Fogged Direct Positive Patents (Class 430/596)
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Publication number: 20030148233Abstract: A radiation sensitive imaging element is described comprising a support bearing one or more hydrophilic colloid layers, wherein a photographically useful compound is incorporated into at least one hydrophilic colloid layer in the form of a self-assembled composition comprising a substantially homogeneous and ordered array of the photographically useful compound and silver and halide atoms, wherein the average minimum distance from each Ag atom in the composition to an atom of the photographically useful compound in the composition is less than 50 Å.Type: ApplicationFiled: December 21, 2001Publication date: August 7, 2003Applicant: Eastman Kodak CompanyInventors: Joseph F. Bringley, Manju Rajeswaran
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Publication number: 20030129549Abstract: A direct positive silver halide photographic light-sensitive material is used for forming a light-absorbing layer of a lenticular lens sheet that includes a film-form substrate and a plurality of light input lenses provided on a light input side of the substrate, the light absorbing layer (black stripes) being provided on a light output side of the substrate in a region other than a condensing region of each of the light input lenses, the silver halide photographic light-sensitive material including a support, and at least one light-sensitive layer having light-sensitive silver halide grains with a grain size of 1 &mgr;m or less at a silver coat weight of 1.5 g/m2 or more on one side of the support, wherein on the side of the support opposite the light-sensitive layer there is no light absorbing layer, and by developing after exposing, from the side opposite the light-sensitive layer via the light input lenses, the light absorbing layer is formed based on a silver image.Type: ApplicationFiled: November 14, 2002Publication date: July 10, 2003Inventors: Junji Miyata, Kenichi Yasuda, Yasufumi Morimoto, Kumpei Oda, Masashi Nishiyama
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Patent number: 6376164Abstract: A silver halide color reversal lightsensitive material comprising a transparent support and, superimposed thereon, a blue-sensitive emulsion layer unit, a green-sensitive emulsion layer unit and a red-sensitive emulsion layer unit, each of these units comprising at least two emulsion sub-layers having the same color sensitivity but different speeds from each other, wherein the material contains a yellow dye in an amount of 0.15 to 1.0 g/m2 and satisfies the relationship: 0.9≦&ggr;′/&ggr;≦1.25 wherein &ggr; and &ggr;′ each represent a point-gamma value of a portion of the material giving a magenta density of 1.Type: GrantFiled: October 20, 2000Date of Patent: April 23, 2002Assignee: Fuji Photo Film Co., Ltd.Inventors: Nobuyuki Haraguchi, Katsuro Nagaoka
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Patent number: 6261750Abstract: A silver halide color light-sensitive material contains at least one light-sensitive silver halide emulsion layer and at least one non-light-sensitive layer on a support, wherein at least one of the non-light-sensitive layers contains a silver halide emulsion having a previously fogged surface, and the non-light-sensitive layer containing the previously fogged emulsion and/or its adjacent layer contains a compound capable of releasing a photographically useful group or its precursor by a coupling reaction with the oxidized form of a developing agent, wherein the previously fogged emulsion is developed during color development to evenly form the oxidized form of a color developing agent, and the photographically useful group or its precursor is released non-imagewise by the coupling reaction.Type: GrantFiled: March 31, 2000Date of Patent: July 17, 2001Assignee: Fuji Photo Film Co., Ltd.Inventors: Yoshio Ishii, Takayuki Ito, Fumitaka Ueda, Hiroyuki Yoneyama
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Patent number: 6187527Abstract: A silver halide color reversal lightsensitive material comprising a transparent support and, superimposed thereon, a blue-sensitive emulsion layer unit, a green-sensitive emulsion layer unit and a red-sensitive emulsion layer unit, each of these units comprising at least two emulsion sub-layers having the same color sensitivity but different speeds from each other, wherein the material contains a yellow dye in an amount of 0.15 to 1.0 g/m2 and satisfies the relationship: 0.9≦&ggr;′/&ggr;≦1.25 wherein &ggr; and &ggr;′ each represent a point-gamma value of a portion of the material giving a magenta density of 1.Type: GrantFiled: February 14, 2000Date of Patent: February 13, 2001Assignee: Fuji Photo Film Co., Ltd.Inventors: Nobuyuki Haraguchi, Katsuro Nagaoka
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Patent number: 6165662Abstract: An electrophotographic photoreceptor having a photosensitive layer containing a binder resin on an electroconductive substrate, wherein at least a part of the binder resin in the photosensitive layer is a polycarbonate resin having a structure of the following formula (1) as main repeating units and a structure of the following formula (2) at one or each terminal and having a viscosity-average molecular weight of from 10,000 to 300,000: ##STR1## where, in the formula (1), each of Y.sup.1 to Y.sup.8 which are independent of one another, is a hydrogen atom, a C.sub.1-10 saturated aliphatic hydrocarbon group, a C.sub.3-10 unsaturated aliphatic hydrocarbon group, a halogen atom, a halogenated alkyl group, a C.sub.1-10 alkoxy group or a C.sub.6-20 aromatic hydrocarbon group which may be substituted, X.sup.1 is ##STR2## an aromatic ring, a single bond, a lactone or fluorene, each of R.sup.1 to R.sup.7 which are independent of one another, is a hydrogen atom, a C.sub.Type: GrantFiled: December 1, 1999Date of Patent: December 26, 2000Assignee: Mitsubishi Chemical CorporationInventors: Satoshi Kato, Itaru Ogawa
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Patent number: 6139999Abstract: An electrophotographic imaging member includingat least one photographic imaging layer anda partially electrically conductive overcoat layer includingfinely divided charge injection enabling particles dispersed ina charge transporting continuous matrix including a cross linked polyamide, charge transport molecules and oxidized charge transport molecules, the continuous matrix being formed from a solution selected from the group includinga first solution includingcrosslinkable alcohol soluble polyamide containing methoxy methyl groups attached to amide nitrogen atoms,an acid having a pK.sub.Type: GrantFiled: October 28, 1999Date of Patent: October 31, 2000Assignee: Xerox CorporationInventors: Timothy J. Fuller, Damodar M. Pai, John F. Yanus, Paul J. DeFeo, Anthony T. Ward, Dale S. Renfer, Harold F. Hammond, Merlin E. Scharfe, Markus R. Silvestri, William W. Limburg
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Patent number: 6127077Abstract: A photoreceptor having a substrate, including: (a) a charge generating layer; (b) a first charge transport layer having a first charge carrier mobility value; and (c) a second charge transport layer having a second charge carrier mobility value, wherein the first charge transport layer is closer to the charge generating layer than the second charge transport layer and the second charge transport layer is contiguous to the first charge transport layer, wherein the second charge carrier mobility value is higher than the first charge carrier mobility value.Type: GrantFiled: September 14, 1998Date of Patent: October 3, 2000Assignee: Xerox CorporationInventors: Damodar M. Pai, Chu-Heng Liu, John F. Yanus, Timothy J. Fuller, Markus R. Silvestri
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Patent number: 6114104Abstract: A direct positive silver halide photographic light sensitive material is disclosed, having yellow, magenta and cyan image forming units, wherein at least one of the color image forming units contains at least two internal latent image forming silver halide emulsions which are different in a factor of contribution to image formation, a silver halide emulsion having a lower factor of contribution to image formation having a part common to sensitivity of a silver silver halide emulsion contained in one of the other two image forming units, and the photographic material is subjected to exposure, based on digitized image information.Type: GrantFiled: September 2, 1999Date of Patent: September 5, 2000Assignee: Konica CorporationInventors: Satoshi Masumi, Shigeo Tanaka
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Patent number: 6099998Abstract: An electrophotographic photoreceptor is disclosed. The topmost layer comprises a binder comprising a crosslinked resin having, as a recurring unit, (a) a portion comprising a constituent having a fluorine or silicon atom at the side chain, (b) a portion having an aromatic group in the main or side chain, and (c) a portion having a hydroxyl group or an amino group.Type: GrantFiled: July 16, 1998Date of Patent: August 8, 2000Assignee: Konica CorporationInventors: Toyoko Shibata, Akira Kinoshita, Tomoo Sakimura
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Patent number: 6071659Abstract: An electrophotographic imaging member includinga substrate,a charge generating layer,a charge transport layer, andan overcoat layer includinga hole transporting hydroxy arylamine compound having at least two hydroxy functional groups,bis-(2-methyl-4-diethylaminophenyl)-phenylmethane anda cross linked polyamide film forming binder.A process for forming an overcoated imaging member is also disclosed.Type: GrantFiled: December 22, 1998Date of Patent: June 6, 2000Assignee: Xerox CorporationInventors: Dale S. Renfer, Damodar M. Pai, Paul J. DeFeo, John F. Yanus, William W. Limburg, Timothy J. Fuller
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Patent number: 6071660Abstract: A photoconductor for use in electrophotographic reproduction devices is disclosed. This photoconductor exhibits dramatically reduced end seal and paper area wear, as well as reduced positive electrical fatigue. The photoconductor of the present invention includes a low surface energy polyolefin wax, such as polyethylene or polypropylene, in relatively large particulate form having a mean particle diameter of from about 6 to about 12.mu., homogeneously dispersed in its charge transport layer.Type: GrantFiled: March 12, 1999Date of Patent: June 6, 2000Assignee: Lexmark International, Inc.Inventors: David Glenn Black, Gregory Walter Haggquist, Dat Quoc Nguyen
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Patent number: 6040098Abstract: Charge generation layers comprising a binder and a charge generation compound, wherein the binder comprises a blend of methyl bisphenol A and an additional resin comprising an epoxy resin, a poly(phenylglycidyl ether)-co-dicyclopentadiene resin, a phenoxy resin or a polyhydroxystyrene resin. Dual layer photoconductors comprise the charge generation layer in combination with a substrate and a charge transport layer.Type: GrantFiled: November 20, 1998Date of Patent: March 21, 2000Assignee: Lexmark International, Inc.Inventors: David Glenn Black, Garry Dale Hinch, Dat Quoc Nguyen, Kasturi Rangan Srinivasan
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Patent number: 6033833Abstract: A new fogging photographic processing solution for a reversal process comprises a compound (I) and a bi-nucleophilic agent. Compound (I) corresponds to the following formula: ##STR1## wherein A is a group capable of being adsorbed to the silver halide surface, L is a linking group and r is 0 or 1, R.sub.1 and R.sub.2 are independently selected from an alkyl group, substituted or unsubstituted, and an aryl group substituted or unsubstituted. A process of producing a positive image by imagewise exposure of a reversal silver halide material comprises contacting the material with the above fogging solution or by imagewise exposure of such a material containing a compound (I) and contacting the material with a solution comprising a bi-nucleophilic agent.Type: GrantFiled: April 29, 1999Date of Patent: March 7, 2000Assignee: Eastman Kodak CompanyInventors: Siu C. Tsoi, Peter J. Twist, David T. Southby
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Patent number: 6030736Abstract: An electrophotographic photoconductor is provided which includes a photoconductive layer formed overlying an electroconductive substrate, wherein the photoconductor includes in a top layer thereof a polysiloxane mixture selected from the group consisting of a polysiloxane mixture of an unmodified polysiloxane compound and a modified polysiloxane compound, a mixture of a methacryl modified polysiloxane compound and an alkyl modified polysiloxane compound, a mixture of a methacryl modified polysiloxane compound and a vinyl modified polysiloxane compound, and a mixture of an alkyl modified polysiloxane compound and a vinyl modified polysiloxane compound. The photoconductor has good durability.Type: GrantFiled: March 30, 1998Date of Patent: February 29, 2000Assignee: Ricoh Company, Ltd.Inventors: Takaaki Ikegami, Yasuo Suzuki, Hiroshi Nakai, Nozomu Tamoto, Koji Kishida
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Patent number: 6017666Abstract: A charge generating composition comprising: a hydroxygallium phthalocyanine an alkoxy-bridged metallophthalocyanine dimer, and a polymer matrix comprised of a reaction product copolymerized from reactants including a vinyl chloride monomer, a vinyl acetate monomer, and a hydroxyalkyl acrylate monomer.Type: GrantFiled: October 14, 1998Date of Patent: January 25, 2000Assignee: Xerox CorporationInventors: Richard H. Nealey, Kenny T. T. Dinh, John G. Matta
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Patent number: 6004709Abstract: An allyloxymethylatedpolyamide composition is disclosed, the allyloxymethylatedpolyamide being represented by Formulae I and II: ##STR1## wherein: n is a positive integer sufficient to achieve a weight average molecular weight between about 5000 and about 100,000,R is an alkylene unit containing from 1 to 10 carbon atoms,between 1 and 99 percent of the R.sub.2 sites are --H, andbetween 1 and 99 percent of the R.sub.2 sites are --H, and the remainder of the R.sub.2 sites is between 25 percent and 99 percent --CH.sub.2 --O--(CH.sub.2).sub.w --CH.dbd.CH.sub.2, whereinw is 1, 2 or 3,between 1 and 75 percent of the R.sub.2 sites are --CH.sub.2 --O--R.sub.5, andR.sub.5 is an alkyl unit containing 1 to 4 carbon atoms, and ##STR2## wherein: m is a positive integer sufficient to achieve a weight average molecular weight between about 5000 and about 100,000,R.sub.1 and R are independently selected from the group consisting of alkylene units containing from 1 to 10 carbon atoms,between 1 and 99 percent of the R.sub.Type: GrantFiled: December 22, 1998Date of Patent: December 21, 1999Assignee: Xerox CorporationInventors: Dale S. Renfer, William W. Limburg, Timothy J. Fuller, John F. Yanus, Damodar M. Pai, Robert W. Nolley, Paul J. DeFeo, Anthony T. Ward
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Patent number: 5994014Abstract: An electrophotographic photoconductor containing an aromatic polycarbonate binder resin and silicone microspheres provides improved wear resistance, increased useful life of the photoconductive drum, a high quality image over the life of the photoconductor, and improved coating uniformity.Type: GrantFiled: February 17, 1998Date of Patent: November 30, 1999Assignee: Lexmark International, Inc.Inventors: Garry Dale Hinch, Paul Dwight Kemmesat, Laura Lee Kierstein, Michael Thomas Moore, Michael George Sloan, Karin Ann Voll, Eric Lawrence Ziercher
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Patent number: 5874207Abstract: A direct-positive silver halide light-sensitive material comprising a support having thereon at least one pre-fogged light-sensitive silver halide emulsion layer, wherein the light-sensitive material comprises a specific onium salt compound in the emulsion layer or a hydrophilic protective colloid layer adjacent thereto. Also disclosed is a method of preparing a pre-fogged light-sensitive silver halide emulsion for use in the light-sensitive material.Type: GrantFiled: May 16, 1997Date of Patent: February 23, 1999Assignee: Fuji Photo Film Co., Ltd.Inventors: Isao Oyagi, Shingo Nishiyama, Nobuaki Inoue
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Patent number: 5747237Abstract: A silver halide photographic material comprising a support having at least one pre-fogged direct positive emulsion layer provided on at least one side of the support, wherein silver halide grain formation of the emulsion is carried out in the presence of a silver halide solvent, the emulsion contains at least one of an Rh salt, an Ru salt or a polybromoiridium salt, and at least one compound selected from the group consisting of compounds represented by the following formula (I), (II) and (III) is added to the emulsion while the silver halide photographic material is prepared:R--SO.sub.2 S--M (I)R--SO.sub.2 S--R.sup.1 (II)R--SO.sub.2 S--L.sub.m --SSO.sub.2 --R.sup.2 (III)wherein R, R.sup.1 and R.sup.2 are the same or different, and each represents an aliphatic group, an aromatic group or a heterocyclic group; M represents a cation; L represents a divalent linking group; and m represents 0 or 1.Type: GrantFiled: May 15, 1996Date of Patent: May 5, 1998Assignee: Fuji Photo Film Co., Ltd.Inventors: Shinichiro Fukui, Koichi Kuno
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Patent number: 5719019Abstract: Room-light handleable direct silver halide emulsions exhibit a broadened Dmin window when certain nitro-substituted aryl- or heteroaryl-containing imidazoles are included. These imidazoles act as excellent rereversal and Dmin suppressants. Photographic elements are prepared from these emulsions that can be handled in room-light if desired.Type: GrantFiled: July 31, 1996Date of Patent: February 17, 1998Assignee: Eastman Kodak CompanyInventors: Gaile Antoinette Janusonis, Roger Lok
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Patent number: 5563027Abstract: A color reversal element having a red sensitive layer containing a cyan dye forming coupler, a green sensitive layer containing a magenta dye forming coupler, and a blue sensitive layer containing a yellow dye forming coupler, the red, green and blue sensitive layers each having a speed .gtoreq.120 as measured at a density of 0.3, a Dmax of .gtoreq.3.30 and a .increment.logE .ltoreq.1.85 measured from a density of 0.20 to 3.20, the Dmax and .increment.logE being measured following exposure and processing of the element. Daylight and tungsten balanced versions of the film are also provided. A method for processing such films and exposing them in electronic film writers is also provided. Film of the present invention allows a wide range of density values in an original film to be more faithfully reproduced and enable more faithful reproduction of colors recorded in the original scanned film.Type: GrantFiled: January 17, 1995Date of Patent: October 8, 1996Assignee: Eastman Kodak CompanyInventors: Cheryl S. Johnston, John D. Baloga
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Patent number: 5534402Abstract: A direct-positive silver halide photographic material is disclosed, which comprises a support having thereon at least one prefogged light-sensitive silver halide emulsion layer, wherein said silver halide emulsion is an emulsion which has been previously fogged with a gold compound and a tellurium compound.Type: GrantFiled: December 13, 1994Date of Patent: July 9, 1996Assignee: Fuji Photo Film Co., Ltd.Inventors: Koichi Kuno, Hiroyuki Mifune
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Patent number: 5523197Abstract: In order to provide a direct-positive material having low contrast and extended latitude that can be manufactured in a consistent and reproducable way a multilayer direct-positive photographic material is disclosed as well as the process to provide it, characterized by the steps of coating on one side of a support at least two layers of direct positive silver halide emulsions of the externally fogged type, at least one layer of which comprises a mixture of direct positive silver halide emulsions of the externally fogged type and at least one layer of which comprises one or more filter dyes; overcoating said emulsion layers with at least one protective layer; coating on the other side of the support at least one backing layer.Type: GrantFiled: April 12, 1995Date of Patent: June 4, 1996Assignee: Agfa-Gevaert, N.V.Inventor: Luc Heremans
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Patent number: 5501946Abstract: A pre-fogged direct reversal silver halide photographic material comprises on a support at least an emulsion layer comprising a previously fogged silver halide emulsion for forming a direct positive image.Type: GrantFiled: July 27, 1994Date of Patent: March 26, 1996Assignee: Fuji Photo Film Co., Ltd.Inventors: Yoshihiro Takagi, Yoshio Inagaki
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Patent number: 5501939Abstract: The present invention provides a photographic material with a pH at 25.degree. C. of at most 7, containing on a support at least one layer, comprising a prefogged direct-positive silver halide emulsion spectrally sensitized with one or more electron-accepting sensitizing dyes in a total amount of at least 0.15 mmole/mole silver halide, the silver halide crystals of said prefogged direct-positive silver halide emulsion containing silver chloride for at least 60 mole %, silver bromide in a range from 0.5 mole % to 39.98 mole % and silver iodide in a range from 0.02 mole % to 2 mole %, characterized in that said silver halide cristals contain silver iodide for at least 0.20 mmole/mole AgX in the outer 10% by weight of said cristals and said layer contains a gelatin species containing Ca.sup.2+ in an amount ranging from 0.2% to 1% by weight.Type: GrantFiled: June 13, 1995Date of Patent: March 26, 1996Assignee: AGFA-Gevaert, N.V.Inventors: Ludo Van Rompuy, Paul Coppens
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Patent number: 5492797Abstract: Disclosed is a direct positive silver halide color photographic light-sensitive material comprising a support and provided thereon, a blue-sensitive emulsion layer containing previously unfogged internal latent image-forming silver halide grains having a spectral sensitivity to blue-light, a green-sensitive emulsion layer containing previously unfogged internal latent image-forming silver halide grains having a spectral sensitivity to green-light, a red-sensitive emulsion layer containing previously unfogged internal latent image-forming silver halide grains having a spectral sensitivity to red-light and a hydrophilic colloidal layer, wherein said blue-sensitive emulsion layer is provided so as to be located farther than both said green-sensitive and said red-sensitive emulsion layers from the support; and at least one of said blue-sensitive emulsion layer, said-green sensitive emulsion layer and said red-sensitive emulsion layer or said hydrophilic colloidal layer contains an internal latent image forming siType: GrantFiled: July 22, 1994Date of Patent: February 20, 1996Assignee: Konica CorporationInventors: Yasuo Tosaka, Masayuki Sasagawa
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Patent number: 5491058Abstract: A film is disclosed for duplicating a silver image in a radiographic film. A single monodispersed fogged direct-positive emulsion layer is employed. To extend exposure latitude the emulsion layer contains micro-crystalline particles of a dye that competes with the fogged direct positive grains of the emulsion layer for absorption of exposing radiation and can be decolorized during photographic processing.Type: GrantFiled: June 28, 1995Date of Patent: February 13, 1996Assignee: Eastman Kodak CompanyInventors: Ralph W. Jones, Catherine C. Wideman, Paul W. Twombly
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Patent number: 5437968Abstract: A silver halide color photograph light-sensitive material having an improved push-processing suitability. The material comprises a support having provided thereon at least one blue-sensitive emulsion layer, at least one green-sensitive emulsion layer, and at least one red-sensitive emulsion layer. The layers adjacent to each of layer having a color sensitivity contain yellow colloidal silver.Type: GrantFiled: October 14, 1994Date of Patent: August 1, 1995Assignee: Fuji Photo Film Co., Ltd.Inventor: Katsurou Nagaoka
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Patent number: 5362621Abstract: A direct positive silver halide photographic material and a method for forming a high contrast image using the same are disclosed, in which a pre-fogged direct positive silver halide emulsion layer contains a salt of a nitrogen-containing compound having at least one pyridine nucleus and at least one pyridinium nucleus. The photographic material, after imagewise exposure, is developed with an alkaline developer containing a developing agent, preferably a reductance compound. The photographic material provides high contrast characteristics having a gamma exceeding 10.Type: GrantFiled: August 18, 1993Date of Patent: November 8, 1994Assignee: Dainippon Ink and Chemicals, Inc.Inventors: Naoki Obi, Kiyoshi Suematsu, Yasuhiko Kojima, Masatoshi Katayama, Yasuo Shigemitsu
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Patent number: 5326683Abstract: A silver halide photographic material comprising a support having thereon a previously fogged silver halide emulsion layer and a light-sensitive silver halide emulsion layer comprising at least one silver halide, wherein at least one of said previously fogged silver halide emulsion layer and a hydrophilic colloid layer adjacent thereto contains at least one hydrazine nucleating agent and at least one of said light-sensitive silver halide emulsion layer and a hydrophilic colloid layer adjacent thereto contains at least one redox compound capable of releasing a development restrainer when oxidized, and wherein said nucleating agent and said redox compound are contained in different layers.Type: GrantFiled: March 30, 1993Date of Patent: July 5, 1994Assignee: Fuji Photo Film Co., Ltd.Inventor: Kazunobu Katoh
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Patent number: 5314799Abstract: There is disclosed a method for preparing a direct reversal type silver halide light-sensitive emulsion which is used for a black-and-white light-sensitive material and has the improved photographic performances of a high sensitivity and a high contrast. The method comprises:A method for preparing a fogging type direct positive silver halide emulsion comprising the steps of:(a) forming an emulsion containing silver halide grains;(b) fogging surfaces of the grains with a reducing agent to form a silver nuclei; and then(c) performing at least one of an adjustment of pH of the emulsion to 4.5 or less and an adjustment of pAg of the emulsion to 8.1 or more.Type: GrantFiled: April 7, 1993Date of Patent: May 24, 1994Assignee: Fuji Photo Film Co., Ltd.Inventor: Yoshihiro Takagi
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Patent number: 5298381Abstract: A direct positive type silver halide photographic light-sensitive material is disclosed, having improved safelight stability and which is capable of providing an image having excellent photographic properties. The light-sensitive material comprises a support having thereon at least one pre-fogged light-sensitive silver halide emulsion layer and at least one light-insensitive hydrophilic colloid layer provided farther from the support than the light-sensitive silver halide emulsion layer. The light-insensitive hydrophilic colloid layer contains a dye dispersed therein in the form of microcrystalline particles.Type: GrantFiled: March 5, 1992Date of Patent: March 29, 1994Assignee: Fuji Photo Film Co., Ltd.Inventors: Nobuaki Inoue, Takahiro Goto
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Patent number: 5248588Abstract: Disclosed is a silver halide photographic material, comprising a support having thereon (i) a silver halide emulsion layer which contains negative-working internal latent image-forming silver halide grains which have been chemically sensitized to a depth of less than 0.02 micrometer from the surface of the grain, and (ii) palladium in an amount from 1.times.10.sup.-9 to 1.times.10.sup.-2 mol per mol of coated silver halide.Type: GrantFiled: May 22, 1991Date of Patent: September 28, 1993Assignee: Fuji Photo Film Co., Ltd.Inventor: Katsuro Nagaoka
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Patent number: 5240828Abstract: Room light handleable direct reversal silver bromide emulsions, with up to 70 mole percent chloride, have a broad Dmin window when from 1.times.10.sup.-6 to 1.times.10.sup.-4 mole per silver mole of a polybromo coordination complex of iridium is incorporated in the silver halide grains. The emulsions are stabilized against deterioration on keeping with mercapto compounds.Type: GrantFiled: September 10, 1990Date of Patent: August 31, 1993Assignee: Eastman Kodak CompanyInventors: Gaile A. Janusonis, Francis R. Hilton, Jr., Richard D. Lucitte, Woodrow G. McDugle, Roger Lok, David Erdtmann
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Patent number: 5221601Abstract: UV sensitive direct positive silver halide photographic material for duplicating processes which can be safely handled under roomlight conditions, said material comprising a support having thereon at least one silver halide emulsion layer comprising a prefogged direct positive silver halide emulsion, preferably one having a chloride content of at least 70 mole % and comprising internal electron traps, said emulsion layer or a hydrophilic colloid layer in water-permeable relationship to said emulsion layer containing at least one nitro-substitued indazole or benzimidazole derivative and at least one non-nitro-substituted indazole or benzimidazole derivative.Type: GrantFiled: September 16, 1991Date of Patent: June 22, 1993Assignee: Agfa-Gevaert, N.V.Inventors: Marc B. Graindourze, Marc H. Van Bockstaele
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Patent number: 5206132Abstract: A direct positive silver halide photographic light-sensitive material which is improved in gradation and suitable for rapid processing comprises a support having thereon a silver halide emulsion layer containing surface-fogged type direct positive silver halide grains, wherein said direct positive silver halide emulsion layer comprises two or more silver halide emulsions substantially different in sensitivity and/or gradation; the ratio of the total area of (111) face to and total surface area of grains in said emulsions is not less than 50%; and the average silver iodide content of grains in said emulsions is not more than 5 mol%.Type: GrantFiled: May 3, 1991Date of Patent: April 27, 1993Assignee: Konica CorporationInventor: Tsuyoshi Mitsuhashi
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Patent number: 5185240Abstract: Disclosed is an autopositive silver halide photographic material which comprises at least one silver halide emulsion layer, characterized in that said emulsion layer or at least one other hydrophilic colloid layers contains at least one compound selected from the group consisting of compounds represented by the following general formulas (1), (2) and (3): ##STR1## wherein R.sub.1 represents hydrogen atom or an alkyl group; and R.sub.2, R.sub.3 and R.sub.4 each represents hydrogen atom, a halogen atom, an alkyl group or an alkoxy group; ##STR2## wherein R.sub.5 represents hydrogen atom or an alkyl group; and R.sub.6 and R.sub.7 each represents hydrogen atom, an alkyl group, a halogen atom or an aryl group; ##STR3## wherein R.sub.8 represents a lower alkylene group; X represents a halogen atom, nitro group, hydroxy group, a cyano group, a lower alkyl group, a lower alkoxy group, ##STR4## or --SO.sub.3 M; R.sub.12 represents hydrogen atom, --OM, a lower alkyl group, a lower alkoxy group or ##STR5## R.sub.Type: GrantFiled: August 10, 1990Date of Patent: February 9, 1993Assignee: Fuji Photo Film Co., Ltd.Inventors: Junji Miyata, Satoshi Kanetake, Yasufumi Morimoto, Kenji Hanayama
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Patent number: 5183733Abstract: Disclosed are silver halide photographic materials, comprising a support having thereon a layer which contains a compound represented by the following general formula (I): ##STR1## wherein A.sub.1 and A.sub.2 each represents groups of atoms which are required to complete aromatic rings, which may be substituted or unsubstituted; R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each independently represents a hydrogen atom, an alkyl group, an alkenyl group, a phenyl group, a five- or six-membered heterocyclic group, an acyl group or an alkoxy group, which may be substituted or unsubstituted; R.sub.5 and R.sub.6 each independently represents an alkyl group, a phenyl group or a five- or six-membered heterocyclic group, which may be substituted or unsubstituted; X represents a p-valent anion; p represents 1, 2 or 3; L represents a methine group which may be substituted or unsubstituted, or a trivalent linking group wherein three, five or seven methine groups are linked by conjugated double bonds; and X may be bonded to A.Type: GrantFiled: June 28, 1991Date of Patent: February 2, 1993Assignee: Fuji Photo Film Co., Ltd.Inventors: Yoshio Inagaki, Tadashi Ikeda
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Patent number: 5166043Abstract: Photographic light-sensitive silver halide material for forming direct-positive images comprising a support, a light-sensitive emulsion layer comprising unfogged internal latent image-type silver halide grains dispersed in a hydrophilic colloid binder and comprising a development nucleator, and at least one protective hydrophilic colloid layer, wherein said light-sensitive emulsion comprises at least one compound that during the development of said material in a surface developer provides iodide ions, the weight ratio of the hydrophilic colloid binder of said emulsion layer to silver halide expressed as silver nitrate ranging from 0.4:1 to 3:1, and said protective hydrophilic colloid layer having a thickness in dry state of 1 to 3 .mu.m. The present invention also relates to a method for making direct-positive images with such a photographic light-sensitive silver halide material.Type: GrantFiled: July 19, 1991Date of Patent: November 24, 1992Assignee: Agfa-Gevaert, N.V.Inventor: Jozef P. De Prijcker
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Patent number: 5147754Abstract: A silver halide photographic material which provides a negative image contains a compound represented by formula (I): ##STR1## wherein R represents an aliphatic group, an aromatic group, or a heterocyclic group; Z represents a development inhibitor group containing an anionic functional group as a partial structure; "Time" represents a divalent group; and n is 0 or 1.Type: GrantFiled: August 7, 1991Date of Patent: September 15, 1992Assignee: Fuji Photo Film Co., Ltd.Inventors: Hisashi Okamura, Hisashi Okada, Morio Yagihara, Kazunobu Katoh
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Patent number: 5112732Abstract: A direct positive silver halide photographic material is disclosed, comprising a support having thereon at least one internal latent image silver halide emulsion layer which has not been prefogged and another hydrophilic colloid layer wherein the grains in the internal latent image silver halide emulsion is formed in the presence of an iron complex compound. The direct positive silver halide photographic material is developed and then direct positive images may be obtained with this material, which feature a high D.sub.max and a low D.sub.min. The disclosed material has a broad range of applications, including as a COM film.Type: GrantFiled: March 28, 1990Date of Patent: May 12, 1992Assignee: Fuji Photo Film Co., Ltd.Inventors: Kazunori Hayashi, deceased, Masahiro Hayashi, heir, Masako Hayashi, heir
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Patent number: 5100761Abstract: A silver halide photographic material comprising one or more silver halide emulsion layers and hydrophilic colloid layers, wherein at least one of the layers contains an acylhydrazine compound as described below. The instant photographic materials have high contrast negative-gradation or positive-gradation characteristics, high maximum image density, excellent reversal characteristics and long-term storage stability.Type: GrantFiled: March 21, 1988Date of Patent: March 31, 1992Assignee: Fuji Photo Film Co., Ltd.Inventors: Morio Yagihara, Hisashi Okada, Kazunobu Katoh, Noriyuki Inoue, Shingo Nishiyama, Tetunori Matushita
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Direct positive silver halide photographic light-sensitive material and a processing method therefor
Patent number: 5049483Abstract: There is disclosed a direct positive silver halide light-sensitive material which can be processed in ultra-rapid processing and have a higher sensitivity, a lower Dmin, an excellent antistatic property and less flactuation of the properties in storing. The light-sensitive material contains an electron-accepting compound in a silver halide emulsion layer, and a fluorinated surfactant and/or at least one of the compounds represented by Formulas I-a to II-b in a photographic component layer: ##STR1## wherein R.sub.1 to R.sub.4 represent independently a hydrogen atom, a lower alkyl group, an alkoxy group, a carboxy group, an alkoxycarbonyl group, a sulfo group, a halogen atom, and a nitro group, provided that at least one of R.sub.1 and R.sub.2 is a carboxy group, an alkoxycarbonyl group or a sulfo group.Type: GrantFiled: June 4, 1990Date of Patent: September 17, 1991Assignee: Konica CorporationInventors: Naoko Yatsuyanagi, Tsuyoshi Mitsuhashi -
Patent number: 5043259Abstract: A pre-fogged direct positive silver halide emulsion comprising silver halide grains which have been formed in the presence of a compound represented by the following formula (I):R--SO.sub.2 --M (I)wherein R represents an aliphatic group, an aromatic group or a heterocyclic group, and M represents a hydrogen atom or a cation. The invention also relates to a method for making such a photographic material.Type: GrantFiled: May 24, 1990Date of Patent: August 27, 1991Assignee: Fuji Photo Film Co., Ltd.Inventor: Naoki Arai
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Patent number: 5037732Abstract: Photographic silver halide emulsions are disclosed comprised of radiation sensitive silver halide grains exhibiting a face centered cubic crystal lattice structure internally containing a carbonyl coordination ligand and a transition metal chosen from groups 8 and 9 of the periodic table of elements.Type: GrantFiled: August 28, 1989Date of Patent: August 6, 1991Assignee: Eastman Kodak CompanyInventors: Woodrow G. McDugle, Alfred P. Marchetti, John E. Keevert, Marian S. Henry, Myra T. Olm
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Patent number: 4994364Abstract: A direct positive image forming method comprising development processing an imagewise exposed direct positive photographic light-sensitive material which comprises a support having thereon at least one layer containing internal latent image type silver halide grains not having been previously fogged after fogging treatment or while fogging treatment, wherein the fogging treatment is conducted in the presence of a compound represented by the following general formula (I): ##STR1## wherein A.sub.1 and A.sub.2 both represent a hydrogen atom or one of A.sub.1 and A.sub.2 represents a hydrogen atom and the other represents a sulfonyl group or an acyl group; G.sub.1 represents a carbonyl group, a sulfonyl group, a sulfoxy group, ##STR2## or an iminomethylene group; L.sub.1 represents a divalent linkage group; X.sub.1 represents --O-- or ##STR3## wherein R.sub.4 represents a hydrogen atom, an alkyl group or an aryl group); Y.sub.1 represents ##STR4## R.sub.1 and R.sub.Type: GrantFiled: August 15, 1989Date of Patent: February 19, 1991Assignee: Fuji Photo Film Co., Ltd.Inventors: Noriyuki Inoue, Morio Yagihara
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Patent number: 4981781Abstract: Photographic silver halide emulsions are disclosed comprised of radiation sensitive silver halide grains exhibiting a face centered cubic crystal lattice structure internally containing oxo coordination ligands and a transition metal chosen from groups 6, 7, and 8 of the periodic table of elements.Type: GrantFiled: August 28, 1989Date of Patent: January 1, 1991Assignee: Eastman Kodak CompanyInventors: Woodrow G. McDugle, John E. Keevert, Alfred P. Marchetti
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Patent number: H972Abstract: A direct positive color photosensitive material comprising an internal latent image silver halide emulsion layer which has not been prefogged, a color image-forming magenta coupler of formula (I) and a nucleation accelerator of formulae (II) and/or (III): ##STR1## wherein Za and Zb represent a ##STR2## group, R.sup.1 and R.sup.2 represent a hydrogen atom or a substituent group, X represents a hydrogen atom or a group which can be eliminated by a coupling reaction, and R.sup.1, R.sup.Type: GrantFiled: October 11, 1988Date of Patent: October 1, 1991Inventor: Noriyuki Inoue
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Patent number: H1119Abstract: Disclosed is a direct positive photographic material having an improved time-dependent storage stability. The material comprises a support having thereon at least one photographic emulsion layer containing previously non-fogged internal latent image type silver halide grains wherein the photographic emulsion layer contains at least one compound of formula (I): ##STR1## where R.sup.11 is an aryl group, R.sup.12 to R.sup.15 each are a hydrogen atom, or an aliphatic or aromatic group, and R.sup.11 to F.sup.15 may have substituent(s) and may form ring(s).Type: GrantFiled: January 18, 1991Date of Patent: December 1, 1992Assignee: Fuji Photo Film Co., Ltd.Inventor: Noriyuki Inoue