Beads Patents (Class 501/33)
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Patent number: 10577709Abstract: Process for deposition of a dense thin film comprising at least one material Px on a substrate, in which: (a) a colloidal suspension is procured containing nanoparticles of at least one material Px, (b) said substrate is immersed in said colloidal suspension, jointly with a counter electrode, (c) an electrical voltage is applied between said substrate and said counter electrode so as to obtain the electrophoretic deposition of a compact film comprising nanoparticles of said at least one material Px on said substrate, (d) said compact film is dried, (e) said film is mechanically consolidated, (f) thermal consolidation is carried out at a temperature TR that does not exceed 0.7 times (and preferably does not exceed 0.5 times) the melting or decomposition temperature (expressed in ° C.) of the material Px that melts at the lowest temperature, preferably at a temperature of between 160° C. and 600° C., and even more preferably at a temperature of between 160° C. and 400° C.Type: GrantFiled: October 30, 2012Date of Patent: March 3, 2020Assignee: I-TENInventors: Frédéric Bouyer, Bruno Vuillemin, Fabien Gaben
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Patent number: 10500570Abstract: Provided is a formed body containing at least one carbonate compound (A1) selected from Na2CO3 or K2CO3, the formed body having a volume of pores with a pore diameter of from 0.05 ?m to 10 ?m of from 0.10 mL/g to 0.30 mL/g and a crushing strength of from 1.8 kgf to 10.0 kgf.Type: GrantFiled: December 10, 2014Date of Patent: December 10, 2019Assignee: MITSUI CHEMICALS, INC.Inventors: Shinichiro Ichikawa, Naoya Takahashi, Masami Murakami
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Patent number: 10352059Abstract: In some embodiments, a shelter includes an impact-resistant panel having an energy-absorbing core positioned between two outer layers, wherein the energy-absorbing core includes a syntactic foam material that has a plurality of hollow microspheres compounded with a polymeric resin.Type: GrantFiled: March 15, 2013Date of Patent: July 16, 2019Assignee: THE UAB RESEARCH FOUNDATIONInventors: Uday Vaidya, Selvum Pillay, Haibin Ning, Krishnan Balaji Thattai Parthasarathy
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Patent number: 10232335Abstract: The ?-eucryptite fine particle production method of the invention includes spraying, into an atmosphere at 50° C. to a temperature lower than 300° C., a solution containing a water-soluble lithium salt, a water-soluble aluminum salt, and colloidal silica, in such amounts that the mole proportions among lithium atoms, aluminum atoms, and silicon atoms (Li:Al:Si) are adjusted to 1:1:1, to thereby dry the solution, and, subsequently, firing the dried product in air at 600 to 1,300° C.Type: GrantFiled: December 16, 2015Date of Patent: March 19, 2019Assignee: NISSAN CHEMICAL INDUSTRIES, LTD.Inventors: Hirokazu Kato, Tadayuki Isaji, Yoshiyuki Kashima, Jun-ichi Nakajima
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Patent number: 10053387Abstract: Glass microbubbles include on an average weight basis: from 25.0 to 37.4 percent by weight of silicon; from 5.7 to 8.6 percent by weight of calcium; from 5.2 to 14.9 percent by weight, on a total combined weight basis, of at least one of sodium or potassium; from 0.3 to 0.9 percent of boron; and from 0.9 to 2.6 percent of phosphorus, wherein the weight ratio of phosphorus to boron is in the range of from 1.4 to 4.2, and wherein the glass microbubbles comprise less than 0.4 percent by weight of zinc. A raw product including the glass microbubbles, and methods of making the raw product are also disclosed.Type: GrantFiled: July 3, 2014Date of Patent: August 21, 2018Assignee: 3M Innovative Properties CompanyInventor: Geoffrey P. Morris
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Patent number: 9731996Abstract: This disclosure provides methods of manufacturing a controlled pore glass, including: (a) adding an acidic solution to a column containing borosilicate glass; (b) flushing the column from step (a) with an aqueous solution until the pH of the effluent is greater than about 6; (c) adding a basic solution to the column from step (b); and (d) flushing the column from step (c) with an aqueous solution until the pH of the effluent is less than about 9 to produce a controlled pore glass.Type: GrantFiled: October 7, 2015Date of Patent: August 15, 2017Assignee: INTERGRATED DNA TECHNOLOGIES, INC.Inventors: Shawn Walsh, Kye Roth, William E. Martin, III, Shawn Allen
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Patent number: 9312045Abstract: A conductive paste composition for a solar cell contains a conductive powder, a glass frit, and a vehicle. The glass fit includes glass containing SO2 within a range of 0.05 to 5.0 (mol %) in terms of oxide.Type: GrantFiled: June 22, 2012Date of Patent: April 12, 2016Assignee: NORITAKE CO., LIMITEDInventors: Yasushi Yoshino, Yusuke Kawamoto, Kosuke Tsunoda
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Patent number: 9200500Abstract: A method comprising placing a composition comprising a wellbore servicing fluid and a Micro-Electro-Mechanical System (MEMS) sensor in a subterranean formation, whereby the MEMS sensor is coated with an elastomer. The elastomer-coated MEMS sensor is used to detect one or more parameters, including a compression or swelling of the elastomer, an expansion of the elastomer, or a change in density of the composition.Type: GrantFiled: October 30, 2012Date of Patent: December 1, 2015Assignee: Halliburton Energy Services, Inc.Inventors: Craig W. Roddy, Ricky L. Covington
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Patent number: 9144475Abstract: The present invention provides a curable composition allowing a cured product having high aesthetic quality, strength and durability along with having high surface lubricating property. A curable composition in the present invention comprises: an inorganic powder and a polymerizable monomer, wherein the inorganic powder contains a spherical composite powder, the spherical composite powder has a complex of silicon dioxide and at least one of alumina and zirconia, and an amorphous part and a crystalline part are mixed in the spherical composite powder. A refractive index difference is not more than 0.05 between the spherical composite powder and a cured product obtained by curing only a compound excluded the spherical composite powder.Type: GrantFiled: April 13, 2011Date of Patent: September 29, 2015Assignees: PANASONIC HEALTHCARE CO., LTD., KAO, CORPORATIONInventors: Masaya Tsujimoto, Mikio Sakaguchi
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Patent number: 9109108Abstract: A hybrid underlayment, includes a thermoplastic making up between 92.0% by volume to 95.5% by volume of the hybrid underlayment. A plurality of expanded microspheres is dispersed through the thermoplastic. The microspheres are expanded to a volume in a range of between 180 square micrometers and 1450 square micrometers. The microspheres makeup between 1.0% by volume to 7.5% by volume of the hybrid underlayment. The hybrid underlayment is extruded into a flat sheet having a thickness of between 1.0 mm and 2.0 mm and a density from 7 pcf to 25 pcf.Type: GrantFiled: June 2, 2015Date of Patent: August 18, 2015Assignee: Pak-Lite, Inc.Inventors: Richard Ford, Richard Allgood
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Patent number: 9016090Abstract: A method for manufacturing a plurality of glass microspheres comprises: melting a batch into a first glass melt in a melter system, processing the first glass melt into a second glass, pulverizing the second glass into a plurality of glass fragments, thermally processing the plurality of glass fragments into a plurality of glass microspheres, providing at least one of a plurality of redox reactions and a plurality of events in at least one of the first glass melt and a melt of the second glass, and the plurality of redox reactions and the plurality of events are induced by a plurality of redox active group (RAG) components.Type: GrantFiled: June 12, 2013Date of Patent: April 28, 2015Inventors: Hamid Hojaji, Laura Gabriela Kocs
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Patent number: 9012047Abstract: The shape and number of surface defects are controlled so that the occurrence of failure is suppressed in an HDD device in which a magnetic head with a very small flying height, such as a DFH head, is mounted. A magnetic disk substrate is characterized in that when laser light with a wavelength of 405 nm and a laser power of 25 mW is irradiated with a spot size of 5 ?m and scattered light from the substrate is detected, the number of defects detected to have a size of 0.1 ?m to not more than 0.3 ?m is less than 50 per 24 cm2 and, with respect to the defects, there is no defect in which, in a bearing curve obtained by a bearing curve plot method using an atomic force microscope, a portion from an apex of the defect to 45% thereof is located in an area of defect height higher than a virtual line connecting from the apex of the defect to 45% thereof.Type: GrantFiled: April 7, 2014Date of Patent: April 21, 2015Assignee: Hoya CorporationInventors: Kouji Kitsunai, Hiroshi Takeda, Yukari Senda
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Patent number: 8853112Abstract: A sintered bead presenting the following chemical analysis, in percentages by weight and for a total of 100%: ZrO2+HfO2: 78%-85%; CeO2: ?15%; Al2O3: >0.1%; additive: >0.1%; impurities: <1%; the additive being selected from MnO, MnO2, Fe2O3, CuO, TiO2, Y2O3, Sb2O3, ZnO, and mixtures thereof. Application to microgrinding and to microdispersion.Type: GrantFiled: February 27, 2006Date of Patent: October 7, 2014Assignee: Saint-Gobain Centre de Recherches et d'Etudes EuropeenInventors: Emmanuel Nonnet, Rimma Khodakovskaya, Moshe Link, Marcel Yancu, Andrei Schon, Eric Hanus
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Patent number: 8609244Abstract: A low density material and a method for preparing a low-density material and precursor for forming a low-density material are provided. An aqueous mixture of inorganic primary component and a blowing agent is formed, the mixture is dried and optionally ground to form an expandable precursor. Such a precursor is then fired with activation of the blowing agent being controlled such that it is activated within a predetermined optimal temperature range. The firing conditions are also controlled to provide a low density sphere containing a heterogeneous sphere wall structure comprising a combination of amorphous glass and a crystalline phase or gas phase or both.Type: GrantFiled: December 8, 2006Date of Patent: December 17, 2013Assignee: James Hardie Technology LimitedInventors: Huagang Zhang, Hamid Hojaji, Shannon Marie Labernik, David L. Melmeth, Thinh Pham, James A. McFarlane
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Patent number: 8476353Abstract: Provided are an amorphous polyamide resin composition having high transparency, and is excellent in heat resistance and stiffness, and a molded product thereof. The glass filler contains, expressed in terms of oxides by mass %, 68 to 74% of silicon dioxide (SiO2), 2 to 5% of aluminum oxide (Al2O3), 2 to 5% of boron oxide (B2O3), 2 to 10% of calcium oxide (CaO), 0 to 5% of zinc oxide (ZnO), 0 to 5% of strontium oxide (SrO), 0 to 1% of barium oxide (BaO), 1 to 5% of magnesium oxide (MgO), 0 to 5% of lithium oxide (Li2O), 5 to 12% of sodium oxide (Na2O), and 0 to 10% of potassium oxide (K2O), where a total amount of lithium oxide (Li2O), sodium oxide (Na2O), and potassium oxide (K2O) is 8 to 12%.Type: GrantFiled: September 25, 2008Date of Patent: July 2, 2013Assignee: Asahi Fiber Glass Company, LimitedInventors: Hideyuki Higashiyama, Keiji Sekine
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Patent number: 8338524Abstract: Disclosed is a glass composition which can be suitably used as a glass filler to be blended into a polycarbonate resin. This glass composition contains, in mass %, 50?SiO2?60, 8?Al2O3?15, 0?MgO?10, 10?CaO?30, 0?Li2O+Na2O+K2O<2, and 5<TiO2?10, and does not substantially contain B2O3, F, ZnO, SrO, BaO and ZrO2.Type: GrantFiled: June 17, 2008Date of Patent: December 25, 2012Assignee: Nippon Sheet Glass Company, LimitedInventors: Kosuke Fujiwara, Akihiro Koyama
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Patent number: 8329806Abstract: The method for producing flaky-glass granules of the present invention is a method for producing flaky-glass granules by allowing a plurality of glass flakes to be bonded to each other so as to be granulated. The method includes the steps of: (I) adding at least one liquid selected from water and a volatile organic solvent to the plurality of glass flakes and stirring a resultant mixture, and (II) drying the plurality of glass flakes stirred with the liquid added thereto. Unlike conventional flaky-glass granules, the flaky-glass granules produced by this method contain neither a binder nor a surface treatment agent for bonding the glass flakes to each other. Thus, when mixed into a thermoplastic resin to be molded at a high temperature, the flaky-glass granules cause neither foam inclusion nor discoloration in a molded article of the resin.Type: GrantFiled: October 3, 2008Date of Patent: December 11, 2012Assignee: Nippon Sheet Glass Company, LimitedInventor: Takeshi Maeda
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Patent number: 8304484Abstract: Disclosed is a glass composition having a stable quality, which can be easily obtained. This glass composition can be used as a glass filler to be blended into a polycarbonate resin, and enables to reduce the load imposed on a glass manufacturing apparatus. Specifically, this glass composition contains, in mass %, 50?SiO2?60, 8?Al2O3?15, 0?MgO?10, 5?CaO<21, 0<SrO+BaO?25, 10<MgO+SrO+BaO?30, 0?Li2O+Na2O+K2O<2, 2<TiO2?10 and 0?ZrO2<2 and does not substantially contain B2O3, F, and ZnO.Type: GrantFiled: June 17, 2008Date of Patent: November 6, 2012Assignee: Nippon Sheet Glass Company, LimitedInventors: Kosuke Fujiwara, Akihiro Koyama
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Patent number: 8261577Abstract: There is provided a method for making hollow microspheres including heating a feed under conditions sufficient to convert at least a portion of the feed into hollow microspheres, where the heating is conducted under a vacuum. There is also provided hollow microspheres made using this method.Type: GrantFiled: December 21, 2009Date of Patent: September 11, 2012Assignee: 3M Innovative Properties CompanyInventor: Gang Qi
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Publication number: 20120202049Abstract: The invention relates to an object containing at least one glass spacer between a first element of said object and a second element of said object, said spacer having a concentration gradient in alkali metal ions from its surface and perpendicular to its surface. The object may be a solar collector under vacuum. The invention also relates to a glass bead having a concentration gradient in alkali metal ions from its surface and perpendicular to its surface and its use as a spacer withstanding a pressure force between two elements, said pressure pushing the two elements together.Type: ApplicationFiled: October 18, 2010Publication date: August 9, 2012Applicant: SAINT-GOBAIN GLASS FRANCEInventors: Serge Valladeau, Xavier Brajer
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Patent number: 8209999Abstract: Silica glass granule having the following features: Area: 100 to 5000 ?m2, ECD: 5 to 100 ?m, Circumference: 20 to 400 ?m, Maximum diameter: 10 to 140 ?m, Minimum diameter: 5 to 80 ?m, where all values are medium values, Specific BET surface area: <1 m2/g Impurities: <50 ppm It is prepared by a) compacting pyrogenic silicon dioxide powder with a tamped density of 15 to 190 g/l to slugs, b) subsequently crushing them and removing slug fragments with a diameter of <100 ?m and >800 ?m, c) the slug fragments having a tamped density of 300 to 600 g/l, and d) subsequently treating them at 600 to 1100° C. in an atmosphere which comprises one or more compounds which are suitable for removing hydroxyl groups, and e) then sintering them at 1200° C. to 1400° C.Type: GrantFiled: June 4, 2008Date of Patent: July 3, 2012Assignee: Evonik Degussa GmbHInventors: Kai Schumacher, Christian Schulze-Isfort, Paul Brandl, Mitsuru Ochiai
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Patent number: 8158035Abstract: It is an object of the present invention to provide a light diffusing member which has excellent optical transparency and light resistance and has excellent light diffusibility despite of a small amount of filler to be added, and a method for producing the same. The light diffusing member of the present invention is a light diffusing member including a base material and ceramic particles contained in the base material, wherein the ceramic particles have a composition in which the total amount of MgO and Al2O3 is 80% by weight or more and the weight ratio [MgO/Al2O3] of MgO and Al2O3 is 0.05 to 5.Type: GrantFiled: December 26, 2007Date of Patent: April 17, 2012Assignee: Kao CorporationInventors: Mikio Sakaguchi, Kazuo Oki
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Patent number: 8080490Abstract: The invention relates to an antimicrobial phosphate glass having the following composition in percent by weight on an oxide basis: P2O5>66-80 percent by weight; SO30-40 percent by weight; B203 0-1 percent by weight; Al2O3>6.2-10 percent by weight; SiO2 0-10 percent by weight; Na2O>9-20 percent by weight; CaO 0-25 percent by weight; MgO 0-15 percent by weight; SrO 0-15 percent by weight; BaO 0-15 percent by weight; ZnO>0-25 percent by weight; Ag2O 0-5 percent by weight; CuO 0-10 percent by weight; GeO2 0-10 percent by weight; TeO2 0-15 percent by weight; Cr2O3 0-10 percent by weight; J 0-10 percent by weight; F 0-3 percent by weight.Type: GrantFiled: February 20, 2004Date of Patent: December 20, 2011Assignee: Schott AGInventors: Jörg Hinrich Fechner, José Zimmer, Karine Seneschal
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Patent number: 8030232Abstract: A titanium-containing oxide glass having a bulky form and substantially having a chemical composition represented by the formula: (M1)1-x(M2)x(Ti1-y1(M3)y1)y2O2 [wherein M1 represents an element selected from Ba, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Na and Ca; M2 represents at least one element selected from Mg, Ba, Ca, Sr, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Na, Sc, Y, Hf, Bi and Ag; M3 represents at least one element selected from V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Zr, Nb, Mo, Ru, Rh, Pd, Al, Si, P, Ga, Ge, In, Sn, Sb and Te; and x, y1, y2 and z satisfy the following requirements: 0?x?0.5, 0?y1<0.31, 1.4<y2<3.3, and 3.9<z<8.0, provided that x+y1?0 when M1 represents Ba, and y1?0 when both M1 and M2 represent Ba].Type: GrantFiled: March 21, 2011Date of Patent: October 4, 2011Assignee: Japan Aerospace Exploration AgencyInventors: Kentei Yono, Yasutomo Arai, Atsunobu Masuno, Takehiko Ishikawa, Shinichi Yoda
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Patent number: 7960300Abstract: A titanium-containing oxide glass having a bulky form and substantially having a chemical composition represented by the formula: (M1)1-x(M2)x(Ti1-y1(M3)y1)y2Oz [wherein M1 represents an element selected from Ba, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Na and Ca; M2 represents at least one element selected from Mg, Ba, Ca, Sr, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Na, Sc, Y, Hf, Bi and Ag; M3 represents at least one element selected from V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Zr, Nb, Mo, Ru, Rh, Pd, Al, Si, P, Ga, Ge, In, Sn, Sb and Te; and x, y1, y2 and z satisfy the following requirements: 0?x?0.5, 0?y1<0.31, 1.4<y2<3.3, and 3.9<z<8.0, provided that x+y1?0 when M1 represents Ba, and y1?0 when both M1 and M2 represent Ba].Type: GrantFiled: September 13, 2007Date of Patent: June 14, 2011Assignee: Japan Aerospace Exploration AgencyInventors: Kentei Yono, Yasutomo Arai, Atsunobu Masuno, Takehiko Ishikawa, Shinichi Yoda
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Publication number: 20110132882Abstract: A filler made of glass beads is provided. The glass improves the absorption and the distribution of the energy of the beam such that an internal wall of the hollow component is not damaged. A process for producing a through-hole in a hollow component is provided. Also, an apparatus for laser drilling is provided.Type: ApplicationFiled: December 2, 2010Publication date: June 9, 2011Inventors: Wolfgang Dorn, Francis-Jurjen Ladru, Michael Riemann
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Patent number: 7947616Abstract: Presently described are retroreflective articles, such as pavement markings, that comprise transparent microspheres partially embedded in a (e.g., polymeric) binder. Also described are (e.g., glass-ceramic) microspheres, methods of making microspheres, as well as compositions of glass materials and compositions of glass-ceramic materials. The microspheres generally comprise lanthanide series oxide(s), titanium oxide (TiO2), and optionally zirconium oxide (ZrO2).Type: GrantFiled: May 12, 2010Date of Patent: May 24, 2011Assignee: 3M Innovative Properties CompanyInventors: Matthew H. Frey, Anatoly Z. Rosenflanz, Kenton D. Budd
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Patent number: 7900474Abstract: Hollow glass microspheres are made using selenium oxide as the blowing agent. The use of selenium oxide provides two unique advantages: lower density and smaller hollow microspheres are obtained because loss of selenium oxide gas out of the liquid glass bubble during formation is slow, and the hollow microspheres will contain a vacuum due to the condensation of selenium oxide gas blowing agent upon cooling of the spheres below 315 deg. C.Type: GrantFiled: August 14, 2008Date of Patent: March 8, 2011Inventor: Warren R. Beck
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Patent number: 7745360Abstract: Presently described are retroreflective articles, such as pavement markings, that comprise transparent microspheres partially embedded in a (e.g., polymeric) binder. Also described are (e.g., glass-ceramic) microspheres, methods of making microspheres, as well as compositions of glass materials and compositions of glass-ceramic materials. The microspheres generally comprise lanthanide series oxide(s), titanium oxide (TiO2), and optionally zirconium oxide (ZrO2).Type: GrantFiled: December 17, 2008Date of Patent: June 29, 2010Assignee: 3M Innovative Properties CompanyInventors: Matthew H. Frey, Anatoly Z. Rosenflanz, Kenton D. Budd
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Patent number: 7744689Abstract: An alkali resistant glass composition having improved durability to withstand highly alkali environments at elevated temperatures, such as curing of cementitious products in an autoclave, is conveniently formed from economical and abundant materials. The glass composition includes increased levels of calcium and iron, and relatively low levels of alkali metals, as compared to many other alkali resistant glass products, and comprises essentially of, by weight, >35% Si2O3, 1-25% CaO, 1-15% Fe2O3, 1-10% R2O, and an amount of Al2O3 such that the ratio of Si2O3:Al2O3 is greater than or equal to 1. Alkali resistance can be improved by forming a passivity layer on the surface of glass articles by treating the articles hydrothermally in a basic environment. Optionally zirconia and/or titania may be added to the composition to further improve alkali resistance.Type: GrantFiled: February 24, 2006Date of Patent: June 29, 2010Assignee: James Hardie Technology LimitedInventors: Hamid Hojaji, David Leslie Melmeth
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Publication number: 20100041537Abstract: Method of making particle compositions exhibiting improved floodability and/or flowability properties. The compositions generally contain particles and non-surface modified nanoparticles.Type: ApplicationFiled: October 26, 2009Publication date: February 18, 2010Inventors: Jimmie R. Baran, JR., Madeline P. Shinbach
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Patent number: 7585799Abstract: The present disclosure relates to microspheres (i.e., beads) having a high index of refraction. The disclosure also relates to retroreflective articles, and in particular pavement markings, comprising such microspheres.Type: GrantFiled: January 20, 2009Date of Patent: September 8, 2009Assignee: 3M Innovative Properties CompanyInventors: Matthew H. Frey, Billy J. Frederick, Jr., Terrance L. Bescup
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Patent number: 7579293Abstract: Presently described are retroreflective articles, such as pavement markings, that comprise transparent microspheres partially embedded in a (e.g., polymeric) binder. Also described are (e.g., glass-ceramic) microspheres, methods of making microspheres, as well as compositions of glass materials and compositions of glass-ceramic materials. The microspheres generally comprise lanthanide series oxide(s), titanium oxide (TiO2), and optionally zirconium oxide (ZrO2).Type: GrantFiled: December 17, 2008Date of Patent: August 25, 2009Assignee: 3M Innovative Properties CompanyInventors: Matthew H. Frey, Anatoly Z. Rosenflanz, Kenton D. Budd
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Patent number: 7524779Abstract: The present invention relates to microspheres (i.e., beads) having a high index of refraction. The invention also relates to retroreflective articles, and in particular pavement markings, comprising such microspheres.Type: GrantFiled: January 27, 2005Date of Patent: April 28, 2009Assignee: 3M Innovative Properties CompanyInventors: Matthew H. Frey, Billy J. Frederick, Jr., Terrance L. Bescup
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Patent number: 7513941Abstract: Presently described are retroreflective articles, such as pavement markings, that comprise transparent microspheres partially embedded in a (e.g. polymeric) binder. Also described are (e.g. glass-ceramic) microspheres, methods of making microspheres, as well as compositions of glass materials and compositions of glass-ceramic materials. The microspheres generally comprise lanthanide series oxide(s), titanium oxide (TiO2), and optionally zirconium oxide (ZrO2).Type: GrantFiled: November 14, 2005Date of Patent: April 7, 2009Assignee: 3M Innovative Properties CompanyInventors: Matthew H. Frey, Anatoly Z. Rosenflanz, Kenton D. Budd
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Patent number: 7498283Abstract: A glass powder having an average particle size of at least 0.5 ?m and smaller than 5.0 ?m, having a specific surface area of at least 1.5 m2/cm3, and having a glass transition temperature higher than 200° C. and lower than 400° C.Type: GrantFiled: July 25, 2005Date of Patent: March 3, 2009Assignee: Asahi Fiber Glass Company, LimitedInventors: Hideki Nakagawa, Hideki Endou
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Patent number: 7494610Abstract: A method of activating a zeolite membrane comprising a step of placing the membrane in contact with a fluid mixture containing ozone, wherein when the fluid mixture is a gaseous mixture, the fluid mixture has a temperature of at least 423K, and wherein when the fluid mixture is a liquid mixture, the fluid mixture has a temperature of 353K.Type: GrantFiled: August 30, 2005Date of Patent: February 24, 2009Assignee: The Hong Kong University of Science and TechnologyInventors: King Lun Yeung, Koon Fung Lam, Samuel Heng, Lik Hang Joseph Chau
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Patent number: 7312168Abstract: In one aspect, the invention provides glass beads and optical devices comprising the glass beads. In other aspects, the invention provides methods of making said glass beads and rapid glass screening methods that use glass beads. Glass beads of the invention comprise greater than 80 weight percent silica, active rare earth dopant, and modifying dopant. In another embodiment the glass beads comprise greater than 80 weight percent silica and at least 5 weight percent germania. In another embodiment, glass beads comprise and from about 20 to about 90 anion mole percent of non-oxide anion.Type: GrantFiled: May 17, 2005Date of Patent: December 25, 2007Assignee: 3M Innovative Properties CompanyInventor: Mark T. Anderson
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Patent number: 7297646Abstract: Ceramics comprising (i) at least one of Nb2O5 or Ta2O5 and (ii) at least two of (a) Al2O3, (b) REO, or (c) at least one of ZrO2 or HfO2. Embodiments of ceramics according to the present invention can be made, formed as, or converted into optical waveguides, glass beads, articles (e.g., plates), fibers, particles (e.g., abrasive particles), and thin coatings.Type: GrantFiled: September 25, 2006Date of Patent: November 20, 2007Assignee: 3M Innovative Properties CompanyInventors: Anatoly Z. Rosenflanz, Craig R. Schardt
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Patent number: 7285508Abstract: The present invention provides a glass flake that is substantially free of boron trioxide (B2O3), barium oxide (BaO), zinc oxide (ZnO), and fluorine (F) and has sufficient heat resistance and good formability for glass flake. The glass flake of the present invention includes a glass composition that contains the following components, expressed in mol %; 50?SiO2?65; 4?Al2O3<12; 5?SrO?25; 10<(MgO+SrO)?30; 20?(MgO+CaO+SrO)?45; and 0<(Li2O+Na2O+K2O)<2; wherein the glass composition is substantially free of B2O3, BaO, ZnO, and F. This glass flake is useful for resin compositions, paints, cosmetics, ink compositions, and the like.Type: GrantFiled: April 30, 2004Date of Patent: October 23, 2007Assignee: Nippon Sheet Glass Company, LimitedInventors: Kosuke Fujiwara, Akihiro Koyama
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Patent number: 7045475Abstract: Glass formulations, and a method of converting such glass formulations to glass beads having a refractive index of at least 1.59 and a high level of retroreflectivity, are provided. The methods and formulations provide beads also having high levels of resistance to degradation by environmental exposure.Type: GrantFiled: April 28, 2004Date of Patent: May 16, 2006Assignee: PQ CorporationInventors: Ufuk Senturk, Michael P. Lanci, Raymond Jackson, John W. Lau
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Patent number: 6914024Abstract: In one aspect, the invention provides glass beads and optical devices comprising the glass beads. In other aspects, the invention provides methods of making said glass beads and rapid glass screening methods that use glass beads. Glass beads of the invention comprise greater than 80 weight percent silica, active rare earth dopant, and modifying dopant. In another embodiment the glass beads comprise greater than 80 weight percent silica and at least 5 weight percent germania. In another embodiment, glass beads comprise and from about 20 to about 90 anion mole percent of non-oxide anion.Type: GrantFiled: April 30, 2004Date of Patent: July 5, 2005Assignee: 3M Innovative Properties CompanyInventor: Mark T. Anderson
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Patent number: 6899827Abstract: Sintered, translucent ceramic microbeads, preferably alumina, titania, zirconia, yttria, zirconium phosphate, or yttrium aluminum garnet (YAG) are doped with one or more optically active species. The beads may be added to substances such as explosives in order to create a distinctive optical signature that identifies a manufacturer, lot number, etc. in the event of the need for forensic analysis. Because the beads have a generally spherical surface, the radius of curvature provides an additional distinguishing characteristic by which a particular sample may be identified. The beads could also be formulated into paints if needed to create distinctive optical signatures for camouflage, decoys, or other countermeasures and could also be applied as a dust to track the movement of personnel, vehicles, etc.Type: GrantFiled: May 16, 2003Date of Patent: May 31, 2005Assignee: UT-Battelle, LLCInventors: Robert J. Lauf, Kimberly K. Anderson, Frederick C. Montgomery
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Publication number: 20040259713Abstract: The present invention relates to microspheres (i.e., beads) that comprise titania and bismuth oxide. The glass microspheres further comprise zirconia. The invention also relates to retroreflective articles, and in particular pavement markings, comprising such microspheres.Type: ApplicationFiled: June 11, 2003Publication date: December 23, 2004Applicant: 3M Innovative Properties CompanyInventor: Matthew H. Frey
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Patent number: 6831028Abstract: This invention provides an antimicrobial glass which exhibits excellent dispersing ability into a resin and excellent transparency besides generating small yellowing and a method for manufacturing the antimicrobial glass. In the antimicrobial glass capable of releasing an Ag ion, a shape of the antimicrobial glass is formed into a polyhedron and, at the same time, an average particle size of the antimicrobial glass is set to a value within a range of 0.1 to 300 &mgr;m.Type: GrantFiled: October 23, 2002Date of Patent: December 14, 2004Assignee: KOA Glass Co., Ltd.Inventors: Masao Ishii, Kenichi Tanaka
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Publication number: 20040209756Abstract: In one aspect, the invention provides glass beads and optical devices comprising the glass beads. In other aspects, the invention provides methods of making said glass beads and rapid glass screening methods that use glass beads. Glass beads of the invention comprise greater than 80 weight percent silica, active rare earth dopant, and modifying dopant. In another embodiment the glass beads comprise greater than 80 weight percent silica and at least 5 weight percent germania. In another embodiment, glass beads comprise and from about 20 to about 90 anion mole percent of non-oxide anion.Type: ApplicationFiled: April 30, 2004Publication date: October 21, 2004Applicant: 3M Innovative Properties CompanyInventors: Mark T. Anderson, Kenton D. Budd, James R. Onstott
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Patent number: 6800574Abstract: In one aspect, the invention provides glass beads and optical devices comprising the glass beads. In other aspects, the invention provides methods of making said glass beads and rapid glass screening methods that use glass beads. Glass beads of the invention comprise greater than 80 weight percent silica, active rare earth dopant, and modifying dopant. In another embodiment the glass beads comprise greater than 80 weight percent silica and at least 5 weight percent germania. In another embodiment, glass beads comprise and from about 20 to about 90 anion mole percent of non-oxide anion.Type: GrantFiled: October 24, 2001Date of Patent: October 5, 2004Assignee: 3M Innovative Properties CompanyInventor: Mark T. Anderson
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Patent number: 6734297Abstract: A labeling reagent for use in oligonucleotide (“oligo”) synthesis, as well as a method of preparing such a labeling reagent, a method of using such a reagent for synthesizing a labeled oligonucleotide, and an oligonucleotide prepared using such a reagent. The reagent can be used to label either the 3′ or 5′ termini of a synthesized oligo, and/or for one or more positions along the oligo. The labeling reagent can be prepared by a reaction scheme that involves the initial preparation of hydroxyacids, tritylated hydroxyacids and coupling of such derivatives to diamine, wherein the amine function serves at an attachment point for labels and the hydroxyl groups can either be used to immoblize the molecules to support or can be converted to provide a phosphorylating reagent.Type: GrantFiled: January 14, 2003Date of Patent: May 11, 2004Assignee: Barrskogen, Inc.Inventor: Tomas Kempe
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Patent number: 6695908Abstract: A method of producing an improved aggregate product from in inferior initial aggregate material base material. A percentage weight of crushed glass material is introduced into the initial aggregate material to form said aggregate product.Type: GrantFiled: April 24, 2001Date of Patent: February 24, 2004Inventor: Douglas E. Raisch
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Publication number: 20030155055Abstract: A vehicle tire balancing material comprising beads (1) formed from a first material (1′) having a higher tribo-electric work function, the beads (1) further having a permanent coating (1″) formed from a second material having a lower tribo-electric work function.Type: ApplicationFiled: September 13, 2002Publication date: August 21, 2003Inventor: Roger Leblanc