Coating Or Impregnation Contains Epoxy Polymer Or Copolymer Or Polyether Patents (Class 442/175)
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Patent number: 6566286Abstract: A polished-piece holder capable of preventing a polished piece from taking scratches, being increased in wear resistance, thickness accuracy, warpage resistance and dimensional stability, and preventing a deterioration in polishing accuracy. The polished-piece holder includes a core layer and a wear-resistant surface layer laminated on at least one of front and rear surfaces of the core layer. The core layer is constituted of at least one thermosetting resin impregnated fibrous layer and the surface layer is likewise constituted of a thermosetting resin impregnated fibrous layer. The thermosetting resin impregnated fibrous layer constituting the surface layer is subject to heating and pressurizing, to thereby provide a prepreg wherein a nonwoven aramid fiber substrate is impregnated with thermosetting resin.Type: GrantFiled: June 9, 2000Date of Patent: May 20, 2003Assignee: Shin-Kobe Electric Machinery Co., Ltd.Inventors: Tooru Sakaguchi, Tsuneo Kawamura
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Publication number: 20030013367Abstract: Disclosed herein is a cloth treating agent comprising a tocopherol and at least one of a polyethylene oxide compound and a derivative thereof. The cloth treating agent permits the provision of a print which has sufficiently high color value and depth in color and can be prevented to the utmost from undergoing bleeding even when the amount of inks applied is great.Type: ApplicationFiled: October 4, 1999Publication date: January 16, 2003Inventors: MARIKO SUZUKI, SHOJI KOIKE
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Publication number: 20020193025Abstract: The invention relates to an external reinforcement for beams, columns, plates and the like, substantially consisting in the combination of fibers and a resin and whereby the majority of the fibers is situated in the longitudinal direction of the reinforcement, characterized in that at least well-defined portions of the external reinforcement are provided with an additional reinforcement formed by fibers which are arranged according to at least one direction differing from the longitudinal direction of the reinforcement.Type: ApplicationFiled: July 15, 2002Publication date: December 19, 2002Inventor: Dirk Christiaan Jozef Isidoor De Neef
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Publication number: 20020182958Abstract: A multilayer printed wiring board includes a core member including a plurality of glass clothes impregnated with a resin. Each of the glass clothes is woven with glass yarns each of which includes a bundle of glass filaments. One or more buildup layers are laminated on one or each surface of the core member. The core member has an elastic modulus which is no less than 100 times that of the buildup layer at 240° C.Type: ApplicationFiled: September 26, 2001Publication date: December 5, 2002Applicant: Fujitsu LimitedInventors: Motoaki Tani, Nobuyuki Hayashi, Hiroyuki Machida, Takeshi Ishitsuka, Yasuo Yamagishi
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Patent number: 6436856Abstract: A curable vinyl ester resin composition capable of undergoing B-staging at room temperature comprises (a) an unmodified vinyl ester resin; (b) a reactive diluent consisting of an ethylenically unsaturated monomer; (c) a free-radical curing agent; (d) a B-staging agent comprising a Group II metal oxide or hydroxide, or a mixture thereof; and (e) a thickening agent comprising an ester, a ketone, an aldehyde or a mixture thereof. The thickening agent coacts with the B-staging agent to cause B-staging of the vinyl ester resin at room temperature. The vinyl ester resin composition according to the invention is particularly useful for impregnating a fibrous material such as a woven fabric material. The fibrous material impregnated with the vinyl ester resin composition of the invention has a shelf life of up to 12 months. B-staging is generally reached in about two weeks following mixture of the various components and impregnation of the fibrous material.Type: GrantFiled: June 14, 2000Date of Patent: August 20, 2002Assignee: Simex Technologies, Inc.Inventor: Halim Chtourou
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Patent number: 6417459Abstract: A fluororesin-impregnated adhesive layer 7 such as PFA is formed on one face or both faces of a prepreg 1 in which a fluororesin-impregnated layer 3 such as PTFE is impregnated and held into E-glass cloth 2 that serves as a basic material of the prepreg. The prepreg has a (mass of 30 g/m2 or less, and is woven by filament bundles each of which is configured by 120 or less glass filaments. Copper foil 5 is placed on the fluororesin-impregnated adhesive layer 7 to form a predetermined conductor pattern on the surface, thereby producing a printed circuit board having a thickness of 0.2 mm or less. Therefore, the printed circuit board is excellent in dielectric characteristics, electrical insulation resistance between through holes, and its long-term reliability, and superior also in flexibility. Consequently, the printed circuit board is applicable to any use such as a high-frequency circuit.Type: GrantFiled: February 21, 2001Date of Patent: July 9, 2002Assignee: Nippon Pillar Packing Co., Ltd.Inventors: Hitoshi Kanzaki, Yasuhiko Ichino, Toshimitsu Tanii, Kouji Ohnishi
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Publication number: 20020031965Abstract: A joint and method for forming a joint between two spaced apart materials having dissimilar coefficients of thermal expansion wherein the space is filled with a blended composite of twisted fibrils of the two materials, preferably quartz and carbon, and an adhesive, preferably an epoxy based adhesive.Type: ApplicationFiled: May 17, 2001Publication date: March 14, 2002Inventors: H. Landis Carter, Frank Christopher Malik
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Patent number: 6309985Abstract: A vibration-damping laminate having a constraining layer secured to a viscoelastic layer. The constraining layer includes a mat of non-thermoplastic fibers. The viscoelastic layer includes a thermoplastic elastomer.Type: GrantFiled: January 25, 1999Date of Patent: October 30, 2001Assignee: Soundwich, Inc.Inventors: R. Craig Virnelson, Jeffrey J. Schroeder, Maurice E. Wheeler
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Patent number: 6294485Abstract: A papermakers dryer fabric is operable to carry a paper web on one face thereof. The fabric comprises a base substrate that is coated and optionally partially or fully impregnated with resin so as to yield a substrate having a substantially impermeable and preferably smooth surface on the paper carrying side of the fabric.Type: GrantFiled: July 16, 1998Date of Patent: September 25, 2001Assignee: Voith Fabrics Heidenheim GmbH & Co. KGInventors: Mark Hodson, Timothy Ashworth, Paul Myerscough
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Patent number: 6242090Abstract: A method of producing a curable prepreg which comprises (i) sandwiching a multi-ply fabric layer comprising at least two superposed sheets of woven reinforcing fabric between solid films of a curable resin composition and (ii) heating the resulting sandwich under pressure so that the resin composition impregnates the sheets of woven reinforcing fabric to form a coherent curable structure.Type: GrantFiled: July 5, 2000Date of Patent: June 5, 2001Assignee: Hexcel CorporationInventors: George Edward Green, John Cook
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Patent number: 6140259Abstract: Glass fiber non-woven fabric for base material of laminate comprising binder binding glass fibers to each other and having glass transition temperature of higher than 120.degree. C.Type: GrantFiled: November 20, 1998Date of Patent: October 31, 2000Assignee: Shin-Kobe Electric Machinery Co., Ltd.Inventors: Masayuki Ushida, Masayuki Noda, Masaru Ogata
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Patent number: 6133167Abstract: A method of producing a curable prepreg which comprises (i) sandwiching a multi-ply fabric layer comprising at least two superposed sheets of woven reinforcing fabric between solid films of a curable resin composition and (ii) heating the resulting sandwich under pressure so that the resin composition impregnates the sheets of woven reinforcing fabric to form a coherent curable structure.Type: GrantFiled: July 26, 1993Date of Patent: October 17, 2000Assignee: Ciba Specialty Chemicals Corp.Inventors: George Edward Green, John Cook
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Patent number: 6124220Abstract: A laminated board comprising an intermediate layer and two surface layers formed thereon, in which board the intermediate layer comprises a central layer made of a nonwoven glass fiber fabric impregnated with a resin composition containing a thermosetting resin and an inorganic filler and upper and lower layers formed on the central layer, each being made of said resin composition containing a thermosetting resin and an inorganic filler, and the two surface layers formed on the intermediate layer are made of a thermosetting resin-impregnated fiber substrate; and a process for production of the laminated board.Type: GrantFiled: September 17, 1996Date of Patent: September 26, 2000Assignee: Sumitomo Bakelite Company LimitedInventors: Takahiro Nakata, Takahisa Iida, Takashi Yamaguchi, Toshihide Kanazawa
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Patent number: 6090729Abstract: A non-porous sheet for bonding to honeycomb-type core structures to be machined on a vacuum chuck includes a woven fiberglass fabric impregnated with a nonporous epoxy-thermoplastic resin having a low melting temperature. The epoxy-thermoplastic resin comprises a blend of bisphenol-A based epoxy and phenoxy thermoplastic. The nonporous sheet is exposed to a relatively low temperature for about five minutes to soften the epoxy-thermoplastic resin. A core structure is placed on the softened sheet and the sheet is allowed to cool to ambient temperature to adhere the non-porous sheet to the core. The core and sheet assembly can then be placed on the surface of a vacuum chuck associated with a machine tool for a subsequent machining operation of the core structure. When the machining operation is finished, the nonporous sheet is easily removed from the core structure by heating the core and sheet assembly slightly above ambient temperature and then peeling off the sheet from the core for reuse.Type: GrantFiled: April 7, 1999Date of Patent: July 18, 2000Assignee: FiberCote Industries, Inc.Inventor: Thomas F. Jonas
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Patent number: 6083855Abstract: A method for manufacturing a cured resin impregnated substrate comprising placing a substrate into a impregnation zone including a solvent containing curable resin to produce a resin impregnated substrate and at least partially curing the resin impregnated substrate to produce a cured resin impregnated substrate, wherein the number of voids in the cured resin impregnated substrate are reduced by processing the substrate in at least one processing step that reduces the number of voids in the cured resin impregnated substrate product.Type: GrantFiled: January 4, 1999Date of Patent: July 4, 2000Assignee: Isola Laminate Systems Corp.Inventors: Larry D. Olson, John R. Wold, Dave F. Miller, Marc Hein, Mary Jo Theyerl, Edward Hammes
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Patent number: 6068715Abstract: A glass fiber mat for a stampable sheet includes long fibers and short fibers which will not separate even during forming and which are distributed uniformly to make the features of the respective fibers effective. A production system includes a double belt press type laminator which stacks the glass fiber mat, a thermoplastic resin melt and a film which is taken up and applies heat and pressure for impregnation, and cools while maintaining a pressure condition. A supply supplies the glass fiber mat into the laminator. A pair of pressure shearing rollers are arranged between the supply and an endless belt of the laminator for partially cutting the glass fibers into short fibers. The rollers are made of steel to apply line pressure to the glass fiber mat to shear the continuous fibers to uniformly distribute the short fibers in long fibers.Type: GrantFiled: February 7, 1997Date of Patent: May 30, 2000Assignee: UBE-Nitto Kasei Co., Ltd.Inventors: Masahiko Yokokita, Akio Onodera, Yoshinobu Shichiri, Toru Watanabe, Shigehiro Matsuno
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Patent number: 6027794Abstract: Prepregs, comprising the following components [A], [B] and [C], with the component [C] distributed near either or both of the surface layers without being regularly arranged.[A]: Long reinforcing fibers[B]: A matrix resin[C]: Long thermoplastic resin fibersThe prepregs of the present invention are tacky and drapable, and the composite materials obtained by heating and forming the prepregs are high in heat resistance, and very high in impact resistance and inter-layer toughness. Furthermore, the prepregs are easy to produce and high in their latitude in availability of materials.Type: GrantFiled: August 8, 1997Date of Patent: February 22, 2000Assignee: Toray Industries, Inc.Inventors: Atsushi Ozaki, Hajime Kishi, Nobuyuki Odagiri, Hiroki Oosedo, Hiroaki Hinomiya
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Patent number: 6013588Abstract: The present invention relates to a printed circuit board and a printed circuit board base material for use in the printed circuit board. The printed circuit board base material of the present invention is produced by impregnating a carbon core material such as carbon cloth with a first resin such as epoxy resin, and the printed circuit board of the present invention is characterized in that resin pores are opened on the printed circuit board base material, second resins such as epoxy resins are filled in the resin pores, circuit layers are formed on the printed circuit board base material, through holes connecting the circuit layer together are provided, and the center line of the resin pore is approximately in line with the center line of the through hole.Type: GrantFiled: August 5, 1997Date of Patent: January 11, 2000Assignee: O.K. Print CorporationInventor: Yosuke Ozaki
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Patent number: 5972810Abstract: There are described a self-adhesive prepreg on the basis of a resin-impregnated fibrous supporting material carrying on at least one surface a layer with an increased ratio of resin to supporting material, and the use thereof for the production of sandwich structures.Type: GrantFiled: March 27, 1997Date of Patent: October 26, 1999Assignee: Isola AGInventors: Hans-Joachim Gabrisch, Marteen De Zwart, Markus Rudin
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Patent number: 5925579Abstract: Reinforcement of structures in high-moisture environments is achieved by applying reinforcement layers which include a fabric portion and an uncured resin portion where the uncured resin contains a moisture curable silicon-modified polyether resin. The uncured reinforcement layer is cured in place about the structure to form a composite reinforcement shell. The uncured reinforcement layer is formed from either dry-woven fabric or woven fabric which is pre-impregnated with a cured resin and then coated with the moisture-curable silicon-modified polyether resin. The invention finds particular use in reinforcing bridge supports and pilings which are at least partially submerged in water. Containment layers are used to prevent de-lamination during curing of the reinforcement structure. Use of a containment layer not only prevents de-lamination caused by waves or other turbulent water, but also enhances the underwater curing process.Type: GrantFiled: May 23, 1996Date of Patent: July 20, 1999Assignees: Hexcel Corporation, Fyfe Co., LLCInventors: John D. Neuner, Frederick P. Isley, Jr.
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Patent number: 5910458Abstract: The present invention provides a needled mat adapted to reinforce a thermosetting matrix material to form a composite, composites formed therefrom, and methods related thereto. The needled mat includes a primary layer of a plurality of unidirectional continuous glass fiber strands coated with a composition which is compatible with the thermosetting matrix material and a secondary layer positioned thereon of a plurality of randomly oriented, generally continuous and/or chopped glass fiber strands coated with a composition which is compatible with the thermosetting matrix material. The mat has a total surface weight ranging from about 1300 to about 11,500 grams per square meter.Type: GrantFiled: May 30, 1997Date of Patent: June 8, 1999Assignee: PPG Industries, Inc.Inventors: Kenneth D. Beer, Christopher G. Cross, Thomas V. Thimons, Thomas P. Unites
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Patent number: 5902755Abstract: A ternary composite with thermal stability of up to at least 200.degree. C. Is formed using a thermally stable matrix resin, high tensile fibers, and borosilicate or sodium tetra borate glass particulates. The composite has stability to acids, toxic wastes and may be formed into sheets, shapes, tubes, containers, flooring materials and the like for use in aerospace, defense, automotive, industrial, nuclear containment or simply building material applications.Type: GrantFiled: April 28, 1997Date of Patent: May 11, 1999Assignee: Tox-Wastech, Inc.Inventors: Richard A. Driggett, William C. Scott
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Patent number: 5883020Abstract: A thermal and acoustical insulation product prepared from a mixture of fiberglass, scrap nylon of less than 0.25" in length and a thermo-setting resin. The insulation product is in a ductliner or molded form. The fiberglass will generally be in a concentration of from 20 to 80 percent by weight of the product; the nylon will be from 1 to 30 percent by weight of the product; and the thermo-setting resin will be from 5 to 35 percent by weight of the product.Type: GrantFiled: July 3, 1996Date of Patent: March 16, 1999Assignee: C.T.A. AcousticsInventors: Matthew Bargo, Edward Koperdak
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Patent number: 5879794Abstract: A method of preparing an adhesive composite is provided where a fluoropolymer having nodes and interconnected fibrils with a void volume formed from the node and interconnected fibril structure is at least partially filled with a paste formed from a thermoset or thermoplastic adhesive and a particulate vapor phase formed inorganic filler having uniform surface curvature, sufficient adhesive and filler are present to provide a composite having between about 5 to about 40 volume percent polymeric substrate, 10-95 volume percent adhesive and filler imbibed within the voids of said substrate and 5 to 85 volume percent inorganic filler is contained within the composite. In the composite, the ratio of mean flow pore size to largest particle size is at least above 0.7; or the ratio of mean flow pore size to average particle size is greater than 1.5; or the ratio of minimum pore size to average particle size is at least above 0.8; or the ratio of minimum pore size to largest particle size is at least above 0.4.Type: GrantFiled: November 8, 1996Date of Patent: March 9, 1999Assignee: W. L. Gore & Associates, Inc.Inventor: Joseph E. Korleski, Jr.
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Patent number: 5837624Abstract: To enhance the tear strength without increasing the thickness, a woven glass cloth having a mass of 15 to 30 g/m.sup.2, for use as a base material for printed wiring board material, is characterized in that the weft or warp is provided by a 75 denier or more strand, thicker than the warp, and thread count of the thicker strand per unit length is set smaller than that of the other strand.Type: GrantFiled: October 15, 1996Date of Patent: November 17, 1998Assignees: Matsushita Electric Works, Ltd., Nitto Boseki Co., LTd.Inventors: Kozo Sakaguchi, Fumio Nagamine, Keita Miyasato, Hiromasa Hattori, Tatsuya Watanabe, Akinori Hibino
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Patent number: 5804277Abstract: A fiber reinforced composite structure and method for fabricating the composite, are described wherein four sets of mechanically flexible fibers are interwoven in a three-dimensional woven structure wherein each fiber is woven through the structure generally along one of the four directions defined generally parallel to a body diagonal of a cube, and wherein the woven structure is impregnated with polymeric, metallic or ceramic matrix material to form a composite material which is braced against deformation by shear applied in any orientation.Type: GrantFiled: July 1, 1996Date of Patent: September 8, 1998Assignee: The United States of America as represented by the Secretary of the Air ForceInventor: Kenneth H. G. Ashbee
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Patent number: 5759658Abstract: A composite panel is provided which includes a resin matrix having embedded therewithin alternating layers of particulates and flexible sheeting. The composite panel is capable of supporting its own weight and exhibits impact resistance and shatter resistance. Preferably, the resin is transparent, the particulates are decorative, and the flexible sheeting becomes transparent upon curing of the resin. The composite panels are included within articles such as tables, desks, other furniture, vertical partitions, decorative panels, doors, windows and floors. Also included is a method of making the composite panels by molding layers of these materials within an open mold.Type: GrantFiled: April 26, 1996Date of Patent: June 2, 1998Assignee: Tables International CorporationInventor: Richard M. Piekos
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Patent number: 5698479Abstract: Glass fiber for non-woven fabric base material of a laminate having a surface treated by sizing agent essentially comprising silane coupling agent and dispersing agent, and said silane coupling agent including epoxy-silane and styryl amino-silane.Type: GrantFiled: August 16, 1996Date of Patent: December 16, 1997Assignee: Shin-Kobe Electric Machinery Co., Ltd.Inventors: Masaru Ogata, Masayuki Noda, Ken-ichi Kariya, Masayuki Arioka, Masaru Tachiiri, Masaaki Yoshida
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Patent number: 5650231Abstract: A polymeric resin for optical fiber strips is formed from a mixture comprising a first base polymer selected from an epoxy acrylate and a urethane acrylate and a copolymer in a proportion of between 0.5% and 20% by weight of said mixture which is compatible with said first polymer and carries polysiloxane chains.Type: GrantFiled: June 6, 1995Date of Patent: July 22, 1997Assignee: Alcatel CableInventors: Jean-Yves Barraud, Sophie Gervat
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Patent number: 5620789Abstract: The invention pertains to a composition useful for curing a polyepoxide or advanced epoxy resin consisting essentially of (A) a curing agent capable of reacting with a polyepoxide at elevated temperatures; and (B) boric acid in an amount of from about 0.01 to about 2.0 parts of polyepoxide.Type: GrantFiled: July 26, 1995Date of Patent: April 15, 1997Assignee: The Dow Chemical CompanyInventors: Joseph Gan, James L. Bertram
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Patent number: 5616405Abstract: Disclosed is a prepreg which is suited for preparing honeycomb sandwich panels, by which the formation of pores in the interlayer zones in the cured composite can be reduced. The prepreg of the present invention comprises a resin composition including an epoxy resin, a curing agent and a solid rubber, and a woven fabric made of reinforcing fibers, the meshes of the woven fabric being crushed such that said prepreg has a cover factor K.sub.p of 97-99.9%. Also disclosed is a reinforcing fabric comprising warps and woofs which are multifilament yarns made of carbon fibers, the widths W (mm) and finenesses D (d:denier) of the warp and woof satisfying the equation of:W=k.multidot.(D/.rho.).sup.5/9(wherein k represents 3.5.times.10.sup.-2 -10.0.times.10.sup.-2 (mm.multidot.d.sup.-5/9) and .rho. represents specific gravity of said carbon fibers), the woven fabric having a cover factor K.sub.c of 90.0-99.8%.Type: GrantFiled: January 4, 1995Date of Patent: April 1, 1997Assignee: Toray Industries, Inc.Inventors: Hajime Kishi, Nobuyuki Odagiri, Tokuo Tazaki, Hideo Nagata, Takeshi Terashita, Akira Nishimura, Hiroyasu Kato
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Patent number: 5614126Abstract: The invention relates to a substantially solventless curable resin composition, in particular for the fabrication of prepregs, which contains more than 45% by weight of substances which are solid at ambient temperature at least or at lower temperature, and which, in addition to comprising customary modifiers, comprises solid epoxy resins or a mixture of liquid and solid epoxy resins, at least one initiator which is sensitive to UV radiation for the polymerisation of the epoxy resins and has the formula I ##STR1## wherein a and b are each independently of the other 1 or 2, R.sup.1 ist a .pi.-arene, R.sup.2 is a .pi.-arene, an indenyl anion or a cyclopentadienyl anion, [X].sup..crclbar. is an anion [LQ.sub.m ].sup..crclbar.Type: GrantFiled: May 24, 1995Date of Patent: March 25, 1997Assignee: Ciba-Geigy CorporationInventors: Urs Gruber, Aloysius H. Manser
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Patent number: 5605745Abstract: The incorporation of 2 to 35 .mu.m particles of a differentially soluble engineering thermoplastic into heat curable epoxy resin systems significantly increases the toughness of such systems without loss of other desirable properties. These toughened epoxy resin systems are useful in preparing carbon fiber reinforced composites having compression strength after impact (CAI) of greater than 45. Ksi 310 MPa after a 1500 in-lb/in impact.Type: GrantFiled: December 29, 1994Date of Patent: February 25, 1997Assignee: Cytec Technology Corp.Inventors: Hans G. Recker, J. Timothy Hartness, Thomas Folda, Helmut Tesch, Thomas Weber, Jack D. Boyd
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Patent number: 5599612Abstract: A prepreg precursor including a carbon fiber woven fabric having applied to the fabric between about 0.5 to about 10 wt % of a stabilizer material for stabilizing the structural form of the fabric. Prepregs can then be produced using the woven fabric. Undesired settlement of matrix resin from the surface of the woven fabric is thus prevented. Hence, compared with a prepreg prepared using conventional woven fabric, a prepreg prepared by using the woven fabric of the invention can hold its tackiness for a long time and can be used to produce a fiber reinforced composite material excellent in smoothness without being devoid of surface resin.Type: GrantFiled: March 22, 1995Date of Patent: February 4, 1997Assignee: Toray Industries, Inc.Inventors: Toshio Muraki, Masazumi Tokunou, Ryuji Sawaoka, Masahiko Hayashi, Toshiaki Higashi, Tokuo Tazaki