473505
    Abstract: A photoconductor containing an optional supporting substrate, a photogenerating layer, and at least one charge transport layer, at least one C-ether of the formula wherein R1, R2, R3 and R4 are independently selected from the group consisting of hydrogen, alkyl, aryl, alkoxy, substituted alkyl, substituted aryl, substituted alkoxy, and halogen, and the sum of n plus m (n+m) is from about 1 to about 10.
    Type: Grant
    Filed: June 15, 2006
    Date of Patent: January 6, 2009
    Assignee: Xerox Corporation
    Inventors: Jin Wu, Kenny-Tuan Dinh, Kathleen M. Carmichael, Michael S. Roetker, Kent J. Evans, Geoffrey M T. Foley, Anthony M. Horgan, Yonn K. Rasmussen, Satchidanand Mishra, Edward F. Grabowski, Liang-Bih Lin
  • Publication number: 20090004586
    Abstract: The present disclosure relates to an electrophotoconductive element comprising a conductive substrate, a charge generation layer including a charge generating compound and a charge transport layer. The charge generation layer includes a first polymer resin and second polymer resin to provide a blend including the charge generating compound. The first polymer resin may therefore indicate an energy at a half charge potential E0.5(POLYMER) upon exposure to light at a wavelength of about 350-500 nm. The blend then also indicates an energy at half charge potential E0.5(BLEND) upon exposure to light at a wavelength of about 350-500 nm. The second polymer resin of the blend is therefore selected to provide that E0.5(BLEND)<E0.5(POLYMER).
    Type: Application
    Filed: June 29, 2007
    Publication date: January 1, 2009
    Inventors: Mark Thomas Bellino, David Glenn Black, Dat Quoc Nguyen, Weimei Luo, Scott Daniel Reeves
  • Publication number: 20090005555
    Abstract: A process which includes treating, mixing, or contacting a Type I titanyl phthalocyanine with a weak acid with a pKa of at least equal to or greater than about 0; dissolving the acid treated Type I titanyl phthalocyanine in a solution of a trihaloacetic acid and an alkylene halide; adding the formed mixture to a solution of an alcohol and an alkylene halide thereby precipitating a Type Y titanyl phthalocyanine; and treating the Type Y titanyl phthalocyanine with monohalobenzene thereby resulting in a high sensitivity titanyl phthalocyanine.
    Type: Application
    Filed: June 27, 2007
    Publication date: January 1, 2009
    Applicant: XEROX CORPORATION
    Inventor: Jin Wu
  • Publication number: 20080311497
    Abstract: A photoconductor that includes a substrate; an undercoat layer thereover wherein the undercoat layer comprises a metal oxide, an electron donor electron acceptor charge transfer complex; a photogenerating layer; and at least one charge transport layer.
    Type: Application
    Filed: June 18, 2007
    Publication date: December 18, 2008
    Applicant: Xerox Corporation
    Inventors: Jin Wu, Linda L. Ferrarese, Marc J. Livecchi, Lin Ma, John J. Wilbert, Lanhui Zhang
  • Patent number: 7462432
    Abstract: An imaging member containing an optional supporting substrate, a photogenerating layer, and at least one charge transport layer of at least one charge transport component, at least one polyphenyl thioether of the formula wherein R1, R2, and R3 are independently selected from the group consisting of hydrogen, alkyl, aryl, alkoxy, substituted alkyl, aryl, alkoxy, and halogen; n is a number of from about 1 to about 10; and a thiophosphate.
    Type: Grant
    Filed: June 15, 2006
    Date of Patent: December 9, 2008
    Assignee: Xerox Corporation
    Inventors: Jin Wu, Kenny-Tuan Dinh, Kathleen M. Carmichael, Michael S. Roetker, Kent J. Evans, Geoffrey M T. Foley, Anthony M. Horgan, Yonn K. Rasmussen, Satchidanand Mishra, Edward F. Grabowski, Liang-Bih Lin, Markus R. Silvestri
  • Publication number: 20080286008
    Abstract: A titanylphthalocyanine crystal having an X-ray diffraction spectrum having plural diffraction peaks and a primary particle diameter not greater than 0.2 ?m, wherein a maximum diffraction peak is observed at a Bragg (2 ?) angle of 27.2±0.2°; main peaks are observed at 9.4°, 9.6° and 24.0°; and a minimum diffraction peak is observed at 7.3°; and preferably no diffraction peak is observed at an angle greater than 7.3° and less than 9.4° when a specific X-ray of CuK? having a wavelength of 1.542 ? irradiates the titanylphthalocyanine crystal.
    Type: Application
    Filed: July 16, 2008
    Publication date: November 20, 2008
    Inventor: Tatsuya NIIMI
  • Patent number: 7452643
    Abstract: An imaging member containing an optional supporting substrate, a photogenerating layer, and at least one charge transport layer of at least one charge transport component, at least one polyphenyl ether of the formula wherein R1, R2, R3 and R4 are independently selected from the group consisting of hydrogen, alkyl, aryl, alkoxy, substituted alkyl, substituted aryl, substituted alkoxy, and halogen, and n is a number of from about 1 to about 10; and wherein a thiophosphate is contained in the photogenerating layer.
    Type: Grant
    Filed: June 15, 2006
    Date of Patent: November 18, 2008
    Assignee: Xerox Corporation
    Inventors: Jin Wu, Kenny-Tuan Dinh, Kathleen M. Carmichael, Michael S. Roetker, Kent J. Evans, Geoffrey M T. Foley, Anthony M. Horgan, Yonn K. Rasmussen, Satchidanand Mishra, Edward F. Grabowski, Liang-Bih Lin, Markus R. Silvestri
  • Patent number: 7449269
    Abstract: The invention provides an electrophotographic photoreceptor capable of producing high quality images even when development is carried out under low electric potential conditions, and also provides an image forming device incorporating such an electrophotographic photoreceptor. In a photosensitive layer 14 of a photoreceptor 1, the mobility of electric charges is 2×10?6 cm2/(V·s) or greater at an electric field intensity E of 1×105 V/cm. Further, the slope ?in equation 1 representing the mobility of electric charges is 5×10?4 or less in an electric field range of 5×104<E<1×105.
    Type: Grant
    Filed: January 13, 2005
    Date of Patent: November 11, 2008
    Assignee: Sharp Kabushiki Kaisha
    Inventor: Hiroshi Sugimura
  • Patent number: 7449270
    Abstract: A two-layered electrophotographic photoreceptor is formed. The two-layered electrophotographic photoreceptor includes an electrically conductive substrate and a charge generating layer and a charge transporting layer form on the electrically conductive substrate, wherein the charge generating layer is a naphthalenetetracarboxylic acid diimide derivative represented by: The two-layered electrophotographic photoreceptor has high photosensitivity and low residual potential.
    Type: Grant
    Filed: June 12, 2006
    Date of Patent: November 11, 2008
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Beom-jun Kim, Seung-ju Kim, Saburo Yokota, Kyung-yol Yon, Moto Makino, Hwan-koo Lee, Ji-uk Kim, Ji-Young Lee
  • Publication number: 20080274419
    Abstract: A photoconductor containing a supporting substrate, a photogenerating layer, and at least one charge transport layer comprised of at least one charge transport component, and wherein the photogenerating layer contains a photogenerating pigment or pigments, and a bis(pyridyl)alkylene.
    Type: Application
    Filed: May 4, 2007
    Publication date: November 6, 2008
    Inventors: Liang-Bih Lin, Daniel V. Levy, Jin Wu, Sherri A. Colon
  • Publication number: 20080274418
    Abstract: A photoconductor containing a supporting substrate, a photogenerating layer, and at least one charge transport layer of at least one charge transport component, and wherein the charge transport layer contains a charge blocking agent, such as a benzoimidazole.
    Type: Application
    Filed: May 4, 2007
    Publication date: November 6, 2008
    Inventors: Liang-Bih Lin, Daniel V. Levy, Jin Wu, Marc J. Livecchi
  • Patent number: 7445876
    Abstract: An imaging member containing an optional supporting substrate, a photogenerating layer and at least one charge transport layer of at least one charge transport component, at least one C-ether of the formula wherein R1, R2, R3 and R4 are independently selected from the group consisting of hydrogen, alkyl, aryl, alkoxy, substituted alkyl, substituted aryl, substituted alkoxy, and halogen, and the sum of n plus m (n+m) is from about 1 to about 10, and an optional antioxidant; and wherein a thiophosphate is contained in the photogenerating layer.
    Type: Grant
    Filed: June 15, 2006
    Date of Patent: November 4, 2008
    Assignee: Xerox Corporation
    Inventors: Jin Wu, Kenny-Tuan Dinh, Kathleen M. Carmichael, Michael S. Roetker, Kent J. Evans, Geoffrey M T. Foley, Anthony M. Horgan, Yonn K. Rasmussen, Satchidanand Mishra, Edward F. Grabowski, Liang-Bih Lin, Markus R. Silvestri
  • Publication number: 20080268356
    Abstract: A photoconductor containing an optional supporting substrate, a photogenerating layer, and at least one charge transport layer comprised of at least one charge transport component, and wherein the photogenerating layer contains a Type V hydroxygallium phthalocyanine having incorporated therein a silanol.
    Type: Application
    Filed: April 27, 2007
    Publication date: October 30, 2008
    Inventors: Jin Wu, Francisco J. Lopez, Linda L. Ferrarese, Liang-Bih Lin
  • Publication number: 20080241720
    Abstract: A photoconductor that contains a first layer, a supporting substrate thereover, a photogenerating layer, and at least one charge transport layer comprised of at least one charge transport component, and wherein the first layer is in contact with the supporting substrate on the reverse side thereof, and which first layer includes a polymer and needle shaped particles with an aspect ratio of from 2 to about 200.
    Type: Application
    Filed: March 29, 2007
    Publication date: October 2, 2008
    Inventors: Jin Wu, Daniel V. Levy, Liang-Bih Lin, Lin Ma, Ryan J. Ehmann
  • Publication number: 20080241721
    Abstract: A photoconductor containing a first layer, a supporting substrate thereover, a photogenerating layer, and at least one charge transport layer comprised of at least one charge transport component, and wherein the first layer is in contact with the supporting substrate on the reverse side thereof, and which layer contains a semi-penetrating polymer network formed from crosslinking a suitable fluoropolymer, and within which network structure is penetrated with a polycarbonate.
    Type: Application
    Filed: March 29, 2007
    Publication date: October 2, 2008
    Inventors: Huoy-Jen Yuh, Robert C U Yu, Yuhua Tong, David M. Skinner
  • Publication number: 20080233500
    Abstract: A photoreceptor device having at least one layer that is a self-assembled patterned binder layer, which may include at least one functional material.
    Type: Application
    Filed: March 23, 2007
    Publication date: September 25, 2008
    Applicant: XEROX CORPORATION
    Inventors: Kathy L. DE JONG, Hany AZIZ
  • Publication number: 20080233502
    Abstract: A photoconductor containing an optional supporting substrate, a photogenerating layer, at least one charge transport layer, and an overcoating layer in contact with and contiguous to the charge transport layer, and which overcoating layer includes a fluoroalkyl ester, and a polymer.
    Type: Application
    Filed: March 23, 2007
    Publication date: September 25, 2008
    Inventors: Jin Wu, Steven D. Bush, Joseph A. Tumminelli, Lanhui Zhang, Lin Ma, Sherri A. Colon, John J. Wilbert
  • Publication number: 20080233503
    Abstract: A photoconductor containing a supporting substrate, a photogenerating layer, and at least one charge transport layer which contains a fluoroalkyl ester.
    Type: Application
    Filed: March 23, 2007
    Publication date: September 25, 2008
    Inventors: Jin Wu, Steven D. Bush, Joseph A. Tumminelli, Marc J. Livecchi, Linda L. Ferrarese, Michael A. Morgan, Lanhui Zhang, Lin Ma, John J. Wilbert, Daniel V. Levy, Liang-Bih Lin
  • Publication number: 20080220352
    Abstract: A photoconductor containing a supporting substrate, a photogenerating layer; and at least one charge transport layer where the photogenerating layer contains a photogenerating pigment and a chelating additive or agent.
    Type: Application
    Filed: March 6, 2007
    Publication date: September 11, 2008
    Inventors: Jin Wu, Kent J. Evans, Dennis J. Prosser, Liang-Bih Lin, Raymond K. Crandall
  • Publication number: 20080220350
    Abstract: A photoconductor containing a substrate; an undercoat layer thereover wherein the undercoat layer includes an electroconducting component dispersed in a rapid curing polymer matrix; a photogenerating layer, and at least one charge transport layer.
    Type: Application
    Filed: March 6, 2007
    Publication date: September 11, 2008
    Inventors: Jin Wu, Dennis J. Prosser, Satchidanand Mishra, Liang-Bih Lin, Daniel V. Levy, Lin Ma
  • Patent number: 7419751
    Abstract: A titanylphthalocyanine crystal having an X-ray diffraction spectrum having plural diffraction peaks and a primary particle diameter not greater than 0.2 ?m, wherein a maximum diffraction peak is observed at a Bragg (2?) angle of 27.2±0.2°; main peaks are observed at 9.4°, 9.6° and 24.0°; and a minimum diffraction peak is observed at 7.3°; and preferably no diffraction peak is observed at an angle greater than 7.3° and less than 9.4° when a specific X-ray of CuK? having a wavelength of 1.542 ? irradiates the titanylphthalocyanine crystal.
    Type: Grant
    Filed: June 5, 2003
    Date of Patent: September 2, 2008
    Assignee: Ricoh Company, Ltd.
    Inventor: Tatsuya Niimi
  • Publication number: 20080176155
    Abstract: A photoconductor containing an optional supporting substrate, a photogenerating layer, and at least one charge transport layer, and wherein the photogenerating layer contains an alkyltriol, such as glycerol, and a photogenerating pigment, such as a Type V titanyl phthalocyanine prepared, for example, by dissolving a Type I titanyl phthalocyanine in a solution of a trihaloacetic acid and an alkylene halide; adding the mixture comprising the dissolved Type I titanyl phthalocyanine to a solution of an alcohol and an alkylene halide thereby precipitating a Type Y titanyl phthalocyanine; and treating the Type Y titanyl phthalocyanine with a monohalobenzene.
    Type: Application
    Filed: January 23, 2007
    Publication date: July 24, 2008
    Inventors: Cuong Vong, Ah-Mee Hor
  • Patent number: 7399564
    Abstract: An electrophotographic photoconductor where generation of cracks, crystallization of a photosensitive layer, and the like occur infrequently by sticking of finger oil. An electrophotographic photoconductor includes a conductive substrate on which a photosensitive layer containing at least a charge generating agent, a hole transfer agent and a binding resin is provided, wherein the binding resin is comprised of a plurality of polycarbonate resins; and the photosensitive layer contains a biphenyl derivative as a plasticizer component represented by the following general formula (1). (wherein R1 to R10 each independently represent a substituted or unsubstituted alkyl group having 1 to 12 carbon atoms, and R represents a substituted or unsubstituted aryl group having 1 to 12 carbon atoms or a substituted or unsubstituted alkylene group having 1 to 12 carbon atoms).
    Type: Grant
    Filed: August 29, 2006
    Date of Patent: July 15, 2008
    Assignee: Kyocera Mita Corporation
    Inventors: Jun Azuma, Junichiro Otsubo
  • Patent number: 7378204
    Abstract: A photoconductive imaging member containing a photogenerating layer, and a charge transport layer, and wherein the charge transport layer is comprised of an arylamine containing a moiety that minimizes oxidation.
    Type: Grant
    Filed: June 15, 2005
    Date of Patent: May 27, 2008
    Assignee: Xerox Corporation
    Inventors: Yu Qi, Nan-Xing Hu, Gregory McGuire, Cheng-Kuo Hsiao
  • Patent number: 7371491
    Abstract: A photoreceptor including an electroconductive substrate; and a charge blocking layer; a moiré preventing layer; and a photosensitive layer, which are overlaid overlying the substrate in this order, wherein the photosensitive layer includes a titanyl phthalocyanine crystal which has an average primary particle diameter not greater than 0.25 ?m, and has an X-ray diffraction spectrum such that a maximum peak is observed at a Bragg (2?) angle of 27.2°±0.2°; a peak is observed at Bragg (2?) angle of 9.4°±0.2°, 9.6±0.2° and 24.0±0.2°; a lowest angle peak is observed at an angle of 7.3°±0.2°; no peak is observed between the lowest angle peak and the 9.4° peak; and no peak is observed at a Bragg (2?) angle of 26.3°±0.2°, when a Cu—K? X-ray having a wavelength of 0.1542 nm (1.542 ?) is used.
    Type: Grant
    Filed: September 20, 2004
    Date of Patent: May 13, 2008
    Assignee: Ricoh Company Limited
    Inventors: Tatsuya Niimi, Nozomu Tamoto, Katsuichi Ohta
  • Patent number: 7371497
    Abstract: An electrophotographic image forming apparatus comprising: an electrophotographic photoreceptor comprising: an electroconductive substrate; a charge generation layer; and a charge transport layer in this order, a charger; an irradiator; an image developer; and a transferer applying an electric current not less than 65 ?A to the electrophotographic photoreceptor, wherein the charge generation layer comprises titanylphthalocyanine crystals having a CuK? 1.542 ? X-ray diffraction spectrum having plural diffraction peaks, wherein a maximum diffraction peak is observed at a Bragg (2?) angle of 27.2°; main peaks are observed at 9.4°, 9.6° and 24.0°; and a minimum diffraction peak is observed at 7.3°; and no diffraction peak is observed at an angle greater than 7.3° and less than 9.4°, wherein said angles may vary by ±0.2° and the minimum interval where no peak is observed between required peaks at 7.3 and 9.4 is 2.0 degrees absolute or more.
    Type: Grant
    Filed: November 2, 2005
    Date of Patent: May 13, 2008
    Assignee: Ricoh Company Ltd.
    Inventors: Naohiro Toda, Tatsuya Niimi
  • Patent number: 7371490
    Abstract: The object of the present invention is to provide a photoconductor that is highly sensitive, stable in image quality under repeated usages, and affords prolonged life. In order attain the object, a photoconductor is provided that comprises a charge generating layer, a charge transporting layer, and a crosslinked charge transporting layer, on an substrate in order, the charge generating layer contains titanyl phthalocyanine crystal particles that exhibit a highest peak at 27.2°, main peaks at 9.4°, 9.6° and 24.0°, a peak at 7.3° as the lowest angle, and with no peaks in a range between 7.3° and 9.4°, and with no peak at 26.3° as Bragg 2?angles (±0.2°) in terms of CuK-? characteristic X-ray wavelength at 1.542 ?, and the averaged primary particle size of the titanyl phthalocyanine crystal particles is 0.
    Type: Grant
    Filed: October 28, 2004
    Date of Patent: May 13, 2008
    Assignee: Ricoh Company, Ltd.
    Inventors: Nozomu Tamoto, Tatsuya Niimi, Tetsuro Suzuki, Katsuichi Ohta
  • Patent number: 7354686
    Abstract: An electrophotographic photoconductor includes an electroconductive substrate, a charge generation layer, and a charge transport layer formed by using a halogen-free solvent, arranged in this order, in which the charge generation layer contains a charge generation material having an average particle diameter smaller than a surface roughness of a plane where the electroconductive substrate is arranged, and a polyvinyl acetal resin having a ratio Mw/Mn of a weight-average molecular weight Mw to a number-average molecular weight Mn is 2.2 or more.
    Type: Grant
    Filed: March 19, 2004
    Date of Patent: April 8, 2008
    Assignee: Ricoh Company, Ltd.
    Inventors: Naohiro Toda, Tatsuya Niimi, Ryohichi Kitajima, Yoshiaki Kawasaki
  • Publication number: 20080057428
    Abstract: A photoconductor containing an optional supporting substrate, a photogenerating layer thereover, and at least one charge transport layer, and wherein the photogenerating layer contains a chelating agent, and a Type V titanyl phthalocyanine prepared, for example, by dissolving a Type I titanyl phthalocyanine in a solution comprising a trihaloacetic acid and an alkylene halide; adding the mixture comprising the dissolved Type I titanyl phthalocyanine to a solution comprising an alcohol and an alkylene halide thereby precipitating a Type Y titanyl phthalocyanine; and treating the Type Y titanyl phthalocyanine with a monohalobenzene.
    Type: Application
    Filed: August 30, 2006
    Publication date: March 6, 2008
    Inventors: Jin Wu, John S. Chambers, Francisco J. Lopez, Daniel V. Levy, Liang-Bih Lin
  • Publication number: 20080057422
    Abstract: A photoconductor containing an optional supporting substrate; a photogenerating layer comprised of a chelating agent and a titanyl phthalocyanine; and at least one charge transport layer comprised of at least one charge transport component, and wherein a silanol is present in at least one of said photogenerating layer and charge transport layer.
    Type: Application
    Filed: August 30, 2006
    Publication date: March 6, 2008
    Inventors: Jin Wu, Michael A. Morgan, Anthony M. Horgan, Liang-Bih Lin
  • Publication number: 20080057423
    Abstract: A photoconductor containing an optional supporting substrate, a photogenerating layer comprised of a chelating agent and a titanyl phthalocyanine; and at least one charge transport layer comprised of at least one charge transport component; and wherein a silanol is present in at least one of the photogenerating layer and charge transport layer, and wherein said at least one charge transport component is comprised of wherein X and Y are independently a suitable hydrocarbon, a halogen, or mixtures thereof.
    Type: Application
    Filed: August 30, 2006
    Publication date: March 6, 2008
    Inventors: Jin Wu, John F. Yanus, Anthony M. Horgan, Liang-Bih Lin
  • Publication number: 20080057426
    Abstract: A photoconductor containing a photogenerating layer, at least one charge transport layer, and a layer in contact with the charge transport layer comprised of a suitable polymer, and wherein the charge transport layer comprises molecules of the formula/structure wherein X represents alkyl.
    Type: Application
    Filed: August 30, 2006
    Publication date: March 6, 2008
    Inventors: Gregory McGuire, Jennifer A. Coggan, Johann Junginger, Nan-Xing Hu, Ah-Mee Hor