Solid Carbonaceous Fuel Dispersed In A Liquid Medium (e.g., Dispersed Coal, Coke, Carbon Powder, Peat, Etc.) Patents (Class 44/280)
  • Patent number: 5082469
    Abstract: Coal-water slurries containing a rheological additive are provided. Rheological additives employed for preparation of the coal-water slurries are amide products obtained by reaction of a polycarboxylic acid with a polyether diamine and, optionally, other amines or hydroxylic compounds. Salts of the amides may also be advantageously employed as dispersants. The additives are employed in an amount from about 0.1 to about 4 percent by weight to provide stable aqueous slurries containing from 60 to 80 percent by weight coal solids.
    Type: Grant
    Filed: July 28, 1988
    Date of Patent: January 21, 1992
    Assignee: Henkel Corporation
    Inventors: William S. Kain, Donald D. Staker
  • Patent number: 5042990
    Abstract: Storage-stable, pumpable, concentrated dispersions of coal in water contain a non-ionic additive constituted by a polymer containing polyethoxy chains grafted onto suitably functionalized polystyrenes having a molecular weight comprised within the range of from 500 to 15000.
    Type: Grant
    Filed: November 27, 1989
    Date of Patent: August 27, 1991
    Assignee: Eniricerche S.p.A.-and- Snamprogetti S.p.A.
    Inventors: Fabrizio Bonaccorsi, Aldo Prevedello, Armando Marcotullio, Edoardo Platone, Arnaldo Roggero, Elio Donati
  • Patent number: 5036013
    Abstract: A method is provided for converting coal to low molecular weight organic compounds comprising combining an aqueous solution of an aqueous-soluble polymeric coal substrate with a lignin peroxidase, oxygen and hydrogen peroxide. The invention is exemplified using the lignin peroxidase from Phanerochaete chrysosporium. Also provided are aqueous-soluble polymeric coal substrates suitable for lignin peroxidase-catalyzed depolymerization and methods of preparing such substrates. Finally, a method is provided for isolating the lignin peroxidase from mycelia-free, unconcentrated media of cultures of P. chrysosporium producing the enzyme.
    Type: Grant
    Filed: September 21, 1990
    Date of Patent: July 30, 1991
    Assignee: The Salk Institute Biotechnology/Industrial Associates, Inc.
    Inventors: Willis A. Wood, Lillian M. Wondrack
  • Patent number: 5028238
    Abstract: Dispersants for aqueous coal suspensions containing(a) lignin sulfonic acid and/or alkali metal, alkaline earth metal and/or ammonium salts thereof,(b) one or more alkyl ether phosphates corresponding to general formulae (I) and/or (II) below ##STR1## in which R is straight-chain or branched C.sub.8 -C.sub.22 alkyl or alkenyl radical,M is hydrogen, an alkali metal, ammonium, or an alkaline earth metal, andm and n are numbers of from 1 to 15, and(c) optionally, other auxiliaries of the type typically present in such dispersants.
    Type: Grant
    Filed: March 11, 1988
    Date of Patent: July 2, 1991
    Inventors: Wolfgang von Rybinski, Thomas Foerster
  • Patent number: 4983187
    Abstract: A method is described for preparing a high-concentration solids suspension, in particular coal or petroleum coke, which can be transported by pipe and be burnt with low emission of harmful substances, comprising crushing the solid to be suspended to a maximum particle size of 6 mm and then grinding it in the presence of additives in aqueous solution to a maximum solid particle size of 300 .mu.m, the method being characterized by adding, either before the crushing or immediately before the grinding, a desulphurizer chosen from CaCo.sub.3, MgCO.sub.3 and dolomite, either alone or in mixture, in a molar ratio to the sulphur contained in the solid of between 1.5 and 3, and adding immediately before or during grinding a desulphurizer also possessing stabilizing and anticorrosive properties and chosen from MgO, Mg(OH).sub.2, CaO and Ca(OH).sub.2, either alone or in mixture, in a quantity of between 0.04 and 0.4% by weight of the final suspension.
    Type: Grant
    Filed: January 3, 1989
    Date of Patent: January 8, 1991
    Assignee: Snamprogetti S.p.A.
    Inventors: Vincenzo Lagana, Dario Ercolani, Elio Donati
  • Patent number: 4983296
    Abstract: Municipal sanitary sewage sludge is disposed of by an improved partial oxidation process without polluting the environment. Aqueous slurries of sewage sludge are upgraded by hydrothermal treatment, preferably while being sheared, concentrated, and then mixed with a supplemental fuel, preferably coal. A pumpable aqueous slurry of sewage sludge-coal and/or petroleum coke is thereby produced having a greater total solids and heat content (HHV) as well as containing an increased amount of sewage sludge for reacting with free-oxygen containing gas in a free-flow partial oxidation gas generator. Hot quench water or steam produced by cooling the hot raw effluent stream of synthesis gas, reducing gas or fuel gas from the gasifier may provide heat for the hydrothermal step.
    Type: Grant
    Filed: August 3, 1989
    Date of Patent: January 8, 1991
    Assignee: Texaco Inc.
    Inventors: Matthew A. McMahon, Robert M. Suggitt, Ronald J. McKeon, Albert Brent
  • Patent number: 4969929
    Abstract: A fluidizing and dispersing additive for coal-water mixtures, constituted by an ethoxylated adduct of either natural humic acids, or of humic acids deriving from partial coal oxidation.
    Type: Grant
    Filed: April 28, 1988
    Date of Patent: November 13, 1990
    Assignee: Eniricerche, S.p.A.
    Inventors: Edoardo Platone, Aldo Prevedello, Riccardo Rausa