Hydraulic Cement Containing Patents (Class 501/124)
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Patent number: 10526541Abstract: The present technology is generally directed to horizontal heat recovery and non-heat recovery coke ovens having monolith crowns. In some embodiments, an HHR coke oven includes a monolith crown that spans the width of the oven between opposing oven sidewalls. The monolith expands upon heating and contracts upon cooling as a single structure. In further embodiments, the crown comprises a thermally-volume-stable material. The crown may be an oven crown, an upcommer arch, a downcommer arch, a J-piece, a single sole flue arch or multiple sole flue arches, a downcommer cleanout, curvilinear corner sections, and/or combined portions of any of the above sections. In some embodiments, the crown is formed at least in part with a thermally-volume-stable material. In further embodiments, the crown is formed as a monolith (or several monolith segments) spanning between supports such as oven sidewalls. In various embodiments, the monolith and thermally-volume-stable features can be used in combination or alone.Type: GrantFiled: June 30, 2015Date of Patent: January 7, 2020Assignee: SUNCOKE TECHNOLOGY AND DEVELOPMENT LLCInventors: Gary Dean West, John Francis Quanci
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Corrosion-resistant refractory binder compositions and oil well completion and production operations
Patent number: 10351753Abstract: Corrosion-resistant refractory binder compositions may include high alumina cement, high-alumina refractory aluminosilicate material, and phosphorous material. Examples of high-alumina refractory aluminosilicate material include crushed firebrick, firebrick grog, refractory mortar, fire clay, mullite, fused mullite, and combinations thereof. The binder composition may be mixed with sufficient amount of fluid such as water to form a slurry and introduced into a wellbore penetrating a subterranean formation, where it may be allowed to set at a point downhole. Such compositions, once set, may exhibit enhanced corrosion and heat resistance. Such compositions, once set, may additionally be cured. Curing may take place at higher temperatures and/or pressures, and may furthermore increase temperature resistance and/or strength of the set binder composition.Type: GrantFiled: December 18, 2013Date of Patent: July 16, 2019Assignee: Halliburton Energy Services, Inc.Inventors: Kyris Agapiou, Ben Iverson, Sam Lewis -
Patent number: 10011764Abstract: A method of fracturing a subterranean formation comprising: introducing a fracturing fluid into the subterranean formation to create or enhance one or more fractures in the subterranean formation; introducing a cement composition into the one or more fractures, wherein the cement composition comprises: (A) cement; (B) water; and (C) an additive; and allowing the cement composition to set, wherein the additive creates a plurality of pores within the set cement.Type: GrantFiled: February 12, 2015Date of Patent: July 3, 2018Assignee: Halliburton Energy Services, Inc.Inventors: Venkata Satya Srikalyan Bhamidipati, Denise N. Benoit, Jimmie D. Weaver, Philip D. Nguyen
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Patent number: 9388976Abstract: A combustor including a housing, an injector body, insulation, an air/fuel premix injector, a hot surface igniter, a fuel injector and a burner. The housing forms a main combustion chamber. The injector body is coupled within the housing and the injector body includes an initial combustion chamber. The insulation lines the initial combustion chamber. The air/fuel premix injector is configured and arranged to dispense a flow of air/fuel mixture into the initial combustion chamber. The hot surface igniter is configured and arranged to heat up and ignite the air/fuel mixture in the initial combustion chamber. The fuel injector dispenses a flow of fuel and the burner dispenses a flow of air. The flow of fuel from the fuel injector and the flow of air from the burner are ignited in the main combustion chamber by the ignition of the air/fuel mixture in the initial combustion chamber.Type: GrantFiled: March 1, 2013Date of Patent: July 12, 2016Assignee: Orbital ATK, Inc.Inventors: Daniel Tilmont, Joseph A. Alifano, Akiva A. Sklar, Nicholas Tiliakos, Vincenzo Verrelli
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Patent number: 8932970Abstract: Hardness, ageing resistance, wetting behavior in relating to water and high thermal conductivity are known characteristics of sintered molded bodies consisting of aluminum oxide; high strength and a high resistance to cracking, i.e., damage tolerance are known characteristics of sintered molded bodies consisting of zirconium oxide. These properties are combined in a material having a large fraction of aluminum oxide, zirconium oxide and optionally strontium aluminate.Type: GrantFiled: April 25, 2008Date of Patent: January 13, 2015Assignee: CeramTec GmbHInventors: Meinhard Kuntz, Ana Herrán Fuertes, Kilian Friederich, Norbert Schneider
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Patent number: 8835338Abstract: This binder for monolithic refractories includes a solid solution obtained by dissolving Ca components in ?-SrAl2O4 or ?-SrAl2O4, wherein when the Ca components are dissolved in the ?-SrAl2O4, a crystallite diameter of the solid solution is from 40 nm to 75 nm, and when the Ca components are dissolved in the ?-SrAl2O4, a crystallite diameter of the solid solution is from 35 nm to 70 nm.Type: GrantFiled: April 28, 2011Date of Patent: September 16, 2014Assignee: Nippon Steel & Sumitomo Metal CorporationInventors: Yoshitoshi Saito, Atsunori Koyama
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Patent number: 8778822Abstract: The present invention provides a ceramic porous body for in-vitro and in-vivo use comprising a composition comprising a calcium aluminate (CA) containing phase and optionally at least one of an accelerator, a retarder, a surfactant, a foaming agent, a reactive alumina, water, a fiber, and a biologically active material, and combinations thereof. Ceramic compositions are provides as well as method of using the ceramic compositions and methods of manufacturing a ceramic porous body. The ceramic porous bodies of this invention may be used as artificial bones, joints, in-vitro support structures, and in-vivo support structures for cells, tissues, organs, and nerve growth and regeneration.Type: GrantFiled: August 9, 2010Date of Patent: July 15, 2014Assignee: Cabertech, Inc.Inventor: Kenneth A. McGowan
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Patent number: 8309483Abstract: A binder for monolithic refractories characterized by containing ingredients comprised of a chemical composition of at least one of CaxSr1-xAl2O4, and CaySr1-yAl4O7 or these plus 12(CaO)z(SrO)1-z.7Al2O3 (where, 0<x<1, 0<y<1, and 0<z<1) and a binder for monolithic refractories and monolithic refractories superior in erosion resistance to slag or molten iron by monolithic refractories comprised of this binder and refractory aggregates are provided.Type: GrantFiled: October 27, 2008Date of Patent: November 13, 2012Assignees: Nippon Steel Corporation, Denki Kagaku Kogyo Kabushiki KaishaInventors: Yoshitoshi Saito, Atsunori Koyama
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Patent number: 8076255Abstract: To provide a long-life refractory capable of maintaining durability under severe conditions. The castable refractory comprises a mixture containing at least one of 2 to 10 mass % of silicon carbide and 3 to 10 mass % of chamotte, as an auxiliary raw material, and a binder material, with the remaining balance being one or more main raw materials selected from corundum, mullite, bauxite, chamotte, talc and silica, and is used in an environment exposed to an alkali component-containing hot gas atmosphere. In an alkali component-containing gas atmosphere at a high temperature (750° C. or more), silicon carbide and/or chamotte are vitrified to a thickness of 1 mm or less in the surface layer of the refractory to prevent the alkali component-containing gas from intruding inside of the refractory.Type: GrantFiled: October 27, 2006Date of Patent: December 13, 2011Assignee: Nippon Steel CorporationInventors: Satoru Ito, Hitoshi Nakamura, Taijiro Matsui, Michio Nitta
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Patent number: 7772146Abstract: The present invention provides a ceramic porous body for in-vitro and in-vivo use comprising a composition comprising a calcium aluminate (CA) containing phase and optionally at least one of an accelerator, a retarder, a surfactant, a foaming agent, a reactive alumina, water, a fiber, and a biologically active material, and combinations thereof. Ceramic compositions are provides as well as method of using the ceramic compositions and methods of manufacturing a ceramic porous body. The ceramic porous bodies of this invention may be used as artificial bones, joints, in-vitro support structures, and in-vivo support structures for cells, tissues, organs, and nerve growth and regeneration.Type: GrantFiled: August 24, 2004Date of Patent: August 10, 2010Inventor: Kenneth A. McGowan
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Patent number: 7710033Abstract: Display panel comprising two plates leaving between them a sealed space that is filled with a discharge gas and is partitioned into discharge cells bounded between these plates by barrier ribs made of a mineral material comprising a mineral binder based on a hydraulic binder, and a mineral filler. By using a hydraulic binder instead of a glassy mineral binder, the display panels may be manufactured at lower temperature.Type: GrantFiled: May 24, 2004Date of Patent: May 4, 2010Inventors: Armand Bettinelli, Jean-Philippe Browaeys
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Patent number: 7632770Abstract: The invention relates to a fired, basic, refractory, industrial ceramic shaped body comprising at least one basic resistor component and an elasticizer component, wherein the elasticizer component is a calcium aluminate having the abbreviated formula CA6. The invention additionally relates to a process for producing the shaped body and to its use.Type: GrantFiled: December 29, 2003Date of Patent: December 15, 2009Assignee: Refratechnik Holding GmbHInventor: Hans-Jürgen Klishchat
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Patent number: 7494950Abstract: The present invention relates in general to implantable compositions, and method for preparing same, containing a calcium salt-containing component, optionally demineralized bone, a plurality of discrete fibers, optionally a flow additive, and optionally continuous reinforcing fibers or an array of organized fibers in the form of mesh. Advantageously, the discrete fibers have a specific aspect ratio (length/diameter) from about 50:1 to about 1000:1. The addition of a small amount of discrete fibers and/or the continuous reinforcing fibers or fiber mesh can cause drastic increases in certain mechanical properties including flexural strength, flexural toughness, and/or screw pullout strength.Type: GrantFiled: September 7, 2004Date of Patent: February 24, 2009Assignees: Synthes (U.S.A.), Synthes GmbHInventors: Bryan Monro Armitage, Ira Ison, Mark Fulmer, Sean Kerr, Michael Lehmicke, Patrick Leamy, William Schiffer
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Patent number: 7459409Abstract: Excellent characteristics concerning slag penetration-resistance, corrosion-resistance, and structural stability on usage of lining-refractory such as equipment for desiliconizing molten iron, a ladle for steel-making, a RH equipment are obtained. Unshaped refractories provide fine particles of under 0.75mm diameter, and aggregate of 0.75-10mm. Furthermore, the fine particles contain 10-35 mass % content of MgO, to the total mass % of the fine particles. Even furthermore, the sum total amount of MgO and Al2O3 is more than 90 mass %, to the total mass % of the fine particle. Additionally, such fine particles has 5-40 mass % of particles made of periclase-spinel, as a source of MgO, to the total mass % of the unshaped refractories. And, the aggregate comprises at least one selected from the group consisting of particles made of alumina and particles made of spinel.Type: GrantFiled: June 23, 2005Date of Patent: December 2, 2008Assignee: JFE Steel CorporationInventor: Yoshisato Kiyota
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Patent number: 7166551Abstract: A subject for the invention is to provide an unshaped refractory composition having not only high thermal resistance but also improved corrosion resistance and improved unsusceptibility to slag infiltration. The invention is “an unshaped refractory composition comprising: (1) 20 to 70% by weight raw spinel material comprising an MgO—Al2O3 spinel phase and containing 2 to 20% by weight magnesia and/or raw spinel/corundum material comprising an MgO—Al2O3 spinel phase and a corundum phase and containing 2 to 20% by weight magnesia; (2) 3 to 12% by weight raw magnesia material having a particle diameter of 0.3 mm or smaller, containing particle sizes of 75 ?m or smaller in an amount of 55 to 85% by weight, and having a magnesia purity of 90% by weight or higher; (3) 3 to 10% by weight alumina cement having a calcia content lower than 20% by weight; (4) 0.3 to 1.5% by weight ultrafine powder consisting mainly of silica; and (5) a raw alumina material as the remainder”.Type: GrantFiled: May 8, 2002Date of Patent: January 23, 2007Assignee: Shinagawa Refractories Co., Ltd.Inventors: Toshihiko Kaneshige, Hisaharu Sasaki, Yukiharu Tabuchi
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Patent number: 7074733Abstract: An unwrought refractory composition, in particular for producing glass furnace hearths, includes a base mixture comprising in wt. %: 1 to 6% of a hydraulic cement, and 94 to 99% of particles of at least a refractory material mainly consisting of alumina (Al2O3), zirconia (ZrO2) and silica (SiO2), the fraction of the particles of the base mixture having a size less than 40 ?m being distributed in wt. % relative to the weight of the base mixture, as follows: fraction<0.5 ?m: ?4%; fraction<2 ?m: ?5%; fraction<10 ?m: ?16%; fraction<40 ?m: 29–45%, the refractory composition further comprising, in wt. % relative to the weight of the base mixture: 0.02 to 0.08% of organic fibers, and 0.075 to 1% of a surfactant.Type: GrantFiled: November 19, 2002Date of Patent: July 11, 2006Assignee: Saint-Gobain Centre de Recherches Et d'Etudes EuropeenInventors: Jacques Marius Louis Guigonis, Thierry Claude Consales
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Patent number: 7025824Abstract: A chemically bonded ceramic material based on calcium aluminate hydrate with additives of primarily calcium titanate, but also chemically similar compounds. The material is a biocompatible material for implants, particularly for orthopaedic and dental applications. The material possesses the properties required for an orthopaedic biocement. It cures through reaction with water and develops its strength within a short period of time, has good workability prior to curing, is shape stable, has a low heat generation during curing, and is friendly to adjacent tissues.Type: GrantFiled: December 19, 2002Date of Patent: April 11, 2006Assignee: CerBio Tech ABInventors: Niklas Axén, Leif Hermansson, Tobias Persson, Kajsa Björklund, Lars Kraft
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Patent number: 6995105Abstract: The use of a three-component water-soluble polymer comprising 5–90% by weight of a component a), preferably of the maleic acid, fumaric acid or itaconic acid type, 5–90% by weight of a component b) essentially from the group consisting of 2-acrylamido-2-methylpropanesulfonic acid, vinylsulfonic acid and vinylphosphonic acid, and 5–90% by weight of a component c) comprising acrylic acid, methacrylic acid, acrylamide or methacrylamide, as fluidizer for refractory compositions comprising alumina cement is described. The copolymer, which has a preferred molecular weight Mw of <50,000, can also be combined with further quality-improving additives such as silica, lime or soda and further customary additives for refractory compositions.Type: GrantFiled: July 8, 1999Date of Patent: February 7, 2006Assignee: SKW Polymers GmbHInventors: Steffen Wache, Johann Plank, Konrad Wutz, Manfred Bichler
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Patent number: 6686305Abstract: Methods of making ceramic bodies are disclosed. The methods include manufacturing calcium aluminate material having a low coefficient of thermal expansion.Type: GrantFiled: September 25, 2002Date of Patent: February 3, 2004Assignee: Corning IncorporatedInventors: Douglas M. Beall, Shahid G. Lakhwani, Linda R. Pinckney
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Patent number: 6667262Abstract: The invention comprises a self-lubricating ceramic composite characterized as having a low porosity derived from a mixture of at least one ceramic powder preferably selected from the group consisting of silicon nitride, silicon carbide, zirconia, alumina, zirconium nitride, tungsten carbide, and titanium carbide; a cemetitious binder, effective amounts of at least one metal silicide, and at least one metal oxide. The ceramic powder mixture can be slurried with sufficient amounts of water and subsequently subjected to pressures of about 6.0 to 7.0 MPa in a mold at temperatures of about 125° to 175° C. to form a self-lubricating ceramic composite capable of maintaining hot-hardness temperatures above 750° C. These self-lubricating ceramic composites are particularly useful in the manufacture of high-performance turbine engines, including engine parts, bearings, gears, rotors and in other areas where high-heat lubricating properties of the ceramic composite are required.Type: GrantFiled: September 7, 2001Date of Patent: December 23, 2003Assignee: The United States of America as represented by the Secretary of the NavyInventors: Vinod S. Agarwala, Alfeo A. Conte, Jr.
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Patent number: 6458732Abstract: A dry refractory composition having superior insulating value. The dry refractory composition also may have excellent resistance to molten metals and slags. The composition includes filler lightweight material, which may be selected from perlite, vermiculite, expanded shale, expanded fireclay, expanded alumina silica hollow spheres, bubble alumina, sintered porous alumina, alumina spinel insulating aggregate, calcium alumina insulating aggregate, expanded mulllite, cordierite, and anorthite, and matrix material, which may be selected from calcined alumina, fused alumina, sintered magnesia, fused magnesia, silica fume, fused silica, silicon carbide, boron carbide, titanium diboride, zirconium boride, boron nitride, aluminum nitride, silicon nitride, Sialon, titanium oxide, barium sulfate, zircon, a sillimanite group mineral, pyrophyllite, fireclay, carbon, and calcium fluoride.Type: GrantFiled: June 7, 1999Date of Patent: October 1, 2002Assignee: Allied Mineral Products, Inc.Inventors: Douglas K. Doza, John Y. Liu
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Patent number: 6287999Abstract: The invention relates to a method of producing refractory compositions and more particularly to a method for producing castable refractory compositions which comprises combining appropriate quantities of bulk particulate refractory aggregates substantially without pre-mixing; separately adding to the aggregate system an appropriate quantity of a pre-blended binder composition; mixing the aggregate system and the pre-blended binder composition in a mixer; and discharging the refractory composition from the mixer.Type: GrantFiled: February 22, 2000Date of Patent: September 11, 2001Assignee: Vesuvius Crucible CompanyInventors: Alan Hey, David Michael Pickard
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Patent number: 6274525Abstract: The process for making the high temperature-resistant ceramic material from the MgO—Al2O3 system includes burning a mixture containing a predetermined amount of magnesium oxide (MgO) of a predetermined grain size distribution in an amount range of from 30 to 99 parts by weight and a predetermined amount of magnesium aluminate (MgAl2O4) of another different predetermined grain size distribution in a range of from 1 to 70 parts by weight to obtain a ceramic product having a thermal expansion coefficient and selecting the amounts of magnesium oxide and magnesium aluminate as well as the predetermined grain size distributions so that the thermal expansion coefficient of the ceramic product is substantially equal to that of platinum and platinum alloys and in a range of from 9×10−6 K−1 to 15×10−6 K−1.Type: GrantFiled: July 22, 1999Date of Patent: August 14, 2001Assignee: Schott GlasInventors: Janusz Zborowski, Uwe Eichhorn, Bartolome Aloy-Dols
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Patent number: 6022593Abstract: A method for placing a thixotropic low-cement castable refractory material without the necessity for forms. A low-cement castable material is mixed with a measured amount of water, then is pumped hydraulically through a hose to a nozzle assembly. Compressed air and a cement setting agent are added to the mixture at the nozzle. The addition of the setting agent at the nozzle overcomes the thixotropic nature of the low-cement castable, so that it will immediately "set" in position when sprayed onto a surface, including vertical and overhead surfaces.Type: GrantFiled: April 29, 1997Date of Patent: February 8, 2000Assignees: Reno & Son, Inc., Oak Mountain Industries, Inc.Inventor: Eric L. Allison
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Patent number: 5976718Abstract: A premix composition for producing an inorganic solid foamed mass by mixing component (A) an aqueous acidic phosphate solution of mainly polyvalent cations and phosphoric acid wherein between 0.8 and 1.75 protons of the phosphoric acid molecule of said phosphate are neutralized by the cations, which also contains one or more fillers dispersed therein, with (B) an oxide, hydroxide or polyvalent salt of a weak acid as hardener and a carbonate foaming agent. A process of producing an inorganic foamed mass using the premix composition and a solid foamed mass produced by the process are also disclosed. The process produces a relatively elastic cross-linked structure due to mainly the secondary phosphates being neutralized versus the tertiary phosphate groups.Type: GrantFiled: June 29, 1998Date of Patent: November 2, 1999Inventor: Gerhard Melcher
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Patent number: 5954872Abstract: The present invention is directed to a dry phosphate cement mixture and process for manufacture of same. The dry mixture includes at least Al(H.sub.2 PO.sub.4).sub.3, a group IIA metal bonded to oxygen, and an aggregate. The process for manufacturing cement includes associating the dry reagent with a substantially polar solvent, such as water. The total reagent concentration is formulated such that only nominally exothermic reactions are observed. The process accommodates variable setting times and provides resulting concrete which exhibits formidable structural integrity.Type: GrantFiled: April 14, 1997Date of Patent: September 21, 1999Assignee: Reno Refractories, Inc.Inventor: James T. Benson
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Patent number: 5932506Abstract: A refractory castable comprised of:about 45% to about 75% by weight high alumina grain;about 2% to about 35% by weight silicon carbide;about 1% to about 8% by weight carbon;about 1% to about 8% by weight calcium aluminate cement; andabout 1% to about 10% by weight fine magnesium aluminate spinel,the spinel having a grain size of less than about 150 .mu.m (100 Tyler mesh) and being comprised of about 10% to about 33% by weight magnesium oxide (MgO) and about 67% to about 90% by weight alumina (Al.sub.2 O.sub.3).Type: GrantFiled: February 23, 1998Date of Patent: August 3, 1999Inventor: Jeffrey E. Bogan
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Patent number: 5783510Abstract: A monolithic refractory composition, which can be rapidly dried after being mixed with water and applied to a desired portion by casting or spraying to form a furnace wall, and which comprises refractory aggregates, a refractory powder, an aluminum alloy powder and a dispersant, wherein the aluminum alloy powder is contained in an amount of from 0.04 to 5 parts by weight per 100 parts by weight of the total amount of the refractory aggregates and the refractory powder.Type: GrantFiled: June 27, 1996Date of Patent: July 21, 1998Assignee: Asahi Glass Company Ltd.Inventors: Otojiro Kida, Eri Suzuki, Yasushi Ono
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Patent number: 5753572Abstract: Mixes suitable for casting or gunning containing a heat-resistant aggregate blend containing at least about 50 wt. % high alumina grain, silicon carbide, and zircon sand, and to the method of utilizing the same to form alkali-resistant linings in high temperature vessels that have improved resistance to build-up.Type: GrantFiled: June 28, 1996Date of Patent: May 19, 1998Assignee: Harbison-Walker Refractories CompanyInventors: Mark C. Langenohl, Christopher L. Macey
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Patent number: 5681785Abstract: A castable refractory which comprises a matrix, making up 100 wt % in total, composed of 3-20 wt % of magnesia clinker having a particle diameter smaller than 0.21 mm and containing more than 95 wt % of MgO and 0.5-3.0 wt % of alumina cement in terms of CaO, with the remainder being alumina, and 0.1-3 wt % of ultrafine powder of amorphous silica and 3-9 wt % of alumina coarse grains having a particle diameter of 8-20 mm, both in terms of outer percentage of the amount of the matrix.Type: GrantFiled: October 28, 1996Date of Patent: October 28, 1997Assignee: Krosaki CorporationInventors: Kazuhiro Furuta, Yusuke Urita, Minoru Kataoka, Hiroshi Kubota, Mitsuo Sugawara
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Patent number: 5681786Abstract: A castable refractory which comprises a matrix, making up 100 wt % in total, composed of 3-20 wt % of magnesia clinker having a particle diameter smaller than 0.21 mm and containing more than 95 wt % of MgO and 0.5-3.0 wt % of alumina cement in terms of CaO, with the remainder being alumina, and 0.1-3 wt % of ultrafine powder of amorphous silica and 41-100 wt % of alumina coarse grains having a particle diameter of 10-50 mm, both in terms of outer percentage of the amount of the matrix.Type: GrantFiled: October 28, 1996Date of Patent: October 28, 1997Assignee: Krosaki CorporationInventors: Kazuhiro Furuta, Yusuke Urita, Minoru Kataoka, Hiroshi Kubota, Mitsuo Sugawara
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Patent number: 5650121Abstract: The disclosed invention provides a method of forming refractory linings for maintaining refractory linings against attack by corrosive materials such as those present in steel manufacture. The method entails spraying an aqueous mixture of a refractory composition that includes at least one refractory material onto the working surface of a refractory lining. Spraying is performed to provide one or more layers of the refractory composition on the refractory lining after each exposure of the lining to corrosive materials such as those incurred in steel manufacture.Type: GrantFiled: June 6, 1995Date of Patent: July 22, 1997Assignee: Minerals Technologies, Inc.Inventors: Julie Annette Dody, Charles R. Rumpeltin, Jr.
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Patent number: 5641348Abstract: A mixture producing a slurry for coating metallic vehicle exhaust conduits utilizing a refractory cement and a caustic or alkaline salt binder. Sufficient amounts of water are also employed in the slurry resulting in a flowable material. The slurry flows over and hardens as a thin uniform coating on the interior surface of an exhaust conduit. The coating exhibits excellent adhesion to the metallic material, does not crack or chip under impact forces, and possesses a coefficient of thermal expansion similar to the underlying metallic structure.Type: GrantFiled: August 7, 1995Date of Patent: June 24, 1997Inventors: Richard N. Miller, Noble Thomas Pessano
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Patent number: 5603759Abstract: A pulverulent mix, sprayable when mixed with a liquid for forming a stable, cement-bonded insulating refractory which can be sprayed onto vertical and overhead surfaces without deformation, comprising a lightweight and/or dense refractory aggregate, a calcium aluminate cement, a microsilica, a ball clay, and a superfine refractory. The superfine refractory comprises 2 to 15 wt. % of the mix and the -325 mesh portion of the mix being from about 40 to 60 wt. %.Type: GrantFiled: May 30, 1995Date of Patent: February 18, 1997Assignee: Indresco Inc.Inventor: Andrew M. Burkhart
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Patent number: 5582695Abstract: The structural part is used in an electolytic cell for production of aluminum and comes into contact with the gas atmosphere in the electrolytic reduction cell. The structural part is made completely from, or is a metal part which is coated with, a concrete composition of 15-30% by weight of a hydraulic cement, 5-10% by weight of microsilica and 65-85% by weight of a refractory filler material.Type: GrantFiled: July 17, 1995Date of Patent: December 10, 1996Assignee: Elkem Aluminium ANSInventor: Odd Olsen
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Patent number: 5578538Abstract: The castable refractory material comprising as binders, per 100 parts by weight of solid components, (a) 10-30 parts by weight of water-inactive, fine refractory powder, which is a mixture of fine refractory powder having an average diameter of 0.2-0.6 .mu.m and fine refractory powder having an average diameter of 1-10 .mu.m at a ratio of 1:2-2:1; (b) 2-7 parts by weight (as an effective amount) of alumina cement having an average diameter of 3-8 .mu.m, cement clinker minerals thereof comprising CaO.Al.sub.2 O.sub.3 and CaO.2Al.sub.2 O.sub.3, with 12CaO.7Al.sub.2 O.sub.3, if any, in such an amount that a diffraction intensity index of the 12CaO.7Al.sub.2 O.sub.3 at a lattice plane distance D of 2.68 .ANG. is 1 or less assuming that the diffraction intensity index of the CaO.Al.sub.2 O.sub.3 at a lattice plane distance D of 2.96 .ANG. is 100; and (c) 0.4-3 parts by weight of fine amorphous silica powder having an average diameter of 0.5 .mu.Type: GrantFiled: May 19, 1995Date of Patent: November 26, 1996Assignee: Taiko Refractories Co., Ltd.Inventors: Chiharu Nishikawa, Jun Ohba
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Patent number: 5549745Abstract: An essentially non-slumping, high density, low moisture and low cement castable composition, consisting of a tempered, pumpable first component containing the castable solids and consisting essentially of a refractory aggregate, a calcium-aluminate cement, a flow aid, a deflocculating agent, and water, the water being present in the lowest amount sufficient to achieve a pumpable consistency of the tempered first component, and a flocculating agent as a second component to be added to said first component at time of installation in an amount sufficient to give the castable a dried bulk density of at least about 120 pcf.Type: GrantFiled: October 27, 1995Date of Patent: August 27, 1996Assignee: Indresco Inc.Inventors: Mark C. Langenohl, Gustav G. Hughes
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Patent number: 5512523Abstract: A monolithic refractory powder mixture containing from 2 to 3 wt % of spheroidized refractory particles having a mean particle size of at most 30 .mu.m of at least one member selected from the group consisting of alumina cement, alumina, titania, bauxite, diaspore, mullite, aluminous shale, chamotte, pyrophyllite, sillimanite, andrewsite, silica rock, chromite, spinel, magnesia, zirconia, zircon, chromia, silicon nitride, aluminum nitride, silicon carbide, boron carbide, zirconium boride and titanium boride, and having a cone flow value of at least 180 mm when a refractory mixture having the powder mixture kneaded by an addition of 6 parts by weight of water per 100 parts by weight of the powder mixture, is cast into a cone-shaped mold with a dimension of 70 mm.o slashed.-100 mm.o slashed..times.60 mm and left to stand for 60 seconds without exerting vibration after removing the cone-shaped mold.Type: GrantFiled: January 13, 1995Date of Patent: April 30, 1996Assignee: Asahi Glass Company Ltd.Inventors: Yasushi Ono, Satoshi Sakamoto, Yutaka Murata, Tetsuo Kaji, Yasuhiko Endo
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Patent number: 5420087Abstract: Refractory or fireproof brick useful as tin bath bottom brick, wherein the brick is made of a calcium aluminate having both coarse and fine grain sizes, and a binder made of calcium aluminate.Type: GrantFiled: February 15, 1994Date of Patent: May 30, 1995Assignee: Didier-Werke AGInventors: Klaus Wieland, Thomas Weichert, Axel Eschner, Christoph Wohrmeyer
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Patent number: 5284712Abstract: The occurrence of efflorescence has been reduced or eliminated in ceramic articles formed from a novel vitreously bonded cement-containing composition. The articles also exhibit improved strength, reduced firing shrinkage and increased frost resistance. The articles are produced by combining hydraulic cement containing calcium silicate and/or calcium aluminate components, vitrifiable inorganic powders forming molten liquid-flowing substances, and reactive or sinterable mineral powders selected from the group consisting of magnesium silicates, aluminum silicates and mixtures thereof; combining the ingredients with water to form a mixture; molding the mixture into an article; hardening the article by hydration; and firing the molded article to a maximum temperature of between about 1000.degree. C. to 1400.degree. C.Type: GrantFiled: September 25, 1992Date of Patent: February 8, 1994Inventors: Kazuyuki Kawai, Kazumasa Goto, Takayuki Shirai
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Patent number: 5252525Abstract: A high temperature ceramic filter is produced from a composition containing refractory cement, aggregate, pore forming additives, and sintering agents. The pore forming additives are synthetic or organic powders or fibers which sublimate, melt, or otherwise disintegrate to produce In situ pores in the cement during the refractory treatment of a cast filter. The filters produced are permeable to high temperature gases commonly found in a coal furnace and can be used to collect particulate matter present in those gases.Type: GrantFiled: February 10, 1992Date of Patent: October 12, 1993Assignees: Virginia Tech Intellectual Properties, Inc., Center for Innovative TechnologyInventors: Sandra Gonzales, Nancy Brown, Jesse J. Brown
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Patent number: 5212126Abstract: A monolithic refractory with improved resistance to molten aluminum and a method of imparting the resistance by adding 0.2 to 1 wt.% polyvinyl chloride powder to the base mix.Type: GrantFiled: June 10, 1991Date of Patent: May 18, 1993Assignee: Dresser Industries, Inc.Inventors: Lawrence D. Fitch, Thomas R. Kleeb
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Patent number: 5135576Abstract: The present invention relates to combined structures of ceramic material and super concrete, which structures comprise an outer layer of ceramic material bonded to an internal structure of super concrete or an outer structure of super concrete bonded to an inner layer of ceramic material.The ceramic material is selected among any class of inorganic non-metallic products which are subjected to a temperature of 540.degree. C. and above during manufacture or use, while the super concrete comprises densely packed particles of inorganic materials embedded in a matrix based on an hydraulic cement and having a strength of at least 70 MPa.Type: GrantFiled: October 18, 1990Date of Patent: August 4, 1992Assignee: Elkem alsInventors: Knut Johansen, Oyvind Larsen, Terje Nilsen
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Patent number: 5073199Abstract: An asbestos-free insulating material suitable for use in molten metal casting is disclosed. The material is made from a mixture comprising lime, siliceous component, wollastonite, inorganic fiber and pitch based graphite fiber. The mixture is mixed with water to form a slurry, shaped, heated in the presence of steam, and dried to remove free water.Type: GrantFiled: November 27, 1990Date of Patent: December 17, 1991Assignee: BNZ Materials, Inc.Inventors: Thomas R. Krowl, Norman Scheffer
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Patent number: 5039454Abstract: A fire barrier composition in the form of a zinc-containing magnesium oxychloride cement is described. The composition exhibits a prolonged pot-life as well as reduced thermal popping when applied to a substrate as a coating. The fire barrier composition can be used for rendering a flammable substrate fire resistant and for encapsulating lead paint.Type: GrantFiled: May 17, 1990Date of Patent: August 13, 1991Inventors: Peter P. Policastro, Raj S. Tarneja
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Patent number: 4992397Abstract: A low thermal conductivity, high strength refractory castable composition with high abrasion resistance consisting essentially of about 55 to 80% by weight amorphous silica, about 5 to 25% by weight of a calcined alumino-silicate aggregate having a density of about 30 to 70 pcf and a particle size of about -10 to +65 mesh, about 5 to 40% by weight of calcined fireclay fines, about 1 to 10% by weight of a flow aid for particle packing, and about 5 to 25% by weight of a calcium aluminate cement.Type: GrantFiled: February 6, 1989Date of Patent: February 12, 1991Inventor: Gustav O. Hughes, Jr.
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Patent number: 4961786Abstract: Certain derivatives of the lanthanide elements greatly enhance the strength of heated alumina refractories in the 500 to 1000 degree Fahrenheit temperature range. Cerium oxide, for example, when added in 1 percent to 5 percent by weight to commercial calcium aluminate cement with tabular alumina aggregate, plus 10 to 30 percent water, and fired at 500 to 1000 degrees Fahrenheit, forms a ceramic bond and becomes as strong as untreated calcium aluminate refractory concrete fired at 2000 degrees Fahrenheit. The cerium modified refractory concrete is 1000 psi to 1500 psi stronger than unmodified refractory concrete at 500 to 1000 degrees Fahrenheit.Type: GrantFiled: May 1, 1989Date of Patent: October 9, 1990Assignee: The United States of America as represented by the Secretary of the NavyInventor: Thomas Novinson
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Patent number: 4943544Abstract: A refractory composition is disclosed which possesses low porosity, high density, exceptional strength and high abrasion resistance and is useful for lining fluid catalytic converter units, e.g., catalyst transfer lines, riser lines, J-bends, cyclones and all other areas where hot abrasion resistance and low thermal conductivity are desired. The composition consists essentially of by weight: (a) 44 to 89% of an abrasion-resistant refractory grain; (b) 10 to 50% of a hydraulically setting cement; (c) 1 to 6% of a filler consisting of very fine, substantially spherical particles of a metal oxide selected from the group consisting of Al.sub.2 O.sub.3, Cr.sub.2 O.sub.3, ZrO.sub.2, TiO.sub.2, clay minerals, carbon and fume SiO.sub.2 ; and (d) 0.01 to 1%, based on the total weight of the constituents (a), (b) and (c), of additives selected from deflocculants and wetting agents.Type: GrantFiled: October 10, 1989Date of Patent: July 24, 1990Assignee: Corhart Refractories CorporationInventors: Charles N. McGarry, Clarence W. J. Miller, Thomas M. Wehrenberg
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Patent number: 4874726Abstract: A refractory composition comprising a fused silica composition comprising a silica compound and a binder and for each 100 parts by weight of said fused silica composition from about 3 to 15 parts by weight of alumina-silica based hollow microspheres.Type: GrantFiled: November 18, 1987Date of Patent: October 17, 1989Assignee: Dresser Industries, Inc.Inventors: Thomas R. Kleeb, Berhl E. Wishon
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Patent number: 4806168Abstract: Refractory material based on grog and hydraulic or chemical binder. The refractory material contains a substantially evenly distributed content of a heat-resistant fiber reinforcement and cutting-material in individual pieces; the use of such refractory material as a constructional material in units for storing valuables, such as bank vaults, safes and the like; and a unit for storing valuables including such refractory material.Type: GrantFiled: June 30, 1987Date of Patent: February 21, 1989Assignees: Hoganas AB, Nordsec Security ABInventors: Lennart Ivarsson, Rolf Lundqvist