Carboxylic Acid Or Derivative Patents (Class 430/635)
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Patent number: 10781165Abstract: Disclosed are a pH-responsive amphoteric surfactant N-lauryl-(?-alkyl)-?-aminopropionic acid and a preparation method and uses thereof. An alkylamine and a solvent are added to a three-necked flask, stirred for complete dissolution, slowly dropwise added with methyl ?-alkyl-acrylate and reacted at room temperature after the ice-water bath is removed. The reaction mixture is refluxed in water bath and evaporated under rotation to remove the solvent and the residual methyl ?-alkyl-acrylate to give N-lauryl-(?-alkyl)-?-aminopropionic acid. Then N-lauryl-(?-alkyl)-?-aminopropionic acid and water are added to a three-necked flask, slowly dropwise added with a sodium hydroxide solution and reacted in water bath to give a crude product, which is filtered and dried to give a purified surfactant sodium N-lauryl-(?-alkyl)-?-aminopropionate. This surfactant is suitable for the foamed acid system and its performance can be switched by adjusting pH due to pH sensitivity.Type: GrantFiled: June 18, 2019Date of Patent: September 22, 2020Assignee: Shaanxi University of Science & TechnologyInventors: Xiaojuan Lai, Zhiqiang Dang, Lei Wang, Shaoyun Ma, Xianwen Li, Wei Tian, Xingen Feng, Yinyin Zhang, Xu Yang
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Patent number: 7579139Abstract: A silver halide color photographic light-sensitive material, in which a non-light-sensitive hydrophilic colloidal layer, on a transmission-type support, contains a solid fine-particle dispersion of a dye represented by formula (I), any one of photographic constituting layers contains a compound represented by formula (A) and/or a compound represented by formula (B) or (FS-2), and the light-sensitive material does not contain any compound represented by formula (C): in formulas (I), (A), (B) and (C), D represents a group to give a compound having a chromophore; X represents a dissociable hydrogen or a group having a dissociable hydrogen; y is an integer from 1 to 7; R1 represents a substituted or unsubstituted alkyl or alkoxy group; R2 and R3 each independently represent a substituted or unsubstituted alkyl group; R4 represents a substituted or unsubstituted alkyl group; M, M1, M2 and M3 each independently represent a cation; n represents an integer of 1 to 7; A and B each independently represent a fluorType: GrantFiled: December 26, 2006Date of Patent: August 25, 2009Assignee: FUJIFILM CorporationInventors: Hidekazu Sakai, Shin Soejima, Shinji Tanaka
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Patent number: 7419775Abstract: A method of manufacturing a micro-particle dispersion having a hydrophobic protective colloid comprising the steps of: (a) dispensing micro-particles in a hydrophilic dispersant to form a hydrophilic micro-particle dispersion having the hydrophilic dispersant as a protective colloid, and (b) adding a dispersant to the hydrophilic micro-particle dispersion, the dispersant having a functional group capable of ion bonding with a hydrophilic group of the hydrophilic dispersant.Type: GrantFiled: November 8, 2005Date of Patent: September 2, 2008Assignee: Konica Minolta Medical & Graphic, Inc.Inventors: Hiroto Ito, Kazuhito Ihara
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Read module, poor connection detection apparatus and poor connection detection method of read module
Patent number: 7385738Abstract: A read module includes: a light source that applies light to an original to read an image; a photoelectric conversion section that converts reflected light from the original into an image signal of the image; and a connector to be electrically connected to a controller connector in a controller. The connector has a plurality of terminals placed side by side in a predetermined direction. The plurality of terminals includes an image signal output terminal section that outputs the image signal to the controller and a power terminal section that inputs electric power for lighting the light source supplied from the controller to the read module. The power terminal section is placed in the proximity of one end of the plurality of terminals in the predetermined direction thereof. The image signal output terminal section is placed in the proximity of an opposite end in the predetermined direction thereof.Type: GrantFiled: January 8, 2004Date of Patent: June 10, 2008Assignee: Brother Kogyo Kabushiki KaishaInventor: Yuji Hori -
Patent number: 7306900Abstract: A silver halide color photosensitive material comprising at least one layer containing at least one compound selected from a group consisting of the following type 1 and type 2, and at least one layer containing at least one fluorine compound represented by the following general formula (A): (Type 1) Compound which undergoes a one-electron oxidation so as to form a one-electron oxidation product capable of, through subsequent bond cleavage reaction, releasing one or more electrons; (Type 2) Compound which undergoes a one-electron oxidation so as to form a one-electron oxidation product capable of, after subsequent bond formation reaction, releasing one or more electrons; Rf?X-M:??General formula (A) wherein Rf represents an alkyl group having 1 to 6 carbons which is substituted with at least one fluorine atom, X represents a divalent coupling group or a single bond, and M represents an anionic group, a cationic group or a betaine group.Type: GrantFiled: September 29, 2006Date of Patent: December 11, 2007Assignee: FUJIFILM CorporationInventor: Koichi Yokota
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Patent number: 7229738Abstract: Disclosed is a silver halide photographic light-sensitive material comprising at least one silver halide emulsion layer on a support, which contains a fluorine compound having two or more fluorinated alkyl groups having two or more carbon atoms and 11 or less fluorine atoms and having at least one of an anionic hydrophilic group and a nonionic hydrophilic group, and has a characteristic curve drawn in orthogonal coordinates of logarithm of light exposure (x-axis) and optical density (y-axis) using equal unit lengths for the both axes, on which gamma is 5.0 or more for the optical density range of 0.3-3.0. There is provided a silver halide photographic light-sensitive material that provides high sensitivity, high contrast, favorable half tone dot quality and superior storage stability.Type: GrantFiled: January 30, 2003Date of Patent: June 12, 2007Assignee: Fujifilm CorporationInventors: Shoji Yasuda, Terukazu Yanagi
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Patent number: 7172855Abstract: Disclosed is a silver halide photographic light-sensitive material having a layer containing a compound of the following formula and a fluorine compound, and has a gamma of 5.0 or more for the optical density range of 0.3 to 3.0: wherein R1 is alkyl or alkenyl, R2 are H, alkyl, alkenyl, aralkyl or aryl, l1 is 1–10, m1 is 1–30, n1 is 0–4, a is 0 or 1, and Z1 is OSO3M or SO3M where M is cation.Type: GrantFiled: September 16, 2004Date of Patent: February 6, 2007Assignee: Fuji Photo Film Co., Ltd.Inventors: Shoji Yasuda, Yoshihisa Tsukada
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Patent number: 7122298Abstract: There is provided a silver halide photographic photosensitive material, containing a support and at least one photosensitive silver halide emulsion layer on the support, the silver halide photographic photosensitive material, further including at least one layer containing an emulsion having at least one surfactant represented by the formula (I), in which the photosensitive material contains a substantially non-color-forming photosensitive emulsion layer. The formula (I) is indicated as (R1—L)n-J-(A)m. In the formula: A represents an acid group or a metal salt thereof; R1 represents an aliphatic group; L represents a divalent group; J represents a linking group, having a valence of n plus m, which links R1—L and A; n represents a natural number of from 1 to 6; and m represents a natural number of from 1 to 3.Type: GrantFiled: March 25, 2005Date of Patent: October 17, 2006Assignee: Fuji Photo Film Co., Ltd.Inventor: Naoto Matsuda
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Patent number: 7105285Abstract: A silver halide color photosensitive material comprises a blue-sensitive layer, a green-sensitive layer, a red-sensitive layer and a non-light-sensitive layer on a support. The silver halide color photosensitive material contains a compound selected from the following type 1 and type 2 compounds, and wherein the blue-sensitive layer meets the relationship of the following formula (I): SB(370 nm)/SB(420 nm)<0.Type: GrantFiled: September 23, 2004Date of Patent: September 12, 2006Assignee: Fuji Photo Film Co., Ltd.Inventors: Toshitaka Ninomiya, Kiyoshi Morimoto, Koichi Yokota, Masahiko Taniguchi, Terukazu Yanagi
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Patent number: 6994953Abstract: A silver halide photosensitive material comprises a light-sensitive silver halide emulsion layer on a support. The photosensitive material has a layer comprising an emulsified dispersion containing a surfactant represented by formula (I), and an emulsion containing tabular silver halide grains having an average aspect ratio of 8 or greater, and at least one sensitizing dye. (R1-LnJA)m??General formula (I) wherein A represents an acid group or a metal salt thereof, R1 represents an aliphatic group containing a linear aliphatic group having 6 or more carbon atoms as a partial structure thereof and having the total number of carbon atoms of 17 or more, L represents a bivalent group, J represents a linking group of n+m valence, n is an integer of 1 to 6, and m is an integer of 1 to 3. The molecular weight of surfactant of the formula (I) divided by m is 430 or greater.Type: GrantFiled: August 20, 2004Date of Patent: February 7, 2006Assignee: Fuji Photo Film Co., Ltd.Inventors: Naoto Matsuda, Yasushi Miyamoto, Tomokazu Yasuda
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Patent number: 6897013Abstract: A silver halide photographic light-sensitive material having one or more layers including at least one light-sensitive silver halide emulsion layer on a support, wherein any of the layers formed on the support contains a compound represented by the following formula (1) and a fluorine-containing surfactant (in the formula (1), R1 represents an alkyl group or alkenyl group having 6-25 carbon atoms, ml represents an integer of 0-30, n1 represents an integer of 0-4, a represents 0 or 1, and Z1 represents OSO3M or SO3M, where M represents a cation). There is provided a silver halide photographic light-sensitive material that shows superior antistatic property and can be stably produced.Type: GrantFiled: March 13, 2003Date of Patent: May 24, 2005Assignee: Fuji Photo Film Co., Ltd.Inventors: Terukazu Yanagi, Yoshihisa Tsukada, Kouichi Yokota, Shinichi Ichikawa, Katsuhiko Kanazawa
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Patent number: 6875563Abstract: A coating composition for use in forming an overcoat layer in a photographic element, said composition comprising an aqueous solution of: a mixture of two or more surfactants; a hydrophilic binder; matte beads; and a lubricating agent; wherein one of the surfactants is represented by the following Formula (I) and is the only fluorosurfactant in the composition: Rf—CH2CH2—S-(A)-D??(I) where Rf is —(CF2)nCF3, n represents the number of CF2 groups and is 3 or 5 in at least 60% of the Rf groups present, and in the remainder of Rf groups n is 7, 9, or 11. A is a divalent linking group that includes substituted alkylene or alkylene (N-alkylene)amide; and D is an ionic group. A photographic element with an outermost layer containing the coating composition is also disclosed.Type: GrantFiled: November 6, 2003Date of Patent: April 5, 2005Assignee: Eastman Kodak CompanyInventors: Michael W. Orem, Ronald R. Andrews
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Patent number: 6794099Abstract: The invention relates to a material to form an indicator element comprising a base material and at least one photosensitive silver halide layer, wherein the base material comprises at least one specular reflective layer between two polymer layers wherein the polymer layer between the at least one specular reflective layer and the silver halide layer is substantially transparent.Type: GrantFiled: April 8, 2003Date of Patent: September 21, 2004Assignee: Eastman Kodak CompanyInventors: Wen-Li A. Chen, Robert P. Bourdelais, Cheryl J. Kaminsky, Richard A. Castle, Thomas M. Smith
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Publication number: 20040137386Abstract: A silver halide color photographic lightsensitive material comprising a support and, superimposed thereon, at least one blue-sensitive layer, at least one green-sensitive layer, at least one red-sensitive layer and at least one non-lightsensitive layer, wherein at least one fluorinated surfactant represented by the following general formula (A) or general formula (B) is contained and wherein a spectral sensitivity ratio at 370 nm as compared to that at 420 nm, which imparts the same density as that of the sensitivity at 420 nm in the spectral sensitivity distribution of the blue-sensitive layer, is 70% or less.Type: ApplicationFiled: September 26, 2003Publication date: July 15, 2004Applicant: FUJI PHOTO FILM CO., LTD.Inventors: Koichi Yokota, Terukazu Yanagi
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Publication number: 20040115571Abstract: Disclosed is a silver halide photographic light-sensitive material having one or more layers including a light-sensitive silver halide emulsion layer on a support, wherein any of the layers contains the specific fluorine compound. The silver halide photographic light-sensitive material can be stably produced and is imparted with antistatic property.Type: ApplicationFiled: November 17, 2003Publication date: June 17, 2004Applicant: Fuji Photo Film Co., Ltd.Inventors: Terukazu Yanagi, Akira Ikeda, Nobuo Hamamoto, Takahiro Ishizuka
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Publication number: 20040002024Abstract: A silver halide photographic light-sensitive material having one or more layers including at least one light-sensitive silver halide emulsion layer on a support, wherein any of the layers formed on the support contains a compound represented by the following formula (1) and a fluorine-containing surfactant (in the formula (1), R1 represents an alkyl group or alkenyl group having 6-25 carbon atoms, ml represents an integer of 0-30, n1 represents an integer of 0-4, a represents 0 or 1, and Z′ represents OSO3M or SO3M, where M represents a cation). There is provided a silver halide photographic light-sensitive material that shows superior antistatic property and can be stably produced.Type: ApplicationFiled: March 13, 2003Publication date: January 1, 2004Inventors: Terukazu Yanagi, Yoshihisa Tsukada, Kouichi Yokota, Shinichi Ichikawa, Katsuhiko Kanazawa
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Publication number: 20030235793Abstract: A silver halide photographic material of the invention contains a support having on at least one surface thereof at least one photosensitive silver halide emulsion layer, and a surface protective layer. The silver halide photographic material of the invention may include a hydrophilic colloid layer containing a hydrophilic colloid, in addition to the surface protective layer. The silver halide photographic material of the invention contains at least two kinds of surfactants that are different from each other. One of the surfactants (type 1) has a fluoroalklyl group or a fluoroalkylene group. The other (type 2) is an anionic surfactant containing ethyleneoxy repeating units and having an alkyloxy group or an alkylcarbonyl group at an end thereof.Type: ApplicationFiled: May 22, 2003Publication date: December 25, 2003Inventors: Katsuhiko Kanazawa, Terukazu Yanagi, Yoshihisa Tsukada, Shinichi Ichikawa
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Patent number: 6664020Abstract: A mass transfer imaging element comprising a substrate having a surface colourant layer containing a pigment to be imagewise transferred, wherein said colourant layer comprises a fluorocarbon additive in an amount to provide a fluorocarbon additive:pigment weight ratio of at least 1:20.Type: GrantFiled: June 13, 1995Date of Patent: December 16, 2003Assignee: 3M Innovative Properties CompanyInventors: David Warner, Ranjan Chhaganbhai Patel
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Patent number: 6613503Abstract: The invention relates to a photographic element comprising a reflection support and an overcoat layer wherein said overcoat layer comprises hydrophilic binder and lubricant, said lubricant has a particle mean diameter of greater than 1 &mgr;m and the volume of particles of lubricant below 1 &mgr;m is less than 5% of said total volume of lubricant.Type: GrantFiled: June 26, 1996Date of Patent: September 2, 2003Assignee: Eastman Kodak CompanyInventors: Walter Harold Isaac, James Stephen Honan, Edgar Erick Riecke
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Patent number: 6582897Abstract: A heat developable light-sensitive material high in heat development activity, excellent in image keeping quality, high in sensitivity and rapidly developable, comprising a support having provided on one side thereof a light-sensitive silver halide, a light-insensitive organic silver salt, a reducing agent for a silver ion and a binder, wherein the reducing agent is a compound represented by the formula (I), and an aromatic carboxylic acid compound represented by the formula (A) and a hydrogen bonding compound are further provided on the same side where the light-sensitive silver halide is provided.Type: GrantFiled: June 21, 2001Date of Patent: June 24, 2003Assignee: Fuji Photo Film Co., Ltd.Inventor: Yasuhiro Yoshioka
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Patent number: 6582896Abstract: A photothermographic material includes on a support a non-photosensitive sliver salt, a photosensitive sliver halide, a nucleation agent, and a binder, and a layer containing specific compounds is formed on an outer side of the image forming layer. Thus, there are obtained such images optimal for photomechanical processes as having a high Dmax (maximum density), a low fog, a good coated surface condition, and less surface defects such as repellency, coating lines or the like.Type: GrantFiled: August 3, 2000Date of Patent: June 24, 2003Assignee: Fuji Photo Film Co., Ltd.Inventors: Tadashi Ito, Yasuo Mukunoki
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Patent number: 6472139Abstract: A hydrophobically capped oligomeric acrylamide or pyrrolidone is employed as a coating aid in coating compositions, especially such compositions useful in the manufacture of photographic products. Preferred coating aids are surfactants having the general formula in which R, R1 and R2 are each independently selected from aliphatic hydrocarbyl, aryl-(aliphatic hydrocarbyl) and (aliphatic hydrocarbyl)-aryl groups, which groups may be unsubstituted, partially fluorinated or fully fluorinated, L is a sulphur atom or a linking group that contains a sulphur atom attached to the T group and T is a hydrophilic oligomeric group obtainable by the oligomerisation of one or more vinyl monomers having an amido function.Type: GrantFiled: February 2, 2001Date of Patent: October 29, 2002Assignee: Eastman Kodak CompanyInventors: Alan R. Pitt, Trevor J. Wear, Elizabeth A. Simister, Alice G. Moon
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Publication number: 20020155402Abstract: A hydrophobically capped oligomeric acrylamide or pyrrolidone is employed as a coating aid in coating compositions, especially such compositions useful in the manufacture of photographic products.Type: ApplicationFiled: February 2, 2001Publication date: October 24, 2002Inventors: Alan R. Pitt, Trevor J. Wear, Elizabeth A. Simister, Alice G. Moon
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Patent number: 6468710Abstract: A silver halide photographic light-sensitive material that has at least one silver halide emulsion layer on a support, the light-sensitive material containing a surfactant represented by the following formula (F), and having the characteristic curve that a gamma in the range of an optical density from 0.3 to 3.0 is 5.0 or more, on the characteristic curve shown in a rectangular coordinate where a logarithmic exposure amount (the x axis) and an optical density (the y axis) are indicated according to the same unit length; [Rf—(Rc)n]m—Z formula (F) wherein Rf represents a perfluoroalkyl group, Rc represents an alkylene group, Z represents a group having an anionic group, cationic group, amphoteric ionic group, or nonionic polar group, n is an integer of 0 or 1, and m is an integer of 1 to 3.Type: GrantFiled: September 28, 2001Date of Patent: October 22, 2002Assignee: Fuji Photo Film Co., Ltd.Inventor: Shoji Yasuda
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Patent number: 6423487Abstract: The present invention provides a thermally processed image recording material having, on a support, an image-forming layer containing at least (a) a silver salt of an organic acid, (b) a reducing agent and (c) a photosensitive silver halide and at least one protective layer provided on the image-forming layer and comprising polymer latex as binders of the image-forming layer and the protective layer, wherein at least one of the image-forming layer and the protective layer contains a viscosity enhancer that increases viscosity of its aqueous solution when the solution is heated and temperature of the solution exceeds a certain transition temperature, and the viscosity enhancer is a polymer selected from the group consisting of polymers containing a (meth)acrylamide derivative represented by the following formula (1) or (2) in an amount of 50 weight % or more as constituent units: (wherein R1 represents H or CH3, R2 represents an alkylene group, R3 to R6 represent H or CH3, and X represents &mType: GrantFiled: April 13, 2001Date of Patent: July 23, 2002Assignee: Fuji Photo Film Co., Ltd.Inventor: Takashi Naoi
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Publication number: 20020076661Abstract: The present invention provides a system of a digital color proof in which consistent images are obtained while minimizing density variation in spite of various variations of conditions due to the use of a silver halide light-sensitive color material, specifically, the present invention provides a method for forming proof images similar to printed images in terms of various characteristics such as the paper quality of silver halide light-sensitive materials, the dot gain, and the density.Type: ApplicationFiled: September 20, 2001Publication date: June 20, 2002Applicant: KONICA CORPORATIONInventors: Tomonori Kawamura, Shigeo Tanaka, Satoshi Nishino, Hirohide Ito, Naohito Naraoka, Naoyo Suzuki, Shinya Watanabe, Masataka Takimoto, Hideaki Sakata, Junichi Tanabe, Tetsuya Taniguchi, Naoki Nozaki, Yasushi Okubo, Koji Daifuku, Katsuji Kondo, Toshitsugu Suzuki
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Publication number: 20020058213Abstract: A silver halide photosensitive material in which a noncoloring compound is used as a high-boiling-point organic solvent for dissolving components of the silver halide photosensitive material that have low solubility in water. Preferably, the silver halide photosensitive material has a hydrophilic colloid layer containing a hydrophilic polymer and the noncoloring compound is contained in the hydrophilic colloid layer. The silver halide photosensitive material produces durable colored images, reduces the formation of stains, improves storability, alleviates fogging and soft-toning of emulsion during storage, inhibits migration of a dispersion medium, is inexpensive, and is produced from materials that cause little damage to the environment.Type: ApplicationFiled: March 22, 2001Publication date: May 16, 2002Inventors: Hisashi Mikoshiba, Hiroyuki Yoneyama, Naoto Matsuda
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Patent number: 6379879Abstract: A color photographic recording material having at least one spectrally sensitized silver halide emulsion layer, characterized in that said silver halide emulsion layer contains an oil former having a pKa value of less than 18 and a DIR coupler and the material contains at least one color coupler, wherein the color coupler and/or the DIR coupler have specific structures, is distinguished by an increased interimage effect in comparison with the prior art without sensitivity being reduced.Type: GrantFiled: February 26, 2001Date of Patent: April 30, 2002Assignee: Agfa-GevaertInventors: Jörg Hagemann, Günter Helling, Heinz Wiesen, Ralf Wirowski, Ralf Büscher
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Patent number: 6333147Abstract: A thermally processed image forming material having on one side of a support at least one image recording layer containing at least one kind of non-photosensitive organic silver salt, a reducing agent for silver ion, and a binder; characterized by having at least one non-recordable layer formed by coating and drying a coating liquid containing a dicarboxylic acid and having a pH of 3.5 or above was disclosed. The thermally processed image forming material has an improved property of the coated surface and prevent coating streaks.Type: GrantFiled: May 11, 2000Date of Patent: December 25, 2001Assignee: Fuji Photo Film Co., Ltd.Inventor: Ichizo Toya
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Publication number: 20010034385Abstract: A hydrophobically capped oligomeric acrylamide or pyrrolidone is employed as a dispersant for hydrophobic materials in an aqueous medium containing a hydrophilic colloid, e.g. gelatin. The hydrophobic materials include photographic addenda such as color couplers or solid particle dyes.Type: ApplicationFiled: January 26, 2001Publication date: October 25, 2001Applicant: Eastman Kodak CompanyInventors: Alan R. Pitt, Trevor J. Wear, Danuta Gibson, Ian M. Newington, Mary C. Brick, John W. Boettcher, Gary N. Barber
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Patent number: 6132951Abstract: Provided is a photographic support which is excellent in mechanical strength and is less liable to get into roll set curl and which is excellent in cutting property and flatness, and a photographic material using the same. The support for photographic material comprises a polyester film, wherein the polyester film comprises two kinds of polyester resins, each has intrinsic viscosity of 0.2-1.2, and a difference in the intrinsic viscosity between the polyester resins is 0.1-1.0.Type: GrantFiled: December 29, 1998Date of Patent: October 17, 2000Assignee: Konica CorporationInventors: Hidetoshi Ezure, Masahito Takada, Kenji Ohnuma, Yasuo Kurachi
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Patent number: 6022681Abstract: A method for producing a light-sensitive silver halide photographic emulsion is disclosed, comprising (a) a step of forming silver halide grain nuclei containing twin grain nuclei in a dispersion medium solution, (b) a step of ripening said grain nuclei to preferentially remain tabular grain nuclei, and (c) a step of growing said tabular grain nuclei into tabular grains to form a tabular silver halide grain, wherein in step (a), a silver halide nucleus having a chloride content of 10 mol % or more based on the amount of silver contained in the nucleus is formed, and the tabular silver halide grain obtained through steps (a), (b) and (c) has a Br content of 50 mol % or more based on the total silver amount.Type: GrantFiled: April 16, 1998Date of Patent: February 8, 2000Assignee: Fuji Photo Film Co., Ltd.Inventors: Yoichi Hosoya, Junichi Yamanouchi, Isao Tuyuki, Shigeharu Urabe
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Patent number: 6004740Abstract: A method is disclosed for washing silver halide photographic emulsions, including desalting and/or concentrating, based on depletion phase separation mechanism, wherein phase separation is effected by the addition of water-soluble non-interactive and non-adsorbing carboxyl polymers. The process involves the separation of the supernatant fluid, containing the undesirable water soluble salts and the added phase separating agents, from the washed and condensed silver halide phase for desalting and redispersion of the latter.Type: GrantFiled: August 28, 1997Date of Patent: December 21, 1999Assignee: Eastman Kodak CompanyInventors: Julia S. Tan, Ramesh Jagannathan
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Patent number: 5994049Abstract: A method is disclosed for washing silver halide photographic emulsions, including desalting and/or concentrating, based on depletion phase separation mechanism, wherein phase separation is effected by the addition of water-soluble non-interactive and non-adsorbing non-ionic polymers or non-ionic surfactant micelles. The process involves the separation of the supernatant fluid, containing the undesirable water-soluble salts and the added phase separating agents, from the washed and condensed silver halide phase and redispersion of the latter.Type: GrantFiled: August 28, 1997Date of Patent: November 30, 1999Assignee: Eastman Kodak CompanyInventors: Julia S. Tan, Ramesh Jagannathan
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Patent number: 5928850Abstract: A silver halide photographic light-sensitive material is disclosed. The light-sensitive material comprises a dispersion material which is obtained by emulsifying a mixture of a yellow coupler represented by the formula and a polymer compound that is insoluble in water and soluble in an organic solvent.Type: GrantFiled: February 18, 1997Date of Patent: July 27, 1999Assignee: Konica CorporationInventors: Kazuhiro Murai, Shigeo Tanaka, Kunimasa Hiyama
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Patent number: 5871899Abstract: A silver halide color photographic element comprising a support, a silver halide emulsion and poly(alkylene oxide)s wherein greater than 50 percent of the poly(alkylene oxide)s have acidic functional end groups with an aqueous pKa.ltoreq.10, or end groups which will react to form acidic functional end groups with an aqueous pKa.ltoreq.10 during development, on both termini; and wherein the poly(alkylene oxide)s have a molecular weight ranging substantially between 1700 and 6000 AMU.Type: GrantFiled: April 30, 1997Date of Patent: February 16, 1999Assignee: Eastman Kodak CompanyInventors: David A. Dickinson, George J. Burgmaier, Thomas R. Welter
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Patent number: 5856062Abstract: A light-sensitive material comprises a light-sensitive hardening layer provided on a support. The light-sensitive hardening layer contains silver halide, a reducing agent and an ethylenically unsaturated polymerizable compound or an ethylenically unsaturated cross-linkable polymer. The light-sensitive hardening layer further contains a coupling agent in an amount of 0.01 to 15 wt. %.Type: GrantFiled: April 18, 1996Date of Patent: January 5, 1999Assignee: Fuji Photo Film Co., Ltd.Inventor: Satoshi Hoshi
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Patent number: 5773204Abstract: The invention concerns a process for coating a photographic support.The process consists of depositing on a support a succession of at least two layers, at least one of which consists of a photosensitive composition, the top layer, situated at the opposite side to the support, containing a given concentration of at least one surfactant, the process being characterized in that a surfactant present in the top layer is introduced into the layer adjacent to the top layer at a concentration equal to at least 25% of the concentration of the same surfactant in the said top layer.Type: GrantFiled: March 17, 1997Date of Patent: June 30, 1998Assignee: Eastman Kodak CompanyInventor: Jean Marie Baumlin
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Patent number: 5726000Abstract: A dispersion of fine solid particles having good production suitability, good dispersion stability and high spectral absorption, which is obtained by pulverizing an aqueous slurry of a dye represented by general formula (II) in the presence of a polyalkylene oxide represented by general formula (I-a) or (I-b): ##STR1## wherein a and b each represents a value of 5 to 500.D--(X).sub.y (II)wherein D represents a compound residue having a chromophore, X represents dissociative hydrogen or a group having dissociative hydrogen, and y is an integer of 1 to 7. An embodiment that a compound represented by general formula (I) is present together with the polyalkylene oxide of general formula (I-a) or (I-b) is also disclosed.Type: GrantFiled: May 8, 1997Date of Patent: March 10, 1998Assignee: Fuji Photo Film Co., Ltd.Inventors: Masatoshi Nakanishi, Yukoh Saitoh, Masahiro Fukuoka
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Patent number: 5719015Abstract: A silver halide photographic material comprising a support having thereon at least one silver halide light-sensitive layer and at least one light-insensitive layer, wherein the support comprises a poly(alkylene aromatic dicarboxylate) having a glass transition temperature of from 50.degree. C. to 200.degree. C. and is heat-treated at a temperature of not lower than 40.degree. C., but lower than the glass transition temperature for 0.1 to 1500 hours after molding the polymer into the support and before the coating of the silver halide light-sensitive layer, and said at least one light-insensitive layer contains a dispersion of crystallites of at least one dye represented by general formula (I):D--(X).sub.y (I)wherein D represents a moiety having a chromophoric group; X represents a dissociable proton or a group having a dissociable proton which is bonded to D either directly or through a bivalent bonding group; and y represents an integer of 1 to 7.Type: GrantFiled: May 14, 1996Date of Patent: February 17, 1998Assignee: Fuji Photo Film Co., Ltd.Inventors: Keiji Mihayashi, Kiyoshi Nakazyo
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Patent number: 5679505Abstract: A photographic film that is especially useful as a motion picture print film is comprised of a support having, in order, on one side thereof an antihalation undercoat and at least one silver halide emulsion layer and having, in order, on the opposite side thereof an antistatic layer and a protective topcoat; wherein the protective topcoat is comprised of a polyurethane binder and a lubricant and the polyurethane binder has a tensile elongation to break of at least 50% and a Young's modulus measured at 2% elongation of at least 50000 lb/in.sup.2. The polyurethane binder provides a tough but flexible protective topcoat that is capable of resisting abrasion and scratching when the film is conveyed through a projector and capable of standing up to the repeated use to which motion picture print films are typically subjected.Type: GrantFiled: December 21, 1995Date of Patent: October 21, 1997Assignee: Eastman Kodak CompanyInventors: Kenneth Lloyd Tingler, Charles Chester Anderson, Lori Jeanne Shaw-Klein
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Patent number: 5610002Abstract: This invention describes gelatin thickening compounds for photographic coating melts with the general structure: ##STR1## wherein: A is an aromatic or heteroaromatic group;X is SO.sub.3 M or CO.sub.2 MM is H or an alkali metal, ammonium or pyridinium ion; each R1 and R2 is independently an alkyl or substituted alkyl group, each alkyl group being straight or branched chain and having 1 to 30 carbon atoms;each R3 and R4 is independently H or an alkyl or substituted alkyl group, each alkyl group being straight or branched chain and having 1 to 30 carbon atoms;each of a, b, c and e is independently 0, 1, 2 or 3, with the proviso that a+b+c+e is at least 1; andd is 1, 2, or 3;with the further proviso that when A is phenyl, X is SO.sub.3 M, d is 1 and any one of a, c, or e is 1, the sum of a+b+c+e is at least 2; and wherein there is a substantial absence of a compound containing one or more --SO.sub.2.sup.- groups in the composition.Type: GrantFiled: November 13, 1995Date of Patent: March 11, 1997Assignee: Eastman Kodak CompanyInventors: Robert J. Ross, Pranab Bagchi, Richard W. Connelly
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Patent number: 5543288Abstract: There is disclosed a novel surface-active compound, and a silver halide photographic material and a processing solution for a silver halide photographic material containing the same. The surface-active compound is represented by the following formula (I): ##STR1## Wherein R.sup.1 represents an aliphatic group, an alicyclic compound group, an aromatic group, or a heterocyclic ring; R.sup.2 represents an aliphatic group, an alicyclic compound group, an aromatic group, a heterocyclic ring, or a group represented by --L--Z; Q.sup.1, Q.sup.2, and Q.sup.3 each represent a single bond, an oxygen atom, a sulfur atom, or a group represented by --N(R.sup.3)--, in which R.sup.3 represents a hydrogen atom or a group represented by R.sup.2 ; L represents a divalent linking group; and Z represents an ionic group.Type: GrantFiled: August 10, 1994Date of Patent: August 6, 1996Assignee: Fuji Photo Film Co., Ltd.Inventors: Tomokazu Yasuda, Yukio Karino, Masatoshi Nakanishi
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Patent number: 5486451Abstract: A method is disclosed of preparing washed silver halide photographic emulsions wherein silver halide grain formation is effected in the presence of an acid-coagulable gelatin derivative or a mixture of gelatin and an acid-coagulable gelatin derivative and coagulation of the emulsion occurs in the presence of ionic copolymers of styrene sulfonic acid and maleic acid.Type: GrantFiled: August 4, 1994Date of Patent: January 23, 1996Assignee: Minnesota Mining and Manufacturing CompanyInventors: Alberto Vacca, Paolo Barletta
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Patent number: 5451497Abstract: The tendency of a photographically useful compound (PUC) to crystallize when dispersed in an aqueous medium is inhibited by codispersing with the PUC a non-color forming, oil-soluble, monomeric or oligomeric organic compound having a glass transition temperature between 0.degree. and 150.degree. C. Preferred organic compounds are oil-soluble sucrose esters, such as sucrose octaacetate, and rosin and derivatives thereof.Type: GrantFiled: December 30, 1993Date of Patent: September 19, 1995Assignee: Eastman Kodak CompanyInventors: David D. Miller, Krishnan Chari
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Patent number: 5445931Abstract: A silver halide photographic material comprising, on a support, at least one silver halide emulsion layer, which has at least one hydrophilic colloid layer (including the silver halide emulsion layer) containing a water-soluble polymer comprising a COOH-containing monomer or a salt thereof which is water-insoluble at a pH.ltoreq.6 and water-soluble at a pH.gtoreq.10. The photographic material is well processed by ultra-rapid processing system, displaying an excellent drying property.Type: GrantFiled: August 3, 1994Date of Patent: August 29, 1995Assignee: Fuji Photo Film Co., Ltd.Inventors: Junichi Yamanouchi, Yutaka Tamura, Yasuyuki Takagi
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Patent number: 5391476Abstract: Water-soluble, non-ionic surface active compounds are provided having the formula ##STR1## wherein R.sup.1 and R.sup.2 are each independently hydrogen or an alkyl group having from 1 to 4 carbon atoms;X is a hydrophobic substituted or unsubstituted arylene group or a hydrophobic substituted or unsubstituted alkylene group;Y.sup.1 and Y.sup.2 are each independently a chemical bond, --CO-- or --(CH.sub.2).sub.m NR.sup.3 CO--;m is an integer from 1 to 6;R.sup.3 is as defined for R.sup.1 and R.sup.2 ; and,Z.sup.1 and Z.sup.2 are each independently a hydrophilic polyhydroxyalkyl group. The compounds are particularly useful as coating aids for the coating of hydrophilic colloid layers in the preparation of photographic materials.Type: GrantFiled: September 17, 1993Date of Patent: February 21, 1995Assignee: Eastman Kodak CompanyInventors: Alan R. Pitt, Ian M. Newington
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Patent number: 5391470Abstract: There is disclosed a silver halide photographic material containing a dispersion of a hydrophobic compound and a water-insoluble and organic solvent-soluble polymer as defined herein. The hydrophobic compound may be a dye which is photochemically inactive during storage but readily decolored and eluted in photographic processing.Type: GrantFiled: August 11, 1993Date of Patent: February 21, 1995Assignee: Fuji Photo Film Co., Ltd.Inventors: Tomokazu Yasuda, Junichi Yamanouchi, Koji Tamoto
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Patent number: 5385812Abstract: The invention discloses a continuous method of manufacture of gelled dispersion melts of "small-particle" microprecipitated photographic agents. The continuous melt manufacturing process of this invention provides dispersion melts that are invariant in agent concentration, melt viscosity, and turbidity as a function of the run time and are also very reproducible and robust in repetitive preparations. Many photographic melts of this invention exhibit high photographic activity and light stability of the agents when exposed to light.Type: GrantFiled: December 28, 1992Date of Patent: January 31, 1995Assignee: Eastman Kodak CompanyInventors: Pranab Bagchi, James T. Beck, Vincent J. Flow, III
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Patent number: 5380628Abstract: Fine particle photographic coupler dispersions are prepared by forming a dispersion of a photographic coupler, coupler solvent and auxiliary coupler solvent in an aqueous gelatin medium containing at least about 1% by weight of an anionic surfactant selected from the group consisting of alkali metal salts of alkarylene sulfonic acids, alkali metal salts of alkyl sulfates, alkaryl sulfonate salts, and alkyl sulfosuccinates; and washing the dispersion with water for a time sufficient to remove at least one-fourth of the surfactant.Type: GrantFiled: July 29, 1991Date of Patent: January 10, 1995Assignee: Eastman Kodak CompanyInventors: John F. Sawyer, Paul L. Zengerle