And Inorganic Silver Compound Patents (Class 430/619)
  • Patent number: 4626500
    Abstract: A heat-developable photographic light-sensitive material is described, comprising a support having thereon, at least one layer containing a compound represented by the general formula (I) or (II) below: ##STR1## wherein R and R' each represents a group selected from a hydrogen atom, an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aralkyl group, an aryl group, an amino group, an acylamino group, an alkoxy group, an alkylthio group, a sulfonylamino group, a heterocyclic ring group and a substituted group of them; X represents atoms forming a 5-membered or 6-membered ring; A represents a group causing a decarboxylation reaction.This heat-developable photographic light-sensitive material provides a high maximum density and low fog by heat-developing at a relatively low temperature and for a short time.
    Type: Grant
    Filed: September 13, 1985
    Date of Patent: December 2, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kozo Sato, Hiroshi Kitaguchi, Hiroyuki Hirai
  • Patent number: 4626499
    Abstract: A heat developable light-sensitive material is described, comprising a support having thereon a light-sensitive silver halide emulsion, a base or a base precursor, and a compound containing a group bonded to a carbon atom is represented by formula (I) ##STR1## wherein R.sup.2 represents an aryl group, a substituted aryl group, a heterocyclic group or a group represented by formula (A), (B), or (C) ##STR2## wherein R.sup.11 through R.sup.16 each represents an alkyl group, a substituted alkyl group, an aryl group, or a substituted aryl group.
    Type: Grant
    Filed: April 26, 1985
    Date of Patent: December 2, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masatoshi Kato, Hiroshi Kitaguchi
  • Patent number: 4622289
    Abstract: A heat-developable light-sensitive material is described, comprising a support and at least one layer containing an alkali metal and/or alkaline earth metal salt of a carboxylic acid as a base precursor.
    Type: Grant
    Filed: April 19, 1984
    Date of Patent: November 11, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Hirai, Kozo Sato
  • Patent number: 4619888
    Abstract: A heat developable light-sensitive material comprising a support and a heat developable light-sensitive layer formed thereon can produce images of high density and less fog in a short period of time and has excellent aging stability. The light-sensitive material contains as a base precursor at least one compound selected from the group consisting of compounds represented by formula [I]: ##STR1## wherein R.sup.1 and R.sup.2 individually represent hydrogen, alkyl, cycloalkyl, alkenyl, alkynyl, aryl, aralkyl, heterocyclic group, or --CO.sub.2 M wherein M represents hydrogen, alkali metal or H.Bx, and R.sup.1 and R.sup.2 can be joined together to form a ring; R.sup.3 represents hydrogen atom, alkyl, cycloalkyl, alkenyl, alkynyl, aralkyl, aryl, or heterocyclic group; x is equal to 1 when B represents a monoacidic base and equal to 1/2 when B represents a diacidic base; and C* represents an asymmetric carbon atom.
    Type: Grant
    Filed: August 26, 1985
    Date of Patent: October 28, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Ken Kawata, Yoshiharu Yabuki, Kouzou Sato, Hiroyuki Hirai
  • Patent number: 4617257
    Abstract: A heat developable light-sensitive material is described, comprising a dye represented by formula (I) or (II) as described in claim 1.
    Type: Grant
    Filed: March 19, 1985
    Date of Patent: October 14, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Satoru Sawada, Toshinao Ukai
  • Patent number: 4614702
    Abstract: A heat-developable color photographic material comprising a support having thereon at least a light-sensitive silver halide, a hydrophilic binder, a dye releasing redox compound capable of releasing a hydrophilic dye and a compound represented by the following general formula (IIA): ##STR1## wherein B represents an alkyl group or a substituted alkyl group; m represents 0 or an integer of 1 to 4; and A represents an alkyl group, an aryl group, a cycloalkyl group, an aralkyl group, an alkoxy group, an aryloxy group, an alkylthio group, an arylthio group, an acyl group, an alkoxycarbonyl group, an amino group, an N-substituted amino group, an acylamino group, a carbamoyl group, an N-substituted carbamoyl group, an alkylsulfonyl group, an arylsulfonyl group, an alkylsulfonylamino group, an arylsulfonylamino group, a sulfamoyl group, an N-substituted sulfamoyl group, a cyano group, a hydroxy group, a nitro group or a halogen atom and when m represents 2 or more A may be the same or different.
    Type: Grant
    Filed: February 14, 1985
    Date of Patent: September 30, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Satoru Sawada, Yoshiharu Yabuki
  • Patent number: 4610957
    Abstract: A heat-developable light-sensitive material comprising a support having thereon at least one light-sensitive silver halide emulsion and an acid precursor having a structural moiety represented by the following formula (I) bonded to carbon atoms: ##STR1## The acid precursor is extremely stable at room temperature but when it is heated above a certain temperature, and the development proceeds to the desired appropriate condition, it releases an acid to neutralize a base, whereby the development is stopped. A heat-developable light-sensitive material containing the acid precursor provides color images having a high S/N ratio and a high image density.
    Type: Grant
    Filed: April 26, 1985
    Date of Patent: September 9, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masatoshi Kato, Hiroshi Kitaguchi
  • Patent number: 4603103
    Abstract: A heat-developable light-sensitive material comprising, on a support, a thermally decomposable organic silver salt. The heat-developable light-sensitive materials have high density and low fog.
    Type: Grant
    Filed: November 26, 1984
    Date of Patent: July 29, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Hirai, Kozo Sato, Hiroshi Hara
  • Patent number: 4599296
    Abstract: A process for forming an image which comprises heating a light-sensitive material comprising a support having thereon at least a light-sensitive silver halide, a binder and a dye releasing redox compound which is reductive to the light-sensitive silver halide and capable of releasing a hydrophilic dye upon reaction with the light-sensitive silver halide by heating, after imagewise exposure or simultaneously with imagewise exposure, in a substantially water-free condition in the presence of a compound represented by the formula (A): ##STR1## wherein R.sup.1 represents a hydrogen atom or a monovalent or divalent aliphatic group; R.sup.2 and R.sup.3, which may be the same or different from each other, each represents a hydrogen atom, an aliphatic group or an aromatic group; R.sup.1 and R.sup.2 may be taken together to form a heterocyclic ring; R.sup.2 and R.sup.3 may be taken together to form a heterocyclic ring; and n represents 1 or 2, to imagewise form a mobile dye is disclosed.
    Type: Grant
    Filed: March 29, 1984
    Date of Patent: July 8, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yukihiko Sakaguchi, Toshiaki Aono, Shinsaku Fujita
  • Patent number: 4595652
    Abstract: A heat-developable light-sensitive material is described, characterized by containing a polymer having a functional group releasing a basic component upon thermal decomposition in the side chain thereof. This polymer is a new base precursor which when added to heat-developable light-sensitive materials increases their storage stability and permits them to form an image of high density and decreased in fog even after storage. Preferred examples of such polymers are polymers having a repeating unit represented by the general formula (I): ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are each a univalent group, L is a divalent connecting group having from 1 to 20 carbon atoms, M is a cation and x is a number equivalent with the valence of M.
    Type: Grant
    Filed: July 30, 1985
    Date of Patent: June 17, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Taku Nakamura, Akira Hibino, Hiroyuki Hirai
  • Patent number: 4594312
    Abstract: Photothermographic elements containing heat bleachable acutance/antihalation dyes and thermographic elements employing heat bleachable dyes of the formula: ##STR1## in which: n is 2, 3, 4 or 5,at least one of R.sup.1 to R.sup.4 represent hydrogen and the remainder of R.sup.1 to R.sup.4 independently represent a hydrogen atom, an optionally substituted cycloalkyl group, an optionally substituted alkenyl group, an optionally substituted alkyl group, an optionally substituted aryl group, an optionally substituted heterocyclic aromatic group, or R.sup.1 and R.sup.2 together or R.sup.3 and R.sup.4 together represent the necessary atoms selected from C, N, O and S to complete a non-aromatic type ring,X.sup..crclbar. is an anion.
    Type: Grant
    Filed: March 6, 1984
    Date of Patent: June 10, 1986
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Gebran J. Sabongi, Stephen S. C. Poon, Bernard A. Lea
  • Patent number: 4587211
    Abstract: Certain effective leuco dyes for silver halide/silver salt/reducing agent photothermographic color imaging materials tend to bleach in the final image. The presently disclosed system of a syringaldazine and a stabilizing binder resin is more stable.
    Type: Grant
    Filed: February 1, 1985
    Date of Patent: May 6, 1986
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Takuzo Ishida, David C. Weigel
  • Patent number: 4585734
    Abstract: Certain effective toning systems for silver halide/silver salt/reducing agent photothermographic imaging materials tend to bleach the final image. The presently disclosed toning system of phthalazine and an active-hydrogen containing heterocyclic compound is more stable than some previous toners.
    Type: Grant
    Filed: February 1, 1985
    Date of Patent: April 29, 1986
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: David C. Weigel
  • Patent number: 4584267
    Abstract: A thermally developable, light-sensitive material is disclosed which has at least one thermally developable, light-sensitive layer formed on a support which contains (a) a light-sensitive silver halide, (b) an organic silver salt, (c) a reducing agent and (d) a binder. Said binder contains gelatin and/or a gelatin derivative and a poly(vinyl alcohol) having a viscosity average polymerization degree of not more than 700.
    Type: Grant
    Filed: September 13, 1984
    Date of Patent: April 22, 1986
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Toyoaki Masukawa, Kunihiro Koshizuka
  • Patent number: 4569906
    Abstract: A thermally developable photosensitive material containing (a) at least one organic silver compound, (b) at least one reducing agent, for said organic silver compound, (c) at least one photosensitive silver halide, and (d) at least one indan or tetralin derivative having at least two carboxyl groups. The indan and tetralin derivatives operate to suppress thermal fog.
    Type: Grant
    Filed: July 24, 1984
    Date of Patent: February 11, 1986
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Gustav Gutman
  • Patent number: 4562143
    Abstract: A method of forming an image by heat development of a photosensitive material comprising a support having a heat development photosensitive layer comprising imagewise exposing said layer and then bringing a non-water-permeable layer into close contact with said photosensitive layer, and heat developing said material, said photosensitive layer containing(a) an organic acid silver salt;(b) a photosensitive silver halide;(c) a reducing agent; and(d) a binder of at least one of gelatin and a gelatin derivative,said non-water-permeable layer comprising a high molecular compound selected from the group consisting of polyethylene, polypropylene, polystyrene, polyvinyl acetate, polyvinyl butyral, polyvinyl acetal, polyvinyl fluoride, polyvinyl pyrrolidone, polyvinyl chloride, polyacrylic ethyl, polymethacrylic methyl, polymethacrylic ethyl, polyvinylidene chloride, chlorinated polyethylene, chlorinated polypropylene, polycarbonate, polybutadiene, cellulose acetate, cellulose acetate butyrate, cellulose acetate propio
    Type: Grant
    Filed: July 20, 1984
    Date of Patent: December 31, 1985
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Shigeto Hirabayashi, Toyoaki Masukawa, Wataru Ishikawa
  • Patent number: 4560763
    Abstract: A base precursor for heat-developable photosensitive material is disclosed. The precursor is comprised of a compound represented by general formula (I) or (II):(R--C.tbd.C--CO.sub.2 H).sub.x.B (I)R--C.tbd.C--CO.sub.2 H).sub.2.B.sub.y (II)The substituents within the general formulae are defined within the specification. The use of this novel base precursor makes it possible to obtain a material which is very stable at normal temperatures and which smoothly decomposes under heating at 80.degree. C. or higher in order to release a basic constituent.
    Type: Grant
    Filed: March 30, 1984
    Date of Patent: December 24, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kozo Sato, Hiroyuki Hirai
  • Patent number: 4558003
    Abstract: The addition of a boric acid or borate ion to a poly(vinyl acetal) composition has been found to cause hardening of the composition. The hardened composition is particularly useful in photothermographic emulsions having a poly(vinyl acetal) layer.
    Type: Grant
    Filed: March 12, 1984
    Date of Patent: December 10, 1985
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Kiyoshi B. Sagawa
  • Patent number: 4555476
    Abstract: An image-forming process is disclosed. This process comprises heating a photographic material comprising a support having provided thereon at least light-sensitive silver halide, binder, and a dye releasing redox compound in the presence of a compound represented by the following general formula (A): ##STR1## wherein R.sub.1 represents a (m+n)-valent straight, branched or cyclic alkane or a (m+n)-valent straight, branched or cyclic alkene, R.sub.2 and R.sub.3, which may be the same or different, each represents a straight, branched or cyclic alkyl group or a straight, branched or cyclic alkenyl group, n represents 0, 1, 2 or 3, and m represents 0, 1 or 2, with m+n being 1 or more,after, or simultaneously with, imagewise exposure in the state of substantial absence of water to thereby imagewise form a mobile dye.
    Type: Grant
    Filed: March 29, 1984
    Date of Patent: November 26, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yukihiko Sakaguchi, Toshiaki Aono, Shinsaku Fujita
  • Patent number: 4555470
    Abstract: A heat-developable color photographic material comprising a support having thereon at least a light-sensitive silver halide, a hydrophilic binder, a dye releasing redox compound and a heat fusible compound which has a melting point of 60.degree. C. or higher and is represented by the following general formula (I), (II) or (III): ##STR1## wherein m represents an integer from 1 to 3; n represents an integer from 1 to 8; q represents an integer from 1 to 4; p represents an integer which meets the requirement for p+g=6; s represents an integer from 1 to 4; r represents an integer which meets the requirement for r+s=8; R represents a hydrogen atom or a substituent as set forth in the specification, and when m, p or r represents 2 or more, R may be the same or different; R.sub.1 represents an organic group in R.sub.1 - (OH).sub.n which is an alcohol, a phenol or a naphthol each having one or more hydroxy group and includes a saccharide; and R.sub.2 represents an organic group in R.sub.
    Type: Grant
    Filed: November 2, 1983
    Date of Patent: November 26, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yukihiko Sakaguchi, Kozo Sato, Hideki Naito, Hiroshi Hara
  • Patent number: 4550071
    Abstract: An image forming method which comprises (A) exposing to an imagewise pattern of light a light-sensitive material having on a support at least (1) a light-sensitive silver halide, (2) a binder, and (3) a compound which is chemically involved in the reduction of the light-sensitive silver halide to silver under high temperature thereby causing the production or the release of a mobile dye, (B) heating the light-sensitive material in a substantially water-free condition to form the mobile dye with an imagewise distribution subsequently to or simultaneously with the exposure, and (C) transferring the mobile dye into a dye-fixing layer under high temperature and fixing it thereto wherein an acidic component participates chemically in the reaction system for forming the mobile dye after the conclusion of the mobile dye-forming reaction to bring about the desirable effect on lowering the fog density thereof.
    Type: Grant
    Filed: April 9, 1984
    Date of Patent: October 29, 1985
    Assignee: Fuji Photo Film. Co., Ltd.
    Inventors: Toshiaki Aono, Koichi Nakamura
  • Patent number: 4546075
    Abstract: A heat-developable photographic material comprising (a) an organic silver salt, (b) a photocatalyst, (c) a reducing agent, (d) a binder, and (e) at least one compound selected from the compound represented by the general formula (I) described below and the compound represented by the general formula (II) described below. ##STR1## wherein X represents a halogen atom; and R represents a hydrogen atom, an alkyl group, an aryl group, an aralkyl group, an acyl group, a carbamoyl group, an alkylsulfonyl group, an arylsulfonyl group, an aralkylsulfonyl group or a heterocyclic residue, ##STR2## wherein X represents a halogen atom; Z represents a sulfur atom, an oxygen atom or >N--R.sub.1 (wherein R.sub.1 represents an alkyl group, an aryl group or an acyl group; (R')n represents a substituent present on the benzene nucleus; and n represents 0 or an integer from 1 to 4.
    Type: Grant
    Filed: September 9, 1983
    Date of Patent: October 8, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroshi Kitaguchi, Isamu Itoh, Itsuo Fujiwara, Yasushi Nozawa, Tadayoshi Kokubo
  • Patent number: 4543309
    Abstract: A composition suitable for application as a layer on a heat-developable image-pattern recording material to enhance the developability and stability thereof, comprising a silver salt of a benzotriazole, a reducing agent, a binder, at least one compound having the following Formula [I]: ##STR1## wherein R.sub.1 represents a hydrogen, an amino radical, or a substituted or unsubstituted alkyl, alkenyl or aryl radical; R.sub.2 represents a hydrogen, an amino alkyl, alkenyl or aryl radical is disclosed. The disclosed composition has improved developability.
    Type: Grant
    Filed: May 16, 1984
    Date of Patent: September 24, 1985
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Shigeto Hirabayashi, Toyoaki Masukawa, Wataru Ishikawa, Tetsuya Harada
  • Patent number: 4536467
    Abstract: A process for forming an image is described, comprising heating a light-sensitive material in a substantially water-free condition to form a mobile dye in an image pattern, said material having a support bearing thereon light-sensitive silver halide, a binder, and a dye-releasing redox compound capable of imagewise reducing the silver halide and releasing a hydrophilic dye on reaction with said silver halide when heated, after or simultaneously with imagewise exposure, in the presence of a compound having a melting point below 60.degree. C.
    Type: Grant
    Filed: March 29, 1984
    Date of Patent: August 20, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yukihiko Sakaguchi, Toshiaki Aono, Shinsaku Fujita
  • Patent number: 4536466
    Abstract: A method of forming an image comprising heating a light-sensitive material having at least a light-sensitive silver halide, a binder and a dye releasing redoc compound which is capable of reducing the light-sensitive silver halide and is capable of reacting with the light-sensitive silver halide by heating to release a hydrophilic dye on a support, under the condition substantially free from water after or simultaneously with imagewise exposure, in the presence of a compound represented by the general formula (A) described below to form imagewise a mobile dye. ##STR1## wherein R represents an alkyl group, a cycloalkyl group, an aryl group or an aralkyl group; R.sup.1 represents an alkyl group, a cycloalkyl group, an aryl group or an aralkyl group; R.sup.2 represents an alkyl group, an aryl group, an aralkyl group, a halogen atom or a group of R.sup.
    Type: Grant
    Filed: March 29, 1984
    Date of Patent: August 20, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yukihiko Sakaguchi, Toshiaki Aono, Shinsaku Fujita
  • Patent number: 4535056
    Abstract: A photographic construction comprises at least one spectrally-sensitized polymeric binder layer containing photographic silver halide and, in association therewitha. a non-light sensitive organic silver salt oxidizing agent,b. at least one biphenol color-forming reducing agent having the formula ##STR1## wherein each R is independently selected from a straight chain or branched alkyl or alkoxy group having 1 to 6 carbon atoms, and phenyl, and R.sup.1 is hydrogen or an alkalilabile protecting group, andc. at least one aliphatic or aromatic carboxylic acid of a specific class, which preferably is p-aminobenzoic acid, as development modifier, andd. optionally, at least one toner.
    Type: Grant
    Filed: March 15, 1984
    Date of Patent: August 13, 1985
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Robert A. Frenchik
  • Patent number: 4529689
    Abstract: Improved heat developable silver films are produced upon coating and drying a binder composition containing (a) a substantially light-insensitive silver sulfinate, (b) a silver halide photocatalyst, and (c) a developer. A preferred film contains (a) silver hexadecylsulfinate, (b) a separately sensitized silver halide emulsion and (c) a Phenidone or Dimezone moiety in a coalesced latex binder.
    Type: Grant
    Filed: October 31, 1983
    Date of Patent: July 16, 1985
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Ross A. Lee
  • Patent number: 4524128
    Abstract: Photographic silver halide is spectrally sensitized by means of at least one bleachable spectral sensitizing dye comprising a cyanine dye nucleus and a particular N-methylene substituent. The spectrally sensitized photographic silver halide is useful in a photothermographic material. An image in the photothermographic material, after exposure, is developed and the spectral sensitizing dye is bleached, especially at elevated pH, by heating the photothermographic material to processing temperature.
    Type: Grant
    Filed: October 24, 1983
    Date of Patent: June 18, 1985
    Assignee: Eastman Kodak Company
    Inventors: Larry D. Edwards, Frederick J. Sauter, George J. Burgmaier
  • Patent number: 4514493
    Abstract: A heat-developable light-sensitive material is described, which contains fine particles of a substantially water-insoluble base precursor incorporated in a binder. This light-sensitive material is superior in stability with the passage of time and the changes on the photographic characteristics such as maximum density, minimum density and sensitivity are less during the storage thereof.
    Type: Grant
    Filed: March 22, 1984
    Date of Patent: April 30, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Hirai, Kozo Sato, Ken Kawata
  • Patent number: 4511650
    Abstract: A heat developable color light-sensitive material is disclosed. The material is comprised of a support base having thereon a light-sensitive silver halide, a binder, a dye-releasing material and a base precursor. The dye-releasing material is reductive to the light-sensitive silver halide and releases hydrophilic dye by causing a reaction with the light-sensitive silver halide by heating. The base precursor is a compound represented by the general formulae (A) and/or (B): ##STR1## wherein the substituents are defined within the specification. The material is capable of forming images by heating in a substantially water free state in order to provide high-density color images in a short period of time. The images formed have a decreased amount of fogging and higher density as compared with conventional materials. Further, the disclosed material has excellent stability when stored.
    Type: Grant
    Filed: March 16, 1984
    Date of Patent: April 16, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Hirai, Ken Kawata
  • Patent number: 4510236
    Abstract: Thermally developable light sensitive material containing a light sensitive silver halide, an oxidizing agent, a reducing agent, and a combination of 2-(hydroxymethyl)-1(2H)-phthalazinone as a toning agent precursor and certain polycarboxylic acids or derivatives thereof as a catalyst for said toning agent precursor. Upon heat development of the exposed photothermographic material, the 2-(hydroxymethyl)-1(2H)-phthalazinone decomposes to form phthalazinone. The thus-formed phthalazinone acts as a toning agent for the light exposed silver halide.
    Type: Grant
    Filed: December 20, 1983
    Date of Patent: April 9, 1985
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Gustav Gutman
  • Patent number: 4507380
    Abstract: A heat-developable color photographic material is disclosed. The material is comprised of a support having thereon a layer containing at least a photographic silver halide and the photographic material containing an organic silver salt oxidizing agent, a reducing agent, a[hydrophobic]binder and a dye releasing compound which releases a diffusible dye upon heat development. The material is characterized by a support capable of receiving a released dye or a support having thereon a layer composed of an organic high molecular weight compound which is capable of receiving a released dye. The heat-developable color photographic material can easily provide a clear and stable color image by imagewise exposure to light and a heat development procedure. A process for forming a color image using the heat-developable color photographic material is also disclosed.
    Type: Grant
    Filed: June 17, 1982
    Date of Patent: March 26, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hideki Naito, Hiroshi Hara, Kozo Sato, Yoshiharu Yabuki
  • Patent number: 4504575
    Abstract: Novel heat-developable (photothermographic) films incorporate a silver alkyl sulfonate as a physical developer, and an organic base to neutralize acidity from the silver sulfonate. Preferably a heat-developable film is produced by coalescing a coating composition comprising a silver alkyl sulfonate, a silver halide emulsion as photocatalyst, a reducing agent, and an aqueous latex dispersion.
    Type: Grant
    Filed: October 31, 1983
    Date of Patent: March 12, 1985
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Ross A. Lee
  • Patent number: 4500626
    Abstract: A heat-developable color photographic material is disclosed. The material is comprised of a support having thereon a layer containing at least a light-sensitive silver halide, a hydrophilic binder, a dye releasing activator and a dye releasing compound which reduces the silver halide and releases a hydrophilic dye. The heat-developable color photographic material can easily provide a clear and stable color image by imagewise exposure to light and a heat-development procedure. A method of forming a color image using the heat-developable color photographic material is also disclosed.
    Type: Grant
    Filed: September 30, 1982
    Date of Patent: February 19, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hideki Naito, Hiroshi Hara, Toshiaki Aono, Kozo Sato, Shinsaku Fujita
  • Patent number: 4499180
    Abstract: A heat-developable color photographic material is disclosed. The material is comprised of a support base, a binder, a light-sensitive silver halide, a dye releasing redox compound which reduces the light-sensitive silver halide and releases a hydrophilic dye by reacting with the light-sensitive silver halide by heating; and a base precursor. The base precursor is represented by the general formula: ##STR1## wherein the substituents are defined within the specification. The material is capable of forming dye images with high density by heating the material after exposure in a substantially water free state. The images can be obtained in a short period of time and maintain their color density during storage. Further, the material produces a relatively low degree of fog based on the high degree of image density obtained.
    Type: Grant
    Filed: February 27, 1984
    Date of Patent: February 12, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Hirai, Ken Kawata
  • Patent number: 4499172
    Abstract: A heat-developable color light-sensitive material comprising a support having thereon at least a light-sensitive silver halide, a binder, a dye releasing redox compound which is capable of reducing the light-sensitive silver halide and is capable of reacting with the light-sensitive silver halide by heating to release a hydrophilic dye and a salt of an alkylcarboxylic acid having a triple bond between the .alpha.-position carbon atom and the .beta.-position carbon atom with an organic base as a base precursor.The heat-developable color light-sensitive material containing the novel base precursor has good stability during preservation and provides a color image having a high color density and low fog in a short time by a simple procedure. A method of forming a color image using the heat-developable color light-sensitive material is also disclosed.
    Type: Grant
    Filed: March 30, 1984
    Date of Patent: February 12, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Hirai, Kozo Sato
  • Patent number: 4480024
    Abstract: Photothermographic systems have not been useful in combination with X-ray purposes because of low speed, poor resolution and poor contrast. A particularly designed photothermographic element in combination with a rare-earth intensifying screen provides a high quality, fast, high resolution photothermographic radiographic system.
    Type: Grant
    Filed: October 21, 1983
    Date of Patent: October 30, 1984
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Thomas D. Lyons, Gregory J. McCarney
  • Patent number: 4476220
    Abstract: Photothermographic emulsions display enhanced spectral sensitization when the silver halide grains are formed in the presence of one or more spectral sensitizing dyes.
    Type: Grant
    Filed: July 1, 1983
    Date of Patent: October 9, 1984
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Keith A. Penfound
  • Patent number: 4473631
    Abstract: A heat-developable color photographic material is disclosed. The material is comprised of a support having thereon at least a light-sensitive silver halide, a hydrophilic binder, a dye releasing compound reductive and capable of releasing a hydrophilic dye and a compound represented by the following general formula (A): ##STR1## wherein A.sub.1, A.sub.2, A.sub.3, and A.sub.4, which may be the same or different, each represents a hydrogen atom or a substituent selected from an alkyl group, a substituted alkyl group, a cycloalkyl group, an aralkyl group, an aryl group, a substituted aryl group and a heterocyclic group, or A.sub.1 and A.sub.2 or A.sub.3 and A.sub.4 may combine with each other to form a ring.The heat-developable color photographic material can easily provide in a short time a clear and stable color image having a high color density and low fog by imagewise exposure and heat development procedure.
    Type: Grant
    Filed: November 4, 1983
    Date of Patent: September 25, 1984
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Hirai, Hideki Naito, Hiroshi Hara, Kozo Sato
  • Patent number: 4469773
    Abstract: A coupler containing in the coupling position a carbamoyloxy group ##STR1## upon oxidative coupling, releases a carbamic acid fragment that, in turn, is capable of thermally releasing ammonia or an amine. Such a carbamoyloxy substituted coupler and carbamic acid fragment are useful in imaging such as in photothermography and thermography. Ammonia or an amine released from the carbamic acid fragment enables imaging in imaging materials that are responsive to ammonia or an amine. The carbamoyloxy substituted coupler also generally is a dye-forming coupler that reacts with the oxidized form of a color developing agent to form a dye. An image is produced in an exposed photothermographic material comprising the carbamoyloxy substituted coupler by thermal development. An image is produced in a thermographic material comprising the carbamoyloxy substituted coupler and a color developing agent by imagewise heating the thermographic material.
    Type: Grant
    Filed: June 15, 1983
    Date of Patent: September 4, 1984
    Assignee: Eastman Kodak Company
    Inventors: Anthony Adin, Csaba A. Kovacs, Delwyn E. Machiele
  • Patent number: 4463079
    Abstract: A diffusion transfer heat-developable color photographic material. The material comprises a support, a photosensitive silver halide, an organic silver salt, a hydrophobic binder, a dye releasing activator, and a dye releasing redox compound which releases a diffusible dye. Color images are obtained with the material by transferring a dye released by heat development. The material makes it possible to obtain clear color images by a simple procedure and the images obtained are stable over a long period of time.
    Type: Grant
    Filed: April 30, 1982
    Date of Patent: July 31, 1984
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hideki Naito, Hiroshi Hara, Kozo Sato
  • Patent number: 4461828
    Abstract: A narrow range of dinuclear spectral sensitizing dyes can be used in photothermographic silver halide emulsions without adversely affecting fog and speed levels with concentration variations.
    Type: Grant
    Filed: May 13, 1983
    Date of Patent: July 24, 1984
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Kenneth W. Metz, Vincent K. Rasbury, Jack E. Reece
  • Patent number: 4460681
    Abstract: Color photothermographic articles are prepared by having the various color-forming layers separated by organic solvent soluble barrier layers insoluble in the organic solvent used to coat at least one of the adjacent color-forming layers.
    Type: Grant
    Filed: March 15, 1983
    Date of Patent: July 17, 1984
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Robert A. Frenchik
  • Patent number: 4459350
    Abstract: A 6-substituted-2,4-bis(trichloromethyl)-s-triazine stabilizer precursor which has a maximum absorption wavelength greater than 320 nanometers and is thermally stable at temperatures up to 150.degree. C. provides improved post-processing stability in a photothermographic silver halide material designed for dry physical development. Such a photothermographic material comprises photographic silver halide and an image forming combination comprising (i) an organic silver salt oxidizing agent, with (ii) a reducing agent for the organic silver salt oxidizing agent. A developed visible image is provided after imagewise exposure by uniformly heating the photothermographic material to moderately elevated temperatures.
    Type: Grant
    Filed: September 29, 1982
    Date of Patent: July 10, 1984
    Assignee: Eastman Kodak Company
    Inventor: Wojciech M. Przezdziecki
  • Patent number: 4452885
    Abstract: A heat-developable photographic material is disclosed. The material is comprised of (a) an organic silver salt, (b) a photocatalyst, (c) a reducing agent, (d) a binder, and (e) at least one compound selected from the group consisting of 2-trihalogenomethyl-3,4-oxadiazoles and the derivatives thereof as an antifogging agent. The use of component (e) does not present environmental pollution problems and successfully reduces fog density.
    Type: Grant
    Filed: September 29, 1982
    Date of Patent: June 5, 1984
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yasushi Nozawa, Tadayoshi Kokubo, Isamu Itoh, Hiroshi Kitaguchi
  • Patent number: 4452883
    Abstract: A photothermographic color construction is disclosed, the construction having at least two color-forming layers comprising:a. a first, spectrally-sensitized, color-forming layer coated out of a solvent system selected from lower alkyl alcohols (up to 4 carbon atoms) ketones (up to 6 carbon atoms), aromatic hydrocarbons (up to 10 carbon atoms), or mixtures thereof,b. an upper, second, different, spectrally-sensitized color-forming layer coated out of a toluene or acetone solvent system, andc.
    Type: Grant
    Filed: May 17, 1983
    Date of Patent: June 5, 1984
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Robert A. Frenchik, Kristen A. Hoff
  • Patent number: 4451561
    Abstract: A heat-development-type image recording material comprising an organic silver salt, a reducing agent, a binder, and an amido derivative of a 5-mercapto-1,2,4-triazole or a 5-mercapto-1,3,4-thiadiazole.
    Type: Grant
    Filed: April 22, 1983
    Date of Patent: May 29, 1984
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Shigeto Hirabayashi, Toyoaki Masukawa, Wataru Ishikawa, Tetsuya Harada
  • Patent number: 4450229
    Abstract: The addition of a class of compounds to a photothermographic emulsion reduces latent image fade.
    Type: Grant
    Filed: May 13, 1983
    Date of Patent: May 22, 1984
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Jack E. Reece
  • Patent number: 4442202
    Abstract: A post-activation type dry image forming material comprising (I) a silver salt component reducible to free silver upon light exposure and including silver iodide; (II) a redox reactive composition capable of making a visual change by a redox reaction of said composition, said reaction being initiated by heating in the presence of free silver; (III) an oxidizing agent for free silver which has an oxidizing capacity for free silver but is rendered photosensitive by heating and which, upon light exposure after said heating, is suppressed with respect to the oxidizing capacity for free silver and capable of catalytically promoting the redox reaction of said composition; and (IV) a photoreactive oxidizing agent, upon light exposure, capable of returning the reduced oxidizing agent for free silver to the original state.
    Type: Grant
    Filed: February 28, 1983
    Date of Patent: April 10, 1984
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Tetsuo Shiga, Takeo Kimura, Yoshinobu Ito, Kageyasu Akashi, Minoru Akiyama, Takeki Matsui
  • Patent number: 4435499
    Abstract: Photosensitive silver halide grains that are thin tabular grains having an average grain thickness of less than 0.3 microns provide advantages, including improved spectral sensitization and image tone, in a photothermographic material comprising photosensitive silver halide and a photosensitive silver halide processing agent. An image is developed in such an exposed photothermographic material by heating the material, such as to a temperature within the range of about 90.degree. C. to about 180.degree. C.
    Type: Grant
    Filed: January 31, 1983
    Date of Patent: March 6, 1984
    Assignee: Eastman Kodak Company
    Inventor: John W. Reeves