Fogging Or Nucleating Agent Containing Patents (Class 430/598)
  • Patent number: 4873172
    Abstract: A process for forming a superhigh contrast negative image with a stable developer is disclosed, which comprises development processing a silver halide photographic material in the presence of a compound of formula (I) and a compound of formula (II) as defined in the specification.
    Type: Grant
    Filed: August 8, 1988
    Date of Patent: October 10, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shoji Ishiguro, Shigeo Hirano, Tadao Shishido, Akio Miyake
  • Patent number: 4873173
    Abstract: A method of forming an image is provided. The method comprises the steps of (a) imagewise exposing a photographic material which comprises a support having provided thereon at least one light-sensitive silver halide emulsion layer and which contains a hydrazine compound represented by the following general formula (I) in the emulsion layer or a hydrophilic colloid layer adjacent thereto, the photographic material being designed so that a difference in sensitivity (sensitivity being defined as log E corresponding to the density of fog+2.0) between (1) the photographic material is development-processed with a developing solution having a sulfite ion concentration of 0.15 mole/l or more, a potassium ion concentration of 0.2 mole/l or more and a pH value ranging from 10.5 to 12.3 and (2) the photographic material is development-processed with the same developing solution as described above, except that the pH value was lowered by 1.0, (.DELTA.log E), is 0.
    Type: Grant
    Filed: October 21, 1987
    Date of Patent: October 10, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Senzo Sasaoka, Tetsuo Yoshida, Nobuaki Inoue
  • Patent number: 4871653
    Abstract: A process for forming a direct-positive image by developing an imagewise exposed photosensitive material, having on a support at least one photographic emulsion layer containing nonprefogged silver halide grains capable of forming an internal latent image, in which development is carried out in the presence of a combination of a nucleating agent and at least one compound having at least one mercapto group selected from a tetrazaindene, a triazaindene, and a pentaazaindene. The hydrogen atom of which mercapto group may optionally be further substituted with an alkali metal atom or an ammonium group. The invention process provides rapid and consistent formation of direct-positive images having high maximum density and low minimum density.
    Type: Grant
    Filed: June 30, 1987
    Date of Patent: October 3, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Noriyuki Inoue, Tatsuo Heki, Tetsuro Kojima
  • Patent number: 4868102
    Abstract: A light-sensitive silver halide direct-positive photographic material which comprises a support and, provided thereon a light-sensitive direct-positive silver halide emulsion layer containing silver halide grains having an internal latent image and a core-shell structure comprising a core and at least one shell stratum either partly or entirely covering said core, the outermost stratum of said shell having been formed in the presence of a nitrogen-containing heterocyclic compound having a mercapto group therein.
    Type: Grant
    Filed: February 2, 1988
    Date of Patent: September 19, 1989
    Assignee: Konica Corporation
    Inventors: Keiji Ogi, Atsushi Kamitakahara, Eiichi Sakamoto, Nariko Isozaki
  • Patent number: 4859579
    Abstract: A silver halide photographic material comprising a support having thereon at least one light-sensitive silver halide photographic emulsion layer, wherein at least one layer selected from the emulsion layer and other hydrophilic colloid layers contains at least one alkynyl substituted heterocyclic quaternary ammonium salt represented by the following general formula (I): ##STR1## wherein Z represents a non-metallic atomic group necessary to form a substituted or unsubstituted 5-membered or 6-membered heterocyclic ring to which a aromatic ring or a heterocyclic ring may further be condensed; R.sup.1 represents a substituted or unsubstituted aliphatic group; X represents ##STR2## Q represents a non-metallic atomic group necessary to form a substituted or unsubstituted 4-membered to 12-membered non-aromatic hydrocarbon ring or substituted or unsubstituted non-aromatic heterocyclic ring; at least one of R.sup.
    Type: Grant
    Filed: January 28, 1988
    Date of Patent: August 22, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shigeo Hirano, Tetsuro Kojima, Mitsuru Yamamoto, Noriyuki Inoue, Tatsuo Heki
  • Patent number: 4857440
    Abstract: Photographic compound (A) capable of releasing a photographically useful group by means of intramolecular nucleophilic displacement exhibits increased resistance to hydrolysis when the compound contains in a coupling position a coupling-off group represented by the formula: ##STR1## wherein Q, R.sub.q, R.sub.1, R.sub.2, R.sub.3, n and PUG are as defined in the application. Such a compound (A) is useful in a photographic silver halide material and process.
    Type: Grant
    Filed: June 30, 1988
    Date of Patent: August 15, 1989
    Assignee: Eastman Kodak Company
    Inventors: William J. Begley, Michael J. Carmody, John M. Buchanan
  • Patent number: 4857445
    Abstract: A direct positive photo-sensitive material is described, wherein the material comprises at least one internal latent image-type silver halide emulsion layer containing core/shell-type silver halide grains consisting of substantially cubic or tetradecahedral grains mainly of the face (100) and being spectrally-sensitized with at least one sensitizing dye having the following formula: ##STR1## wherein R.sup.1 and R.sup.2 represent each a lower alkyl group substituted with a sulfonato, carboxyl or hydroxyl group, at least one of R.sup.1 and R.sup.2 being a sulfonatoalkyl group, R.sup.3 represents a hydrogen atom or a lower alkyl or substituted or unsubstituted phenethyl group, R.sup.4 represents a chlorine atom, a methoxy or ethoxy group or a hydrogen atom, R.sup.5 represents a chlorine atom or a phenyl, alkoxy or alkyl group, M.sup.+1 represents a cationic residue, m represents 0 or 1 with the proviso that when an inner salt is formed, m is 0.
    Type: Grant
    Filed: February 19, 1987
    Date of Patent: August 15, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tetsuo Yoshida, Tatsuo Heki
  • Patent number: 4845020
    Abstract: A method of processing a silver halide photographic material comprising processing the silver halide photographic material in the presence of an antifoggant which is an organic compound which loses its developing restraining function by a reduction oxidation reaction with oxidized developers. The method improves the discrimination between image and non-image areas of the silver halide photographic material by the novel antifoggant which restrains fog selectively in non-image areas without decreasing photographic sensitivity and image density. The organic compound can be an anti-foggant which possesses a moiety according to the Kendall-Pelz rule and either a mercapto group or a cyclic NH group.
    Type: Grant
    Filed: July 24, 1987
    Date of Patent: July 4, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Isamu Itoh, Keiji Mihayashi
  • Patent number: 4828973
    Abstract: A silver halide photographic material is described, which comprises a support having provided thereon at least one hydrophilic layer containing at least one alkynyl-substituted heterocyclic quaternary ammonium salt represented by the following general formula (I): ##STR1## wherein Z represents non-metallic atoms necessary for forming a 5- or 6-membered heterocyclic nucleus;R.sup.1 represents an aliphatic group, and R.sup.2 represents a hydrogen atom, an aliphatic group or an aromatic group, at least one of R.sup.1, R.sup.2 and Z having an alkynyl group, and at least one of the substituents R.sup.1 and Z including the group X-(L).sub.m - wherein X represents a group effective for accelerating adsorption onto silver halide grains and L represents a divalent linking group;Y represents a charge-balancing counter ion;n represents 0 or 1; andm represents 0 or 1.
    Type: Grant
    Filed: March 4, 1987
    Date of Patent: May 9, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shigeo Hirano, Ashita Murai, Seiji Suzuki
  • Patent number: 4820616
    Abstract: The sensitivity of highly sensitive color photographic recording materials may be enhanced by compounds releasing fogging or development accelerating compounds as a result of a reaction with color developer oxidation products and fogging may at the same time be reduced by using compounds corresponding to formula I as silver halide stabilizers: ##STR1## wherein Z denotes the atoms required for completing an oxazole or oxazine ring andY denotes a condensed aromatic ring system having at least one aromatic ring optionally substituted with an acid group, or a substituent carrying an acid group.
    Type: Grant
    Filed: February 11, 1987
    Date of Patent: April 11, 1989
    Assignee: Agfa-Gevaert Aktiengesellschaft
    Inventors: Reinhart Matejec, Manfred Becker, Heinrich Odenwalder, Hans-Joerg Metz
  • Patent number: 4801520
    Abstract: A direct positive color light-sensitive material comprising a support having provided thereon at least one photographic emulsion layer containing unfogged internal latent image type silver halide particles and a color image forming coupler, wherein said color image forming coupler itself is substantially nondiffusible and produces or releases a dye upon oxidation coupling with a color developing agent, and said light-sensitive material contains at least one development inhibitor-releasing type coupler selected from the group consisting of compounds represented by formulae (D-I) and (D-II)Coup--Z (D-I)Coup--TIME--Z (D-II)wherein Coup represents a coupler residual group; Z represents a diffusible development inhibitor or a precursor thereof; and TIME represents a timing group.
    Type: Grant
    Filed: July 17, 1987
    Date of Patent: January 31, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Noriyuki Inoue, Tatsuo Heki
  • Patent number: 4800154
    Abstract: A silver halide photographic emulsion comprising at least one spectral sensitizing dye having the following general formula (I):Dye--J.sup.1 --CONH--J.sup.2 --NHNHG--R (I)wherein Dye represents a dye residue capable of becoming a spectral sensitizing dye; J.sup.1 represents a substituted or unsubstituted alkylene group, a substituted or unsubstituted arylene group, a substituted or unsubstituted aralkylene group, or a substituted or unsubstituted alkarylene group; J.sup.2 represents a substituted or unsubstituted arylene group; R represents hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted alkoxy group, or a substituted or unsubstituted aryloxy group; and G represents a carbonyl group, a sulfonyl group, a sulfoxy group, a phosphoryl group, or a substituted or unsubstituted iminomethylene group.
    Type: Grant
    Filed: October 16, 1986
    Date of Patent: January 24, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masaki Okazaki, Haruo Takei
  • Patent number: 4798780
    Abstract: A silver halide photographic light sensitive emulsion containing a hydrazine of the general formulaR.sup.3 -NR.sup.4 -NR.sup.5 -G-X (I)in which:R.sup.3 represents an aryl group,one of R.sup.4 and R.sup.5 is a hydrogen and the other is selected from hydrogen, aryl sulphonyl and trifluoroacetyl,G represents carbonyl, sulphonyl, sulphoxy, phosphoryl or an N-substituted or unsubstituted imino group andX is a moiety such that at a pH in the range of 9.5 to 12.5 in the presence of an oxidized hydroquinone a cyclization reaction takes place cleaving the moiety -G-X from the remainder of the molecule and forming a cyclic structure comprising atoms of the moiety -G-X.
    Type: Grant
    Filed: June 29, 1987
    Date of Patent: January 17, 1989
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Kevin P. Hall, Andrew W. Mott
  • Patent number: 4786587
    Abstract: A silver halide photographic material comprising at least one negative type silver halide emulsion layer coated on a support, said emulsion comprising two kinds of monodisperse emulsions each having a means grain sizes of not more than 0.5 micron and, differing in mean grain size from each other at least by 0.1 micron, and said photographic material further comprising a hydrazine derivative in at least one photographic layer, whereby negative images of high density and very high contrast can be obtained with a high photographic speed and without black spots.
    Type: Grant
    Filed: October 26, 1987
    Date of Patent: November 22, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Ken-ichi Kuwabara
  • Patent number: 4783396
    Abstract: The present invention provides silver halide photographic materials containing a havel compound, which when reduced, releases a photographically useful group as triggered off by the cleavage of the nitrogen-oxygen single bond in the compound and which is represented by the following general formula (I): ##STR1## wherein EAG represents a group which accepts an electron from a reducing substance; N and O each represents nitrogen atom and an oxygen atom, respectively; R.sup.1 and R.sup.2 each represents a substituent other than a hydrogen atom, and when R.sup.1 or R.sup.2 is bonded to --(Time).sub.t PUG, R.sup.1 or R.sup.2 is a mere bond or a substituent other than a hydrogen atom, and R.sup.1 and R.sup.
    Type: Grant
    Filed: October 30, 1986
    Date of Patent: November 8, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Koki Nakamura, Sahigeru Nakamura
  • Patent number: 4770982
    Abstract: A silver halide photographic material is disclosed which contains a compound represented by formula (I)RED--L.sub.1).sub.v B--L.sub.2).sub.w PUG (I)wherein RED represents a group adapted to release the group (L.sub.1).sub.v B--L.sub.2).sub.w PUG upon oxidation: L.sub.1 represents a group adapted to release the group B--L.sub.2).sub.w PUG after cleavage from RED; B represents a group which, after cleavage of the bond with L.sub.1 or RED, releases the group (L.sub.2).sub.w PUG upon reaction with an oxidized developing agent; L.sub.2 represents a group which, after cleavage from B, releases PUG; PUG represents a photographically useful group; and v and w each represents 0 or 1.
    Type: Grant
    Filed: June 4, 1986
    Date of Patent: September 13, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Seiji Ichijima, Shigeo Hirano, Koki Nakamura, Keiji Mihayashi
  • Patent number: 4769316
    Abstract: A restraining method for restraining the formation of a re-reversal negative image is described, comprising incorporating a cyanine dye or a merocyanine dye which is electron donative and is adsorbable on silver halide in at least one hydrophilic colloid layer of an internal latent image type direct positive silver halide photographic material as a re-reversal restrainer.
    Type: Grant
    Filed: June 18, 1986
    Date of Patent: September 6, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tsutomu Miyasaki, Shigeo Hirano, Kiyoshi Morimoto
  • Patent number: 4767692
    Abstract: A novel silver halide photographic material is provided comprising a support and at least one silver halide photographic emulsion layer formed thereon and containing in said photographic emulsion layer or at least one hydrophilic colloid layer a compound represented by formula (I): ##STR1## wherein R.sup.1 and R.sup.2 may be the same or different and each represents a hydrogen atom, an aliphatic residual group, an aromatic residual group, or a heterocyclic residual group; R.sup.3 represents a hydrogen atom or an aliphatic residual group; L.sub.1 represents a divalent aliphatic group, a divalent aromatic group, or a divalent heterocyclic group; L.sub.2 represents --O--, --CONR--, --NRCO--, --SO.sub.2 NR--, --NRSO.sub.2 --, --OCO--, --COO--, --S--, --NR--, --CO--, --SO--, --SO.sub.2 --, --OCOO--, --NRCONR'--, --NRCOO--, --OCONR--, or --NRSO.sub.
    Type: Grant
    Filed: January 5, 1987
    Date of Patent: August 30, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoshio Inagaki, Morio Yagihara, Shigeo Hirano
  • Patent number: 4749644
    Abstract: In a light-sensitive direct posi silver halide color photographic material having photographic constituent layers comprising at least one silver halide emulsion layer containing latent image type silver halide grains not previously fogged, which is capable of giving a direct posi image by subjecting the whole surface to exposure or effecting surface development in the presence of a fogging agent, after image exposure, the improvement wherein said internal latent image type silver halide grains are composed of at least two groups of internal latent image type silver halide grains having average grain sizes different from each other, and at least one compound capable of releasing a development inhibiting substance or its precursor through the reaction with the oxidized product of a color developing agent is contained in at least one layer of said photographic constituent layers.
    Type: Grant
    Filed: June 18, 1986
    Date of Patent: June 7, 1988
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Yasuo Tosaka, Keiji Ogi, Atsushi Kamitakahara
  • Patent number: 4746601
    Abstract: A silver halide photographic light-sensitive material comprising a support having provided thereon at least one photographic layer including at least one silver halide emulsion layer, whereinat least one silver halide emulsion layer contains silver halide grains whose average value of the diameter corresponding to the projected area of a group of silver halide grains that take 40% of the total projected area of whole silver halide grains present in said silver halide emulsion layer is at least 1.5 .mu.m andat least one photographic layer contains at least one compound capable of imagewise releasing a fogging agent or a precursor thereof or a development accelerator or a precursor thereof corresponding to a quantity of developed silver upon development, is disclosed. This material is of very high sensitivity and, furthermore, has a high developing speed and has reduced for formation irrespective of its high sensitivity.
    Type: Grant
    Filed: March 9, 1987
    Date of Patent: May 24, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Keiji Mihayashi, Hidetoshi Kobayashi, Shunji Takada
  • Patent number: 4737439
    Abstract: A radiation-sensitive composition including silver halide grains capable of forming an internal latent image and a nucleating agent is useful as a coating on a support to form a photographic element.
    Type: Grant
    Filed: July 28, 1986
    Date of Patent: April 12, 1988
    Assignee: Eastman Kodak Company
    Inventors: John P. Freeman, Roy L. Orvis, Richard L. Parton, Karl E. Wiegers
  • Patent number: 4734357
    Abstract: A silver halide color light-sensitive material is described, which is increased in sensitivity, is adapted to form an image of high contrast, or is accelerated in development by incorporating a small amount of a specific compound which imagewise releases a foggant or a development accelerator. This compound is represented by the formula: Coup-(TIME).sub.n -FA (wherein Coup represents a coupler radical capable of undergoing a coupling reaction with an oxidized product of an aromatic primary amine developing agent; TIME represents a timing group which is eliminated from Coup by the coupling reaction and, thereafter, releases FA; n is 0 or 1; and FA represents a group which is eliminated from Coup in the coupling reaction when n is 0, whereas FA is released from TIME when n is 1. The FA has adsorption properties with respect to silver halide grains and also has a substantial fogging action with respect to the silver halide grains).
    Type: Grant
    Filed: January 14, 1987
    Date of Patent: March 29, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Keiji Mihayashi, Hidetoshi Kobayashi, Isamu Itoh
  • Patent number: 4725533
    Abstract: A silver halide photographic material forming a wash-off relief image comprising a support having provided thereon a layer containing a tanning developing agent such as catechol, hydroquinone or pyrogallol, emulsified and dispersed in a high boiling point solvent such as butyl phthalate, butyl benzoate or tricreryl phosphate, and a layer containing a silver halide direct reversal emulsion.
    Type: Grant
    Filed: February 25, 1986
    Date of Patent: February 16, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yutaka Oka, Khotarou Endou
  • Patent number: 4724199
    Abstract: A silver halide photographic light-sensitive material containing, in at least one layer thereof, a compound capable of releasing a fogging agent upon an oxidation-reduction reaction with an oxidation product of a developing agent under an alkaline condition. The material has an increased sensitivity, an increased contrast and an accelerated development rate.
    Type: Grant
    Filed: October 28, 1985
    Date of Patent: February 9, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hidetoshi Kobayashi, Masaharu Toriuchi, Isamu Itoh
  • Patent number: 4719174
    Abstract: A direct positive silver halide photographic light-sensitive material is described containing a weak electron donative, adsorptive compound represented by formula (I) or (II) effective for depressing formation of a re-reversed negative image, which is not a spectral sensitizing agent for silver halide or a nucleating agent:D--L--X (I)D--X (II)whereinD represents electron donative atoms comprising an aromatic ring or hereto ring, which is unsubstituted or substituted;L represents a linking group containing at least one of C, N, S and O and an atom or atoms necessary for cutting a .pi.-conjunction system; andX represents a group which is adsorptive with respect to silver halide and contains at least one of C, N, S, O and Se.
    Type: Grant
    Filed: April 2, 1986
    Date of Patent: January 12, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shigeo Hirano, Tsutomu Miyasaka, Shinsaku Fujita
  • Patent number: 4698297
    Abstract: A silver halide color photographic light-sensitive material comprising a support having thereon at least one silver halide emulsion layer, the color photographic light-sensitive material containing a compound capable of releasing a group represented by the general formula (I) described below upon the reaction with the oxidation product of a developing agent: ##STR1## wherein W and Z each represents an oxygen atom, a sulfur atom or a group of ##STR2## X.sub.1, X.sub.2, X.sub.3, X.sub.4 and X.sub.5 each represents a hydrogen atom or an organic residue; PUG represents a photographically useful group; n represents 1 or 2; any two of X.sub.1, X.sub.2, X.sub.3, X.sub.4, X.sub.5 and PUG each represents a divalent group and may be connected to each other to form a cyclic structure; and when n represents 2, two Z's, two X.sub.3 's and two X.sub.4 's may be the same or different.
    Type: Grant
    Filed: May 28, 1985
    Date of Patent: October 6, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Seiji Ichijima, Noboru Sasaki
  • Patent number: 4690885
    Abstract: A silver halide photographic material which comprises a support having coated thereon a light-sensitive silver halide emulsion layer, wherein the photographic material contains at least one blocked photographic agent represented by the following general formula (I): ##STR1## wherein A represents a photographic agent moiety which is bonded to a blocking moiety through a hetero atom, or a precursor thereof; R.sup.1, R.sup.2 and R.sup.3 each represents a hydrogen atom, or a substituent group; and Z represents atoms necessary to form a carbocyclic ring or a heterocyclic ring (except for a heterocyclic ring which contains an NH group at the position adjacent to the carbon atom to which R.sup.1 is attached). The blocked photographic agent is completely stable upon storage of the photographic material, and releases a photographic agent at a desired time upon processing. The blocked photographic agent also exhibits its function to a substantial degree over a wide range of pH.
    Type: Grant
    Filed: October 16, 1985
    Date of Patent: September 1, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Morio Yagihara, Akihiko Ikegawa
  • Patent number: 4684604
    Abstract: Photographic elements and processes are described which employ a compound containing a hydrazide moiety attached by a linking group, comprising an acidic group or an active methylene group adjacent to an acidic group, to a heteroatom of a moiety containing a photographically useful group comprising a photographic dye or precursor thereof or a photographic reagent; wherein:(a) the hydrazide moiety is capable of being oxidized to an azo group by an oxidized developing agent,(b) the azo group formation causes the release of the photographically useful group, and(c) the released photographically useful group does not contain the linking group or the nitrogen atoms of the hydrazide moiety.
    Type: Grant
    Filed: April 24, 1986
    Date of Patent: August 4, 1987
    Assignee: Eastman Kodak Company
    Inventor: John W. Harder
  • Patent number: 4663272
    Abstract: A silver halide photographic material is described comprising at least one layer which contains at least(1) a polymer comprising as constitutional components thereof a repeating unit having a photographically useful group and at least one repeating unit having a sulfinic acid group or a sulfinate group, and(2) a compound having at least one functional group capable of reacting with at least one of a sulfinic acid group and sulfinate group and at least one functional group capable of reacting with at least one of a sulfinic acid group, a sulfinate group and a primary amino group.Said photographic group-containing polymer (1) may be fixed in a photographic layer according to the present photographic material, and does not substantially migrate therefrom during development or other photographic treatment, thus resulting in formation of color images of high density.
    Type: Grant
    Filed: August 7, 1985
    Date of Patent: May 5, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Taku Nakamura
  • Patent number: 4656123
    Abstract: A silver halide light-sensitive material is described, comprising a support having provided thereon at least two silver halide emulsion layers differing in color sensitivity, wherein at least one of said layers contains at least one compound capable of releasing a fogging agent, a development accelerator, or a precursor thereof in proportion to the amount of silver developed, and a layer containing silver halide grains which are not substantially developed by the development processing of said material is provided between said two emulsion layers differing in color sensitivity. The material has improved color reproducibility.
    Type: Grant
    Filed: January 25, 1985
    Date of Patent: April 7, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Keiji Mihayashi, Hidetoshi Kobayashi
  • Patent number: 4652516
    Abstract: A silver halide color photographic light-sensitive material comprising a support having thereon at least one silver halide emulsion layer, the color photographic light-sensitive material containing a compound capable of releasing a group represented by the general formula (I) described below upon the reaction with the oxidation product of a developing agent: ##STR1## wherein W represents an oxygen atom, a sulfur atom or a group ##STR2## (wherein R represents a hydrogen atom or an organic residue); X represents an electron withdrawing substituent; Y represents a hydrogen atom or a substituent; PUG represents a photographically useful group or a precursor thereof; X and Y each represents a divalent group and may be connected to each other to form a cyclic structure; and when W represents the group ##STR3## and R represents an organic residue, R and X or R and Y each represents a divalent group and may be connected to each other to form a cyclic structure.
    Type: Grant
    Filed: May 24, 1985
    Date of Patent: March 24, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Seiji Ichijima, Shingo Sato, Mitsunori Ono, Noboru Sasaki
  • Patent number: 4650746
    Abstract: This invention relates to a photographic element comprising a support, and coated on the support at least one negative-working photographic emulsion comprising radiation-sensitive silver halide grains capable of forming a surface latent image and a binder, and in the support or in a remaining hydrophilic colloid layer coated on the support in an amount sufficient to increase contrast, a hydrazine compound of the formula ##STR1## wherein R.sup.1 is a phenyl nucleus having a Hammet sigma value-derived electron withdrawing characteristic of less than +0.30.
    Type: Grant
    Filed: July 12, 1979
    Date of Patent: March 17, 1987
    Assignee: Eastman Kodak Company
    Inventors: Joseph M. Simson, Harold E. Jordan
  • Patent number: 4643965
    Abstract: A direct positive photographic light-sensitive material is described, comprising a support and at least one internal latent image type silver halide emulsion layer containing core/shell type silver halide grains which are composed of a silver halide core subjected to at least one of doping with metal ions and chemical sensitization, and a silver halide shell covering at least sensitivity sites of said core, and a binder, wherein said core/shell type silver halide grains consist of two or more kinds of grains each having a different average grain size, and the core of the core/shell type silver halide grains having a larger average grain size is doped with a larger amount of lead ions, cadmium ions, or Group VIII metal ions.
    Type: Grant
    Filed: May 24, 1984
    Date of Patent: February 17, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Satosi Kubota, Tetsuo Yoshida, Hideki Ohmatsu
  • Patent number: 4639408
    Abstract: A process for forming an image comprising a heating step is described, wherein a photographic material is heated in the presence of a compound represented by formula (I) ##STR1## wherein X represents an atomic group completing a carbocyclic aromatic ring or a heterocyclic aromatic ring; R.sup.1 is selected from groups represented by formulae (A), (B), and (C) ##STR2## in which R.sup.11 and R.sup.12 each represents a substituted or unsubstituted alkyl group, a cycloalkyl group, a substituted or unsubstituted alkenyl group, an aralkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted heterocyclic group, an alkyloxy or aryloxy group, an alkylthio or arylthio group, or a substituted or unsubstituted amino group, or R.sup.11 and R.sup.12 together form a 5-membered or 6-membered ring; R.sup.2 represents a group selected from the groups represented by R.sup.11 ; R.sup.1 and R.sup.
    Type: Grant
    Filed: November 20, 1985
    Date of Patent: January 27, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroshi Kitaguchi, Masatoshi Kato
  • Patent number: 4636457
    Abstract: Direct positive photographic elements are disclosed employing internal latent image silver halide emulsions associated with developer autoxidation promoter agents constituted by 5 or 6 membered nucleus-containing heterocyclic compounds comprising an azomethine group, whose methine group is substituted with a 5-amino-1,2,4-triazolyl group, and/or copper complex compounds thereof.Preferably said direct positive photographic elements are multi-layer elements comprising internal latent image type type silver halide emulsion layers sensitized to different regions of the visible light and associated with image-dye providing compounds (photographic color couplers).
    Type: Grant
    Filed: July 15, 1985
    Date of Patent: January 13, 1987
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Luigi Valbusa, Enzo Coraluppi, Andrea Quaglia, Mario Tavella
  • Patent number: 4634653
    Abstract: A direct positive silver halide photographic emulsion which is able to provide a high maximum density and a low minimum density, and having a high developing progress. The emulsion contains at least one of the sensitizing dyes represented by following general formulate I, II, III, and IV and at least one of the compounds represented by general formulae V and VI; ##STR1## The substituents are defined in the specification.
    Type: Grant
    Filed: March 18, 1985
    Date of Patent: January 6, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Ichizo Toya, Yuji Mihara, Haruo Takei
  • Patent number: 4629678
    Abstract: An internal latent image-type direct positive silver halide light-sensitive material is described, comprising a support having at least one photographic emulsion layer thereon, wherein said layer contains internal latent image-type direct positive silver halide grains, the surfaces of which are chemically sensitized, wherein a compound of the general formula (I) is added as a finish additive to the photographic emulsion layer or at least one hydrophilic colloid layer adjacent to the photographic emulsion layer.General Formula (I): ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are defined as herein. The light-sensitive material exhibits a very satisfactory reversal performance and is greatly improved in stability over the course of time.
    Type: Grant
    Filed: October 29, 1984
    Date of Patent: December 16, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Ashita Murai
  • Patent number: 4619884
    Abstract: Photographic elements and assemblages are described which employ nondiffusible N',N'-diaromatic carbocyclic--or diaromatic heterocyclic--sulfonohydrazide compounds which are capable of releasing photographically useful groups in an imagewise manner as a function of silver halide development.
    Type: Grant
    Filed: July 29, 1985
    Date of Patent: October 28, 1986
    Assignee: Eastman Kodak Company
    Inventor: Stephen P. Singer
  • Patent number: 4618572
    Abstract: A silver halide photographic light-sensitive material is disclosed, comprising a support having provided thereon at least one silver halide emulsion layer and containing, in a silver halide emulsion layer having an average iodide content of about 8 mol % or more, a compound capable of releasing a fogging agent or a precursor thereof, or of releasing a development accelerator or a precursor thereof upon development in proportion to the amount of developed silver.
    Type: Grant
    Filed: December 12, 1984
    Date of Patent: October 21, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Keiji Mihayashi, Hidetoshi Kobayashi, Shunji Takada
  • Patent number: 4618563
    Abstract: A silver halide photographic light-sensitive material is described, comprising a support having thereon a light-sensitive silver halide emulsion layer having associated therewith a blocked photographic agent represented by formula (I) ##STR1## wherein A represents a photographically useful agent moiety, which may have a timing group; X.sup.1 and X.sup.2 each represents a carbonyl group, a sulfonyl group, or a sulfinyl group; Z represents an atomic group forming a 5-membered, 6-membered, or 7-membered ring; R.sup.1 and R.sup.2, which may be the same or different, each represents a hydrogen atom, a halogen atom, an alkyl group, an alkenyl group, a cycloalkyl group, an aryl group, an alkoxy group, an acyl group, a sulfonyl group, or a heterocyclic group; R.sup.3 represents an alkyl group, an alkenyl group, a cycloalkyl group, a heterocyclic group, an aryl group, or an aralkyl group; m represents 0, 1, or 2; n represents 0 or 1; and the total of m+n is 1, 2, or 3.
    Type: Grant
    Filed: August 15, 1984
    Date of Patent: October 21, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Mitsunori Ono, Isamu Itoh, Keiji Mihayashi
  • Patent number: 4613563
    Abstract: A silver halide photographic light-sensitive material comprising a support having provided thereon at least one internal latent image type direct positive silver halide emulsion layer is disclosed, wherein(1) said internal latent image type direct positive silver halide emulsion layer comprises at least two layers having substantially the same color sensitivity, or(2) at least said internal latent image type direct positive silver halide emulsion and a solid pigment-containing layer contiguous thereto, which is positioned on the side opposite to the side of the silver halide emulsion layer to be exposed, are provided,and wherein at least one internal latent image type direct positive silver halide emulsion in (1) or (2) has a binder/silver halide (calculated as silver) ratio by weight of more than 1.25.
    Type: Grant
    Filed: January 29, 1985
    Date of Patent: September 23, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Ashita Murai
  • Patent number: 4610959
    Abstract: A direct positive silver halide photographic material is described, comprising a support having thereon at least an internal latent image-type direct positive silver halide emulsion layer containing a hydrazine series nucleating agent, wherein said silver halide emulsion layer or a layer adjacent to the silver halide emulsion layer contains a non-dye image-forming compound represented by following general formula (I) in an amount sufficient for accelerating nucleation; ##STR1## wherein Z.sub.1 and Z.sub.2, which may be the same or different, each represents an atomic group necessary for forming a benzene ring or a naphthalene ring; G.sub.1 and G.sub.2, which may be the same or different, each represents hydrogen or a substituent which does not adversely influence the image; A.sub.1, A.sub.2 and A.sub.3, which may be the same or different, each represents hydrogen or a substituent which does not adversely influence the image; B.sub.1, B.sub.2 and B.sub.
    Type: Grant
    Filed: February 20, 1985
    Date of Patent: September 9, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shigetoshi Ono, Shigeru Nakamura, Kazuhiko Matsumoto
  • Patent number: 4609610
    Abstract: Photographic elements and assemblages are described which employ nondiffusible compounds which release photographically useful groups in an imagewise manner as the result of a .beta.-elimination reaction.
    Type: Grant
    Filed: August 1, 1985
    Date of Patent: September 2, 1986
    Assignee: Eastman Kodak Company
    Inventors: Richard P. Dunlap, Thomas E. Gompf
  • Patent number: 4601976
    Abstract: A multilayer color photographic light-sensitive material containing no image-receiving layer is described, comprising a support, an internal latent image type direct reversal silver halide emulsion layer combined with a dye-providing substance, and a void layer between the support and the layer containing the dye-providing substance closest to the support.
    Type: Grant
    Filed: August 15, 1985
    Date of Patent: July 22, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Yukio Karino
  • Patent number: 4585731
    Abstract: A silver halide color photographic light-sensitive material is disclosed, comprising a support having thereon at least one silver halide emulsion layer, wherein at least one silver halide emulsion layer contains a coupler which is subjected to a coupling reaction with an oxidation product of a color developing agent to produce a diffusible coupling product which exerts a fogging effect in a developing solution; the silver halide color photographic light-sensitive material provides increased contrast and sensitivity, development is accelerated, and stability during storage is improved.
    Type: Grant
    Filed: August 10, 1984
    Date of Patent: April 29, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hidetoshi Kobayashi, Keiji Mihayashi
  • Patent number: 4582779
    Abstract: A previously unfogged internal latent image-type direct positive silver halide emulsion and a photographic material incorporating such emulsion are described, wherein the emulsion contains at least one sensitizing dye represented by formula (I): ##STR1## wherein one of R.sup.1 and R.sup.2 represents a sulfoalkyl group and the other thereof represents an unsubstituted or substituted alkyl group, an unsubstituted or substituted aryl group, or a pyridyl group; X represents a sulfur atom or an oxygen atom; Y represents a sulfur atom, an oxygen atom, or ##STR2## wherein R represents a lower alkyl group or --CH.sub.2).sub.n.sbsb.1 O--CH.sub.2).sub.n.sbsb.2 OH, wherein n.sub.1 and n.sub.2 each represents an integer of 1 to 4; and W represents a hydrogen atom, a halogen atom, a lower alkyl group, a lower alkoxy group, or an unsubstituted or substituted phenyl group.
    Type: Grant
    Filed: June 28, 1984
    Date of Patent: April 15, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Satosi Kubota, Tadao Sugimoto
  • Patent number: 4576905
    Abstract: Compounds containing an aromatic ring portion fused with a tellurazolium or derivative tellurazole, tellurazoline (including tellurazolinylidene), or tellurazolinium ring portion are disclosed together with processes and intermediates for their preparation. With properly selected pendant groups these tellurazolium and derivative compounds can be usefully employed as dyes, antifoggants or stabilizers, nucleating agents, latent image keeping addenda, or speed or contrast altering addenda in silver halide photographic systems.
    Type: Grant
    Filed: October 12, 1984
    Date of Patent: March 18, 1986
    Assignee: Eastman Kodak Company
    Inventors: Wolfgang H. H. Gunther, Ronald E. Leone, Rosemary Przyklek
  • Patent number: 4572892
    Abstract: A black and white direct positive photographic element intended for the formation of a viewable silver image is disclosed. One or more silver halide emulsion layers are present containing internal latent image forming silver halide grains. A maximum density enhancing antifoggant is located in an undercoat between the emulsion layer or layers and the support to impart an increase in photographic speed, an extended overexposure margin before encountering rereversal, a decrease in minimum density, and an increase in the covering power of developed silver.
    Type: Grant
    Filed: June 6, 1985
    Date of Patent: February 25, 1986
    Assignee: Eastman Kodak Company
    Inventor: Harry A. Hoyen
  • Patent number: RE32097
    Abstract: Blended emulsions for use in forming a direct-positive image are disclosed. The emulsions are comprised of a first, radiation-sensitive core-shell grain population having a relatively low coefficient of variation and a second, substantially smaller size grain population capable of .Iadd.internally forming a latent image by .Iaddend.internally trapping photolytically generated electrons. Photographic elements incorporating the blended emulsions exhibit improved covering power and can exhibit enhanced speed.
    Type: Grant
    Filed: July 2, 1984
    Date of Patent: March 25, 1986
    Assignee: Eastman Kodak Company
    Inventors: Robert A. Silverman, Harry A. Hoyen
  • Patent number: RE32149
    Abstract: Photographic elements particularly adapted for forming direct-positive images are disclosed in which a radiation-sensitive core-shell emulsion layer and a silver halide emulsion layer incapable of forming a surface latent image within the direct-positive exposure latitude of the first emulsion layer and containing a grain population capable of internally .Iadd.forming a latent image by internally .Iaddend.trapping photolytically generated electrons are both present. The photographic elements are capable of exhibiting increased covering power, greater maximum density, and increased speed.
    Type: Grant
    Filed: July 2, 1984
    Date of Patent: May 20, 1986
    Assignee: Eastman Kodak Company
    Inventors: Robert A. Silverman, Harry A. Hoyen