Mercaptan, Thioether, Thione, Disulfide Or Organic Bisulfite Patents (Class 430/611)
  • Patent number: 6737228
    Abstract: A black-and-white silver halide photographic film material has been provided, wherein said material has first and second major surfaces, at least one of which is coated with at least one light-sensitive silver halide emulsion layer, overcoated with a protective antistress layer, wherein said emulsion layer(s) have chemically and spectrally sensitized {111} tabular hexagonal emulsion grains or crystals rich in silver bromide in an amount covering at least 50% of the total projective grain surface of all grains, wherein said grains further have an average equivalent volume diameter in the range from 0.3 &mgr;m up to 1.5 &mgr;m and an average grain thickness of less than 0.30 &mgr;m, and an average amount of iodide from 0.05 mole % up to 0.5 mole % based on silver over the whole grain volume, characterized in that said material comprises, in an amount of at least 0.
    Type: Grant
    Filed: May 16, 2002
    Date of Patent: May 18, 2004
    Assignee: AGFA-Gevaert
    Inventors: Kathy Elst, Johan Loccufier
  • Patent number: 6737227
    Abstract: Thermally developable compositions such thermographic and photothermographic emulsions include certain heterocyclic disulfide compounds and ascorbic acid or reductone reducing agents. These compositions can be used in thermally developable materials such as thermographic and photothermographic materials to provide increased image density and shortened development time, and to allow development at lower temperatures. Such materials can have imaging layers on one or both sides of the support.
    Type: Grant
    Filed: March 7, 2003
    Date of Patent: May 18, 2004
    Assignee: Eastman Kodak Company
    Inventors: Doreen C. Lynch, Stacy M. Ulrich
  • Patent number: 6733959
    Abstract: Photothermographic materials prepared using aqueous formulations include silver halides that are chemically sensitized using certain tellurium-containing compounds. Such tellurium-containing chemical sensitizing compounds are generally provided in aqueous solution or in an aqueous solid particulate dispersion and can be represented by the following Structure I, II, or III: Te(L)m(X1)n  (II) Pd(X2)2[Te(R′)2]2  (III) wherein X represents the same or different COR, CSR, CNRRa, CR, PRRa, or P(OR)2 groups, R and Ra are independently alkyl, alkenyl, or aryl groups, L is a ligand derived from a neutral Lewis base, X1 and X2 independently represent a halo, OCN, SCN, S2CNRRa, S2COR, S2CSR S2P(OR)2, S2PRRa, SeCN, TeCN, CN, SR, OR, alkyl, aryl, N3, or O2CR group, R′ is an alkyl or aryl group, p is 2 or 4, m is 0, 1, 2, or 4, and n is 2 or 4 provided that when m is 0 or 2, n is 2 or 4, and when m is 1 or 4, n is 2.
    Type: Grant
    Filed: August 6, 2001
    Date of Patent: May 11, 2004
    Assignee: Eastman Kodak Company
    Inventors: Henry J. Gysling, David A. Dickinson, Mark Lelental, John W. Boettcher
  • Publication number: 20040086812
    Abstract: A silver halide color photographic lightsensitive material containing at least one compound capable of increasing photographic speed, the compound having at least three heteroatoms in its molecule, and wherein at least one layer of the silver halide emulsion layers comprises an emulsion, the emulsion consisting of a lightsensitive silver halide emulsion wherein 50% or more in number of all the silver halide grains are occupied by tabular grains having (111) faces as main planes, the tabular grains (i) composed of silver iodobromide or silver chloroiodobromide, (ii) having an equivalent circle diameter of 1.0 &mgr;m or more and a thickness of 0.15 &mgr;m or less, and (iii) composed of core portions of 0.1 &mgr;m or less thickness free of growth ring structure and composed of silver iodobromide and shell portions having ten or more dislocation lines.
    Type: Application
    Filed: October 23, 2003
    Publication date: May 6, 2004
    Applicant: FUJI PHOTO FILM CO., LTD.
    Inventors: Masaaki Miki, Yoshiyasu Inami, Junichiro Hosokawa
  • Patent number: 6727057
    Abstract: A heat-developable photosensitive material comprising at least one light-sensitive layer containing an organic silver salt, light-sensitive silver halide and a reducing agent and at least one light-insensitive layer on a support, wherein the heat-developable photosensitive material comprises a water-soluble metal phthalocyanine compound.
    Type: Grant
    Filed: March 31, 2003
    Date of Patent: April 27, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Keiichi Suzuki, Yoshiharu Yabuki
  • Patent number: 6720134
    Abstract: A silver halide photographic emulsion comprising grains, wherein 70% or more of the total projected area of the grains is occupied by silver halide grains each meeting requirements (a) to (d) below (a) the grain is composed of a tabular silver halide host grain having two mutually parallel main planes and aspect ratio of 2 or more, and a silver halide protrusion portion epitaxially junctioned on the surface of the host grain; (b) the silver bromide contents of both the host grain and the protrusion portion are 70 mol % or more; (c) the percentage of the silver amount in the protrusion is 12% or less of the silver amount in the host grain; and (d) the grain has a shallow electron-trapping zone.
    Type: Grant
    Filed: January 14, 2002
    Date of Patent: April 13, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yasushi Miyamoto, Toshihiro Nishikawa, Nobuyuki Haraguchi, Hideo Ikeda, Takayoshi Mori
  • Patent number: 6713241
    Abstract: Aqueous-based thermally sensitive emulsions and imaging materials include a mixture of binders in at least one imaging layer. These binder mixtures include from 70 to about 99 weight % of hydrophilic binders such as gelatin and gelatin derivatives, and the remainder of the total binder weight is composed of one or more hydrophobic binders or water-dispersible polymer latexes. These binder mixtures are particularly useful in imaging layers of thermographic and photothermographic materials and provide long term keeping and reduced crystallization of fatty acids.
    Type: Grant
    Filed: August 9, 2002
    Date of Patent: March 30, 2004
    Assignee: Eastman Kodak Company
    Inventors: Kathleen M. Vaeth, Charles L. Bauer, Jon A. Hammerschmidt, David M. Teegarden
  • Publication number: 20040058281
    Abstract: An image forming method using a photothermographic material comprising, on at least one side of a support, at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent and a binder, wherein the photothermographic material: 1) having a gamma value of 2.0 to 4.0 is developed in a thermal development device configured such that a distance between an exposing section and a developing section is not more than 50 cm; 2) having a silver salt of fatty acid at an application amount of 5 mmol/m2 to 18 mmol/m2 is developed in a thermal development device configured such that a distance between an exposing section and a developing section is not more than 50 cm; 3) is discharged from a thermal development device within 35 seconds after heating for thermal development is ceased.
    Type: Application
    Filed: August 21, 2003
    Publication date: March 25, 2004
    Inventors: Katsutoshi Yamane, Sumito Yamada, Eiichi Okutsu, Tomoyuki Ohzeki, Yutaka Oka
  • Patent number: 6709809
    Abstract: A silver salt photothermographic material is disclosed, comprising at least a light sensitive layer and at least a light insensitive layer, the light sensitive layer comprising organic silver salt grains, a light sensitive emulsion containing light sensitive silver halide grains and medium, a reducing agent and a binder, wherein at least one of the light sensitive layer and the light insensitive layer contains a silver-saving agent and the photothermographic material which has been subjected to thermal development at 123° C. for 13.5 sec. exhibits an average contrast of 2.0 to 6.0 within the density range of 0.25 to 2.0 on a characteristic curve of the photothermographic material.
    Type: Grant
    Filed: June 21, 2001
    Date of Patent: March 23, 2004
    Assignee: Konica Corporation
    Inventors: Hiroyuki Yanagisawa, Socman Ho Kimura
  • Patent number: 6703191
    Abstract: Thermally developable compositions such thermographic and photothermographic emulsions include certain triazine-thione compounds. These emulsions can be used in thermally developable materials such as thermographic and photothermographic materials to provide increased image density and shortened development time, and to allow development at lower temperatures. Such materials can have imaging layers on one or both sides of the support.
    Type: Grant
    Filed: January 14, 2003
    Date of Patent: March 9, 2004
    Assignee: Eastman Kodak Company
    Inventors: Doreen C. Lynch, Stacy M. Ulrich, Paul G. Skoug
  • Publication number: 20040043341
    Abstract: A photothermographic material is disclosed, comprising on a support a light-sensitive emulsion containing a light-insensitive organic silver salt and a light-sensitive silver halide, a reducing agent for silver ions and a binder, wherein the photothermographic material further comprises a compound represented by the following formula (A-1) or (B) and a compound represented by the following formula (A-2).
    Type: Application
    Filed: August 13, 2003
    Publication date: March 4, 2004
    Applicant: Konica Corporation
    Inventors: Kiyokazu Morita, Ayumu Nishijima
  • Patent number: 6699652
    Abstract: This invention relates to a silver halide photographic element comprising a support bearing a cyan dye image-forming unit comprised of at least one red-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, a magenta dye image-forming unit comprising at least one green-sensitive silver halide emulsion layer having associated therewith at least one magenta dye-forming coupler, and a yellow dye image-forming unit comprising at least one blue-sensitive silver halide emulsion layer having associated therewith at least one yellow dye-forming coupler, wherein at least one of the dye image forming units contains layers of differing sensitivities, and the layer of highest sensitivity contains a development promoting agent or a specific coupler as described herein, or a combination thereof, and a silver halide emulsion comprising tabular silver halide grains having associated therewith at least two dye layers comprising (a) an inner dye layer adjacent to the silver ha
    Type: Grant
    Filed: January 17, 2003
    Date of Patent: March 2, 2004
    Assignee: Eastman Kodak Company
    Inventors: Sharon G. Johnston, Stephen P. Singer, Drake M. Michno, James A. Friday, David R. Foster
  • Publication number: 20040038163
    Abstract: Disclosed is a photothermographic material comprising, on one side of a support, a photosensitive silver halide, a non-photosensitive silver salt of an organic acid, a reducing agent for silver ions and a binder, which is characterized by containing one or more phenol compounds as the reducing agent and one or more compounds satisfying at least one of the following requirements A and B in combination:
    Type: Application
    Filed: August 19, 2003
    Publication date: February 26, 2004
    Applicant: Fuji Photo Film Co., Ltd.
    Inventors: Yasuhiro Yoshioka, Makoto Suzuki
  • Publication number: 20040038161
    Abstract: The present invention provides the photothermographic material including a photosensitive silver halide, a reducing agent for reducing silver ions, a binder and a non-photosensitive organic silver salt, wherein the photosensitive silver halide has a silver iodide content ranging from 40 mol % to 100 mol %, and has a particle size ranging from 5 nm to 80 nm, and wherein the non-photosensitive organic silver salt is prepared in the presence of the photosensitive silver halide which has been preformed, such that the non-photosensitive organic silver salt includes the photosensitive silver halide.
    Type: Application
    Filed: August 7, 2003
    Publication date: February 26, 2004
    Inventor: Tomoyuki Ohzeki
  • Publication number: 20040033454
    Abstract: The present invention provides a photothermographic material, comprising a photosensitive silver halide, a non-photosensitive organic solvent salt, a reducing agent for a silver ion, and a binder on one face of a support, for being applied by using an organic solvent, the photothermographic material further comprising at least one compound selected from the group of compounds consisting of: a compound represented by the following general formula (1), a compound having a &bgr;-lactam ring, a compound having a group that is adsorptive to a silver halide and a group that reduces a silver halide and a precursor thereof: 1
    Type: Application
    Filed: August 4, 2003
    Publication date: February 19, 2004
    Inventors: Tomoyuki Ohzeki, Hiroyuki Mifune, Tadashi Inaba, Kohzaburoh Yamada, Katsuyuki Watanabe
  • Publication number: 20040029056
    Abstract: Disclosed are a thermal recording material having a thermal recording layer containing an electron-donating dye precursor and an electron-accepting compound, wherein the thermal recording layer comprises an electron-accepting compound of the general formula (I), 1
    Type: Application
    Filed: July 15, 2003
    Publication date: February 12, 2004
    Inventor: Hidetaka Tsukada
  • Publication number: 20040029054
    Abstract: Aqueous-based thermally sensitive emulsions and imaging materials include a mixture of binders in at least one imaging layer. These binder mixtures include from 70 to about 99 weight % of hydrophilic binders such as gelatin and gelatin derivatives, and the remainder of the total binder weight is composed of one or more hydrophobic binders or water-dispersible polymer latexes. These binder mixtures are particularly useful in imaging layers of thermographic and photothermographic materials and provide long term keeping and reduced crystallization of fatty acids.
    Type: Application
    Filed: August 9, 2002
    Publication date: February 12, 2004
    Applicant: Eastman Kodak Company
    Inventors: Kathleen M. Vaeth, Charles L. Bauer, Jon A. Hammerschmidt, David M. Teegarden
  • Patent number: 6689552
    Abstract: A color photographic silver halide material which can be developed to form a negative, at least 95 mol % of the silver halides of which consist of AgCl, and which contains at least one light-sensitive silver halide emulsion layer, the silver halide of which contains at least one compound of formulae (I), (II) and (III): [IrClnF6-n]2−M2+  (I) wherein n denotes 0 or an integer from 1 to 6 and M2+ denotes 1 or 2 cations with a total number of 2 positive charges, [Fe(CN)6]m−Mm+  (II) wherein m denotes 2 or 3 and Mm+ denotes 1 to 3 cations with a total number of m positive charges, wherein o denotes 0, 1 or 2 and R denotes an alkyl, aryl or aralkyl, is distinguished under scanning exposure and on analogue exposure by sharp contrast which is independent of exposure time and by a stable latent image.
    Type: Grant
    Filed: November 5, 2001
    Date of Patent: February 10, 2004
    Assignee: Agfa-Gevaert
    Inventors: Cuong Ly, Edgar Draber, Matthias Feigl, Günter Helling, Thomas Kaluschke, Michael Missfeldt, Maria Nietgen, Heinz-Horst Teitscheid, Ralf Weimann, Heinz Wiesen
  • Publication number: 20040023174
    Abstract: A photothermographic material comprising a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent for a silver ion and a binder on one surface of a support, wherein a silver behenate-content of the non-photosensitive organic silver salt is 40 to 70 mol %, and the photothermographic material comprises a compound that can be one-electron-oxidized to provide a one-electron oxidation product, which further releases at least 1 electron, one of during and after a subsequent reaction.
    Type: Application
    Filed: April 1, 2003
    Publication date: February 5, 2004
    Inventors: Tomoyuki Ohzeki, Kohzaburoh Yamada
  • Patent number: 6686115
    Abstract: A blue-sensitive, radiographic silver halide film comprises a silver halide emulsion layer comprising predominantly tabular silver halide grains that have an aspect ratio of at least 15, a grain thickness of at least 0.1 &mgr;M, and comprise at least 90 mol % bromide and from about 0.5 to about 2.75 mol % iodide, based on total silver halide. Substantially all of the iodide is present in an internal localized portion of the tabular silver halide grains that excludes the surface of the grains. The tabular silver halide grains are dispersed in a hydrophilic polymeric vehicle mixture comprising at least 0.5% of oxidized gelatin, based on the total dry weight of the polymeric vehicle mixture in the emulsion layer. In addition, the tabular grain emulsion includes a mercapto-substituted benzothiazole, benzoxazole, or benzimidazole to provide desired image tone and processability.
    Type: Grant
    Filed: March 26, 2003
    Date of Patent: February 3, 2004
    Assignee: Eastman Kodak Company
    Inventors: Robert E. Dickerson, Richard F. Davis, Susan K. Mroczek
  • Patent number: 6686143
    Abstract: This invention relates to a photographic element comprising a support and a silver halide emulsion layer, the emulsion layer comprising a water soluble Au(I) complex having the formula [L—Au—L]n−M+n wherein the complex is symmetrical; L is an organothiosulfonato ligand which is an antifogging, stabilizing, or sensitizing compound, n is 1 to 4, and M is a cationic counterion. This invention further relates to a silver halide photographic element comprising a support and a silver halide emulsion layer, the emulsion layer comprising an organothiosulfonato Au(I) complex having the formula [A—SO2S—Au—SSO2—A]n−M+n wherein M is a cationic counterion; A is a substituted or unsubstituted organic group; and n is 1 to 4; and wherein the compound is symmetrical. It further relates to a method of preparing a silver halide emulsion utilizing said organothiosulfonato Au(I) complexes.
    Type: Grant
    Filed: August 7, 2002
    Date of Patent: February 3, 2004
    Assignee: Eastman Kodak Company
    Inventors: Roger Lok, Brian P. Cleary, Alton L. Chitty, Weimar W. White
  • Publication number: 20040018458
    Abstract: The present invention provides a photothermographic material including a support having disposed on one surface of the support, at least one image forming layer containing a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent, a development accelerator and a binder, and at least one protective layer on the identical surface, wherein 50% by mass or more of the binder contained in the image forming layer is a water soluble binder, and the reducing agent is contained in the form of a solid dispersion.
    Type: Application
    Filed: May 15, 2003
    Publication date: January 29, 2004
    Inventor: Hajime Nakagawa
  • Patent number: 6682878
    Abstract: A thermal development photosensitive material suitable for medical diagnoses, industrial photography, printing and COM. The material contains at least one photosensitive silver halide, a non-photosensitive organic silver salt, a binder, at least one of compounds represented by the following formula (I) and at least one of compounds represented by the following formula (II) on one surface of a substrate. The material has high sensitivity and provides an image with a tone close to a pure black tone.
    Type: Grant
    Filed: December 5, 2001
    Date of Patent: January 27, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kouta Fukui, Yasuhiro Yoshioka
  • Publication number: 20040013984
    Abstract: Organic solvent-based photothermographic materials comprise one or more mercaptotriazoles represented by the following Structure I as toner(s): 1
    Type: Application
    Filed: July 11, 2002
    Publication date: January 22, 2004
    Applicant: Eastman Kodak Company
    Inventors: Doreen C. Lynch, Stacy M. Ulrich, Chaofeng Zou
  • Publication number: 20040005521
    Abstract: A silver salt photothermographic material exhibiting enhanced image quality and superior uniformity without causing uneven density is disclosed, comprising on a support a light-sensitive layer comprising a light-sensitive emulsion containing organic silver salt grains and light-sensitive silver halide grains, a reducing agent and a binder and a conductive layer, wherein the conductive layer contains at least one of compounds represented by the following general formulas: 1 (Rf2)—(A2)s LiO3S—(CF2)m—SO3Li MO3S—(CF2)t—SO3M L[O3S—(CF2)u—SO3]
    Type: Application
    Filed: June 10, 2003
    Publication date: January 8, 2004
    Inventor: Shinji Kudo
  • Publication number: 20030224309
    Abstract: A silver halide photosensitive material comprises at least one light sensitive silver halide emulsion layer on a support. The silver halide photosensitive material contains at least one compound capable of undergoing a one-electron oxidation to thereby form a one-electron oxidation product thereof, the one-electron oxidation product being capable of releasing further one or more electrons, and at least one reducing compound having a C/H value of 3 or less, and another reducing compound having a C/H value of more than 3, the C/H value representing a ratio of (the number of Group IV elements)/(the sum of Groups III, V, VI and VII elements).
    Type: Application
    Filed: March 10, 2003
    Publication date: December 4, 2003
    Applicant: FUJI PHOTO FILM CO., LTD.
    Inventors: Naoki Asanuma, Kohzaburoh Yamada, Yasuhiro Shimada
  • Patent number: 6649334
    Abstract: A silver halide photographic emulsion wherein a variation coefficient of an equivalent-circle diameter of all the silver halide grains is 40% or less, and 50% or more of the total projected area is occupied by tabular grains satisfying requirements (i) to (v): (i) silver iodobromide having (111) faces as principal surfaces; (ii) the equivalent-sphere diameter of 0.5 &mgr;m or less, a thickness of 0.20 &mgr;m or less, and an average aspect ratio of 3 or more; (iii) a silver iodide content of 2 mol % or more and 6 mol % or less; (iv) a multiple-structure having a quintuple structure or more in which a silver iodide distribution has at least two maximums from a center to an edge, the first maximum is in a range of 3 to 25% by a silver amount constituting grains, and the second maximum is in a range of 50 to 80%; and (v) ten or more of dislocation lines per grain are present at a fringe portion.
    Type: Grant
    Filed: January 18, 2002
    Date of Patent: November 18, 2003
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Hideo Ikeda
  • Publication number: 20030203322
    Abstract: The present invention provides a spectrally sensitized photothermographic silver halide element support having a first surface and a second surface, a photothermographic composition that is to be exposed to a laser being disposed on the first surface of the support. The element has at least one back layer disposed on the second surface of the support. The photothermographic composition comprises silver halide emulsion grains having a number average grain size of less than 0.1 &mgr;m and that are spectrally sensitized with a sensitizing dye having a spectral sensitivity that corresponds to the spectral properties of the laser. The photothermographic composition further comprises an organic silver salt, a reducing agent for silver ions, and at least one dye. In addition, the photothermographic composition has a transmission optical density greater than 0.1 at the exposure wavelength, and the back layer has a transmission optical density greater than 0.1 at the exposure wavelength.
    Type: Application
    Filed: December 23, 2002
    Publication date: October 30, 2003
    Applicant: Eastman Kodak Company
    Inventors: Thomas C. Geisler, Thomas J. Kub, Darlene F. Stewart, Mark C. Skinner, Bryan V. Hunt
  • Publication number: 20030203329
    Abstract: A silver halide photosensitive material containing a compound selected from Types 1-4 below which is capable of undergoing a one-electron oxidation to form a one-electron oxidation product (OEOP), and a reducing compound (Type 1) the OEOP is capable of releasing further two or more electrons accompanying a subsequent bond cleavage reaction, (Type 2) the OEOP is capable of releasing further one electron accompanying a subsequent bond cleavage reaction, and the compound having, in its molecule, two or more groups adsorptive to silver halide, (Type 3) the OEOP is capable of releasing further one or more electrons after going through a subsequent bond forming process, and (Type 4) the OEOP is capable of releasing further one or more electrons after going through a subsequent intramolecular ring cleavage reaction.
    Type: Application
    Filed: February 7, 2003
    Publication date: October 30, 2003
    Applicant: Fuji Photo Film Co., Ltd.
    Inventors: Kohzaburoh Yamada, Naoki Asanuma
  • Patent number: 6638708
    Abstract: The present disclosure relates to dispersions of silver (carboxylate-n-alkyl thiolate). The carboxylates are typically silver salts of long chain fatty acids and the n-alkyl thiolate is preferably 1-dodecanethiol. These silver (carboxylate-n-alkyl thiolate) particles can be used to formulate imaging forming compositions that are useful in aqueous thermographic or photothermographic imaging elements.
    Type: Grant
    Filed: July 22, 2002
    Date of Patent: October 28, 2003
    Assignee: Eastman Kodak Company
    Inventors: Peter J. Ghyzel, Mark Lelental, David A. Dickinson, Alan R. Pitt, Trevor J. Wear
  • Publication number: 20030198905
    Abstract: A silver halide color photosensitive material has at least one blue-sensitive silver halide emulsion layer containing a yellow coupler, at least one green-sensitive silver halide emulsion layer containing a magenta coupler, at least one red-sensitive silver halide emulsion layer containing a cyan coupler, and at least one non-lightsensitive layer, on a support. The photosensitive material contains, in at least one of the layers, a compound having a reducing group and a compound having at least three hetero atoms capable of increasing a photographic speed of the photosensitive material in comparison with the case where the material does not contain the same.
    Type: Application
    Filed: November 19, 2002
    Publication date: October 23, 2003
    Applicant: FUJI PHOTO FILM CO., LTD.
    Inventors: Junichiro Hosokawa, Kohzaburoh Yamada, Yasuhiro Shimada
  • Patent number: 6635413
    Abstract: A process for producing a lightsensitive silver halide emulsion comprising silver halide grains, wherein the emulsion contains tabular silver halide grains in an amount of at least 50% of the total projected area of all the silver halide grains, the average iodine content of all the silver halide grains is at least 2 mol %, and the tabular silver halide grains have at least 10 dislocation lines per grain, wherein the process comprises (step 1) set fourth below, and the process comprises a step of performing chemical sensitization so that a selenium sensitizer is added in an amount of 2.
    Type: Grant
    Filed: March 8, 2000
    Date of Patent: October 21, 2003
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoshiyasu Inami, Hirotomo Sasaki, Hiroshi Takeuchi, Shunichi Aida
  • Publication number: 20030190565
    Abstract: A heat developable image recording material including a photosensitive silver halide, a reducing agent for silver ions, a binder and non-photosensitive organic acid silver salt particles on one side of the surface of a substrate. A content of silver behenate in the non-photosensitive organic acid silver salt particles is 90 mol % to 100 mol %, and at least one kind of mercapto compound is contained in a surface of the substrate at the same side as a layer having the photosensitive silver halide. The heat developable image recording material includes a compound represented by following the general formula (1) wherein, R21, R22 and R23 each independently represent a substituted or non-substituted alkyl group. When R21, R22 or R23 have a substituent, the substituent is a halogen atom etc. The non-photosensitive organic particles are prepared from organic acids including at least behenic acid and erucic acid, and a content of the erucic acid is 0.000001 mol % to 0.4 mol %.
    Type: Application
    Filed: October 24, 2002
    Publication date: October 9, 2003
    Inventors: Itsuo Fujiwara, Seiichi Yamamoto, Takayoshi Oyamada
  • Patent number: 6627375
    Abstract: A silver halide photographic material is disclosed, comprising a support having provided thereon at least a silver halide emulsion layer, which contains at least one compound represented by the following formula (I), and has a characteristic curve of gamma value being 5.0 or more in optical density of from 0.3 to 3.0 on the characteristic curve shown on the orthogonal axis of coordinates having equal unit length expressed by logarithmic exposure amount (x axis) and optical density (y axis): (X)l—(L)m—(A—B)n  (I) wherein X represents a silver halide-adsorptive group having at least one of N, S, P, Se and Te atom, or a light absorptive group; L represents a divalent linking group having at least one of C, N, S and O atom; A represents an electron donative group; B represents a releasing group or a hydrogen atom, which forms radical A. by releasing or deproton after oxidation; l and m each represents an integer of from 0 to 3; and n represents 1 or 2.
    Type: Grant
    Filed: December 21, 2001
    Date of Patent: September 30, 2003
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Shoji Yasuda
  • Patent number: 6620577
    Abstract: Photothermographic imaging materials having increased photospeed are provided by certain selenium chemical sensitizers that are added during the formulation of a photothermographic emulsion. These selenium chemical sensitizers can be used alone or in combination with other sulfur, tellurium, or gold chemical sensitizers as well as with oxidatively decomposed sulfur-containing compounds.
    Type: Grant
    Filed: February 25, 2002
    Date of Patent: September 16, 2003
    Assignee: Eastman Kodak Company
    Inventors: Doreen C. Lynch, Andrea L. Opatz, Henry J. Gysling, Sharon M. Simpson
  • Publication number: 20030162134
    Abstract: A photothermographic material that comprises a support having thereon one or more thermally-developable imaging layers comprising a binder and in reactive association, a photosensitive silver halide, a non-photosensitive source of reducible silver ions, and a reducing composition for the non-photosensitive source reducible silver ions. The thermally-developable layers further comprises one or more radiation absorbing compounds that provide a total absorbance of greater than 0.6 and up to and including 3 in the thermally-developable imaging layer(s). These photothermographic materials exhibit reduced mottle without significant loss in sensitivity.
    Type: Application
    Filed: December 5, 2001
    Publication date: August 28, 2003
    Applicant: Eastman Kodak Company
    Inventors: Bryan V. Hunt, Steven H. Kong, William D. Ramsden, Gary E. Labelle
  • Publication number: 20030157447
    Abstract: A silver halide photographic light-sensitive emulsion comprising a silver halide and a compound represented by the following Formula (I): 1
    Type: Application
    Filed: July 19, 2002
    Publication date: August 21, 2003
    Inventors: Tatsuo Tanaka, Nobuaki Kagawa, Yoshiko Iwai, Tomohiro Oshiyama
  • Patent number: 6605418
    Abstract: Thermally developable compositions such thermographic and photothermographic emulsions include certain quaternary phthalazine compounds. These emulsions can be used in thermally developable materials such as thermographic and photothermographic materials to provide improved sensitometric and post processing properties. Such materials can have imaging layers on one or both sides of the support.
    Type: Grant
    Filed: October 28, 2002
    Date of Patent: August 12, 2003
    Assignee: Eastman Kodak Company
    Inventors: William D. Ramsden, Chaofeng Zou
  • Publication number: 20030138738
    Abstract: A photothermographic material that comprises a support having thereon one or more thermally-developable imaging layers comprising a binder and in reactive association, a photosensitive silver halide, a non-photosensitive source of reducible silver ions, and a reducing composition for the non-photosensitive source reducible silver ions. The thermally-developable layers further comprises one or more radiation absorbing compounds that provide a total absorbance of greater than 0.6 and up to and including 3 in the thermally-developable imaging layer(s). These photothermographic materials are independently coated and dried while the material is conveyed at a rate of at least meters per minute.
    Type: Application
    Filed: December 5, 2001
    Publication date: July 24, 2003
    Applicant: Eastman Kodak Company
    Inventors: Bryan V. Hunt, Steven H. Kong, William D. Ramsden, Gary E. Labelle
  • Patent number: 6593075
    Abstract: A silver halide photographic light-sensitive material having at least one emulsion layer comprising silver halide grains, with the emulsion layer further comprising at least one compound represented by the following formula (I) and at least one compound represented by the following formula (II), (III), (IV-1), (IV-2), (V-1), (V-2), (V-3) or (VI): (X&Parenclosest;1&Parenopenst;L&Parenclosest;m&Parenopenst;A—B)n  (I)  (Het&Parenclosest;k1&Brketopenst;&Parenopenst;Q1&Parenclosest;k2&Parenopenst;Hy)]k3  (III) wherein the substituents as defined herein the specification.
    Type: Grant
    Filed: July 24, 2000
    Date of Patent: July 15, 2003
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shinichi Ichikawa, Takeshi Suzumoto, Kohzaburoh Yamada, Tadashi Inaba
  • Patent number: 6593073
    Abstract: A silver halide photographic element comprises at least one silver halide emulsion layer comprising a silver halide emulsion comprising core/shell silver halide grains wherein the core region comprises silver bromide with from about 5 to about 20% silver iodide and the shell region comprises silver bromide with about 0.1 to about 10% silver iodide and said layer contains a fragmentable electron donor compound of the formula X—Y′ or a compound which contains a moiety of the formula —X—Y′; wherein X is an electron donor moiety, Y′ is a leaving proton H or a leaving group Y, with the proviso that if Y′ is a proton, a base, &bgr;−, is covalently linked directly or indirectly to X, and wherein: 1) X—Y′ has an oxidation potential between 0 and about 1.
    Type: Grant
    Filed: December 20, 1999
    Date of Patent: July 15, 2003
    Assignee: Eastman Kodak Company
    Inventors: Jon N. Eikenberry, Yun C. Chang
  • Publication number: 20030118952
    Abstract: The second silver halide photosensitive material comprises a substrate and at least one photosensitive silver halide emulsion layer formed thereon, the silver halide photosensitive material comprising at least two types of silver halide grains with different projected areas having photosensitivity in the same photosensitivity range; silver halide grains having a larger projected area having a refractive index n1 and an average thickness a, and silver halide grains having a smaller projected area having a refractive index n2 and an average thickness b; and the silver halide grains satisfying the conditions defined by the following equation (1):
    Type: Application
    Filed: May 23, 2002
    Publication date: June 26, 2003
    Applicant: FUJI PHOTO FILM CO., LTD.
    Inventors: Kiyoteru Miyake, Masahiro Asami
  • Patent number: 6566043
    Abstract: The present invention is to provide a silver halide photographic light-sensitive material comprising a support having thereon a light-sensitive silver halide emulsion layer comprising a compound represented by Formula, Formula 1 Z—S—X wherein Z represents a group represented by Formula 1-2; X represents a hydrogen atom or Z—S—, wherein A1, A2, A3, A4, and A5 each represent ═N—, ═N(→O)—, or ═CR91—, in which R91 represents a substituent, and at least two of A1, A2, A3, A4, and A5 are respectively ═N(→O)— and ═CR91—.
    Type: Grant
    Filed: August 30, 2001
    Date of Patent: May 20, 2003
    Assignee: Konica Corporation
    Inventors: Emiko Kataoka, Nobuaki Kagawa, Tatsuo Tanaka
  • Patent number: 6558894
    Abstract: A photothermographic material comprising, on one surface of a support, at least one kind of photosensitive silver halide, a silver salt of an organic acid, a reducing agent for silver ions, and a binder, wherein (1) said material further comprises two or more kinds of organic polyhalogenated compounds, and (2) a melting point of a mixture which consists of the organic polyhalogenated compounds in the same content ratio as the content ratio of said compounds in the photothermographic material is in the range of from −10° C. to 50° C. relative to a heat development temperature for the photothermographic material. The photothermographic material of the present invention shows high sensitivity and superior storability before heat development, and the material can be used for medical images, photoengraving and the like.
    Type: Grant
    Filed: January 11, 2001
    Date of Patent: May 6, 2003
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Kouta Fukui
  • Publication number: 20030068592
    Abstract: A silver halide photographic emulsion comprising grains, wherein 70% or more of the total projected area of the grains is occupied by silver halide grains each meeting requirements (a) to (d) below
    Type: Application
    Filed: January 14, 2002
    Publication date: April 10, 2003
    Applicant: FUJI PHOTO FILM CO., LTD.
    Inventors: Yasushi Miyamoto, Toshihiro Nishikawa, Nobuyuki Haraguchi, Hideo Ikeda, Takayoshi Mori
  • Patent number: 6534226
    Abstract: This invention comprises an imaging element comprising an imaging layer having associated therewith a compound of Structure I: In the above Structure I, the substituents are as defined in the application. Such compounds have good reactivity and can by used to block photographically useful compounds such as developing agents until thermally activated under preselected conditions. Compounds according to the present invention are especially useful in color photothermographic imaging elements.
    Type: Grant
    Filed: November 20, 2000
    Date of Patent: March 18, 2003
    Assignee: Eastman Kodak Company
    Inventors: Zbyslaw R. Owczarczyk, David T. Southby, Xiqiang Yang
  • Patent number: 6514678
    Abstract: Aqueous-based photothermographic materials have improved stability to increase in Dmin during aging by including certain water-soluble or water-dispersible antifoggants that have a pKa of 8 or less. These antifoggants are represented by Structure I: R1—SO2—C(R2)R3—(CO)m—(L)n—SG  I wherein R1 is an aliphatic or cyclic group, R2 and R3 are independently hydrogen or bromine as long as at least one of them is bromine, L is an aliphatic divalent linking group, m and n are independently 0 or 1, and SG is a solubilizing group having a pKa of 8 or less.
    Type: Grant
    Filed: December 11, 2001
    Date of Patent: February 4, 2003
    Assignee: Eastman Kodak Company
    Inventors: George J. Burgmaier, Roger L. Klaus
  • Patent number: 6514683
    Abstract: This invention comprises a photographic element comprising at least one light-sensitive silver halide emulsion layer containing a fragmentable electron donating compound of the formula: X—Y′ or a compound which contains a moiety of the formula —X—Y′; wherein X is an electron donor moiety, Y′ is a leaving proton H or a leaving group Y, with the proviso that if Y′ is a proton, a base, &bgr;−, is present in the emulsion layer, and wherein: 1) X—Y′ has an oxidation potential between 0 and about 1.4 V; and 2) the oxidized form of X—Y′ undergoes a bond cleavage reaction to give the radical X• and the leaving fragment Y′; and 3) the radical X• has an oxidation potential ≦−0.
    Type: Grant
    Filed: January 5, 2001
    Date of Patent: February 4, 2003
    Assignee: Eastman Kodak Company
    Inventors: Annabel A. Muenter, Steven P. Szatynski, Sharon G. Johnston
  • Patent number: 6506548
    Abstract: This invention relates to a silver halide photographic element comprising at least one silver halide emulsion layer and further comprising an antifoggant represented by the following Structure I: wherein R1 is an aliphatic or cyclic group, R2 and R3 are independently hydrogen or bromine as long as at least one of them is bromine, L is a divalent linking group, m and n are independently 0 or 1, and SG is a solubilizing group that has a pKa of 8 or less.
    Type: Grant
    Filed: December 11, 2001
    Date of Patent: January 14, 2003
    Assignee: Eastman Kodak Company
    Inventors: Roger L. Klaus, George J. Burgmaier, Jon N. Eikenberry, Jerzy Z. Mydlarz, Nicholas E. Grzeskowiak
  • Publication number: 20030008249
    Abstract: A silver halide photographic emulsion wherein a variation coefficient of an equivalent-circle diameter of all the silver halide grains is 40% or less, and 50% or more of the total projected area is occupied by tabular grains satisfying requirements (i) to (v):
    Type: Application
    Filed: January 18, 2002
    Publication date: January 9, 2003
    Applicant: FUJI PHOTO FILM CO., LTD.
    Inventor: Hideo Ikeda