Alkyl Amino Group Patents (Class 430/74)
  • Patent number: 6187493
    Abstract: The present invention provides an electrophotosensitive material comprising a conductive substrate and a photosensitive layer provided on the conductive substrate, the photosensitive layer comprising a specific hole transferring material and/or electron transferring material and a binding resin of a polyester resin which is a substantially linear polymer obtained by using a specific dihydroxy compound represented by the general formula (1): wherein R1 is an alkylene group having 2 to 4 carbon atoms; and R2, R3, R4 and R5 are the same or different and indicate a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, an aryl group or an aralkyl group or the like. This photosensitive material is improved in sensitivity, and is also superior in adhesion to conductive substrate as well as mechanical strength such as wear resistance, etc.
    Type: Grant
    Filed: February 10, 1998
    Date of Patent: February 13, 2001
    Assignee: Kyocera Mita Corporation
    Inventors: Masato Katsukawa, Akiyoshi Urano, Ayako Sugase, Mitsuo Ihara, Ichiro Yamazato, Yuka Nakamura
  • Patent number: 6107439
    Abstract: A conductive composition including a mixture of a reaction product ofa hole transporting hydroxy functionalized aryl amine,a hydroxy functionalized arylamine that is different from the hole transporting hydroxy functionalized aryl amine,a cross linkable polyamide, andand an acid capable of simultaneously cross linking the polyamide and oxidizing a portion of the hydroxy functionalized arylamine,the mixture of a reaction product includinga hole transporting hydroxy functionalized aryl amine andan oxidized hydroxy functionalized aryl amine in aa crosslinked polyamide matrix.Other embodiments including processes for applying the aforementioned composition and processes for using devices containing the compositions in high speed laser printing and related printing systems are also disclosed.
    Type: Grant
    Filed: December 22, 1998
    Date of Patent: August 22, 2000
    Assignee: Xerox Corporation
    Inventors: John F. Yanus, Damodar M. Pai, Timothy J. Fuller, Paul J. DeFeo, Markus R. Silvestri, Dale S. Renfer, William W. Limburg
  • Patent number: 6090512
    Abstract: An electrophotographic photoreceptor includes a conductive substrate and a photosensitive layer on the conductive substrate. The photosensitive layer contains an arylamine compound of a formula (I): ##STR1## where A.sub.1, A.sub.2, A.sub.3 and A.sub.4 each independently represents a substituted or unsubstituted group selected from an alkyl group, an aralkyl group, an aryl group, a heterocyclic group and a condensed polycyclic group; Y represents a substituted or unsubstituted group selected from an alkylene group, an aralkylene group, an alkenylene group, an arylene group, and a bivalent heterocyclic group; and R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7 and R.sub.
    Type: Grant
    Filed: May 28, 1999
    Date of Patent: July 18, 2000
    Assignee: Mitsubishi Chemical Corporation
    Inventor: Atsuo Saita
  • Patent number: 6040100
    Abstract: An electrophotographic photosensitive member is formed of a support, and a photosensitive layer disposed on the support. The photosensitive layer is characterized by containing an azo pigment having an organic group represented by formula (1) below: wherein A denotes a residue group of formula (1A) below: ##STR1## and k.sub.1, k.sub.2, Z.sub.1, Z.sub.2, D; R.sub.1 and R.sub.2 are defined in the text. The group of the formula (1) may provide at least one of up to 4 azo-substituents of the azo pigment having an entire structure represented by ##STR2## wherein Ar denotes an aromatic or heterocyclic core unit, Cp denotes a coupler residue group, and --(N.dbd.N--Cp) denotes such an azo-substituent. The photosensitive member can exhibit good electrophotographic performances including high and stable sensitivity on repetitive use.
    Type: Grant
    Filed: March 3, 1999
    Date of Patent: March 21, 2000
    Assignee: Canon Kabushiki Kaisha
    Inventors: Masato Tanaka, Hideyuki Takai, Kouichi Nakata
  • Patent number: 5945242
    Abstract: Disclosed is an electrophotographic photoreceptor having a high sensitivity, a high endurance and a high stability against repeated use which comprises a conductive support with a light-sensitive layer containing one or more hydrazone compounds represented by the following formula (I): ##STR1## wherein R.sub.1 represents an alkyl group of 5 or more carbon atoms, R.sub.2 represents a substituted or unsubstituted alkyl group, alkenyl group, aralkyl group, aryl group or heterocyclic group, and R.sub.3 and R.sub.4 each represent a hydrogen atom, an alkyl group, an alkoxy group or a halogen atom.
    Type: Grant
    Filed: October 7, 1997
    Date of Patent: August 31, 1999
    Assignee: Mitsubishi Paper Mills Limited
    Inventors: Tomoko Taniguchi, Tatsuya Kodera
  • Patent number: 5707768
    Abstract: A diamine compound of the following formula (1): ##STR1## wherein R.sub.1 is a hydrogen atom, a lower alkyl group or a lower alkoxy group, each of A.sub.1, A.sub.2 and A.sub.3 which are independent of one another, is a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, or a group of the following formula (2): ##STR2## wherein R.sub.1 is as defined above, and X is a substituted or unsubstituted arylene group or a substituted or unsubstituted heterocyclic bivalent group.
    Type: Grant
    Filed: November 28, 1995
    Date of Patent: January 13, 1998
    Assignee: Hodogaya Chemical Co., Ltd.
    Inventors: Mitsutoshi Anzai, Atsushi Takesue, Takanobu Watanabe, Chieko Inayoshi
  • Patent number: 5700614
    Abstract: Cyclopentadiene derivative compounds, and an electrophotographic photoconductor comprising one cyclopentadiene derivative compound are disclosed. The cyclopentadiene derivative compounds are useful for use in a photoconductive layer, and readily soluble in a binder resin. The electrophotographic photoconductor can be prepared by using a simple, effective production method. The electrophotographic photoconductor comprising one cyclopentadiene derivative compound provides a good light sensitivity and high durability.
    Type: Grant
    Filed: March 2, 1995
    Date of Patent: December 23, 1997
    Assignee: Ricoh Company, Ltd.
    Inventors: Megumi Kawahara, Ikuko Yamada, Masayuki Shoshi, Akio Kojima
  • Patent number: 5561017
    Abstract: A polyester polymer comprising repeating units (I), or repeating units (I) and (II), and having a reduced viscosity (.eta. sp/c) of 0.2 to 10.0 dl/g, measured at 20.degree. C. as a 0.5 g/dl solution dissolved in methylene chloride is prepared by allowing a dihydric phenol (III), or dihydric phenols (III) and (IV), to react with a carbonate precursor or a dibasic acid. An electrophotographic photoreceptor which comprises an electroconductive substrate and a photosensitive layer disposed on the electroconductive substrate and containing the polyester polymer as a charge transporting material or a binder resin. ##STR1## wherein, W is --O-- or single bond, X is a divalent group which is derived from a dihydric phenol containing a hydrazine structure, each of R.sup.25 and R.sup.26 is a halogen atom, an alkyl group, a cycloalkyl group or an aryl group, each of m and n is an integer of 0 to 4, Y is single bond, --O--, --S--, --SO--, --SO.sub.2 --, --CR.sup.27 R.sup.28 --, a 1,1-cycloalkylene group or an .alpha.,.
    Type: Grant
    Filed: December 6, 1995
    Date of Patent: October 1, 1996
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Tomohiro Nagao, Shuji Sakamoto, Hironobu Morishita, Hideyuki Miyamoto
  • Patent number: 5486441
    Abstract: A 1,4-bis(4,4-diphenyl-1,3-butadienyl)benzene derivative represented by formula (I): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, and R.sup.4 each independently represents a lower alkyl group which may be substituted, an aralkyl group which may be substituted, or an aryl group which may be substituted, and an electrophotographic photoreceptor using the compound are disclosed. The photoreceptor provides a high carrier drift mobility.
    Type: Grant
    Filed: April 27, 1995
    Date of Patent: January 23, 1996
    Assignee: Takasago International Corporation
    Inventors: Yoshimasa Matsushima, Toshimitsu Hagiwara
  • Patent number: 5463128
    Abstract: A 1,4-bis(4,4-diphenyl-1,3-butadienyl)benzene derivative represented by formula (I): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, and R.sup.4 each independently represents a lower alkyl group which may be substituted, an aralkyl group which may be substituted, or an aryl group which may be substituted, and an electrophotographic photoreceptor using the compound are disclosed. The photoreceptor provides a high carrier drift mobility.
    Type: Grant
    Filed: April 28, 1994
    Date of Patent: October 31, 1995
    Assignee: Takasago International Corporation
    Inventors: Yoshimasa Matsushima, Toshimitsu Hagiwara
  • Patent number: 5453343
    Abstract: Organic photoreceptors of the functionally separated laminated type containing a hydrazone compound in the charge transport layer thereof which provides low crystallinity and improved sensitivity, durability, and reproducibility. The hydrazone compound disclosed in the present invention is presented by the following general formula (I): ##STR1## wherein R.sub.1 represents a substituted or unsubstituted C.sub.1 -C.sub.4 alkyl group, R.sub.2 represents a hydrogen atom, or an alkyl or alkoxy group; n is an integer of either 1 or 2; R.sub.3 and R.sub.4 each independently represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group or a substituted or unsubstituted aralkyl group; or alternatively R.sub.3 and R.sub.4 form a substituted or unsubstituted aromatic heterocyclic ring residue cojointly with the nitrogen atom to which they are bonded.
    Type: Grant
    Filed: February 9, 1993
    Date of Patent: September 26, 1995
    Assignee: Industrial Technology Research Institute
    Inventors: Jia-Ming Liu, Shih-Ying Shen, Kuei-Fei Teng
  • Patent number: 5445909
    Abstract: An electrophotographic photoreceptor high in sensitivity and contrast potential after light irradiation is disclosed. The photoreceptor comprises an electroconductive substrate having thereon a photoconductive layer comprising a charge generating layer comprising a charge generating material, and a charge transporting layer comprising a charge transporting material, wherein the ionization potential IPg of the charge generating material is lower than the ionization potential IPt of the charge transporting material, the difference therebetween is 0.35 eV or less, and the difference between the ionization potential IPg1 of the charge generating layer and the ionization potential IPt1 of the charge transporting layer is within the range of -0.1 to +0.1 eV.
    Type: Grant
    Filed: July 9, 1993
    Date of Patent: August 29, 1995
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Yutaka Akasaki, Katsuhiro Sato, Katsumi Nukada
  • Patent number: 5443933
    Abstract: An electrophotographic photoreceptor which is highly sensitive to light having a wavelength in the oscillatory wavelength region of semiconductor laser and responds quickly and is excellent in other electrophotographic characteristics and which consists an electroconductive support, a charge-generating layer and a charge-transfer layer, the two layers being placed on the support, and said charge-transfer layer containing a specific butadiene compound having formula (I); ##STR1## and a monophenol type antioxidant, the weight ratio of the monophenol type antioxidant/the butadiene compound ranging from 5/95 to 40/80.
    Type: Grant
    Filed: September 10, 1993
    Date of Patent: August 22, 1995
    Assignees: Shindengen Electric Manufacturing Co., Ltd., Yamanashi Electronics Co., Ltd., Takasago International Corporation
    Inventors: Kenichi Fujimori, Yoshitaro Nakayama, Takumi Shinohara, Atsushi Iwanami, Toshimitsu Hagiwara, Tohru Kobayashi
  • Patent number: 5436100
    Abstract: An electrophotographic photoconductor is composed of an electroconductive substrate and a photoconductive layer formed thereon including a m-phenylenediamine derivative of formula (I): ##STR1## wherein Ar represents a non-condensed polycyclic hydrocarbon group other than a phenyl group, or a condensed polycyclic hydrocarbon group having not more than 18 carbon atoms; and R.sup.1, R.sup.2, R.sup.3 and R.sup.4 each represent hydrogen a halogen atom a cyano group, a nitro group, an alkyl group, an alkoxyl group, an aryl group, an aryloxy group, an alkylmercapto group, a group represented by ##STR2## in which R.sup.6 and R.sup.7 each represent hydrogen, an alkyl group, or an aryl group, an alkylenedioxy group or an alkylenedithio group. Novel m-phenylenediamine derivatives for use in the electrophotoconductor and intermediates for producing the m-phenylenediamine derivatives, and methods of those derivatives are disclosed.
    Type: Grant
    Filed: April 7, 1994
    Date of Patent: July 25, 1995
    Assignee: Ricoh Company, Ltd.
    Inventors: Tomoyuki Shimada, Masaomi Sasaki, Tamotsu Aruga, Hiroshi Adachi
  • Patent number: 5389479
    Abstract: The present invention provides a highly sensitive and highly durable electrophotographic photoconductor providing a conductive support and a photosensitive layer formed thereon, the photosensitive layer comprising a bis-enamine compound of the formula (I): ##STR1## wherein "A" is a C.sub.6-12 arylene group which may have a substituent, a bivalent heterocyclic reside which may have a substituent, a C.sub.2-4 lower alkylene group which may have a substituent; "B" is a lower dialkylamino group, a lower alkoxy group, a lower alkyl group, a hydrogen atom or a halogen atom; and k is an integer from 1 to 5 provided that when k is an integer of 2 or more, "B" may be identifcal or different, may together form a ring; and n is an integer from 2 to 4.
    Type: Grant
    Filed: August 24, 1993
    Date of Patent: February 14, 1995
    Assignee: Sharp Kabushiki Kaisha
    Inventors: Kiyofumi Morimoto, Akihiro Kondo, Satoshi Machino, Kazuhiro Emoto, Akiko Masuda
  • Patent number: 5368965
    Abstract: An electrophotographic photoreceptor comprises an .alpha.-form copper phthalocyanine composition, which is obtained by treating a copper tetranitrophthalocyanine and copper phthalocyanine simultaneously to convert the crystalline form into .alpha.-form, and a photoconductive squarylium compound as the photoconductive material, and the ratios of the copper tetranitrophthalocyanine and the squarylium compound to the .alpha.-form copper phthalocyanine composition are limited to a particular range. The photoreceptor has a high photosensitivity and an excellent durability.
    Type: Grant
    Filed: April 23, 1993
    Date of Patent: November 29, 1994
    Assignee: Citizen Watch Co., Ltd.
    Inventors: Mizue Fujimori, Ken Nagasawa, Yorinobu Yamada
  • Patent number: 5362589
    Abstract: A phthalocyanine mixed crystal comprising a halogenated indium phthalocyanine and a halogenated gallium phthalocyanine and an electrophotographic photoreceptor containing the phthalocyanine mixed crystal. The phthalocyanine mixed crystal is a charge generating material which provides an electrophotographic photoreceptor excellent in sensitivity, stability on repeated use, and environmental stability.
    Type: Grant
    Filed: November 2, 1993
    Date of Patent: November 8, 1994
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Katsumi Nukada, Akira Imai, Katsumi Daimon, Masakazu Iijima
  • Patent number: 5356742
    Abstract: An electrophotographic photoconductor is composed of an electroconductive substrate and a photoconductive layer formed thereon, the photoconductive layer includes a dipyrenylamine derivative of formula (I): ##STR1## wherein R represents an alkyl group with 1 to 12 carbon atoms, which may have a substituent, or an aryl group which may have a substituent. Novel dipyrenylamine derivatives of formula (I), in which R is --ph--(R.sup.4)n, wherein, ph is a phenyl group, R.sup.4 is hydrogen, an unsubstituted or substituted alkyl group having 1 to 12 carbon atoms, an unsubstituted or substituted alkoxyl group having 1 to 12 carbon atoms, n is an integer of 1 to 5, and when n is 2 to 5, R.sup.4 may be the same or different, which are for use in the photoconductive layer of the electrophotographic photoconductor, are synthesized.
    Type: Grant
    Filed: February 28, 1992
    Date of Patent: October 18, 1994
    Assignee: Ricoh Company, Ltd.
    Inventors: Tomoyuki Shimada, Masaomi Sasaki, Tamotsu Aruga, Hiroshi Adachi
  • Patent number: 5338634
    Abstract: The present invention provides a new diamino compound represented by the following general formula [I] or [X] excellent in charge transporting properties. ##STR1## The present invention provides a photosensitive member and an electroluminescence device both of which comprise the diamino compound of the general formula [I] or [X] as a charge transporting material.
    Type: Grant
    Filed: July 30, 1992
    Date of Patent: August 16, 1994
    Assignee: Minolta Camera Kabushiki Kaisha
    Inventor: Hideaki Ueda
  • Patent number: 5338633
    Abstract: An electrophotographic photoreceptor comprising an electrically conductive substrate and a photoconductive layer formed thereon, wherein said photoconductive layer contains a compound of the formula ( I ): ##STR1## wherein R.sup.1 to R.sup.18 are respectively and independently a hydrogen atom, a halogen atom, a saturated or unsaturated aliphatic hydrocarbon group, an aromatic hydrocarbon group, an alkoxy group, an aryloxy group, a dialkylamino group or a diarylamino group, wherein the aliphatic hydrocarbon group, the aromatic hydrocarbon group, the alkoxy group, the aryloxy group, the dialkylamino group and the diarylamino group may have substituents, X is a bivalent hydrocarbon group which may have substituents, each of A.sup.1 and A.sup.2 is a saturated or unsaturated aliphatic hydrocarbon group or an aromatic hydrocarbon group, or is bonded to R.sup.5 or R.sup.
    Type: Grant
    Filed: May 22, 1992
    Date of Patent: August 16, 1994
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Mamoru Nozomi, Sumiko Watabe, Ryoko Aso
  • Patent number: 5330866
    Abstract: The present invention provides a new amino compound represented by the following general formula [I] excellent in charge transporting properties. ##STR1## The present invention provides a photosensitve member and an electroluminescence device both of which comprise the amino compound of the general formula [I] as a charge transporting material.
    Type: Grant
    Filed: February 14, 1992
    Date of Patent: July 19, 1994
    Assignee: Minolta Camera Kabushiki Kaisha
    Inventor: Hideaki Ueda
  • Patent number: 5314775
    Abstract: The present invention provides a new diamino compound represented by the following general formula [I]. ##STR1## The present invention provides also a photosensitive member and an electroluminescence device both of which comprise the diamino compound of the general formula [I] as a charge transporting material.
    Type: Grant
    Filed: August 10, 1992
    Date of Patent: May 24, 1994
    Assignee: Minolta Camera Kabushiki Kaisha
    Inventor: Hideaki Ueda
  • Patent number: 5308726
    Abstract: An electrophotographic photosensitive element is here disclosed which comprises a conductive substrate and at least a photosensitive layer formed on the conductive substrate, the electrophotographic photosensitive element being characterized in that the photosensitive layer contains, as a charge transport material, a compound represented by the formula (1), (2) or (3) ##STR1##
    Type: Grant
    Filed: December 14, 1992
    Date of Patent: May 3, 1994
    Assignee: NEC Corporation
    Inventors: Akira Hirano, Eriko Tsuruoka
  • Patent number: 5275899
    Abstract: Photoconductive compositions useful in the fabrication of digital, laser-imaged offset printing plates. The compositions comprise a mixture of (a) an infrared-sensitive organic photoconductor sensitive to light in the wavelength range of 700-9090 nm; (b) a visible light-sensitive organic photoconductor sensitive to light in the wavelength range of 400-700 nm; (c) an ultraviolet-sensitive organic photoconductor sensitive to light in the wavelength range of 300-400 nm; and (d) a binder.
    Type: Grant
    Filed: April 13, 1992
    Date of Patent: January 4, 1994
    Assignee: Sun Chemical Corporation
    Inventors: Ken-ichi Shimazu, Jayanti S. Patel, Nishith V. Merchant
  • Patent number: 5272030
    Abstract: An enamine derivative containing a fluoroalkyl group, a fluoroaryl group or a fluoroaralkyl group is effective as a charge transport material in an electrophotographic member excellent in sensitivity, residual potential, durability and the like electrophotographic properties.
    Type: Grant
    Filed: March 20, 1991
    Date of Patent: December 21, 1993
    Assignee: Hitachi Chemical Company, Ltd.
    Inventors: Yoshii Morishita, Shigeru Hayashida, Yasushi Sugimoto, Hiroko Ishikawa, Hiroshi Kobayashi, Takaaki Sonoda
  • Patent number: 5268246
    Abstract: An electrophotographic photoconductor is composed of an electroconductive support and a photoconductive layer formed thereon comprising a novel pyrene-ring-containing olefin compound having formula [I]: ##STR1## wherein R.sup.1 and R.sup.2 each represent hydrogen or an alkyl group which may have a substituent; Y is an aliphatic hydrocarbon group which may have a substituent, a cyclic hydrocarbon group which may have a substituent, or an aromatic group which may have a substituent; n is an integer of 0 or 1, and m is an integer of 1 to 3, provided that when n is 0, m is 1, R.sup.1 is hydrogen, and Y is an aromatic group with a substituent ##STR2## R.sup.5 and R.sup.3 each represent hydrogen, and Y and R.sup.1 may be bonded to form a ring, a method of synthesizing the pyrene-ring-containing olefin compound and an intermediate therefor are disclosed.
    Type: Grant
    Filed: April 9, 1991
    Date of Patent: December 7, 1993
    Assignee: Ricoh Company, Ltd.
    Inventors: Tamotsu Aruga, Masaomi Sasaki, Tomoyuki Shimada, Hiroshi Adachi
  • Patent number: 5250377
    Abstract: Aromatic diolefinic compounds including 1,4-divinylbenzene derivatives, which are useful not only as organic photoconductive materials for electrophotography, but also as intermediates for producing diethyl aromatic compounds which are also useful as organic photoconductive materials for electrophotography, the aromatic diethyl compounds, an electrophotographic photoconductor containing any of the above aromatic diethyl compounds in a photosensitive layer thereof, and a charge transporting medium containing any of the aromatic diethyl compound are disclosed.
    Type: Grant
    Filed: February 21, 1992
    Date of Patent: October 5, 1993
    Assignee: Ricoh Company, Ltd.
    Inventors: Tomoyuki Shimada, Masaomi Sasaki, Mitsuru Hashimoto
  • Patent number: 5246808
    Abstract: The present invention provides a hydrazone compound of the following general formula (I). This compound presents a higher hole mobility as compared with a conventional electric charge transferring material such as a conventional hydrazone compound or the like. Accordingly, when a photosensitive layer contains, as the electric charge transferring material, the hydrazone compound of the present invention, there can be obtained an electrophotosensitive material which is excellent in sensitivity and charging ability and has high repeating characteristics. ##STR1## (wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 may be same as or different from one another, and each is a hydrogen atom, an alkyl group, an alkoxy group, an aralkyl group or an aryl group, each of said alkyl, alkoxy, aralkyl and aryl groups may have a substituent group; A.sup.1, A.sup.2, A.sup.3, A.sup.4, A.sup.5 and A.sup.
    Type: Grant
    Filed: March 12, 1992
    Date of Patent: September 21, 1993
    Assignee: Mita Industrial Co., Ltd.
    Inventors: Yasuyuki Hanatani, Hiroaki Iwasaki
  • Patent number: 5223364
    Abstract: The electrophotographic photoconductor of the present invention includes a conductive substrate and a photosensitive layer containing perylene pigment as a charge generating material formed on the conductive substrate. The X-ray diffraction peak of the perylene pigment exhibits its peak when the value of 2.theta. is 14.degree.(.+-.0.3.degree.), and the half-width of the peak when the value of 2.theta. is 14.degree. (.+-.0.3.degree.) is 0.5 or more. This electrophotographic photoconductor has excellent qualities of low residual potential and stabilized quality.
    Type: Grant
    Filed: July 2, 1991
    Date of Patent: June 29, 1993
    Assignee: Mita Industrial Co., Ltd.
    Inventors: Tatsuo Maeda, Eiichi Miyamoto, Nariaki Muto
  • Patent number: 5219693
    Abstract: Disclosed is a printing plate, for an electrophotographic process, which comprises an electroconductive support and a photosensitive layer formed on the electroconductive support, in which the photosensitive layer is formed by incorporating (a) a trisazo pigment represented by the general formula (I) and (b) at least one member selected from perynone pigments and anthanthrone pigments as photoconductive substances and (c) at least one electron donor substance as a sensitizer in an alkali-soluble binder resin. This printing plate has a high sensitivity and a printing image having a high quality is formed on the printing plate without contamination of the non-image area due to the electrophotography, and prints having a high-quality image can be obtained by using this printing plate.
    Type: Grant
    Filed: October 29, 1990
    Date of Patent: June 15, 1993
    Assignee: Iwatsu Electric Co., Ltd.
    Inventors: Akio Akao, Seiji Kuwakubo, Takao Soma, Takeo Kadoi
  • Patent number: 5168025
    Abstract: An electrophotographic photoreceptor comprising an electrically conductive support and a photosensitive layer formed thereon, wherein said photosensitive layer contains an arylamine compound of the formula (I): ##STR1## wherein each of Ar.sup.1 and Ar.sup.2 which may be the same or different, is an arylene group which may have substituents, each of R.sup.1, R.sup.2, R.sup.3 and R.sup.4 which may be the same or different, is an alkyl group which may have substituents, an aryl group which may have substituents, or a heterocyclic group which may have substituents, provided that R.sup.1 may, together with R.sup.2 or Ar.sup.1, form a ring containing the adjacent nitrogen atom, and R.sup.3 may, together with R.sup.4 or Ar.sup.2, form a ring containing the adjacent nitrogen atom, each of R.sup.5, R.sup.6, R.sup.7 and R.sup.
    Type: Grant
    Filed: September 11, 1991
    Date of Patent: December 1, 1992
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Hitoshi Ono, Atsuo Saita
  • Patent number: 5158850
    Abstract: An electrophotographic photoconductor comprising an electroconductive support and a photoconductive layer formed thereon comprising as an effective component at least one polyether compound represented by formula (I): ##STR1## wherein Ar represents a phenylene group or a biphenylene group; R.sup.1 and R.sup.2 each represent an alkyl group which may have a substituent, or an aryl group which may have a substituent; and n is an integer of 1 to 4. Furthermore, charge transporting material comprising the above polyether compound, polyether compounds having formula (II) for use in the electrophotographic photoconductor and a method of preparing the same are disclosed, ##STR2## wherein m is an integer of 1 or 2.
    Type: Grant
    Filed: December 13, 1990
    Date of Patent: October 27, 1992
    Assignee: Ricoh Company, Ltd.
    Inventors: Masaomi Sasaki, Tamotsu Aruga, Tomoyuki Shimada
  • Patent number: 5145759
    Abstract: An electrophotographic recording material comprising on an electrically conductive support a negatively chargeable photoconductive recording layer which contains in an electrically insulating organic polymer binder material at least one photoconductive n-type pigment substance and at least one p-type photoconductive charge transport substance as defined herein by a general formula (I) to (V), wherein said layer has a thickness in the range of 4 to 40 .mu.m and comprises 8 to 80% by weight of said n-type pigment substance and 0.01 to 40% by weight of said p-type charge transport substance that is molecularly distributed in said electrically insulating organic polymeric binder material that has a voluem resistivity of at least 10.sup.14 Ohm-m, and wherein said recording layer in electrostatically charged state requires for 10% and 90% discharge respectively exposures to conductivity increasing electromagnetic radiation that differ by a factor 4.5 or less.
    Type: Grant
    Filed: April 16, 1990
    Date of Patent: September 8, 1992
    Assignee: AGFA-Gevaert, N.V.
    Inventors: David R. Terrell, Stefaan K. De Meutter, Marcel J. Monbaliu
  • Patent number: 5139913
    Abstract: A photosensor having a photoconductive layer made of built-up monomelecular membranes containing a squarylium pigment represented by the formula (I): ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4, which may be the same or different, each represents an alkyl group.
    Type: Grant
    Filed: May 21, 1990
    Date of Patent: August 18, 1992
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Suk Kim, Makoto Furuki, Lyong S. Pu
  • Patent number: 5128227
    Abstract: An electrophotographic recording material which comprises an electrically conductive support having thereon a photoconductive layer containing one or more p-type photoconductive charge transport substances, characterized in that at least one of the p-type charge transport substances is a hydrazone compound corresponding to a general formula (I) to (V) as defined in the description, and the use of a said hydrazone compound in the charge transporting layer of a bilayer-system photoconductive material comprising a charge generating layer in contiguous relationship with said charge transporting layer.
    Type: Grant
    Filed: March 25, 1991
    Date of Patent: July 7, 1992
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Marcel J. Monbaliu, David R. Terrell, Stefaan K. De Meutter, Paul R. Callant
  • Patent number: 5112759
    Abstract: An electrophotographic photosensitive member comprises an electroconductive support and a photosensitive layer laid on the electroconductive support, the photosensitive layer containing a compound represented by the following general formula (1): ##STR1## wherein R in a substituted or unsubstituted aromatic group or heterocyclic group; X is substituted or unsubstituted benzenediyl, 2,3-pyridinediyl, 3,4-pyridinediyl or 2,3-pyrazinediyl; Y is an oxygen atom, a sulfur atom or a dicyanomethylene group, Z is an oxygen atom, a sulfur atom, a dicyanomethylene group or ##STR2## m is an integer of 1 2 or 3; and n is an integer of 0 or 1.
    Type: Grant
    Filed: March 30, 1990
    Date of Patent: May 12, 1992
    Assignee: Canon Kabushiki Kaisha
    Inventors: Akihiro Senoo, Kazushi Iuchi, Hajime Miyazaki, Shintetsu Go, Toshie Miyaji
  • Patent number: 5106713
    Abstract: The cyclized squaraines essentially as represented by the formula ##STR1## wherein R.sub.1 and R.sub.2 are independently selected from alkyl and hydrogen; R.sub.3 and R.sub.4 are independently selected from alkyl and benzyl; X is hydrogen, hydroxy, alkyl, alkoxy or halogen; and m is a number of from zero to about 3; and layered imaging members thereof.
    Type: Grant
    Filed: September 26, 1990
    Date of Patent: April 21, 1992
    Assignee: Xerox Corporation
    Inventor: Kock-Yee Law
  • Patent number: 5106712
    Abstract: A novel electrophotographic photoreceptor is provided comprising on an electrically conductive support a layer containing a charge carrier-transporting compound and a charge carrier-generating compound or a charge carrier-transporting compound-containing layer and a charge-generating compound-containing layer, characterized in that as said charge carrier-generating compound there is contained a novel bisazo compound represented by the general formula (1-A), (1-B) or (1-C):Cp--N.dbd.N--Ar.sup.1 --C.tbd.C--.sub.n Ar.sup.2 --N.dbd.N--Cp (1-A)wherein Ar.sup.1 and Ar.sup.2 each represents an arylene group, divalent condensed polycyclic aromatic group or divalent heterocyclic aromatic group; Cp represents a coupler residue; and n represents an integer 2 or 3;Cp--N.dbd.N--Ar.sup.1 --C.tbd.C--Ar.sup.2 --C.tbd.C--Ar.sup.3 --C.tbd.C--Ar.sup.4 --N.dbd.N--Cp (1-B)wherein Ar.sup.1, Ar.sup.2, Ar.sup.3 and Ar.sup.
    Type: Grant
    Filed: July 6, 1990
    Date of Patent: April 21, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Katsugi Kitatani, Naonori Makino, Satoshi Hoshi
  • Patent number: 5104758
    Abstract: An electrophotographic photoreceptor comprising an electrically conductive substrate having thereon a photosensitive layer is disclosed, wherein the photosensitive layer contains, as a charge generating material, a dispersion of selenium or a selenium alloy and at least one squarylium compound represented by formula (I): ##STR1## wherein A represents a fluorine atom, a hydrogen atom or a hydroxyl group, with B representing a hydroxyl group; or A represents a hydrogen atom or a fluorine atom, with B representing a methyl group, in the same binder resin. The electrophotographic photoreceptor not only has broad spectral sensitivity from the visible to infrared region but is excellent in other electrophotographic properties.
    Type: Grant
    Filed: May 11, 1990
    Date of Patent: April 14, 1992
    Assignee: Fuji Xerox Co, Ltd.
    Inventors: Kiyokazu Mashimo, Ryosaku Igarashi, Ichiro Takegawa, Yasuo Sakaguchi, Shigetoshi Nakamura, Kohichi Yamamoto
  • Patent number: 5093219
    Abstract: A novel electrophotographic photoreceptor is provided comprising a light-sensitive layer containing at least one of acetylene compounds represented by general formula (I) provided on an electrically conductive support:Ar.sup.1 C.tbd.C--AR.sup.3 --C.tbd.C--AR.sup.2 (I)wherein Ar.sup.1 and Ar.sup.2 each represents an aromatic carbon ring or aromatic heterocyclic group; and Ar.sup.3 represents an arylene group, divalent condensed polycyclic aromatic group or divalent aromatic heterocyclic group.
    Type: Grant
    Filed: August 17, 1990
    Date of Patent: March 3, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Naonori Makino, Satoshi Hoshi, Katsugi Kitatani
  • Patent number: 5061584
    Abstract: An electrophotographic photoreceptor comprising a support having thereon a photosensitive layer, in which said photosensitive layer contains a butadiene compound represented by the following general formula: ##STR1## wherein each of A.sub.1 -A.sub.4, which may be the same or different, is an alkyl group, a hydrazone compound represented by the following general formula [II]: ##STR2## wherein each of B.sub.1 and B.sub.2, which may be the same or different, is an alkyl group, a phenyl group, a benzyl group or a methoxyphenyl group, R.sub.1 is hydrogen, an alkyl group or O-R in which R is a straight-chain or branched alkyl, alkenyl or alkadienyl group having from 5 to 10 carbon atoms or an aralkyl group having from 7 to 10 carbon atoms, and R.sub.2 is an alkyl group, a phenyl group, a methoxy group, an ethoxy group, a benzyl group, a methoxyphenyl group, a tolyl group or a naphtyl group, and a monophenol compound.
    Type: Grant
    Filed: December 15, 1989
    Date of Patent: October 29, 1991
    Assignees: Shindengen Electric Manufacturing Co., Ltd, Yamanashi Electronics Co., Ltd.
    Inventors: Kenichi Fujimori, Yoshitaro Nakayama, Hajime Suzuki, Yoshiko Shima
  • Patent number: 5055615
    Abstract: Novel squarium compounds which have a flat photo-sensitivity in the wide range from the visible ray region to the near infrared ray region as a charge generator and which can be prepared by reacting squaric acid and an aniline derivative, and electrophotographic photoreceptors containing them are provided.
    Type: Grant
    Filed: August 17, 1988
    Date of Patent: October 8, 1991
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Seki Kin, Hiroyuki Tanaka, Satoshi Saeki, Kaoru Torikoshi, Lyong S. Pu
  • Patent number: 5047589
    Abstract: An electrophotographic light-sensitive material comprising a conductive support having formed thereon a light-sensitive layer containing a squarylium compound represented by formula (I) or (II) ##STR1## wherein R.sub.1 represents a hydrogen atom, a methyl group, a carboxy group, a halogen atom, a trifluoromethyl group, an alkyl or phenyl-substituted carbonamido group, or an alkyl- or phenyl-substituted sulfonamido group; X.sub.1 and X.sub.2 each represents a group shown by ##STR2## wherein Z represents an atomic group necessary for forming a ring and R.sub.2 and R.sub.3, each represents an alkyl group having from 1 to 20 carbon atoms, a phenyl group, an unsubstituted benzyl group, or a benzyl group substituted by at least one of an alkyl group having from 1 to 6 carbon atoms, a hydroxy group, an alkoxy group having from 1 to 4 carbon atoms, a halogen atom, a nitro group, a cyano group, an alkoxycarbonyl group having from 2 to 5 carbon atoms, and a trifluoromethyl group); and X.sub.
    Type: Grant
    Filed: December 2, 1988
    Date of Patent: September 10, 1991
    Assignee: Fuji Xerox Co. Ltd.
    Inventors: Yutaka Akasaki, Akihiko Tokida, Kaoru Torikoshi, Tooru Ishii, Hidemi Suto, Akira Imai
  • Patent number: 5024912
    Abstract: A 5H-dibenzo [a,d] cycloheptenylidene derivative and a 5H-dibenzo [1,d] cycloheptenylidene derivative represented by the following general formula [I]: ##STR1## wherein X is --CH.sub.2 --CH.sub.2 -- or --CH.dbd.CH--; R.sub.1 and R.sub.2 are alkyl groups, aralkyl groups, aromatic groups or heterocyclic groups, R.sub.3 and R.sub.4 are hydrogen atoms, alkyl groups, alkoxy groups or halogen atoms; and Ar.sub.1 is an aromatic group or a heterocyclic group, process for producing those derivatives, and electrophotographic photosensitive member using the same.
    Type: Grant
    Filed: May 10, 1989
    Date of Patent: June 18, 1991
    Assignee: Canon Kabushiki Kaisha
    Inventors: Toshie Neishi, Toshihiro Kikuchi, Takao Takiguchi, Koichi Suzuki, Masakazu Matsumoto
  • Patent number: 5019473
    Abstract: An electrophotographic recording element having a layer comprising a photoconductive perylene pigment, as a charge generation material, that is sufficiently finely and uniformly dispersed in a polymeric binder to provide the element with excellent electrophotographic speed. The perylene pigments are perylene-3,4,9,10-tetracarboxylic acid imide derivatives.
    Type: Grant
    Filed: February 23, 1990
    Date of Patent: May 28, 1991
    Assignee: Eastman Kodak Company
    Inventors: Khe C. Nguyen, William T. Gruenbaum
  • Patent number: 5004661
    Abstract: A process for the preparation of squaraines which comprises a cycloaddition, reductive alkylation and condensation reaction wherein there is reacted a nitroarylacetyl halide with a tetraalkoxy olefin, and a trialkylamine in a solvent; followed by the reaction of the resulting nitroaryl dione with hydrogen in the presence of an aldehyde and a catalyst in a solvent; and thereafter reacting the formed dialkylaminoaryl hydroxycyclobutene dione with N,N-dialkylaniline in an alcohol.
    Type: Grant
    Filed: May 30, 1989
    Date of Patent: April 2, 1991
    Assignee: Xerox Corporation
    Inventors: Kock-Yee Law, F. Courtney Bailey
  • Patent number: 4992350
    Abstract: An electrophotographic photoconductor is disclosed, which comprises an electroconductive support and a photoconductive layer formed thereon comprising as an effective component at least one biphenyl compound represented by the following formula (I): ##STR1## wherein R.sup.1 and R.sup.2 each represent an alkyl group which may have a substituent, an alkoxyl group which may have a substituent, or an aryl group which may have a substituent, provided that at least one of R.sup.1 and R.sup.2 represents an unsubstituted or substituted aryl group. Furthermore, charge transporting materials comprising the above biphenyl compound and novel biphenyl compounds having formula (II) for use in the electrophotographic photoconductor are disclosed.
    Type: Grant
    Filed: September 19, 1989
    Date of Patent: February 12, 1991
    Assignee: Ricoh Company, Ltd.
    Inventors: Masaomi Sasaki, Tamotsu Aruga, Tomoyuki Shimada
  • Patent number: 4988593
    Abstract: An electrophotographic photosensitive member having a photosensitive layer is formed on a support and contains an azo pigment expressed by a general formula [I] or [II]: ##STR1## where A, B.sub.1 and B.sub.2 are aromatic hydrocarbon nucleus groups or heterocyclic groups which may be optionally linked by coupler groups, A is an univalent group, B.sub.1 is an univalent, bivalent or trivalent group, and B.sub.2 is a bivalent or trivalent group; X is a residue necessary for forming a polycyclic aromatic nucleus or a heterocycle by condensation with a benzene nucleus; R is a halogen atom, an alkyl group or an alkoxy group; n.sub.1 is an integer from 1 to 3; and n.sub.2 is an integer from 1 to 3. This photosensitive layer may be composed of a charge generation layer containing the above azo pigment and a charge transport layer.
    Type: Grant
    Filed: September 20, 1989
    Date of Patent: January 29, 1991
    Assignee: Canon Kabushiki Kaisha
    Inventor: Hideyuki Takai
  • Patent number: 4983483
    Abstract: A photoreceptor comprising a conductive support, a charge generation layer coated on the conductive support and a charge transport layer coated on the charge generation layer wherein the charge generation layer comprises a polymer binder and an induced alpha-type charge generation material prepared by milling a mixture of a copper phthalocyanine pigment and a squarylium pigment.
    Type: Grant
    Filed: April 14, 1989
    Date of Patent: January 8, 1991
    Assignee: Industrial Technology Research Institute
    Inventor: Lii C. Tsai
  • Patent number: 4959290
    Abstract: Indenylidene compounds, which are useful not only as the photoconductive material for electrophotography, but also as a charge transporting material employed in a function-separating type photoconductor in which an organic or inorganic pigment is used as a charge generating material, and an electrophotographic photoconductor containing at least one of the above indenylidene compounds in a photoconductive layer thereof, are disclosed.
    Type: Grant
    Filed: December 8, 1988
    Date of Patent: September 25, 1990
    Assignee: Ricoh Company, Ltd.
    Inventors: Tamotsu Aruga, Masaomi Sasaki, Mitsuru Hashimoto