And Aluminum Compound (e.g., Clay, Aluminum Oxide, Etc.) Patents (Class 501/100)
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Patent number: 11208354Abstract: The present invention relates to a zirconia mullite refractory composite comprising 55 wt.-% to 65 wt.-% Al2O3, 15 wt.-% to 25 wt.-% SiO2, 15 wt.-% to 25 wt.-% ZrO2 and less than 3 wt.-% raw material based impurities, whereby the mineralogical composition of the composite comprises 65 wt.-% to 85 wt.-% mullite and 15 wt.-% to 35 wt.-% zirconia.Type: GrantFiled: November 3, 2016Date of Patent: December 28, 2021Assignee: ImerTech SASInventors: Marie-Laure Bouchetou, Olivier Joubert, Jacques Poirier, Michael Weissenbacher
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Patent number: 10961160Abstract: A fluoride sintered body suitable for a moderator which moderates high-energy neutrons so as to generate neutrons for medical care with which an affected part of the deep part of the body is irradiated to make a tumor extinct comprises MgF2 of a compact polycrystalline structure having a bulk density of 2.90 g/cm3 or more and as regards mechanical strengths, a bending strength of 10 MPa or more and a Vickers hardness of 71 or more.Type: GrantFiled: May 27, 2014Date of Patent: March 30, 2021Assignees: UNIVERSITY OF TSUKUBA, DAICO MFG CO., LTD.Inventors: Hiroaki Kumada, Tetsuyuki Nakamura, Takuji Shigeoka, Takeshi Ikeda
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Patent number: 10646129Abstract: Methods and an apparatus are provided, which may be used for determining the prognosis and/or diagnosis of a subject demonstrating burst suppression, whereby the subject has or is at risk of developing brain damage. In particular, the methods and apparatus determine the prognosis and/or diagnosis through the detection of bursts from a reading of electrical and/or electromagnetic activity of the subject's brain, such as an electroencephalogram (EEG), and subsequent analysis of one or more burst metrics derived therefrom.Type: GrantFiled: November 20, 2014Date of Patent: May 12, 2020Assignee: THE COUNCIL OF THE QUEENSLAND INSTITUTE OF MEDICAL RESEARCHInventors: Michael Breakspear, James Roberts, Sampsa Vanhatalo
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Patent number: 10429130Abstract: A refractory kiln car formed using a refractory composition has excellent resistance to high-temperature thermal shock and creep. The refractory composition is based primarily on chamotte having controlled particle sizes, and may also include mullite, fused silica, calcined alumina and microsilica, having controlled particle sizes. The refractory composition includes an aqueous colloidal silica binder that provides excellent castability and binding between the ingredients following drying.Type: GrantFiled: January 11, 2018Date of Patent: October 1, 2019Assignee: Magneco/Metrel, Inc.Inventors: Eric Boring, Michael W. Anderson, Daniel Snyder, Lara Binz
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Patent number: 9994486Abstract: A refractory composition yields refractory articles having excellent resistance to high-temperature thermal shock and creep. The refractory composition is based primarily on chamotte having controlled particle sizes, and may also include mullite, fused silica, calcined alumina and microsilica, having controlled particle sizes. The refractory composition includes an aqueous colloidal silica binder that provides excellent castability and binding between the ingredients following drying.Type: GrantFiled: March 16, 2017Date of Patent: June 12, 2018Assignee: Magneco/Metrel, Inc.Inventors: Michael W Anderson, Daniel Snyder, Lara Binz, Eric Boring
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Patent number: 9879168Abstract: There is provided a method for producing hexagonal boron nitride, including a heating step of heating a mixture containing boron carbide and an alkaline earth metal compound under an ammonia atmosphere at 1300-1500° C. to obtain a product containing hexagonal boron nitride, wherein a molar ratio of the boron carbide to the alkaline earth metal compound in the mixture is 0.5-2.0.Type: GrantFiled: January 8, 2015Date of Patent: January 30, 2018Assignee: Denka Company LimitedInventors: Junichi Tatami, Midori Sotokawa, Koki Ikarashi, Hideki Hirotsuru
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Patent number: 9683782Abstract: Methods for forming monolithic refractory compositions may include providing a particulate refractory composition including 2 to 90 mass-% alumina, aluminosilicate, or mixtures thereof; 2 to 70 mass-% silicon carbide; 2 to 10 mass-% carbon; 1 to 10 mass-% Si powder; 1 to 3 mass-% microsilica; and up to 5 mass-% ferrosilicon. The methods may further include adding an amount of water to the particulate refractory composition to form a uniform mixture, installing the uniform mixture and allowing it to set, such that the monolithic refractory composition is required, and heat-treating the set mixture at a temperature no higher than 1200° C. under atmospheric conditions to form a monolithic refractory composition. The methods may optionally include heat-treating the obtained monolithic refractory composition to form silicon carbide whiskers within the monolithic refractory composition.Type: GrantFiled: April 17, 2014Date of Patent: June 20, 2017Assignee: Calderys FranceInventors: Patrick Malkmus, Jerome Soudier
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Patent number: 9416055Abstract: A composition suitable for firing to obtain a ceramic material therefrom may include from about 1 to about 40 wt. % based on the total dry weight of the composition a first particulate material having a Mohs hardness of at least about 8.5 and a d50 of from about 7 ?m to about 500 ?m. The composition may include at least about 50 wt. % based on the total dry weight of the composition a second particulate material comprising alumina. The composition may include from 0 to about 10 wt. % based on the total dry weight of the composition a sintering aid. A green body or ceramic material may be formed from the composition. Ballistic armor may be formed from the composition or may include the ceramic material.Type: GrantFiled: June 21, 2013Date of Patent: August 16, 2016Assignee: Imerys Ceramics FranceInventors: Gilles Gasgnier, Wen Zhang
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Patent number: 9182291Abstract: A device for measuring the temperature in molten metals contains a thermocouple arranged in a ceramic tube that is closed on one side, and has an external protective body that surrounds the tube, forming an annular space between the outer surface of the tube and the inner surface of the protective body. The protective body is formed of a mixture containing 75 to 90% by weight aluminum oxide, 2 to 10% by weight silicon oxide, 7 to 15% by weight graphite, 0.1 to 1% by weight Fe2O3, 0.1 to 1% by weight (K2O+Na2O), and 0.1 to 1% by weight MgO.Type: GrantFiled: March 14, 2013Date of Patent: November 10, 2015Assignee: Heraeus Electro-Nite International N.V.Inventors: Martin Kendall, Marek Grabowy
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Patent number: 8975200Abstract: The present invention relates to catalysts, to processes for making catalysts and to chemical processes employing such catalysts. The catalysts are preferably used for converting acetic acid to ethanol. The catalyst comprises a precious metal and one or more active metals on a modified support that comprises cobalt.Type: GrantFiled: August 27, 2012Date of Patent: March 10, 2015Assignee: Celanese International CorporationInventors: Zhenhua Zhou, Heiko Weiner, Radmila Wollrab
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Patent number: 8728966Abstract: It is an object to provide an aluminum oxycarbide composition capable of suppressing oxidation of Al4O4C during use to maintain advantageous effects of Al4O4C for a long time. In an aluminum oxycarbide composition comprising Al4O4C crystals, the Al4O4C crystals have an average diameter of 20 ?m or more, based on an assumption that a cross-sectional area of each Al4O4C crystal during observation of the aluminum oxycarbide composition in an arbitrary cross-section thereof is converted into a diameter of a circle having the same area as the cross-sectional area. This aluminum oxycarbide composition can be produced by subjecting a carbon-based raw material and an alumina-based raw material to melting in an arc furnace and then cooling within the arc furnace.Type: GrantFiled: August 31, 2012Date of Patent: May 20, 2014Assignee: Krosakiharima CorporationInventors: Keiichiro Akamine, Joki Yoshitomi
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Patent number: 8618006Abstract: A cement free refractory mixture contains aluminum oxide, silicon carbide, fumed silica, aluminum metal, an anti-oxidant, reactive alumina, and a carbon-bearing material. The mixture can be formed by conventional techniques to create refractory articles to contain or direct the flow of liquid metals. Refractory articles formed by the mixture do not require firing to achieve an initial cure.Type: GrantFiled: January 31, 2012Date of Patent: December 31, 2013Assignee: Vesuvius Crucible CompanyInventors: Robert A. Pattillo, Samuel B. Bonsall
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Patent number: 8450228Abstract: In a carbon-containing refractory composed of a refractory aggregate, a carbon based raw material, and a carbon bond connecting between the refractory aggregate or the carbon based raw material, transition metal-containing nanoparticles having particle diameters of 1,000 nm or less and containing a transition metal are contained in the above-described carbon bond while being dispersed. When the carbon-containing refractory is heat-treated, flexible structures of carbon fiber-shaped textures having diameters of 50 nm or less are formed in the inside of a carbon bond and, thereby, an increase in strength, a reduction in modulus of elasticity, and a reduction in thermal expansion coefficient are facilitated. Therefore, a carbon-containing refractory exhibiting high thermal shock resistance, high abrasion resistance, and high corrosion resistance are provided.Type: GrantFiled: April 19, 2006Date of Patent: May 28, 2013Assignee: Krosaki Harima CorporationInventors: Katsumi Morikawa, Koichi Haren, Joki Yoshitomi, Toshiyuki Hokii, Keisuke Asano
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Patent number: 8357625Abstract: An object of the present invention is to provide a catalyst exhibiting excellent performance particularly in partial oxidation reaction. Another object is to provide a method for efficiently producing carboxylic acid or carboxylic anhydride through vapor-phase partial oxidation of an organic compound by use of an oxygen-containing gas in the presence of the catalyst. The catalyst contains (1) diamond; (2) at least one species selected from among Group 5 transition element oxides, collectively called oxide A; and (3) at least one species selected from among Group 4 transition element oxides, collectively called oxide B. The method for producing a carboxylic acid or a carboxylic anhydride includes subjecting an organic compound to vapor phase partial oxidation by use of an oxygen-containing gas in the presence of the catalyst, wherein the organic compound is an aromatic compound having one or more substituents in a molecule thereof, the substituents each including a carbon atom bonded to an aromatic ring.Type: GrantFiled: June 18, 2009Date of Patent: January 22, 2013Assignee: Mitsubishi Gas Chemical Company, Inc.Inventor: Atsushi Okamoto
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Publication number: 20120308813Abstract: A temperature-resistant ceramic hybrid material has a matrix made of calcium silicate hydrate. Carbon is embedded in the matrix. The carbon is predominantly composed of graphite particles having an ordered graphitic lattice structure and the carbon makes up a weight fraction of up to 40%. The matrix is composed of tobermorite and/or xonotlite and can contain wollastonite rods and/or granular silicate. The size of the graphite particles is 0.01-3 mm. The hybrid material is especially suitable for casting devices for non-ferrous metals.Type: ApplicationFiled: January 14, 2011Publication date: December 6, 2012Applicant: CALISTHERM VERWALTUNGS GMBHInventors: Klaus Hoelscher, Tobias Hoelscher, Wolf Huettner, Axel Lengen, Hans-Juergen Schneider, Winfried Stellmach
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Patent number: 8251129Abstract: In an operation of continuous casting of steel grade such as aluminum-killed steel where a nozzle clogging phenomenon is particularly likely to occur, it is intended to prevent adhesion of inclusions (typically, Al2O3) on a nozzle used in the casting operation, and clogging of the nozzle due to the inclusions. A refractory material 10 is arranged to define a part or an entirety of a molten steel-contacting surface of a continuous casting nozzle, wherein the refractory material 10 contains: a CaO component in an amount of 0.5 mass % or more; one or both of B2O3 and R2O (R is one selected from the group consisting of Na, K and Li) in an amount of 0.5 mass % or more; Al2O3 in an amount of 50 mass % or more; and free carbon in an amount of 8.0 to 34.5 mass %, and wherein a total amount of CaO, B2O3 and R2O is in the range of 1.0 to 15.0 mass %, and a mass ratio of CaO/(B2O3+R2O) is in the range of 0.1 to 3.0.Type: GrantFiled: May 13, 2010Date of Patent: August 28, 2012Assignee: Krosakiharima CorporationInventors: Katsumi Morikawa, Akinari Sasaki, Hiroshi Otsuka, Yuichi Tsukaguchi
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Patent number: 8227364Abstract: The present invention relates to a porous planting medium containing minerals and a method for preparing the same, and more particularly, to a porous planting medium prepared by using bentonite and/or zeolite and minerals for promoting plant growth as raw materials and a method for preparing the same. The porous planting medium containing minerals according to the present invention can provide places where plants can grow due to the pores therein and create the ideal environment for plant growth due to minerals used therein. Also, since it is installed in a building with plant seeds germinated therein, it can provide effects of interior decoration, wood bathing due to anion generation and a pleasant interior environment.Type: GrantFiled: December 22, 2008Date of Patent: July 24, 2012Inventor: Se-Lin Lee
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Patent number: 8163666Abstract: It is intended to provide a taphole mix capable of forming SiC bonds with minimum of an excess and a deficiency in components thereof, and excellent in drillability. A fine particle fraction having a particle diameter of 75 ?m or less is comprised of three components consisting of a silicon nitride-based material, a carbon-based material, and roseki, or comprised of the three component, and one or more selected from the group consisting of an alumina-based material, a silicon carbide-based material, a rare-earth element oxide-based material, clay, a high-purity silica-based material containing SiO2 in an amount of 80 mass % or more, a boron compound-based material in an amount of less than 0.3 mass % with respect to 100 mass % of the silicon nitride-based material, and a metal powder in an amount of less than 10 mass % with respect to 100 mass % of the carbon-based material.Type: GrantFiled: October 18, 2007Date of Patent: April 24, 2012Assignee: Krosakiharima CorporationInventor: Yutaka Kitazawa
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Publication number: 20120046155Abstract: A high-temperature, heat-resistant fill material is disclosed. The high-temperature, heat-resistant fill material includes an alumina refractory waste material having one or more of a used alumina-magnesium-carbon material, a used high-alumina material and a used fused-grain alumina material is disclosed. A method for method for manufacturing a material is also disclosed.Type: ApplicationFiled: November 3, 2011Publication date: February 23, 2012Applicants: Melt Solutions, L.L.C., Edw. C. Levy Co.Inventor: Thomas M. Dunn
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Publication number: 20110298166Abstract: The present invention provides a carbonaceous refractory, and a method of production of the same, which prevents a drop in the molten pig iron corrosion resistance, molten pig iron penetration resistance, and other properties of carbonaceous refractories required for blast furnace bottom refractories and, further, raises the mechanical strength of the refractories so as to suppress cracking due to thermal stress, that is, a carbonaceous refractory characterized by comprising a carbonaceous material comprised of one or more of calcined anthracite, calcined coke, natural graphite, or artificial graphite in 60 to 85 mass %, a refractory metal oxide in 5 to 15 mass %, metal silicon in 4 to 15 mass %, and carbon black in 2 to 10 mass % and by being obtained by adding an organic binder to refractory materials made a total 100 mass %, kneading the materials, then molding them and firing them in a nonoxidizing atmosphere.Type: ApplicationFiled: February 17, 2010Publication date: December 8, 2011Inventors: Hiroyuki Inoue, Michio Nitta, Taijiro Matsui, Tsutomu Wakasa, Yoshiyuki Yamagami, Toru Mochida
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Publication number: 20110206937Abstract: A composite article includes a substrate and a ceramic nanocomposite layer disposed on the substrate. The ceramic nanocomposite layer has a composition that includes silicon, boron, carbon and nitrogen.Type: ApplicationFiled: February 25, 2010Publication date: August 25, 2011Inventor: Wayde R. Schmidt
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Publication number: 20110152059Abstract: A high-chromia refractory, comprised of: about 60% to about 99% by weight of refractory grain, wherein the refractory grain is comprised of grains having about 20% to 100% by weight chromia; 0% to about 35% by weight of a fine particulate, the fine particulate selected from chromic oxide, alumina, ceria, yttria, lanthanum oxide, or combinations thereof; and about 1% to about 8% of a liquid resin or pitch.Type: ApplicationFiled: December 23, 2009Publication date: June 23, 2011Inventors: H. David Prior, Glenn H. McIntyre, III
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Publication number: 20100261599Abstract: A high-temperature, heat-resistant fill material is disclosed. The high-temperature, heat-resistant fill material includes an alumina refractory waste material having one or more of a used alumina-magnesium-carbon material, a used high-alumina material and a used fused-grain alumina material is disclosed. A method for method for manufacturing a material is also disclosed.Type: ApplicationFiled: April 10, 2009Publication date: October 14, 2010Applicant: Edw. C. Levy Co.Inventor: Thomas M. Dunn
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Publication number: 20100240518Abstract: To provide a process for producing high-purity highly oxidized refractory particles easily with good productivity by treating a spent refractory containing ZrO2 and Al2O3 to reduce components other than ZrO2 and Al2O3 to levels unproblematic for practical use as raw material for electrofused refractories and to increase the content of the ZrO2 and/or Al2O3 component. A process for producing refractory particles, which comprises introducing to and melting in a melting furnace both a spent refractory which contains, by mass % as chemical components, from 75 to 97% of ZrO2 and/or Al2O3, from 2 to 25% of SiO2, from 0.4 to 7% in total of Na2O, K2O and Li2O(Na2O+K2O+Li2O), at most 2% of CaO and at most 2% of MgO, and carbon particles in an amount of from 1 to 8% by outer mass percentage based on the spent refractory, and after the melting, tapping the melt while blowing compressed air against the melt to form refractory particles having the content of ZrO2 and/or Al2O3 increased.Type: ApplicationFiled: June 7, 2010Publication date: September 23, 2010Applicant: AGC CERAMICS CO., LTD.Inventor: Yukihiro USHIMARU
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Publication number: 20100233497Abstract: A non-conductive ceramic material contains a base ceramic material and at least one other ceramic material having a lower coefficient of thermal expansion than that of the base material so that the coefficient of thermal expansion of the non-conductive ceramic material is identical to that of a metallic material to which it will be matched. Methods of making and using same are disclosed.Type: ApplicationFiled: April 8, 2008Publication date: September 16, 2010Inventors: Alfred Thimm, Jürgen Ruska, Johannes Ernst, Stefan Stolz
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Patent number: 7759276Abstract: The invention relates to a formed body comprising an at least partially amorphous inorganic supporting structure and an adsorption agent, which adsorption agent is disposed on and/or in the amorphous inorganic supporting structure. The invention further relates to a process for the production of same and to the use of said formed body in a filtering system, preferably in a motor vehicle.Type: GrantFiled: July 21, 2005Date of Patent: July 20, 2010Assignee: helsa-Automotive GmbH & Co. KGInventor: Thomas Wolff
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Publication number: 20100160142Abstract: A magnesia-carbon brick comprised of about 50 to about 95% by weight magnesia and about 1 to about 20% by weight carbon, with or without metallic additions, such that the chemical analysis of the mixture of aggregates used in the brick will comprise, by chemical analysis, about 2 to about 15% SiO2, about 3 to about 50% Al2O3, and about 50 to about 95% MgO.Type: ApplicationFiled: December 18, 2008Publication date: June 24, 2010Inventors: Shyam Miglani, H. David Prior, David J. Michael
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Publication number: 20100065977Abstract: In one aspect, the present invention provides a method of providing a filling material for use in connection with an opening in a container used in molten metal processing including: recovering used refractory bricks; crushing the used refractory bricks into particles; and covering the opening with the particles.Type: ApplicationFiled: September 12, 2008Publication date: March 18, 2010Inventor: Joseph R. Quigley
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Patent number: 7612006Abstract: To provide a sintered silicon nitride with conductivity and densification, an oxide of titanium group elements, such as titanium oxide, hafnium oxide, zirconium oxide and the like, aluminum oxide and/or aluminum nitride is added as needed to silicon nitride-oxidant of rare-earth elements-aluminum oxide system or silicon nitride-oxide of rare-earth elements-magnesia system, and then specified quantity of carbon nonotube (CNT) is added to the above mixture. CNT generates silicon carbide after the reaction with contiguous or proximal silicon nitride and the like depending on the sintering duration at high temperature. Since silicon carbide is generated along with nanotubes, the silicon carbide functions as conductor with excellent heat resistance, corrosion resistance and the like.Type: GrantFiled: September 27, 2005Date of Patent: November 3, 2009Assignee: Yokohama TLO Company, Ltd.Inventors: Katsutoshi Komeya, Junichi Tatami, Takeshi Meguro, Tomofumi Katashima, Toru Wakihara
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Publication number: 20090269573Abstract: The present invention provides a new high-performance composite material that uses inexpensive materials, has high toughness, has a low coefficient of friction, excellent wear resistance, lower electrical resistance, and excellent electromagnetic wave absorption, and corresponding manufacturing method. A sintered body containing 0.1˜90 mass % of carbon nanotubes 2 and 99.9˜10 mass % of alumina-silica ceramic 3. The alumina-silica ceramic 3 contains 99.5˜5 mass % alumina and 0.5˜95 mass % silica. A nanocomposite 1, wherein the nano crystals of the carbon nanotubes 2 and the alumina-silica ceramic 3 are mutually intertwined, exists as a construction element. The carbon nanotubes 2 and alumina-silica ceramic 3 raw materials are placed in a water or alcohol solvent to form a slurry that is then stirred for 3˜180 minutes after which the solvent is removed from this mixture material that is then sintered in a non-oxygenated atmosphere in the temperature range of 800° C.˜1,800° C. for 5 minutes to 5 hours.Type: ApplicationFiled: August 31, 2006Publication date: October 29, 2009Applicant: National University Corporation Tohoku UniversityInventors: Mamoru Omori, Toshiyuki Hashida, Hisamichi Kimura, Akira Okubo, Yoshihiro Murakami, Shun Ito, Akihisa Inoue
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Patent number: 7485282Abstract: A process is described for the synthesis of metal oxides in a nanometric particle form that cannot be easily obtained by conventional bulk synthesis techniques. The method makes use of Colloid Occluded Carbons (COC) and Colloid Imprinted Carbons (CIC) as reagents and as templating agents for the preparation of metal oxides in nanometric particle form. The nanometric particles are suitable useful in the field of chemical catalysis, particularly for petroleum refining when in porous form, and as sensors, optical wave guides, and coatings.Type: GrantFiled: March 23, 2005Date of Patent: February 3, 2009Assignee: Board of Trustees of Michigan State UniversityInventors: Thomas J. Pinnavaia, Seong-Su Kim
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Patent number: 7446978Abstract: The magnetic head slider material of the present invention is constituted by a sintered body containing 100 parts by weight of alumina, 20 to 120 parts by weight of titanium carbide, and 0.2 to 9 parts by weight of carbon.Type: GrantFiled: May 17, 2005Date of Patent: November 4, 2008Assignee: TDK CorporationInventors: Yukio Kawaguchi, Kei Sugiura, Masahiro Itoh, Minoru Sakurabayashi, Atsushi Hitomi
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Patent number: 7387977Abstract: A binder is mixed to alumina powder with a purity of 99.5% or more (step S11), the mixture is granulated (step S12), resultant granule powder is formed with a die (step S13), and a formed compact is sintered in a hot-pressing manner (step S14).Type: GrantFiled: March 8, 2006Date of Patent: June 17, 2008Assignee: NGK Insulators, Ltd.Inventors: Yutaka Mori, Hiroto Matsuda, Kazuhiro Nobori
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Patent number: 7348286Abstract: Ceramic composite material that has excellent mechanical properties within a range from room temperature to high temperature and high die release with respect to glass, resins, ceramics, and similar substances. The ceramic composite material is composed of a ceramic phase and a phase containing 2 to 98 wt. % carbon and/or boron nitride as the main component, and that has a mean particle size of 100 nm or less, wherein the thermal expansion coefficient is within a range of 2.0-9.0×10?6/° C. and the surface roughness after surface polishing is 0.05 ?m or less. The sintered body of the material is obtained by sintering a mixture of powdered starting materials at a sintering temperature of 800-1500° C. and a sintering pressure of 200 MPa or higher.Type: GrantFiled: October 28, 2004Date of Patent: March 25, 2008Assignee: Sumitomo Electric Industries, Ltd.Inventors: Masashi Yoshimura, Tomoyuki Ueno
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Patent number: 7306828Abstract: The present invention is directed towards a ceramic nanocomposite comprising a nanostructured carbon component inside a ceramic host. The ceramic nanocomposite may further comprise vapor grown carbon fibers. Such nanostructured carbon materials impart both structural and thermal barrier enhancements to the ceramic host. The present invention is also directed towards a method of making these ceramic nanocomposites and for methods of using them in various applications.Type: GrantFiled: December 22, 2005Date of Patent: December 11, 2007Assignee: William Marsh Rice UniversityInventors: Enrique V. Barrera, Leonard Lee Yowell, Jr., Brian Mitchell Mayeaux, Erica L. Corral, Joseph Cesarano, III
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Patent number: 7204878Abstract: This invention relates to refractory mixes produced by mixing a refractory material with an organic binder and heating to a temperature of typically from about 50° C. to about 100° C. to form a stable composite granulate. The refractor mixes comprise a major amount of a refractory material and a minor amount of a binder composition comprising (a) condensed tannin and (b) furfuryl alcohol. The refractory mixes are used to prepare shaped (e.g. bricks) and unshaped (e.g. blast furnace tap holes, troughs, and tundish liners) refractory products. The invention also relates to a process for preparing the refractory products using the refractory mixes.Type: GrantFiled: October 11, 2005Date of Patent: April 17, 2007Assignee: Ashland Licensing and Intellectual Property LLCInventor: Mark R. Stancliffe
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Patent number: 7182891Abstract: This invention concerns a non-basic refractory batch as well as its use.Type: GrantFiled: November 12, 2003Date of Patent: February 27, 2007Assignee: Refractory Intellectual Property GmbH & Co. KGInventors: Malgorzata Bugajski, Karl-Heinz Dott, Alfons Lueftenegger
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Patent number: 7112549Abstract: A low-thermal-expansion, rigid and wear-resistant ceramic is provided. The low-thermal-expansion ceramic of the invention includes 60 vol % to 99.9 vol % of at least one selected from the group consisting of cordierite, spodumene and eucryptite and 0.1 vol % to 40 vol % of at least one selected from the group consisting of carbides, nitrides, borides and silicides of group IVa elements, group Va elements and group VIa elements, and boron carbide. The ceramic has a porosity of 0.5% or less and a thermal expansion coefficient, at 10° C. to 40° C., of 1.5×10?6/° C. or less.Type: GrantFiled: September 20, 2001Date of Patent: September 26, 2006Assignee: Sumitomo Metal Industries, Ltd.Inventors: Yasuki Yoshitomi, Tadahisa Arahori
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Patent number: 6875716Abstract: A carbonaceous refractory material is produced by adding an organic binder to a mixture containing a carbonaceous material comprising a carbonaceous raw material comprising calcined anthracite, calcined coke, artificial graphite or natural graphite or a mixture thereof at 50 to 85% as the principal raw material, alumina particle at 5 to 15%, metal silicon particle at 5 to 15%, and one or two or more of titanium carbide powder, titanium nitride powder and titanium carbonitride powder at 5 to 20% in total, kneading and molding the resulting mixture and baking the molded article under non-oxidizing atmosphere. By using the carbonaceous refractory material as the inner lining material for the side wall and bottom of blast furnace hearth, the consumption of the inner lining material due to the dissolution thereof in melted pig iron can be decreased, and simultaneously, the abrasion due to the flow of melted pig iron can be decreased, which works to prolong the life of the blast furnace.Type: GrantFiled: March 30, 2001Date of Patent: April 5, 2005Assignees: Nippon Steel Corporation, Nippon Electrode Company, Ltd.Inventors: Akio Ishii, Hitoshi Nakamura, Michio Nitta, Tsutomu Wakasa, Hirofumi Mikami, Yoshiyuki Yamagami
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Patent number: 6875374Abstract: Composite materials formed of a matrix of fused ceramic grains with single-wall carbon nanotubes dispersed throughout the matrix and a high relative density, notably that achieved by electric field-assisted sintering, demonstrate unusually high electrical conductivity in combination with high-performance mechanical properties including high fracture toughness. This combination of electrical and mechanical properties makes these composites useful as electrical conductors in applications where high-performance materials are needed due to exposure to extreme conditions such as high temperatures and mechanical stresses.Type: GrantFiled: February 26, 2003Date of Patent: April 5, 2005Assignee: The Regents of the University of CaliforniaInventors: Guodong Zhan, Joshua D. Kuntz, Amiya K. Mukherjee
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Patent number: 6846763Abstract: A refractory repair batch material includes a refractory, in particular a basic resistor component in granule form and a binder system. The binder system contains at least one hard bitumen component in granule form, at least one ignitable metal powder and at least one combustible mineral oil.Type: GrantFiled: November 18, 2003Date of Patent: January 25, 2005Assignee: Refratechnik Holding GmbHInventors: Helge Jansen, Heinrich Grosse Daldrup
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Publication number: 20040152582Abstract: An objective of the present invention is to provide an aluminum nitride sintered body making it possible to keep a volume resistivity of 108 &OHgr;·cm or more, and guarantee covering-up capability, a large radiant heat amount and measurement accuracy with a thermoviewer. A carbon-containing aluminum nitride sintered body of the present invention of the present invention comprising: carbon whose peak cannot be detected on its X-ray diffraction chart or whose peak is below its detection limit thereon; in a matrix made of aluminum nitride.Type: ApplicationFiled: December 11, 2003Publication date: August 5, 2004Applicant: IBIDEN CO., LTD.Inventors: Yasutaka Ito, Yasuji Hiramatsu
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Publication number: 20040150140Abstract: Composites of ceramic materials, notably alumina or metal oxides in general, with single-wall carbon nanotubes are consolidated by electric field-assisted sintering to achieve a fully dense material that has an unusually high fracture toughness compared to the ceramic alone, and also when compared to composites that contain multi-wall rather than single-wall carbon nanotubes, and when compared to composites that are sintered by methods that do not include exposure to an electric field.Type: ApplicationFiled: January 30, 2003Publication date: August 5, 2004Applicant: THE REGENTS OF THE UNIVERSITY OF CALIFORNIAInventors: Guodong Zhan, Amiya K. Mukherjee, Joshua D. Kuntz, Julin Wan
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Publication number: 20040106509Abstract: Refractories obtained by molding a refractory raw material composition containing a refractory raw material including graphite grains having an average grain size of 500 nm or less or a refractory raw material including graphite grains obtained by graphitizing carbon black and a refractory filler. Or refractories containing carbonaceous grains (A) selected from carbon black or graphite grains obtained by graphitizing carbon black and having a DBP absorption (x) of 80 ml/100 g or more, carbonaceous grains (B) selected from carbon black and graphite grains obtained by graphitizing carbon black and having a DBP absorption (x) of less than 80 ml/100 g, and a refractory filler. Refractories excellent in corrosion resistance, oxidation resistance and thermal shock resistance, especially carbon-contained refractories having a low carbon content are thereby provided.Type: ApplicationFiled: September 8, 2003Publication date: June 3, 2004Inventors: Tsunemi Ochiai, Shigeyuki Takanaga
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Publication number: 20040102307Abstract: This invention concerns a non-basic refractory batch as well as its use.Type: ApplicationFiled: November 12, 2003Publication date: May 27, 2004Applicant: Refractory Intellectual Property GmbH & Co. KGInventors: Malgorzata Bugajski, Karl-Heinz Dott, Alfons Lueftenegger
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Publication number: 20040029706Abstract: The present invention is directed towards a ceramic nanocomposite comprising a nanostructured carbon component inside a ceramic host. The ceramic nanocomposite may further comprise vapor grown carbon fibers. Such nanostructured carbon materials impart both structural and thermal barrier enhancements to the ceramic host. The present invention is also directed towards a method of making these ceramic nanocomposites and for methods of using them in various applications.Type: ApplicationFiled: February 13, 2003Publication date: February 12, 2004Inventors: Enrique V. Barrera, Leonard Lee Yowell, Brian Mitchell Mayeaux, Erica L. Corral, Joseph Cesarano
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Publication number: 20030218151Abstract: The present invention provides aluminum oxide crystalline materials including dopants and oxygen vacancy defects and methods of making such crystalline materials. The crystalline materials of the present invention have particular utility in optical data storage applications.Type: ApplicationFiled: December 4, 2002Publication date: November 27, 2003Inventor: Mark Akselrod
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Publication number: 20030139280Abstract: An electroconductive low thermal expansion ceramic sintered body is disclosed which containing a &bgr;-eucryptite phase in a quantity of not less than 75 vol. % and not more than 99 vol. % and having an absolute value of thermal expansion coefficient of not more than 1.0×10−7/K at a temperature of 0° C. to 50° C., a volumetric specific resistance of not more than 1.0×107 &OHgr;·cm, and a specific rigidity of not less than 40 GPa/g/cm3.Type: ApplicationFiled: November 25, 2002Publication date: July 24, 2003Inventors: Fumiaki Takahashi, Tetsuro Nose, Masashi Nakabayashi
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Publication number: 20030060354Abstract: An improved process of curing resin-bonded refractory brick lining of a ladle within a housing by heating the brick in air at an effective temperature to produce resin vapors and transferring the vapors from the ladle comprising transferring the vapors at a temperature above the condensation temperature of the transferred vapors to an auxiliary burner to effect combustion of the transferred vapors to produce non-toxic gases. The process provides an efficacious and environmentally sound treatment of resin-bonded refractory bricks.Type: ApplicationFiled: May 20, 2002Publication date: March 27, 2003Inventors: Paul W. Loukas, Manfred Sallaberger
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Patent number: 6461991Abstract: A re-usable alumina-magnesia graphite refractory suitably used for a refractory for continuous casting, such as a long nozzle used for pouring a molten metal from a ladle capable of re-use or intermittent use to a tundish, an immersion nozzle used for charging a molten metal from a tundish to a mold and a long stopper for controlling the flow rate of the molten steel; and produced by blending 3 to 60 wt % of magnesia having a particle size of 0.02 to 1.0 mm to a compound comprising mainly alumina and graphite, and kneading, molding, and baking the compound. The raw material compound comprising mainly alumina and graphite can contain spinel or zirconia.Type: GrantFiled: August 24, 2000Date of Patent: October 8, 2002Assignee: Krosaki CorporationInventors: Koji Ogata, Shoji Iitsuka