Fluorine Containing Patents (Class 501/151)
  • Patent number: 4652218
    Abstract: A canned motor pump is adapted for use at high temperatures and enables generated heat from the motor to be absorbed in a treating fluid or liquid upon circulation through the motor thereby conserving heat values in the treating fluid or liquid. The canned motor pump can circulate high temperature treating fluids, or liquids through the canned motor portion without damaging the coils of the motor because of a ceramic-like high temperature insulation used for the electrical field windings, which insulation is provided by mixing a silicone resin, synthetic fluoro-mica and a devitrified mica glass and impregnating the electrical winding coils with such material, whereafter the material is cured and then subjected to an elevated temperature above 300.degree. C. to form the ceramic-like insulation.
    Type: Grant
    Filed: December 6, 1985
    Date of Patent: March 24, 1987
    Assignee: Nikkiso Co., Ltd.
    Inventors: Toshiaki Tsutsui, Hiroshi Ohki
  • Patent number: 4636480
    Abstract: A composite is produced by forming a porous compact of a ceramic member selected from the group consisting of boron carbide, hafnium carbide, hafnium nitride, niobium carbide, niobium nitride, silicon carbide, silicon nitride, tantalum carbide, tantalum nitride, titanium carbide, titanium nitride, vanadium carbide, vanadium nitride, zirconium carbide and zirconium nitride, and infiltrating the compact with a member selected from the group consisting of barium fluoride, calcium fluoride, magnesium fluoride, strontium fluoride, cerium fluoride, dysprosium fluoride, gadolinium fluoride, lanthanum fluoride, samarium fluoride, yttrium fluoride, and a mixture of said fluoride with a metal oxide.
    Type: Grant
    Filed: July 29, 1985
    Date of Patent: January 13, 1987
    Assignee: General Electric Company
    Inventor: William B. Hillig
  • Patent number: 4626369
    Abstract: Lead zirconate titanate ceramics comprise from about 92 to 99.0 weight pent of lead zirconate and lead titanate in ratio from 0.505 to 0.54:0.495 to 0.46 respectively, from about 0.5 to about 2 weight percent of one or more fluorides or chlorides of an alkali metal or alkaline earth except francium or radium, and 0.5 to 6 weight percent of one or more oxides of magnesium, barium, chromium, scandium, aluminum, lanthanium, praesodymium, neodymium or samarium. The ceramic after pressing is annealed at a temperature from about 1050.degree. to 1350.degree. C. Ceramic elements made from the above ceramics are useful as sonar and microphone transducers.
    Type: Grant
    Filed: June 26, 1985
    Date of Patent: December 2, 1986
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventor: Basil E. Walker, Jr.
  • Patent number: 4623435
    Abstract: A backfill composition for use with sacrificial magnesium anodes used in the cathodic protection of ferrous metal structures comprises an anion-releasing material capable of releasing fluoride, phosphate or zincate ions in water-soluble form and a magnesium-transporting adjuvant capable of transporting magnesium ion by ion exchange conduction. Suitable anion-releasing materials include calcium fluoride, cryolite, magnesium silicate and sodium silicofluoride, while suitable magnesium transporting adjuvants include bentonite clay, calcium sulfate, calcium carbonate, calcium hydroxide and magnesium silicate.
    Type: Grant
    Filed: September 1, 1983
    Date of Patent: November 18, 1986
    Assignee: Columbia Gas System Service Corporation
    Inventors: John W. Nebgen, Gary D. Hinshaw
  • Patent number: 4562164
    Abstract: A ceramic-like high temperature insulation for electrical coils is provided by mixing a silicone resin, synthetic fluoro-mica and a devitrified mica glass, impregnating an electrical coil with such material, curing the material and then treating the material to an elevated temperature about 300.degree. C. The elevated temperature treatment may be effected either prior to or during use of the coil.
    Type: Grant
    Filed: January 23, 1985
    Date of Patent: December 31, 1985
    Assignee: Nikkiso Co. Ltd.
    Inventors: Haruo Miyazaki, Yasuaki Yamasaki, Tsutomu Oshiyama
  • Patent number: 4540677
    Abstract: A powder composition for producing sintered ceramic, which composition contains fluororesin powder which has not been used in the prior art as one of the materials constituting a molding assistant to be blended in the composition. With this composition, it is possible to produce a high-density green molding with few molding defects under a relatively low molding pressure. The invention also provides a process for producing such a composition.
    Type: Grant
    Filed: September 27, 1984
    Date of Patent: September 10, 1985
    Assignee: Ibiden Kabushiki Kaisha
    Inventors: Ryo Enomoto, Kiyotaka Tsukada
  • Patent number: 4503157
    Abstract: There are provided a novel sintered apatite body and a novel sintered apatite-mineral fiber material composite. The crystals of the sintered apatite have fine dense crystalline structures comprising needle-like fine crystals and are entangled together, whereby the mechanical properties of the sintered apatite body or composite are markedly enhanced. The sintered body and composite wherein the apatite is hydroxyapatite are useful for bioceramic uses. The sintered apatite body or composite is produced by baking an apatite material alone or in contact with a reinforcing mineral fiber material in the presence of water under pressure at a temperature lower than 1000.degree. C., and further at a temperature lower than the temperature causing deterioration of the fiber material in the case of the composite.
    Type: Grant
    Filed: April 28, 1983
    Date of Patent: March 5, 1985
    Assignee: Ina Seito Co., Ltd.
    Inventor: Seiichi Hatahira
  • Patent number: 4500644
    Abstract: Dense sialon grain is produced by briquetting mixtures of micronized silicon and reactive alumina. Sialon powder is produced by ball milling the briquettes after nitriding. The starting mixtures can contain from 10 to 38% reactive alumina with the balance of the mixture micronized silicon. Mixtures made within this range when pressed into dense briquettes and nitrided produce useful sialon grain having minimal free alumina contamination.
    Type: Grant
    Filed: December 19, 1983
    Date of Patent: February 19, 1985
    Assignee: Dresser Industries, Inc.
    Inventors: Howard M. Winkelbauer, Kenneth W. Hill, Ke-Chin Wang
  • Patent number: 4495300
    Abstract: A low thermal expansion cordierite ceramic is produced by combining cordierite with a zirconium compound and a phosphorus compound and sintering the resultant mixture thereby giving rise to zircon therein.
    Type: Grant
    Filed: May 14, 1984
    Date of Patent: January 22, 1985
    Assignee: Agency of Industrial Science and Technology, Ministry of International Trade and Industry
    Inventor: Shiro Sano
  • Patent number: 4486257
    Abstract: A composition of at least one member selected from the group consisting of sodium fluoride and calcium fluoride and optionally containing kaolin is powerful adhesive for ceramic articles which is used by interposing the adhesive intimately between the opposed surfaces for union of the ceramic articles and heating the adhesive to a temperature equal to or higher than the decomposition temperature of the fluoride used.
    Type: Grant
    Filed: September 7, 1982
    Date of Patent: December 4, 1984
    Assignee: Agency of Industrial Science & Technology Ministry of International Trade & Technology
    Inventors: Yoshihiro Ebata, Saburo Kose, Makoto Kinoshita, Tsutomu Ueno
  • Patent number: 4485182
    Abstract: A powder composition for producing sintered ceramic, which composition contains fluororesin powder which has not been used in the prior art as one of the materials constituting a molding assistant to be blended in the composition. With this composition, it is possible to produce a high-density green molding with few molding defects under a relatively low molding pressure. The invention also provides a process for producing such a composition.
    Type: Grant
    Filed: July 25, 1983
    Date of Patent: November 27, 1984
    Assignee: Ibiden Kabushiki Kaisha
    Inventors: Ryo Enomoto, Kiyotaka Tsukada
  • Patent number: 4484972
    Abstract: Adhesion of two silicon nitride parts is accomplished by interposing a layer of calcium fluoride or a mixture of calcium fluoride with kaoline between the two silicon nitride parts and heating the resultant interposed layer.
    Type: Grant
    Filed: August 12, 1982
    Date of Patent: November 27, 1984
    Assignee: Agency of Industrial Science & Technology Ministry of International Trade & Industry
    Inventors: Yoshihiro Ebata, Nobuyuki Tamari, Makoto Kinoshita, Yasuo Toibana
  • Patent number: 4483935
    Abstract: An electrolyte, containing alkali halide, is physically transformed by means of activation-triggering energy falling within a continuum of parameters defining threshold and maximum limits. The activation-triggering energy comprises various ionizing and subionizing forms. The resultant energy state exists in the frozen or molten condition and, in the latter, it is maintained for economically long periods either by a simultaneously induced chain reaction which is nearly powered by the heat of the material or by continuous exposure to radiation. Refurbishing impulses continue the effect.
    Type: Grant
    Filed: September 10, 1981
    Date of Patent: November 20, 1984
    Inventor: Isaac M. Diller
  • Patent number: 4475144
    Abstract: The present invention provides a dielectric ceramic composition having excellent electric properties and able to be sintered at a temperature between 750.degree. and 1000.degree. C.According to the invention, said composition comprises from 90 to 98% by weight of barium titanate, from 0.5 to 2.5% by weight of lithium oxide and 1.5 to 8% by weight of zinc fluoride.
    Type: Grant
    Filed: January 27, 1983
    Date of Patent: October 2, 1984
    Assignee: LCC.CICE-Compagnie Europeenne de Composants Electroniques
    Inventors: Alain Lagrange, Alain Beauger
  • Patent number: 4471060
    Abstract: The method concerns forming a relatively stable slip of silicon metal particles and yttrium containing particles. In one embodiment, a casting slip of silicon metal particles is formed in water. Particles of a yttrium containing sintering aid are added to the casting slip. The yttrium containing sintering aid is a compound which has at least some solubility in water to form Y.sup.+3 ions which have a high potential for totally flocculating the silicon metal particles into a semiporous solid. A small amount of a fluoride salt is added to the casting slip which contains the yttrium containing sintering aid. The fluoride salt is one which will produce fluoride anions when dissolved in water. The small amount of the fluoride anions produced are effective to suppress the flocculation of the silicon metal particles by the Y.sup.
    Type: Grant
    Filed: July 8, 1983
    Date of Patent: September 11, 1984
    Assignee: Ford Motor Company
    Inventors: Ray A. Dickie, John A. Mangels
  • Patent number: 4457496
    Abstract: The invention concerns a filtration block for liquid alloys and metals, with a mechanical and physical-chemical effect.Agglomerating, for example by sintering, elements of an active mineral compound based on fluorides, results in a porous structure with a high degree of permeability, which acts both by a mechanical filtration effect and by a washing action in respect of the metal under the action of the active mineral compound which acts as a flux and provides for trapping inclusions.Use for the final purification of aluminium, aluminium-base alloys, magnesium and magnesium-base alloys.
    Type: Grant
    Filed: April 9, 1982
    Date of Patent: July 3, 1984
    Assignee: Servimetal
    Inventors: Pierre du Manoir de Juaye, Pierre Guerit, Gilbert Pollet, Marc Vassiliadis
  • Patent number: 4455382
    Abstract: This invention is directed to the preparation of neutralized polyelectrolyte complexes exhibiting hydrophobic behavior containing crystals of an organic polycation exchanged lithium and/or sodium water-swelling mica. The process for making such products comprises:(1) forming a glass-ceramic body containing crystals selected from the group of fluorhectorite, hydroxyl hectorite, boron fluorphlogopite, hydroxyl boron phlogopite, and solid solutions among those and between those and other structurally-compatible species selected from the group of talc, fluortalc, polylithionite, fluorpolylithionite, phlogopite, and fluorphlogopite;(2) contacting that body with a polar liquid to cause swelling and disintegration of the body accompanied with the formation of a gel; and(3) contacting said gel with a source of organic polycations to cause a reaction between the Li.sup.+ and/or Na.sup.
    Type: Grant
    Filed: January 27, 1983
    Date of Patent: June 19, 1984
    Assignee: Corning Glass Works
    Inventor: Shy-Hsien Wu
  • Patent number: 4453981
    Abstract: There is disclosed a method of producing a slurry composed of ion-exchanged, synthetic mica crystals dispersed in a polar liquid. The method comprises providing a synthetic, lithium and/or sodium, water-swelling body of selected crystal type, and dispersing the mica body in the polar liquid while simultaneously effecting an exchange of larger cations from a contacting source with lithium and/or sodium ions from the mica crystals. The synthetic mica body may be vigorously mixed in a dilute solution of the exchangeable ion source. Alternatively, the mica body may be disintegrated in a mixer, the exchangeable ion source added to form a paste and more liquid added to dilute the paste.
    Type: Grant
    Filed: March 2, 1983
    Date of Patent: June 12, 1984
    Assignee: Corning Glass Works
    Inventor: Mark P. Taylor
  • Patent number: 4454237
    Abstract: This invention is directed to the preparation of an organic-inorganic composite body demonstrating hydrophobic behavior containing crystals of an organic polycation-exchanged lithium and/or sodium water-swelling mica, the organic polycation being selected from the group of aminosilanes and organic chrome complexes.
    Type: Grant
    Filed: January 27, 1983
    Date of Patent: June 12, 1984
    Assignee: Corning Glass Works
    Inventors: Syed N. Hoda, Anthony R. Olszewski
  • Patent number: 4447283
    Abstract: An adhesive having as its active component at least one fluoride selected from the group consisting of alkali metal fluorides except for sodium fluoride and alkaline earth metal fluorides except for calcium fluoride or a combination of the aforementioned at least one fluoride with kaolin and an adhesive having as its active component a combination of at least one member selected from the group consisting of yttria and alkaline earth metal compounds except for fluorides, an alkali metal fluoride, and at least one member selected from the group consisting of kaolin and alkaline earth metal fluorides both provide fast adhesion easily between two ceramic articles by a method which comprises the steps of interposing the adhesive between the ceramic articles and heating the ceramic articles with the adhesive therebetween to a temperature equal to or higher than the decomposition temperature of the fluoride in the adhesive.
    Type: Grant
    Filed: September 16, 1982
    Date of Patent: May 8, 1984
    Assignees: Agency of Industrial Science and Technology, Ministry of International Trade and Industry
    Inventors: Yoshihiro Ebata, Saburo Kose, Ryozo Hayami
  • Patent number: 4400760
    Abstract: A dielectric ceramic composition which has excellent electrical properties and can be sintered at a temperature within the range of 750.degree. C. to 1000.degree. C. contains 85 to 97% by weight of barium titanate, 0.5 to 2.5% by weight of lithium oxide and 2.5 to 12% by weight of cadmium fluoride.
    Type: Grant
    Filed: May 25, 1982
    Date of Patent: August 23, 1983
    Assignee: LCC.CICE - Compagnie Europeenne de Composants Electroniques
    Inventors: Alain Lagrange, Alain Beauger
  • Patent number: 4400759
    Abstract: A dielectric ceramic composition which has excellent electrical properties and can be sintered at a temperature within the range of 750.degree. C. to 1000.degree. C. contains 90 to 98% by weight of barium titanate, 0.5 to 2.5% by weight of lithium oxide and 1.5 to 8% by weight of cupric fluoride.
    Type: Grant
    Filed: May 25, 1982
    Date of Patent: August 23, 1983
    Assignee: LCC-CICE-Compagnie Europeenne de Composants Electroniques
    Inventors: Alain Lagrange, Alain Beauger
  • Patent number: 4376168
    Abstract: A strong and biocompatible sintered phosphate of calcium ceramics are obtained by sintering a powdery material substantially consisting of phosphate of calcium having a Ca/P ratio of 1.4-1.75, e.g. apatite group and/or tricalcium phosphate, and not exceeding 15% by weight of CaO-P.sub.2 O.sub.5 frit having a Ca/P ratio of 0.2-0.75. Y.sub.2 O.sub.3 incorporation therein improves the bending strength of the ceramics. Furthermore, a P.sub.2 O.sub.5 -metal oxide frit wherein metal oxide being one or more selected from BaO, CaO, MgO, ZnO, NaO and K.sub.2 O provides a more improved bending strength. The Y.sub.2 O.sub.3 incorporation herein still improves the strength of the sintered product.
    Type: Grant
    Filed: April 21, 1981
    Date of Patent: March 8, 1983
    Assignee: NGK Spark Plugs Co., Ltd.
    Inventors: Akio Takami, Kazuo Kondo
  • Patent number: 4309467
    Abstract: The present invention relates to a composition particularly suitable for as structural components subject to high-temperature environments containing gaseous hydrogen and fluorine. The composition of the present invention consists essentially of lanthanum hexaboride-molybdenum diboride with dispersed silicon. The composition is formed by hot pressing a powder mixture of lanthanum hexaboride as the major constituent and molybdenum disilicide. This composition exhibits substantial resistance to thermal shock and corrosion in environments containing hydrogen and fluorine gases at material surface temperatures up to about 1850.degree. K. Upon exposure of the hot-pressed composition to high-temperature environments containing fluorine gases, a highly protective layer of lanthanum trifluoride containing dispersed molybdenum is formed on exposed surfaces of the composition.
    Type: Grant
    Filed: August 22, 1980
    Date of Patent: January 5, 1982
    Assignee: The United States of America as represented by Department of Energy
    Inventors: Louis Kovach, Cressie E. Holcombe
  • Patent number: 4308064
    Abstract: A strong and biocompatible sintered phosphate of calcium ceramics are obtained by sintering a powdery material substantially consisting of phosphate of calcium having a Ca/P ratio of 1.4-1.75, e.g. apatite group and/or tricalcium phosphate, and not exceeding 15% by weight of CaO-P.sub.2 O.sub.5 frit having a Ca/P ratio of 0.2-0.75. Y.sub.2 O.sub.3 incorporation therein improves the bending strength of the ceramics. Furthermore, a P.sub.2 O.sub.5 -metal oxide frit wherein metal oxide being one or more selected from BaO, CaO, MgO, ZnO, NaO and K.sub.2 O provides a more improved bending strength. The Y.sub.2 O.sub.3 incorporation herein still improves the strength of the sintered product.
    Type: Grant
    Filed: July 23, 1980
    Date of Patent: December 29, 1981
    Assignee: NGK Spark Plugs Co., Ltd.
    Inventors: Akio Takami, Kazuo Kondo
  • Patent number: 4297139
    Abstract: The present invention is related to the production of crystal-containing gels and papers, films, fibers, boards, and coatings made therefrom. The process for making the gels comprises three general steps: first, a fully or predominantly crystalline body is formed containing crystals consisting essentially of a lithium and/or sodium water-swelling mica selected from the group of fluorhectorite, hydroxyl hectorite, boron fluorphlogopite, hydroxyl boron phlogopite, and solid solutions among those and between those and other structurally-compatible species selected from the group of talc, fluortalc, polylithionite, fluorpolylithionite, phlogopite, and fluorphlogopite; second, that body is contacted with a polar liquid, desirably water, to cause swelling and disintegration of the body accompanied with the formation of a gel; and, third, the solid:liquid ratio of the gel is adjusted to a desired value depending upon the application therefor.
    Type: Grant
    Filed: June 25, 1980
    Date of Patent: October 27, 1981
    Assignee: Corning Glass Works
    Inventors: George H. Beall, David G. Grossman, Syed N. Hoda, Karen R. Kubinski