Abstract: Apparatus and method for determining the tendency of hydrocarbon liquid to foul equipment includes a horizontal polymeric membrane made from polymers containing polar atoms, a light source for scanning hydrocarbon liquid sample on the membrane, and means for measuring the difference in light reflected by the asphaltene ring and the membrane matrix. Energy sources other than light may be employed.

Abstract: Apparatus and method for determining the tendency of hydrocarbon liquid to foul equipment includes a horizontal TLC plate, a light source for scanning hydrocarbon liquid sample on the TLC plate, and means for measuring the difference in light reflected by the asphaltene ring and the TLC matrix. Energy sources other than light may be employed.

Abstract: A composition having regulated occurrence of opacity and clarity at selected temperatures; method of making and using such a composition to create a temperature-indicating device by filling the composition in a suitable container of transparent material and having a background in the form of a color, a letter or a number i.e., in order to be able to visually interpret the difference between opacity and clarity. A reversible indicating device is made which can show if the upper or lower limits of a pre-set temperature interval has been exceeded or fallen below.

Abstract: A photoactivated time-temperature indicator is based on diacetylenic salts. A thermally unreactive ("inactive") diacetylenic salt (or a mixture of such salts) is mixed, in a polymeric matrix, with a material that generates acid upon exposure to light. Photoexcitation, preferably by UV or near UV light, causes the formation of a thermal reactive ("active") free diacetylenic acid. Following this activation step, a progressive color development occurs at a rate that increases with temperature. The indicator is useful for monitoring the freshness of perishable products, particularly those that require refrigeration.

Abstract: One measurement each is obtained from two optical sensors of ion concentration, following which the measured values are used for empirical determination of the ionic strength of an electrolytic solution. The sensors contain the same indicator substance but differ with regard to surface modification, thus ensuring different responses to ionic strength in spite of identical excitation and fluorescence wavelengths and the resulting simplicity of the optical system.

Abstract: A new class of chemical reagents called release tags which comprise signal, release and reactivity groups is disclosed and a release tag involving a pentafluorobenzoyl signal group, a methionylamide release group, and an active ester reactivity group is used to analyze the hormone, thyroxine, in serum, involving quantitation of the released signal group by gas chromatography with electron capture detection.

Abstract: An indicator comprising azo dye(s), epoxy compound(s) and a separating membrane can be utilized for detection of the completion of thermal sterilization treatment in the medical field and also for thermal inspection in such various fields as testing, instrumentation and the like. The indicator can be used also for detection of the completion of alkylene oxide gas sterilization treatment by ethylene oxide gas or the like.

Abstract: A non-destructive on-site method of inspection, and testing of the insulating performance and reconditioning of a concentric insulating tubular conduit member is disclosed. The insulating tubular conduit members comprise concentric walled members with an intermediate annular insulating cavity defined therebetween. This non-destructive method of testing and inspection is based on a determination of the presence of an unacceptable level of moisture in the annular insulating cavity. Visual, auditory, electrical, and radioactive indicating means can be employed in accordance with the principles of this invention.

Abstract: A cleaning and disinfecting article of manufacture and method are provided wherein the cleaning and disinfecting article of manufacture comprises a cleaning and disinfecting ingredient which includes a cleaning and disinfecting agent, a solid color indicator composition which includes a color indicator agent and a matrix agent supporting the color indicator agent, wherein the matrix agent is a matrix salt; and a stabilizing salt. The cleaning and disinfecting ingredient has a bleaching tendency relative to the color indicator agent such that when the solid color indicator composition is in an aqueous solution of the cleaning and disinfecting ingredient, the presence of the cleaning and disinfecting ingredient in the solution minimizes the display of color in the solution for as long as significant amounts of the cleaning and disinfecting ingredient are present.

Abstract: A method of monitoring if a stored product has exceeded a predetermined temperature using an assembly, which comprises coated onto a carrier a gelatin layer containing an acidic reactant, color former and an encapsulated non-aqueous solvent.

Abstract: A thermochromic composition comprising:(i) at least one electron-donating organic chromogenic compound,(ii) at least one compound serving as a color developing material and selected from thiourea and derivatives thereof, guanidine and derivatives thereof, benzothiazole, and benzothiazolyl derivatives represented by the formula ##STR1## wherein A is --H, ##STR2## --NR.sub.2, --H.multidot.NR.sub.3 or --CSNR.sub.2 in which R is H, C.sub.1 -C.sub.10 alkyl, benzyl optionally substituted with C.sub.1 -C.sub.6 alkyl or cyclohexyl optionally substituted with C.sub.1 -C.sub.6 alkyl, with the proviso that all of R in --NR.sub.2, --H.multidot.NR.sub.3 and --CSNR.sub.2 can not be H, and M is Cu, Zn, Fe, Ni, Co or Te, and(iii) and at least one compound serving as a desensitizer and selected from the group consisting of alcohols, esters, ketones, ethers, acid amides, carboxylic acids and hydrocarbons.

Abstract: A reagent and method for in vitro determination of the eye irritating properties of individual compounds and/or mixtures is disclosed. The material to be assessed is combined with the reagent which provides a response, for example, the production of a precipitate, which is proportional to the deleterious response elicited by the material in the human eye.

Abstract: A method of analyzing molecular layers of amino-functional group coupling agents on inorganic substrates is disclosed. A saturated solution of 1-dimethylaminonaphthalene-5-sulfonyl chloride is added to a sample to be tested, and sufficient time is allowed, with or without heating, for the reaction of the 1-dimethylaminonaphthalene-5-sulfonyl chloride with any amino functional group coupling agent which might be present. The color intensity of the reaction product is compared under ultraviolet light in an otherwise substantially dark room with the color intensity of standards representative of known thicknesses of coupling agent to determine the existence and thickness of the coupling agent on the particles being analyzed.

Abstract: A method is described for testing equipment to determine whether it will continue to function when in the presence of a sodium fire, which is of much less cost than prior testing methods. The method includes spraying sodium monoxide on the equipment while it lies within an enclosure. The sodium monoxide is a fine powder, and the moisture within the chamber is maintained at a high level which is much above 20%. The moisture turns the sodium monoxide to sodium hydroxide, or lye, which is the most damaging component of a sodium fire.

Abstract: Heat-sensitive compositions which rapidly develop color upon heating and rapidly discharge their color upon cooling, comprising an intimate mixture of a 3,3-bis (p-aminophenyl) phthalide and an organic acid. The color-producing and color-discharging cycle may be reproduced many times without noticeable change in response. The novel compositions of the invention are useful as temperature indicators, thermal display media, safety papers and validation devices.

Abstract: An elapsed time indicator in which an indicator, such as a flowable colorant, is releasably contained within an enclosure at least a portion of which is a volatilizable, preferably sublimable, substance.

Abstract: Dyeings on cellulose with direct or reactive dyestuffs are given improved wet fastness properties by aftertreatment with a reaction product or mixture of a polybasic amino compound (A) with an N-methylol compound (B) or with formaldehyde or a formaldehyde donor and optionally a crosslinking catalyst (C). Particular direct or reactive dyestuffs and polybasic amino compounds are determined to be suitable in the dyeing and aftertreatment when the dyestuff and the polybasic amino compound (A) are such that when mixed together in aqueous solution they give a precipitate which, after washing and drying does not redissolve in aqueous alkali at pH.gtoreq.12 at room temperature.

Abstract: A quick and inexpensive test for the detection of fetal pulmonary maturity comprising the steps of acidifying a given volume of amniotic fluid, adding a given volume of an ether, agitating and observing the number of bubbles existing in the ether layer. The number of bubbles existing in the ether layer after a certain observational period may be correlated with the existence of pulmonary immaturity in a fetus.

Abstract: A method for determining the coating weight and composition of a zinc phosphate coating on a ferrous metal surface comprises stripping the coating from a known area using an aqueous solution of sodium hydroxide and triethanolamine, thereafter measuring the iron and phosphate contents by colorimetric analysis of the stripping solution and then determining the coating weight and composition based on such measurements.

Abstract: An adjustable accumulated thermal exposure indicator device, and method of use, for affixing to and indicating deterioration of perishable goods and the like, comprising (1) a reactant yielding material that reacts via one or more steps at a rate depending on time, temperature, and pH to provide an amine and (2) an indicator that reacts at a time, temperature, concentration and pH dependent rate with the amine to produce a visible reaction that is indicative of the expiration of a predetermined time-temperature history related to the useful life of the goods to which the device is affixed. Also provided is a device or article that is responsive to accumulated thermal exposure for the controlled release of immobilized alcohols and amines.

Abstract: A test means, test device, and method for determining the ionic strength or specific gravity of a test sample as well as a method for making the device, are disclosed. The test means comprises a weakly acidic polyelectrolyte polymer, at least 50 percent of the carboxyl groups of which are present in the form of the salt of a quaternary ammonium ion having the structure ##STR1## in which the R substituents, same or different, are hydrogen, lower alkyl or aryl, with the proviso that at least one of R is other than hydrogen; and an indicator means capable of producing a detectable response to ion exchange between the polyelectrolyte salt and the test sample. The device comprises a carrier matrix incorporated with the test means. The method for determining the ionic strength or specific gravity comprises contacting the test sample with the test means or device and observing a detectable response.

Abstract: An apparatus and method for measuring minute quantities of moisture and other contaminants within sealed enclosures such as electronic assemblies which may be subject to large external atmospheric pressure variations.An array of vacuum quality valves (20 thru 32) is arranged to permit cleansing of the test apparatus of residual atmospheric components from a vacuum source (13). This purging operation evacuates a gas sample bottle (36), which is then connected by valve settings to provide the drive for withdrawing a gas sample from the sealed enclosure under test into the sample bottle through a colometric detector tube (Drager tube) (19) which indicates moisture content. The sample bottle (36) may be disconnected and its contents (drawn from the test enclosure) separately subjected to mass spectrograph analysis. The use of an inert reference gas (12) admitted during the test, facilitates the determination of free volume and internal pressure within the test unit.

Abstract: A method for determining the spatial and phase distribution of a liquid-vapor multiphase fluid. The method comprises adding a fluorescent monomer and a quencher to the fluid to be studied. The fluid is then dispersed and the monomer excited. The excited monomer combines with the quencher to form a fluorescent exciplex. The monomer fluorescence is predominantly in the vapor phase and the exciplex fluorescence is predominantly in the liquid phase.

Abstract: A technique for accurately and repeatably measuring the depths of junctions between adjacent layers in a semiconductor wafer, even when the depths are relatively shallow. A groove is formed in the surface of the wafer, with a cylindrical grooving tool that is inclined to the planar surface of the wafer, to form a groove that is tapered in width and depth. The wafer is then conventionally treated to enhance the contrast between the layers as they are exposed on the groove surface. Since each planar junction intersects the groove surface at an angle, the corresponding junction line appears as a part of an ellipse, and exhibits a well defined peak at the center of the groove. Direct measurement of the depth of the groove at this point, using a standard profilometer, provides the desired junction depth.

Abstract: The present method can determine the presence and amount of silvery white metallic impurities in a silvery white molten solder composition. In accordance with the method of this invention, a transparent substrate which has sequential layers of metal deposited on one of the surfaces thereof is prepared. A first layer is formed directly on the substrate of a thin film of a colored metal such as copper or gold. A second thicker layer of a silvery white metal, the presence and amount of which is desired to be evaluated in the solder composition, deposited over the first layer. In use, the substrate is placed in contact with the molten solder. The amount of time required for the second layer to dissolve into the solder bath and the exposed first colored layer to change color due to alloying with the metal of the solder, is measured. The time required for the color change to occur is correlated to the level of contamination of the silvery white metal in the solder bath.

Abstract: A method and an apparatus for detecting a boundary surface between a blood plasma and a blood corpuscle suspension obtained after centrifuging are disclosed. An impedance across a pair of electrodes is measured by applying an A.C. voltage across the electrodes at such a frequency that impedances of the blood plasma and the blood corpuscle suspension are made greatly different from each other. When the impedance changes abruptly, it is determined that the electrodes have passed through the boundary surface.

Abstract: The disclosure relates to an apparatus for measuring the size of gas entrained particles by detecting the rate of incandescent burning of the particles. Entrained particles are passed at a controlled velocity through a heated zone where they are gradually consumed. The radiant energy emitted by the burning particles is detected at varying locations along the path of flow through the heated zone. An indication of particle size distribution is obtained by deriving the third derivative of detected radiant energy intensity with respect to distance of flow through the heated zone.

Abstract: An improved test means, device and method for determining the ionic strength or specific gravity of an aqueous sample are disclosed. The test means comprises a weakly basic polyelectrolyte polymer salt and an indicator means capable of producing a detectable response to ion exchange between the polymer salt and the test sample. The polymer salt is one in which one or more of the basic moieties of the polymer is present as the salt of a strong organic acid.

Abstract: System and means for irreversibly recording the incidence of a predetermined temperature comprising a cholesteric liquid crystal system and an activator material capable of interacting with the liquid crystal system to induce a unique irreversible change in the optical properties thereof sustantially at the predetermined temperature. The system preferably includes means for separating the liquid crystal system and activator at temperatures below the activation temperature of the activator.

Abstract: The volume change of a hydraulic cement slurry can be measured by measuring the amount of pressurized gas which flows into or out of the volume initially occupied by the slurry during the setting of the cement, for example, where the slurry is one formed by dissolving in the slurry mix water a correlated amount of gas-forming reactants having a delayed rate of reaction such that the gas production occurs mainly at the time the volume of the slurry mix water is being reduced to a low value during the setting and hardening of the cement.

Abstract: A liquid melt becomes converted to crystalline form at a particular temperature either spontaneously or when artificially nucleated. The liquid releases heat at crystallization. If the liquid is in a supercooled state when it begins to crystallize, its temperature will rise from the particular temperature at which it is nucleated.Another liquid material is mixed with the liquid to be crystallized. The liquid additive has properties of forming a metastable solid together with the crystallizing material. When the liquid additive exsolves, the crystalline aggregate is weakened and is easily decomposed into fragments of small size. The liquid additive materials may include monohydric alcohols, diols and triols. The liquid additive material may be included in the liquid to be crystallized, in small amounts, amounts to two percent (2%) to five percent (5%) being typical.

Abstract: Disclosed is a toxicity test for chemical substances using the phylum Nematoda.According to this test, substances can be easily, rapidly, and inexpensively analyzed for their ability to induce mutations, promote tumor formation, act as teratogens, and cause abnormalities in development, metabolic function, and neuromuscular function.

Abstract: This invention provides novel thermochromic compositions which exhibit distinct color changes at temperatures in the range of about 165.degree. C. to about 240.degree. C. The compositions comprise basic copper carbonate and a sulfur compound. Paint formulations containing these novel thermochromic compositions or complexes of copper and sulfur-containing organic acids are also provided. The compositions are useful with heat-recoverable memory metal couplings to prevent overheating of the couplings during installation.

Abstract: A method for checking noise of a spectrometer or spectrophotometer. The method is of the type comprising measuring absorbance (A) or percent transmittance (%T) of a solution over a period of time. The method is characterized in that the solution comprises from about 0.040 to about 0.090 M nitrite, the nitrite being present as a nitrite ionized constituent.

Abstract: A pigment for a color-changing heat indicator comprising a product obtained by interaction of an aqueous solution containing ions of copper and mercury with an aqueous solution of a nitrogen-containing organic compound: an amide of carbonic acid, an amide of thiocarbonic acid, a tertiary amine to give a reaction mixture which is reacted with an aqueous solution containing ions of iodine at an atomic ratio of copper:mercury:iodine equal to 2:1.5:3-5 and an amount of the nitrogen-containing organic compound equal to 0.8-8% of the total content of copper and mercury; the pigment has its critical temperature of from 38.degree. to 70.degree. C. and a heat-resistance of from 160.degree. to 180.degree. C.

Abstract: A test procedure is disclosed for evaluating the solderability properties of molten solder. In the method of this invention, a testpiece is provided which has a transparent support with a film of metal such as copper deposited on one surface of the transparent support. The surface having the metal film is immersed in the molten solder and the time required for alloying to occur and be observed through the transparent support is measured to determine rate of alloying and, thereby, the solderability properties of the molten solder under evaluation.

Abstract: An indicator system and device for visually monitoring ethylene oxide sterilization by color changes of the indicating composition of the system upon sufficient and properly conditioned exposure of the composition to ethylene oxide provides a controlled method for indicating the effective sterilization of articles by ethylene oxide. The indicating composition of this invention undergoes color changes that are progressive with the conditions and periods of sterilization, such that a final and complete color change indicates the completion of an effective ethylene oxide sterilization. The indicating composition comprises a leuco precursor of an aryl methane dye selected from the groups herein defined; and an acidic constituent. Acidic organic compounds such as diphenolic acid (4,4-bis [4-hydroxyphenyl] pentanoic acid) are effective acid constituents because they enhance hue, develop color and stabilize the final color change.

Abstract: In the reference electrode for the oxygen probe comprising a mixture of Cr powder and Cr.sub.2 O.sub.3 powder, an improved reference electrode characterized in that Cr powder and Cr.sub.2 O.sub.3 powder are mixed in a ratio 97%:3% to 80%:20% and the mixture is sintered beforehand. An oxygen probe using this electrode exhibits improved response, stability and reproducibility in molten steel.

Abstract: A recording device is described, useful as an integrated time-temperature or radiation-dosage history indicator. The device contains a substrate having deposited thereon at least two indicating units, one being unreacted and representing zero time of exposure and the other unit being pre-reacted. Each unit is comprised of an acetylenic compound containing at least one --C.tbd.C--C.tbd.C-- group, capable of reacting by 1,4-addition polymerization thereby forming an end-point color after an irreversible, progressive color change upon thermal annealing or exposure to actinic radiation. The end-point color represents an integrated time-temperature history of thermal annealing or radiation-dosage history. Each unit is constructed such that the time required to form the end-point color by thermal annealing at a given temperature or for a known thermal history, or exposure to actinic radiation at a given average radiation dosage rate, is predetermined.

Abstract: For the recording of local boundary-layer flow-line directions in liquid media by means of a photographic layer,(a) small reagent depots or deposits, with a volume of about 0.2 mm.sup.3, of a water-soluble substance reactive to silver ions ("chemical flow line indicators") are applied in raster fashion to the surface which is to be exposed to the flow and which surface is previously coated with a dry or swelled photographic sheet film,(b) the reagent deposits are covered with an inert layer which is soluble in the liquid flow medium,(c) the surface so prepared is exposed to the flow of an aqueous flow medium, and(d) the film is developed according to conventional means.The reagent deposits, which may be present as a paste, can contain a precipitation agent for silver ions. The deposits can be applied as a dot raster to the surface which is to be exposed to the flow (and which is coated with a photographic film) by means of screen printing or by means of a hole raster template.

Abstract: A method of testing additives for the ability to prevent coal particles from freezing and adhering to the sides of coal cars and metal storage devices which comprises the steps of:(a) coating the treatment to be tested on the inside of a small interior diameter steel or aluminum cylinder;(b) soaking the thus-treated cylinder in water for a short time to simulate exposure to precipitation;(c) immediately loading the water-treated cylinder with coal particles;(d) compressing the coal within the cylinder;(e) freezing the coal within the cylinder;(f) removing the coal from the cylinder using means capable of measuring the force required to remove the coal; and(g) comparing that force against the force required to remove the coal from a similar non-treated cylinder.

Abstract: A composition is disclosed for determining the ionic strength or specific gravity of an aqueous test sample, the composition comprising a strongly acidic or strongly basic polyelectrolyte, a buffer substance capable of providing a pH of about 5.5, and an indicator means capable of producing a detectable response to ion exchange between the polyelectrolyte and the sample. The test device comprises a carrier matrix incorporated with the test composition, and the method for its use comprises contacting an aqueous test sample with the device and observing a detectable response.

Abstract: Novel and stable compositions of matter are disclosed which change color sharply upon a transition from a liquid state to a solid state or from a solid state to a liquid state, which change of state is at substantially a predetermined temperature corresponding to a temperature to be measured.The constituents of the novel compositions of matter comprise:1. a solvent (I) consisting of a single substance or a mixture of substances and adapted to change from a solid state at substantially a predetermined temperature to a liquid state and2. an indicator system (II) consisting of one or more substances different from (I), characterized in that(a) (II) is soluble in (I) when the latter is in the liquid phase, and(b) (II) changes color visible to the naked eye when (I) passes from the solid to the liquid phase or from the liquid to the solid phase.Thermometers containing said stable compositions of matter are also disclosed.