Thermal Imaging Composition Patents (Class 430/964)
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Patent number: 5242889Abstract: A thermally-transferred color filter array element comprising a support having thereon a polymeric dye image-receiving layer containing a thermally-transferred image comprising a repeating pattern of colorants of an arylidene blue dye having the formula: ##STR1## wherein: R.sup.1 and R.sup.2 each independently represents hydrogen, a substituted or unsubstituted alkyl group having from 1 to about 8 carbon atoms, a cycloalkyl group having from about 5 to about 8 carbon atoms, a substituted or unsubstituted alkenyl group having from about 2 to about 8 carbon atoms, or a substituted or unsubstituted aralkyl group having from about 7 to about 14 carbon atoms;R.sup.3 represents hydrogen, a substituted or unsubstituted alkyl or alkoxy group having from 1 to about 8 carbon atoms, halogen, or a fused aryl ring;or R.sup.2 and R.sup.3 may represent the elements which may be taken together to form a 5- or 6-membered heterocyclic ring;X represents hydrogen, fluorine, chlorine or bromine; andn is 1 to 4.Type: GrantFiled: November 24, 1992Date of Patent: September 7, 1993Assignee: Eastman Kodak CompanyInventors: Leslie Shuttleworth, Helmut Weber
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Patent number: 5242784Abstract: An optical phase change media comprises a substrate, an active layer having a crystalline and a liquid state, a dielectric layer and a reflective layer. The active layer is of a thickness which will transmit incident light. The dielectric layer is of a thickness such that light passing through the active layer is reflected by the reflective layer and destructively interferes with the incident light reflected directly off of the active layer, thereby causing the crystalline state of the active layer to absorb more light than the liquid state. The result is that the media experiences reduced temperature during writing.Type: GrantFiled: June 22, 1992Date of Patent: September 7, 1993Assignee: International Business Machines CorporationInventors: Martin Y. Chen, Kurt A. Rubin
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Patent number: 5234798Abstract: Structures for items such as promotional materials, game pieces, lottery tickets, security documents and other articles, which feature one or more thermal reactive layers that are activated by heat from a hidden image formed of infrared sensitive, heat generating material such as carbon black preprinted under the thermal reactive layers during manufacture. The thermal reactive layers permit transmission of radiant energy such as infrared to the heat generating, hidden layers. The heated image conducts heat to the thermal reactive layers which employ a coloring agent and a developer which, when exposed to the heat, react or act in concert in order to form a corresponding image on the face of the item.Type: GrantFiled: October 4, 1991Date of Patent: August 10, 1993Assignee: Dittler Brothers, IncorporatedInventors: Byrne E. Heninger, Donna C. Stimpson, Stephen M. Ems
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Patent number: 5230970Abstract: A process of radiation-induced formation of a uniform metal or metal oxide region suitable for device application or for repairing transparent defects in pattern metal films of lithographic masks has been found. The process requires that the heat evolved during the radiation-induced reactions be carefully limited to produce the desired uniformity.Type: GrantFiled: May 28, 1992Date of Patent: July 27, 1993Assignee: AT&T Bell LaboratoriesInventors: Donald K. Atwood, Georgia J. Fisanick, Michal E. Gross, Abraham Katzir, Gary L. Wolk
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Patent number: 5227277Abstract: An imaging medium comprises a layer, depolymerizable by exposure to actinic radiation and substantially non-tacky prior to depolymerization but becoming tacky upon at least partial depolymerization, disposed adjacent a layer of an imaging material, which has a cohesive strength greater than the adhesive strength between the imaging material and the depolymerizable layer prior to depolymerization. This medium is imagewise exposed to radiation, thereby causing at least partial depolymerization of the polymer in the exposed areas, so rendering these exposed areas tacky and firmly attaching exposed areas of the imaging material layer to the depolymerizable layer. The unexposed areas of the imaging material are then removed from the depolymerizable layer.Type: GrantFiled: April 17, 1991Date of Patent: July 13, 1993Assignee: Polaroid CorporationInventor: Kenneth C. Waterman
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Patent number: 5225314Abstract: An imaging medium comprises a layer, depolymerizable by exposure to actinic radiation and undergoing a reduction in cohesivity upon at least partial depolymerization, disposed adjacent a layer of an imaging material, which has a cohesive strength greater than the cohesive strength of the depolymerizable layer after depolymerization. This medium is imagewise exposed to radiation, thereby causing at least partial depolymerization of the polymer in the exposed areas, so rendering these exposed areas lower in cohesivity than the unexposed areas. The exposed areas of the imaging material are then removed from the depolymerizable layer.Type: GrantFiled: April 17, 1991Date of Patent: July 6, 1993Assignee: Polaroid CorporationInventors: Kenneth C. Waterman, Michael A. Young, Edward P. Lindholm
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Patent number: 5223371Abstract: A thermal developing type photosensitive pressure sensitive recording medium records an image and transfers the image onto an image receiving medium. The image recording medium includes a substrate, microcapsules and binder. The microcapsules are formed on the substrate, and encapsulate therein dye and polymerizable compound. A latent image is formed in a combination of the microcapsules by changing mechanical strength thereof upon photopolymerization of the polymerizable compound for forming cured and non-cured microcapsules. The dye flows out of the non-cured microcapsules and is transferred onto an image receiving layer by rupturing the non-cured microcapsules upon pressure application. The binder fixes the microcapsules onto the substrate. The binder contains a pressure sensitive adhesive agent.Type: GrantFiled: May 21, 1992Date of Patent: June 29, 1993Assignee: Brother Kogyo Kabushiki KaishaInventor: Mitsuru Ohta
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Patent number: 5219706Abstract: There are disclosed a novel naphthalocyanine derivative represented by the general formula [I] or [II] shown below, a process for preparing said derivative, an optical information recording medium using said derivative, and a process for preparing thereof: ##STR1## wherein M is a metal, metal oxide, metal hydroxide and the like, R.sup.1 is an alkyl group of 1-22 carbon atoms, n is an integer of 1 to 4, and Y.sub.1 and Y.sub.2 aryloxy group and the like.Type: GrantFiled: January 21, 1992Date of Patent: June 15, 1993Assignee: Hitachi, Ltd.Inventors: Seiji Tai, Shigeru Hayashida, Nobuyuki Hayashi, Yasushi Iwakabe, Shunichi Numata, Noriyuki Kinjo, Susumu Era, Setsuo Kobayashi, Akio Mukoh, Yoshio Sato
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Patent number: 5217844Abstract: An optical recording medium includes a silver grain layer containing a large number of blackened fine silver grains and a coloring matter layer containing coloring matter on a base board and the coloring matter has an ability of absorbing near-infrared ray. When laser beam having a density of optical energy more than a boundary which represents a threshold with respect to the density of optical energy is radiated to the optical recording medium, a part of the latter is deformed to form a plurality of convexities which will be utilized as optical recording pit. The recording pits formed in this way are detected by presence or absence of reflection of radiated light whereby the content of optical recorded informations can be read. The optical recording pits are not deformed further irrespective of how long a reading light comprising laser beam having a density of energy less than the threshold is repeatedly radiated to the optical pits.Type: GrantFiled: November 8, 1989Date of Patent: June 8, 1993Assignee: Kyodo Printing Co., Ltd.Inventors: Yoichi Fukushima, Minoru Fujita, Yuji Kakinuma
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Patent number: 5215869Abstract: This invention relates to the preparation of a supported modulating film having a permanent yellow imaged layer of the homopolymer of 10,12-docosadiyndioic acid monomer; said monomer having the structure ##STR1## and to the use of said film as a blue light modulator in the production of master printing plates or printed circuit boards.Type: GrantFiled: April 2, 1992Date of Patent: June 1, 1993Assignee: ISP Investments Inc.Inventor: Kou-Chang Liu
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Patent number: 5215870Abstract: This invention relates to the preparation of a supported modulating film having a permanent yellow imaged layer of the homopolymer of a crystalline diacetylene cinnamate monomer ##STR1## and to the use of said film as a light modulator in the production of master printing plates or printed circuit boards.Type: GrantFiled: May 6, 1992Date of Patent: June 1, 1993Assignee: ISP Investments Inc.Inventors: Kou-Chang Liu, David F. Lewis, John C. Hornby
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Patent number: 5213939Abstract: A light- and heat-sensitive recording material is disclosed which includes a support having thereon a recording layer containing a diazo compound, a coupling component, and an organic base compound, wherein the diazo compound is a 1-substituted amino-3-alkoxybenzene-4-diazonium salt and the coupling component is a compound prepared from any of cyclohexane-1,3-dione, 3-cyclohexenone, or 2-cyclohexenone. The light- and heat-sensitive recording material according to the present invention can develop an excellent magenta color hue and has excellent storage properties before recording use (shelf life).Type: GrantFiled: September 23, 1991Date of Patent: May 25, 1993Assignee: Fuji Photo Film Co., Ltd.Inventors: Takekatsu Sugiyama, Sadao Ishige, Naoto Yanagihara, Hiroshi Kamikawa, Keiichi Tateishi
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Patent number: 5198321Abstract: A method for forming an image is described which includes bringing a transparent heat-sensitive recording material including a transparent support made of a synthetic polymer having thereon a transparent heat-sensitive recording layer into contact with a light-absorbing material, at least at the time of effecting recording, and irradiating the light-absorbing material with a laser beam to heat the transparent heat-sensitive recording layer and to cause color formation therein. High speed, high density, and high quality recording can be performed with an increased light absorption efficiency.Type: GrantFiled: October 3, 1991Date of Patent: March 30, 1993Assignee: Fuji Photo Film Co., Ltd.Inventors: Noriyuki Hosoi, Kotaro Nakamura
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Patent number: 5196297Abstract: This invention relates to novel recording materials which employ color-forming di- and triarylmethane compounds possessing certain S-containing ring-closing moieties, namely, or thiolactone, dithiolactone or thioether ring-closing moiety and to a method of forming color by contacting these dye precursor compounds with a Lewis acid material capable of opening the thiolactone, dithiolactone or thioether ring-closing moiety whereby the compound is rendered colored, that is, converted to its chromophore color.Type: GrantFiled: December 5, 1986Date of Patent: March 23, 1993Assignee: Polaroid CorporationInventors: Edward J. Dombrowski, Jr., James R. Freedman, Patrick F. King
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Patent number: 5192645Abstract: A thermal imaging method for forming color images is provided which employs as the color image-forming material, a colorless precursor of a preformed image dye possessing at least one thermal protecting group that undergoes fragmentation upon heating and at least one leaving group that undergoes irreversible elimination upon heating, said protecting and leaving groups maintaining the precursor in its colorless form until heat is applied to effect removal of these groups whereby the precursor is converted to an image dye.Type: GrantFiled: July 12, 1991Date of Patent: March 9, 1993Assignee: Polaroid CorporationInventors: Roger A. Boggs, Alan L. Borror, Patrick R. Conlon, Richard L. Cournoyer, Ernest W. Ellis, David P. Waller
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Patent number: 5188923Abstract: An optical storage medium for storing binary data adapted to be written upon by a laser forming an array of encoded spots is composed of a substrate possibly covered with a mirror layer and including a matrix of a transparent dielectric material such as a polymer upon which a vacuum deposited discontinuous film of nucleated metallic islands is deposited having thicknesses of less than about 100 .ANG.. The particles extend up to 1000 .ANG. transversely generally parallel to the surface of said substrate. The islands are separated by a short distance for facilitating coalescence of particles together to effect writing of spots at low energy by the lateral motion and gathering of the islands during heating of the islands by a laser beam or the like. Each spot represents a data bit in a binary position code. The matrix material has low thermal conductivity and preferably a low melting point to facilitate writing at low energy.Type: GrantFiled: March 12, 1990Date of Patent: February 23, 1993Assignee: International Business Machines CorporationInventors: Kie Y. Ahn, Harold N. Lynt, Jr., Victor B. Jipson
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Patent number: 5180652Abstract: A light- and heat-sensitive composition which contains a photo-hardenable composition and at least one dye, a light- and heat-sensitive recording material which contains a support having the composition provided on at least one side thereof, and an image-forming process using the recording material are disclosed.Type: GrantFiled: January 18, 1990Date of Patent: January 19, 1993Assignee: Fuji Photo Film Co., Ltd.Inventors: Jun Yamaguchi, Sadao Ishige, Kozo Sato, Shintaro Washizu, Isamu Itoh
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Patent number: 5178990Abstract: A method of identifying the output energy, main wavelength, position, pattern, etc., of light, which comprises irradiating a photosensitive coloring medium comprising a base material, a heat-sensitive coloring material, and a light absorptive material releasing heat sufficient for coloring the heat-sensitive coloring material by absorbing the light and identifying the output energy, main wavelength, position, pattern, etc., of the light from the colored extent thereof.Type: GrantFiled: August 9, 1990Date of Patent: January 12, 1993Assignee: Jujo Paper Co., Ltd.Inventors: Toshimi Satake, Tomoaki Nagai, Hiroshi Fukui, Miyuki Yokoyama, Akio Sekine
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Patent number: 5175069Abstract: A thermally-transferred color filter array element comprising a support having thereon a polymeric dye image-receiving layer containing a thermally-transferred image comprising a repeating pattern of colorants of a maleimide blue dye having the formula: ##STR1## wherein: R.sup.1 and R.sup.2 each independently represents hydrogen; a substituted or unsubstituted alkyl group having from 1 to about 8 carbon atoms; a cycloalkyl group having from about 5 to about 8 carbon atoms; or a substituted or unsubstituted alkenyl group having from about 2 to about 8 carbon atoms;R.sup.1 and R.sup.2 may represent the elements which may be taken together to form a 5- or 6-membered heterocyclic ring;each Y independently represents hydrogen; a substituted or unsubstituted alkyl group having from 1 to about 8 carbon atoms; an alkoxy group OR.sup.Type: GrantFiled: June 14, 1991Date of Patent: December 29, 1992Assignee: Eastman Kodak CompanyInventors: Leslie Shuttleworth, Helmut Weber
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Patent number: 5175081Abstract: The post-processing stability of silver halide photothermographic emulsions is enhanced by the presence of stabilizing amounts of certain azlactones.Type: GrantFiled: May 6, 1992Date of Patent: December 29, 1992Assignee: Minnesota Mining and Manufacturing CompanyInventors: Larry R. Krepski, Kumars Sakizadeh, Sharon M. Simpson, David R. Whitcomb
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Patent number: 5171650Abstract: A unique method/system for simultaneously creating and transferring a contrasting pattern of intelligence on and from a composite ablation-transfer imaging medium to a receptor element in contiguous registration therewith is improvedly radiation sensitive and versatile, is kinetically rapid and not dependent on a sensitized ablative topcoat, and is well adopted for such applications as, e.g.Type: GrantFiled: May 29, 1991Date of Patent: December 15, 1992Assignee: Graphics Technology International, Inc.Inventors: Ernest W. Ellis, Diane M. Foley, Dana R. Arnold
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Patent number: 5158862Abstract: This invention relates to the preparation of a supported modulating film having a permanent orange yellow imaged layer of the homopolymer of crystralline 5,7-dodecadiyn-1,12-bis(isopropyl carbamate) monomer having the structure ##STR1## and to the use of said film as a blue light modulator in the production of master printing plates or printed circuit boards.Type: GrantFiled: February 3, 1992Date of Patent: October 27, 1992Assignee: ISP Investments Inc.Inventor: Kou-Chang Liu
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Patent number: 5158866Abstract: The post-processing stability of silver halide photothermographic emulsions is enhanced by the presence of stabilizing amounts of certain structurally defined amido compounds.Type: GrantFiled: August 31, 1990Date of Patent: October 27, 1992Assignee: Minnesota Mining and Manufacturing CompanyInventors: Sharon M. Simpson, Larry R. Krepski, Kumars Sakizadeh, David R. Whitcomb
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Patent number: 5153106Abstract: The invention relates to a process for direct and permanent photopositive scribing on a thermochromic coating composition consisting essentially of certain thermosensitive aryl diacetylenes which contain a moiety selected from the group of sulfonyl, amino, urethanyl, carboxylate and nitro radicals, and a dye capable of absorbing radiation energy generated by a laser in a wavelength of from about 600 to about 1,500 nm and to the coating composition comprising said aryl diacetylene and energy absorbing dye.Type: GrantFiled: March 11, 1991Date of Patent: October 6, 1992Assignee: ISP Investments Inc.Inventor: Kou-Chang Liu
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Patent number: 5149616Abstract: This invention relates to the preparation of a supported modulating film having a permanent orange yellow imaged layer of the homopolymer of crystalline 5,7-dodecadiyn-1,12-bis(isopropyl carbamate) monomer having the structure ##STR1## and to the use of said film as a blue light modulator in the production of master printing plates or printed circuit boards.Type: GrantFiled: October 23, 1990Date of Patent: September 22, 1992Assignee: ISP Investments Inc.Inventor: Kou-Chang Liu
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Patent number: 5135842Abstract: A thermal-dye-bleach construction comprising a thermal nucleophile-generating agent in association with a polymethine dye having a nucleus of general formula (I): ##STR1## in which: n is 0, 1, 2 or 3;R.sup.1 and R.sup.4 are independently selected from the group consisting of hydrogen atoms, optionally substituted alkyl groups of up to 30 carbon atoms, optionally substituted alkenyl groups of up to 30 carbon atoms and optionally substituted aryl groups of up to 14 carbon atoms; andR.sup.1 and R.sup.2 together and/or R.sup.3 and R.sup.4 together may represent the necessary atoms to complete a 5 or 6-membered optionally substituted heterocyclic ring; orone or more of R.sup.1 to R.sup.4 may represent the necessary atoms to complete an optionally substituted 5 or 6-membered heterocyclic ring fused to the phenyl ring on which the NR.sup.1 R.sup.2 or NR.sup.3 R.sup.4 group is attached;R.sup.5 and R.sup.Type: GrantFiled: May 29, 1990Date of Patent: August 4, 1992Assignee: Minnesota Mining and Manufacturing CompanyInventors: Jonathan P. Kitchin, Mark P. Kirk, Dian E. Stevenson, Randall H. Helland
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Patent number: 5104767Abstract: A method of forming an image is disclosed comprising irradiating a heat-sensitive recording material with a laser beam, wherein the heat-sensitive recording material includes a support having provided thereon a light-absorbing layer containing microcapsules which encapsulate a core substance containing carbon black and a binder, and tranferring a latent image thus formed on the light-absorbing layer, in accordance with the pattern and amount of the laser beam irradiation, to an image-receiving film under pressure to thereby obtain a visible image on the image-receiving film.Type: GrantFiled: September 27, 1990Date of Patent: April 14, 1992Assignee: Fuji Photo Film Co., Ltd.Inventor: Kotaro Nakamura
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Patent number: 5073472Abstract: A light-sensitive material comprising a light-sensitive layer provided on a support wherein the light-sensitive layer contains a reducing agent, at least two microcapsules (i) and (II), each of the microcapsules (I) and (II) independently containing silver halide, a polymerizable compound and a color image forming substance, and the microcapsules differing from each other with respect to at least one of the silver halide, the polymerizable compound and the color image forming substance.Type: GrantFiled: December 5, 1988Date of Patent: December 17, 1991Assignee: Fuji Photo Film Co., Ltd.Inventor: Soichiro Yamamoto
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Patent number: 5064743Abstract: A thermal transfer recording medium having a support and provided thereon, plural heat softening layers is disclosed.Type: GrantFiled: May 15, 1989Date of Patent: November 12, 1991Assignee: Konica CorporationInventors: Kunihiro Koshizuka, Toshiaki Tezuka, Takao Abe
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Patent number: 5049472Abstract: A method of and an apparatus for recording an image on a recording medium. A heat-sensitive sheet having a light-transmissive base sheet provided with a heat-fusible supercooled substance layer is made to abut a copy original such that the heat-fusible supercooled substance layer faces the original image to be copied while flashlight is projected onto the base sheet of the heat-sensitive sheet. Thus, the image portion of the copy original to be copied absorbs the light transmitted through the heat-sensitive sheet and thereby generates heat so that an adhesive area containing a pattern corresponding to the original image is formed on the supercooled substance layer. After the heat-sensitive sheet has been removed from the copy original, such an adhesive area is transferred to the recording medium owing to the adhesiveness of the adhesive area.Type: GrantFiled: October 27, 1989Date of Patent: September 17, 1991Assignee: Canon Kabushiki KaishaInventors: Nagao Hosono, Yukio Nagase, Tatsuo Takeuchi, Hiroshi Satomura, Hidemi Egami, Yuji Sakemi, Yasushi Miura
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Patent number: 5034313Abstract: A particulate metastable Group Ib metal colloid is prepared is formed by plating a Group Ib metal onto small nuclei in a suspension to form non-spherical particles of varying color. The preparation is stable below about 100.degree. C., but when coated onto a support, can be used to form a visible image by application of thermal energy.Type: GrantFiled: April 28, 1989Date of Patent: July 23, 1991Assignee: Eastman Kodak CompanyInventor: David C. Shuman
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Patent number: 5034292Abstract: A method of forming visible images on a differentiated background comprises the application of thermal energy to a coating of metastable metal colloid on a support. Thermal energy is able to convert the metastable metal colloid to a stable spheroidal form. Computer control of a laser beam or thermal print head can be employed to provide highly resolved images carrying graphic, digital and textural information.Type: GrantFiled: March 13, 1990Date of Patent: July 23, 1991Assignee: Eastman Kodak CompanyInventors: Hugh S. A. Gilmour, David C. Shuman
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Patent number: 5028523Abstract: Radiation sensitive thermally developable imaging elements comprise:a) photosensitive silver halide,b) light insensitive silver salt oxidizing agent,c) reducing agent for silver ions, andd) an antifoggant or speed enhancing compound comprising hydrobromic acid salts of nitrogen-containing heterocyclic ring compounds which are further associated with a pair of bromine atoms. The antifoggants are effective in reducing spurious background image densities.Type: GrantFiled: June 4, 1990Date of Patent: July 2, 1991Assignee: Minnesota Mining and Manufacturing CompanyInventor: Paul G. Skoug
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Patent number: 5006863Abstract: A heat sensitive copy system uses a magnetic thermal transfer ribbon to transfer images onto an adjacent medium and near infra-red energy is used to transfer the images from the medium onto thermal paper or onto translucent paper for producing multiple copies in a manner which is not thickness sensitive.Type: GrantFiled: February 8, 1989Date of Patent: April 9, 1991Assignee: NCR CorporationInventor: Shashi G. Talvalkar
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Patent number: 5004660Abstract: The master disc contains a substrate plate which is preferably provided with an optically detectable guide track and a recording layer of polysulphone such as poly(1-butene sulphone) to which, preferably, a colorant is added and in which an optically readable information track is provided by patterned exposure, a pit or groove being formed in the polysulphone layer. A matrix is formed by applying a metal layer to the polysulphone layer by means of an electroless deposition process and then, applying a further metal layer by means of an electrodeposition process or applying a curable synthetic resin layer together with a metal disc, after which the synthetic resin is made to cure.Type: GrantFiled: October 17, 1989Date of Patent: April 2, 1991Assignee: U.S. Philips CorporationInventors: Maarten A. Van Andel, Johannes P. J. G. Van Liempd, Josephus M. Wijn
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Patent number: 4997744Abstract: Provided is a process and solvent solution for coating an aza-annulene chromophore containing film directly onto a polycarbonate or polymethylmethacrylate comprising base. In the process, a solution of the chromophore, e.g., phthalocyanine, porphyrin or naphthalocynine, is cast directly onto the polycarbonate or polymethylmethacrylate base, with the solvent used in formulating the solution comprising a C.sub.5 -C.sub.7 cyclic alcohol, or a mixture of solvents including at least one of the aforementioned alcohols. The solvent is then removed, preferably by evaporation, in order to yield a smooth, homogeneous chromophore containing film directly on the polycarbonate or polymethylmethacrylate comprising base.Type: GrantFiled: December 21, 1988Date of Patent: March 5, 1991Assignee: Hoechst Celanese Corp.Inventors: Palaiyur S. Kalyanaraman, David E. Nikles
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Patent number: 4971896Abstract: A method of forming a thin film pattern on a base having a step portion. This method comprises a first step of forming a thin film of given material on the base, a second step of forming a predetermined pattern of a first photoresist film on said thin film at one of a first portion including a lower part of the step portion and a second portion including an upper part of the step portion, a third step of forming a predetermined pattern of a second photoresist film on said thin film at the other of the first and second portions and a fourth step of applying ion-milling to said thin film of given material using masks said first and second photoresist film patterns formed on said thin film at the first and second portions.Type: GrantFiled: December 7, 1988Date of Patent: November 20, 1990Assignee: Hitachi, Ltd.Inventors: Takashi Kawabe, Ataru Kobayashi, Moriaki Fuyama, Makoto Morijiri, Eiji Ashida, Masatoshi Tsuchiya, Tetsuya Okai, Masanobu Hanazono, Shinichi Hara, Shinji Narishige, Hiroshi Ikeda
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Patent number: 4963458Abstract: A light-sensitive image forming method using a recording element which comprises a recording layer on a support is disclosed. The recording layer contains at least two active components of a photopolymerizable composition such as a polymerizable compound and a polymerization initiator, both of which are essential for a photopolymerization reaction. The components are separated from each other by the shell of microcapsules in such manner that at least one component is contained in the microcapsules which are dispersed in the recording layer and the other component is arranged outside of the microcapsule. The image forming method comprises the steps of: heating the recording element to form the photopolymerizable composition in the recording layer; and imagewise exposing to light the recording element to imagewise polymerize the photopolymerizable composition.Type: GrantFiled: September 6, 1988Date of Patent: October 16, 1990Assignee: Fuji Photo Film Co., Ltd.Inventors: Shunichi Ishikawa, Fumiaki Shinozaki
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Patent number: 4960679Abstract: An image forming device is provided which comprises an image forming layer containing molecules of an organic compound capable of phase transition, and functional molecules such as those of a photochromic compound. An image forming process is also provided which employs the above-mentioned device.Type: GrantFiled: January 11, 1990Date of Patent: October 2, 1990Assignee: Canon Kabushiki KaishaInventors: Takashi Nakagiri, Yukuo Nishimura, Kunihiro Sakai, Yoshinori Tomida, Ken Eguchi, Kenji Saito
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Patent number: 4904572Abstract: This invention relates to the use of 3,5-dihydroxybenzoic acid as an organic acidic reagent in thermographic recording materials comprising a di- or triarylmethane thiolactone dye precursor, silver behenate and a polymeric binder, and in a further embodiment, relates to coating compositions useful in the preparation of the recording materials.Type: GrantFiled: April 18, 1988Date of Patent: February 27, 1990Assignee: Polaroid CorporationInventors: Edward J. Dombrowski, Jr., Patrick F. King
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Patent number: 4902599Abstract: A light-sensitive material is described, comprising a support having provided thereon a light-sensitive layer containing at least a light-sensitive silver halide, a developing agent, a polymerizable compound, a color image forming substance, and a hydrazine derivative represented by at least one of the following formula (I) and a hydrazine derivative represented by the following formula (II), in which said color image forming substance is immobilized by imagewise exposure to light, followed by heat development under conditions substantially not containing water: ##STR1## wherein R.sub.1 represents a substituted or unsubstituted alkyl, aralkyl, aryl, alkenyl, alkynyl, or heterocyclic group; and R.sub.2 represents a hydrogen atom or a substituted or unsubstituted alkyl, cycloalkyl, aralkyl, aryl, alkenyl, alkynyl, heterocyclic, alkoxy, aryloxy, alkylthio, arylthio, or amino group; ##STR2## wherein R.sub.Type: GrantFiled: October 10, 1986Date of Patent: February 20, 1990Assignee: Fuji Photo Film Co., Ltd.Inventors: Soichiro Yamamoto, Toshiaki Aono, Koichi Nakamura, Kozo Sato
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Patent number: 4893581Abstract: A display method is provided which comprises imparting a thermal energy to a display medium prepared by polymerizing a monomolecular film of a diacetylene derivative compound or a built-up film thereof and brought to a first state, so as to change said display medium to a second state within a temperature wherein the reversibility of change between the first state and the second state can be maintained.Type: GrantFiled: November 14, 1988Date of Patent: January 16, 1990Assignee: Canon Kabushiki KaishaInventors: Hiroshi Matsuda, Toshihiko Miyazaki
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Patent number: 4886739Abstract: In a thermally processable imaging element and process an imaging layer comprising a photothermographic or thermographic imaging composition and 2.5 to 20% by weight of the layer of at least one hydrolyzed polyalkoxysilane (hydrolyzed Si(OR.sub.1).sub.4 or hydrolyzed R.sub.2 --Si(OR.sub.3).sub.3) enables increased maximum image density. Such a hydrolyzed polyalkoxysilane in a hydrophobic imaging layer of such an element enables increased adhesion of the imaging layer to a contiguous hydrophobic hydrophilio layer, particularly a hydrophilic overcoat layer.Type: GrantFiled: August 10, 1988Date of Patent: December 12, 1989Assignee: Eastman Kodak CompanyInventor: Wojciech M. Przezdziecki
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Patent number: 4879205Abstract: An optical disk is formed by stacking a polycarbonate substrate with a first protective layer of amorphous silicon, a recording layer of an InSb alloy, and a second protective layer of an ultraviolet-setting resin, in the order named. The first and second protective layers are formed by sputtering and spin-coating, respectively. After the recording layer of the optical disk, formed in this manner, is subjected to initial crystallization, a light beam is applied to the recording layer. Thereupon, the irradiated portion of the recording layer undergoes phase transformation, thus forming recording marks in different crystal phases. Information is read by applying a weak laser beam to the recording layer with the recording marks therein. As the recording marks are cooled gradually by being exposed to a laser beam, they undergo phase transformation, so that the information is erased.Type: GrantFiled: September 15, 1987Date of Patent: November 7, 1989Assignee: Kabushiki Kaisha ToshibaInventor: Katsumi Suzuki
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Patent number: 4873173Abstract: A method of forming an image is provided. The method comprises the steps of (a) imagewise exposing a photographic material which comprises a support having provided thereon at least one light-sensitive silver halide emulsion layer and which contains a hydrazine compound represented by the following general formula (I) in the emulsion layer or a hydrophilic colloid layer adjacent thereto, the photographic material being designed so that a difference in sensitivity (sensitivity being defined as log E corresponding to the density of fog+2.0) between (1) the photographic material is development-processed with a developing solution having a sulfite ion concentration of 0.15 mole/l or more, a potassium ion concentration of 0.2 mole/l or more and a pH value ranging from 10.5 to 12.3 and (2) the photographic material is development-processed with the same developing solution as described above, except that the pH value was lowered by 1.0, (.DELTA.log E), is 0.Type: GrantFiled: October 21, 1987Date of Patent: October 10, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Senzo Sasaoka, Tetsuo Yoshida, Nobuaki Inoue
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Patent number: 4871649Abstract: An optical recording medium wherein recording information has been recorded as pits, comprises an absorptive layer and a reflective layer placed thereon, the absorptive layer having, on the surface, concave portions thermally deformed by heat generated upon irradiation of light beams, and the reflective layer having concave pits formed by deformation as a consequence of the thermal deformation of the absorptive layer and covering said concave portions of the absorptive layer in such a state that the concave portions are not exposed.Type: GrantFiled: March 19, 1987Date of Patent: October 3, 1989Assignee: Canon Kabushiki KaishaInventors: Hiroyuki Imataki, Mizuho Hiraoka, Sachiko Ichikawa, Yoshihiro Ogawa, Hitoshi Yoshino
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Patent number: 4863819Abstract: A data card comprising a self-supporting, wallet size plastic card base upon which is disposed a film substrate layer, a highly reflective layer and an optical storage layer which is a selected photosensitive layer which has been exposed at an actinic wavelength and developed to be substantially opaque over a portion of its extent, except for an imagewise exposure pattern of clear and partially clear data marks revealing to varying extends reflectivity in the underlying reflective layer. Data spots may have one of four different reflectivities thereby representing a quadrinary digit 0, 1, 2 or 3 replacing two binary digits. The reflective layer is matched to the selected optical storage layer so that the reflective layer is highly reflective at a read beam wavelength in the red or near infrared and less reflective at actinic wavelengths either in the blue/green range or in the ultraviolet.Type: GrantFiled: June 22, 1988Date of Patent: September 5, 1989Assignee: Drexler Technology CorporationInventors: Jerome Drexler, Eric W. Bouldin
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Patent number: 4847181Abstract: A laser marking method comprising steps of preparing a label material consisting of a colour layer and a transparant layer, applying the label material on a marking surface of a work, illuminating the marking surface through the label material with a laser beam of a wave length transilluminating the transparent layer so as to form a mark of a certain information on the marking surface of the work and in the coloured layer of the label material, and removing the label material from the marking surface of the work to produce a recorded label. The label can be produced simultaniously with the mark on the work wherein the information shown on the label is sophisticatedly identical with the information of the mark on the work surface.Type: GrantFiled: August 7, 1987Date of Patent: July 11, 1989Assignee: Mazda Motor CorporationInventor: Kiyofumi Shimokawa
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Patent number: 4845000Abstract: A radiation-sensitive carrier body directly utilized as a stamper has a glass substrate, a first highly adhesive layer securely adhered to the substrate, a radiation-sensitive layer which discharges a gas component upon being irradiated with a laser beam and which locally forms a protuberance due to the absorbed energy, a second highly adhesive layer securely adhered to the specific material of the radiation-sensitive layer and which deforms in accordance with deformation of the layer, and a metal layer which has a high releasability to allow easy separation from a optical disk substrate material such as an acrylic material when the carrier body is used as a stamper substrate for manufacturing optical disks. A protuberance formed on the carrier body such as a continuous spiral protuberance allows formation of a corresponding spiral groove in the acrylic material, serving as a pre-track into which desired information will be digitally written by a user.Type: GrantFiled: December 4, 1986Date of Patent: July 4, 1989Assignee: Tokyo Shibaura Denki Kabushiki KaishaInventors: Yoshikatsu Takeoka, Nobuaki Yasuda, Akio Hori, Norio Ozawa
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Patent number: 4837127Abstract: A recording medium comprising a substrate and a recording layer arranged on the substrate, said recording layer being removable by irradiation of radiation having high energy density thereto through evaporation or fusion in the area having received said irradiation, which is characterized in that said recording layer comprises indium and at least one metal compound selected from the group consisting of a metal sulfide, a metal fluoride and a metal oxide and contains at least one metal showing a surface tension of not less than 600 dyne/cm within temperatures of the melting point thereof to a temperature higher than the melting point by 300.degree. C.Type: GrantFiled: May 28, 1986Date of Patent: June 6, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Shinichiro Ohara, Kyoichi Naruo