Fogging Or Nucleating Agent Containing Patents (Class 430/598)
  • Patent number: 6534226
    Abstract: This invention comprises an imaging element comprising an imaging layer having associated therewith a compound of Structure I: In the above Structure I, the substituents are as defined in the application. Such compounds have good reactivity and can by used to block photographically useful compounds such as developing agents until thermally activated under preselected conditions. Compounds according to the present invention are especially useful in color photothermographic imaging elements.
    Type: Grant
    Filed: November 20, 2000
    Date of Patent: March 18, 2003
    Assignee: Eastman Kodak Company
    Inventors: Zbyslaw R. Owczarczyk, David T. Southby, Xiqiang Yang
  • Patent number: 6521389
    Abstract: A silver halide photographic light-sensitive material, which contains at least one compound of the formula (1): Formula (1) wherein PUG represents a nitrogen-containing heterocyclic group which is bonded to the adjacent carbonyl group through a nitrogen atom, the heterocyclic group directly or indirectly has at least one nitro group as its substituent(s) and can give a pKa value of 9 to 11, ph represents a phenyl group and directly or indirectly has at least one dissociating group as its substituent(s), Z represents a substituent being capable of substitution on the benzene ring, and p is 0 to 4.
    Type: Grant
    Filed: August 10, 2001
    Date of Patent: February 18, 2003
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kohzaburoh Yamada, Masahiko Taniguchi, Takashi Hoshimiya, Hirokazu Kyota, Toshihide Ezoe, Shoji Yasuda
  • Patent number: 6506548
    Abstract: This invention relates to a silver halide photographic element comprising at least one silver halide emulsion layer and further comprising an antifoggant represented by the following Structure I: wherein R1 is an aliphatic or cyclic group, R2 and R3 are independently hydrogen or bromine as long as at least one of them is bromine, L is a divalent linking group, m and n are independently 0 or 1, and SG is a solubilizing group that has a pKa of 8 or less.
    Type: Grant
    Filed: December 11, 2001
    Date of Patent: January 14, 2003
    Assignee: Eastman Kodak Company
    Inventors: Roger L. Klaus, George J. Burgmaier, Jon N. Eikenberry, Jerzy Z. Mydlarz, Nicholas E. Grzeskowiak
  • Patent number: 6506546
    Abstract: This invention comprises an imaging element comprising an imaging layer having associated therewith a compound of Structure I: wherein PUG is a photographically useful group; LINK 1 and LINK 2 are linking groups; TIME is a timing group; T represents t independently selected substituted or unsubstituted alkyl or aryl groups, t is 0, 1, or 2 and if t is 2, the T groups can form a ring; HET is a heterocyclic group which optionally can form a ring with a T group; R12 is hydrogen, substituted or unsubstituted alkyl or substituted or unsubstituted aryl, or R12 can form a ring with a T group or with HET; 1 is 0 or 1; m is 0, 1, or 2; and n is 0 or 1.
    Type: Grant
    Filed: December 30, 1999
    Date of Patent: January 14, 2003
    Assignee: Eastman Kodak Company
    Inventors: Zbyslaw R. Owozarczyk, Xiqiang Yang, David T. Southby
  • Publication number: 20030008251
    Abstract: Disclosed is a photothermographic material containing a non-photosensitive silver salt, a photosensitive silver halide and a binder on a support, which comprises a nucleating agent and a surfactant represented by the following formula (F):
    Type: Application
    Filed: September 26, 2001
    Publication date: January 9, 2003
    Inventor: Tetsuo Yamaguchi
  • Patent number: 6489088
    Abstract: A color diffusion-transfer photographic light-sensitive material provided with at least two light-sensitive silver halide emulsion layers, each of which is combined with a non-diffusive dye image forming compound forming or releasing a diffusive dye or its precursor in relation to silver development, or with a dye image forming compound whose diffusibility changes in relation to silver development, on a support, the light-sensitive material comprises a specific hydrazine compound and a specific compound improved in storability.
    Type: Grant
    Filed: March 14, 2001
    Date of Patent: December 3, 2002
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Nobutaka Fukagawa, Shinichi Ichikawa, Masaru Yoshikawa
  • Publication number: 20020177090
    Abstract: The present invention provides a photothermographic material having an image-forming layer that contains a non-photosensitive silver salt of an organic acid, a photosensitive silver halide, a specific nucleating agent, a compound represented by the formula (1) and a binder on at least one side of a support: 1
    Type: Application
    Filed: January 16, 2002
    Publication date: November 28, 2002
    Inventor: Makoto Ishihara
  • Publication number: 20020155401
    Abstract: The present invention provides a photothermographic material containing a non-photosensitive silver salt of an organic acid, a photosensitive silver halide, a reducing agent for silver ions and a binder on one surface of a support, which comprises at least one compound represented by the following formula (I) and at least one compound producing imagewise a chemical species that can form development initiation points on and in the vicinity of the non-photosensitive silver salt of an organic acid:
    Type: Application
    Filed: January 16, 2002
    Publication date: October 24, 2002
    Inventor: Tetsuo Yamaguchi
  • Patent number: 6458505
    Abstract: A photothermographic material having, on a support, an image-forming layer that contains at least a non-photosensitive silver salt of an organic acid, a photosensitive silver halide, a nucleating agent and a binder, and at least one protective layer outer than the image-forming layer on the support, wherein the protective layer contains at least one compound selected from the group consisting of the compounds represented by the following formula (1) and the compounds represented by the following formula (2) as emulsion dispersion or solid dispersion: C—(Y)n—CZ1Z2X  Formula (1) wherein, in the formula (1), Q represents an alkyl group, an aryl group or a heterocyclic group, which groups may have one or more substituents, Y represents a divalent bridging group, n represents 0 or 1, Z1 and Z2 represents a halogen atom, and X represents hydrogen atom or an electron-withdrawing group, wherein, in the formula (2), M represents hydrogen atom or a k-valent cation; k represents
    Type: Grant
    Filed: March 22, 2001
    Date of Patent: October 1, 2002
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Tadashi Ito
  • Publication number: 20020132179
    Abstract: A silver halide photographic light-sensitive material, which contains at least one compound of the formula (1):
    Type: Application
    Filed: August 10, 2001
    Publication date: September 19, 2002
    Inventors: Kohzaburoh Yamada, Masahiko Taniguchi, Takashi Hoshimiya, Hirokazu Kyota, Toshihide Ezoe, Shoji Yasuda
  • Patent number: 6444392
    Abstract: A black and white graphic arts film comprising a support having thereon at least one emulsion layer, said emulsion layer comprising: a trinuclear merocyanine spectral sensitising dye; 2-methylthio-4-hydroxy-6-methyl-1,3,3a,7-tetraazaindene (SMe-TAI); and a photosensitive silver halide.
    Type: Grant
    Filed: August 10, 2001
    Date of Patent: September 3, 2002
    Assignee: Eastman Kodak Company
    Inventor: Julie Baker
  • Patent number: 6440618
    Abstract: This invention relates to an imaging element comprising an imaging layer having associated therewith a compound of Structure I: In the above Structure I, the substituents are as defined in the application, wherein B is a six-membered heteroaromatic ring. Such compounds have good reactivity and can by used to block photographically useful compounds such as developing agents until thermally activated under preselected conditions. Compounds according to the present invention are especially useful in color photothermographic imaging elements.
    Type: Grant
    Filed: November 13, 2000
    Date of Patent: August 27, 2002
    Assignee: Eastman Kodak Company
    Inventors: Wojciech K. Slusarek, Xiqiang Yang, David H. Levy
  • Patent number: 6428947
    Abstract: This invention comprises multicolor photographic element comprising a support bearing a cyan dye image-forming unit comprising at least one red-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, a magenta dye image-forming unit comprising at least one green-sensitive silver halide emulsion layer having associated therewith at least one magenta dye-forming coupler, a yellow dye image-forming unit comprising at least one blue-sensitive silver halide emulsion layer having associated therewith at least one yellow dye-forming coupler, wherein at least one of said red-sensitive or green-sensitive layers comprises a fragmentable electron donating compound of the formula: X—Y′ or a compound which contains a moiety of the formula —X—Y′; wherein the speed gain deriving from addition of said compound to said layer is less than or equal to 0.
    Type: Grant
    Filed: January 5, 2001
    Date of Patent: August 6, 2002
    Assignee: Eastman Kodak Company
    Inventors: Sharon G. Johnston, Annabel A. Muenter, Steven P. Szatynski, Jerome R. Lenhard
  • Publication number: 20020055068
    Abstract: In a photothermographic material having an image-forming layer and a protective layer on a support, (A) a nucleating agent having a particular structure is added to at least one of the layers formed on the image-forming layer side of the support and NH4+ content in all the layers formed on the image-forming layer side is controlled to be 0.06 mmol/m2 or less, or (B) a nucleating agent and an organic acid compound having a particular structure are added to at least one of the layers formed on the image-forming layer side so that film surface pH is substantially unchanged. This photothermographic material is characterized by low fog, high Dmax, little increase of fog during storage and little temperature and humidity dependency upon heat development.
    Type: Application
    Filed: August 14, 2001
    Publication date: May 9, 2002
    Inventor: Tokuju Oikawa
  • Patent number: 6383711
    Abstract: A high contrast photographic material comprises a support bearing a silver halide emulsion layer, containing in the emulsion layer or in an adjacent hydrophilic layer, a hydrazide nucleating agent characterized in that the emulsion layer contains silver halide grains of octahedral character which are spectrally sensitized and silver halide grains which are not octahedral in character eg cubic. Preferably only the grains which are octahedral in character are spectrally sensitized. Preferably the emulsion layer or an adjacent hydrophilic colloid layer contains a booster compound eg an amine rendering the material developable in a developer solution having a pH below 11. Preferably both types of grain are chemically sensitized. The use of tabular grains as causer emulsions enhances the absorption characteristics of the dyes so that as well as providing high photographic sensitivity the dye peaks are broadened.
    Type: Grant
    Filed: August 21, 2000
    Date of Patent: May 7, 2002
    Assignee: Eastman Kodak Company
    Inventors: Jurjen F. Winkel, Michael B. Ledger
  • Publication number: 20020042015
    Abstract: A color diffusion-transfer photographic light-sensitive material provided with at least two light-sensitive silver halide emulsion layers, each of which is combined with a non-diffusive dye image forming compound forming or releasing a diffusive dye or its precursor in relation to silver development, or with a dye image forming compound whose diffusibility changes in relation to silver development, on a support, the light-sensitive material comprises a specific hydrazine compound and a specific compound improved in storability.
    Type: Application
    Filed: March 14, 2001
    Publication date: April 11, 2002
    Inventors: Nobutaka Fukagawa, Shinichi Ichikawa, Masaru Yoshikawa
  • Patent number: 6361920
    Abstract: A high contrast silver halide photographic material is disclosed containing a new type of hydrazide compound represented by following general formula I, the different symbols of which are defined in the description. The photographic material is preferably a graphic arts material for pre-press applications. High gradation and excellent dot quality, exposure latitude and stability on continuous processing are obtained.
    Type: Grant
    Filed: September 13, 2000
    Date of Patent: March 26, 2002
    Assignee: AGFA Gevaert
    Inventors: Johan August Loccufier, Stefaan Lingier, Pascal Frans Meeus
  • Patent number: 6355394
    Abstract: A high contrast silver halide photographic material is disclosed containing a new type of hydrazide compound represented by following general formula I, the different symbols of which are defined in the description. The photographic material is preferably a graphic arts material for pre-press applications. High gradation and excellent dot quality, exposure latitude and stability on continuous processing are obtained.
    Type: Grant
    Filed: September 7, 2000
    Date of Patent: March 12, 2002
    Assignee: Agfa Gevaert
    Inventors: Johan August Loccufier, Stefaan Lingier, Pascal Frans Meeus
  • Publication number: 20020004185
    Abstract: A black-and-white silver halide photographic material has been disclosed, coated on a support with at least one light-sensitive emulsion layer, comprising a spectrally sensitized prefogged direct-positive silver halide emulsion, providing peak absorption in the wavelength range from 600 nm up to 700 nm, wherein said emulsion comprises a binder and core-shell emulsion crystals having silver bromide in a total amount of at least 80 mole %, characterized in that said emulsion is spectrally sensitized with a combination of a desensitizing dye having an absorption maximum wavelength in a range from 600 nm up to 700 nm, if present as a sole dye in said emulsion, and at least one azacyanine dye having an absorption maximum at a more hypsochromic wavelength.
    Type: Application
    Filed: June 2, 2001
    Publication date: January 10, 2002
    Inventors: Kris Viaene, Paul Callant
  • Patent number: 6319640
    Abstract: This invention relates to an imaging element comprising an imaging layer having associated therewith a compound of Structure I: In the above Structure I, the substituents are as defined in the application. Such compounds have good reactivity and can by used to block photographically useful compounds such as developing agents until thermally activated under preselected conditions. Compounds according to the present invention are especially useful in color photothermographic imaging elements.
    Type: Grant
    Filed: November 13, 2000
    Date of Patent: November 20, 2001
    Assignee: Eastman Kodak Company
    Inventors: Wojciech K. Slusarek, Xiqiang Yang, David H. Levy
  • Patent number: 6306551
    Abstract: This invention relates to an imaging element comprising an imaging layer having associated therewith a compound of Structure I: wherein the substituents are as defined in the specification.
    Type: Grant
    Filed: December 30, 1999
    Date of Patent: October 23, 2001
    Assignee: Eastman Kodak Company
    Inventors: Zbyslaw R. Owczarczyk, Xiqiang Yang, David H. Levy, Mark E. Irving
  • Publication number: 20010014435
    Abstract: A photothermographic image forming element contains a non-photosensitive silver salt which has been formed by simultaneously adding and mixing previously prepared solutions of silver nitrate and an organic acid alkali metal salt. A photosensitive layer containing a photosensitive silver halide or a layer disposed adjacent thereto or both contain a nucleating agent. The element produces a low fog, high contrast image.
    Type: Application
    Filed: March 23, 1999
    Publication date: August 16, 2001
    Applicant: Kazuki Yamazaki
    Inventor: KAZUKI YAMAZAKI
  • Patent number: 6245497
    Abstract: A photographic element comprises a support bearing a cyan dye image-forming unit comprising at least one red-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, a magenta dye image-forming unit comprising at least one green-sensitive silver halide emulsion layer having associated therewith at least one magenta dye-forming coupler, a yellow dye image-forming unit comprising at least one blue-sensitive silver halide emulsion layer having associated therewith at least one yellow dye-forming coupler, wherein at least one of said emulsion layers comprises a) an emulsion with 3D, core/shell grains of at least 0.
    Type: Grant
    Filed: December 20, 1999
    Date of Patent: June 12, 2001
    Assignee: Eastman Kodak Company
    Inventors: Jon N. Eikenberry, David T. Southby
  • Patent number: 6242170
    Abstract: This invention provides a multicolor photographic element comprising a support bearing a cyan dye image-forming unit comprising at least one red-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, a magenta dye image-forming unit comprising at least one green-sensitive silver halide emulsion layer having associated therewith at least one magenta dye-forming coupler, a yellow dye image-forming unit comprising at least one blue-sensitive silver halide emulsion layer having associated therewith at least one yellow dye-forming coupler, wherein at least one of said emulsion layers comprises large tabular grains having an average equivalent circular diameter of greater than 3 &mgr;m and contains a one equivalent image dye-forming coupler and a fragmentable electron donating compound of the formula: X—Y′ or a compound which contains a moiety of the formula —X—Y′; wherein X is an electron donor moiety, Y′ is a leaving proton H
    Type: Grant
    Filed: December 20, 1999
    Date of Patent: June 5, 2001
    Assignee: Eastman Kodak Company
    Inventors: Joseph P. Pepe, Jeffrey C. Hansen, James A. Friday, Annabel A. Muenter, David T. Southby
  • Patent number: 6225036
    Abstract: A multicolor photographic element comprising a support bearing a cyan dye image-forming unit comprising at least one red-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, a magenta dye image-forming unit comprising at least one green-sensitive silver halide emulsion layer having associated therewith at least one magenta dye-forming coupler, a yellow dye image-forming unit comprising at least one blue-sensitive silver halide emulsion layer having associated therewith at least one yellow dye-forming coupler, wherein at least one of said emulsion layers comprises tabular grains having {111} major faces containing greater than 50 mole percent bromide, and accounting for greater than 50 percent total grain projected area precipitated in a peptizer that is a water dispersible cationic starch, and contains a fragmentable electron donating sensitizer.
    Type: Grant
    Filed: March 23, 2000
    Date of Patent: May 1, 2001
    Assignee: Eastman Kodak Company
    Inventors: Joe E. Maskasky, Kenneth J. Reed, Victor P. Scaccia, James A. Friday
  • Patent number: 6177240
    Abstract: A thermographic recording element having an image forming layer contains an organic silver salt, a reducing agent, an optional photosensitive silver halide, and a specific nucleating agent. The element has high Dmax, high sensitivity, satisfactory contrast, and minimal dependency of photographic properties on developing conditions.
    Type: Grant
    Filed: November 17, 1998
    Date of Patent: January 23, 2001
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kohzaburoh Yamada, Hiroyuki Suzuki, Toshihide Ezoe
  • Patent number: 6171752
    Abstract: A photographic material comprises a support bearing at least one silver halide emulsion layer. The material contains in the emulsion layer or an adjacent hydrophilic colloid layer, a nucleating agent. One or more of the layers further comprises a polymeric material capable of partitioning the nucleating agent in order to control nucleation and thereby allow the level of pepper fog and raw stock keeping to be controlled.
    Type: Grant
    Filed: December 9, 1998
    Date of Patent: January 9, 2001
    Assignee: Eastman Kodak Company
    Inventors: Julie Baker, John M. Higgins
  • Patent number: 6156491
    Abstract: A heat-developable light-sensitive material comprising a support and at least one image-forming layer, and containing a light-insensitive silver salt, a light-sensitive silver halide and a binder, wherein the light-sensitive material comprises at least one image-forming layer which contains: a light-sensitive silver halide which has been spectrally sensitized to from 750 to 1,400 nm; and a binder comprising a polymer latex having a glass transition temperature of from -30.degree. C. to 40.degree. C.
    Type: Grant
    Filed: March 25, 1999
    Date of Patent: December 5, 2000
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Takahiro Goto
  • Patent number: 6033833
    Abstract: A new fogging photographic processing solution for a reversal process comprises a compound (I) and a bi-nucleophilic agent. Compound (I) corresponds to the following formula: ##STR1## wherein A is a group capable of being adsorbed to the silver halide surface, L is a linking group and r is 0 or 1, R.sub.1 and R.sub.2 are independently selected from an alkyl group, substituted or unsubstituted, and an aryl group substituted or unsubstituted. A process of producing a positive image by imagewise exposure of a reversal silver halide material comprises contacting the material with the above fogging solution or by imagewise exposure of such a material containing a compound (I) and contacting the material with a solution comprising a bi-nucleophilic agent.
    Type: Grant
    Filed: April 29, 1999
    Date of Patent: March 7, 2000
    Assignee: Eastman Kodak Company
    Inventors: Siu C. Tsoi, Peter J. Twist, David T. Southby
  • Patent number: 5998105
    Abstract: Disclosed is a method of image formation comprising the steps of: (i) subjecting a silver halide color photographic material to scanning exposure with a beam modulated in accordance with image information to prepare a scanning-exposed photographic material, wherein the silver halide color photographic material comprises a support having provided thereon a photographic constituent layer containing at least one reducing agent for color formation represented by formula (I) and at least one dye-forming coupler, and wherein a scanning pitch of the beam is smaller than an effective beam diameter of the beam, and an inter-raster overlap width of the beam is from 5% to 95% of the effective beam diameter; and (ii) developing the scanning-exposed photographic material:R.sup.11 --NHNH--X--R.sup.12 (I)wherein R.sup.11 represents an aryl group or a heterocyclic group; R.sup.12 represents an alkyl group, an alkenyl group, an alkinyl group, an aryl group or a heterocyclic group; X represents --SO.sub.
    Type: Grant
    Filed: December 2, 1996
    Date of Patent: December 7, 1999
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Yasuhiro Murakoshi
  • Patent number: 5998087
    Abstract: A silver halide photographic material is disclosed containing a new type of hydrazide compounds represented by following general formula I, the different symbols of which are defined in the description. ##STR1## In a preferred embodiment Q is chosen from pyridinium, quinolinium or isoquinolinium. In a most preferred embodiment Q is a pyridinium substituted on the N.sup.+ with a C.sub.5 to C.sub.8 alkyl group.The photographic material is preferably a graphic arts recording material. High gradation and excellent hard dot quality are obtained.
    Type: Grant
    Filed: January 22, 1999
    Date of Patent: December 7, 1999
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Johan Loccufier, Stefaan Lingier, Sabine Emmers, Jean-Marie Dewanckele, Pierre De Clercq, Noel Hosten, Dirk Van Haver
  • Patent number: 5989774
    Abstract: A silver halide photographic material is disclosed containing a new type of hydrazide compound represented by following general formula I, the different symbols of which are defined in the description. ##STR1## In a preferred embodiment Q is pyridinium, substituted with a propargyllic group or butynyl group.The photographic material is preferably a graphic arts recording material. High gradation and excellent hard dot quality are obtained.
    Type: Grant
    Filed: September 10, 1998
    Date of Patent: November 23, 1999
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Johan Loccufier, Stefaan Lingier, Paul Callant, Sabine Emmers
  • Patent number: 5985508
    Abstract: A silver halide photographic material is disclosed, comprising a support having thereon at least one silver halide emulsion layer, wherein said emulsion layer contains a heavy metal selected from Ir, Ru, Rh, Re and Cr in an amount of at least 1.times.10.sup.-5 mol per mol of silver halide and (1) silver halide grains having a silver chloride content of 95 mol % or more, said grains being formed under acidic conditions and then subjected to gold-sulfur sensitization, (2) a silver halide having a silver chloride content of 95 mol % or more and then subjected to Se or Te sensitization or (3) silver halide grains having a silver chloride content of 95 mol % or more and conatianing at least one iron compound, and at least one of said emulsion layer and other hydrophilic colloid layers contains at least one hydrazine derivative and at least one nucleation accelerator. Also, disclosed is a method for producing the above-described silver halide photographic material.
    Type: Grant
    Filed: January 3, 1997
    Date of Patent: November 16, 1999
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tadashi Ito, Takahiro Goto, Shoji Yasuda
  • Patent number: 5981138
    Abstract: A hydrazine compound represented by the following formula (I):Ar.sub.1 --NH--NH--G.sub.1 --R.sub.1 (I)wherein Ar.sub.1 represents an aromatic group; G.sub.1 represents a carbonyl group, a sulfonyl group, a sulfoxy group, a phosphoryl group, an oxalyl group or an iminomethylene group; R.sub.1 represents a hydrogen atom or a block group; and at least one of Ar.sub.1 and R.sub.1 has a group represented by the following formula (II): ##STR1## wherein * represents a bond for connecting directly or through a liking group to Ar.sub.1 or R.sub.1 ; Z represents a nonmetallic atom group capable of forming a 5- or 6-membered unsaturated heterocyclic ring having a conjugated positive charge; and X.sup.- represents --O.sup.-, --S.sup.- or --N.sup.- --R.sub.2, wherein R.sub.2 represents an alkyl group, an alkenyl group, an alkynyl group, an aryl group or a heterocyclic group. Also disclosed is a silver halide photographic light-sensitive material containing the hydrazine compound.
    Type: Grant
    Filed: September 4, 1997
    Date of Patent: November 9, 1999
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Suzuki, Kohzaburoh Yamada, Hiroshi Takeuchi, Toshihide Ezoe, Takashi Hoshimiya
  • Patent number: 5965322
    Abstract: There is disclosed a silver halide color photographic light-sensitive material that contains, in photographic constitutional layers on a support, a hydrazine-series reducing agent for color formation, and a phenol-series magenta coupler having an acylamino group at the 5-position, and/or a naphthol-series cyan coupler having an amido group at the 5-position. The light-sensitive material makes low-replenishment and low-discharge processing possible, and exhibits good color reproducibility and good color-forming property.
    Type: Grant
    Filed: February 18, 1997
    Date of Patent: October 12, 1999
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toshiyuki Makuta, Koki Nakamura, Kiyoshi Takeuchi
  • Patent number: 5939233
    Abstract: Nucleating agents that promote high contrast in photographic films are disclosed. The nucleating agents are aryl sulfonamido hydrazides having pyridinium, phosphonium or cycloalkenylpyridinium functional groups. The nucleating agents increase the speed and contrast of graphic arts films and improve dot quality in halftone applications. Boosters are not required to obtain good dot quality and photographic speed.
    Type: Grant
    Filed: October 28, 1998
    Date of Patent: August 17, 1999
    Assignee: Kodak Polychrome Graphics LLC
    Inventors: Syeda Husain, John F. Pilot, Rajendra J. Shah
  • Patent number: 5932404
    Abstract: The present invention is a silver halide photographic material including at least one layer which contains; a polymer comprising as constituent components thereof a repeating unit having a photographically useful group and at least one repeating unit having an imidazole group; and a compound having at least one functional group which reacts with an imidazole group and at least one other functional group capable of reacting with an imidazole group and a primary amine group, the amount of the compound being sufficient to insure adequate fixation of said polymer.
    Type: Grant
    Filed: December 18, 1996
    Date of Patent: August 3, 1999
    Assignee: Eastman Kodak Company
    Inventors: Tienteh Chen, Hwei-ling Yau, Dorothy T. Java
  • Patent number: 5922524
    Abstract: A colour photographic recording material having camera sensitivity, possessing on a transparent support at least one silver halide emulsion layer unit which is sensitive to part of the visible spectrum and consists of at least the following constituent layers:a) a spectrally sensitised silver halide emulsion layer containing an effective quantity of a FAR coupler (coupler, which during coupling releases groups producing fogging nuclei) and optionally a colour coupler, the latter during the colour development process coupling with a dye of which the colour is complementary to the spectral sensitisation of layer a), andb) a fine-grained silver halide emulsion layer having low light-sensitivity, of which the silver halide grains are not spectrally sensitised, being a layer adjacent to layer a),with layer b) containing a colour coupler which during the colour development process couples with a dye of which the colour is complementary to the spectral sensitisation of layer a) and the molar quantity of colour coupl
    Type: Grant
    Filed: February 3, 1997
    Date of Patent: July 13, 1999
    Assignee: Agfa-Gevaert AG
    Inventors: Ralf Buscher, Peter Bell, Hans-Ulrich Borst, Jorg Siegel, Johannes Willsau, Heinrich Odenwalder
  • Patent number: 5888694
    Abstract: A silver halide photographic material is described, which comprises a compound represented by the following formula (I) or (II):A.paren open-st.(L).sub.m --B).sub.n (I)(A--(L).sub.m .paren close-st..sub.n B (II)wherein A represents an adsorption accelerating group to silver halide or a precursor thereof; B represents a quaternised nitrogen-containing heterocyclic ring and a counter ion thereof; L represents a linking group; m represents 0 or 1; and n represents an integer of from 1 to 4. An image formation method is also described, which comprises the steps of exposing the above-described silver halide photographic material and developing the exposed material with a specific developer.
    Type: Grant
    Filed: February 18, 1997
    Date of Patent: March 30, 1999
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kohzaburoh Yamada, Toshiaki Kubo
  • Patent number: 5874207
    Abstract: A direct-positive silver halide light-sensitive material comprising a support having thereon at least one pre-fogged light-sensitive silver halide emulsion layer, wherein the light-sensitive material comprises a specific onium salt compound in the emulsion layer or a hydrophilic protective colloid layer adjacent thereto. Also disclosed is a method of preparing a pre-fogged light-sensitive silver halide emulsion for use in the light-sensitive material.
    Type: Grant
    Filed: May 16, 1997
    Date of Patent: February 23, 1999
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Isao Oyagi, Shingo Nishiyama, Nobuaki Inoue
  • Patent number: 5866313
    Abstract: A silver halide photographic light-sensitive material having at least one light-sensitive silver halide emulsion layer, on a support, and comprising a reducing agent for color formation of carbamoyl-substituted hydrazine, a dye-forming coupler and at least one photographic stabilizer selected from five groups of compounds.
    Type: Grant
    Filed: November 29, 1996
    Date of Patent: February 2, 1999
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Katsumi Hirano
  • Patent number: 5834172
    Abstract: A photographic coating composition comprising an aqueous medium containing a hydrophilic colloid and having dispersed therein solid particles of a yellow filter dye also contains a oxidized developer scavenger of formula III ##STR1## wherein x.sup.1 =hydrogen or a process cleavable group;R.sup.14 =an electron withdrawing and aqueous solubilizing group;R.sup.15 =a substituent group;R.sup.16 =a ballasting group;R.sup.17 =a substituent group;i=1, 2, 3, or 4; andj=1, 2, 3, or 4.The coating composition is stable with regard to crystal growth of the dispersed solid particles of filter dye even when held at coating temperatures (about 45.degree. C.) for several hours.
    Type: Grant
    Filed: February 23, 1996
    Date of Patent: November 10, 1998
    Assignee: Eastman Kodak Company
    Inventors: Paul Leo Zengerle, John Victor Nelson, Mary Christine Brick
  • Patent number: 5830630
    Abstract: A light-sensitive sheet comprises an aluminum alloy support and a light-sensitive layer. The aluminum alloy support contains grains of secondary phase. The maximum grain size of the grains of secondary phase essentially is less than 5 .mu.m. Silver halide light-sensitive materials having the aluminum alloy support are also disclosed.
    Type: Grant
    Filed: October 23, 1996
    Date of Patent: November 3, 1998
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Satoshi Hoshi, Hirokazu Sakaki, Yoshinori Hotta
  • Patent number: 5798204
    Abstract: A development processing method is described, which includes the steps of (a) exposing an ultrahigh-contrast silver halide photographic material comprising a support having thereon at least one light-sensitive silver halide emulsion layer and (b) developing the exposed silver halide photographic material with a developer while the developer is replenished with a development replenisher, wherein the developer and the development replenisher each contains a dihydroxybenzene developing agent and an auxiliary developing agent exhibiting a superadditive property to the dihydroxybenzene developing agent, and both the developer and the development replenisher have such a property that an increase of the pH is 0.25 or less when 0.1 mol of sodium hydroxide is added to 1 liter thereof; the developer has a pH from 9.5 up to but excluding 11.0; and the developer replenisher is added in an amount of 225 ml/m.sup.2 or less.
    Type: Grant
    Filed: December 16, 1996
    Date of Patent: August 25, 1998
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kouta Fukui, Mitsunori Hirano, Nobuaki Inoue
  • Patent number: 5780198
    Abstract: A silver halide photographic material comprising a plurality of light-sensitive silver halide emulsion layers, wherein (A) at least one of the layers contains a hydrazine nucleating agent represented by formula (II): ##STR1## wherein R.sub.1 represents an aliphatic group or an aromatic group; R.sub.2 represents a hydrogen atom, an alkyl group, an aryl group, an alkoxy group, an aryloxy group, an amino group, a hydrazine group, a carbamoyl group, or an oxycarbonyl group; G.sub.1 represents a carbonyl group, a sulfonyl group, a sulfinyl group, a sulfoxy group, ##STR2## a thiocarbonyl group, or an iminomethylene group; and A.sub.3 and A.sub.4 each represents a hydrogen atom, a substituted or unsubstituted alkylsulfonyl group, a substituted or unsubstituted arylsulfonyl group, or a substituted or unsubstituted acyl group, provided that at least one of A.sub.3 and A.sub.
    Type: Grant
    Filed: February 15, 1995
    Date of Patent: July 14, 1998
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takahiro Goto, Kazunobu Katoh, Minoru Sakai
  • Patent number: 5753411
    Abstract: A silver halide color photographic light-sensitive material is disclosed, comprising a support having thereon at least one photographic constituent layer, wherein any one of the photographic constituent layer contains at least one reducing agent for color formation represented by formula (I), at least one dye forming coupler and at least one water-insoluble polymer.
    Type: Grant
    Filed: November 27, 1996
    Date of Patent: May 19, 1998
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Toshiyuki Makuta
  • Patent number: 5744279
    Abstract: A silver halide photographic material is disclosed, comprising a support having provided thereon at least one silver halide emulsion layer, at least one layer of the emulsion layer and other hydrophilic colloid layers containing at least one hydrazine-type nucleating agent having, in the vicinity of the hydrazine group, an anionic group or a nonionic group which forms an intramolecular hydrogen bond with a hydrogen atom of the hydrazine, and also containing at least one of the onium salt compounds represented by formulae (a), (b) and (c), or at least one of the amine compounds represented by formulae (d), (e), (f), (g), (h), (i) and (j). Also disclosed is a method for processing, after exposure, the silver halide photographic material described above with a developer containing a reductone-type developing agent and having a pH of 12 or less.
    Type: Grant
    Filed: February 1, 1996
    Date of Patent: April 28, 1998
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toshihide Ezoe, Toshiaki Kubo, Hiroshi Takeuchi, Kazunobu Katoh, Shigeo Hirano, Kazuki Yamazaki, Takashi Hoshimiya, Minoru Sakai, Tetsuo Yoshida
  • Patent number: 5736299
    Abstract: A silver halide color photographic material is disclosed, wherein it comprises a support having thereon one or more constituent layers including at least one silver halide emulsion layer, wherein at least one hydrophilic colloid layer of said constituent layers contains a coupler represented by the following formula (M) or formula (I) and at least one hydrophilic colloid layer of said constituent layers contains a compound represented by the following formula (H): ##STR1##
    Type: Grant
    Filed: January 23, 1996
    Date of Patent: April 7, 1998
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toshiyuki Watanabe, Hiroshi Fukuzawa, Michio Ono, Takashi Nakamura
  • Patent number: 5723617
    Abstract: A series of novel pyrrolo?2,1-a!isoquinoline dyes has been prepared using readily available starting materials via a simple synthetic pathway. These dyes have narrow absorption bands in the range of 500-900 nm. Those that absorb in the near-infrared region (700-1400 nm) lack significant absorption in the 300-400 nm ultraviolet region of the spectrum; this is an advantage for use in an applications such as imaging setting film. In addition, the greater thermal and chemical stability of these dyes in comparison to their indolizine analogues should be valuable in many applications.
    Type: Grant
    Filed: December 21, 1995
    Date of Patent: March 3, 1998
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Gregory D. Cuny
  • Patent number: 5719007
    Abstract: A silver halide color photographic material is described, which comprises a support having thereon at least one blue-sensitive silver halide emulsion layer, at least one green-sensitive silver halide emulsion layer, at least one red-sensitive silver halide emulsion layer and at least one light-insensitive layer, wherein one or more of the above layers contains at least one compound represented by formula (A-I), (A-II), (A-III), (A-IV) or (A-V) and one or more of the above layers contains at least one compound represented by formula (H): ##STR1##
    Type: Grant
    Filed: January 29, 1996
    Date of Patent: February 17, 1998
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Mamoru Sakurazawa, Hisashi Mikoshiba, Masakazu Morigaki