Glass And Material Other Than Glass (e.g., Crystal Glass, Opal Glass, Etc.) Patents (Class 501/32)
  • Patent number: 7189670
    Abstract: A dielectric ceramic obtained by firing a raw material comprising an alumina powder, a crystallizable glass powder mainly containing SiO2, CaO and MgO, and a noncrystallizable glass powder mainly containing SiO2, B2O3 and Na2O. After the firing, the dielectric ceramic contains an alumina crystal phase, a diopside crystal phase (Ca(Mg, Al)(Si, Al)2O6) and a magnesia-spinel crystal phase (MgAl2O4) and has a porosity of not higher than 2.2% when measured by a mercury penetration method.
    Type: Grant
    Filed: June 28, 2005
    Date of Patent: March 13, 2007
    Assignee: Sanyo Electric Co., Ltd.
    Inventors: Koh Masahara, Hiroshi Nonoue
  • Patent number: 7189669
    Abstract: A dielectric ceramic material which is obtained by firing a raw material comprising an alumina powder and a glass powder containing at least SiO2 and MgO, the dielectric ceramic material being characterized in that a ratio (MgAl2O4 (311)/Al2O3 (116)) in X-ray diffraction peak intensity of an MgAl2O4 (311) to an Al2O3 (116) is at least 0.5.
    Type: Grant
    Filed: February 15, 2005
    Date of Patent: March 13, 2007
    Assignee: Sanyo Electric Co., Ltd.
    Inventors: Koh Masahara, Hiroshi Nonoue, Kenichiro Wakisaka
  • Patent number: 7189470
    Abstract: A solid oxide fuel cell device incorporates a sealing material resistant to hydrogen gas permeation at a sealing temperature in the intermediate temperature range of 600° C.–800° C., the seal having a CTE in the 100×10?7/° C. to 120×10?7/° C., wherein the sealing material comprises in weight %, of: (i) a 80 to 95 wt % of glass frit, the glass frit itself having a composition in mole percent of: SiO2 70–85%; Al2O3 0–5%; Na2O3 0–8%; K2O 10–25%; ZnO 0–10%; ZrO2 0–6%; MgO 0–7%; TiO2 0–2%; and (ii) and 5 wt % to 25 wt % of addition comprising at least one of: alumina, zirconia or leucite.
    Type: Grant
    Filed: January 18, 2005
    Date of Patent: March 13, 2007
    Assignee: Corning Incorporated
    Inventors: Jeffrey E Cortright, Lisa A Lamberson, Pamela A Maurey, Robert M Morena
  • Patent number: 7179526
    Abstract: Plasma spraying, apparatus for plasma spraying, and methods of plasma spraying.
    Type: Grant
    Filed: August 2, 2002
    Date of Patent: February 20, 2007
    Assignee: 3M Innovative Properties Company
    Inventors: Anatoly Z. Rosenflanz, Ahmet Celikkaya, Thomas J. Anderson
  • Patent number: 7172649
    Abstract: The disclosure relates to a leucite glass ceramic doped with nanoscale metal oxide, to a doped leucite glass ceramic powder suitable for its production, to a method for producing the doped leucite glass ceramic, to its use as dental material, to a dental product containing it and to the use of the nanoscale metal oxide powders for the production of the doped glass ceramic or of the doped leucite glass ceramic powder.
    Type: Grant
    Filed: December 30, 2003
    Date of Patent: February 6, 2007
    Assignees: Chemichl AG
    Inventors: Thomas Conrad, Gerhard Meyer
  • Patent number: 7161117
    Abstract: A window glass for vehicles equipped with a conductor, which comprises a glass plate, a patterned conductor layer formed on the glass plate, and a covering layer formed to cover the conductor layer, wherein the covering layer comprises a fired product obtained by firing a composition containing a crystalline glass powder and a reducing agent capable of reducing silver ions.
    Type: Grant
    Filed: December 8, 2004
    Date of Patent: January 9, 2007
    Assignee: Asahi Glass Company, Limited
    Inventors: Toshio Minowa, Hiroyuki Hayakawa, Shuji Taguchi
  • Patent number: 7160823
    Abstract: Low dielectric constant dielectric ceramics for a borosilicate-based low temperature fired multi-layer substrate is disclosed which can be fired at a wide temperature range of above and below 900° C. and exhibits a low loss electrical property. By controlling the types and addition amount of the alkaline earth metal oxide, the linear shrinkage behavior can be considerably controlled while maintaining the electrical property unchanged. The composition facilitates matching a linear shrinkage with a heterogeneous material having certain shrinkage characteristics.
    Type: Grant
    Filed: August 7, 2003
    Date of Patent: January 9, 2007
    Assignee: Korea Institute of Science and Technology
    Inventors: Jae-Hwan Park, Jae-Gwan Park, Dong-Soon Shin, Young-Jin Choi
  • Patent number: 7144833
    Abstract: A dielectric ceramic composition containing crystalline glass, amorphous glass and a ceramic filler, characterized in that a softening point of said crystalline glass is higher than a softening point of said amorphous glass and is 900° C. or lower, and 27% by weight or higher of the crystalline glass and less than 20% by weight of the amorphous glass are contained in the ceramic composition and the total content of the crystalline glass and the amorphous glass is 60% by weight or lower, and 40% by weight or higher of the ceramic filler is contained in the ceramic composition.
    Type: Grant
    Filed: September 29, 2004
    Date of Patent: December 5, 2006
    Assignee: Sanyo Electric Co., Ltd.
    Inventors: Takashi Umemoto, Hiroshi Nonoue, Toshio Tanuma, Kenichiro Wakisaka
  • Patent number: 7144618
    Abstract: A multilayer composite includes an insulating substrate and patterned conductive layers and insulating layers alternately laminated on the insulating substrate. In a laminating process, a correcting insulating layer is formed on a laminate when a predetermined number of layers are laminated or when a predetermined degree of warpage of the laminate is detected by monitoring. The correcting insulating layer has a different composition from that of the other insulating layers to correct the warpage of the laminate.
    Type: Grant
    Filed: October 9, 2003
    Date of Patent: December 5, 2006
    Assignee: Murata Manufacturing Co., Ltd.
    Inventors: Yoshiyuki Tonami, Yuji Sugiyama, Michiaki Iha
  • Patent number: 7141521
    Abstract: This invention relates to a flat float glass that can be prestressed or transformed into a glass ceramic with high quartz mixed crystals or keatite mixed crystals. To eliminate undesirable surface defects during floating and to achieve superior characteristics of the glass or of the glass ceramic, in particular with regard to a low coefficient of thermal expansion and high light transmittance, the glass has a concentration of less than 300 ppb Pt, less than 30 ppb Rh, less than 1.5 wt. % ZnO and less than 1 wt. % SnO2, and is refined during melting without the use of the conventional fining agents arsenic oxide and/or antimony oxide.
    Type: Grant
    Filed: December 27, 2004
    Date of Patent: November 28, 2006
    Assignee: Schott Glas
    Inventors: Friedrich Siebers, Peter Nass, Gerhard Lautenschläger, Otmar Becker
  • Patent number: 7138347
    Abstract: A thick-film composition comprising: (a) conductive metal; (b) crystallized glass; (c) amorphous glass; and (d) organic medium.
    Type: Grant
    Filed: August 14, 2003
    Date of Patent: November 21, 2006
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Takuya Konno
  • Patent number: 7094361
    Abstract: Optically transparent composite materials in which solid solution inorganic nanoparticles are dispersed in a host matrix inert thereto, wherein the nanoparticles are doped with one or more active ions at a level up to about 60 mole % and consist of particles having a dispersed particle size between about 1 and about 100 nm, and the composite material with the nanoparticles dispersed therein is optically transparent to wavelengths at which excitation, fluorescence or luminescence of the active ions occur. Luminescent devices incorporating the composite materials are also disclosed.
    Type: Grant
    Filed: March 2, 2004
    Date of Patent: August 22, 2006
    Assignee: Rutgers, The State University
    Inventors: Richard E. Riman, John Ballato
  • Patent number: 7091142
    Abstract: The invention encompasses a glass-ceramic comprising a continuous glass phase and a crystal phase comprising tetragonal leucite, wherein the glass-ceramic has a crack-free glass phase and a crystal phase comprising leucite crystals distributed essentially homogeneously in the glass phase. The crystal phase has a particle size distribution made of from about 5% to about 70% of a first group of leucite crystals having particle sizes of <1 ?m and from about 30% to about 95% of a second group of leucite crystals having particle sizes of ?1 ?m. The proportion of Li2O in the glass-ceramic is preferably below 0.5% by weight. It is preferred that not only the glass phase but also the crystal phase is essentially free of cracks. The corresponding glass-ceramics are particularly suitable for use in the dental sector, in particular as facing ceramics.
    Type: Grant
    Filed: December 3, 2003
    Date of Patent: August 15, 2006
    Assignee: Wieland Dental Ceramics GmbH
    Inventors: Steffen Assmann, Peter Appel, Reinhard Armbrust
  • Patent number: 7087293
    Abstract: The present invention relates to a Cd-free and Pb-free glass composition comprising, based in mol %, 1–10% MO where M is selected from Ba, Sr, Ca and mixtures thereof, 5–30% MgO, 0.3–5% CuO, 0–2.5% P2O5, 0–2.5% ZrO2, 24–45% ZnO, 2–10% Al2O3, 35–50% SiO2 and 0.1–3% A2O where A is selected from the group of alkali elements and mixtures thereof wherein the glass composition is useful in thick paste dielectric materials which are compatible with AlN substrates.
    Type: Grant
    Filed: December 1, 2005
    Date of Patent: August 8, 2006
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Yong Cho, Kenneth Warren Hang
  • Patent number: 7071135
    Abstract: A ceramic body comprising a crystal phase of aluminum titanate in an amount of 50 to 95% by weight, and a glass phase in an amount of 5 to 50% by weight. The inventive ceramic body may include a second crystal phase, for example mullite in an amount of up to 40% by weight. The glass is an aluminosilicate including, in weight percent on an oxide basis, of 50–90 SiO2, 1–25 Al2O3, 0.5–10 TiO2, 0.5–20 R2O, where R is selected from the group consisting of Li, Na, K, Ru, Cs, Fr, and 0.5–20 R?O, where R? is selected from the group consisting of Be, Mg, Ca, Ba, Ra, and wherein the ceramic body includes not more than 2% by weight Fe2O3.
    Type: Grant
    Filed: September 29, 2004
    Date of Patent: July 4, 2006
    Assignee: Corning Incorporated
    Inventors: Steven B. Ogunwumi, Patrick D. Tepesch
  • Patent number: 7053016
    Abstract: A ceramic porous body is provided which uses a binder made of a glass that has excellent acid resistance and alkali resistance and which can be used for a long period of time as a filtration filter. The ceramic porous body is formed from ceramic particles that are bonded using a glass binder comprising 5 to 20 mol % of a plurality of metal oxides, selected from the group consisting of Li2O, Na2O, K2O, MgO, CaO, SrO and BaO and containing at least two alkali metal oxides selected from the group consisting of Li2O, Na2O and K2O as an essential component, at least 3 mol % of at least one of ZrO2 and TiO2 as a total amount, and SiO2 and incidental impurities as the balance.
    Type: Grant
    Filed: December 3, 2002
    Date of Patent: May 30, 2006
    Assignee: NGK Insulators, Ltd.
    Inventors: Takahiro Mizuno, Manabu Isomura, Tomonori Takahashi
  • Patent number: 7034637
    Abstract: An electronic component including a magnetic member comprising an iron oxide magnetic composition, a nonmagnetic member in contact with the magnetic member and including a glass ceramic composite composition, and an internal conductor portion disposed in at least one of the magnetic member and the nonmagnetic member. The glass ceramic composite composition includes crystallized glass as a main component, and quartz as a sub-component filler. The crystallized glass contains 25 percent by weight to 55 percent by weight of SiO2, 30 percent by weight to 55 percent by weight of MgO, 5 percent by weight to 30 percent by weight of Al2O3, and 0 percent by weight to 30 percent by weight of B2O3, and the content of the quartz is 5 percent by weight to 30 percent by weight relative to 100 percent by weight of the crystallized glass.
    Type: Grant
    Filed: April 21, 2004
    Date of Patent: April 25, 2006
    Assignee: Murata Manufacturing Co., Ltd.
    Inventors: Daiji Kono, Hiroaki Kikuta
  • Patent number: 7030048
    Abstract: present invention relates to a Cd-free and Pb-free glass composition comprising, based in mol %, 1–10% MO where M is selected from Ba, Sr, Ca and mixtures thereof, 5–30% MgO, 0.3–5% CuO, 0–2.5% P2O5, 0–2.5% ZrO2, 24–45% ZnO, 2–10% Al2O3, 35–50% SiO2 and 0.1–3% A2O where A is selected from the group of alkali elements and mixtures thereof wherein the glass composition is useful in thick paste dielectric materials which are compatible with AlN substrates.
    Type: Grant
    Filed: August 5, 2003
    Date of Patent: April 18, 2006
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Yong Cho, Kenneth Warren Hang
  • Patent number: 6953756
    Abstract: A glass ceramic sintered body containing gahnite and cordierite as crystal phases, having a thermal expansion coefficient at 40 to 400° C. of not larger than 5×10?6/° C., a dielectric constant of not larger than 7 and a Young's modulus of not larger than 150 GPa. A wiring board having an insulating substrate made of the glass ceramic sintered body features very high reliability in the primary mounting and in the secondary mounting.
    Type: Grant
    Filed: October 22, 2003
    Date of Patent: October 11, 2005
    Assignee: Kyocera Corporation
    Inventors: Shinya Kawai, Toshifumi Higashi
  • Patent number: 6946415
    Abstract: An insulating ceramic composition includes a mixture of a ceramic powder containing MgAl2O4 and a glass powder containing 30-60% by mole of silicon oxide on the basis of SiO2 and 20-55% by mole of magnesium oxide on the basis of MgO, and the ceramic powder further includes Mg2SiO4 and TiO2. The insulating ceramic composition can be fired at 1000° C. and co-sintered with Ag and Cu. An insulating ceramic obtained by sintering the insulating ceramic composition has a high Q-factor and is therefore suitable for ceramic multilayer substrates used at high frequencies.
    Type: Grant
    Filed: March 26, 2002
    Date of Patent: September 20, 2005
    Assignee: Murata Manufacturing Co., Ltd.
    Inventors: Osamu Chikagawa, Sadaaki Sakamoto, Yoichi Moriya
  • Patent number: 6939819
    Abstract: A glass ceramic composition which consists essentially of an inorganic material powder having a melting point or a glass transition point of at least 1,000° C. and a glass powder having a glass transition point of from 450 to 800° C., wherein the average of the major axes L of particles of the above inorganic material powder is from 0.5 to 15 ?m, and the average of the ratios L/W of the major axes L to the minor axes W is at most 1.4. Further, a glass ceramic composition which consists essentially of, as represented by mass percentage, from 10 to 58% of an inorganic material powder having a melting point or a glass transition point of at least 1,000° C. and from 42 to 90% of a glass powder having a glass transition point of from 450 to 800° C., wherein the glass powder consists essentially of, as represented by mol %, SiO2: 35 to 70%, B2O3: 0 to 30%, Al2O3: 3 to 18%, MgO: 0 to 40%, CaO: 0 to 19%, BaO: 0 to 35% and ZnO: 0 to 9%.
    Type: Grant
    Filed: June 18, 2003
    Date of Patent: September 6, 2005
    Assignee: Asahi Glass Company, Limited
    Inventors: Hiroshi Usui, Hitoshi Onoda, Kazunari Watanabe, Yumi Okuyama, Yasuko Osaki, Katsuyoshi Nakayama
  • Patent number: 6935594
    Abstract: Methods and compositions for fabricating composite parts including at least one structural material and at least one protective material that are integrally bonded without the use of secondary bonding operations. One or more of the materials forming the layers of the composite parts may be a ceramic composition with or without porosity and one or more of the materials may be a polymer composition. Methods including co-injection processes also are provided for fabricating multi-layered structures in which each layer serves a desired function while still being integrated into the overall structure.
    Type: Grant
    Filed: November 12, 2002
    Date of Patent: August 30, 2005
    Assignee: Advanced Ceramics Research, Inc.
    Inventors: K. Ranji Vaidyanathan, Catherine Green, John W. Gillespie, Shridhar Yarlagadda, Gregory J. Artz
  • Patent number: 6924245
    Abstract: A glass ceramic composition which can be fired at a low temperature and which has a high dielectric constant, a relatively small thermal expansion coefficient and a small temperature coefficient of dielectric constant is provided. The glass ceramic composition contains about 5% to 75% by weight of TiO2 powder, about 5% to 75% by weight of CaTiSiO5 powder and about 15% to 50% by weight of glass powder.
    Type: Grant
    Filed: May 21, 2003
    Date of Patent: August 2, 2005
    Assignee: Murata Manufacturing Co., Ltd.
    Inventor: Sadaaki Sakamoto
  • Patent number: 6921730
    Abstract: A phosphor layer is composed of tri-band phosphor particles bound together by a binder. A material as the main component of the binder is a mixture of (1) a compound formed by calcium oxide, barium oxide, and boron oxide, and (2) calcium pyrophosphate. Dissolved in the main component material of the binder is a luminescent component that converts ultraviolet radiation of 254 nm to ultraviolet radiation of longer wavelengths or to visible light. Examples of such a luminescent component include an oxide of gadolinium (Gd), terbium (Tb), europium (Eu), neodymium (Nd), or dysprosium (Dy), each of which belongs to lanthanum series, and an oxide of thallium (Tl), tin (Sn), lead (Pb), or bismuth (Bi).
    Type: Grant
    Filed: March 13, 2003
    Date of Patent: July 26, 2005
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Tomoko Atagi, Masanobu Ito
  • Patent number: 6914023
    Abstract: The object of the present invention is to provide a flat-panel-display substrate which is high in heat resistance, of which the coefficient of thermal expansion is approximated to that of a thick film dielectric layer, which is low at high temperatures in reactivity with the lead-doped thick film dielectric layer, and which can be made to have a large area. The substrate of the present invention is obtained by sintering a body comprising glass powder and a filler made of metal and/or semi-metal oxide, and is constituted by the sintered body and whose average coefficient of linear thermal expansion is from 7 to 9.5 ppm/° C. in the temperature range of 25 to 700° C. The glass powder includes alkaline-earth oxide, 15 to 50% by weight of silicon oxide, and no greater than 2% by weight of boron oxide. Furthermore, the filler is at a concentration of 10 to 30% by volume of the total amount of the glass powder and the filler in the mould.
    Type: Grant
    Filed: July 16, 2003
    Date of Patent: July 5, 2005
    Assignee: TDK Corporation
    Inventors: Takaji Shimosaka, Yukihiko Shirakawa, Shirou Ootsuki
  • Patent number: 6905989
    Abstract: Tunable dielectric materials including an electronically tunable dielectric ceramic and a low loss glass additive are disclosed. The tunable dielectric may comprise a ferroelectric perskovite material such as barium strontium titanate. The glass additive may comprise boron, barium, calcium, lithium, manganese, silicon, zinc and/or aluminum-containing glasses having dielectric losses of less than 0.003 at 2 GHz. The materials may further include other additives such as non-tunable metal oxides and silicates. The low loss glass additive enables the materials to be sintered at relatively low temperatures while providing improved properties such as low microwave losses and high breakdown strengths.
    Type: Grant
    Filed: May 31, 2002
    Date of Patent: June 14, 2005
    Assignee: Paratek Microwave, Inc.
    Inventors: Marion E. Ellis, Steven Wesley Winn, Luna H. Chiu
  • Patent number: 6905990
    Abstract: The present invention provides a ceramic color composition which comprises, as a solid powder, 50 to 90 wt. % of a mixture containing 5 to 95 parts by weight of a first lead-free glass powder comprising at least SiO2, ZnO, and B2O3 as glass components, and 5 to 95 parts by weight of a second lead-free glass powder comprising at least SiO2, Bi2O3, and B2O3 as glass components, 10 to 40 wt. % of an inorganic pigment, and 0 to 10 wt. % of an inorganic filler. The composition is free of lead and exhibits an excellent mold release property during the heat-molding process of a glass plate having the composition printed thereon. After firing, the composition is excellent in acid resistance, coloration in the bus bar portion, and plating resistance.
    Type: Grant
    Filed: December 14, 2000
    Date of Patent: June 14, 2005
    Assignee: Okuno Chemical Industries Co., Ltd.
    Inventors: Shigehiro Sanichi, Yoshito Nokami
  • Patent number: 6903035
    Abstract: An inorganic composition comprises an inorganic matrix, wherein an inorganic layered compound is contained in the inorganic matrix. The inorganic matrix is preferably a metal oxide glass produced by a sol-gel method, and the inorganic layered compound is preferably swelling synthetic mica. A method of producing a film includes the steps of: hydrolyzing, dehydrating, and condensing an organic metal compound to obtain a reaction product; adding and dispersing the inorganic layered compound in the reaction product; coating the reaction product containing the inorganic layered compound on a substrate surface; and heating the substrate surface coated with the reaction product at a temperature of not more than 200° C. to vitrify the reaction product.
    Type: Grant
    Filed: July 30, 2002
    Date of Patent: June 7, 2005
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toshiaki Aono, Keisuke Ozeki
  • Patent number: 6899827
    Abstract: Sintered, translucent ceramic microbeads, preferably alumina, titania, zirconia, yttria, zirconium phosphate, or yttrium aluminum garnet (YAG) are doped with one or more optically active species. The beads may be added to substances such as explosives in order to create a distinctive optical signature that identifies a manufacturer, lot number, etc. in the event of the need for forensic analysis. Because the beads have a generally spherical surface, the radius of curvature provides an additional distinguishing characteristic by which a particular sample may be identified. The beads could also be formulated into paints if needed to create distinctive optical signatures for camouflage, decoys, or other countermeasures and could also be applied as a dust to track the movement of personnel, vehicles, etc.
    Type: Grant
    Filed: May 16, 2003
    Date of Patent: May 31, 2005
    Assignee: UT-Battelle, LLC
    Inventors: Robert J. Lauf, Kimberly K. Anderson, Frederick C. Montgomery
  • Patent number: 6897172
    Abstract: The present invention provides a dielectric ceramic composition comprising: 30 to 90% by weight of a crystallized glass powder capable of depositing a diopside crystal, 1 to 40% by weight of a calcium titanate powder, a strontium titanate powder or a mixed powder thereof, and 0 to 60% by weight of at least one kind of a powder selected from the group consisting of Al2O3, TiO2, ZrO2, MgTiO3, BaTi4O9, La2Ti2O7, Nd2Ti2O7, Ca2Nb2O7, SrZrO3 and CaZrO3, and a dielectric ceramics obtained by firing the same.
    Type: Grant
    Filed: January 23, 2003
    Date of Patent: May 24, 2005
    Assignee: Kyocera Corporation
    Inventors: Tatsuji Furuse, Seiichiro Hirahara, Shuji Nakazawa, Yasushi Ode, Tomoyuki Kojima, Fumiaki Sekine, Hiroshi Makino, Manabu Yonekura
  • Patent number: 6887808
    Abstract: Polarized glass articles having a wavelength range that is broadened for high contrast-ratio applications. A method that imparts to a glass article a high contrast ratio of at least 40 dB for use as dichroic glass polarizers over a wavelength range of 880 nm to 1,690 nm while keeping a high transmission value. The method comprises the step of heating the glass article at a temperature ranging from 400 to 450° C. in a reducing atmosphere for a period of time ranging from 12 to 30 hours. Preferably, the reducing atmosphere is hydrogen at atmospheric pressure.
    Type: Grant
    Filed: October 3, 2003
    Date of Patent: May 3, 2005
    Assignee: Corning Incorporated
    Inventor: Kenjiro Hasui
  • Patent number: 6881691
    Abstract: A dielectric ceramic article precursor and a process for preparing a dielectric ceramic article are presented. The ceramic article precursor comprises a crystalline aluminosilicate zeolite or an amorphous aluminosilicate, a zinc oxide additive and a glass phase. The ceramic article precursor can optionally contain at least one forming aid selected from binders, plasticizers and surfactants. The process for preparing a dielectric ceramic article involves forming a mixture from the above components into a shaped article such as a tape and then calcining the shaped article at a temperature of about 700° C. to about 1000° C. for a time of about 0.5 to about 24 hours.
    Type: Grant
    Filed: February 24, 2004
    Date of Patent: April 19, 2005
    Assignee: UOP LLC
    Inventor: Robert L. Bedard
  • Patent number: 6878651
    Abstract: A glass composition consisting essentially by mol percent of about 55<SiO2<75; 5<BaO<30; and 2 <MgO<22 for use as a matrix of composite materials. A method of making a glass matrix-ceramic particulate composition useful for sealing electrochemical structures, such as solid oxide fuel cells is also disclosed. Method steps include the admixture of finely divided Mg2SiO4 particulates with the matrix glass, to reach an overall composition by mol percent of about 55<SiO2<65; 5<BaO<15; and 25<MgO<35.
    Type: Grant
    Filed: December 1, 2000
    Date of Patent: April 12, 2005
    Assignee: Ford Global Technologies, LLC
    Inventor: Gary Mark Crosbie
  • Patent number: 6875715
    Abstract: Glass powder for a dielectric material has a nature that, when fired, diopside (CaMgSi2O6) and at least one of titanite (CaTi(SiO4)O) and titania (TiO2) are precipitated. Preferably, the glass powder has a composition including SiO2, CaO, MgO, and TiO2 and the total content of these components is 80 mass % or more. Preferably, the glass powder comprises, by mass percent, 35-65% SiO2, 10-30% CaO, 10-20% MgO, and 12-30% TiO2.
    Type: Grant
    Filed: March 4, 2003
    Date of Patent: April 5, 2005
    Assignee: Nippon Electric Glass Co., Ltd.
    Inventors: Yoshikatsu Nishikawa, Yoshio Umayahara
  • Patent number: 6866929
    Abstract: Glass powders and methods for producing glass powders. The powders preferably have a small particle size, narrow size distribution and a spherical morphology. The method includes forming the particles by a spray pyrolysis technique. The invention also includes novel devices and products formed from the glass powders.
    Type: Grant
    Filed: December 21, 2001
    Date of Patent: March 15, 2005
    Assignee: Cabot Corporation
    Inventors: Toivo T. Kodas, Mark J. Hampden-Smith, James Caruso, Quint H. Powell, Audunn Ludviksson
  • Patent number: 6852655
    Abstract: The invention is to offer such a dielectric ceramic enabling to simultaneously sinter with the low resistant conductor of Ag based metals and Cu based metals, having the excellent mechanical strength and exhibiting the excellent dielectric characteristics in the GHz zone. Mixed powders of Si: 20 to 30 weight %, B: 5 to 30 weight %, Al: 20 to 30 weight %, Ca: 10 to 20 weight %, and Zn: 10 to 20 weight % are prepared, melted, and rapidly cooled to produce glass frits. The glass frits are granulated and mixed with gahnite filler and titania filler which are inorganic filler powders. Subsequently, a binder is thrown into the powders to produce a composition of dielectric ceramic, and then is formed, followed by sintering. The mixed powders may contain at least one kind of alkali metal of Li, K and Na.
    Type: Grant
    Filed: January 30, 2003
    Date of Patent: February 8, 2005
    Assignee: NGK Spark Plug Co., Ltd.
    Inventors: Eiji Kodera, Kazuyuki Fujii, Makoto Baba, Hidetoshi Mizutani, Manabu Sato
  • Patent number: 6846760
    Abstract: This invention relates to a flat float glass that can be prestressed or transformed into a glass ceramic with high quartz mixed crystals or keatite mixed crystals. To eliminate undesirable surface defects during floating and to achieve superior characteristics of the glass or of he glass ceramic, in particular with regard to a low coefficient of thermal expansion and high light transmittance, the glass has a concentration of less than 300 ppb Pt, less than 30 ppb Rh, less than 1.5 wt. % ZnO and less than 1 wt. % SnO2, and is refined during melting without the use of the conventional fining agents arsenic oxide and/or antimony oxide.
    Type: Grant
    Filed: April 9, 2001
    Date of Patent: January 25, 2005
    Assignee: Schott Glas
    Inventors: Friedrich Siebers, Peter Nass, Gerhard Lautenschläger, Otmar Becker
  • Patent number: 6844278
    Abstract: A dense lead-free glass ceramic that has low dielectric constant and low dielectric loss for producing high-frequency ceramic devices, such as inductors and low temperature co-fired ceramics (LTCC), is disclosed. The glass ceramic consists of 15-35% by weight of lead-free borosilicate glasses with low softening point, 15-35% by weight of lead-free borosilicate glasses with high softening point, 20-80% by weight of combination of amorphous and crystalline SiO2-filler (preferably 5-30% by weight of amorphous SiO2, 10-50% by weight of crystalline SiO2) and 0.1-10% by weight of at least one oxide of Al2O3, BaO, Sb2O3, V2O5, CoO, MgO, B2O3, Nb2O5, SrO and ZnO. The glass ceramic can be densified up to 99% of its theoretical density after firing and is co-firable with conductive metals between 800-900° C. The dense glass ceramic has dielectric constant of 4.2-4.6 and loss tangent (tan ?)<0.0025 at 20 MHz and good thermal/mechanical strength for application in high frequency electronic devices.
    Type: Grant
    Filed: September 18, 2002
    Date of Patent: January 18, 2005
    Assignee: AEM, Inc.
    Inventors: Liwu Wang, Xiang-Ming Li, Albert Tian, Daniel H. Chang, Zhong Zheng
  • Patent number: 6841493
    Abstract: The present invention is directed to a glass composition comprising, based on mole %, 15-35% MO where M is selected from BaO, CaO, MgO, PbO, SrO and mixtures thereof, 30-60% TiO2, 10-30% B2O3, 1-7% P2O5, 0-3% Li2O and 2-16% Ln2O3 where Ln is selected from the group of rare earth elements and mixtures thereof. The invention is further directed to the glass composition incorporated in a thick film composition or a castable dielectric composition comprising a dispersion of finely divided solids comprising, based on solids: (a) 30-100 wt. % the glass composition; (b) 0-50 wt. % ceramic filler; both dispersed in a solution of (c) an organic polymeric binder; and (d) a volatile organic solvent. The invention is still further directed to the castable dielectric composition used in a method of forming a high K green tape by casting a thin layer of the castable dispersion onto a flexible sheet and heating the cast layer to remove the volatile organic solvent.
    Type: Grant
    Filed: March 17, 2003
    Date of Patent: January 11, 2005
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Yong Cho, Kenneth Warren Hang
  • Patent number: 6835681
    Abstract: A dielectric ceramic composition containing a first component and a second component (25 to 80 wt %) is used. The first component is a complex oxide represented by Formula: xZrO2-yTiO2-zL(1+u)/3M(2−u)/3O2 (L is at least one element selected from the group consisting of Mg, Zn, Co, and Mn, and M is at least one element selected from the group consisting of Nb and Tb. x, y, z, and u are numerical values represented by x+y+z=1, 0.10≦x≦0.60, 0.20 ≦y≦0.60, 0.01≦z≦0.70, 0≦u≦1.90). The second component is a glass composition containing an oxide of at least one element selected from the group consisting of Si, B, Al, Ba, Ca, Sr, Zn, Ti, La, and Nd.
    Type: Grant
    Filed: December 19, 2001
    Date of Patent: December 28, 2004
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Kojiro Okuyama, Hiroshi Kagata, Junichi Kato, Hiroyuki Hase
  • Patent number: 6835682
    Abstract: The present invention relates to an alkali-containing magnesium borosilicate glass composition comprising, in mole %, 10-25% SiO2, 10-25% B2O3, 5-10% BaO, 40-65% MgO, 0.5-3% ZrO2, 0.3-3% P2O5, and 0.2-5% M2O where M is selected from the group of alkali elements and mixtures thereof. The invention is further directed to a castable dielectric composition comprising a dispersion of finely divided solids comprising, based on solids: (a) 50-90 wt. % the glass composition as described above; (b) 10-50 wt. % ceramic filler; both dispersed in a solution of (c) an organic polymeric binder; and (d) a volatile organic solvent. The invention is still further directed to the castable dielectric composition described above used in a method of forming a high TCE LTCC green tape by casting a thin layer of the castable dispersion onto a flexible substrate and heating the cast layer to remove the volatile organic.
    Type: Grant
    Filed: March 17, 2003
    Date of Patent: December 28, 2004
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Yong Cho, Kenneth Warren Hang
  • Patent number: 6835680
    Abstract: A ceramic color composition comprising, as represented by mass percentage, from 60 to 85% of a low melting point glass powder, from 15 to 40% of a heat-resistant pigment powder, from 0 to 15% of heat-resistant whiskers, and from 0 to 15% of a refractory powder, wherein Fe3O4: 1 to 35%, MnO2: 1 to 24%, Cr2O3+CuO≧1%, and Cr2O3/8.5+CuO/23+NiO/3.3+CoO/0.71+V2O/56+Se/0.45≦1%.
    Type: Grant
    Filed: March 8, 2004
    Date of Patent: December 28, 2004
    Assignee: Asahi Glass Company, Limited
    Inventors: Shuji Taguchi, Shiro Ootaki, Toru Kudo
  • Patent number: 6828263
    Abstract: Glass composition for use as sealing material in fuel cells, comprising a glass matrix with main components consisting of SiO2, Al2O3, and one or more compounds from group I metal oxides and/or group II metal oxides, and a filler material evenly dispersed in the matrix, wherein the filler material consists of particles of one or more refractive compounds from the group: MgO—MgAl2O4, stabilized zirconia, rare earth oxides, (Mg,Ca)SiO3, Mg2SiO4, MgSiO3, CaSiO3, CaZrO3, ThO2, TiO2, MIIAlSi2O8, where MII=Ca, Sr or Ba.
    Type: Grant
    Filed: July 10, 2002
    Date of Patent: December 7, 2004
    Assignee: Haldor Topsoe A/S
    Inventors: Jørgen Gutzon Larsen, Peter Halvor Larsen, Carsten Bagger
  • Publication number: 20040241455
    Abstract: Enclosed are crystallized glasses suitable for a substrate for an information recording medium such as a magnetic disc, optical disc, or optomagnetic disc, a substrate for information recording medium using such a crystallized glass substrate, and an information recording medium using such a substrate for information recording medium. The crystallized glasses are capable of providing a glass substrate having a high Young's modulus, as well as excellent mechanical strength, surface flatness, and heat resistance and having an excellent surface smoothness upon polishing. Glass substrate having an excellent surface smoothness using such a crystallized glass are also disclosed.
    Type: Application
    Filed: June 23, 2004
    Publication date: December 2, 2004
    Applicant: HOYA CORPORATION
    Inventors: Xuelu Zou, Kouji Azegami
  • Patent number: 6825140
    Abstract: A glass paste comprising an inorganic powder, wherein the powder has a refractive index of 2.0 or more, a reflective index at wavelengths of light of 400 nm, 550 nm and 700 nm in a light reflection spectrum of 80% or more, a primary particle size measured by scanning electron microscopy of from 0.1 &mgr;m to 10 &mgr;m, and a BET specific surface area of from 0.1 m2/g to 15 m2/g.
    Type: Grant
    Filed: April 11, 2001
    Date of Patent: November 30, 2004
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Kunio Saegusa, Shinichiro Tanaka
  • Patent number: 6825139
    Abstract: The invention relates to a crystalline composition, a poly-crystalline product and an article of manufacture comprising an amount of SiO2, Al2O3, CaO, Fe2O3, TiO2, K2O, P2O5, Cr2O3, ZnO, MgO, Na2O, Li2O, CeO2, ZrO2 and MnO2 and methods for preparation the same.
    Type: Grant
    Filed: January 8, 2002
    Date of Patent: November 30, 2004
    Assignee: GlassCerax Ltd.
    Inventors: Alexander Raichel, Svetlana Raichel
  • Publication number: 20040232839
    Abstract: A glass paste used as a starting material of a transparent dielectric of a plasma display panel (“PDP”), the glass paste enabling the baking time required in forming a dielectric layer of the PDP to be shortened without reducing the transmissivity of the dielectric layer. A decomposition accelerator for accelerating the decomposition of an organic component is included in the glass paste so as to contact with the organic component. As a result, the decomposition of the organic component is accelerated when the glass paste is baked. Moreover, since the organic component is substantially eliminated before the baking temperature reaches a temperature at which a glass powder in the glass paste begins to melt, gas from decomposing organic component is not generated when the glass powder melts, and consequently the trapping of gas bubbles within the dielectric layer is prevented.
    Type: Application
    Filed: June 24, 2004
    Publication date: November 25, 2004
    Inventors: Morio Fujitani, Hiroyuki Yonehara, Masaki Aoki, Hideki Asida, Junichi Hibino
  • Patent number: 6818574
    Abstract: A compact, low electric resistance and high heat-spreading electric circuit substrate, which is suitable for an electric circuit used at microwave of 1 GHz or more as used in the field of wireless communication such as portable telephones or optical communication, is provided. Also provided is a joined body of glass-ceramic with aluminum nitride sintered body, the glass-ceramic containing crystals having the strongest line in the range of 2&thgr;=27.6°-28.2° in powder X-ray diffraction using CuK&agr; line, e.g., anorthite crystals, and having a composition containing 0.5-30 mass % of Zn component in terms of oxide, not more than 10 mass % in total of Ti component and Zr component in terms of corresponding oxides and not more than 5 mass % of Pb component in terms of oxide.
    Type: Grant
    Filed: June 14, 2002
    Date of Patent: November 16, 2004
    Assignee: Tokuyama Corporation
    Inventor: Kenichiro Miyahara
  • Publication number: 20040198580
    Abstract: Low dielectric constant dielectric ceramics for a borosilicate-based low temperature fired multi-layer substrate is disclosed which can be fired at a wide temperature range of above and below 900° C. and exhibits a low loss electrical property. By controlling the types and addition amount of the alkali earth metal oxide, the linear shrinkage behavior can be considerably controlled while maintaining the electrical property unchanged. The composition facilitates matching a linear shrinkage with a heterogeneous material having certain shrinkage characteristics.
    Type: Application
    Filed: August 7, 2003
    Publication date: October 7, 2004
    Inventors: Jae-Hwan Park, Jae-Gwan Park, Dong-Soon Shin, Young-Jin Choi
  • Patent number: RE38959
    Abstract: An aluminosilicate glass having a composition consisting essentially of, as calculated in weight percent on an oxide basis, of 58-70% SiO2, 12-22% Al2O3, 3-15% B2O3, 2-12% CaO, 0-3% SrO, 0-3% BaO, 0-8% MgO, 10-25% MCSB (i.e., MgO+CaO+SrO+BaO), and SrO and BaO in combination being less than 3%.
    Type: Grant
    Filed: May 8, 2002
    Date of Patent: January 31, 2006
    Assignee: Corning Incorporated
    Inventor: Jeffrey T. Kohli