Noble Metal Or Compound Thereof Patents (Class 430/605)
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Patent number: 4837143Abstract: A silver halide photographic light-sensitive material comprising a support bearing at least one silver halide emulsion layer is disclosed. The silver halide emulsion layer contains silver halide grains comprising not less than 80 mol% of silver chloride and a water soluble iridium compound in an amount of from 10.sup.-8 to 10.sup.-5 mol per mol of a silver halide contained in the emulsion layer. And the emulsion layer is hardened with a hardner represented by General Formula [I] or [II]. ##STR1## The photographic material has an excellent antipressure property and suitable for a rapid processing.Type: GrantFiled: December 29, 1988Date of Patent: June 6, 1989Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Kazuo Komorita, Kaoru Onodera
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Patent number: 4835093Abstract: A photographic silver halide emulsion is disclosed comprised of radiation sensitive silver halide grains exhibiting a face centered cubic crystal lattice structure and internally containing rhenium ions.Type: GrantFiled: April 8, 1988Date of Patent: May 30, 1989Assignee: Eastman Kodak CompanyInventors: Gaile A. Janusonis, Ralph W. Jones, James R. Buntaine, Myra T. Olm, Raymond S. Eachus
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Patent number: 4828962Abstract: Photographic elements comprising a negative working silver halide emulsion containing high intensity reciprocity failure reducing amounts of dopant comprising both ruthenium and iridium ions.Type: GrantFiled: September 8, 1987Date of Patent: May 9, 1989Assignee: Minnesota Mining and Manufacturing CompanyInventors: Nicholas E. Grzeskowiak, Keith A. Penfound
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Patent number: 4818671Abstract: A silver halide color photographic material improved in sensitivity, gradiation and maximum density when the material is treated with a rapid processing. The silver halide color photographic material comprises a support and photograhic component layers including at least one silver halide emulsion layer comprising (a) silver halide grains comprising not less than 80 mol % of silver chloride, (b) a gold compound in an amount of from 5.times.10.sup.-7 to 5.times.10.sup.-3 mol per mol of silver halide contained in said silver halide emulsion layer, (c) a sulfur sensitizer and (d) a spectral sensitizing dye represented by the following general formula [I]: ##STR1## wherein X.sub.1, X.sub.2, X.sub.3 and X.sub.4 are a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, an aryl group or a hydroxy group, respectively; R.sub.1 and R.sub.2 are an alkyl group, respective;y X.sup..crclbar. is a counter anion and n is 0 or 1.Type: GrantFiled: July 29, 1987Date of Patent: April 4, 1989Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Keiji Ohbayashi, Mitsuhiro Okumura, Takaaki Kojima, Shigeo Tanaka
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Patent number: 4806462Abstract: A silver halide photographic material is disclosed, comprising a support having thereon at least one photographic silver halide emulsion layer containing silver halide grains dispersed in a dispersing medium, wherein in said silver halide grains, a total weight of the portion where at least one polyvalent metal ion is doped in an amount of not less than 1.times.10.sup.-4 mol per mol of the doped silver halide, is at least 10% based on the total weight of said silver halide grains.Type: GrantFiled: May 1, 1987Date of Patent: February 21, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Seiji Yamashita, Naoto Ohshima, Shunji Takada
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Patent number: 4786588Abstract: A water-soluble silver salt and a water-soluble halide are reacted to obtain silver halide particles, and these are, after being demineralized, transhalogenated by adding thereto a water-soluble bromide in an amount of 0.1 mol % to 7 mol % of the total silver halide amount just before or during the sulfur sensitization, to obtain a sulfur-sensitized silver halide emulsion of high sensitivity. The present photographic materials contain the sulfur-sensitized silver halide emulsion and have high sensitivity and excellent pressure characteristics. The transhalogenation along with the sulfur sensitization is effective for the improvement of the sensitivity and the pressure characteristics of the materials.Type: GrantFiled: September 22, 1986Date of Patent: November 22, 1988Assignee: Fuji Photo Film Co., Ltd.Inventor: Tadashi Ogawa
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Patent number: 4746603Abstract: Negative type silver halide photographic emulsions are provided, formed by growing silver halide grains in the presence of a water-soluble iridium salt in a molar ratio of 3.times.10.sup.-4 mol or more to the amount of the total silver halides used in the formation of the silver halide grains and then chemically sensitizing the surfaces of the grains formed with a sulfur compound or with a sulfur compound and a gold compound. The present emulsions have high sensitivity and extremely improved variation of sensitivity and gradation under broad exposure conditions of high intensity exposure and low intensity exposure.Type: GrantFiled: July 3, 1986Date of Patent: May 24, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Seiji Yamashita, Naoto Ohshima, Shunji Takada
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Patent number: 4729946Abstract: A silver halide photographic light-sensitive material is disclosed, comprising a monodisperse silver halide emulsion of 0.30 .mu.m or less in average silver halide grain size containing at least 75 mol % silver chloride and 2 mol % or less silver iodide, and having incorporated in said emulsion a dye represented by the formula (I) ##STR1## wherein Z represents atoms forming a thiazoline nucleus, a thiazole nucleus, or a benzothiazole nucleus,X represents an oxygen atom or a sulfur atom, andR.sub.1 and R.sub.2 each represents an unsubstituted or substituted aliphatic group or an unsubstituted or substituted aromatic group.Type: GrantFiled: November 19, 1986Date of Patent: March 8, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Yasuo Kasama, Kiyohiko Yamamuro
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Patent number: 4722884Abstract: A negative silver halide photographic light-sensitive material is provided, having a silver halide emulsion layer, which layer comprises silver haloiodide grains prepared in the presence of an iridium salt in an amount of 1.times.10.sup.-8 to 1.times.10.sup.-5 mole per one mole of silver, wherein the silver iodide content in the surface part of said grain is larger than the average silver iodide content in said grain, and additionally containing in said emulsion layer or in some other hydrophilic colloid layer, a compound of formula (I):R.sub.1 --NHNH--CHO (I)wherein R.sub.1 represents an aliphatic group or an aromatic group. Said photographic light-sensitive material is, after being exposed imagewise, developed with a developer containing 0.15 mole/l or more sulfite ion and having a pH value of 9.5-12.3, to form negative images having ultra-high contrast.Type: GrantFiled: July 23, 1985Date of Patent: February 2, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Nobuaki Inoue, Senzo Sasaoka, Kenichi Kuwabara, Kimitaka Kameoka
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Patent number: 4713321Abstract: A process for preparing a silver halide photographic emulsion to be used for a photographic material is provided. Therein, additives such as dyes, sensitizers, auxiliary agents to be used upon gold sensitization, and so on are utilized within a period from at the silver halide grain forming time to just before the emulsion coating, and oxidizing agents are added at the time when the functions of the additives become substantially needless to result in conversion of the additives to those having no bad influences on photographic characteristics of the emulsion prepared, or to those having such chemical structures as to facilitate their removal with a washing treatment or the like.Silver halide emulsions prepared by the described process are also disclosed.Type: GrantFiled: February 14, 1986Date of Patent: December 15, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroyuki Mifune, Tadao Shishido, Yoshiaki Suzuki
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Patent number: 4705747Abstract: Improved silver halide emulsions are obtained by the combined use of an iridium compound and an imidazole before termination of crystal growth.Type: GrantFiled: February 24, 1986Date of Patent: November 10, 1987Assignee: Agfa Gevaert AktiengesellschaftInventors: Sieghart Klotzer, Bruno Mucke, Gunther Mahlberg, Manfred Becker
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Patent number: 4704349Abstract: Photographic direct-positive emulsions with silver halide crystals of layered structure are prepared.The silver halide crystals of these emulsions can form a latent internal image and are superficially converted to silver iodide. Normal surface developers are suitable for developing.Type: GrantFiled: March 18, 1987Date of Patent: November 3, 1987Assignee: Ciba-Geigy AGInventor: Arnd Kriebel
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Patent number: 4693965Abstract: A method for manufacturing a chemically and spectrally sensitized silver halide emulsion is described, which comprises carrying out chemical ripening of the emulsion in the presence of an iridium salt and a photographic spectral sensitizing dye.Type: GrantFiled: November 27, 1985Date of Patent: September 15, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Mikio Ihama, Tadaaki Tani
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Patent number: 4683192Abstract: A silver halide photographic emulsion containing silver halide grains, the surface of which is a (110) crystal plane substantially composed of silver bromide or silver iodobromide is disclosed. A process for producing a silver halide photographic emulsion containing silver halide grains the surface of which is substantially composed of silver bromide or silver iodobromide, which comprises performing growth of the silver halide grains in an aqueous medium in the presence of a hydrophilic protective colloid and a compound accelerating the development of a (110) crystal plane is also disclosed.Type: GrantFiled: April 19, 1985Date of Patent: July 28, 1987Assignee: Fuji Photo Film Co., Ltd.Inventor: Shingo Nishiyama
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Patent number: 4681836Abstract: A silver halide photographic material having at least one silver halide emulsion layer which contains silver halide grains containing from 1.times.10.sup.-8 to 8.times.10.sup.-6 mole of a rhodium salt per mole of silver, and containing in said emulsion layer or another hydrophilic colloidal layer a compound represented by formula (I)R.sup.1 -NHNH-G-R.sup.2 (I)wherein R.sup.1 represents an aliphatic group or an aromatic group; R.sup.2 represents a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted alkoxy group, or a substituted or unsubstituted aryloxy group; and G represents a carbonyl group, a sulfonyl group, a sulfoxy group, a phosphoryl group, or an N-substituted or unsubstituted imino group; is exposed to imagewise pattern of light and then development-processed with a developer containing 0.15 mole/liter or more of sulfite ion and having a pH adjusted to from 9.5 to 12.Type: GrantFiled: November 20, 1986Date of Patent: July 21, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Nobuaki Inoue, Yoshio Inagaki, Kimitaka Kameoka
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Patent number: 4659654Abstract: A silver halide photographic light-sensitive emulsion contains silver halide particles, chemically sensitized, the average concentration of the silver iodide of which is from 0.5 to 10 mole % and which have inside part wherein not less than 20 mole percent silver iodide is present locally; and at least one cyanine dyes having the Formulas [I], [II] and [III] as herein described.Type: GrantFiled: September 26, 1985Date of Patent: April 21, 1987Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Iku Metoki, Akio Suzuki, Eiji Yoshida, Kiyoshi Sato, Masumi Hosaka
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Patent number: 4643965Abstract: A direct positive photographic light-sensitive material is described, comprising a support and at least one internal latent image type silver halide emulsion layer containing core/shell type silver halide grains which are composed of a silver halide core subjected to at least one of doping with metal ions and chemical sensitization, and a silver halide shell covering at least sensitivity sites of said core, and a binder, wherein said core/shell type silver halide grains consist of two or more kinds of grains each having a different average grain size, and the core of the core/shell type silver halide grains having a larger average grain size is doped with a larger amount of lead ions, cadmium ions, or Group VIII metal ions.Type: GrantFiled: May 24, 1984Date of Patent: February 17, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Satosi Kubota, Tetsuo Yoshida, Hideki Ohmatsu
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Patent number: 4639414Abstract: A heat developable light-sensitive material comprising a support having thereon (1) a light-sensitive silver halide emulsion, (2) at least one of a base and a base precursor, and (3) a binder, wherein the silver halide emulsion is one which is chemically sensitized in the presence of a sensitizing dye. With the heat developable light-sensitive material, decrease in sensitivity and formation of fog during preservation thereof are prevented.Type: GrantFiled: June 13, 1985Date of Patent: January 27, 1987Assignee: Fuji Photo Film Co., Ltd.Inventor: Yukihiko Sakaguchi
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Patent number: 4639416Abstract: An internal latent image-type silver halide emulsion containing core/shell type silver halide grains with a mean grain size of about 0.4 .mu.m or less, the grains comprising a core of chemically sensitized silver halide and a shell of silver halide covering at least the light-sensitive sites of the core and the surface of the grains being chemically sensitized wherein the core is chemically sensitized to such an extent that the difference between fog density F.sub.1 and fog density F.sub.2 as defined herein (i.e., internal fog density) is at least 0.10. This emulsion permits the formation of good reversal images in which D.sub.max is high and D.sub.min is low and, furthermore, has a superior storage stability.Type: GrantFiled: May 11, 1984Date of Patent: January 27, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Tetsuo Yoshida, Tadayoshi Kokubo
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Patent number: 4634661Abstract: A negative working photographic element is disclosed capable of producing a high contrast silver image. The photographic element is comprised of surface latent image forming monodispersed silver halide grains having a mean diameter of less than 0.7 .mu.m, a contrast enhancing arylhydrazide, and, in an amount sufficient to stabilize sensitivity, a carboxyalkyl substituted 3H-thiazoline-2-thione.Type: GrantFiled: July 18, 1985Date of Patent: January 6, 1987Assignee: Eastman Kodak CompanyInventor: Anthony Cavallaro
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Patent number: 4629678Abstract: An internal latent image-type direct positive silver halide light-sensitive material is described, comprising a support having at least one photographic emulsion layer thereon, wherein said layer contains internal latent image-type direct positive silver halide grains, the surfaces of which are chemically sensitized, wherein a compound of the general formula (I) is added as a finish additive to the photographic emulsion layer or at least one hydrophilic colloid layer adjacent to the photographic emulsion layer.General Formula (I): ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are defined as herein. The light-sensitive material exhibits a very satisfactory reversal performance and is greatly improved in stability over the course of time.Type: GrantFiled: October 29, 1984Date of Patent: December 16, 1986Assignee: Fuji Photo Film Co., Ltd.Inventor: Ashita Murai
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Patent number: 4623612Abstract: An improved method of developing silver halide photographic light-sensitive materials comprising at least one silver halide emulsion layer on a support is disclosed. In the improvement, said silver halide emulsion layer contains core/shell type silver halide grains having a shell thickness of 25 to 150 .ANG. wherein the surface of the core is subjected to chemical sensitization treatment and the surface of the shell is not subjected to chemical sensitization, and a developing solution contains a solvent for silver halide. It is possible to carry out spectral sensitization without causing a reduction in intrinsic sensitivity and to provide high-speed silver halide light-sensitive materials which are excellent in anti-fading property of latent images and excellent in stabilization with the passage of time using the above-described improved method.Type: GrantFiled: October 21, 1985Date of Patent: November 18, 1986Assignee: Fuji Photo Film Co., Ltd.Inventors: Toshihiro Nishikawa, Hatsumi Tanemura
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Patent number: 4621041Abstract: Disclosed is a method for plate-making which comprises imagewise exposing by scanning type flash exposure a lithographic printing plate comprising a support and at least a silver halide emulsion layer containing at least 70 mol % of silver chloride and prepared with addition of a water soluble iridium compound during emulsification or physical ripening of silver halide and a water soluble gold compound at any time before coating of the emulsion and thereafter subjecting the exposed emulsion to diffusion transfer development.Type: GrantFiled: July 11, 1984Date of Patent: November 4, 1986Assignee: Mitsubishi Paper Mills, Ltd.Inventors: Masahiko Saikawa, Eiji Kanada, Kazunaka Endo
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Patent number: 4618574Abstract: A negative working photographic element is disclosed capable of producing a high contrast silver image. The photographic element is comprised of surface latent image forming monodispersed silver halide grains having a mean diameter of less than 0.7 .mu.m, a contrast enhancing arylhydrazide, and, in an amount sufficient to reduce pepper fog while maintaining high contrast a polyhydroxybenzene and a carboxyalkyl-3H-thiazoline-2-thione.Type: GrantFiled: July 18, 1985Date of Patent: October 21, 1986Assignee: Eastman Kodak CompanyInventor: Anthony Cavallaro
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Patent number: 4618570Abstract: A silver halide photographic material having at least one layer of silver halide emulsion layers containing a silver halide having a silver chloride content of not less than 25 molar %, characterized in that at least one of said silver halide emulsion layers contains a silver halide sensitized with a compound having the following formula (Ia), and/or a compound having the following formula (Ib) and is hardened with a compound having the following formula (II) and/or a compound having the formula (III); ##STR1## in the above formulae (Ia), (Ib), (II) and (III), R.sub.1 to R.sub.20, Z.sub.1 and Z.sub.2, n.sub.1 and n.sub.2, Q and Q', L, p and q are defined in the specification.The photographic material of the invention not only shows a higher sensitivity, a lower infrared sensor fogging, a superior sharpness or color reproductivity and a superior whiteness but also exerts a good storage property with time or a lower change in sensitivity after storage.Type: GrantFiled: March 15, 1985Date of Patent: October 21, 1986Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Takashi Kadowaki, Kaoru Onodera
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Patent number: 4617258Abstract: A silver halide photographic material is disclosed. It contains per 100 g of silver at least 40 mg of a water-soluble compound comprising an element of group VIII of the periodic table and having a molecular weight of at least 100, and 1.2 to 120 mg of a black-and-white silver halide developing agent. The material has improved gradation characteristics and is subject to minimum variation in photographic characteristics.Type: GrantFiled: March 25, 1986Date of Patent: October 14, 1986Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Hiroshi Menjo, Nobuo Sakamoto, Yoshikazu Watanabe
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Patent number: 4617259Abstract: A silver halide color photographic material comprising a support having thereon at least a layer containing a group of silver halide grains having a relation that the larger an amount of silver of a grain is, the larger an amount of a content of silver iodide therein is, at a correlative coefficient of not less than 0.7 between a silver halide crystal grain size and a silver iodide content therein. The silver halide color photographic material has improved granularity and an improved gradient, and uses a small amount of silver.Type: GrantFiled: September 26, 1985Date of Patent: October 14, 1986Assignee: Fuji Photo Film Co., Ltd.Inventors: Tadashi Ogawa, Satoshi Nagaoka, Yuichi Ohashi
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Patent number: 4607006Abstract: A silver halide photographic light-sensitive material is described containing at least one electron-donative, silver halide-adsorptive compound represented by the following general formula (A) or (B), which is not a spectral sensitizing agent for silver halide or a nucleating agent:D--L--X (A)D--X (B)wherein D represents an electron donative atomic group comprising an aromatic ring or hetero ring, which may be unsubstituted or substituted with at least one substituent; L represents a linkage group containing at least one of C, N, S or O; and X represents a group which is adsorptive with a silver halide-adsorptive group containing at least one of C, N, S, O or Se, said N being optionally quarternized.Type: GrantFiled: October 9, 1984Date of Patent: August 19, 1986Assignee: Fuji Photo Film Co., Ltd.Inventors: Shigeo Hirano, Yasuhisa Sano, Haruo Takei, Tsutomu Miyasaka, Shinsaku Fujita
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Patent number: 4581328Abstract: An internal latent image core/shell silver halide photographic emulsion containing core/shell silver halide grains is disclosed, the grains comprising a silver halide core which is doped with a metal ion or chemically sensitized or is both doped with a metal ion and chemically sensitized, and a silver halide shell which covers at least a sensitivity speck of the core, wherein both added iodine ion and a polymer having a specific repeating unit described in the specification are present on the surface of the core/shell silver halide grains. The emulsion has a high sensitivity even without chemical sensitization of the surface of core/shell silver halide grains.Type: GrantFiled: November 16, 1984Date of Patent: April 8, 1986Assignee: Fuji Photo Film Co., Ltd.Inventor: Junichi Matsuyama
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Patent number: 4565778Abstract: Silver halide photographic materials with higher sensitivity and less fogging having at least one silver halide emulsion layer over a photographic base or support wherein the emulsion of said emulsion layer substantially contains core/shell-type silver halide grains or core/shell-type monodisperse silver halide grains, core portion of said grain containing silver iodide in a greater amount than that contained in shell portion of said grain and said emulsion is subjected to chemical ripening in the presence of a labile selenium compound, optionally with coexistence of a silver halide solvent, and said emulsion may contain further a specific phenol compound.Type: GrantFiled: March 26, 1984Date of Patent: January 21, 1986Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Akihiko Miyamoto, Hideki Takiguchi, Shoji Matsuzaka, Hiroshi Kashiwagi, Yoshiyuki Nonaka
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Patent number: 4504570Abstract: High aspect ratio tabular grain direct reversal silver halide emulsions are disclosed. The emulsions can be incorporated in photographic elements, such as multicolor photographic elements. Image transfer film units incorporating these direct reversal emulsions are specifically disclosed.Type: GrantFiled: December 23, 1983Date of Patent: March 12, 1985Assignee: Eastman Kodak CompanyInventors: Francis J. Evans, Richard L. Daubendiek, Ronald G. Raleigh
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Patent number: 4496652Abstract: Novel silver halide crystals useful for both negative and positive photographic elements are produced by balanced double jet precipitation. Using that process, silver halide adds preferentially to the (111) surfaces of tetradecahedral silver bromide or iodobromide crystals to form cubic crystals which have corners containing a different silver halide from that in the lateral surfaces. In a specific embodiment, a crystal has corners composed of silver bromochloride, while the crystal substrate consists of highly photosensitive silver iodobromide.Type: GrantFiled: June 16, 1980Date of Patent: January 29, 1985Assignee: E. I. Du Pont de Nemours and CompanyInventors: Eugene F. Haugh, Earle L. Kitts, Jr., Daniel J. Mickewich
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Patent number: 4495274Abstract: Direct positive silver halide photographic materials comprising a support, a silver halide emulsion layer comprising fogged silver halide particles prepared in the presence of a water soluble iridium salt or a water soluble rhodium salt, and a hydrophilic colloidal layer comprising (a) a compound selected from Formula I and II and (b) at least one compound selected from the group consisting of Formula III and a gold compound, said Formula I being ##STR1## wherein R.sub.1 is hydrogen, alkyl, --SO.sub.3 M, or --COOM, wherein M is selected from hydrogen, alkali metals, and ammonium, and R.sub.2 is selected from hydrogen and lower alkyls, said Formula II being ##STR2## wherein R.sub.3 is selected from hydrogen, alkyl, --SO.sub.3 M, and --COOM, and R.sub.4 is selected from hydrogen, alkyl, and --CH.sub.2 --S--(CH.sub.2).sub.n --Y', wherein n is an integer of from 1 to 3, and Y' is selected from hydrogen and --SO.sub.3 M, and said Formula III beingH.sub.2 N--Y--NH--Y].sub.m NH.sub.Type: GrantFiled: April 21, 1983Date of Patent: January 22, 1985Assignee: Konishiroku Photo Industry Co., Ltd.Inventor: Kazuhiro Yoshida
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Patent number: 4477561Abstract: A silver halide photographic material having formed on a support two or more layers that are sensitive to the lights of substantially the same spectral region but different in light sensitivity is disclosed. At least one of the layers other than the one having maximum light sensitivity contains at least 40 mg, per 100 g of silver, of a water-soluble compound containing an element of Group VIII of the periodic table which has a molecular weight of 100 or more. The material has a wide latitude for exposure, and this latitude will not vary greatly with time during storage.Type: GrantFiled: February 17, 1983Date of Patent: October 16, 1984Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Hiroshi Menjo, Yoshikazu Watanabe, Nobuo Sakamoto
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Patent number: 4469783Abstract: A silver halide photographic emulsion is described, which has halogen composition comprises at least 60 mole % of silver chloride, 40 mole % or less of silver bromide, and 5 mole % or less of silver bromide. Grain formation is performed in the presence of a silver halide solvent selected from the group consisting of tetrasubstituted thioureas and organic thioethers, and from 10.sup.-8 to 10.sup.-5 mole of a water-soluble iridium compound per mole of silver halide. This photographic emulsion exhibits high sensitivity and provides high contrast even by flash exposure. Thus, it is useful for the production of light-sensitive materials to be used in the production of printing plates in accordance with photographic engraving.Type: GrantFiled: June 3, 1983Date of Patent: September 4, 1984Assignee: Fuji Photo Film Co., Ltd.Inventors: Kenichi Kuwabara, Satoshi Kubota, Hiroyuki Mifune
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Patent number: 4459347Abstract: The use of oxythioamido substituted arylhydrazides in producing images in silver halide photographic elements is disclosed. The oxythioamido substituted arylhydrazide can be incorporated in photographic silver halide emulsions. The oxythioamido substituent is capable of promoting adsorption of the arylhydrazide to silver halide grain surfaces. In negative working surface latent image forming emulsions the oxythioamido substituted arylhydrazides permit higher speeds to be achieved. In direct positive internal latent image forming emulsions increased nucleation activity can be achieved.Type: GrantFiled: May 11, 1983Date of Patent: July 10, 1984Assignee: Eastman Kodak CompanyInventors: Richard L. Parton, James A. Friday
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Patent number: 4452882Abstract: A silver halide photographic light-sensitive material and a developing process used in connection with that material are disclosed. The material is comprised of a support having thereon a silver halide emulsion layer containing a silver halide emulsion in which at least 80 mole % of the whole silver halide is composed of silver chloride, the mean grain size thereof is less than 0.4 .mu.m, and which contains more than 1.times.10.sup.-6 mole of a water-soluble rhodium salt per mole of silver at an optional period before finishing the first ripening in the production step for the silver halide emulsion. The material also contains 1.times.10.sup.-5 to 1.times.10.sup.-2 mole of polyalkylene oxide having a molecular weight of at least 600 or a derivative thereof per mole of silver. The process involves imagewise exposing the material and processing it in a developer containing 0.05 to 0.5 mole/liter of a dihydroxybenzene series developing agent, 0 to 0.05 g/liter of an auxiliary developing agent, at least 0.Type: GrantFiled: April 29, 1983Date of Patent: June 5, 1984Assignee: Fuji Photo Film Co., Ltd.Inventors: Yoshitaka Akimura, Eiichi Okutsu, Shigenori Moriuchi, Naomi Saeki, Taiji Hashimura, Hiroyuki Mifune
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Patent number: 4451560Abstract: A method for forming a photosensitive element which comprises contacting silver halide in a plurality of spaced depressions in a surface with a mixture of a silver halide solvent and preformed sensitivity centers.Type: GrantFiled: November 15, 1982Date of Patent: May 29, 1984Assignee: Polaroid CorporationInventors: Arthur M. Gerber, Judith Loucks
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Patent number: 4444874Abstract: Photographic elements particularly adapted for forming direct-positive images are disclosed in which a radiation-sensitive core-shell emulsion layer and a silver halide emulsion layer incapable of forming a surface latent image within the direct-positive exposure latitude of the first emulsion layer and containing a grain population capable of internally trapping photolytically generated electrons are both present. The photographic elements are capable of exhibiting increased covering power, greater maximum density, and increased speed.Type: GrantFiled: September 15, 1982Date of Patent: April 24, 1984Assignee: Eastman Kodak CompanyInventors: Robert A. Silverman, Harry A. Hoyen
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Patent number: 4444865Abstract: Blended emulsions for use in forming a direct-positive image are disclosed. The emulsions are comprised of a first, radiation-sensitive core-shell grain population having a relatively low coefficient of variation and a second, substantially smaller size grain population capable of internally trapping photolytically generated electrons. Photographic elements incorporating the blended emulsions exhibit improved covering power and can exhibit enhanced speed.Type: GrantFiled: September 15, 1982Date of Patent: April 24, 1984Assignee: Eastman Kodak CompanyInventors: Robert A. Silverman, Harry A. Hoyen
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Patent number: 4439520Abstract: High aspect ratio chemically and spectrally sensitized tabular grain silver halide emulsions, photographic elements incorporating these emulsions, and processes for the use of the photographic elements are disclosed. In the tabular grain emulsions the silver halide grains having a thickness of less than 0.3 micron and a diameter of at least 0.6 micron have a high aspect ratio and account for at least 50 percent of the total projected area of the silver halide grains present.Type: GrantFiled: September 30, 1982Date of Patent: March 27, 1984Assignee: Eastman Kodak CompanyInventors: James T. Kofron, Robert E. Booms, Cynthia G. Jones, John A. Haefner, Herbert S. Wilgus, Francis J. Evans
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Patent number: 4433047Abstract: Photographic elements particularly adapted for forming direct-positive images are disclosed in which a radiation-sensitive core-shell emulsion layer and a silver halide emulsion layer incapable of forming a surface latent image within the direct-positive exposure latitude of the first emulsion layer and containing a grain population capable of internally trapping photolytically generated electrons are both present. The photographic elements are capable of exhibiting increased covering power, greater maximum density, and increased speed.Type: GrantFiled: September 15, 1982Date of Patent: February 21, 1984Assignee: Eastman Kodak CompanyInventors: Robert A. Silverman, Harry A. Hoyen
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Patent number: 4431731Abstract: An internal latent image silver halide emulsion is disclosed comprising core/shell silver halide particles having a chemically sensitized surface which are composed of a core of silver halide doped with metal ions and/or subjected to chemical sensitization and a shell which covers said core as far as to do at least the sensitive sites of said core and a binder, wherein said silver halide emulsions contain a polymer containing a repeating unit represented by the following general formula (I) in an amount of 2 mg to 1000 mg per mole of silver as the weight of said repeating units in said polymer: ##STR1## wherein R.sup.1 represents a hydrogen atom or an alkyl group and Q represents a group selected from the group consisting of the following (1)-(4): ##STR2## wherein q represents an integer of 2 to 4, ##STR3## wherein R.sup.2 and R.sup.3 each represents a hydrogen atom or an alkyl group, ##STR4## wherein Z.sup.Type: GrantFiled: February 17, 1982Date of Patent: February 14, 1984Assignee: Fuji Photo Film Co., Ltd.Inventors: Tadao Sugimoto, Ichizo Toya, Shigeharu Urabe, Shinji Sakaguchi
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Patent number: 4431730Abstract: A process for the preparation of an internal latent image type silver halide emulsion containing silver halide grains comprising a central core of silver halide doped with metal ions, chemically sensitized or a combination thereof and an outer shell of silver halide covering at least light-sensitive sites of the central core characterized in that the surface of the silver halide grains are chemically sensitized in the presence of a polymer containing the repeating unit represented by general formula (I) ##STR1## wherein symbols R.sup.1 and Q are defined in the specification.Type: GrantFiled: February 17, 1982Date of Patent: February 14, 1984Assignee: Fuji Photo Film Co., Ltd.Inventors: Shigeharu Urabe, Shinji Sakaguchi, Ichizo Toya, Tadao Sugimoto
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Patent number: 4430426Abstract: Silver halide emulsions lack stability in that their properties vary over a period of time. Various stabilizers have been used to reduce the rate and degree of variation. The combination of uracils and nitroso-substituted phenols has been found to provide a synergistic stabilization of speed in silver halide emulsions. Other stabilizers may be combined with those two classes to further improve the stability of the emulsion.Type: GrantFiled: June 4, 1982Date of Patent: February 7, 1984Assignee: Minnesota Mining and Manufacturing CompanyInventors: George W. Beebe, Philip Hine, Nelson B. O'Bryan, Steven M. Shor
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Patent number: 4419443Abstract: A silver halide photographic light-sensitive material is described comprising a support having thereon at least one silver halide emulsion layer wherein the silver halide emulsion has been chemically ripened in the presence of at least one compound containing at unit represented by the formula ##STR1## wherein M represents hydrogen, an alkali metal atom, or NH.sub.4. The silver halide photographic light-sensitive material shows high sensitivity without an accompanying increase in fog.Type: GrantFiled: November 10, 1981Date of Patent: December 6, 1983Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroyuki Mifune, Yoshiharu Fuseya, Shinpei Ikenoue
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Patent number: 4401754Abstract: A silver halide photographic emulsion characterized in that it comprises silver halide grains which are reduction-sensitized during the process of growing said grains and containing a compound of the formula ##STR1## wherein R.sub.1 and R.sub.2 are selected from the group consisting of a hydrogen atom, an alkyl group, an alkenyl group, an aryl group, an acyl group and a cycloalkyl group and R.sub.3, R.sub.4, R.sub.5 and R.sub.6 are selected from the group consisting of a hydrogen atom, a halogen atom, a hydroxy group, an alkyl group, an alkenyl group, a cycloalkyl group, an aryl group, an alkoxy group, an acyl group, a carboxyl group, an aldehyde group, an amino group, a sulfo group, an alkylthio group, an acylamino group, an aryloxy group, an arylthio group, an alkylamino group, an alkoxycabonyl group and a sulfonamide group. The emulsion exhibits both high sensitivity and improved stability as compared with prior art compositions.Type: GrantFiled: October 30, 1981Date of Patent: August 30, 1983Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Akio Suzuki, Hiroaki Shiozawa, Takeo Koitabashi, Hideki Takiguchi
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Patent number: 4395478Abstract: A radiation-sensitive emulsion for use in forming a direct-positive image is disclosed. The emulsion is comprised of core-shell silver halide grains. The shell portions of the grains contain polyvalent metal ions to reduce rereversal.Type: GrantFiled: November 12, 1981Date of Patent: July 26, 1983Assignee: Eastman Kodak CompanyInventor: Harry A. Hoyen
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Patent number: RE32097Abstract: Blended emulsions for use in forming a direct-positive image are disclosed. The emulsions are comprised of a first, radiation-sensitive core-shell grain population having a relatively low coefficient of variation and a second, substantially smaller size grain population capable of .Iadd.internally forming a latent image by .Iaddend.internally trapping photolytically generated electrons. Photographic elements incorporating the blended emulsions exhibit improved covering power and can exhibit enhanced speed.Type: GrantFiled: July 2, 1984Date of Patent: March 25, 1986Assignee: Eastman Kodak CompanyInventors: Robert A. Silverman, Harry A. Hoyen
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Patent number: RE32149Abstract: Photographic elements particularly adapted for forming direct-positive images are disclosed in which a radiation-sensitive core-shell emulsion layer and a silver halide emulsion layer incapable of forming a surface latent image within the direct-positive exposure latitude of the first emulsion layer and containing a grain population capable of internally .Iadd.forming a latent image by internally .Iaddend.trapping photolytically generated electrons are both present. The photographic elements are capable of exhibiting increased covering power, greater maximum density, and increased speed.Type: GrantFiled: July 2, 1984Date of Patent: May 20, 1986Assignee: Eastman Kodak CompanyInventors: Robert A. Silverman, Harry A. Hoyen