Abstract: A fluorinated ether compound represented by A-O—(Rf1O)m—Rf2—[C(O)N(R1)]p-Q1-C(R2)[-Q2-SiR3nL3-n]2, wherein A is a C1-20 perfluoroalkyl group, Rf1 is a linear fluoroalkylene group, m is an integer of from 2 to 500, Rf2 is a linear fluoroalkylene group, R1 is a hydrogen atom or an alkyl group, p is 0 or 1, Q1 is a single bond or an alkylene group, R2 is a hydrogen atom, a monovalent hydrocarbon group or the like, Q2 is an alkylene group, R3 is a hydrogen atom or a monovalent hydrocarbon group, L is a hydrolyzable group, and n is an integer of from 0 to 2 is provided. A fluorinated ether composition and a coating liquid capable of forming a surface layer excellent in initial water/oil repellency, fingerprint stain removability, abrasion resistance, light resistance and chemical resistance, an article having a surface layer, and a method for producing it are also provided.

Abstract: The disclosure provides partially fluorinated piperazine carboxamide compounds having terminal fluoroaliphatic groups and polysiloxane groups. This invention also relates to polymer compositions comprising the fluorochemical composition and shaped articles made from the thermoplastic composition. See Formula (I).

Abstract: A surface-modified polymer composition formed from an oligomeric or polymeric additive and a base polymer is disclosed. The surface-modified polymer provides non-fouling and/or non-thrombogenic properties. The composition is particularly useful in articles and materials for medical applications.

Abstract: A resin formed body 10 having a surface in which hydrophobic fine particles 11 are distributed, the hydrophobic fine particles having a BET specific surface area of not less than 300 m2/g. Despite the hydrophobic fine particles are added in a small amount, the resin formed body exhibits a high water-sliding property and can be used also in the form of a film and a bottle.

Abstract: A bodyside liner material for use in disposable absorbent personal care products has an average material plane and includes a plurality of raised areas extending in a z-direction from the average material plane; a plurality of apertures through the liner material; a hydrophobic treatment agent disposed on the raised areas; and a plurality of land areas disposed between the raised areas, wherein the land areas are hydrophilic. The bodyside liner material can also include a plurality of raised areas extending in a z-direction from the average material plane; a plurality of depressed areas alternating with the plurality of raised areas, wherein the depressed areas extend in the opposite z-direction from the average material plane, and wherein the depressed areas are hydrophilic; a plurality of apertures through the liner material, wherein the apertures are disposed only in the depressions; and a hydrophobic treatment agent disposed on the raised areas.

Abstract: A surge material for use in disposable absorbent personal care products includes a wearer-facing surface, a plurality of elongate grooves in the wearer-facing surface, and a plurality of apertures disposed in the grooves and extending through the surge material. The surge material can also have an average material plane and including a plurality of ridges extending in a z-direction from the average material plane, a plurality of grooves alternating with the plurality of ridges, wherein the grooves extend in the opposite z-direction from the average material plane, and a plurality of apertures through the surge material, wherein the apertures are disposed only in the grooves. The surge material can also include a hydrophobic treatment agent disposed on the ridges and a hydrophilic treatment agent disposed within the grooves.

Abstract: A pattern quality management chart includes a chart substrate which is made of the same material as a substrate patterned by a first region having a predetermined affinity to a functional liquid for pattern formation and a second region having an affinity lower than the predetermined affinity, and at least one unit region group formed on the surface of the chart substrate.

Abstract: A masked etching process can prepare patterned nanocellulose for use in conformal electronics such as electrodermal structures might be adhered to human skin.

Abstract: Coating compositions which include a blend of a fluorochemical and a particulate additive comprising a bimodal size distribution of inorganic nanoparticles are provided. The bimodal distribution of inorganic nanoparticles may include a quantity of smaller nanoparticles having an average size distribution of between about 1 to about 15 nm, and a quantity of larger nanoparticles having an average size distribution of between about 40 to about 500 nm. The smaller and larger nanoparticles may be present in a ratio of the smaller sized particles to the larger sized particles of at least 1.2, with the total amount of nanoparticles being present in an amount of between about 0.1 to about 10 wt. % based on total composition weight.

Abstract: A fluorine-containing polymer having (a) a repeating unit derived from a fluorine-containing monomer indicated by the formula CH2?C(—X)—C(?O)—Y—Z—Rf, (b) a repeating unit derived from a cyclic-hydrocarbon-group-containing acrylate ester monomer indicated by the formula CH2?CQ11—C(?O)—O-Q12, and (c) a repeating unit derived from an aliphatic-hydrocarbon-group-containing acrylate ester monomer indicated by the formula CH2?CQ21—C(?O)—O-Q22. The fluorine-containing polymer is produced by polymerizing in the presence of one or both of (d) a silicon-containing monomer and a silicon-containing chain transfer agent.

Abstract: A method for lithography patterning includes providing a substrate; forming a material layer over the substrate; exposing a portion of the material layer to a radiation; and removing an unexposed portion of the material layer in a developer, resulting in a patterned material layer. The developer has a Log P value greater than 1.82 and contains an organic solvent. In an embodiment, the organic solvent is an n-butyl acetate derivative that is represented by the formula CH3R5CHR4CHR3CHR2COOCH2R1, wherein R1, R2, R3, R4, and R5 are each selected from a group consisting of hydrogen, a methyl group, an ethyl group, and a fluoroalkyl group.

Abstract: Laminates are described having a durable outer film surface for use in making lightweight liquidproof articles, including articles of apparel, such as outerwear garments. A method of making the laminate and a lightweight outerwear garment having an abrasion resistant exterior film surface is described.

Abstract: Laminates are described having a durable outer film surface for use in making lightweight liquidproof articles of apparel, such as outerwear garments. A method of making the laminate and a lightweight outerwear garment having an abrasion resistant exterior film surface is described.

Abstract: Methods of forming a nanocellulose composite are provided. The methods can include blending a copolymer with a nanocellulose to form the nanocellulose composite. The copolymer can be a reaction product of a first monomer, a second monomer, and a third monomer. The first monomer is a hydrophilic monomer, the second monomer is a cellulose-reactive monomer and the third monomer is an amphiphobic monomer.

Abstract: An article of manufacture comprising a substrate and an outer polymer coating on the substrate. The polymer coating comprises an oleophobic grafted polymer comprising a crosslinked fluoroelastomer group. A perfluorinated polyether is grafted to the crosslinked fluoroelastomer group.

Abstract: Disclosed is a copolymer of a polyfluoroalkyl alcohol (meth)acrylic acid derivative represented by the formula: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cOCOCR?CH2 (R: H or CH3, n: 1 to 6, a: 1 to 4, b: 1 to 3, and c: 1 to 3), and a (meth)acrylic acid polyoxyalkylene ester represented by the formula: R1(OR2)p(OR3)qOCOCR?CH2 (R: H or CH3; R1: H, an alkyl group, or an aromatic group; R2 and R3: alkylene groups having 1 to 6 carbon atoms; p: 2 to 50, q: 0 or 1 to 50), and also disclosed is a water- and oil-repellent comprising this fluorine-containing copolymer as an active ingredient. The water- and oil-repellent comprising this fluorine-containing copolymer as an active ingredient can be used as a stain-proof-type water- and oil-repellent that can apply effective stain-proof finish and stain removal finish to fiber fabrics, and that has excellent washing durability.

Abstract: Disclosed is a fluorine-containing composition which contains a fluorine-containing polymer that has repeating units respectively derived from (A) a fluorine-containing monomer that is an alpha-chloroacrylate having a fluoroalkyl group, (B) a monomer that has a linear or branched hydrocarbon group but does not have a fluoroalkyl group, and (C) a monomer that has a cyclic hydrocarbon group but does not have a fluoroalkyl group. This fluorine-containing composition is capable of providing a base such as a fiber product with excellent water repellency, especially strong water repellency.

Abstract: A stain resistant, oil and water repellent composition comprising a copolymer prepared from fluorinated methacrylate, carbonate methacrylate, and methacrylic acid or salt thereof, a method of providing stain resistance, oil and water repellency to substrates, and a treated substrate.

Abstract: Coating compositions which include a blend of a fluorochemical and a particulate additive comprising a bimodal size distribution of inorganic nanoparticles are provided. The bimodal distribution of inorganic nanoparticles may include a quantity of smaller nanoparticles having an average size distribution of between about 1 to about 15 nm, and a quantity of larger nanoparticles having an average size distribution of between about 40 to about 500 nm. The smaller and larger nanoparticles may be present in a ratio of the smaller sized particles to the larger sized particles of at least 1.2, with the total amount of nanoparticles being present in an amount of between about 0.1 to about 10 wt. % based on total composition weight.

Abstract: An article comprising a microporous membrane. A first porous fabric is laminated to a first side of the microporous membrane. A second porous fabric is laminated to a second opposite side of the microporous membrane to form a laminate with the membrane and the first porous fabric. The laminate has two fabric sides separated by the microporous membrane. A treatment material is applied to the laminate to form a treated laminate. The treated laminate has an oil resistance of at least a number 7 determined by AATCC 118 testing on both fabric sides and has an air permeability through the treated laminate of at least 0.01 CFM per square foot determined by ASTM D737 testing.

Abstract: An aqueous emulsion composition comprising: i) partially fluorinated copolymer; ii) one or more co-solvents; iii) one or more surfactants; and optionally iv) one or more defoamers; wherein the co-solvent comprises fatty acids, esters of fatty acids, glycerides, glycols, or mixture thereof, and is useful for providing water and oil repellency to fibrous substrates without excessive pad roller build-up during application.

Abstract: The present invention relates to fibers exhibiting a water contact angle of above 150° and water contact angle hysteresis of below 15°, methods of producing the same, and applications thereof. The present invention further relates to superhydrophobic fiber mats, methods of producing the same, and applications thereof.

Abstract: Disclosed herein are surface-modified membranes and other surface-modified substrates exhibiting switchable oleophobicity and oleophilicity in aqueous media. These membranes and substrates may be used for variety of applications, including controllable oil/water separation processes, oil spill cleanup, and oil/water purification. Also provided are the making and processing of such surface-modified membranes and other surface-modified substrates.

Abstract: Disclosed is a fluorine-containing polymer prepared by polymerizing: (I) a polyfluoroalkyl group-containing (meth)acrylate, in the presence of: (II) an isocyanate compound blocked with a pyrazole compound or a malonate ester. A water- and oil-repellent composition containing the fluorine-containing polymer can impart the excellent water- and oil-repellency, and excellent durability thereof to substrates.

Abstract: The present invention provides a fabric having soil resistance and no oil stains after wiping and a manufacturing method thereof. The fabric of the present invention comprises an underlayer and a soil-resistant protection film, which can effectively prevent oil corrosion, penetration, and permeation of the surface of the fabric, thus resulting in no oil stains after wiping. The manufacturing method of the present invention comprises the steps of dyeing, setting, performing an underlayer surface treatment to form an underlayer on a surface of the fabric, and performing a soil resistance processing treatment to form a soil-resistant protection film on the surface of the underlayer.

Abstract: A composition for imparting surface properties to substrates comprising a polymer of at least one polyurethane having at least one urea linkage prepared by: (i) reacting (a) at least one diisocyanate, polyisocyanate, or mixture thereof, having isocyanate groups, and (b) at least one fluorinated compound selected from the formula (I): Rf1-L-X??(I) wherein Rf1 is a monovalent, partially or fully fluorinated, linear or branched, alkyl radical having 2 to 100 carbon atoms; optionally interrupted by 1 to 50 oxygen atoms; wherein the ratio of carbon atoms to oxygen atoms is at least 2:1 and no oxygen atoms are bonded to each other; L is a bond or a linear or branched divalent linking group having 1 to about 20 carbon atoms, said linking group optionally interrupted by 1 to about 4 hetero-radicals selected from the group consisting of —O—, —NR1—, —S—, —SO—, —SO2—, and —N(R1)C(O)— wherein R1 is H or C1 to C6 alkyl, and said linking group optionally substituted with CH2Cl; X is an isocyanate-reactive group selec

Abstract: Disclosed is a fluorine-containing polymer prepared by polymerizing (I) a polyfluoroalkyl group-containing (meth)acrylate which is substituted at alpha-position, in the presence of (II) a blocked isocyanate compound. A water- and oil-repellent composition containing the fluorine-containing polymer can impart the excellent water- and oil-repellency, and excellent durability thereof to substrates.

Abstract: A fluoropolymer composition comprising monomers copolymerized in the following percentages by weight: (a) from about 20% to about 95% of a fluoroalkyl monomer, or mixture of monomers, (b) from about 5% to about 80% of at least one of: (i) an alkyl (meth)acrylate monomer having a linear, branched or cyclic alkyl group of from about 6 to about 18 carbons; or (ii) one or more ionizable water solvatable monomers; and (c) from about 0.05% to about 2% non-fluorinated polymerizable nanoparticles.

Abstract: A stain resistant, oil and water repellent composition comprising a copolymer prepared from fluorinated methacrylate, carbonate methacrylate, and methacrylic acid or salt thereof, a method of providing stain resistance, oil and water repellency to substrates, and a treated substrate.

Abstract: Highly durable hydrophobic, oleophobic, and anti-icing coatings and methods of their preparation and use are described herein.

Abstract: A waterproof fabric (20) made such by the application of a protective film (10), coupled or coated on a side of the fabric (20). When the film (10) is already produced by extrusion in advance, it is attached onto the fabric and may comprise an adhesive layer (12) to the extruded film, or the adhesive layer may be coated on the fabric (20). The water/oil repellent and waterproof fabric (20) may also be obtained by coating at least one layer of materials made up of fluorocarbon, polyurethane, acrylic resins, with or without the addition of hollow microspheres of thermoplastic material.

Abstract: A surface treatment agent, which can impart the excellent water- and oil-repellency, soil resistance and feeling to the substrate, is obtained from a fluorine-containing polymer which contains: (A) a monomer which comprises; (A1) a fluorine-containing monomer of the formula: CH2?C(—X)—C(?O)—Y—Z—Rf wherein X is a hydrogen atom, a monovalent organic group, or a halogen atom, Y is —O— or —NH—, Z is a direct bond or a divalent organic group, and Rf is a fluoroalkyl group having 1 to 20 carbon atoms, and (A2) a (meth)acrylate monomer having a cyclic hydrocarbon group, and (B) at least one functional organopolysiloxane selected from the group consisting of a mercapto-functional organopolysiloxane, a vinyl-functional organopolysiloxane, a (meth)acrylamide-functional organopolysiloxane and a (meth)acrylate-functional group.

Abstract: The invention relates to a composition which, when mixed with a polymer composition, allows for the formation of a continuous and cohesive film. The film is characterized in that it provides water, grease and oil resistance, provides a water vapour barrier and can be used as wax replacement treatment and a top coat for flexible packaging, but also on other substrates. This film is formed at a very fast set speed without the need of thermal energy. The composition contains i) a salt of one or more of myristic, palmitic and stearic acid; and preferably also ii) a C9-C18 fatty acid complex of a metal ion, said metal ion having an oxidation state of at least 3. The invention also provides processes and coated substrates.

Abstract: A water- and oil-repellent agent is an aqueous emulsion containing: (I) a fluorine-containing copolymer, (II) a surfactant, and (III) an aqueous medium. The fluorine-containing copolymer contains repeating units derived from (a) a fluorine-containing monomer containing a fluoroalkyl group having 1 to 6 carbon atoms and (b) a fluorine-free monomer selected from the group consisting of vinyl halide and vinylidene halide, wherein the fluorine-containing copolymer has a melt viscosity of 1,000 to 100,000 cP at a temperature of 100° C. under a load of 25 kgf/cm2.

Abstract: Disclosed in this specification is an aqueous dispersion for treating a textile. The dispersion generally includes surface-functionalized inorganic oxides in combination with a fluorochemical. Significantly lower concentrations of fluorochemicals are present in comparison to prior art dispersions.

Abstract: A textile having high fluorine adhesion rate, and excellent water- and oil-repellency can be obtained by a method of producing a treated textile, comprising steps of: (1) preparing a treatment liquid comprising a water- and oil-repellent agent which comprises at least one fluorine-containing compound selected from the group consisting of a fluorine-containing polymer or a fluorine-containing low molecular weight compound, (2) adjusting pH of the treatment liquid to at most 7, (3) applying the treatment liquid to a textile, (4) treating the textile with steam, and (5) washing the textile with water and dehydrating the textile, wherein the treatment liquid comprises a thermally gelling substance and a salt.

Abstract: A water- and oil-repellent agent is an aqueous emulsion containing a fluorine-containing polymer. The fluorine-containing polymer comprises (a) a fluorine-containing monomer, and (b) a crosslinkable monomer, wherein the monomers (a) and (b) are polymerized in the presence of a chain transfer agent to produce the fluorine-containing polymer.

Abstract: A method is described for manufacturing a finish formulation for the hydrophobic and/or oleophobic finishing of surfaces, comprising a dispersant incorporating dispersed, activated particles with hydrophobic and/or oleophobic surface groups and a binder, in which particles with hydrophobic and/or oleophobic surface groups are comminuted in the dispersant for activation, and the binder is added before or after activation. The obtained finish formulation clearly improves the physical properties of a transparent finish while maintaining very good hydrophobing/oleophobing. It is suitable for finishing all surfaces, in particular for finishing fibers or textiles of all kinds.

Abstract: A textile having high fluorine adhesion rate, and excellent water- and oil-repellency can be obtained by a method of producing a treated textile, comprising steps of: (1) preparing a treatment liquid comprising a water- and oil-repellent agent which comprises at least one fluorine-containing compound selected from the group consisting of a fluorine-containing polymer or a fluorine-containing low molecular weight compound, (2) adjusting pH of the treatment liquid to at most 7, (3) applying the treatment liquid to a textile, (4) treating the textile with steam, and (5) washing the textile with water and dehydrating the textile, wherein the treatment liquid comprises a thermally gelling substance.

Abstract: In order to provide grease, oil and wax resistance to a paper substrate, a coating containing a binder, a filler material and calcium carbonate is used. The coating of the invention is essentially free from fluorocarbons, which are considered harmful to human and animal populations, and surfactants and other chemicals which may alter the color of the coated paper. The coated paper has a GE brightness level between approximately 50 and approximately 90, while providing superior grease, oil and wax resistance.

Abstract: An article includes a microporous membrane. A porous fabric is laminated to the microporous membrane to form a laminate with a membrane side and a fabric side. A treatment material is applied to the laminate to form a treated laminate. The treated laminate having an oil resistance of at least a number 7 determined by AATCC 118 testing on both the membrane side and the fabric side. The treated laminate also has an air permeability through the treated laminate of at least 0.01 CFM per square foot determined by ASTM D737 testing.

Abstract: Compositions and methods for treating substrates, such as fibrous materials, are disclosed. Such compositions and methods can be used to impart or maintain a level of oil repellency and/or water repellency in fibrous substrates such as paper-based materials and/or textiles. In general, such compositions can utilize a copolymer having a plurality of polycationic segments, which can be joined by various other polymeric segments such as silicones and/or hydrophilic polymeric segments. The copolymer can be formulated as a highly-branched polymer, which can have substantivity to a fibrous material to impart oil repellency and/or water repellency. In several instances, the copolymer can be formulated to be fluorine-free. Various details of such copolymers are discussed, as well as methods of utilizing and making such copolymers.

Abstract: Compositions comprising cationic compounds having fluorinated ether groups and hydrolyzable silane groups are provided, the compounds having the formula: (I)

Abstract: The present invention relates to a urethane-based coating having nanoparticles for improving the characteristics of a papermaking process belt, roll cover and belts used in textile applications. For example, the present invention improves resistance to flex fatigue, crack propagation, groove closure and wear characteristics of urethane coatings on such belts and roll coverings. The present invention also improves the resistance to water and oil permeation characteristics of urethane coated belts and roll coverings.

Abstract: Excellent water repellency and Oil repellency are imparted to a textile by a method including (1) preparing a treatment liquid comprising a water- and oil-repellent agent, (2) adjusting pH of the treatment liquid to at most 7, (3) applying the treatment liquid to a textile, (4) treating the textile with steam, and (5) washing the textile with water and dehydrating the textile, wherein the water- and oil-repellent agent comprises at least one fluorine-containing compound selected from the group consisting of a fluorine-containing polymer and a fluorine-containing low molecular weight compound, and the water- and oil-repellent agent or the treatment liquid contains a cationic emulsifier and/or a salt.

Abstract: Compositions and methods for treating substrates, such as fibrous materials, are disclosed. Such compositions and methods can be used to impart or maintain a level of oil repellency and/or water repellency in fibrous substrates such as paper-based materials and/or textiles. In general, such compositions can utilize a copolymer having a plurality of polycationic segments, which can be joined by various other polymeric segments such as silicones and/or hydrophilic polymeric segments. The copolymer can be formulated as a highly-branched polymer, which can have substantivity to a fibrous material to impart oil repellency and/or water repellency. In several instances, the copolymer can be formulated to be fluorine-free. Various details of such copolymers are discussed, as well as methods of utilizing and making such copolymers.

Abstract: The invention relates to fabrics, comprising fibers and a coating that is covalently bound on the surface of the fibers, characterized in that the fabrics are temperature-stable at 200° C. The invention further relates to methods for the production thereof, fuel cells and gas diffusion layers comprising the fabrics, and to the use thereof in fuel cells and gas diffusion layers.

Abstract: Disclosed is a versatile method to produce superhydrophobic surfaces by combining electrospinning and initiated chemical vapor deposition (iCVD). A wide variety of surfaces, including electrospun polyester fibers, may be coated by the inventive method. In one embodiment, poly(caprolactone) (PCL) was electrospun and then coated by iCVD with a thin layer of hydrophobic polymerized perfluoroalkyl ethyl methacrylate (PPFEMA). In certain embodiments said coated surfaces exhibit water contact angles of above 150 degrees, oleophobicities of at least Grade-8 and sliding angles of less than 12 degrees (for a water droplet of about 20 mg).

Abstract: Disclosed are embodiments and methods relating to the treatment of textile, such as a textile substrate, with an aqueous dispersion of surface-functionalized particles and a fluorochemical, or a textile substrate treated with an aqueous dispersion of surface-functionalized particles, a fluorochemical, and a flame retardant chemical. Textiles treated in accordance with the disclosed embodiments (e.g., fluorine concentration of from 20 to 900 ppm) demonstrate an average burn rate less than about 4.0 inch/minute, and an average weight loss is less than about 40% of the original weight. During burning of the treated textile, flaming drips extinguish (on average) in less than about 2 seconds, or does not increase the peak heat release rate by more than about 70%, and the mass loss rate by more than about 50%.

Abstract: A fluoropolymer composition comprising monomers copolymerized in the following percentages by weight: (a) from about 20% to about 95% of a fluoroalkyl monomer, or mixture of monomers, (b) from about 5% to about 80% of at least one of: (i) an alkyl (meth)acrylate monomer having a linear, branched or cyclic alkyl group of from about 6 to about 18 carbons; or (ii) one or more ionizable water solvatable monomers; and (c) from about 0.05% to about 2% non-fluorinated polymerizable nanoparticles.