And Alkaline Earth Metal Or Magnesium Compound (e.g., Dolomite, Magnesium Oxide, Etc.) Patents (Class 501/101)
-
Patent number: 11440847Abstract: A method for producing a granular material from sintered magnesia by sintering of pressed articles, in particular pellets, from MgO powder, preferably from caustic MgO powder, and subsequent mechanical comminution of the pressed articles, the sintering being carried out in such a way that the granular material has a grain porosity (total porosity), according to DIN EN 993-1:1195-04 and DIN EN 993-18:1999-01, of from 15 to 38 vol %, preferably 20 to 38 vol %. Also, a batch for producing a coarse ceramic, refractory, shaped or unshaped product containing the porous sintered magnesia, to such a product produced from the batch and to a method for its production, to a lining, in particular a working casing and/or a backing, of a large-volume industrial furnace, the lining, in particular the working casing and/or the backing, having at least one such product, as well as to such an industrial furnace.Type: GrantFiled: September 13, 2018Date of Patent: September 13, 2022Assignee: REFRATECHNIK HOLDING GMBHInventors: Hans-Jürgen Klischat, Robert Plummer, Carsten Vellmer, Holger Wirsing
-
Patent number: 11035038Abstract: A solid delivery precursor is described, which is useful for volatilization to generate precursor vapor for a vapor deposition process. The solid delivery precursor comprises solid bodies of compacted particulate precursor, e.g., in a form such as pellets, platelets, tablets, beads, discs, or monoliths. When utilized in a vapor deposition process such as chemical vapor deposition, pulsed chemical vapor deposition, or atomic layer deposition, the solid delivery precursor in the form of solid bodies of compacted particulate precursor provide substantially increased flux of precursor vapor when subjected to volatilization conditions, in relation to the particulate precursor. As a result, vapor deposition process operation can be carried out in shorter periods of time, thereby achieving increased manufacturing rates of products such as semiconductor products, flat-panel displays, solar panels, LEDs, optical coatings, and the like.Type: GrantFiled: October 6, 2016Date of Patent: June 15, 2021Assignee: Entegris, Inc.Inventors: Thomas H. Baum, Yuqi Li, David James Eldridge, Robert L. Wright
-
Patent number: 10227260Abstract: A refractory has the form of a dry, mineral batch of fire-resistant mineral materials combined in such a way that refractories which are long-term resistant to fayalite-containing slags, sulfidic melts (mattes), sulfates and non-ferrous metal melts and are used for refractory linings in industrial non-ferrous metal melting furnaces can be manufactured. The refractory at least contains: —at least one coarse-grained magnesia raw material as the main component; —magnesia (MgO) meal; —at least one fire-resistant reagent which, during the melting process, acts (in situ) in a reducing manner on non-ferrous metal oxide melts and/or non-ferrous metal iron oxide melts and converts same into non-ferrous metal melts.Type: GrantFiled: November 30, 2015Date of Patent: March 12, 2019Assignee: Refratechnik Holding GmbHInventors: Helge Jansen, Thomas Schemmel, Volker Stein
-
Patent number: 10207955Abstract: A refractory has the form of a dry, mineral batch of fire-resistant mineral materials combined in such a way that refractories which are long-term resistant to fayalite-containing slags, sulfidic melts (mattes), sulfates and non-ferrous metal melts and are used for refractory linings in industrial non-ferrous metal melting furnaces can be manufactured. The refractory at least contains: —at least one coarse-grained olivine raw material as the main component; —magnesia (MgO) meal; —at least one fire-resistant reagent which, during the melting process, acts (in situ) in a reducing manner on non-ferrous metal oxide melts and/or non-ferrous metal iron oxide melts and converts same into non-ferrous metal melts.Type: GrantFiled: December 10, 2015Date of Patent: February 19, 2019Assignee: Refratechnik Holding GmbHInventors: Helge Jansen, Thomas Schemmel, Volker Stein
-
Patent number: 9606098Abstract: A moisture content indicator for visually indicating the moisture content of a wood substrate and methods of making the moisture content indicator are provided.Type: GrantFiled: March 29, 2013Date of Patent: March 28, 2017Assignee: Weyerhaeuser NR CompanyInventors: Jack G. Winterowd, Erik M. Parker, Malinda J. De Lashmutt, Wayne Lindell, Tri Tran
-
Patent number: 9296660Abstract: Achieved is a ceramic carbon composite material and a ceramic-coated ceramic carbon composite material which are lighter than ceramics and excellent in at least one of properties including oxidation resistance, resistance to dust generation, heat conductivity, electrical conductivity, strength, and denseness. The ceramic carbon composite material is a ceramic carbon composite material in which an interfacial layer of a ceramic is formed between carbon particles of or containing graphite. The ceramic carbon composite material can be produced by forming a green body from ceramic-coated powder in which the surfaces of carbon particles of or containing graphite are coated with individual ceramic layers and sintering the green body.Type: GrantFiled: September 1, 2010Date of Patent: March 29, 2016Assignee: Toyo Tanso Co., Ltd.Inventors: Yoshinari Miyamoto, Weiwu Chen, Masaharu Nakamura, Taihei Matsumoto, Tetsuro Tojo
-
Patent number: 8722220Abstract: Provided is a hydrophobic catalyst layer for a polymer electrolyte fuel cell to which hydrophobicity is imparted so that the dissipation property of produced water is improved and which simultaneously has an increased effective surface area and an increased utilization ratio of a catalyst, and a method of producing the same. The catalyst layer for a polymer electrolyte fuel cell includes a catalyst obtained by reducing a platinum oxide, a hydrophobic agent, and a proton conductive electrolyte, wherein the hydrophobic agent is mainly composed of alkylsiloxane. An Si compound containing a hydrophobic substituent is brought into contact with a platinum oxide to subject the Si compound to hydrolysis and a polymerization reaction by the catalytic action of the platinum oxide, and then it is reduced, thereby obtaining a hydrophobic catalyst layer carrying an alkylsiloxane polymer.Type: GrantFiled: March 13, 2013Date of Patent: May 13, 2014Assignee: Canon Kabushiki KaishaInventors: Kazuhiro Yamada, Kazuya Miyazaki
-
Patent number: 8450228Abstract: In a carbon-containing refractory composed of a refractory aggregate, a carbon based raw material, and a carbon bond connecting between the refractory aggregate or the carbon based raw material, transition metal-containing nanoparticles having particle diameters of 1,000 nm or less and containing a transition metal are contained in the above-described carbon bond while being dispersed. When the carbon-containing refractory is heat-treated, flexible structures of carbon fiber-shaped textures having diameters of 50 nm or less are formed in the inside of a carbon bond and, thereby, an increase in strength, a reduction in modulus of elasticity, and a reduction in thermal expansion coefficient are facilitated. Therefore, a carbon-containing refractory exhibiting high thermal shock resistance, high abrasion resistance, and high corrosion resistance are provided.Type: GrantFiled: April 19, 2006Date of Patent: May 28, 2013Assignee: Krosaki Harima CorporationInventors: Katsumi Morikawa, Koichi Haren, Joki Yoshitomi, Toshiyuki Hokii, Keisuke Asano
-
Publication number: 20120308813Abstract: A temperature-resistant ceramic hybrid material has a matrix made of calcium silicate hydrate. Carbon is embedded in the matrix. The carbon is predominantly composed of graphite particles having an ordered graphitic lattice structure and the carbon makes up a weight fraction of up to 40%. The matrix is composed of tobermorite and/or xonotlite and can contain wollastonite rods and/or granular silicate. The size of the graphite particles is 0.01-3 mm. The hybrid material is especially suitable for casting devices for non-ferrous metals.Type: ApplicationFiled: January 14, 2011Publication date: December 6, 2012Applicant: CALISTHERM VERWALTUNGS GMBHInventors: Klaus Hoelscher, Tobias Hoelscher, Wolf Huettner, Axel Lengen, Hans-Juergen Schneider, Winfried Stellmach
-
Patent number: 8278230Abstract: The present application relates to perfume systems and consumer products comprising new perfumes and/or such perfume systems, as well as processes for making and using such perfume systems and consumer products.Type: GrantFiled: December 17, 2010Date of Patent: October 2, 2012Assignee: The Procter & Gamble CompanyInventors: Johan Smets, David Thomas Stanton, Rafael Trujillo Rosaldo, Allan Campbell McRitchie, Hugo Robert Germain Denutte, Thierry Granier, Andreas Hanhart, Jerzy A. Bajgrowicz, Philip Kraft
-
Patent number: 8251129Abstract: In an operation of continuous casting of steel grade such as aluminum-killed steel where a nozzle clogging phenomenon is particularly likely to occur, it is intended to prevent adhesion of inclusions (typically, Al2O3) on a nozzle used in the casting operation, and clogging of the nozzle due to the inclusions. A refractory material 10 is arranged to define a part or an entirety of a molten steel-contacting surface of a continuous casting nozzle, wherein the refractory material 10 contains: a CaO component in an amount of 0.5 mass % or more; one or both of B2O3 and R2O (R is one selected from the group consisting of Na, K and Li) in an amount of 0.5 mass % or more; Al2O3 in an amount of 50 mass % or more; and free carbon in an amount of 8.0 to 34.5 mass %, and wherein a total amount of CaO, B2O3 and R2O is in the range of 1.0 to 15.0 mass %, and a mass ratio of CaO/(B2O3+R2O) is in the range of 0.1 to 3.0.Type: GrantFiled: May 13, 2010Date of Patent: August 28, 2012Assignee: Krosakiharima CorporationInventors: Katsumi Morikawa, Akinari Sasaki, Hiroshi Otsuka, Yuichi Tsukaguchi
-
Patent number: 8026191Abstract: The present invention provides a carbon-containing refractory composition comprising a carbon-containing refractory matrix material, and a binder selected from molasses, lignosulphonate, magnesium sulfate, magnesium chloride, and a mixture thereof. The inventive composition having satisfactory good thermal and physical properties causes no environmental hazard.Type: GrantFiled: May 8, 2007Date of Patent: September 27, 2011Assignee: Wonjin Worldwide Co., Ltd.Inventor: Jeong Heo
-
Publication number: 20110152059Abstract: A high-chromia refractory, comprised of: about 60% to about 99% by weight of refractory grain, wherein the refractory grain is comprised of grains having about 20% to 100% by weight chromia; 0% to about 35% by weight of a fine particulate, the fine particulate selected from chromic oxide, alumina, ceria, yttria, lanthanum oxide, or combinations thereof; and about 1% to about 8% of a liquid resin or pitch.Type: ApplicationFiled: December 23, 2009Publication date: June 23, 2011Inventors: H. David Prior, Glenn H. McIntyre, III
-
Publication number: 20100233497Abstract: A non-conductive ceramic material contains a base ceramic material and at least one other ceramic material having a lower coefficient of thermal expansion than that of the base material so that the coefficient of thermal expansion of the non-conductive ceramic material is identical to that of a metallic material to which it will be matched. Methods of making and using same are disclosed.Type: ApplicationFiled: April 8, 2008Publication date: September 16, 2010Inventors: Alfred Thimm, Jürgen Ruska, Johannes Ernst, Stefan Stolz
-
Publication number: 20100093515Abstract: The invention relates to a refractory, ceramically fired, carbon-bonded magnesia brick whose matrix is more than 70% by weight, in particular from 80 to 98% by weight, of MgO grains and also a carbon framework binder matrix resulting from carbonization, and pores, wherein the MgO grains are fixed by means of carbon bonding of the carbon framework and at least 30%, in particular from 50 to 100%, of the MgO grains have at least one sintering bridge resulting from the ceramic firing.Type: ApplicationFiled: February 26, 2008Publication date: April 15, 2010Inventor: Helge Jansen
-
Publication number: 20100065977Abstract: In one aspect, the present invention provides a method of providing a filling material for use in connection with an opening in a container used in molten metal processing including: recovering used refractory bricks; crushing the used refractory bricks into particles; and covering the opening with the particles.Type: ApplicationFiled: September 12, 2008Publication date: March 18, 2010Inventor: Joseph R. Quigley
-
Publication number: 20090233783Abstract: The present invention provides a carbon-containing refractory composition comprising a carbon-containing refractory matrix material, and a binder selected from molasses, lignosulphonate, magnesium sulfate, magnesium chloride, and a mixture thereof. The inventive composition having satisfactory good thermal and physical properties causes no environmental hazard.Type: ApplicationFiled: May 8, 2007Publication date: September 17, 2009Inventor: Jeong Heo
-
Patent number: 7204878Abstract: This invention relates to refractory mixes produced by mixing a refractory material with an organic binder and heating to a temperature of typically from about 50° C. to about 100° C. to form a stable composite granulate. The refractor mixes comprise a major amount of a refractory material and a minor amount of a binder composition comprising (a) condensed tannin and (b) furfuryl alcohol. The refractory mixes are used to prepare shaped (e.g. bricks) and unshaped (e.g. blast furnace tap holes, troughs, and tundish liners) refractory products. The invention also relates to a process for preparing the refractory products using the refractory mixes.Type: GrantFiled: October 11, 2005Date of Patent: April 17, 2007Assignee: Ashland Licensing and Intellectual Property LLCInventor: Mark R. Stancliffe
-
Patent number: 7182891Abstract: This invention concerns a non-basic refractory batch as well as its use.Type: GrantFiled: November 12, 2003Date of Patent: February 27, 2007Assignee: Refractory Intellectual Property GmbH & Co. KGInventors: Malgorzata Bugajski, Karl-Heinz Dott, Alfons Lueftenegger
-
Patent number: 7179550Abstract: A member of supporting magnetic disc substrates is provided, comprising a ceramic sinter containing a ceramic component and at least one conductive component selected from a group consisting of iron, niobium, tin zinc, copper, nickel, cobalt, and chromium, wherein the ceramic sinter has conductive aggregates on its peripheral surface. In the member, the ceramic component may be forsterite and the conductive component is iron oxide, wherein the ceramic sinter comprises a main phase of 2MgO.SiO2 and a secondary phase of at least one of MgFe2O4, Fe3O4 and Fe2O3.Type: GrantFiled: March 28, 2003Date of Patent: February 20, 2007Assignee: Kyocera CorporationInventors: Masahiro Okumura, Tetsuzi Hayasaki
-
Patent number: 7060642Abstract: Refractories obtained by molding a refractory raw material composition containing a refractory raw material including graphite grains having an average grain size of 500 nm or less or a refractory raw material including graphite grains obtained by graphitizing carbon black and a refractory filler. Or refractories containing carbonaceous grains (A) selected from carbon black or graphite grains obtained by graphitizing carbon black and having a DBP absorption (x) of 80 ml/100 g or more, carbonaceous grains (B) selected from carbon black and graphite grains obtained by graphitizing carbon black and having a DBP absorption (x) of less than 80 ml/100 g, and a refractory filler. Refractories excellent in corrosion resistance, oxidation resistance and thermal shock resistance, especially carbon-contained refractories having a low carbon content are thereby provided.Type: GrantFiled: March 6, 2002Date of Patent: June 13, 2006Assignees: Kyushu Refractories Co., Ltd.Inventors: Tsunemi Ochiai, Shigeyuki Takanaga
-
Patent number: 6846766Abstract: A batch, in particular for the production of a refractory shaped body, includes at least one refractory metal oxide component and a synthetic resin component as a binder, and a graphitizing auxiliary for producing crystalline graphite carbon from the resin. The graphitizing auxiliary originates from a group consisting of reducible organic compounds of transition elements and/or a group of active organic or inorganic metal compounds or metals, such as resin-soluble metal salts, chemically precipitated or micronized metal oxides or metals. The graphitizing auxiliary is available in molecular form over the time and/or temperature range of conversion of the synthetic resin into carbon (carbonization).Type: GrantFiled: November 13, 2000Date of Patent: January 25, 2005Assignee: Refratechnik Holding GmbHInventors: Peter Bartha, Helge Jansen, Heinrich Grosse Daldrup
-
Patent number: 6846763Abstract: A refractory repair batch material includes a refractory, in particular a basic resistor component in granule form and a binder system. The binder system contains at least one hard bitumen component in granule form, at least one ignitable metal powder and at least one combustible mineral oil.Type: GrantFiled: November 18, 2003Date of Patent: January 25, 2005Assignee: Refratechnik Holding GmbHInventors: Helge Jansen, Heinrich Grosse Daldrup
-
Patent number: 6846510Abstract: The invention relates to a method for deposition of a catalyst, in particular a method for coating a membrane electrode unit (MEA) for a fuel cell. Said method requires no external electrical field as usual for conventional galvanic techniques. The support for the catalytic layer is first capacitively charged (pseudocapacitance). When brought into contact with an electrolyte solution, comprising the catalyst in the form of dissolved metal salt ions, an in-situ reduction (deposition) of the metal salt ions to give metallic catalyst occurs at the site of contact.Type: GrantFiled: November 28, 2001Date of Patent: January 25, 2005Assignees: Forschungszentrum Julich GmbH, Prof. Dr. Rolf HempelmannInventors: Rolf Hempelmann, Heinz Schmitz, March-Simon Löffler, Harald Natter, Jiri Divisek
-
Patent number: 6844281Abstract: A preform for use in a metal matrix composite, particularly for a magnesium metal composite. In the preform the reinforcing material typically is silicon carbide, boron nitride, titanium nitride, carbon or graphite. The binder used in the preform is sintered magnesium fluoride, which avoids the known problems which result from the high reactivity of molten magnesium metal with other binders, such as silica and alumina, which results in the formation of magnesium oxide in the reinforced composite. The presence of magnesium oxide crystals in the metal matrix adversely affects the properties of the composite. The preform generally has a void volume of from about 50% to about 95%.Type: GrantFiled: November 18, 2002Date of Patent: January 18, 2005Assignee: Her Majesty the Queen in right of Canada, as represented by the Minister of Natural ResourcesInventors: Jason S. H. Lo, Areekattuthazhayil K. Kuriakose, Raul Santos
-
Publication number: 20040106509Abstract: Refractories obtained by molding a refractory raw material composition containing a refractory raw material including graphite grains having an average grain size of 500 nm or less or a refractory raw material including graphite grains obtained by graphitizing carbon black and a refractory filler. Or refractories containing carbonaceous grains (A) selected from carbon black or graphite grains obtained by graphitizing carbon black and having a DBP absorption (x) of 80 ml/100 g or more, carbonaceous grains (B) selected from carbon black and graphite grains obtained by graphitizing carbon black and having a DBP absorption (x) of less than 80 ml/100 g, and a refractory filler. Refractories excellent in corrosion resistance, oxidation resistance and thermal shock resistance, especially carbon-contained refractories having a low carbon content are thereby provided.Type: ApplicationFiled: September 8, 2003Publication date: June 3, 2004Inventors: Tsunemi Ochiai, Shigeyuki Takanaga
-
Publication number: 20040102306Abstract: The invention relates to a refractory repair batch material, which includes a refractory, in particular basic resistor component in granule form and a binder system, the binder system containing at least one hard bitumen component in granule form, at least one ignitable metal powder and at least one combustible mineral oil.Type: ApplicationFiled: November 18, 2003Publication date: May 27, 2004Inventors: Helge Jansen, Heinrich Grosse Daldrup
-
Patent number: 6645425Abstract: The invention relates to a refractory batch containing at least one refractory metal oxide component, at least one binder component, such as resin or pitch, if appropriate antioxidants, at least one carbon carrier, such as soot and/or graphite, and reinforcement fibers which are formed from a stainless steel material, which at the temperatures of use forms a coat of the refractory metal oxide on its surface, and to a shaped body made from the batch and to a process for producing the shaped body.Type: GrantFiled: June 1, 2000Date of Patent: November 11, 2003Assignee: Refractechnik Holding GmbHInventors: Hans Wienand, Helge Jansen, Peter Bartha
-
Patent number: 6586355Abstract: An improved submerged entry nozzle is provided which is useful in the casting of aluminum killed molten steel. The nozzle has an improved slagline sleeve or collar which surrounds the outer portion of the nozzle to protect it from corrosion during the casting process. The slagline sleeve is made from resin bonded zirconia/graphite which has been formulated so that upon curing of the resin to form resite, there is a reduction in the contractile tendency which results in a reduction in stress fracturing. The reduction of the contractile tendency and the resulting resistance to stress fracturing is achieved by adding an effective amount of calcium oxide to the resin-zirconia-graphite mixture which is used to form the sleeve.Type: GrantFiled: December 20, 2001Date of Patent: July 1, 2003Assignee: Baker RefractoriesInventors: Donald B. Hoover, Franklin A. Renda, Donald J. Griffin, Colin Richmond
-
Patent number: 6533146Abstract: A continuous casting nozzle for casting molten steel, wherein at least a surface layer of an inner bore of the continuous casting nozzle contacting with a molten steel is formed of a refractory comprising: an aggregate consisting essentially of alumina (Al2O3) or an aggregate comprising alumina (A12O3) as its main ingredient and melting point thereof being at least 1800 degree centigrade: from 15 to 60 wt. % and roseki as a balance. The refractory is added thermosetting resin as binder, kneaded, formed, and sintered in an anti-oxidizing atmosphere.Type: GrantFiled: December 5, 2000Date of Patent: March 18, 2003Assignee: Akechi Ceramics Kabushiki KaishaInventors: Mituru Ando, Kazumi Oguri, Toshiyuki Muroi, Toshikazu Takasu
-
Patent number: 6533994Abstract: The invention relates to an alkaline (basic), refractory ceramic hollow item.Type: GrantFiled: December 11, 2000Date of Patent: March 18, 2003Assignee: Didier-Werke AGInventors: Steven Lee, Dirk Masurat, Ian Proudfoot, Jim McIntosh
-
Publication number: 20020177517Abstract: An improved submerged entry nozzle is provided which is useful in the casting of aluminum killed molten steel. The nozzle has an improved slagline sleeve or collar which surrounds the outer portion of the nozzle to protect it from corrosion during the casting process. The slagline sleeve is made from resin bonded zirconia/graphite which has been formulated so that upon curing of the resin to form resite, there is a reduction in the contractile tendency which results in a reduction in stress fracturing. The reduction of the contractile tendency and the resulting resistance to stress fracturing is achieved by adding an effective amount of calcium oxide to the resin-zirconia-graphite mixture which is used to form the sleeve.Type: ApplicationFiled: February 11, 2002Publication date: November 28, 2002Applicant: Baker Refractories, Inc.Inventors: Donald B. Hoover, Franklin A. Renda, Donald J. Griffin, Colin Richmond
-
Patent number: 6464932Abstract: An unburned carbon-containing refractory suitable for lining a molten metal container, which can prevent deformation of the outer steel shell, improve the life of the container, suppress reduction in molten steel temperature, and minimize energy losses without sacrificing the life of the wear lining. A molten metal container capable of reducing energy losses and having stable durability is also provided. The unburned carbon-containing refractory contains a refractory aggregate and 30% by weight or less of a carbon raw material containing at least graphite, wherein the carbon content X (% by weight) and the thermal conductivity &lgr;(W/m° C.) of the refractory satisfy the relationship: &lgr;≦0.8X+7, and the refractory contains 20 parts by weight or more of a refractory aggregate having an apparent porosity of 10% or smaller and a greater size than 1 mm per 100 parts by weight of the total of the refractory aggregate and the carbon raw material.Type: GrantFiled: May 30, 2000Date of Patent: October 15, 2002Assignee: Shinagawa Refractories Co., Ltd.Inventors: Osamu Nomura, Yasuhiro Hoshiyama, Atsushi Torigoe
-
Patent number: 6461991Abstract: A re-usable alumina-magnesia graphite refractory suitably used for a refractory for continuous casting, such as a long nozzle used for pouring a molten metal from a ladle capable of re-use or intermittent use to a tundish, an immersion nozzle used for charging a molten metal from a tundish to a mold and a long stopper for controlling the flow rate of the molten steel; and produced by blending 3 to 60 wt % of magnesia having a particle size of 0.02 to 1.0 mm to a compound comprising mainly alumina and graphite, and kneading, molding, and baking the compound. The raw material compound comprising mainly alumina and graphite can contain spinel or zirconia.Type: GrantFiled: August 24, 2000Date of Patent: October 8, 2002Assignee: Krosaki CorporationInventors: Koji Ogata, Shoji Iitsuka
-
Patent number: 6423129Abstract: A coating for roofs and the like to inexpensively provide protection from ultraviolet light and for wood or steel substrates to inexpensively provide flame or chemical resistance respectively. The coating comprises an adhesive and a recycled ceramic powder and may also comprise a recycled granular ceramic material. An additive to sealants, caulking, and other construction materials to inexpensively provide improved fire resistance and insulation and other enhanced properties. The additive comprises a recycled ceramic powder and may also comprise a recycled granular ceramic material.Type: GrantFiled: February 15, 2000Date of Patent: July 23, 2002Inventor: Robert T. Fitzgibbons, Jr.
-
Patent number: 6410469Abstract: An improved submerged entry nozzle is provided which is useful in the casting of aluminum killed molten steel. The nozzle has an improved slagline sleeve or collar which surrounds the outer portion of the nozzle to protect it from corrosion during the casting process. The slagline sleeve is made from resin bonded zirconia/graphite which has been formulated so that upon curing of the resin to form resite, there is a reduction in the contractile tendency which results in a reduction in stress fracturing. The reduction of the contractile tendency and the resulting resistance to stress fracturing is achieved by adding an effective amount of calcium oxide to the resin-zirconia-graphite mixture which is used to form the sleeve.Type: GrantFiled: August 11, 1999Date of Patent: June 25, 2002Assignee: Baker Refractories, Inc.Inventors: Donald B. Hoover, Franklin A. Renda, Donald J. Griffin, Colin Richmond
-
Publication number: 20020022567Abstract: An essentially non-slumping sprayable refractory castable composition that is applied without forms is disclosed comprising (a) a tempered, pumpable first component comprising (i) one hundred weight percent of a refractory composition comprising from about 60 to 90 weight percent of a refractory aggregate, from about 2 to 25 weight percent of an ultrafine refractory material having an average particle diameter size less than or equal to about 3 microns, from about 0.5 to 15 weight percent of a binder, and from about 0.05 to 2.Type: ApplicationFiled: August 29, 2001Publication date: February 21, 2002Inventors: Xiangmin Li, Robert M. Cullen
-
Patent number: 6313056Abstract: An essentially non-slumping sprayable refractory castable composition that is applied without forms is disclosed comprising (a) a tempered, pumpable first component comprising (i) one hundred weight percent of a refractory composition comprising from about 60 to 90 weight percent of a refractory aggregate, from about 2 to 25 weight percent of an ultrafine refractory material having an average particle diameter size less than or equal to about 3 microns, from about 0.5 to 15 weight percent of a binder, and from about 0.05 to 2.Type: GrantFiled: August 20, 1998Date of Patent: November 6, 2001Assignee: Harbison-Walker Refractories CompanyInventors: Xiangmin Li, Robert M. Cullen
-
Publication number: 20010024748Abstract: The invention improves operability in forming a catalyst electrode, and improves performance of a fuel cell. A catalyst-loaded carbon is dispersed in a mixed solution of an azeotropic solvent and ion exchanged water. An electrolyte solution is added to the dispersed solution. A solvent, such as ethanol or the like, is added to adjust the viscosity and the water content of the solution, thereby providing an electrode catalyst solution. The use of the obtained solution as an ink for forming a catalyst layer through printing improves printing characteristic and drying characteristic.Type: ApplicationFiled: March 19, 2001Publication date: September 27, 2001Inventors: Seiji Mizuno, Tatsuya Kawahara
-
Patent number: 6288001Abstract: A graphite-containing monolithic refractory material comprises at least one component selected from alumina and alumina-magnesia spinel, which are divided into selected particle size regions, artificial graphite having a selected average particle size, and pitch powder. The refractory material may optionally comprise a selected amount of silicon carbide having a selected average particle size. The graphite-containing monolithic refractory material exhibits excellent casting workability at a low moisture content, and both excellent corrosion resistance and spalling resistance. The refractory material is suitable as a casting monolithic refractory material for lining a topedo ladle car.Type: GrantFiled: December 22, 1998Date of Patent: September 11, 2001Assignee: Kawasaki Steel CorporationInventors: Yoshisato Kiyota, Masato Kumagai, Masao Nanbu, Shigenobu Takata, Masakazu Iida, Noboru Komatsubara, Toyohide Yamaguchi
-
Patent number: 6284689Abstract: The invention relates to refractory waste materials and in particular to waste materials removed from furnace linings. Refractory waste materials often have hydrolysable contaminants making the material unsuitable for use in making new products. The invention provides an economical treatment process that renders such materials suitable for reuse. The process includes maintaining a particulate feedstock created from the waste material at a temperature in the range 275-500° C. and applying superheated steam to the material.Type: GrantFiled: September 1, 2000Date of Patent: September 4, 2001Assignee: Vesuvius Crucible CompanyInventor: Ian Strawbridge
-
Patent number: 6283341Abstract: A continuous casting nozzle for casting molten steel, wherein at least a surface layer of an inner bore of the continuous casting nozzle contacting with a molten steel is formed of a refractory comprising: an aggregate consisting essentially of zirconia (ZrO2), or comprising zirconia (ZrO2) as its main component and melting point thereof being at least 1750° C.: from 15 to 60 wt. %; and roseki as a balance. The refractory is added to a thermosetting resin as a binder, kneaded, formed, and sintered in an anti-oxidizing atmosphere.Type: GrantFiled: July 8, 1999Date of Patent: September 4, 2001Assignee: Akechi Ceramics Kabushiki KaishaInventors: Toshiyuki Muroi, Kazumi Oguri
-
Patent number: 6257466Abstract: A continuous casting nozzle for casting molten steel, wherein the surface layer of the bore of said continuous casting nozzle contacting with the molten steel is formed of a refractory material comprising silicon carbide from 1 to 10 wt %, an aggregate comprising alumina or an aggregate which comprises alumina as main component whose melting point is not less than 1800 degree C. from 15 to 60 wt %, and roseki as a main component from 30 to 84 wt %.Type: GrantFiled: April 17, 2000Date of Patent: July 10, 2001Assignee: Akechi Ceramics Kabushiki KaishaInventors: Toshiyuki Muroi, Kazumi Oguri
-
Patent number: 6113802Abstract: An insulation material which is substantially free of fibers and which has a density of less than about 2.5 g/cc and a thermal conductivity of less than about 5 W/Km is formed from a composition comprising at least about 2%, by weight, carbon. The insulation material is resistant to thermal shock and is easily machined.Type: GrantFiled: March 19, 1998Date of Patent: September 5, 2000Assignee: Micropyretics Heaters International, Inc.Inventor: Srinivas Penumella
-
Patent number: 5990027Abstract: Flexible graphite sheet having embedded ceramic fibers extending from its surfaces into the sheet to increase the permeability of the sheet to resin. The resin impregnated sheet is formed into a sealing gasket.Type: GrantFiled: July 2, 1997Date of Patent: November 23, 1999Assignee: UCAR Carbon Technology CorporationInventors: Robert Angelo Mercuri, Joseph Paul Capp, Jeffrey John Gough
-
Patent number: 5932506Abstract: A refractory castable comprised of:about 45% to about 75% by weight high alumina grain;about 2% to about 35% by weight silicon carbide;about 1% to about 8% by weight carbon;about 1% to about 8% by weight calcium aluminate cement; andabout 1% to about 10% by weight fine magnesium aluminate spinel,the spinel having a grain size of less than about 150 .mu.m (100 Tyler mesh) and being comprised of about 10% to about 33% by weight magnesium oxide (MgO) and about 67% to about 90% by weight alumina (Al.sub.2 O.sub.3).Type: GrantFiled: February 23, 1998Date of Patent: August 3, 1999Inventor: Jeffrey E. Bogan
-
Patent number: 5912243Abstract: A compound having the formula R--S(O).sub.n CH.sub.2 CH.sub.2 CH.dbd.CF.sub.Type: GrantFiled: August 28, 1996Date of Patent: June 15, 1999Assignee: Zeneca LimitedInventors: Alan John Dowling, Alison Mary Craig, Christopher Richard Ayles Godfrey, Harjinder Singh Bansal, Matthew Brian Hotson, Michael Drysdale Turnbull, Nan Catherine Sillars, Roger Salmon, Steven Fitzjohn
-
Patent number: 5911900Abstract: The invention is related to a continuous casting nozzle for casting of aluminum killed steel without clogging of the bore of the nozzle. The surface layer of the bore of the continuous casting nozzle contacting with the molten steel is formed of a refractory comprising graphite from 10 to 35 wt %, an aggregate of 10 to 60 wt % selected from alumina matter, zirconia matter, zircon matter, or alumina-silica matter and roseki containing the pyrophyllite (Al.sub.2 O.sub.3 .multidot.4SiO.sub.2 .multidot.H.sub.2 O) as the main component as the remaining part of the above mentioned materials.Type: GrantFiled: November 28, 1997Date of Patent: June 15, 1999Assignee: Akechi CeramicsInventors: Toshiyuki Muroi, Shojiro Naito
-
Patent number: 5866490Abstract: Disclosed is a monolithic refractory comprising 1 to 30 weight parts of pitch having 65 to 90 wt.-% of fixed carbon and a softening point of 250.degree. to 350.degree. C. to form a carbon bond, relative to 100 weight parts of refractory material so as to form carbon bond. The monolithic refractory can contain 0.01 to 0.5 weight parts of carbon fiber. The composition of the invention may be used as any type of monolithic refractory such as gunning material, casting material, in particular, aqueous type casting material, burning type hot repairing mix, mortar, Tamping material, and any basic, neutral, or acid refractory material may be used. The monolithic refractory is capable of solving the drawbacks of the conventional monolithic refractories such as rupture, lack of low shrinkage, low bonding strength, low hot strength, and having both superior strength and superior applicability.Type: GrantFiled: December 26, 1996Date of Patent: February 2, 1999Assignee: Kyushu Refractories Co., Ltd.Inventors: Akira Watanabe, Hirokuni Takahashi, Shigeyuki Takanaga, Yasutoshi Mizuta
-
Patent number: 5856251Abstract: Castable refractory for a slide gate plate is mainly formed of alumina raw material and amorphous carbon raw material of 2 to 15 wt %, and contains silicon carbide and/or boron carbide, the total content thereof being equal to 0.5 to 10 wt % (the content of boron carbide is equal to or less than 3 wt %, and when the content of boron carbide is less than 0.5 wt %, silicon carbide is set to 3 wt % or more), 2 to 10 wt % magnesia of 1 mm or less in particle size, 0.2 to 3 wt % silica fine powder of 5 micrometers or less in particle size, and 0.1 to 5 wt % salt of condensate of formalin and aromatic sulfonate.Type: GrantFiled: June 9, 1997Date of Patent: January 5, 1999Assignee: Toshiba Ceramics Co., Ltd.Inventors: Hisahiro Teranishi, Isao Imai, Toshihiro Indou