Donor-acceptor Complex Photoconductor Patents (Class 430/900)
  • Patent number: 4359512
    Abstract: Disclosed is a panchromatic photoconductive element for electrophotography having a layered structure comprising a substrate, a barrier layer and a photoconductive layer. The barrier layer inhibits injection of carriers from the substrate. Amorphous silicon forms a matrix for either the photoconductive layer or the barrier layer.
    Type: Grant
    Filed: March 5, 1981
    Date of Patent: November 16, 1982
    Assignee: Canon Kabushiki Kaisha
    Inventors: Tadaji Fukuda, Shigeru Shirai, Junichiro Kanbe
  • Patent number: 4357405
    Abstract: Organic electron donor compounds for use in electrophotographic constructions must ordinarily be sensitized to desired regions of the electromagnetic spectrum. Highly fluorinated aliphatic sulfonyl, carbonyl, or carbonyloxy dyes have been found to be efficient sensitizers for such organic donor compounds.
    Type: Grant
    Filed: February 23, 1981
    Date of Patent: November 2, 1982
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Louis M. Leichter, John J. Stofko, Jr., Terry J. Sonnonstine
  • Patent number: 4352876
    Abstract: A complex type electrophotographic plate comprising an electroconductive support and a charge generating layer and a charge transport layer characterized in that the charge generating layer contains at least a copper phthalocyanine and the charge transport layer contains at least a trinitrofluorenone, has excellent photosensitivity and adhesion to the support.
    Type: Grant
    Filed: September 12, 1980
    Date of Patent: October 5, 1982
    Assignee: Hitachi, Ltd.
    Inventors: Shigeo Suzuki, Atsushi Kakuta, Hiroyuki Oka, Yasuki Mori, Hirosada Morishita
  • Patent number: 4346157
    Abstract: A complex type electrophotographic plate comprises a conductive support; a first layer, adhered to the support, of a charge generating material, said first layer having a thickness of 0.1 to 5 .mu.m; and a second layer, superposed on the first layer, of a homogeneous mixture of a charge transport material and an insulating, resinous binder therefor, said second layer having a thickness of 5 to 100 .mu.m and being substantially transparent to light of a wave length of 4200 to 8000 A; wherein said charge transport material is at least one member selected from the class consisting of nonionic compounds represented by the general formula: X--(CH.dbd.CH).sub.n Ar where X is a heterocyclic group selected from the group consisting of ##STR1## and Y is O or S, R is a lower alkyl group; the hetero ring may be substituted; n is an integer of 0, 1 or 2; and Ar is an aryl or substituted aryl group.The electrophotographic plate has a high light sensitivity and can be used in more than 10.sup.3 repetitions without fatigue.
    Type: Grant
    Filed: February 9, 1981
    Date of Patent: August 24, 1982
    Assignee: Hitachi, Ltd.
    Inventors: Atsushi Kakuta, Shigeo Suzuki, Yasuki Mori, Hirosada Morishita
  • Patent number: 4341852
    Abstract: Polycyanoanthracenes containing three or more cyano groups, and in particular the novel compound 2,6,9,10-tetracyanoanthracene, are sensitizers for organic photoconductors.
    Type: Grant
    Filed: October 2, 1980
    Date of Patent: July 27, 1982
    Assignee: Eastman Kodak Company
    Inventors: Susan L. Mattes, Samir Y. Farid
  • Patent number: 4334000
    Abstract: Dual layer organic photoconductive elements which are stable, have good negative charge acceptance and are sensitive over a broad range of the spectrum, including near the infrared band, and the process for preparing same. The charge-generating layer comprises a mixture of a charge-generating diane dye, such as Chlorodiane Blue, and a cyanine dye as a near-infrared sensitizer.
    Type: Grant
    Filed: December 19, 1980
    Date of Patent: June 8, 1982
    Assignee: Pitney Bowes Inc.
    Inventors: Mike S. H. Chang, John T. Donoghue, Peter G. Edelman
  • Patent number: 4329416
    Abstract: A method for preparing an electrophotographic element wherein in the formation of a co-crystalline complex photosensitive layer a conducting substrate or another photosensitive layer is over-coated with a solution consisting essentially of a pyrylium dye and an electric insulating polymer and dried at least two times respectively.
    Type: Grant
    Filed: September 4, 1980
    Date of Patent: May 11, 1982
    Assignee: Ricoh Co., Ltd.
    Inventors: Kiyoshi Tanikawa, Masao Yoshikawa, Tsutomu Sato
  • Patent number: 4329284
    Abstract: 1,2-oxachalcogenol-1-ium salts are presented. A novel method for making the salts is also presented. The salts are useful in improving the quantum efficiency of organic photoconductive compositions containing organic donor compounds having photoconductive properties.
    Type: Grant
    Filed: January 19, 1981
    Date of Patent: May 11, 1982
    Assignee: Eastman Kodak Company
    Inventors: Michael R. Detty, Thomas E. Goliber, Bruce J. Murray, Jerome H. Perlstein
  • Patent number: 4315980
    Abstract: An electrophotographic member in which a photoconductive layer and a protective layer are superposed in order on a photoconductive support, wherein the improvement comprises:said protective layer containing at least one metallocene or a compound having at least one metallocene nucleus in its molecular structure.
    Type: Grant
    Filed: April 4, 1980
    Date of Patent: February 16, 1982
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Shigeru Sadamatsu, Kohichi Yamamoto, Kazuaki Ohmi
  • Patent number: 4315981
    Abstract: This invention relates to an electrophotographic recording material consisting of an electroconductive support material and a photoconductive double layer of organic materials which consists of a homogeneous, opaque, charge carrier producing dyestuff layer from a more annealed quinone or the substitution product thereof, selected from the group consisting of dibenzopyrene quinone, anthanthrone, pyranthrone, dibenzanthrone, and flavanthrone, possible substituents being halogen, nitro, amino, hydroxy, alkoxy, mercapto or alkyl mercapto groups, and of a transparent top layer of insulating materials with at least one charge transporting compound.
    Type: Grant
    Filed: March 2, 1978
    Date of Patent: February 16, 1982
    Assignee: Hoechst Aktiengesellschaft
    Inventor: Wolfgang Wiedemann
  • Patent number: 4286036
    Abstract: For reversal development of an electrical potential pattern formed by imagewise exposure of a uniformly charged photoconductive layer, the charging of the layer is restricted to such a level below its breakdown voltage that the contact between the photoconductive layer and the toner powder used in the development step is insulating, and a magnetisable and inductively attractable toner powder is applied for the development. The toner powder is applied by means of a magnetic brush device comprising a conductive development roller which is provided with an electrical potential suited for reversal development. Preferably the photoconductive layer is charged to a level of at most 35-75% of its breakdown voltage, and a scorotron preferably is used for the charging. The photoconductive layer may comprise a photoconductive polymer and/or a bisazo pigment as photosensitive compound, or may be a layer of "pink" zinc oxide dispersed in a binder.
    Type: Grant
    Filed: April 3, 1980
    Date of Patent: August 25, 1981
    Assignee: Oce-Nederland B.V.
    Inventor: Roelof R. Hendriksma
  • Patent number: 4281053
    Abstract: A photoconductive laminate and its use are disclosed, the laminate comprising two layers of compounds, each layer being a single phase and at least one of the compounds having a generally planar polycyclic nucleus.
    Type: Grant
    Filed: February 7, 1980
    Date of Patent: July 28, 1981
    Assignee: Eastman Kodak Company
    Inventor: Ching W. Tang
  • Patent number: 4264695
    Abstract: A photosensitive material for use in electrophotography which comprises a conductive support, a first layer consisting essentially of a substance capable of generating a conductive carrier through light absorption and an electron donor or an electron acceptor, and a second layer consisting essentially of an electron acceptor or an electron donor, to wit, a substance constituting the opposite party of the electron donor or the electron acceptor contained in the first layer, said first and second layers being formed in that order on said conductive support.
    Type: Grant
    Filed: January 28, 1980
    Date of Patent: April 28, 1981
    Assignee: Ricoh Co., Ltd.
    Inventors: Akio Kozima, Mitsuru Hashimoto, Masafumi Ohta, Masaomi Sasaki, Zenjiro Okuno
  • Patent number: 4245021
    Abstract: An electrophotographic element according to the present invention exhibits an exceedingly high sensitivity and it comprises (1) an electroconductive support, a charge producing layer consisting essentially of a charge producing substance and a charge transport layer consisting essentially of a charge transport substance having the following general formula and a binder, the last-mentioned two layers being superposed in that order or vice versa on said support, or (2) an electroconductive support and a photosensitive layer, superposed thereon, and consisting essentially of a charge producing substance, a charge transport substance having said general formula and a binder: ##STR1## (wherein n is an integer of 1 or 2, R.sub.1 stands for hydrogen atom or an alkyl, nitro, dialkylamino, alkoxy, nitrile or carboxylic ester group, and R.sub.2 and R.sub.3 stand for hydrogen or halogen atom or nitro or dialkylamino group respectively).
    Type: Grant
    Filed: February 12, 1979
    Date of Patent: January 13, 1981
    Assignee: Ricoh Co., Ltd.
    Inventors: Takeo Kazami, Kiyoshi Sakai, Mitsuru Hashimoto, Masaomi Sasaki, Kyoji Tsutsui, Masafumi Ohta
  • Patent number: 4226967
    Abstract: An electron acceptor polycondensation polymer of the formula (I) ##STR1## wherein R.sub.1 is a hydrogen atom or an alkyl group, an aryl group or an aralkyl group having not more than 15 carbon atoms; C.sub.m is a divalent connecting group; FLac is an electron acceptor group having a fluorene nucleus as its basic structure; X and Y are a carbonyl group or an acid amide group forming a urethane linkage with the oxygen atom of the diol; R.sub.2 is a bifunctional organic residue having not more than 20 carbon atoms, n is a number greater than 10 which represents the degree of polycondensation of the resultant polycondensation polymer.
    Type: Grant
    Filed: April 30, 1979
    Date of Patent: October 7, 1980
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Shigeo Tazuke, Hajime Nagahara