Heterocyclic Compound Containing, E.g., Heterocyclic Monomer, Etc. Patents (Class 430/630)
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Patent number: 8711358Abstract: A device that detects smoke, both indoor and outdoor; especially applicable in areas prone to sustained water flooding. It can be used in underground locations susceptible to water ingress so it can be submersed in up to 6 feet of water for up to 24 hours. Usable in applications that requires NEMA 6P or IP68 level of water protection.Type: GrantFiled: February 24, 2013Date of Patent: April 29, 2014Assignee: Temitayo GboluajeInventor: Temitayo Gboluaje
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Patent number: 7803514Abstract: Disclosed herein may be a photosensitive composition, a microfabricated structure including the same, a device including the microfabricated structure, and methods of fabricating the microfabricated structure and the device. The photosensitive composition, including a multifunctional photosensitive resin, a two-photon photosensitizer, an organic solvent, and a silver compound, may be subjected to two- or three-dimensional microfabrication, thus realizing the microfabricated structure containing silver nanoparticles.Type: GrantFiled: August 26, 2008Date of Patent: September 28, 2010Assignee: Samsung Electronics Co., Ltd.Inventor: Jong Jin Park
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Publication number: 20080166670Abstract: A liquid-type composition for forming a photosensitive polymer complex and a method of preparing a photosensitive polymer complex containing silver nanoparticles using the same are provided. The composition for forming a photosensitive polymer complex includes a multifunctional epoxy resin, a photoacid generator, an organic solvent and a silver compound, or additionally includes a multifunctional acrylate resin and a photoinitiator, or an additive, e.g., a surfactant or a flow improver. This composition is applied, selectively exposed, and developed, thus preparing a photosensitive polymer complex, which contains silver nanoparticles uniformly dispersed and formed in the polymer pattern portion thereof through photo reduction and is therefore improved in terms of physical or chemical properties, e.g., heat resistance and wear resistance.Type: ApplicationFiled: June 5, 2007Publication date: July 10, 2008Inventors: Jong Jin Park, Byung Ha Park, Young Ung Ha
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Patent number: 7186501Abstract: The present invention provides a photothermographic material, having a support and an image-forming layer containing a photosensitive silver halide, a non-photosensitive organic silver salt, and a reducer for the organic silver salt on at least one surface of the support, wherein the image-forming layer contains a hydrophilic polymer which has a vinyl monomer unit containing a quaternary nitrogen atom-containing group or a nitrogen-containing heterocyclic group.Type: GrantFiled: September 19, 2005Date of Patent: March 6, 2007Assignee: Fujifilm CorporationInventor: Seiichi Yamamoto
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Patent number: 7019453Abstract: A nonlinear optical chromophore having the formula D-?-A, wherein ? is a ? bridge including a thiophene ring having oxygen atoms bonded directly to the 3 and 4 positions of the thiophene ring, D is a donor, and A is an acceptor.Type: GrantFiled: July 23, 2003Date of Patent: March 28, 2006Assignee: Lumera CorporationInventors: Diyun Huang, Baoquan Chen
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Patent number: 6887656Abstract: Disclosed is a color photographic element comprising at least one light sensitive silver halide emulsion layer containing a compound that does not react with oxidized developer, has a Log Kow high enough to improve speed, compared to the same layer without the compound, and comprises (1) a thiadiazole, or (2) an oxadiazole, or (3) a 1,2,4 triazole bearing an amido substituent, and does not contain a hydroxyl or thiol group or their tautomeric equivalents on the azole ring.Type: GrantFiled: January 17, 2003Date of Patent: May 3, 2005Assignee: Eastman Kodak CompanyInventors: Louis E. Friedrich, Philip A. Allway, Judith A. Bogie, Bernard A. Clark, Charles E. Heckler, Stephen P. Singer
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Patent number: 6822384Abstract: In various embodiments, chromophores are described that include novel electron acceptors, novel electron donors, and/or novel conjugated bridges that are useful in nonlinear optical applications. In some embodiments, the present invention provides chromophore architectures wherein a chromophore contains more than one electron acceptor in electronic communication with a single electron donor, and/or more than one electron donor in electronic communication with a single electron acceptor. Also described is processes for providing materials comprising the novel chromophores and polymer matrices containing the novel chromophores. Electro-optic devices described herein contain one or more of the described electron acceptors, electron donors, conjugated bridges, or chromophores.Type: GrantFiled: March 13, 2003Date of Patent: November 23, 2004Assignee: Lumera CorporationInventors: Diyun Huang, Tim Londergan, Galina K. Todorova, Jingsong Zhu
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Patent number: 6783926Abstract: A device for establishing electrical connection between at least one contact pad on an integrated circuit (IC) card and corresponding conductive elements of a printed circuit board (PCB) having a plurality of evenly aligned brush contacts comprised in the PCB. An optional housing is adapted to apply pressure to the inserted card to press the contact pad of said card against the contacts comprised in the PCB. Each contact comprised in the PCB comprises a contact leg and a contact head that is attached to an open end of said contact leg. The contact legs are created and made flexible by removing unwanted parts of the PCB thus creating desired gaps between said contact legs. The contact head is created by attaching a conductor to the open end of a contact leg. The housing and the PCB together define a card insertion plane therebetween having a card insertion ingress at a front boundary thereof.Type: GrantFiled: September 12, 2002Date of Patent: August 31, 2004Inventor: Kenneth Reece
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Patent number: 6750603Abstract: A nonlinear optical chromophore having the formula D-&pgr;-A, wherein &pgr; is a &pgr; bridge including a thiophene ring having oxygen atoms bonded directly to the 3 and 4 positions of the thiophene ring, D is a donor, and A is an acceptor.Type: GrantFiled: November 22, 2002Date of Patent: June 15, 2004Assignee: Lumera CorporationInventors: Diyun Huang, Baoquan Chen
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Patent number: 6720134Abstract: A silver halide photographic emulsion comprising grains, wherein 70% or more of the total projected area of the grains is occupied by silver halide grains each meeting requirements (a) to (d) below (a) the grain is composed of a tabular silver halide host grain having two mutually parallel main planes and aspect ratio of 2 or more, and a silver halide protrusion portion epitaxially junctioned on the surface of the host grain; (b) the silver bromide contents of both the host grain and the protrusion portion are 70 mol % or more; (c) the percentage of the silver amount in the protrusion is 12% or less of the silver amount in the host grain; and (d) the grain has a shallow electron-trapping zone.Type: GrantFiled: January 14, 2002Date of Patent: April 13, 2004Assignee: Fuji Photo Film Co., Ltd.Inventors: Yasushi Miyamoto, Toshihiro Nishikawa, Nobuyuki Haraguchi, Hideo Ikeda, Takayoshi Mori
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Patent number: 6713243Abstract: A silver halide photosensitive material in which a noncoloring compound is used as a high-boiling-point organic solvent for dissolving components of the silver halide photosensitive material that have low solubility in water. Preferably, the silver halide photosensitive material has a hydrophilic colloid layer containing a hydrophilic polymer and the noncoloring compound is contained in the hydrophilic colloid layer. The silver halide photosensitive material produces durable colored images, reduces the formation of stains, improves storability, alleviates fogging and soft-toning of emulsion during storage, inhibits migration of a dispersion medium, is inexpensive, and is produced from materials that cause little damage to the environment.Type: GrantFiled: March 22, 2001Date of Patent: March 30, 2004Assignee: Fuji Photo Film Co., Ltd.Inventors: Hisashi Mikoshiba, Hiroyuki Yoneyama, Naoto Matsuda
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Patent number: 6593076Abstract: A photothermographica material is disclosed, comprising an organic silver salt and a light sensitive silver halide, wherein the photothermographic material contains a hydrophilic binder of 0.5 to 2 g per mol of the organic silver salt and the organic silver salt having been formed in the presence of the silver halide of 7×1015 to 3×1017 grains per mol of the organic salt.Type: GrantFiled: April 18, 2001Date of Patent: July 15, 2003Assignee: Konica CorporationInventors: Keiko Maeda, Tetsuo Shima, Kazuyoshi Goan
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Publication number: 20030124473Abstract: A silver salt photothermographic material is disclosed, comprising a support having provided thereon a light-sensitive layer containing light-sensitive silver halide, a light-insensitive organic silver salt and a binder, wherein the photothermographic material exhibits a gradation of 2.0 to 5.0 within the density region of 0.5 and 2.0 on a photographic characteristic curve obtained when the photothermographic material is subjected to exposure of 50 &mgr;J/cm2 and thermal development at 124° C. for 16 sec.; the light-sensitive layer comprises lower and upper layers and a glass transition temperature of a binder contained in the lower layer being higher than that of a binder contained in the upper layer.Type: ApplicationFiled: June 5, 2002Publication date: July 3, 2003Inventor: Tsuyoshi Mitsuhashi
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Patent number: 6548238Abstract: The stability of the dyes which are obtained after processing a color photographic material is improved by the addition of a polyvinylcaprolactam.Type: GrantFiled: July 20, 2001Date of Patent: April 15, 2003Assignee: AGFA-GevaertInventors: Beate Weber, Bernd Spachmann, Heinz Wiesen
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Publication number: 20020187414Abstract: Disclosed are marking particles comprising a resin, a chelating agent, and a spiropyran material which is of the formula 1Type: ApplicationFiled: January 11, 2002Publication date: December 12, 2002Applicant: Xerox CorporationInventors: Daniel A. Foucher, Raj D. Patel, Naveen Chopra, Peter M. Kazmaier
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Patent number: 6423487Abstract: The present invention provides a thermally processed image recording material having, on a support, an image-forming layer containing at least (a) a silver salt of an organic acid, (b) a reducing agent and (c) a photosensitive silver halide and at least one protective layer provided on the image-forming layer and comprising polymer latex as binders of the image-forming layer and the protective layer, wherein at least one of the image-forming layer and the protective layer contains a viscosity enhancer that increases viscosity of its aqueous solution when the solution is heated and temperature of the solution exceeds a certain transition temperature, and the viscosity enhancer is a polymer selected from the group consisting of polymers containing a (meth)acrylamide derivative represented by the following formula (1) or (2) in an amount of 50 weight % or more as constituent units: (wherein R1 represents H or CH3, R2 represents an alkylene group, R3 to R6 represent H or CH3, and X represents &mType: GrantFiled: April 13, 2001Date of Patent: July 23, 2002Assignee: Fuji Photo Film Co., Ltd.Inventor: Takashi Naoi
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Patent number: 6316177Abstract: Disclosed is a color silver halide photographic element comprising a light-sensitive silver halide emulsion layer or a non-silver containing light-insensitive layer, said light-sensitive or light-insensitive layer containing a polymer compound comprising a heterocycle unit derived from: (a) a heterocycle monomer (1) comprising two or more annulated rings containing, in total, a minimum of three ring heteroatoms of which no more than two of the heteroatoms are connected in sequence to each other and (2) having a ClogP less than 6.2; or (b) a monocyclic heterocycle monomer having exactly three ring heteroatoms and having a ClogP less than 8.75; with the proviso that the heterocycle unit does not contain a hydroxy or mercapto group (or their tautomeric equivalent), and does not react with oxidized developer; and the amount of the polymer compound in the element being sufficient to increase the photographic speed of the element compared to the same element without the compound.Type: GrantFiled: March 31, 2000Date of Patent: November 13, 2001Assignee: Eastman Kodak CompanyInventors: Philip A. Allway, Tienteh Chen, David S. Ross, Stephen P. Singer
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Publication number: 20010034385Abstract: A hydrophobically capped oligomeric acrylamide or pyrrolidone is employed as a dispersant for hydrophobic materials in an aqueous medium containing a hydrophilic colloid, e.g. gelatin. The hydrophobic materials include photographic addenda such as color couplers or solid particle dyes.Type: ApplicationFiled: January 26, 2001Publication date: October 25, 2001Applicant: Eastman Kodak CompanyInventors: Alan R. Pitt, Trevor J. Wear, Danuta Gibson, Ian M. Newington, Mary C. Brick, John W. Boettcher, Gary N. Barber
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Patent number: 6171774Abstract: A silver halide photographic light sensitive material is disclosed.Type: GrantFiled: November 9, 1998Date of Patent: January 9, 2001Assignee: Konica CorporationInventors: Kunimasa Hiyama, Kazuhiro Murai
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Patent number: 6107017Abstract: A photographic element comprises a support bearing at least one silver halide emulsion and at least one high-boiling solvent of structure I, below: ##STR1## wherein: each m is independently 0, 1 or 2;each R.sub.1 is independently methyl or ethyl;n is 2 to 7;each R.sub.2 and each R.sub.3 may be the same or different and is individually selected from hydrogen or an alkyl group with up to five carbon atoms; andthe sum of the number of carbon atoms in each R.sub.1 plus each R.sub.2 plus each R.sub.3 taken together is four to eight.Type: GrantFiled: June 24, 1998Date of Patent: August 22, 2000Assignee: Eastman Kodak CompanyInventors: Paul B. Merkel, Ronald E. Leone
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Patent number: 5985530Abstract: A silver halide photographic material is disclosed, comprising a support having on one side the support photographic component layers, wherein at least one of the component layers contains a composite polymeric material comprising inorganic particles and a hydrophobic polymer, a silver halide emulsion layer comprising a silver halide emulsion containing silver halide grains having an average chloride content of not less than 60 mol % and containing a metal dopant.Type: GrantFiled: July 25, 1997Date of Patent: November 16, 1999Assignee: Konica CorporationInventors: Wataru Ishikawa, Takehiro Kobayashi, Hirohide Ito
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Patent number: 5932404Abstract: The present invention is a silver halide photographic material including at least one layer which contains; a polymer comprising as constituent components thereof a repeating unit having a photographically useful group and at least one repeating unit having an imidazole group; and a compound having at least one functional group which reacts with an imidazole group and at least one other functional group capable of reacting with an imidazole group and a primary amine group, the amount of the compound being sufficient to insure adequate fixation of said polymer.Type: GrantFiled: December 18, 1996Date of Patent: August 3, 1999Assignee: Eastman Kodak CompanyInventors: Tienteh Chen, Hwei-ling Yau, Dorothy T. Java
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Patent number: 5888719Abstract: A color photographic material with a support and at least one spectrally sensitised silver halide emulsion layer containing at least one color coupler, which layer contains a polymer with repeat units of the structure I ##STR1## in which R.sub.1, R.sub.2, R.sub.3 are identical or different and mean hydrogen, alkyl or halogen,L means a chemical bond or a linking member andX means a group which reacts with NH.sub.2 --, COOH-- or OH-- groups in an addition or condensation reaction,in dispersed form with an average particle size of <300 nm, is distinguished by improved "dark fading" stability.Type: GrantFiled: July 29, 1996Date of Patent: March 30, 1999Assignee: AGFA-Gevaert AGInventor: Gunter Helling
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Patent number: 5834575Abstract: As a heteroaromatic compound made functional so as to be used in nonlinear optical materials, the present invention provides a heteroaromatic compound represented by the following Formula (1), (2), (3) or (4), a polymer obtained from any of these, a nonlinear optical element comprised of the polymer, an optical device having such an element, and a process for producing them. ##STR1## wherein Ar.sup.1, Ar.sup.2 and Ar.sup.3 each independently represent an aromatic group or an aromatic group having a substituent, R.sup.1, R.sup.2 and R.sup.3 each independently represent a hydrogen atom or a monovalent organic group, X represents a monovalent organic group, Y represents a hydrogen atom or a monovalent functional group, and n represents an integer of 2 to 10.Type: GrantFiled: November 13, 1996Date of Patent: November 10, 1998Assignee: Hitachi Chemical Company, Ltd.Inventors: Yutaka Honda, Iwao Fukuchi, Masato Taya, Kwan-Yue Alex Jen
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Patent number: 5824465Abstract: Disclosed is a polyalkylene naphthalate film, preferably the homopolymer of naphthalene-2,6-dicarboxylic acid and ethylene glycol (PEN), comprising a UV absorbing compound of the 2-hydroxyphenyl-triazine type for quenching of the UV fluorescence at 429 nm. The polymeric film is preferably used as support for a photographic material, preferably a color negative or color reversal photographic material.Type: GrantFiled: March 30, 1998Date of Patent: October 20, 1998Assignee: Agfa-Gevaert, N.V.Inventors: August Marien, Jorg Hagemann, Beate Weber
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Patent number: 5698367Abstract: Disclosed is a lithographic printing plate having a silver halide emulsion layer and a layer containing physical development nuclei on a support, the improvement wherein a water-soluble polymer having a structural unit represented by the formula (I): ##STR1## wherein R.sup.1 represents H or alkyl; Q represents divalent linking group; R.sup.2 represents divalent linking group or direct bond; and A represents a functional group represented by the formula: --S--C(.dbd.N--R.sup.4)--NH--R.sup.3, --Z--X(.dbd.Y)--(R.sup.5).sub.m or --W--(SH).sub.n where respective substituents are defined in the specification is contained in the layer containing physical development nuclei.Type: GrantFiled: December 7, 1995Date of Patent: December 16, 1997Assignee: Mitsubishi Paper Mills, LimitedInventors: Akira Furukawa, Motozo Yamano, Satoshi Shimonodan
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Patent number: 5698329Abstract: A coated film having a polymeric film substrate with a subbing layer containing an organic acid and a polymer which has a repeating unit(s) containing a pendant nitrogen atom(s). The ratio of organic acid to polymer in the subbing layer is in the range from 1:0.1 to 20 by weight. The coated film exhibits excellent adhesion to photographic emulsion layers, even when applied prior to completion of any film stretching operation.Type: GrantFiled: June 5, 1995Date of Patent: December 16, 1997Assignee: Imperial Chemical Industries PLCInventor: Julian Neal Robinson
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Patent number: 5591568Abstract: This invention provides composition and method to overcome the very high viscosity of prior small-particle dispersions when admixed with gelatin in aqueous solution for coating a photographic film element.The invention is generally accomplished by the utilization of a second surfactant in the melt formulated by the admixture of the small-particle dispersion and the gelatin solution. The surfactants of this invention, that is, utilized to control the rheology of such said melts, have the following general structure: ##STR1## wherein n=5 to 20 andx=1 to 4.Type: GrantFiled: September 6, 1994Date of Patent: January 7, 1997Assignee: Eastman Kodak CompanyInventors: Pranab Bagchi, James L. Edwards, Danuta Gibson, Thomas A. Rosiek, Brian Thomas, Vincent J. Flow, III
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Patent number: 5527665Abstract: An improved hardener and a photographic element comprising same defined by ##STR1## wherein: the substituent groups are as defined in the specification.Type: GrantFiled: May 31, 1995Date of Patent: June 18, 1996Assignee: E. I. Du Pont de Nemours and CompanyInventors: Ludovic Fodor, Timothy D. Weatherill, Rolf T. Weberg
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Patent number: 5492800Abstract: A silver halide photographic light-sensitive material has at least one silver halide emulsion layer. 50% or more of a total projected area of silver halide grains of at least one silver halide emulsion in the silver halide emulsion layer are accounted for by tabular grains each having an average aspect ratio of 2 or more and containing dislocations.Type: GrantFiled: June 3, 1994Date of Patent: February 20, 1996Assignee: Fuji Photo Film Co., Ltd.Inventor: Hiroyuki Yamagami
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Patent number: 5478715Abstract: A silver halide photographic material comprising a support and a silver halide emulsion layer provided thereon. The silver halide emulsion is prepared by nuclear formation, crystal growth and chemical sensitization. All or a part of the nuclear formation or the crystal growth is conducted in the presence of a hexa-coordinated cyano-complex to introduce the complex into crystal lattice of the silver halide. The density of the hexa-coordinated cyano-complex contained in surface parts of silver halide grains is in the range of 10.sup.-4 to 10.sup.-2 mol per 1 mol of silver. The surface parts of silver halide grains has a thickness of not more than 20.ANG. from the surfaces of the grains. The chemical sensitization is conducted using a gold sensitizer. The silver halide emulsion is prepared using a synthetic polymer as a protective colloid in place of gelatin. In the cases in which gelatin is used, it is present in an amount of not more than 10 g per 1 mol of silver.Type: GrantFiled: June 14, 1994Date of Patent: December 26, 1995Assignee: Fuji Photo Film Co., Ltd.Inventors: Tomoyuki Ohzeki, Shinji Ikari
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Patent number: 5455152Abstract: An ultraviolet absorbing monomer of formula (A): ##STR1## wherein: R.sub.4 and R.sub.5 are, independently, a substituted or unsubstituted alkylene with or without intervening oxygen, sulfur or nitrogen atoms; R.sub.6 is H or a substituted or unsubstituted methyl; and the benzo ring, the hydroxy substituted phenyl ring and the phenyl ring of the styryl group may be further substituted or unsubstituted. A method of making such monomers and photographic elements containing UV absorbing polymers formed from such monomers are also provided.Type: GrantFiled: September 27, 1994Date of Patent: October 3, 1995Assignee: Eastman Kodak CompanyInventor: Lal C. Vishwakarma
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Patent number: 5443948Abstract: An improved process for manufacturing a spectrally sensitized photographic element comprising the combination of ultrafiltration of silver halide grains in combination with a supersensitizing additive consisting of ##STR1## wherein D.sup.+ is Na.sup.+, K.sup.+, Li.sup.+, NH4.sup.+ ; n is 1-5; m is 1-10.Type: GrantFiled: March 21, 1994Date of Patent: August 22, 1995Assignee: E. I. Du Pont de Nemours and CompanyInventors: Mark D. Franke, Richard J. Legg, Alden D. West, Anna E. Doyle
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Patent number: 5420004Abstract: An internal latent image type positive silver halide emulsion has improved sensitivity reduction in low illuminance exposures. A color diffusion transfer light-sensitive material incorporates the emulsion and has reduced sensitivity reduction. The internal latent image type positive silver halide emulsion is prepared using a polymer having a repetitive unit derived from an ethylenically unsaturated monomer having at least one thioether structure on a side chain as a deflocculating agent to form silver halide grains and subjecting the grain surfaces to a chemical sensitization in the presence of a polymer having a repetitive unit represented by the following Formula (I): ##STR1## wherein R.sup.1 represents a hydrogen atom or a substituted or unsubstituted alkyl group and Q represents a group selected from the group consisting of groups represented by the following Formula (1) to Formula (4): ##STR2## wherein q represents an integer of 2 to 4; ##STR3## wherein R.sup.2 and R.sup.Type: GrantFiled: August 10, 1993Date of Patent: May 30, 1995Assignee: Fuji Photo Film Co., Ltd.Inventors: Munehisa Fujita, Toru Sano
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Patent number: 5405738Abstract: A silver halide photographic light-sensitive material has at least one silver halide emulsion layer on a support. The silver halide emulsion layer contains a silver halide emulsion in which 50% or more of the projected area or the number of all silver halide grains are occupied by substantially perfect cubic silver halide grains, which are silver bromochloroiodide or silver bromoiodide grains having a silver iodide content of 0.5 mol % or more and a silver chloride content of 3 mol % or less and are spectrally sensitized with sensitizing dyes.Type: GrantFiled: June 8, 1993Date of Patent: April 11, 1995Assignee: Fuji Photo Film Co., Ltd.Inventor: Mitsuhiro Uchida
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Patent number: 5358831Abstract: This invention provides composition and method to overcome the very high viscosity of prior small-particle dispersions when admixed with gelatin in aqueous solution for coating a photographic film element.The invention is generally accomplished by the utilization of a second surfactant in the melt formulated by the admixture of the small-particle dispersion and the gelatin solution. The surfactants of this invention, that is, utilized to control the theology of such said melts, have the following general structure: ##STR1## wherein n=5 to 20 andx=1 to 4.Type: GrantFiled: December 13, 1990Date of Patent: October 25, 1994Assignee: Eastman Kodak companyInventors: Pranab Bagchi, James L. Edwards, Danuta Gibson, Thomas A. Rosiek, Brian Thomas, Vincent J. Flow, III
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Patent number: 5354826Abstract: Polymeric color couplers with repeating units of a polymerized monomer K of formula I ##STR1## with R.sup.1 H or an optionally substituted alkyl group;R.sup.2, R.sup.3, R.sup.4 (identical or different) H, Cl, --COOH or optionally substituted alkyl groups; andX H or a group releaseable by coupling provide, during chromogenic development: magenta dye images with high dye yield and advantageous absorption level.Type: GrantFiled: April 28, 1993Date of Patent: October 11, 1994Assignee: Agfa-Gevaert AGInventors: Gunter Helling, Rainer Bialek, Ralf Weimann
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Patent number: 5352563Abstract: A silver halide photographic light-sensitive material is disclosed, which comprises a support and provided thereon, a silver halide photographic emulsion layer and a protective layer in that order, wherein at least one layer of said emulsion layer and said protective layer contains a cyclodextrin compound and said emulsion layer contains a hydrazine derivative or a compound represented by the following formula (T): ##STR1##Type: GrantFiled: January 19, 1993Date of Patent: October 4, 1994Assignee: Konica CorporationInventors: Satomi Kawasaki, Shyouji Nishio, Hideki Komatsu
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Patent number: 5284733Abstract: A silver halide photographic material is disclosed. The photographic material comprises a support having coated thereon one or more hydrophilic colloidal layers, at least one of the hydrophilic colloidal layers being a negative working silver halide emulsion layer, wherein said silver halide emulsion layer or another hydrophilic colloidal layer contains a water-soluble polymer or copolymer having a quaternary ammonium salt in a repeating unit. The process for forming a high contrast negative image using the photographic material is also disclosed.Type: GrantFiled: October 1, 1991Date of Patent: February 8, 1994Assignee: Dainippon Ink and Chemicals, Inc.Inventors: Yasuhiko Kojima, Naoki Obi, Yasuo Shigemitsu, Kiyoshi Suematsu
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Patent number: 5256527Abstract: The invention provides stable dispersions of couplers and methods of their formation. The stable dispersions are formed by the use of a nonionic water soluble polymer in combination with an anionic surfactant having a sulfate or sulfonate head group and a hydrophobic group of 8 to 20 carbons. The preferred nonionic water soluble polymers are polyethyleneoxide and polyvinylpyrrolidene. It is preferred that the dispersions have a pH of between about 5 and 5.5.Type: GrantFiled: September 9, 1991Date of Patent: October 26, 1993Assignee: Eastman Kodak CompanyInventors: Krishnan Chari, James T. Beck
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Patent number: 5254448Abstract: Disclosed is a silver halide photographic light-sensitive material that comprises a support having thereon a conductive layer containing a water-soluble polymer or a metal oxide and a photographic component layer having at least one surface active agent containing a fluorine compound. The silver halide photographic light-sensitive material according to this invention does not cause any deterioration of antistatic properties even after photographic processing, also does not cause any faulty transport even when used in the automatic transport apparatus comprising a transport path having a surface coated with Teflon, and not tends to cause flaws even after raw stock.Type: GrantFiled: December 23, 1991Date of Patent: October 19, 1993Assignee: Konica CorporationInventors: Taketoshi Yamada, Yasuhiko Takamuki, Youji Aritomi
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Patent number: 5234807Abstract: The polymerization and copolymerization of photographically useful vinyl monomers can be effected by dissolving such monomers in an isotropic oil-in-water microemulsion or in an isotropic water-in-oil microemulsion, each comprising monomers or comonomers, surfactants and/or cosurfactants, water, and optionally electrolytes. The microemulsion may be characterized as transparent or nearly transparent to the eye at 1% (w/w) or greater monomer, ultrafine in particle (droplet) size (typically in the range of 30 to 900 .ANG. in diameter), and spontaneously formed upon combining all the components with moderate stirring. The polymerization process is subsequently initiated with free radical initiators or with ultraviolet light. The components are chosen so that photographically useful polymers or photographically useful latexes are obtained, and said polymers or latexes may be coated in a photographic element.Type: GrantFiled: November 21, 1991Date of Patent: August 10, 1993Assignee: Eastman Kodak CompanyInventors: John Texter, Tienteh Chen, Edward Schofield
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Patent number: 5087554Abstract: The invention provides stable dispersions of couplers and methods of their formation. The stable dispersions are formed by the use of a nonionic water soluble polymer in combination with an anionic surfactant having a sulfate or sulfonate head group and a hydrophobic group of 8 to 20 carbons. The preferred nonionic water soluble polymers are polyethyleneoxide and polyvinylpyrrolidene. It is preferred that the dispersions have a pH of between about 5 and 5.5.Type: GrantFiled: June 27, 1990Date of Patent: February 11, 1992Assignee: Eastman Kodak CompanyInventors: Krishnan Chari, James T. Beck
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Patent number: 4957857Abstract: The invention provides stable dispersions of couplers and methods of their formation. The stable dispersions are formed by the use of a nonionic water soluble polymer in combination with an anionic surfactant having a sulfate or sulfonate head group and a hydrophobic group of 8 to 20 carbons. The preferred nonionic water soluble polymers are polyethyleneoxide and polyvinylpyrrolidene.Type: GrantFiled: December 23, 1988Date of Patent: September 18, 1990Assignee: Eastman Kodak CompanyInventor: Krishnan Chari
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Patent number: 4916053Abstract: A negative-tupe silver halide photographic material is provided, having high sensitivity and good graininess with low fog. The material has at least one silver halide emulsion layer on a support, wherein chemically-sensitized silver halide grains contained in the emulsion of said emulsion layer comprise normal crystalline grains, and said emulsion layer containing said normal crystalline silver halide grains contains a polymer having a repeating unit represented by formula (I): ##STR1## wherein R.sub.1 represents a hydrogen atom or an alkyl group; Q represents one group selected from formulae (i), (ii), (iii), and (iv); ##STR2## wherein q is an integer of from 2 to 4; ##STR3## wherein R.sup.2 and R.sup.3 each represents a hydrogen atom or an alkyl group; ##STR4## wherein Z.sup.1 represents an atomic group forming a lactam ring, an oxazolidone ring, or a pyridone ring;A represents a single bond, ##STR5## B represents --O-- or ##STR6## wherein R.sup.Type: GrantFiled: September 16, 1988Date of Patent: April 10, 1990Assignee: Fuji Photo Film Co., Ltd.Inventors: Naoto Ohshima, Toshiaki Hayakawa, Shunji Takada
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Patent number: 4916047Abstract: A silver halide light-sensitive material comprising a support having thereon at least one silver halide emulsion layer, and containing a compound containing a repeating unit, said compound containing a repeating unit being connected at the repeating unit to a compound represented by formula (I) at the position of the PWR or Time moiety:PWR--Time.sub.t PUG (I)wherein PWR represents a moiety capable of releasing (Time.sub.t PUG upon reduction, and PUG represents a group which can fulfil a photographically useful function after the release; Time represents a moiety capable of releasing PUG through a reaction subsequent to the release from PWR in the form of --Time.sub.t PUG; and t represents 0 or 1.Type: GrantFiled: April 29, 1988Date of Patent: April 10, 1990Assignee: Fuji Photo Film Co., Ltd.Inventors: Keizo Koya, Junichi Yamanouchi, Masaharu Toriuchi, Yoshisada Nakamura
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Patent number: 4898808Abstract: An antistatic silver halide photographic light-sensitive material having a support, provided thereon, at least one light-sensitive layer and at least one non-light-sensitive layer is disclosed. Said at least one non-light-sensitive layer comprises a polymer compound consisting essentially of a repeated structural unit represented by Formula [I], and a formamide compound represented by Formula [II]; ##STR1## wherein Z, and Z.sub.2 represent the group of the atoms necessary to form a six-membered ring with--N.sup..sym. --; R represents a divalent group; R.sub.1 and R.sub.2 represent independently one selected from the group consisting of an alkyl group and an aryl group; R.sub.3 represents a hydrocarbon group; R.sub.5 and R.sub.6 represent independently a hydrogen atom or an alkyl group; X.sub.1.sup..crclbar. and X.sub.2.sup..crclbar. represent an anion; a and l represent an integer of 0 and 1.Type: GrantFiled: January 17, 1989Date of Patent: February 6, 1990Assignee: Konica CorporationInventors: Noriki Tachibana, Masato Nishizeki, Nobuaki Kagawa
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Patent number: 4877720Abstract: A silver halide photographic material comprising a support having thereon at least one silver halide emulsion layer, at least one layer of the silver halide photographic material comprising at least one compound represented by formula (I):PWR--Time--.sub.t --POL (I)wherein PWR represents a group capable of releasing (Time--.sub.t POL upon reduction; Time represents a divalent organic group capable of releasing POL via a subsequent reaction after (Time--.sub.t POL is released from PWR; t is 0 or 1; and POL represents a polymer group.The compound represented by formula (I) is a useful functional polymer whose properties are drastically changed upon reduction and reveal photographically useful function.Type: GrantFiled: April 29, 1988Date of Patent: October 31, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Kozo Sato, Shigeru Ohno, Sumito Yamada
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Patent number: H1127Abstract: A silver halide photographic material that contains a polymer including a repeating unit represented by the following general formula (I) and having a weight average molecular weight of no more than 30,000: ##STR1## wherein R.sup.1 is a hydrogen atom or an alkyl group; Z represents the atomic group necessary to form a lactam ring, an oxazolidone ring or a pyrrolidone ring; A is a simple linkage, --CO--, --COO(CH.sub.2).sub.n or --CONR.sup.2 (CH.sub.2).sub.n where R.sup.2 is a hydrogen atom or an alkyl group, and n is an integer of 1-6. This photographic material experiences a minimum level of increase in fogging during rapid processing and produces image having improved sharpness and granularity.Type: GrantFiled: October 3, 1990Date of Patent: January 5, 1993Assignee: Konica CorporationInventors: Hiroshi Shimazaki, Fumie Fukazawa, Masayuki Kurematsu, Kenjiro Ushiyama, Satoru Shimba
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Patent number: H1578Abstract: A silver halide photographic light-sensitive material is disclosed. The light-sensitive material comprises a support having thereon a silver halide emulsion layer and optionally a hydrophilic colloid layer, at least one of said emulsion layer and said hydrophilic colloid layer contains a water-soluble polymer which comprises repeating unit represented by formula 1 in an amount of 10 to 100 mol %, and a electric conductive layer being provided between the support and the silver halide emulsion layer and comprising a binder and fine particles of an electric conductive crystalline metal oxide of ZnO, Ti0.sub.2, SnO.sub.2, Al.sub.2 O.sub.3, In.sub.2 O.sub.3, SiO.sub.2, MgO, BaO, MoO.sub.3, V.sub.2 O5 or a mixture thereof, each of which has a volumetric resistivity of not higher than 10.sup.7 .OMEGA.m; ##STR1## wherein R.sup.1 and R.sup.2 are each independently a hydrogen atom, an alkyl group, a halogen atom or a --CH.sub.2 COOM.sup.1, in which M.sup.Type: GrantFiled: December 8, 1994Date of Patent: August 6, 1996Inventor: Masaaki Taguchi