Composition For Visible Imaging By Radiation Only Patents (Class 430/616)
  • Patent number: 4837134
    Abstract: A data card for optical information featuring a gelatin layer having a thin black crust at the top of the layer. The crust is formed by developed black irregular oblong silver particles within the top 0.5 micron of the gelatin colloid matrix. The remainder of the colloid matrix is substantially clear gelatin and a reflective metallic layer is disposed below the gelatin. The strip is laminated into a wallet-size card and may be pre-patterned during formation of the crust with control indicia or pre-recorded data. User data may be recorded by modifying the black silver particles in the crust with a laser to expose the reflective underlayer. A laser or other light source is used to read data on the medium with optical contrast between the black surface metallic layer underlying the gelatin layer which can be observed in the recorded spots.
    Type: Grant
    Filed: April 16, 1987
    Date of Patent: June 6, 1989
    Assignee: Drexler Technology Corporation
    Inventors: Eric W. Bouldin, Jerome Drexler
  • Patent number: 4788129
    Abstract: A medium in tape form for laser recorded optical information featuring a gelatin layer having a thin black crust at the top of the layer. The crust is formed by developed black filamentary silver particles within the top 0.5 micron of a gelatin colloid matrix. The remainder of the colloid matrix is substantially clear gelatin and a reflective metallic layer is disposed below the gelatin. The tape may be disposed on reels and may be pre-patterned during formation of the crust with indicia, such as servo track guides or timing marks. User data may be recorded by modification or by displacing the black silver particles in the crust with a laser to expose the reflective underlayer. A laser or other light source is used to read data on the medium with optical contrast between the black surface and the reflective metallic layer underlying the gelatin layer which can be observed in the recorded spots.
    Type: Grant
    Filed: November 28, 1986
    Date of Patent: November 29, 1988
    Assignee: Drexler Technology Corporation
    Inventors: Eric W. Bouldin, Jerome Drexler
  • Patent number: 4767571
    Abstract: The present invention relates to an infrared absorbent comprising a metal complex. With the use of the infrared absorbent, there is provided an infrared absorbing material capable of absorbing near infrared light having a wavelength of 700-1500 nm or far infrared light with a high transmittance of visible light and a good fastness to heat and light. The infrared absorbent is suitable for various applications such as a safelight filter for infrared sensitive materials, control of growth of plants, cut-off of heat radiation, infrared cut filter harmful to tissues of human eyes, infrared cut filter for semiconductor light receiving elements or color solid image pick-up elements, and infrared cut filter for an optoelectronic integrated circuit wherein electrical and optical elements are incorporated in the same substrate.
    Type: Grant
    Filed: June 21, 1985
    Date of Patent: August 30, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoshiaki Suzuki, Gouichi Hayashi
  • Patent number: 4762770
    Abstract: An optical memory disk for laser recorded optical information featuring a gelatin layer having a thin black crust at the top of the layer. The crust is formed by developed black irregular oblong silver particles within the top 0.5 micron of a gelatin colloid matrix. The remainder of the colloid matrix is substantially clear gelatin and a reflective metallic layer is disposed below the gelatin. The disk may be pre-patterned during formation of the crust with control indicia, such as servo track guides or timing marks. User data may be recorded by modification of the black silver particles in the crust with a laser to expose the reflective underlayer. A laser or other light source is used to read data on the medium with optical contrast between the black surface and the reflective metallic layer underlying the gelatin layer which can be observed in the recorded spots.
    Type: Grant
    Filed: April 16, 1987
    Date of Patent: August 9, 1988
    Assignee: Drexler Technology Corporation
    Inventors: Eric W. Bouldin, Jerome Drexler
  • Patent number: 4753864
    Abstract: A medium in tape form for laser recorded optical information featuring a gelatin layer having a thin black crust at the top of the layer. The crust is formed by developed black irregular silver particles within the top 0.5 micron of a gelatin colloid matrix. The remainder of the colloid matrix is substantially clear gelatin and a reflective metallic layer is disposed below the gelatin. The tape may be disposed on reels and may be pre-patterned during formation of the crust with indicia, such as servo track guides or timing marks. User data may be recorded by modification of the black silver particles in the crust with a laser to expose the reflective underlayer. A laser or other light source is used to read data on the medium with optical contrast between the black surface and the reflective metallic layer underlying the gelatin layer which can be observed in the recorded spots.
    Type: Grant
    Filed: April 16, 1987
    Date of Patent: June 28, 1988
    Assignee: Drexler Technology Corporation
    Inventors: Eric W. Bouldin, Jerome Drexler
  • Patent number: 4670366
    Abstract: The invention relates to high energy beam-sensitive glass articles exhibiting insensitivity and/or inertness to actinic radiation, i.e., glass articles which are darkened and/or colored within a thin surface layer of, e.g., about 0.1-3 .mu.m upon exposure to a high energy beam, electron beam, and ion beams in particular, without a subsequent development step, and which need no fixing to stabilize the colored image, since both the recorded image and the glass article are sensitive to radiation in the spectral range of uv and longer wavelengths. More particularly, the instant invention is concerned with Ag.sup.+ ion-exchanged glass articles having base glass within alkali metal silicate composition fields containing at least one of the oxides of transition metals which have one to four d-electrons in an atomic state. Whereas the base glass composition can be varied widely, spontaneous reduction as well as photo-reduction of Ag.sup.
    Type: Grant
    Filed: June 12, 1984
    Date of Patent: June 2, 1987
    Assignee: Canyon Materials Research & Engineering
    Inventor: Che-Kuang Wu
  • Patent number: 4613553
    Abstract: Metallic salts of organic charge-transfer agents, such as TCNQ, TNAP, TCNE and DDQ and their derivatives, can be processed by an electron beam for a variety of useful electronic and optical applications. The metallic charge transfer salts can be used to deposit high resolution conductive lines directly without developing solutions or subsequent metallization steps. The compounds can also be employed in the conventional manner as resists for doping (i.e., ion diffusion or implantation) and to diffuse metals into substrates. In particular, electronic devices, optical devices and image-storage devices are disclosed which can be formed by simple electron beam processed of metal charge-transfer salt films deposited on substrates.
    Type: Grant
    Filed: May 31, 1985
    Date of Patent: September 23, 1986
    Assignee: Brown University Research Foundation
    Inventors: William M. Risen, Jr., Efstratios I. Kamitsos
  • Patent number: 4536471
    Abstract: An optical information recording medium for recording and reproducing information by way of applying high density energy beams to a reflective recording layer on a support, said recording layer comprising a hydrophilic colloid; a compound capable of producing a water-insoluble copper complex; and reflective fine particles consisting essentially of copper. A process for manufacturing said optical information recording medium is also provided.
    Type: Grant
    Filed: March 15, 1984
    Date of Patent: August 20, 1985
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Shinichi Nishi, Taxey Satoh, Fumio Shimada, Toshiaki Takahashi
  • Patent number: 4463089
    Abstract: An improved reflective silver laser recording and data storage medium for direct read after writing, having a protective gold plating on the silver particles of the reflective surface. The gold plating increases the recording sensitivity resulting in higher contrast ratios for the recorded data. Increased contrast ratios between recorded and non-recorded reflective areas are obtained by the gold plating allowing lower laser energy for readout of recorded data. The reflective silver surface is plated with gold by an electroless ion displacement procedure.
    Type: Grant
    Filed: December 20, 1982
    Date of Patent: July 31, 1984
    Assignee: Drexler Technology Corporation
    Inventor: Eric W. Bouldin
  • Patent number: 4451556
    Abstract: Imaging compositions employing a tellurium compound, a reductant precursor, a masked reducing agent and a source of labile hydrogen are improved by the inclusion of a base which may be inorganic or organic. Suitable inorganic bases include alkali metal hydroxides, alkaline earth metal hydroxides and ammonium hydroxide. Suitable organic bases include amines and heterocyclic nitrogen atom containing compounds.
    Type: Grant
    Filed: June 28, 1982
    Date of Patent: May 29, 1984
    Assignee: Energy Conversion Devices, Inc.
    Inventor: Terry T. Yu
  • Patent number: 4396701
    Abstract: An underlayer for a laser recording and data storage medium with a light absorption characteristic suited to a recording laser. The underlayer is formed by creating a nuclei layer in a silver-halide photosensitive emulsion layer and then contacting the emulsion layer with a chromogenic reducing agent and a chromogenic dye coupler. The reflective layer may be formed prior to this step by subjecting the nuclei layer to a monobath having a silver-halide solvent and a silver reducing agent until a reflective surface layer of non-filamentary silver particles is formed, or after the step by chemical vapor deposition or sputtering of a reflective metal layer over the underlayer.
    Type: Grant
    Filed: September 11, 1981
    Date of Patent: August 2, 1983
    Assignee: Drexler Technology Corporation
    Inventor: Eric W. Bouldin
  • Patent number: 4383029
    Abstract: Disclosed in this invention is a recording medium characterized by forming on the support a recording layer containing a metastable sensitive substance which is an intermediate product of a reaction between a first colorless or light-colored material containing the S atoms released by light irradiation and a second colorless or light-colored material which develops color as it is sulfurized by said S atoms.
    Type: Grant
    Filed: May 27, 1982
    Date of Patent: May 10, 1983
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Noboru Yamada, Mutsuo Takenaga, Kenichi Nishiuchi
  • Patent number: 4365018
    Abstract: A self-exposing imaging element is disclosed comprising a support member, a light sensitive layer, and a layer containing reagents which will chemically react in a chemiluminescent reaction to produce light which exposes the light sensitive layer when in contact with an original. Reagents in the light generating layer are physically or chemically segregated prior to exposure to prevent reaction, for example, by encapsulation of one of the reactants, the reaction solvent, or a catalyst. To copy the self-exposing imaging element is placed in contact with an original, the light generating layer is activated by causing the reactants to mix or introducing the reaction solvent or catalyst and the radiant energy generated produces an image of the original in the radiation sensitive layer by reflex imaging or direct transmission imaging.
    Type: Grant
    Filed: May 11, 1981
    Date of Patent: December 21, 1982
    Assignee: The Mead Corporation
    Inventors: E. Bryant Crutchfield, Richard F. Wright, Paul C. Adair, Seth O. Harris, Dale R. Shackle, Dennis L. Williams
  • Patent number: 4363870
    Abstract: A method for making a laser recording and data storage medium by first exposing a Lippman emulsion to light in order to form a depthwise nuclei gradient, then physically developing the emulsion until a reflective surface layer of spheroid silver particles, having the desired degree of reflectivity, is attained and then chemically developing the remaining nuclei to form a dark underlayer of filamentary silver particles.
    Type: Grant
    Filed: September 11, 1981
    Date of Patent: December 14, 1982
    Assignee: Drexler Technology Corporation
    Inventor: Eric W. Bouldin
  • Patent number: 4356256
    Abstract: A light-sensitive composition comprising:(1) a plurality of vesicles comprising lipid membranes containing rhodopsin;(2) a mixture of enzymes comprising phosphodiesterase and GTPase;(3) a first nucleotide capable of interacting with GTPase to form a cofactor necessary for the activation of phosphodiesterase;(4) at least one metal cation selected from the group consisting of Mg.sup.+2 and Mn.sup.+2 ; and(5) a second nucleotide capable of being hydrolyzed to produce a proton, said hydrolysis reaction being catalyzed by activated phosphodiesterase, said phosphodiesterase also being activated by rhodopsin exposed by light in the presence of said cofactor and said metal cationis useful in preparing photographic elements comprising means for detecting the hydrolysis reaction, such as an indicator dye.
    Type: Grant
    Filed: August 24, 1981
    Date of Patent: October 26, 1982
    Assignee: Eastman Kodak Co.
    Inventors: David F. O'Brien, Patricia N. Tyminski
  • Patent number: 4347309
    Abstract: A photosensitive material in the form of a silver and chlorine-containing polyphosphate which exhibits permanent visible darkening on exposure to ultraviolet or short wavelength visible light, is described.
    Type: Grant
    Filed: February 25, 1981
    Date of Patent: August 31, 1982
    Assignee: Corning Glass Works
    Inventor: Che-Kuang Wu
  • Patent number: 4343879
    Abstract: A laser recording medium consisting of shiny silver particles in a colloid matrix having at least one superposed layer of colloid matrix containing dispersed metal particles other than silver to lower the reflectivity of the medium.
    Type: Grant
    Filed: August 22, 1980
    Date of Patent: August 10, 1982
    Assignee: Drexler Technology Corporation
    Inventors: Jerome Drexler, Eric W. Bouldin
  • Patent number: 4312938
    Abstract: A broadband laser recording and data storage medium for direct read after writing, formed from a photosensitive silver-halide emulsion in four steps. First, a non-saturating actinic radiation exposure is used to create latent images. A normal photographic development is used to produce a medium of gray neutral density. The surface of the remaining silver halide is fogged in a water or alcohol based solution to create a very thin layer of silver precipitating nuclei on the surface. Finally, a single-step, negative silver diffusion transfer process is used to dissolve the unexposed and undeveloped silver halide, forming silver ion complexes.
    Type: Grant
    Filed: October 17, 1980
    Date of Patent: January 26, 1982
    Assignee: Drexler Technology Corporation
    Inventors: Jerome Drexler, Eric W. Bouldin
  • Patent number: 4298684
    Abstract: A reflective laser recording and data storage medium, for direct reading after writing, formed from a photosensitive silver-halide emulsion including silver precipitating nuclei. A single step negative silver diffusion transfer process is used to develop silver nuclei of the latent image and dissolve unexposed silver halide elsewhere, forming silver ion complexes. These complexes are transported by diffusion transfer to the developing silver nuclei sites where silver is precipitated and adsorbed to form a high concentration of non-filamentary particles at a surface of a low melting temperature dielectric matrix which is highly reflective of light and electrically non-conducting.
    Type: Grant
    Filed: June 20, 1980
    Date of Patent: November 3, 1981
    Assignee: Drexler Technology Corporation
    Inventors: Eric W. Bouldin, Jerome Drexler
  • Patent number: 4284716
    Abstract: A broadband laser recording and data storage medium for direct read after writing, formed from a photosensitive silver-halide emulsion in four steps. First, a non-saturating actinic radiation exposure is used to create latent images. A normal photographic development is used to produce a medium of gray neutral density. The surface of the remaining silver halide is fogged in a water or alcohol based solution to create a very thin layer of silver precipitating nuclei on the surface. Finally, a single-step, negative silver diffusion transfer process is used to dissolve the unexposed and undeveloped silver halide, forming silver ion complexes.
    Type: Grant
    Filed: April 14, 1980
    Date of Patent: August 18, 1981
    Assignee: Drexler Technology Corporation
    Inventors: Jerome Drexler, Eric W. Bouldin
  • Patent number: 4278756
    Abstract: A reflective laser recording and data storage medium, for direct reading after writing, formed from a photosensitive silver-halide emulsion wherein a surface latent image exposure on the recording area forms a depthwise gradient of silver nuclei. A single step negative silver diffusion transfer process is used to develop silver nuclei of the latent image and dissolve unexposed silver halide elsewhere, forming silver ion complexes. These complexes are transported by diffusion transfer to the developing silver nuclei sites where silver is precipitated and adsorbed to form a high concentration of non-filamentary particles at a surface of a low melting temperature dielectric matrix which is highly reflective of light and electrically non-conducting.
    Type: Grant
    Filed: July 6, 1979
    Date of Patent: July 14, 1981
    Assignee: Drexler Technology Corporation
    Inventors: Eric W. Bouldin, Jerome Drexler
  • Patent number: 4278758
    Abstract: A method for making a reflective data storage medium by creating a volume concentration gradient of silver precipitating nuclei on one surface of a silver halide emulsion coated photoplate. This volume concentration is then built up by a silver diffusion transfer negative development using primarily solution physical development until the surface becomes reflective. Lastly, a thermal annealing step is used to increase reflectivity, recording sensitivity and produce a more uniform contrast ratio.
    Type: Grant
    Filed: September 6, 1979
    Date of Patent: July 14, 1981
    Assignee: Drexler Technology Corporation
    Inventors: Jerome Drexler, Eric W. Bouldin
  • Patent number: 4275141
    Abstract: An ultraviolet-sensitive optical information recording material comprising doped silver chloride and tin oxide which exhibits high ultraviolet darkening sensitivity and good resistance to darkening or bleaching by visible light, and a method for optically recording information in permanent, optically-readable form in such a material by direct writing without chemical development, are described.
    Type: Grant
    Filed: October 22, 1979
    Date of Patent: June 23, 1981
    Assignee: Corning Glass Works
    Inventors: Nicholas F. Borrelli, Peter L. Young
  • Patent number: 4269917
    Abstract: A reflective laser recording and data storage medium, for direct reading after writing, formed from a photosensitive silver-halide emulsion wherein a surface latent image exposure on the recording area forms a depthwise gradient of silver nuclei. A single step negative silver diffusion transfer process is used to develop silver nuclei of the latent image and dissolve unexposed silver halide elsewhere, forming silver ion complexes. These complexes are transported by diffusion transfer to the developing silver nuclei sites where silver is precipitated and adsorbed to form a high concentration of non-filamentary particles at a surface of a low melting temperature dielectric colloid matrix which is highly reflective of light and electrically non-conducting.
    Type: Grant
    Filed: July 14, 1980
    Date of Patent: May 26, 1981
    Assignee: Drexler Technology Corporation
    Inventors: Jerome Drexler, Eric W. Bouldin
  • Patent number: 4259424
    Abstract: An improved heat-developable photosensitive material is disclosed which comprises an infrared rays-absorbing layer provided in contact with or adjacent to a layer comprising a reducible organic silver salt.
    Type: Grant
    Filed: February 5, 1979
    Date of Patent: March 31, 1981
    Assignee: Canon Kabushiki Kaisha
    Inventors: Ichiro Endo, Hajime Kobayashi, Toshiyuki Komatsu, Shigeru Ohno
  • Patent number: 4252895
    Abstract: A photodevelopable silver halide photosensitive material wherein a visible image is formed by a latent image-forming step in which high illumination exposure is effected for a short time and a subsequent light development step in which low illumination exposure is effected, which comprises at least one compound of the formula: ##STR1## wherein R.sub.1 is hydrogen, lower alkyl or a substituted or unsubstituted aryl group and salts thereof.
    Type: Grant
    Filed: July 31, 1979
    Date of Patent: February 24, 1981
    Assignee: Oriental Photo Industrial Co., Ltd.
    Inventors: Masahiro Kato, Shoichiro Sumi, Shoji Iwata
  • Patent number: 4239846
    Abstract: Disclosed are tellurium (IV) compounds represented by the formula: ##STR1## wherein: D is a Lewis base function containing a group VA or VIA donor atom;Q represents the atoms necessary to complete a 5- or 6-membered ring, when taken together with C, D and Te, when m is 1 and represents the atoms linking C and D when m is greater than 1;R.sub.1 and R.sub.2 are independently selected from the group consisting of hydrogen, alkyl and aryl;X is an anion;n is 1 or 2; andm is an integer from 1 to 500.These compounds are useful in an image-forming combination comprising the described Te(IV) compound and a reducing agent. The image-forming combination is useful in a variety of materials, including a dry amplification element.
    Type: Grant
    Filed: April 10, 1978
    Date of Patent: December 16, 1980
    Assignee: Eastman Kodak Company
    Inventors: Henry J. Gysling, Sylvia A. Gardner
  • Patent number: 4213784
    Abstract: In a process for producing thermally developable light-sensitive composition which comprises heating a composition containing (a) an organic silver salt and (b) a light-sensitive silver halide, the improvement wherein the heating is conducted in the presence of (c) a sulfur-containing compound.
    Type: Grant
    Filed: July 3, 1978
    Date of Patent: July 22, 1980
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shinpei Ikenoue, Takao Masuda
  • Patent number: 4208478
    Abstract: A Te(II) complex represented by the formula: RTeM(R').sub.3 wherein M is lead, tin, germanium or silicon; R and R' are alkyl or aryl is useful in an imaging material to provide a non-silver image. The imaging material can be a photographic material, especially a heat-developable photographic material containing, for example, a photosensitive metal salt other than the Te(II) material or other sources of developable nuclei.
    Type: Grant
    Filed: October 13, 1977
    Date of Patent: June 17, 1980
    Assignee: Eastman Kodak Company
    Inventors: Sylvia A. Gardner, Henry J. Gysling