Polyhetero Atom Ring Fused To Another Ring Having Polyhetero Atoms Patents (Class 430/615)
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Patent number: 7455959Abstract: The invention provides a color photographic element comprising at least one light-sensitive silver halide emulsion layer or a non silver-containing light-insensitive layer, in which at least one of these layers contains a colorless imidazole compound of formula (I) that undergoes less than 10% chemical or redox reaction with oxidized developer and which enables the photographic speed of the element to be increased by at least 0.Type: GrantFiled: October 1, 2004Date of Patent: November 25, 2008Assignee: Eastman Kodak CompanyInventors: Bernard A. Clark, Philip A. Allway, Tania Zuberi, Stephen P. Singer, Charles E. Heckler, Louis E. Friedrich
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Patent number: 7384731Abstract: A method for forming color images comprising subjecting a silver halide color photosensitive material to a development processing in the presence of a compound (A) defined below, wherein the silver halide color photosensitive material having a blue-sensitive unit, a green-sensitive unit and a red-sensitive unit, each of which comprises at least one silver halide emulsion layer, and at least one non-light-sensitive layer on a support, compound (A): a heterocyclic compound having one or two hetero atoms, the heterocyclic compound being capable of increasing speed of the silver halide color photosensitive material by the presence thereof in comparison to the case where the heterocyclic compound is absent.Type: GrantFiled: September 21, 2004Date of Patent: June 10, 2008Assignee: FUJIFILM CorporationInventors: Junichiro Hosokawa, Naoharu Kiyoto, Yoshio Ishii, Takanori Hioki, Katsumi Kobayashi, Takashi Hoshimiya
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Patent number: 7303851Abstract: Disclosed is a silver halide photographic light-sensitive material wherein a silver halide emulsion layer and/or a hydrophilic colloid layer contains at least one hydrazine derivative, and a silver halide emulsion is spectrally sensitized with a particular dye, and which contains a benzotriazol compound. There is provided a silver halide photographic light-sensitive material that exhibits superior residual color property and can provide stable photographic performance even after a long term running with a reduced silver amount.Type: GrantFiled: September 29, 2003Date of Patent: December 4, 2007Assignee: Fujifilm CorporationInventors: Mitsunori Hirano, Kunio Ishigaki, Tokuju Oikawa
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Patent number: 7267935Abstract: Incorporating a crown ether-alkali metal complex cation of an enolate anion of an aldehyde having at least one electron withdrawing group in the alpha (?) position, provides thermally developable materials with imaging properties that have little change with changes in humidity. Both photothermographic and thermographic materials are provided, and particularly photothermographic materials having lower silver coverage.Type: GrantFiled: June 19, 2006Date of Patent: September 11, 2007Assignee: Carestream Health, Inc.Inventors: Sharon M. Simpson, Kumars Sakizadeh
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Patent number: 7232652Abstract: A photothermographic material including, on at least one side of a support, an image forming layer including at least a photosensitive silver halide, a first organic silver salt, a reducing agent, and a binder, and at least one non-photosensitive layer which is disposed on the same side as the image forming layer and farther from the support than the image forming layer, wherein 50% or more of a total projected area of the photosensitive silver halide is occupied by tabular grains having a silver iodide content of 40 mol % or higher and an aspect ratio of 2 or more, and the non-photosensitive layer comprises a second organic silver salt, and an image forming method using the same. The invention provides a photothermographic material and an image forming method excellent in image tone and image storability.Type: GrantFiled: November 7, 2005Date of Patent: June 19, 2007Assignee: Fujifilm CorporationInventor: Kouta Fukui
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Patent number: 7175977Abstract: A black and white monosheet thermographic recording material comprising a support and a thermosensitive element, the thermosensitive element containing a substantially light-insensitive organic silver salt, an organic reducing agent therefor in thermal working relationship therewith, a binder and at least one five-membered heterocyclic ring compound selected from the group consisting of optionally substituted, optionally annelated 1-thia-2,3-diazole compounds; optionally substituted, optionally annelated 1-thia-2,5-diazole compounds; optionally substituted 1-thia-2,4-diazole compounds; optionally substituted 1-thia-3,4-diazole compounds; optionally substituted thiatriazole compounds; optionally substituted, optionally annelated 1-seleno-2,3-diazole compounds; optionally substituted, optionally annelated 1-seleno-2,5-diazole compounds; optionally substituted 1-seleno-2,4-diazole compounds; optionally substituted 1-seleno-3,4-diazole compounds; and optionally substituted selenotriazole compounds, with the proviType: GrantFiled: November 30, 2004Date of Patent: February 13, 2007Assignee: Agfa-GevaertInventors: Ingrid Geuens, Johan Loccufier
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Patent number: 7153638Abstract: A silver halide color photosensitive material comprising a support and, superimposed thereon, a blue-sensitive layer unit, a green-sensitive layer unit and a red-sensitive layer unit, each of these light-sensitive layer units composed of at least one silver halide emulsion layer, together with at least one nonphotosensitive layer, wherein at least one compound (A) and at least one compound (B) are contained, the compound (A) being a heterocyclic compound of less than 4.5 C log P which when added, is capable of enhancing the sensitivity of the silver halide color photosensitive material as compared with that exhibited when not added, the compound (B) being a heterocyclic compound of 4.5 or greater C log P which when added, is capable of enhancing the sensitivity of the silver halide color photosensitive material as compared with that exhibited when not added.Type: GrantFiled: February 25, 2005Date of Patent: December 26, 2006Assignee: Fuji Photo Film Co., Ltd.Inventors: Junichiro Hosokawa, Takanori Hioki
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Patent number: 7125657Abstract: The present invention provides a photothermographic material including a support having disposed thereon an image-forming layer that contains at least a non-photosensitive organic silver salt, a photosensitive silver halide, a reducing agent and a binder, and further including a compound represented by the following formula (I): A-(W)n-P??(I) wherein A represents an atomic group having at least two mercapto groups as the substituent; W represents a divalent linking group; n represents 0 or 1; and P represents a pyrazolidone group.Type: GrantFiled: December 16, 2003Date of Patent: October 24, 2006Assignee: Fuji Photo Film Co., Ltd.Inventors: Katsuyuki Watanabe, Hiroyuki Mifune
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Patent number: 7097963Abstract: Black-and-white, aqueous-based, silver halide-containing photothermographic materials have increased stability after imaging with the incorporation of at least 0.0002 mol/m2 of a halogen-substituted tetraazaindene compound.Type: GrantFiled: April 18, 2005Date of Patent: August 29, 2006Assignee: Eastman Kodak CompanyInventors: Chaofeng Zou, Kumars Sakizadeh, George J. Burgmaier, Roger L. Klaus
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Patent number: 7074550Abstract: A silver halide color photosensitive material comprising a support and, superimposed thereon, at least one blue-sensitive silver halide emulsion layer, green-sensitive silver halide emulsion layer and red-sensitive silver halide emulsion layer, wherein (i) the specified speed of the photosensitive material is 350 or higher, (ii) the coating amount of silver in the photosensitive material is 7 g/m2 or less, and (iii) any of the color-sensitive silver halide emulsion layers is composed of two or more silver halide emulsion layers of different photographic speeds, of which the silver halide emulsion layer with the highest photographic speed contains tabular silver halide grains of 8 or greater aspect ratio in a ratio of 70% or more based on the total projected area and regular-crystal silver halide grains of 0.1 to 0.5 ?m equivalent sphere diameter in a ratio of 0.5 to 5% based on the total projected area.Type: GrantFiled: September 23, 2004Date of Patent: July 11, 2006Assignee: Fuji Photo Film Co., Ltd.Inventor: Masaaki Miki
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Patent number: 6929906Abstract: A silver halide color photosensitive material comprises at least one light-sensitive silver halide emulsion layer and at least one nonlight-sensitive layer. At least one of the nonlight-sensitive layers contains colloidal silver. The colloidal silver-containing nonlight-sensitive layer or a nonlight-sensitive layer adjacent to the colloidal silver-containing nonlight-sensitive layer contains a compound capable of releasing a development inhibitor or a precursor thereof by a coupling reaction with an oxidized developing agent. At least one layer selected from the group consisting of the light-sensitive silver halide emulsion layer and the nonlight-sensitive layer contains a compound (B), which is a compound having at least three hetero atoms and capable of enhancing the photographic speed of the photosensitive material in comparison to the same photosensitive materials without the compound.Type: GrantFiled: October 30, 2003Date of Patent: August 16, 2005Assignee: Fuji Photo Film Co., Ltd.Inventors: Yoshio Ishii, Koji Takaku
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Patent number: 6887656Abstract: Disclosed is a color photographic element comprising at least one light sensitive silver halide emulsion layer containing a compound that does not react with oxidized developer, has a Log Kow high enough to improve speed, compared to the same layer without the compound, and comprises (1) a thiadiazole, or (2) an oxadiazole, or (3) a 1,2,4 triazole bearing an amido substituent, and does not contain a hydroxyl or thiol group or their tautomeric equivalents on the azole ring.Type: GrantFiled: January 17, 2003Date of Patent: May 3, 2005Assignee: Eastman Kodak CompanyInventors: Louis E. Friedrich, Philip A. Allway, Judith A. Bogie, Bernard A. Clark, Charles E. Heckler, Stephen P. Singer
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Patent number: 6821719Abstract: A process for producing a deformed image comprising the steps of: digitally exposing a color photographic silver halide material, said color photographic silver halide material comprising on a deformable plastic support at least one blue-sensitive silver halide emulsion layer containing at least one yellow coupler, at least one green-sensitive silver halide emulsion layer containing at least one magenta coupler and at least one red-sensitive silver halide emulsion layer containing at least one cyan coupler; conventionally processing said exposed color photographic material to produce an image; and deforming said color photographic material.Type: GrantFiled: November 14, 2003Date of Patent: November 23, 2004Assignee: AGFA-GevaertInventors: Ly Cuong, Markus Geiger, Leon Vermeulen, Arno Schmuck
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Patent number: 6811963Abstract: This invention relates to a silver halide photographic element comprising a support bearing a cyan dye image-forming unit comprised of at least one red-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, a magenta dye image-forming unit comprising at least one green-sensitive silver halide emulsion layer having associated therewith at least one magenta dye-forming coupler, and a yellow dye image-forming unit comprising at least one blue-sensitive silver halide emulsion layer having associated therewith at least one yellow dye-forming coupler, wherein at least one of the dye image forming units contains layers of differing sensitivities, and the layer of highest sensitivity contains a development promoting agent or a specific coupler as described herein, or a combination thereof, and a silver halide emulsion comprising tabular silver halide grains having associated therewith at least two dye layers comprising (a) an inner dye layer adjacent to the silver haType: GrantFiled: January 17, 2003Date of Patent: November 2, 2004Assignee: Eastman Kodak CompanyInventors: Sharon G. Johnston, Stephen P. Singer, Drake M. Michno, James A. Friday, David R. Foster
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Publication number: 20040142288Abstract: This invention relates to a silver halide photographic element comprising a support bearing a cyan dye image-forming unit comprised of at least one red-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, a magenta dye image-forming unit comprising at least one green-sensitive silver halide emulsion layer having associated therewith at least one magenta dye-forming coupler, and a yellow dye image-forming unit comprising at least one blue-sensitive silver halide emulsion layer having associated therewith at least one yellow dye-forming coupler, wherein said photographic element has an ISO speed rating of 800 or greater and has an integrated RMS green granularity equal to or less than 11.2.Type: ApplicationFiled: January 17, 2003Publication date: July 22, 2004Inventors: James A. Friday, Roger A. Weiss, Anabisdally I. Bodden
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Publication number: 20040126721Abstract: Disclosed is a silver halide photographic light-sensitive material wherein a silver halide emulsion layer and/or a hydrophilic colloid layer contains at least one hydrazine derivative, and a silver halide emulsion is spectrally sensitized with a particular dye, and which contains a benzotriazol compound. There is provided a silver halide photographic light-sensitive material that exhibits superior residual color property and can provide stable photographic performance even after a long term running with a reduced silver amount.Type: ApplicationFiled: September 29, 2003Publication date: July 1, 2004Inventors: Mitsunori Hirano, Kunio Ishigaki, Tokuju Oikawa
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Publication number: 20040126723Abstract: The present invention provides a photothermographic material including a support having disposed thereon an image-forming layer that contains at least a non-photosensitive organic silver salt, a photosensitive silver halide, a reducing agent and a binder, and further including a compound represented by the following formula (I):Type: ApplicationFiled: December 16, 2003Publication date: July 1, 2004Inventors: Katsuyuki Watanabe, Hiroyuki Mifune
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Publication number: 20040086812Abstract: A silver halide color photographic lightsensitive material containing at least one compound capable of increasing photographic speed, the compound having at least three heteroatoms in its molecule, and wherein at least one layer of the silver halide emulsion layers comprises an emulsion, the emulsion consisting of a lightsensitive silver halide emulsion wherein 50% or more in number of all the silver halide grains are occupied by tabular grains having (111) faces as main planes, the tabular grains (i) composed of silver iodobromide or silver chloroiodobromide, (ii) having an equivalent circle diameter of 1.0 &mgr;m or more and a thickness of 0.15 &mgr;m or less, and (iii) composed of core portions of 0.1 &mgr;m or less thickness free of growth ring structure and composed of silver iodobromide and shell portions having ten or more dislocation lines.Type: ApplicationFiled: October 23, 2003Publication date: May 6, 2004Applicant: FUJI PHOTO FILM CO., LTD.Inventors: Masaaki Miki, Yoshiyasu Inami, Junichiro Hosokawa
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Patent number: 6699652Abstract: This invention relates to a silver halide photographic element comprising a support bearing a cyan dye image-forming unit comprised of at least one red-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, a magenta dye image-forming unit comprising at least one green-sensitive silver halide emulsion layer having associated therewith at least one magenta dye-forming coupler, and a yellow dye image-forming unit comprising at least one blue-sensitive silver halide emulsion layer having associated therewith at least one yellow dye-forming coupler, wherein at least one of the dye image forming units contains layers of differing sensitivities, and the layer of highest sensitivity contains a development promoting agent or a specific coupler as described herein, or a combination thereof, and a silver halide emulsion comprising tabular silver halide grains having associated therewith at least two dye layers comprising (a) an inner dye layer adjacent to the silver haType: GrantFiled: January 17, 2003Date of Patent: March 2, 2004Assignee: Eastman Kodak CompanyInventors: Sharon G. Johnston, Stephen P. Singer, Drake M. Michno, James A. Friday, David R. Foster
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Publication number: 20030232289Abstract: Disclosed is a colour photographic element containing one or more cyan dye-forming couplers, a UV absorber and a specific class of stabiliser, and an imaging process used therewith. The element exhibits improved stability.Type: ApplicationFiled: October 11, 2002Publication date: December 18, 2003Applicant: Eastman Kodak CompanyInventors: Danuta Gibson, Llewellyn J. Leyshon, David Clarke
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Publication number: 20030157447Abstract: A silver halide photographic light-sensitive emulsion comprising a silver halide and a compound represented by the following Formula (I): 1Type: ApplicationFiled: July 19, 2002Publication date: August 21, 2003Inventors: Tatsuo Tanaka, Nobuaki Kagawa, Yoshiko Iwai, Tomohiro Oshiyama
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Publication number: 20030091943Abstract: A black-and-white photothermographic material that is sensitive at a wavelength greater than 700 nm, and comprises a support having thereon one or more thermally-developable imaging layers comprising a binder and in reactive association, a photosensitive silver halide, a non-photosensitive source of reducible silver ions, and a reducing composition for the non-photosensitive source reducible silver ions. The thermally-developable layers further comprises one or more indolenine dyes as post-processing stabilizing compounds and one or more merocyanine dyes or cyanine spectral sensitizing dyes that comprise one or more thioalkyl, thioaryl, or thioether groups.Type: ApplicationFiled: June 29, 2001Publication date: May 15, 2003Applicant: Eastman Kodak CompanyInventors: Steven H. Kong, Bryan V. Hunt, Wiliam D. Ramsden
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Patent number: 6548239Abstract: Disclosed is a photothermographic material containing a non-photosensitive silver salt and a photosensitive silver halide on a support, wherein the photosensitive silver halide is spectrally sensitized with a spectral sensitizing dye so that maximum spectral sensitivity wavelength could become longer than 730 nm and the conditions defined by the following formulas (1) and (2) and/or the conditions defined by the following formulas (3) and (4) could be satisfied: 300≧S(&lgr; max)/S(&lgr; max+30 nm)≧4.5 Formula (1) 30≧S(&lgr; max)/S(&lgr; max−30 nm)≧2 Formula (2) 300≧Abs.(&lgr; max)/Abs.(&lgr; max−30 nm)≧4.5 Formula (3) 30≧Abs.(&lgr; max)/Abs.(&lgr; max−30 nm)≧2 Formula (4) wherein, in the above formulas, &lgr;max denotes maximum spectral sensitivity wavelength, Abs.(&lgr;) denotes optical density at a wavelength of &lgr; and S(&lgr;) denotes spectral sensitivity at a wavelength of &lgr;.Type: GrantFiled: April 6, 2001Date of Patent: April 15, 2003Assignee: Fuji Photo Film Co., Ltd.Inventor: Takahiro Goto
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Patent number: 6511797Abstract: Provided is a photothermographic material having, on one surface of its support, at least one type of photosensitive silver halide grains, a non-photosensitive silver salt of an organic acid, a reducing agent for silver ions, and a binder; which contains an organic polyhalogen compound of the following general formula (I) and in which the silver halide grains have a hexacyano-metal complex of the following general formula (II) in their outermost surfaces: wherein Q represents an alkyl group optionally having one or more substituents, an aryl group optionally having one or more substituents, or a heterocyclic group optionally having one or more substituents; X1 and X2 each independently represent a halogen atom; Z represents a hydrogen atom or an electron-attracting group; Y represents —C(═O)—, —SO— or —SO2—; and n indicates 0 or 1; [M(CN)6]n− (II) wherein M represents Fe, Ru, Os, Co, Rh, Ir, Cr or Re; and n indicates 3 orType: GrantFiled: August 3, 2000Date of Patent: January 28, 2003Assignee: Fuji Photo Film Co., Ltd.Inventor: Shinji Ikari
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Patent number: 6482583Abstract: Provided is a photothermographic material having, on one surface of its support, at least one type of photosensitive silver halide grains, a non-photosensitive silver salt of an organic acid, a reducing agent for silver ions, and a binder; which contains a compound of the following general formula (I) and in which the silver halide grains have a hexacyano-metal complex of the following general formula (II) in their outermost surfaces: wherein R11, R12, R13 and R14 may be the same or different, and each independently represents a hydrogen atom, a halogen atom, a hydroxyl group, an amino group, a nitro group, a cyano group, a carboxyl group or its salt, a sulfo group or its salt, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, or a group of R15—D—; where R15 represents a hydrogen atom, a halogen atom, a hydroxyl group, an amino group, a nitro group, a cyano group a carboxyl group or its salt, a sulfo group or its salt, an alkyl group, an alkType: GrantFiled: August 3, 2000Date of Patent: November 19, 2002Assignee: Fuji Photo Film Co., Ltd.Inventor: Shinji Ikari
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Patent number: 6455242Abstract: Disclosed is a color photographic element comprising at least one of (1) a light sensitive silver halide emulsion layer and (2) a non-silver containing light insensitive layer, said at least one layer containing a compound with a minimum of three heteroatoms that does not react with oxidized developer and that has a ClogP sufficient to increase the photographic speed of said element compared to the same element without the compound. The invention provides improved light sensitivity.Type: GrantFiled: September 18, 2001Date of Patent: September 24, 2002Assignee: Eastman Kodak CompanyInventors: Philip A. Allway, Bernard A. Clark, John D. Goddard, Louis E. Friedrich, James A. Friday, Stephen P. Singer, Marcello Vitale
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Patent number: 6444392Abstract: A black and white graphic arts film comprising a support having thereon at least one emulsion layer, said emulsion layer comprising: a trinuclear merocyanine spectral sensitising dye; 2-methylthio-4-hydroxy-6-methyl-1,3,3a,7-tetraazaindene (SMe-TAI); and a photosensitive silver halide.Type: GrantFiled: August 10, 2001Date of Patent: September 3, 2002Assignee: Eastman Kodak CompanyInventor: Julie Baker
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Patent number: 6426180Abstract: Disclosed is a color silver halide photographic element comprising a support bearing: (1) a light sensitive silver halide emulsion layer; (2) a nitrogen heterocycle with a minimum of three heteroatoms that does not react with oxidized developer, does not contain free thiol substituents, and has a C log P sufficient to increase the photographic speed of said element compared to the same element without the compound, said heterocycle compound located either in said light sensitive layer or in a layer adjacent to it; and (3) an ETARC, in or adjacent to said light sensitive silver halide emulsion layer, that releases, upon reaction with oxidized developer, an electron transfer agent having a C log P of at least 2.40. The invention provides improved light sensitivity.Type: GrantFiled: October 17, 2000Date of Patent: July 30, 2002Assignee: Eastman Kodak CompanyInventors: Joseph F. Bringley, James A. Friday, Stephen P. Singer, Marcello Vitale
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Patent number: 6413710Abstract: Photothermographic emulsions and materials that are highly sensitive to imaging radiation and that provide high contrast images are provided by making the emulsions with photosensitive silver halide grains that have been formed in the presence of a hydroxytetrazaindene or an N-heterocyclic compound comprising at least one mercapto group, such as a mercapto tetrazole. Such grains can then be chemically sensitized before or after mixing with an organic silver salt using a sulfur-, tellurium-containing, or gold-containing chemical sensitizing compound, or mixtures thereof.Type: GrantFiled: April 12, 2001Date of Patent: July 2, 2002Assignee: Eastman Kodak CompanyInventors: Steven M. Shor, Chaofeng Zou, Sharon Simpson, Stacy M. Ulrich
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Patent number: 6383731Abstract: The object of the present invention is to provides a novel polyhalogenomethylsulfonyl compound which can be used for providing a thermally processed image recording material which has a high sensitivity, gives less fog, and has a good stock stability and a good image storage stability of dark and high temperature or light storage. According to the present invention, there is provided a polyhalogenomethylsulfonyl compound represented by the following formula (1), or salts thereof, or hydrates or solvates thereof: wherein Z1 and Z2 each independently represents a halogen atom; A represents a hydrogen atom or a halogen atom; and R1 represents an alkyl group having from 2 to 12 carbon atoms, which may have one or more substituents, an alkenyl group having from 2 to 12 carbon atoms, which may have one or more substituents, or an alkinyl group having from 2 to 12 carbon atoms, which may have one or more substituents.Type: GrantFiled: August 20, 2001Date of Patent: May 7, 2002Assignee: Fuji Photo Film Co., Ltd.Inventors: Masaru Takasaki, Katsuyuki Watanabe, Hisashi Okamura
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Patent number: 6350564Abstract: Disclosed is a color silver halide photographic element comprising a support bearing: (1) a light sensitive silver halide emulsion layer; (2) a nitrogen heterocycle with a minimum of three heteroatoms that does not react with oxidized developer, does not contain free thiol substituents, and has a ClogP sufficient to increase the photographic speed of said element compared to the same element without the compound, said heterocycle compound located either in said light sensitive layer or in a layer adjacent to it; and (3) a light reflecting silver halide material; provided that the heterocycle compound and the light reflecting material are located either (a) in different layers of the element located close enough to each other so that a super-additive speed increase is realized or (b) in the same light sensitive layer. The invention provides improved light sensitivity.Type: GrantFiled: October 17, 2000Date of Patent: February 26, 2002Assignee: Eastman Kodak CompanyInventors: Joseph F. Bringley, James A. Friday, Stephen P. Singer, Marcello Vitale
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Patent number: 6331386Abstract: A photothermographic element has a non-photosensitive organic silver salt, a photosensitive silver halide, and a binder on a support. A polymer latex constitutes at least 50% by weight of the binder in an image forming layer containing the photosensitive silver halide. The image forming layer has been formed by applying a coating solution in which at least 60% by weight of a solvent is water. The image forming layer contains a specific compound as a nucleating agent and has been formed by applying a coating solution having added thereto a water dispersion of the compound. The element exhibits a high contrast, long-term storage stability, and no increase of Dmin upon printing to PS plates.Type: GrantFiled: April 28, 1999Date of Patent: December 18, 2001Assignee: Fuji Photo Film Co., Ltd.Inventors: Toshihide Ezoe, Kohzaburoh Yamada
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Patent number: 6329135Abstract: A silver halide photothermographic material is disclosed, comprising a support having thereon a light-sensitive layer and light-insensitive layer, wherein the light-sensitive layer or the light-insensitive layer comprises a heteroatom-containing macrocyclic compound, and the light-sensitive layer comprising a sensitizing dye exhibiting maximum sensitivity at a wavelength of 600 nm or more.Type: GrantFiled: June 2, 2000Date of Patent: December 11, 2001Assignee: Konica CorporationInventor: Hiroshi Kashiwagi
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Patent number: 6319660Abstract: Disclosed is a color photographic element comprising at least one of (1) a light sensitive silver halide emulsion layer and (2) a non-silver containing light insensitive layer, said at least one layer containing a compound with a minimum of three heteroatoms that does not react with oxidized developer and that has a ClogP sufficient to increase the photographic speed of said element compared to the same element without the compound. The invention provides improved light sensitivity.Type: GrantFiled: July 21, 1999Date of Patent: November 20, 2001Assignee: Eastman Kodak CompanyInventors: Philip A. Allway, Bernard A. Clark, John D. Goddard, Louis E. Friedrich, James A. Friday, Stephen P. Singer, Marcello Vitale
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Patent number: 6316177Abstract: Disclosed is a color silver halide photographic element comprising a light-sensitive silver halide emulsion layer or a non-silver containing light-insensitive layer, said light-sensitive or light-insensitive layer containing a polymer compound comprising a heterocycle unit derived from: (a) a heterocycle monomer (1) comprising two or more annulated rings containing, in total, a minimum of three ring heteroatoms of which no more than two of the heteroatoms are connected in sequence to each other and (2) having a ClogP less than 6.2; or (b) a monocyclic heterocycle monomer having exactly three ring heteroatoms and having a ClogP less than 8.75; with the proviso that the heterocycle unit does not contain a hydroxy or mercapto group (or their tautomeric equivalent), and does not react with oxidized developer; and the amount of the polymer compound in the element being sufficient to increase the photographic speed of the element compared to the same element without the compound.Type: GrantFiled: March 31, 2000Date of Patent: November 13, 2001Assignee: Eastman Kodak CompanyInventors: Philip A. Allway, Tienteh Chen, David S. Ross, Stephen P. Singer
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Patent number: 6297001Abstract: A photothermographic material is disclosed, comprising a non-photosensitive organic silver salt, a photosensitive silver halide, a reducing agent a binder and a cross-linking agent; the photothermographic material further comprising a compound capable of generating a labile species other than a halogen atom upon exposure to ultraviolet radiation or visible radiation to deactivate the reducing agent.Type: GrantFiled: February 28, 2000Date of Patent: October 2, 2001Assignee: Konica CorporationInventors: Hideki Takiguchi, Katsura Hirai
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Patent number: 6277554Abstract: In a thermographic recording element comprising an organic silver salt, a photosensitive silver halide, and a reducing agent, there are further included a specific compound and a hydrazine derivative. The element exhibits a high contrast and the minimized dependency of photographic properties on developing temperature.Type: GrantFiled: May 11, 1999Date of Patent: August 21, 2001Assignee: Fuji Photo Film, Co., Ltd.Inventors: Kohzaburoh Yamada, Hiroyuki Suzuki, Toshihide Ezoe
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Publication number: 20010010895Abstract: Disclosed is a color photographic element comprising:Type: ApplicationFiled: July 21, 1999Publication date: August 2, 2001Inventors: PHILIP A. ALLWAY, LOUIS E. FRIEDRICH, STEPHEN P. SINGER
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Patent number: 6248512Abstract: An image forming method for a thermally processable photosensitive material is disclosed, comprising exposing a thermally processable photosensitive material to light using a laser light source, and subjecting the exposed photosensitive material to thermal processing, wherein the thermally processable photosensitive material comprises a support having thereon an organic silver salt, a binder, a photosensitive silver halide, and a compound containing nitrogen covalently bonded to halogen represented by the following formula or a nitrogen-containing acyclic compound associated with a pair of halogen atoms represented by the following formulaType: GrantFiled: April 8, 1999Date of Patent: June 19, 2001Assignee: Konica CorporationInventors: Norio Miura, Keiko Ishidai
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Patent number: 6214529Abstract: This invention relates to a method of reducing fog in a silver halide emulsion comprising taking a high fogging emulsion which has been chemically sensitized and cooled, holding the high fogging emulsion in the form of a melt in preparation for coating on a support, and prior to or during said holding, contacting the emulsion with an isothiazolin-one compound represented by the following formula wherein R1 is a substituent; and Z contains the carbon atoms necessary to form a substituted or unsubstituted non-aromatic ring. It also relates to silver halide photographic elements containing such emulsions.Type: GrantFiled: October 12, 1999Date of Patent: April 10, 2001Assignee: Eastman Kodak CompanyInventors: Jon N. Eikenberry, Kenneth G. Harbison
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Patent number: 6190849Abstract: The invention provides a color photographic element comprising: a) a first light sensitive silver halide emulsion layer containing a tetrazole compound of Formula I: wherein when R1 is hydrogen, then R2 is an alkyl, aryl, alkoxy , aryloxy, alkylthio or arylthio, sulfoxyl, sulfonyl, sulfamoyl, —O—CO—, —O—SO2—, a heterocyclic group, a carbonyl group or an amino group or when R2 is a thiol (—SH) group, then R1 is an alkyl, aryl or heterocyclic group provided further that the ClogP for the compound of Formula I is at least 2.0 and less than 7.Type: GrantFiled: July 21, 1999Date of Patent: February 20, 2001Assignee: Eastman Kodak CompanyInventors: Paul A. Burns, Louis E. Friedrich, Stephen P. Singer
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Patent number: 6190848Abstract: The invention provides a color photographic element comprising: a) a first light sensitive silver halide emulsion layer containing a compound of Formula I: wherein Q represents the atoms necessary to form a triazole ring and the associated bonds, provided that the ring members may be substituted and that two of such members may join to form a fused ring; provided further that the ClogP for the compound of Formula I is from 4.75 to 9.0; and b) a second light sensitive silver halide emulsion layer, having a spectral sensitivity different from that of the first light sensitive silver halide emulsion layer, containing a compound of Formula II: COUP-(TIME)j-INH II wherein: 1) COUP is a coupler parent group capable of forming a dye upon reaction with an oxidized developer; 2) TIME is a timing group and j is 0 or 1; and 3) INH is a mild silver development inhibitor fragment. The invention provides improved color reproduction.Type: GrantFiled: July 21, 1999Date of Patent: February 20, 2001Assignee: Eastman Kodak CompanyInventors: Jane S. Boff, Bernard A. Clark, Louis E. Friedrich, Stephen P. Singer
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Patent number: 6153372Abstract: A photothermographic element contains a non-photosensitive organic silver salt, a photosensitive silver halide which has been formed independent of the non-photosensitive organic silver salt, and a binder. An image forming layer contains the photosensitive silver halide, a latex of a polymer having a Tg of -30.degree. C. to 40.degree. C. as a main binder, and a compound of formula (I): ##STR1## wherein X is --N.dbd., --N(R)--, --0--, or --S--, wherein R is hydrogen, hydroxyl, aliphatic hydrocarbon, aryl or heterocyclic group, Z is a single bond or a group of atoms necessary to form a 5- to 7-membered ring with X, and Q.sub.1 and Q.sub.2 each are a group of atoms necessary to form an aromatic hydrocarbon or heterocyclic ring fused to the ring completed by Z.Type: GrantFiled: October 2, 1998Date of Patent: November 28, 2000Assignee: Fuji Photo Film Co., Ltd.Inventors: Tsutomu Arai, Ryo Suzuki, Takahiro Goto
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Patent number: 6140029Abstract: The invention provides a silver halide photographic element comprising a non-light sensitive layer containing elemental silver and a nitrogen heterocycle compound having a ClogP of at least 4.5, which compound comprises a ring system of one or more fused rings containing at least one --N--H bond, the ring system comprising a total of at least three nitrogen ring members and the associated bonds; provided that the compound does not contain an --SH group or >C.dbd.S group and does not react with an oxidized developer.Type: GrantFiled: September 30, 1999Date of Patent: October 31, 2000Assignee: Eastman Kodak CompanyInventors: Bernard A. Clark, Jane S. Boff, Philip A. Allway, Louis E. Friedrich, Stephen P. Singer
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Patent number: 5981161Abstract: A silver halide photographic light sensitive material is diclosed, comprising a support having a silver halide emulsion layer containing cubic silver halide grains containing iodide of 0.1 to 1.0 mol % and an iridium salt of 1.times.10.sup.-8 to 1.times.10.sup.Type: GrantFiled: June 20, 1997Date of Patent: November 9, 1999Assignee: Konica CorporationInventor: Yuji Hosoi
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Patent number: 5972589Abstract: The present invention relates to a method for manufacturing a silver halide photographic emulsion comprising a nucleation step, a growing step and a washing step, wherein a reduction sensitization is performed between said growing step and said washing step in the presence of a sulfuring agent and a stabilizer. According to a preferred embodiment a fine grain silver halide emulsion is added either between the addition of stabilizer and the addition of sulfuring agent or between the addition of sulfuring agent and the start of reduction sensitization or both.Type: GrantFiled: October 22, 1997Date of Patent: October 26, 1999Assignee: Imation CorporationInventors: Jouri Breslav, Maria Stella Garozzo
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Patent number: 5968724Abstract: This invention relates to silver halide photographic element comprising a silver halide emulsion chemically sensitized in the presence of an isothiazolin-one compound represented by the formula ##STR1## wherein R.sup.1 is a substituent; and Z is a substituted or unsubstituted saturated ring, wherein the isothiazolin-one compound was added after precipitation of the emulsion.Type: GrantFiled: October 22, 1998Date of Patent: October 19, 1999Assignee: Eastman Kodak CompanyInventors: Jon N. Eikenberry, Roger L. Klaus, Roger L. Lok, Jerzy Z. Mydlarz, Brian S. White
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Patent number: 5958668Abstract: A recording medium comprising a support having thereon a recording layer comprising an organic silver salt, a developing agent for the organic silver salt, a water-soluble binder and an antifoggant in an amount of from 10 mol % to 40 mol % based on the organic silver salt. The recording material has a long shelf life and provides a high-density image.Type: GrantFiled: May 21, 1997Date of Patent: September 28, 1999Assignee: Fuji Photo Film Co., Ltd.Inventors: Hirotaka Matsumoto, Kimi Ikeda, Hisashi Okada
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Patent number: 5955252Abstract: A silver halide photographic material comprising a support having thereon at least one silver halide emulsion layer containing silver halide grains having a silver chloride content of at least 70 mol % and containing a transition metal selected from the group consisting of elements belonging to Groups V to VIII of the Periodic Table in an amount of at least 1.times.10.sup.-7 mol per mol of silver, the silver halide grains being formed in the presence of a compound represented by following formula (I); ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, and R.sup.4, which may be the same or different, each represents a hydrogen atom, an alkyl group, an aryl group, an amino group, a hydroxy group, an alkoxy group, an alkylthio group, a carbamoyl group, a halogen atom, a cyano group, a carboxy group, an alkoxycarbonyl group, or a heterocyclic residue; and R.sup.1 and R.sup.2 or R.sup.2 and R.sup.3 may combine with each other and form a 5-membered or 6-membered ring; and with the proviso that at least one of R.sup.Type: GrantFiled: September 28, 1994Date of Patent: September 21, 1999Assignee: Fuji Photo Film Co., Ltd.Inventors: Takahiro Goto, Nobuaki Inoue
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Patent number: 5939248Abstract: A photothermographic material having a photosensitive medium comprising: photosensitive silver halide, a reducible silver source, a reducing agent for silver ion, a hydrobromic acid salt of a nitrogen-containing heterocyclic ring or fused ring nucleus associated with a pair of bromine atoms CHARACTERIZED IN THAT the photosensitive medium additionally comprises as an antifoggant, substantially in the absence of an antifoggant effective amount of mercury and other heavy metal salts, a tribromomethyl ketone compound of general formula (I): ##STR1## in which; R represents an alkyl group, an aryl group, a carbocyclic ring or fused ring nucleus or a heterocyclic ring or fused ring nucleus.Type: GrantFiled: September 24, 1993Date of Patent: August 17, 1999Assignee: Minnesota Mining and Manufacturing CompanyInventors: Mark P. Kirk, David B. Oliff