Substituted Patents (Class 430/72)
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Patent number: 4939053Abstract: The present invention relates to a photosensitive member containing a specific azo compound for a charge generating agent, which is improved in photosensitive properties, in particular, sensitivity. The specific azo compound is represented by the formula (1): ##STR1## wherein A represents an aromatic hydrocarbon or a heterocyclic ring; R.sub.1 and R.sub.2 independently represent a hydrogen, a halogen atom, or an alkyl, aralkyl, aryl, condensed polycyclic ring or condensed heterocyclic ring; or R.sub.1 and R.sub.2 combinedly form a cyclic ring; n represents an integer from 1 to 4.Type: GrantFiled: February 10, 1988Date of Patent: July 3, 1990Assignee: Minolta Camera Kabushiki KaishaInventor: Hideaki Ueda
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Patent number: 4939058Abstract: An electrophotographic photoreceptor having on a conductive support a photoconductive layer containing a specific azo compound is disclosed.Type: GrantFiled: November 30, 1988Date of Patent: July 3, 1990Assignee: Konica CorporationInventors: Toyoko Shibata, Takahiro Takagi, Shinchi Suzuki, Hiroko Fukawa, Osamu Sasaki
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Patent number: 4925760Abstract: Disclosed is an improved layered photoresponsive imaging member comprised of a supporting substrate, a vacuum evaporated photogenerator layer comprised of certain pyranthrone pigments including tribromo-8,16-pyranthrenedione and trichloro-8,16-pyranthrenedione; and an aryl amine hole transport layer comprised of molecules of the following formula: ##STR1## dispersed in a resinous binder and wherein X is selected from the group consisting of halogen and alkyl.Type: GrantFiled: July 5, 1988Date of Patent: May 15, 1990Assignee: Xerox CorporationInventors: Giuseppa Baranyi, Ah-Mee Hor, Rafik O. Loutfy, Zoran D. Popovic
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Patent number: 4916039Abstract: An electrophotographic photoconductor is disclosed which comprises an electroconductive support and a photoconductive layer formed thereon, which photoconductive layer comprises as a charge generating material an azo pigment having general formula (I): ##STR1## wherein R.sup.1, R.sup.2, X, A and n are respectively defined in the specification.Type: GrantFiled: July 8, 1988Date of Patent: April 10, 1990Assignee: Ricoh Company, Ltd.Inventors: Mitsuru Hashimoto, Masaomi Sasaki
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Patent number: 4916040Abstract: This invention relates to a photosensitive member wherein a photoconductive layer containing a N-cyanoimine compound represented by the following formula [I], [II] or [III] is formed on or over an electroconductive substrate; ##STR1## wherein R.sub.1 -R.sub.13 are respectively a hydrogen atom, an alkyl group, an alkoxy group, a halogen atom, a nitro group, a cyano group, a substituted sulfonyl group or a carboxylate group; n is an integer of 0-4; Z is a residual group which forms a ring with the benzene ring; Z may have a substituent; X is an oxygen atom or N-CN.Type: GrantFiled: August 2, 1989Date of Patent: April 10, 1990Assignee: Minolta Camera Kabushiki KaishaInventor: Hideaki Ueda
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Patent number: 4912001Abstract: An electrophotographic photoreceptor is provided with a photosensitive layer, which contains an azo compound having in the molecule thereof at least one azo group coupled with a couple residuum represented by the following general formula (I): ##STR1## wherein X means an atomic group necessary for condensing with a benzene ring to form a substituted or unsubstituted aromatic hydrocarbon ring, or substituted or unsubstituted aromatic heterocyclic ring, Y denotes a radical selected from the group consisting of hydrogen, halogen atoms, cyano radicals, and substituted or unsubstituted alkyl, or alkoxy group, and n stands for an integer of 0.about.4, R.sub.1 and R.sub.2 designate, respectively, hydrogen, substituted or unsubstituted alkyl, substituted or unsubstituted alalkyl, substituted or unsubstituted aromatic hydrocarbon ring or substituted or unsubstituted aromatic heterocyclic ring, and said R.sub.1 and R.sub.2 may be mutually same or different, or may form a ring together with nitrogen atom.Type: GrantFiled: December 22, 1988Date of Patent: March 27, 1990Assignee: Dainichi Seika Color & Chemicals Mfg. Co., Ltd.Inventors: Hisao Kouno, Hiroaki Saikatsu, Osamu Suda, Tetsuhiro Umezaki, Norio Tanaka, Toshifumi Sekino, Masaru Hasegawa, Yoshio Abe, Shojiro Horiguchi
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Patent number: 4908457Abstract: 1,2,4,5-benzoylenebis(anthraquinone[1,2-d]imidazole) compounds represented by following general formula (1) or ##STR1## wherein R and R' each are hydrogen atom, a halogen atom, hydroxyl group, a lower alkyl group, a lower alkoxy group or an aryl group which may be substituted and m and n each are an integer of 1 or 2, and photosensitive members for electrophotography having a photosensitive layer containing them.Type: GrantFiled: December 7, 1988Date of Patent: March 13, 1990Assignee: Sharp Kabushiki KaishaInventors: Satoshi Katayama, Yoshihide Shimoda, Hiroshi Sugimura, Eiji Imada, Shuhei Tsuchimoto
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Layered electrophotographic photosensitive member containing substituted polycyclo trisazo compounds
Patent number: 4895781Abstract: An electrophotographic photosensitive member is disclosed which has a photosensitive layer on an electroconductive support. The photosensitive layer contains a trisazo pigment having the specific structural formula.Type: GrantFiled: March 21, 1989Date of Patent: January 23, 1990Assignee: Canon Kabushiki KaishaInventor: Hideyuki Takai -
Patent number: 4891289Abstract: The present invention relates to a photosensitive member containing a specific styryl compound for a charge transporting material, which is improved in photographic propertied such as photosensitivity and repeating properties.Type: GrantFiled: April 25, 1988Date of Patent: January 2, 1990Assignee: Minolta Camera Kabushiki KaishaInventor: Hideaki Ueda
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Patent number: 4882249Abstract: Disclosed are a photoconductive composition containing a new tetrakisazo compound of the following formula (1) and an electrophotographic photoreceptor having a photosensitive layer which contains the tetrakisazo compound of the formula (1): ##STR1## wherein R.sup.11, R.sup.12, A, Ar.sup.1, Ar.sup.2, Ar.sup.3, Ar.sup.4, Ar.sup.5, and Ar.sup.6 are defined hereinbefore. The electrophotographic photoreceptor has both high sensitivity and high durability, and the sensitivity thereof is barely lowered even after repeated use.Type: GrantFiled: September 12, 1988Date of Patent: November 21, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Katsugi Kitatani, Satoshi Hoshi
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Patent number: 4882427Abstract: This invention provides an optical semiconductor material comprising: (1) a noncrystalline titanium phthalocyanine compound which does not show substantial X-ray diffraction peak in X-ray diffraction chart, (2) a pseudo-noncrystalline titanium phthalocyanine compound which shows broad X-ray diffraction peaks at Bragg angles of 6.9.degree., 15.5.degree., 23.4.degree. and 25.5.degree. measured by using CuK.alpha. beam and (3) an assembly of said noncrystalline titanium phthalocyanine compound and pseudo-noncrystalline titanium phthalocyanine compound. Further, this invention provides an electrophotographic plate comprising an electrically conductive substrate, and a charge-generating layer and charge-transferring layer on the electrically conductive substrate, characterized in that the charge-generating layer contains the above noncrystalline and/or pseudo-noncrystalline titanium phthalocyanine compound(s).Type: GrantFiled: February 17, 1989Date of Patent: November 21, 1989Assignee: Toyo Ink Manufacturing Co., Ltd.Inventors: Toshio Enokida, Shigemasa Takano
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Patent number: 4877702Abstract: There is disclosed an electrophotographic sensitive layer which is provided with a single-layer type sensitive layer containing a specific perylene type compound as an electric charge generating substance, a specific diamine derivative of the following general formula as an electric charge transferring substance, and a binding resin. ##STR1## wherein R.sup.5, R.sup.6, R.sup.7, and R.sup.Type: GrantFiled: October 27, 1988Date of Patent: October 31, 1989Assignee: Mita Industrial Co., Ltd.Inventors: Eiichi Miyamoto, Nariaki Mutou, Tooru Nakazawa
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Patent number: 4871637Abstract: Disclosed are a photoconductive composition containing a new bisazo compound of the following formula (1) and an electrophotographic photoreceptor having a photosensitive layer which contains the bisazo compound of the formula (1): ##STR1## wherein Z, B.sub.1, B.sub.2, A, and L are defined hereinafter. The electrophotographic photoreceptor has both high sensitivity and high durability, and the sensitivity thereof is barely lowered even after repeated use.Type: GrantFiled: September 19, 1988Date of Patent: October 3, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Katsugi Kitatani, Satoshi Hoshi
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Patent number: 4869984Abstract: New electrophotographic elements contain electron-transport agents comprising derivatives of certain substituted 1,4-naphthoquinones in which the keto oxygens at the 4-positions have been replaced by certain cyanoalkoxycarbonylmethylene groups, and the keto oxygens at the 1-positions have been replaced by cyanoimino groups.Type: GrantFiled: December 21, 1988Date of Patent: September 26, 1989Assignee: Eastman Kodak CompanyInventors: Teh-Ming Kung, William B. Vreeland, Ralph H. Young
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Patent number: 4869985Abstract: New electrophotographic elements contain electron-transport agents comprising derivatives of certain substituted 1,4-naphthoquinones in which the keto oxygens at the 4-positions have been replaced by certain cyanoalkoxycarbonylmethylene groups.Type: GrantFiled: December 21, 1988Date of Patent: September 26, 1989Assignee: Eastman Kodak CompanyInventors: Teh-Ming Kung, William B. Vreeland, Ralph H. Young
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Patent number: 4868079Abstract: An electrophotoconductor is disclosed, comprising a conductive support having provided thereon a photoconductive layer comprising a resin binder having dispersed therein an anthanthrone compound, a phthalocyanine compound, and an oxadiazole compound. The electrophotoconductor exhibits high sensitivity in the wavelength region of from 760 to 850 nm and high negative charge retention and is suitable for use in a recording device using a semiconductor laser as a light source.Type: GrantFiled: April 13, 1988Date of Patent: September 19, 1989Assignee: Dainippon Ink and Chemicals, Inc.Inventors: Nguyen C. Khe, Masanobu Nakamura, Midori Fukawatase, Kenji Takahashi
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Patent number: 4859555Abstract: An electrophotographic printing plate comprises a substrate having formed thereon a photoconductive layer comprising (a) a disazo based compound, (b) a perynone based compound, (c) a hole transport material, and (d) an alkali-soluble resin.Type: GrantFiled: October 13, 1987Date of Patent: August 22, 1989Assignee: Dainippon Ink & Chemical, Inc.Inventors: Yoshihiro Nishio, Masanobu Nakamura, Midori Fukawatase, Kenji Takahashi
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Patent number: 4859556Abstract: An electrophotographic photoconductor is disclosed which comprises an electroconductive support material and a photosensitive layer comprising at least one of the stilbene compounds of the formula ##STR1## wherein R.sup.1 represents hydrogen or ##STR2## R.sup.2 represents hydrogen, an alkyl group or a substituted or unsubstituted phenyl group; A represents ##STR3## when R.sup.1 is hydrogen; while, when R.sup.1 is ##STR4## A represents ##STR5## a 9-anthryl group or a substituted or unsubstituted N-alkylcarbazolyl group, wherein R.sup.3 represents hydrogen, an alkyl group, an alkoxy group, a halogen or a substituted amino group represented by ##STR6## in which R.sup.4 and R.sup.5 independently represent an alkyl group, a substituted or unsubstituted aryl group, or a substituted or unsubstituted aralkyl group, and R.sup.4 and R.sup.5 may form a ring in combination, and m is an integer of 0 through 3 and n is an integer of 0 or 1, provided that, when R.sup.1 is hydrogen and n=0, A is ##STR7## in which R.sup.Type: GrantFiled: August 9, 1988Date of Patent: August 22, 1989Assignee: Ricoh Company, Ltd.Inventor: Masaomi Sasaki
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Patent number: 4853308Abstract: A layered photoresponsive imaging member comprised of a supporting substrate, a photogenerating layer, and a hole transport layer comprised of novel bis(diarylamino)fluorenes of the formula: ##STR1## where R and R' are independently selected from the group consisting of hydrogen, alkyl, and substituted alkyl groups; and Ar and Ar' are independently selected from the group consisting of aryl and substituted aryl substituents.Type: GrantFiled: November 9, 1987Date of Patent: August 1, 1989Assignee: Xerox CorporationInventors: Beng S. Ong, John R. C. Fuller, Dasarao K. Murti
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Patent number: 4840862Abstract: A photoconductive composition containing at least one of azaazulenium salt compounds represented by the following formula (I): ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 each represents a hydrogen atom, a halogen atom, a hydroxyl group, a nitro group, a carboxyl group, a sulfonic acid group, a mercapto group or a monovalent organic residue; A represents a divalent organic group bonded by the double bond; X.sup..crclbar. represents an anionic group; n is the number of X.sup..crclbar. groups required to balance the positive charge; provided that each X.sup..crclbar. group may be bonded to any of R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6 or A to form an inner salt; and any two of R.sub.2, R.sup.3, R.sub.4, R.sub.5 and R.sub.6 bonded to adjacent carbon atoms may be linked to form a substituted or unsubstituted aromatic carbocyclic or aromatic heterocyclic ring.Type: GrantFiled: August 7, 1987Date of Patent: June 20, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Naonori Makino, Takanori Hioki, Yoshio Inagaki, Seiji Horie
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Patent number: 4835080Abstract: There is disclosed a photoreceptor which comprises a brominated anthanthrone pigment represented by the structural formula shown below: ##STR1## contained in the photosensitive layer, the brominated anthanthrone pigment exhibiting a X-ray diffraction spectrum having the respective diffraction strengths S (18.4.degree.) and S (26.7.degree.) at 2.theta.=18.4.degree. and 26.7.degree. which satisfy the relationship of0.2.ltoreq.S (18.4.degree.) / S (26.7.degree.).ltoreq.1.0;or exhibiting a X-ray diffraction spectrum having the respective half-value widths of diffraction strength of .DELTA..theta.(18.4.degree.) and .DELTA..theta.(26.7.degree.) at 2.theta.=18.4.degree.and 26.7.degree. which satisfy the relationship of{.DELTA..theta.(18.4.degree.).ltoreq.0.8.degree.} and/or{.DELTA..theta.(26.7.degree.).ltoreq.1.degree.}.Type: GrantFiled: June 9, 1987Date of Patent: May 30, 1989Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Yoshiaki Takei, Eiichi Kijima, Satoshi Goto, Hiroyuki Nomori
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Patent number: 4833054Abstract: An electrophotographic photoreceptor comprising an electrically conductive support having provided thereon a photosensitive layer composed of a charge generating layer and a charge transport layer, wherein said charge generating layer contains a bisazo compound represented by formula (I) ##STR1## wherein X, Y, and A are defined in the specification, and said charge transport layer contains a benzidine compound represented by formula (II) ##STR2## wherein R.sub.1, R.sub.2, and R.sub.3 are as defined in the specification. The photoreceptor exhibits high photoresponse performance even in a weak electric field and exhibits high sensitivity in a visible light region.Type: GrantFiled: October 30, 1987Date of Patent: May 23, 1989Assignee: Fuji Xerox Co., Ltd.Inventors: Yutaka Akasaki, Katsuhiro Sato, Tokita, Hidemi Suto
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Patent number: 4830942Abstract: An electrophotographic photoconductor an electroconductive substrate, an intermediate layer comprising a charge generating azo pigment and a thermosetting resin, a charge generating layer and a charge transporting layer, which layers are successively overlaid on the electroconductive substrate, the charge generating azo pigment being any of the azo pigments (1) through (4): ##STR1##Type: GrantFiled: May 26, 1987Date of Patent: May 16, 1989Assignee: Ricoh Company Ltd.Inventors: Toshio Fukagai, Michio Kimura, Masafumi Ohta, Mitsuru Hashimoto
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Patent number: 4822704Abstract: An electrophotographic photoreceptor is disclosed, comprising a conductive support having provided thereon a photosensitive layer containing a bisazo compound respresented by formula (I) ##STR1## wherein Y represents a hydrogen atom, an alkyl group, an alkoxy group, a halogen atom, a cyano group, a nitro group or a hydroxyl group; and A represents a substituted or unsubstituted divalent aromatic hydrocarbon group or a substituted unsubstituted divalent nitrogen-containing heterocyclic group. The photoreceptor exhibits excellent sensitivity and durability.Type: GrantFiled: July 31, 1987Date of Patent: April 18, 1989Assignee: Fuji Xerox Co., Ltd.Inventors: Yutaka Akasaki, Akihiko Tokita, Kaoru Torikoshi, Akira Imai, Touru Ishii
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Patent number: 4820600Abstract: An electrophotographic photoreceptor is disclosed, comprising a conductive support having provided thereon a photosensitive layer containing a bisazo compound represented by formula (I) ##STR1## wherein X represents a halogen atom or a nitro group, and A represents a substituted or unsubstituted divalent aromatic hydrocarbon group or a substituted unsubstituted divalent nitrogen-containing heterocyclic group. The photoreceptor exhibits excellent sensitivity and durability.Type: GrantFiled: August 5, 1987Date of Patent: April 11, 1989Assignee: Fuji Xerox Co., Ltd.Inventors: Yutaka Akasaki, Akihiko Tokita, Kaoru Torikoshi, Akira Imai, Touru Ishii
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Patent number: 4820788Abstract: Poly(silyl silanes) have been prepared. They have high photosensitivity and excellent resistance to oxygen-reactive ion etching processes. They are useful as photodepolymerizable photoresists, barrier layers, etc.Type: GrantFiled: October 31, 1986Date of Patent: April 11, 1989Assignee: John M. ZeiglerInventor: John M. Zeigler
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Patent number: 4820602Abstract: An electrophotographic photosensitive member has a photosensitive layer on an electroconductive support, wherein said photosensitive layer contains a compound represented by the formula: ##STR1## [wherein Ar.sub.1 represents a phenyl group having one or more group selected from alkoxy groups and alkyl groups, Ar.sub.2 represents a phenyl group having one or more group selected from nitro group, cyano group and halogen atoms, R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7, R.sub.8, R.sub.9, R.sub.10, R.sub.11 and R.sub.12 represnt hydrogen atom, halogen atom, alkyl group, aralkyl group, alkoxy group, nitro group, cyano group, trifluoromethyl group or substituted amino group, with proviso that R.sub.5 and R.sub.6, R.sub.6 and R.sub.7, R.sub.7 and R.sub.8, R.sub.9 and R.sub.10, R.sub.10 and R.sub.11, R.sub.11 and R.sub.12 may form a fused aromatic ring together with a part of the carbazole ring].Type: GrantFiled: July 14, 1987Date of Patent: April 11, 1989Assignee: Canon Kabushiki KaishaInventor: Masakazu Matsumoto
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Patent number: 4808503Abstract: Disclosed herein is a electrophotographic photoreceptor having high sensitivity and excellent durability. The photoreceptor has a photosensitive layer which contains an azo compound having the tetraphenylthiophene or tetraphenylthiophene-1,1-dioxide skeleton.Type: GrantFiled: August 28, 1987Date of Patent: February 28, 1989Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Yasuyuki Yamada, Hisato Itoh, Tsutomu Nishizawa, Akihiro Yamaguchi
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Patent number: 4797337Abstract: Photoconductive imaging members comprising a supporting substrate, a hole transport layer, and a photogenerating layer comprising disazo compounds selected from the group consisting of: ##STR1## wherein X is selected from the group consisting of: ##STR2## wherein Y is selected from the group consisting of: ##STR3## The photoconductive imaging members possess high cyclic stability, high photosensitivity, good dark development potential, low dark decay values, and excellent panchromaticity. They are non-toxic and may be made inexpensively, which renders them disposable.Type: GrantFiled: July 27, 1987Date of Patent: January 10, 1989Assignee: Xerox CorporationInventors: Kock-Yee Law, Ihor W. Tarnawskyj
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Patent number: 4760003Abstract: An electrophotographic photosensitive member comprises a photosensitive layer on a substrate, said photosensitive layer comprising a disazo pigment represented by the formula (1).Type: GrantFiled: May 21, 1986Date of Patent: July 26, 1988Assignee: Canon Kabushiki KaishaInventors: Masakazu Matsumoto, Takao Takiguchi, Masataka Yamashita, Shoji Umehara, Shozo Ishikawa, Hajime Miyazaki
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Patent number: 4743523Abstract: A photosensitive member for electrophotography comprising a photosensitive layer containing an azo pigment selected from those represented by the following formulas (1)-(6): ##STR1## wherein R is an alkyl, aralkyl, aryl, or acyl each capable of having a substituent; Ar is an arylene or heterocyclic group each capable of having a substituent; Ar is a coupler residue group having a phenolic OH group; B is hydrogen, nitroso, or an alkyl, aralkyl, aryl or acyl group capable of having a substituent; and n is 0 or 1.Type: GrantFiled: March 27, 1986Date of Patent: May 10, 1988Assignee: Canon Kabushiki KaishaInventors: Masataka Yamashita, Takao Takiguchi, Shoji Umehara, Masakazu Matsumoto, Shozo Ishikawa
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Patent number: 4737430Abstract: An electrophotographic photosensitive member having a photesensitive layer containing an azo compound represented by the following Formula [I],Formula [I] ##STR1## wherein Y.sub.1, Y.sub.2, Y.sub.3 and Y.sub.4 each is a hydrogen atom, an alkyl group, an alkoxy group or a halogen atom; A.sub.1 and A.sub.2 each represents ##STR2## wherein Z is a group of atoms necessary to complete a substituted or unsubstituted aromatic carbocyclic ring of a substituted or unsubstituted aromatic heterocyclic ring; Q.sub.3 is substituted or unsubstituted carbamoyl group or a substituted or unsubstituted sulfamoyl group; R.sub.1 is a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted amino group, a substituted or unsubstituted carbamoyl group, a carboxyl group, a carboxyl group or ester group thereof, or a cyano group; A' is a substituted or unsubstituted aryl group; and R.sub.2 and R.sub.Type: GrantFiled: August 21, 1985Date of Patent: April 12, 1988Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Akira Kinoshita, Naohiro Hirose, Kiyoshi Sawada
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Patent number: 4735882Abstract: An electrophotographic photosensitive member comprises a photosensitive layer containing an azo pigment selected from the following general formulae (1) to (5): ##STR1## wherein groups Ar are arylene groups and divalent heterocyclic groups, each of which may contain a substituent; n is 0 or 1; and group A is a coupler residue group having a phenolic OH group.Type: GrantFiled: April 1, 1986Date of Patent: April 5, 1988Assignee: Canon Kabushiki KaishaInventors: Masataka Yamashita, Takao Takiguchi, Shoji Umehara, Masakazu Matsumoto, Shozo Ishikawa
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Patent number: 4728593Abstract: Polyimide-electron donor charge transfer complexes, supported or unsupported, as photoconductive elements characterized by photoconductivities in excess of the sum of the individual photoconductivities of the polyimide and electron donor components.Type: GrantFiled: June 9, 1986Date of Patent: March 1, 1988Assignee: E. I. Du Pont de Nemours and CompanyInventors: Steven C. Freilich, Stephen Mazur
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Patent number: 4719163Abstract: Multi-active photoconductive insulating elements which are sensitive in the far red region of the spectrum are comprised of a charge-generation layer and a charge-transport layer in electrical contact therewith and contain, as the charge-generating agent within the charge-generation layer, the compound N,N'-bis[2-(3-methylphenyl)ethyl]perylene-3,4:9,10-bis(dicarboximide). The charge-generation layer is capable, upon exposure to activating radiation, of highly effective generation and injection of charge carriers and the charge-transport layer, which is comprised of an organic composition containing an organic photoconductive material, is capable of accepting and transporting the injected charge carriers to thereby form a highly advantageous multi-active photoconductive insulating element.Type: GrantFiled: June 19, 1986Date of Patent: January 12, 1988Assignee: Eastman Kodak CompanyInventors: William J. Staudenmayer, Michael T. Regan
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Patent number: 4708921Abstract: The present invention relates to a photosensitive material for use in electrophotography, characterized by having a photosensitive layer containing a disazo pigment having the following general formula (I), ##STR1## wherein A represents a coupler residue.Type: GrantFiled: January 21, 1986Date of Patent: November 24, 1987Assignee: Ricoh Co., Ltd.Inventor: Mitsuru Hashimoto
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Patent number: 4702982Abstract: This invention relates to an electrophotographic photosensitive member utilizing a novel electrophotographic photosensitive material, more particularly to an electrophotographic photosensitive member endowed with high sensitivity as well as excellent potential stability during repeated copying by incorporating an azo pigment having a specific molecular structure in the photosensitive layer.Type: GrantFiled: May 22, 1986Date of Patent: October 27, 1987Assignee: Canon Kabushiki KaishaInventors: Masakazu Matsumoto, Takao Takiguchi, Masataka Yamashita, Shoji Umehara, Shozo Ishikawa
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Patent number: 4673630Abstract: Photoconductive films contain specified azulenium salt compounds. Electrophotographic photosensitive members are provided with a photoconductive film containing at least one of the specified azulenium salt compounds.Type: GrantFiled: June 6, 1985Date of Patent: June 16, 1987Assignee: Canon Kabushiki KaishaInventors: Kazuhara Katagiri, Yoshihiro Oguchi, Takeshi Ohtake, Kozo Arao, Makoto Kitahara, Yoshio Takasu
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Patent number: 4666810Abstract: An electrophotographic photosensitive member comprises a photosensitive layer containing an azo pigment selected from the general formulae (1) to (6).Type: GrantFiled: April 15, 1986Date of Patent: May 19, 1987Assignee: Canon Kabushiki KaishaInventors: Shoji Umehara, Masakazu Matsumoto, Takao Takiguchi, Masataka Yamashita, Shozo Ishikawa
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Patent number: 4666805Abstract: The present invention relates to a novel disazo compound having the following general formula (I), ##STR1## wherein A represents ##STR2## (wherein R represents an alkyl, alkoxy, nitro, halogen, cyano or halomethyl group; n represents an integer of 0, 1, 2 or 3; and R may be the same or different when n is an integer of 2 or 3), and a method for preparing the same.The present invention further relates to a photosensitive material for use in electrophotography, characterized by providing a photosensitive layer containing a disazo pigment having the following general formula (VII), ##STR3## wherein A.sub.1 represents a coupler residue and R' represents hydrogen or a lower alkyl group.Type: GrantFiled: June 11, 1985Date of Patent: May 19, 1987Assignee: Ricoh Co., Ltd.Inventor: Mitsuru Hashimoto
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Patent number: 4647520Abstract: A photoreceptor comprising a photosensitive layer and an electroconductive support, wherein the photosensitive layer contains an azo compound represented by the following Formula [I]: ##STR1## wherein A is a substituted or unsubstituted alkyl group, or a substituted or unsubstituted aryl group, B is an oxygen atom or a sulfur atom; R is a hydrogen atom, an alkyl group, an alkoxy group, or a halogen atom; and Cp is ##STR2## wherein Z represents a group of atoms necessary for constituting a substituted or unsubstituted aromatic carbon ring, or a substituted or unsubstituted aromatic heterocyclic ring; Y is a substituted or unsubstituted carbamoyl group or a substituted or unsubstituted sulfamoyl group;R.sub.1 is a hydrogen atom, a substituted or unsubstituted amino group, a substituted or unsubstituted carbamoyl group, a carboxy group and the esters thereof, or cyano group; A' is a substituted or unsubstituted aryl group;R.sub.2 and R.sub.Type: GrantFiled: September 27, 1985Date of Patent: March 3, 1987Assignee: Konoshiroku Photo Industry Co., Ltd.Inventors: Kazumasa Watanabe, Satoru Ikeuchi, Osamu Sasaki, Naohiro Hirose
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Patent number: 4631242Abstract: An electrophotographic material comprises a conductive support and a light-sensitive layer containing at least one of the azo compound of the formulas [I]-[III]:formula [I]:Cp.sub.1 --N.dbd.N--A--N.dbd.N--Cp.sub.2A represents a divalent residue which bonds through C atoms to N atoms which constitute azo and Cp.sub.1 is a group of by the formula: ##STR1## Z represents a substituted or unsubstituted carbocyclic aromatic ring, a substituted or unsubstituted heterocyclic aromatic ring or a unsaturated monocyclic hydrocarbon ring and R represents an aryl group containing one or two CF.sub.3 groups and Cp.sub.2 is a coupler residue different from said Cp.sub.1 and is selected from following formulas (a)-(f): ##STR2## Z.sup.1 and Z.sup.2 represent a substituted or unsubstituted aromatic hydrocarbon ring or substituted or unsubstituted hetero ring, R.sup.1 and R.sup.2 represent substituted or unsubstituted alkyl, aralkyl, aryl or hetero ring group, R.sup.3 represents an alkyl or carboxyl group or an ester thereof, R.Type: GrantFiled: September 5, 1985Date of Patent: December 23, 1986Assignee: Mitsubishi Paper Mills, Ltd.Inventors: Kazuhiro Emoto, Kozo Haino, Akira Itoh
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Patent number: 4629670Abstract: Photoconductive films contain specified azulenium salt compounds. Electrophotographic photosensitive members are provided with a photoconductive film containing at least one of the specified azulenium salt compounds.Type: GrantFiled: June 7, 1985Date of Patent: December 16, 1986Assignee: Canon Kabushiki KaishaInventors: Kazuharu Katagiri, Yoshihiro Oguchi, Takeshi Ohtake, Kozo Arao, Yoshio Takasu
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Patent number: 4619990Abstract: Polymeric dyes having pendent chromophore groups which are selected from azo, tricyanovinyl, anthraquinone, methine, and indoaniline groups fall into two classes, [A] condensation polymers, and [B] polymers derived from copolymerized ethylenically-unsaturated monomers, the dyes being capable of undergoing thermoplastic deformation by a focused laser beam when in a layer of thickness in the range of 0.1 to 100 micrometers and having an absorptivity in the range of 10 to 250 Lg.sup.-1 cm.sup.-1. They are film-forming, thermally- and light-stable, and solvent-coatable. These compounds are useful as coloring and light-absorbing agents, particularly as the light-absorbing agents in thin optical recording layers.Type: GrantFiled: March 11, 1985Date of Patent: October 28, 1986Assignee: Minnesota Mining and Manufacturing CompanyInventor: Mohamed A. Elmasry
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Patent number: 4618672Abstract: Bisazo compounds represented by the general formula ##STR1## wherein R represents a halogen selected from the group consisting of fluorine, chlorine, bromine and iodine, and when R is fluorine, it is at the ortho, para or meta position in each phenylcarbamoyl group; when R is chlorine, it is at the ortho position; when R is bromine, it is positioned at the ortho or meta position; and when R is iodine, it is at the meta position, which bisazo compounds are particularly suitable for use in the charge generating layer of a layered electrophotographic photoconductor.Type: GrantFiled: April 21, 1981Date of Patent: October 21, 1986Assignee: Ricoh Company, Ltd.Inventor: Mitsuru Hashimoto
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Patent number: 4617151Abstract: 2- or 2,3-substituted 5,6,11,12-tetraseleneotetracene or -tetrathiotetracene of the formula ##STR1## in which X is S or Se, R is alkoxy, hydroxyalkoxy, aryloxy, cycloalkoxy, aralkoxy, --OH, --NH.sub.2, --Cl, --Br or substituted amino and Y is hydrogen or --COR. The compounds can be bonded as side groups to polymers. The polymers and the compounds combine with electron acceptors to form charge transfer complexes which can be used as electrically conductive layers.Type: GrantFiled: March 15, 1985Date of Patent: October 14, 1986Assignee: Ciba-Geigy CorporationInventors: Carl W. Mayer, Vratislav Kvita, Josef Pfeifer
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Patent number: 4612271Abstract: A photosensitive composition is provided comprising at least one azo compound represented by formula (1) ##STR1## wherein A.sup.1 represents a substituted or unsubstituted carbocyclic or heterocyclic aromatic ring; X represents an atomic group forming a substituted or unsubstituted carbocyclic or heterocyclic aromatic ring upon condensation with benzene rings; Ar represents a carbocyclic or heterocyclic aromatic ring substituted by at least one perfluoroalkyl group (groups other than perfluoroalkyl group may also be present); and n represents an integer of 3, 4, 5, or 6.Type: GrantFiled: December 19, 1985Date of Patent: September 16, 1986Assignee: Fuji Photo Film Co., Ltd.Inventors: Naonori Makino, Seiji Horie, Hideo Sato
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Patent number: 4609602Abstract: Disclosed is an improved layered photoresponsive imaging member comprised of a photogenerating layer, and in contact therewith an electron transporting layer comprised of compounds selected from the group consisting of anthraquinodimethanes, and anthrone derivatives of the following formulas dispersed in an inactive resinous binder: ##STR1## wherein A and B are independently selected from the group consisiting of CN and COOR, wherein R is an alkyl group; X and Y are independently selected from the group consisting of alkyl, aryl, halide, COOR, CN, hydroxy, and nitro; m is a number of from zero to about 3; and n is a number of from zero to about 3.Type: GrantFiled: March 8, 1985Date of Patent: September 2, 1986Assignee: Xerox CorporationInventors: Beng S. Ong, Dasarao K. Murti, Barkev Keoshkerian
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Patent number: 4606987Abstract: An electrophotographic photosensitive material has a photosensitive layer formed on an electroconductive substrate, with the photosensitive layer containing a polymeric binder and an organic photoconductor represented by the following formulaA--CH.dbd.CH).sub.n CH.dbd.NNHYwherein A is selected from the group consisting of an alkyl group having 1 to 12 carbon atoms, an aralkyl group having 7 to 14 carbon atoms, an aryl group having 6 to 20 carbon atoms and a heterocyclic residue of a 3- to 30- membered ring,wherein n is 1 or 2,Y is selected from the group consisting of --SO.sub.2 R', ##STR1## wherein R' is selected from the group consisting of an alkyl group having 1 to 12 carbon atoms, an aralkyl group having 7 to 14 carbon atoms, an aryl group having 6 to 20 carbon atoms and a heterocyclic residue of a 3- to 30- membered ring, and R.sup.2 and R.sup.3, R.sup.4 and R.sup.5, either form a ring together with the nitrogen atom to which R.sup.2 and R.sup.3, R.sup.4 and R.sup.5 are bonded and in this case R.sup.Type: GrantFiled: July 9, 1985Date of Patent: August 19, 1986Assignee: Toray Industries, Inc.Inventors: Kazuo Matsuura, Hiroki Osedo, Keisuke Ohshima
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Patent number: 4600674Abstract: Disclosed is an electrophotographic photoconductive material excellent in sensitivity and durability which comprises an electroconductive substrate and, provided thereon, a photosensitive layer containing a trisazo pigment represented by the general formula ##STR1## wherein R's, which may be the same or different, represent each a hydrogen atom, halogen atom, substituted or unsubstituted alkyl group, alkoxyl group, or nitrile group; n is an integer of 1 or 2; and A represents ##STR2## wherein Z represents a group of atoms necessary to complete a substituted or unsubstituted aromatic carbon ring or a substituted or unsubstituted aromatic hetero-ring; X represents a hydrogen atom, an alkyl group, or a group of atoms necessary to complete a substituted or unsubstituted aromatic carbon ring, a substituted or unsubstituted aromatic hetero ring, or a substituted or unsubstituted hetero ring; m is 0 or 1; B represents a group of atoms necessary to complete a substituted or unsubstituted aromatic carbon ring, a substType: GrantFiled: June 24, 1985Date of Patent: July 15, 1986Assignee: Mitsubishi Paper Mills, Ltd.Inventors: Kazuhiro Emoto, Akira Itoh