And Inorganic Silver Compound Patents (Class 430/619)
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Patent number: 5985537Abstract: A photothermographic element comprising a substrate having on at least one side thereof a photothermographic system comprising silver halide spectrally sensitized to the infrared region of the electromagnetic spectrum, a light insensitive silver source, a reducing agent for silver ion, and a binder, said element further comprising at least one layer which contains an infrared-absorbing dye having a central nucleus of the formula ##STR1## wherein n is an integer of 1 to 12,Q is an ionic acidic moiety,and M is a cation, in an amount sufficient as to provide a transmission optical density of at least 0.1 at the wavelength of maximum sensitivity of said sensitized silver halide.Type: GrantFiled: November 10, 1993Date of Patent: November 16, 1999Assignee: Minnesota, Mining & Manufacturing Co.Inventors: James B. Philip, Jr., Charles W. Gomez
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Patent number: 5981156Abstract: A method of making a thermally processable imaging element which comprises:i) forming a solution of poly(vinyl alcohol) in water;ii) adding matte particles to the resulting aqueous medium;iii) adding a compound of the formula I or formula II to the aqueous medium in an amount sufficient to inhibit agglomeration of the matte particles: ##STR1## wherein: the substituents are as described in the specification; iv) coating an image recording layer onto one side of a support;v) coating the aqueous medium containing the matte particles as an overcoat layer over the image recording layer or as backing layer on the side of the support opposite the image recording layer.Type: GrantFiled: August 20, 1997Date of Patent: November 9, 1999Assignee: Eastman Kodak CompanyInventors: Sharon M. Melpolder, Peter J. Cowdery-Corvan, Alfred J. Alton
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Patent number: 5981151Abstract: According to the present invention there is provided a photothermographic material comprising on a support a photo-addressable thermally developable element containing a substantially light-insensitive organic heavy-metal salt, photosensitive silver halide in catalytic association with said substantially light-insensitive organic heavy-metal salt, a reductor for said substantially light-insensitive organic heavy-metal salt and a binder, said photothermographic material having on the same side of the support as said photo-addressable thermally developable element an outermost layer having two phases at least one of which being a dispersion phase of thermoplastic particles, characterized in that said two phases exhibit different affinities for at least one printing liquid selected from the group consisting of ink and an abhesive fluid for ink.Type: GrantFiled: July 23, 1998Date of Patent: November 9, 1999Assignee: Agfa-Gevaert, N.V.Inventors: Luc Leenders, Ludo Van Rompuy
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Patent number: 5968725Abstract: A photothermographic material comprising a photosensitive silver halide, an organic silver salt, a reducing agent, and an ultrahigh contrast promoting agent, typically a hydrazine derivative. In one embodiment, a compound having a group for promoting adsorption to the silver halide is contained for suppressing occurrence of pepper fog. In another embodiment, a 5- or 6-membered heterocyclic mercapto compound having at least two nitrogen atoms or a tetraazaindene compound is contained for suppressing a change of photographic properties, typically image enlargement with a variation of developing conditions. In either case, the photothermographic material can form super-high contrast images of quality.Type: GrantFiled: April 24, 1997Date of Patent: October 19, 1999Assignee: Fuji Photo Film Co., Ltd.Inventors: Kazunobu Katoh, Minoru Sakai
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Patent number: 5965347Abstract: A thermally processable imaging element which comprises a support bearing an imaging layer containing in reactive association an image-forming combination comprising an organic silver salt oxidizing agent with a reducing agent for the organic silver salt oxidizing agent, wherein the imaging layer comprises a binder and a chlorinated hydrocarbon.Type: GrantFiled: November 26, 1997Date of Patent: October 12, 1999Assignee: Eastman Kodak CompanyInventors: Charles L. Bauer, Dorothy T. Java
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Patent number: 5965346Abstract: A photothermographic material is disclosed, comprising a support having on at least one surface thereof a light-sensitive silver halide grain, an organic salt, a reducing agent for silver ion and a binder, wherein the heat-developable light-sensitive material contains a methine dye represented by formula (I).Type: GrantFiled: July 31, 1997Date of Patent: October 12, 1999Assignee: Fuji Photo Film Co., Ltd.Inventors: Yoshio Inagaki, Naoyuki Hanaki, Hirohiko Tsuzuki
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Patent number: 5965348Abstract: In a thermographic material comprising an organic acid silver, the organic acid silver having a half-width of up to 21.0' as measured by X-ray diffractometry is used. Then the thermographic material experiences a minimal change of photographic properties during shelf storage.Type: GrantFiled: May 16, 1997Date of Patent: October 12, 1999Assignee: Fuji Photo Film Co., Ltd.Inventor: Ichizo Toya
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Patent number: 5965331Abstract: An apparatus and a method for bringing a thermographic imaging element (11) to a desired temperature by means of thermal contact with a heating body (10, 30) which is at least filled with an accessory material in a first phase (15) and with said accessory material in a second phase (16) comprise pressure setting means (17, 18) for setting a desired pressure, energy means (19) for exchanging thermal energy with said heating body, detection means for detecting a phase or a phase transition of said accessory material, and relocation means for bringing said imaging element into contact with said heating body.Type: GrantFiled: June 26, 1997Date of Patent: October 12, 1999Assignee: AGFA-Gevaert, N.V.Inventors: Leo Oelbrandt, Karl Anthonissen, Marc De Niel, Martin De Kegelaer
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Patent number: 5962212Abstract: A thermographic recording element comprising an organic acid silver salt, a reducing agent, a specific hydrazine derivative, and optionally, a photosensitive silver halide is improved in storage stability and forms images having high Dmax.Type: GrantFiled: June 3, 1998Date of Patent: October 5, 1999Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroyuki Suzuki, Toshiaki Kubo, Kohzaburoh Yamada
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Patent number: 5958668Abstract: A recording medium comprising a support having thereon a recording layer comprising an organic silver salt, a developing agent for the organic silver salt, a water-soluble binder and an antifoggant in an amount of from 10 mol % to 40 mol % based on the organic silver salt. The recording material has a long shelf life and provides a high-density image.Type: GrantFiled: May 21, 1997Date of Patent: September 28, 1999Assignee: Fuji Photo Film Co., Ltd.Inventors: Hirotaka Matsumoto, Kimi Ikeda, Hisashi Okada
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Patent number: 5958667Abstract: A photothermographic recording material comprising a support and a photo-addressable thermally developable element containing a substantially light-insensitive organic silver salt, a reducing agent therefor in thermal working relationship therewith, photosensitive silver halide spectrally sensitized to wavelengths >700 nm with a dye and in catalytic association with the substantially light-insensitive organic silver salt and a water-soluble binder, a water-dispersible binder or a mixture of a water-soluble and a water-dispersible binder, characterized in that the photothermographic recording material has an infra-red sensitivity of less than 80 J/m.sup.2 and the dye satisfies the following test: an exposure required by a photothermographic recording material A, consisting of a polyester 100 .mu.Type: GrantFiled: July 8, 1997Date of Patent: September 28, 1999Assignee: Agfa-GevaertInventors: Geert Deroover, Paul Callant, Herman Uytterhoeven
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Patent number: 5952167Abstract: A photothermographic material comprising (a) a reducible silver source, (b) a photocatalyst, (c) a reducing agent, (d) a binder, and (e) a compound represented by the following formula (I): wherein Q represents an atomic group necessary to form a six-membered heterocycle containing two to four nitrogen atoms; Y represents --CO--, --SO--, or --SO.sub.2 --; X.sub.1 and X.sub.2 each represent a halogen atom; and A represents a hydrogen atom or an electron withdrawing group, the photothermographic material exhibiting low fogging without deterioration in image tone and sensitivity decrease.Type: GrantFiled: March 5, 1997Date of Patent: September 14, 1999Assignee: Fuji Photo Film Co., Ltd.Inventors: Hisashi Okada, Naoki Asanuma, Ichizo Toya
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Patent number: 5948608Abstract: A photothermographic material comprising light-sensitive silver halide grains, with the photosensitive material further comprising a heptamethine cyanine dye containing at least one arylthio or thienyl group as substituent.Type: GrantFiled: April 25, 1997Date of Patent: September 7, 1999Assignee: Fuji Photo Film Co., Ltd.Inventors: Yoshio Inagaki, Toyohisa Oya, Katsumi Kobayashi, Hirohiko Tsuzuki
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Patent number: 5945263Abstract: A photothermographic recording material comprising a support; a photo-addressable thermally developable element comprising a substantially light-insensitive organic silver salt, photosensitive silver halide in catalytic association with the substantially light-insensitive organic silver salt spectrally sensitized to the infrared region of the electromagnetic spectrum and a binder; and in a hydrophobic layer an antihalation dye according to the general formula (I): ##STR1## wherein R.sup.1 and R.sup.15 independently represent an alkyl group or an alkyl group substituted with at least one fluorine, chlorine, bromine or an alkoxy-, aryloxy- or ester-group; R.sup.2, R.sup.3, R.sup.16 and R.sup.17 independently represent an alkyl group; R.sup.4, R.sup.5, R.sup.6, R.sup.7, R.sup.18, R.sup.19, R.sup.20 and R.sup.Type: GrantFiled: May 30, 1997Date of Patent: August 31, 1999Assignee: Agfa-Gevaert N.V.Inventors: Geert Deroover, Etienne Van Thillo, Ivan Hoogmartens, Hans Strijckers
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Patent number: 5939248Abstract: A photothermographic material having a photosensitive medium comprising: photosensitive silver halide, a reducible silver source, a reducing agent for silver ion, a hydrobromic acid salt of a nitrogen-containing heterocyclic ring or fused ring nucleus associated with a pair of bromine atoms CHARACTERIZED IN THAT the photosensitive medium additionally comprises as an antifoggant, substantially in the absence of an antifoggant effective amount of mercury and other heavy metal salts, a tribromomethyl ketone compound of general formula (I): ##STR1## in which; R represents an alkyl group, an aryl group, a carbocyclic ring or fused ring nucleus or a heterocyclic ring or fused ring nucleus.Type: GrantFiled: September 24, 1993Date of Patent: August 17, 1999Assignee: Minnesota Mining and Manufacturing CompanyInventors: Mark P. Kirk, David B. Oliff
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Patent number: 5939249Abstract: A negative-acting photothermographic element comprises a support bearing at least one heat-developable, photosensitive, image-forming photothermographic emulsion layer that contains photosensitive silver halide grains doped with iridium and copper; a non-photosensitive, reducible source of silver; a reducing agent for the non-photosensitive, reducible source of silver; and a binder. A process of forming photothermographic emulsions from doped silver halide grains by forming silver soaps in the presence of those grains is also described.Type: GrantFiled: June 24, 1997Date of Patent: August 17, 1999Assignee: Imation Corp.Inventor: Chaofeng Zou
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Patent number: 5928856Abstract: A thermographic imaging element comprises:(a) a support;(b) an imaging layer comprising:(i) an oxidizing agent;(ii) a first reducing agent which has high activity with an activation energy of less than 10 Joules/sq.cm.;(iii) a second reducing agent which has low activity with an activation energy of greater than or equal to 10 Joules/sq. cm.; and(iv) a third reducing agent comprising a boron compound containing at least one boron-hydrogen bond.Type: GrantFiled: March 20, 1998Date of Patent: July 27, 1999Assignee: Eastman Kodak CompanyInventors: Thomas D. Weaver, David F. Jennings
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Patent number: 5928855Abstract: A thermographic imaging element comprises:(a) a support;(b) an imaging layer comprising:(i) a silver salt;(ii) a first reducing agent which has high activity with an activation energy of less than 10 Joules/sq.cm.;(iii) a second reducing agent which has low activity with an activation energy of greater than or equal to 10 Joules/sq. cm.; and(iv) a third reducing agent comprising a silicon compound containing at least one silicon-hydrogen bond.Type: GrantFiled: March 20, 1998Date of Patent: July 27, 1999Assignee: Eastman Kodak CompanyInventors: Thomas D. Weaver, David F. Jennings
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Patent number: 5928857Abstract: A spectrally sensitized photothermographic silver halide element comprising a support layer having on at least one surface thereof a photothermographic composition, said composition comprising a polyvinyl acetal binder, a light insensitive silver source, a reducing agent for silver ion and infrared radiation sensitive silver halide grains, wherein said composition also comprises a polymeric component which is not a polyvinyl acetal, or a metal soap other than a silver soap of an organic acid (especially not the long chain fatty acid normally present in silver halide based photothermographic elements) which is dispersed in said composition in an amount of from 0.3 to 20% by weight of said polyvinyl acetal, which polymeric component has higher strength of adhesion to polyester film than does the polyvinyl acetal, and said polymeric may exist as a separate phase within said polyvinyl acetal.Type: GrantFiled: December 18, 1996Date of Patent: July 27, 1999Assignee: Minnesota Mining and Manufacturing CompanyInventors: Thomas C. Geisler, Kimberly K. Marquardt
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Patent number: 5922528Abstract: A thermographic imaging element comprising:(a) a support; and(b) an imaging layer comprising:(i) an oxidizing agent;(ii) a first reducing agent; and(iii) a second reducing agent comprising a silicon compound containing at least one silicon-hydrogen bond.Type: GrantFiled: March 20, 1998Date of Patent: July 13, 1999Assignee: Eastman Kodak CompanyInventors: Thomas D. Weaver, David F. Jennings
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Patent number: 5922529Abstract: A photothermographic material has a photosensitive layer containing a binder, organic silver salt, reducing agent, and silver halide on one surface of a support. The photosensitive layer further contains a specific sulfur-containing compound and a merocyanine dye of specific structure and has an absorbance of 0.15-1.0 at an exposure wavelength. Sharpness, sensitivity, and aging stability are improved.Type: GrantFiled: December 23, 1997Date of Patent: July 13, 1999Assignee: Fuji Photo Film Co., Ltd.Inventors: Hirohiko Tsuzuki, Hisashi Okada, Yoshio Inagaki
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Patent number: 5891616Abstract: A process for producing a suspension of particles containing a substantially light-insensitive organic silver salt of an organic carboxylic acid, comprising simultaneous metered addition of an aqueous solution or suspension of an organic carboxylic acid or its salt; and an aqueous solution of a silver salt to an aqueous liquid, wherein the metered addition of the aqueous solution or suspension of the organic carboxylic acid or its salt; and/or the aqueous solution of the silver salt is regulated by the concentration of silver ions or the concentration of anions of the silver salt in the aqueous liquid; for use in the production of (photo)thermographic materials.Type: GrantFiled: July 17, 1996Date of Patent: April 6, 1999Assignee: Agfa-GevaertInventors: Yvan Gilliams, Herman Uytterhoeven
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Patent number: 5891610Abstract: Thermally processable imaging elements in which the image is formed by imagewise heating or by imagewise exposure to light followed by uniform heating has a protective overcoat layer containing poly(silicic acid), and a mixture of a water-soluble hydroxyl-containing polymer and a polyvinyl acetal.Type: GrantFiled: June 12, 1997Date of Patent: April 6, 1999Assignee: Eastman Kodak CompanyInventors: Charles L. Bauer, Wayne A. Bowman
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Patent number: 5885765Abstract: A recording material for producing high contrast images comprising at least one thermosensitive element, comprising a layer comprising a substantially light-insensitive organic silver salt in at least one binder and in thermal working relationship therewith an organic reducing agent therefor, on a support, characterized in that the recording material is light-insensitive and the layer contains colloidal particles comprising silicon dioxide at a coating weight given by expression (1): ##EQU1## wherein B represents the total weight of all binders in the layer, AGOS represents the total weight of organic silver salt in the layer and S represents the weight of the colloidal particles in the layer; and wherein a protective layer is optionally applied to the thermosensitive element being thereby an outermost layer of the recording material.Type: GrantFiled: December 26, 1996Date of Patent: March 23, 1999Assignee: Agfa-GevaertInventors: Bartholomeus Horsten, Vankeerberghen An, Leenders Luc
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Patent number: 5876905Abstract: A dual-coated radiographic element capable of producing a viewable image when heated following imagewise exposure is disclosed comprised of, on opposite sides of a transparent film, layer units containing radiation-sensitive radiation-sensitive silver halide grains, a light-insensitive source of silver, and a reducing agent for said light-insensitive reducible source of silver. Greater than 50 percent of total projected area of said silver halide grains being provided by tabular grains (a) having {100} major faces, (b) containing greater than 70 mole percent chloride, based on silver, (c) exhibiting an average thickness of less than 0.3 .mu.m, and (d) exhibiting an average equivalent circular diameter of greater than 0.6 .mu.m.Type: GrantFiled: March 20, 1997Date of Patent: March 2, 1999Assignee: Eastman Kodak CompanyInventors: Mark E. Irving, David H. Levy, Lyn M. Eshelman, Debra L. Hartsell
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Patent number: 5876915Abstract: A photothermographic recording material comprising a support and a photo-addressable thermally developable element comprising a substantially light-insensitive organic silver salt, a reducing agent therefor in thermal working relationship therewith, photosensitive silver halide spectrally sensitized with a dye and in catalytic association with the substantially light-insensitive organic silver salt and a binder, characterized in that the dye is represented by formula (I): ##STR1## with an anion if necessary for charge compensation, wherein Z.sup.1 and Z.sup.2 independently represent S, O or Se; R.sup.1 and R.sup.13 independently represent an alkylene group; X.sup.1 and X.sup.2 independently represent a --(C.dbd.O)--R.sup.18, a --(SO.sub.2)R.sup.19 or a (S.dbd.O)--R.sup.20 group where R.sup.18, R.sup.19, and R.sup.20 independently represent an alkoxy-, aryloxy-, amino- or substituted amino-group.Type: GrantFiled: July 8, 1997Date of Patent: March 2, 1999Assignee: Agfa-GevaertInventors: Geert Deroover, Ivan Hoogmartens, Hans Strijckers
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Patent number: 5869229Abstract: A photothermographic material contains a compound of formula (I): ##STR1## wherein X represents --N.dbd., --N(R)--, --O--or --S--wherein R represents hydrogen, hydroxy, aliphatic hydrocarbon, aryl or heterocyclic group, Z represents a valence bond or a group of non-metallic atoms necessary to form a 5 to 7-membered ring with X, and each of Q.sub.1 and Q.sub.2 represents a group of non-metallic atoms necessary to form an aromatic hydrocarbon ring or aromatic heterocycle fused to the ring completed by Z. The material has high sensitivity in the infrared region and a minimal sensitivity change with varying storage conditions.Type: GrantFiled: September 9, 1997Date of Patent: February 9, 1999Assignee: Fuji Photo Film Co., Ltd.Inventors: Hisashi Okada, Naoki Asanuma, Ryo Suzuki, Shiegeo Hirano
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Patent number: 5858637Abstract: A process of preparing a photothermographic composition of enhanced photosensitivity is disclosed comprised of (a) precipitating light-sensitive silver halide grains in the presence of a non-aqueous polymeric peptizer and (b) then combining the silver halide grains with an oxidation-reduction image-forming combination comprised of an organic silver compound and a reducing agent for the silver organic compound. Light-sensitivity of the silver halide grains is enhanced by, prior to step (b), sensitizing the silver halide grains with a gold sensitizer dissolved in an aqueous medium.Type: GrantFiled: June 27, 1997Date of Patent: January 12, 1999Assignee: Eastman Kodak CompanyInventors: Lyn M. Eshelman, Mark E. Irving, David H. Levy, Kathleen R. C. Gisser
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Patent number: 5858640Abstract: This invention provides a thermally processable imaging element comprising a support and a thermographic or photothermographic imaging layer, said imaging layer comprising a sulfenimide compound represented by the formula: ##STR1## wherein M represents the atoms necessary to form, with R.sup.1 and R.sup.2, a five or six-membered ring or a multiple ring system; w is 1 or 0, wherein when w is 0, R.sup.1 and R.sup.2 are independently substituted or unsubstituted aliphatic, aromatic or heterocyclic groups, and when w is 1, R.sup.1 and R.sup.2 are independently carbonyl or sulfonyl groups; R.sup.3 is independently a substituted or unsubstituted aliphatic, aromatic or heterocyclic group and x is 0 or 1.In one embodiment the thermally processable imaging element comprises:(a) photographic silver halide, and(b) an image-forming combination comprising(i) an organic silver salt oxidizing agent, with(ii) a reducing agent for the organic silver salt oxidizing agent.Type: GrantFiled: May 16, 1997Date of Patent: January 12, 1999Assignee: Eastman Kodak CompanyInventors: Peter J. Cowdery-Corvan, Roger L. Klaus, Franklin D. Saeva
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Patent number: 5856062Abstract: A light-sensitive material comprises a light-sensitive hardening layer provided on a support. The light-sensitive hardening layer contains silver halide, a reducing agent and an ethylenically unsaturated polymerizable compound or an ethylenically unsaturated cross-linkable polymer. The light-sensitive hardening layer further contains a coupling agent in an amount of 0.01 to 15 wt. %.Type: GrantFiled: April 18, 1996Date of Patent: January 5, 1999Assignee: Fuji Photo Film Co., Ltd.Inventor: Satoshi Hoshi
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Patent number: 5851755Abstract: A photothermographic recording material comprising a photo-addressable thermally developable element containing a substantially light-insensitive organic silver salt, photosensitive silver halide in catalytic association with the substantially light-insensitive organic silver salt and spectrally sensitized to infra-red light with a dye, a supersensitizer for the dye, a reducing agent in thermal working relationship with the substantially light-insensitive organic silver salt and a binder, wherein the binder includes a water soluble polymer, a water-dispersible polymer or a water soluble polymer and a water-dispersible polymer; the dye absorbs electromagnetic radiation in the wavelength range from 700 to 1100 nm; and the supersensitizer is a stilbene compound represented by general formula (I): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently hydrogen or alkyl, aryl, aralkyl, alkaryl, alkoxy or aryloxy groups; and R.sup.5, R.sup.6, R.sup.7, R.sup.8, R.sup.9, R.sup.10, R.sup.11 and R.Type: GrantFiled: July 8, 1997Date of Patent: December 22, 1998Assignee: Agfa-GevaertInventors: Herman Uytterhoeven, Johan Loccufier, Geert Deroover, Paul Callant
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Patent number: 5843632Abstract: A photothermographic composition of enhanced photosensitivity is disclosed prepared by a process of (a) precipitating light-sensitive silver halide grains in the presence of a non-aqueous polymeric peptizer and (b) then combining the silver halide grains with a non-aqueous polymeric vehicle containing an oxidation-reduction image-forming combination comprised of an organic silver compound and a reducing agent for the organic silver compound. Light-sensitivity of the silver halide grains is enhanced by, prior to step (b), sensitizing the silver halide grains with a 1,1,3,3-tetra-substituted thiourea or selenourea having an acid dissociation constant of less than 7.0, the thiourea or selenourea being dissolved in an aqueous medium.Type: GrantFiled: June 27, 1997Date of Patent: December 1, 1998Assignee: Eastman Kodak CompanyInventors: Lyn M. Eshelman, Mark E. Irving, David H. Levy, Kathleen R. C. Gisser
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Patent number: 5843618Abstract: An aqueous-developable chromogenic photographic heat-transferable non-aqueous dye-diffusion-transfer photographic element is disclosed, wherein said element comprises radiation sensitive silver halide, a dye-providing compound that forms or releases a heat-transferable image dye upon reaction of said compound with the oxidation product of a primary amine developing agent, a hydrophilic binder, and a thermal solvent for facilitating non-aqueous diffusion transfer according to formula (I) ##STR1## wherein AH is a hydrogen bond donating group with an aqueous pK.sub.a value for proton loss of greater than 6;L.sup.1 and L.sup.Type: GrantFiled: June 8, 1993Date of Patent: December 1, 1998Assignee: Eastman Kodak CompanyInventors: David Scott Bailey, Ronald Henry White, John Texter
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Patent number: 5840475Abstract: An element is disclosed containing a photothermographic layer capable of providing a retained viewable image when imagewise exposed and heated. The Layer contains a high chloride {100} tabular grains.Type: GrantFiled: October 28, 1996Date of Patent: November 24, 1998Assignee: Eastman Kodak CompanyInventors: David H. Levy, Lyn M. Eshelman, Mark E. Irving, Debra L. Hartsell
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Patent number: 5840469Abstract: A thermographic element comprises a support having coated on at least one surface thereof a thermographic imaging system that contains a substantially light insensitive metal salt; a gallic acid reducing agent; and an infrared absorbing compound.These elements provide images that have high density in the ultraviolet spectral region when exposed to infrared radiation.Type: GrantFiled: May 13, 1997Date of Patent: November 24, 1998Assignee: Imation Corp.Inventors: Jon Alfred Bjork, James Bernard Philip
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Patent number: 5795708Abstract: A heat processable film comprising:a base layer;a dichroic mirror layer; anda heat processable emulsion layer which is exposed by radiation having a predetermined range of wavelengths; wherein the dichroic mirror layer reflects radiation at least having the predetermined range of wavelengths to the emulsion layer and transmits radiation having wavelengths outside the predetermined range of wavelengths.Type: GrantFiled: August 16, 1996Date of Patent: August 18, 1998Assignee: Eastman Kodak CompanyInventor: John Claude Boutet
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Patent number: 5783380Abstract: A thermally processable imaging element is comprised of:(1) a support;(2) a thermographic or photothermographic imaging layer on one side of the support;(3) a transparent protective layer comprising:(A) a film forming binder;(B) a dye in said protective layer in an amount sufficient to impart a pre-selected color thereto; and(C) matte particles, the color of which substantially matches the color of the protective layer.Type: GrantFiled: September 24, 1996Date of Patent: July 21, 1998Assignee: Eastman Kodak CompanyInventors: Dennis Edward Smith, Sharon Marilyn Melpolder, John Leonard Muehlbauer
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Patent number: 5766828Abstract: An infrared laser addressable imaging element comprising a substrate bearing a first layer comprising a reducible light-insensitive silver salt and a binder; and a second layer comprising an infrared absorber, a reducing agent for said silver salt and a binder; wherein said binder of said first layer is a polymeric medium having a glass transition temperature of at least 80.degree. C.Type: GrantFiled: September 9, 1996Date of Patent: June 16, 1998Assignee: Imation Corp.Inventors: Ranjana C. Patel, Jonathan C. Vogel
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Patent number: 5763153Abstract: A photothermographic material containing photosensitive silver halide grains, in which a cyanine dye containing at least one of an alkylthio group, an arylthio group, and a substituent group having a thioether bond is included, thereby the photographic material exhibiting low fogging, high sensitivity, and improved stability.Type: GrantFiled: October 9, 1996Date of Patent: June 9, 1998Assignee: Fuji Photo Film Co. LtdInventors: Hirohiko Tsuzuki, Yoshio Inagaki
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Patent number: 5750328Abstract: Thermally processable imaging elements in which the image is formed by imagewise heating or by imagewise exposure to light followed by uniform heating are comprised of a support, a thermographic or photothermographic imaging layer, a protective overcoat layer and a backing layer and include in at least one layer thereof, polymeric matte particles comprising a polymeric core surrounded by a layer of colloidal inorganic particles. The polymeric matte particles provide enhanced image quality and improved processing characteristics with respect to adhesion, dusting and lack of haze.Type: GrantFiled: April 16, 1996Date of Patent: May 12, 1998Assignee: Eastman Kodak CompanyInventors: Sharon Marilyn Melpolder, Dennis Edward Smith, Christopher Edwin Wheeler, John Leonard Muehlbauer
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Patent number: 5714311Abstract: This invention provides a thermally processable imaging element comprising a support and a thermographic or photothermographic imaging layer, said imaging layer comprising an aryliodonium compound represented by the formula: ##STR1## wherein R.sup.1 and R.sup.2 and R.sup.3 are independently H, or aliphatic, aromatic or heterocyclic groups, alkoxy groups, hydroxy groups, halogen atoms, aryloxy groups, alkylthio groups, arylthio groups, acyl groups, sulfonyl groups, acyloxy groups, carboxyl groups, cyano groups, nitro groups, sulfo groups, alkylsulfoxide or trifluoralkyl groups, or any two of R.sup.1, R.sup.2 and R.sup.3 together represent the atoms necessary to form a five or six-membered ring or a multiple ring system;R.sup.4 is a carboxylate salt or 0.sup.- ; w is 0 or 1; and X.sup.- is an anionic counter ion; with the proviso that when R.sup.3 is a carboxyl or sulfo group, w is 0 and R.sup.4 is 0.sup.-.Type: GrantFiled: January 8, 1997Date of Patent: February 3, 1998Assignee: Eastman Kodak CompanyInventors: Peter J. Cowdery-Corvan, Roger L. Klaus, Franklin D. Saeva
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Patent number: 5710095Abstract: A recording material comprising on the same side of a support, called the heat-sensitive side, (1) one or more layers comprising an imaging composition essentially consisting of (i) a substantially light-insensitive organic silver salt being in thermal working relationship with (ii) a reducing agent, and (2) at said same side covering said imaging composition a protective later, characterized in that said protective layer mainly comprises an organic thermosetting or moisture-hardened polymer or an organic thermosetting or moisture-hardened polymer composition.Type: GrantFiled: May 2, 1996Date of Patent: January 20, 1998Assignee: Agfa-GevaertInventors: Bartholomeus Cyriel Horsten, Guy Denis Jansen, Ronald Schuerwegen, Marc Irene Van Damme, Luc Herwig Leenders
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Patent number: 5705324Abstract: 4-Substituted isoxazole compounds are useful as co-developers in combination with hindered phenol developers to produce high contrast black-and-white photothermographic and thermographic elements.The photothermographic and thermographic elements may be used as a photomask in a process where there is a subsequent exposure of an ultraviolet or short wavelength visible radiation-sensitive imageable medium.Type: GrantFiled: March 14, 1996Date of Patent: January 6, 1998Assignee: Minnesota Mining and Manufacturing CompanyInventor: Thomas J. Murray
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Patent number: 5705323Abstract: Heat bleachable antihalation compositions are prepared using metallized or unmetallized formazan dyes, hexaarylbiimidzoles having alkoxy substituents and organic carboxylic acids. These compositions are rapidly bleached at relatively low temperatures and can be used in photothermographic elements.Type: GrantFiled: January 5, 1996Date of Patent: January 6, 1998Assignee: Eastman Kodak CompanyInventors: Robert James Perry, Ramanuj Goswami, Paul Anthony Zielinski
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Patent number: 5698380Abstract: A method for forming an image, which comprises a step of subjecting a light-sensitive material to exposure to laser light having a multi-longitudinal-mode, wherein the light-sensitive material comprises a support having provided thereon at least one layer containing light-sensitive silver halide grains having an average grain size of no greater than 0.2 .mu.m, and the light-sensitive silver halide grains have a coverage rate of no greater than 1 g/m.sup.2, based on silver.Type: GrantFiled: November 7, 1995Date of Patent: December 16, 1997Assignee: Fuji Photo Film Co., Ltd.Inventor: Ichizo Toya
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Patent number: 5698365Abstract: A heat development color photographic material excellent in discrimination and raw preservability of images, which comprises a support, and at least a light-sensitive silver halide, a binder, a coupler and a reducing agent formed thereon, in which a 2-acylamino-4-sulfonamidophenol derivative represented by the following general formula (I) is contained as said reducing agent: ##STR1## wherein R.sub.1 represents a substituent group (for example, alkyl or aryl); R.sub.2 to R.sub.4 each represents hydrogen or a substituent group (for example, halogen, alkyl or aryl); and R.sub.5 represents a substituent group (for example, alkyl or aryl).Type: GrantFiled: March 17, 1997Date of Patent: December 16, 1997Assignee: Fuji Photo Film Co., Ltd.Inventors: Toshiki Taguchi, Koki Nakamura
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Patent number: 5686228Abstract: Certain propenenitrile compounds have been found to function as antifoggants and serve to improve the initial minimum density of black and white photo-thermographic and thermographic elements.Type: GrantFiled: February 25, 1997Date of Patent: November 11, 1997Assignee: Imation Corp.Inventors: Thomas J. Murray, Paul G. Skoug
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Patent number: 5681693Abstract: The addition of 3-substituted-5-mercapto-1H-tetrazoles to silver halide photothermographic emulsions improves the post-processing stability of the emulsion.Type: GrantFiled: August 12, 1992Date of Patent: October 28, 1997Assignee: Minnesota Mining and Manufacturing CompanyInventors: Massimo Bertoldi, Stefano Mana, Cristina Soncini
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Patent number: 5677121Abstract: A silver halide photographic material which is useful for photography and diagnostic imaging and exhibits excellent storability to ordinary aging, excellent image storability, high sensitivity and low D.sub.min is disclosed. The heat-developable silver halide infrared ray-sensitive material comprises a support having on one side of the support an emulsion layer containing a binder, a nonsensitive silver salt, a reducing agent for silver ion and silver halide grains spectrally sensitized at a wavelength within the region of from 750 to 1,400 nm, wherein the nonsensitive silver salt comprises a mixture of silver salts of at least three kinds of acids, one of the acids is behenic acid, and the content of the behenic acid in the acids is from not less than 35 to less than 90 mol %.Type: GrantFiled: May 22, 1996Date of Patent: October 14, 1997Assignee: Fuji Photo Film Co., Ltd.Inventor: Hirohiko Tsuzuki
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Patent number: 5663042Abstract: A thermographic element comprising in a non-aqueous binder medium a silver salt oxidizing agent in reactive association with a compound comprising a plurality of redox color releasing moieties such that oxidation of each redox color releasing moiety causes release from said compound of a thermally diffusible dye.The compounds many of which are new incorporate two or more developer moieties into a single molecule to minimize the diffusibility of the compound. Following oxidation, either directly by the silver salt or by means of a cross-oxidizing agent, each oxidized developer moiety releases a thermally diffusible dye. The compounds are of sufficient size and molecular weight to slow or prevent diffusion in imaging systems and yet possess several active developer moieties per molecule which is advantageous over known ballasted dye releasers which comprise bulky molecules with only a single developer moiety.Type: GrantFiled: February 3, 1995Date of Patent: September 2, 1997Assignee: Minnesota Mining and Manufacturing CompanyInventors: Duncan McL. A. Grieve, Justine A. Mooney, William E. Bottomley, John H. A. Stibbard, Andrew W. Mott, Robert J. D. Nairne, David C. Bays, Stephen S. C. Poon, Raymond J. Kenney, Gilbert L. Eian, Takuzo Ishida, Doreen C. Lynch, Roger A. Mader, Sharon M. Simpson, Kim M. Vogel