And Titanium, Zirconium, Vanadium, Tungsten, Or Molybdenum Patents (Class 501/46)
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Publication number: 20080207428Abstract: The present claimed invention intends to provide a responsive glass membrane for ion selective electrode glass and an ion selective electrode comprising the responsive glass membrane that produces a self-cleaning function when the ultraviolet rays are irradiated although no change is brought in a composition of a sample solution as being an object to be measured and that is low in electric resistance value and superior in responsivity under an ordinary measurement environment. The responsive glass membrane for ion selective electrode is made of the titanium-containing oxide glass that contains 20˜80 mol % of titanium dioxide and lithium oxide.Type: ApplicationFiled: February 26, 2008Publication date: August 28, 2008Inventors: Yuji Nishio, Yasukazu Iwamoto, Tadanori Hashimoto
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Publication number: 20080190034Abstract: Ceramic materials and articles comprising at least 35 percent by weight Al2O3, and a plurality of cells having an average cell size of less than 3 micrometers.Type: ApplicationFiled: December 30, 2005Publication date: August 14, 2008Inventors: Anatoly Z. Rosenflanz, Berkan K. Endres, Thomas J. Anderson
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Patent number: 7396786Abstract: A glass containing 5 to 25 mass % of P2O5, 0 to 15 mass % of B2O3, 0 to 5 mass % of SiO2+GeO2, 21 to 50 mass % of BaO+SrO, 0 to 3 mass % of Li2O+Na2O+K2O, and 35 to 65 mass % of Nb2O5, not substantially containing PbO, satisfying Nb2O5/(BaO+SrO)=0.85 to 2.20, having a dielectric constant of 15 or greater, a dielectric loss of 10.0×10?4 or less, and a resistivity of 1.0×1016 ?·cm or more.Type: GrantFiled: January 22, 2003Date of Patent: July 8, 2008Assignee: Kabushiki Kaisha OharaInventors: Masaaki Miyata, Kazuo Ohara
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Patent number: 7396787Abstract: The lead-free, preferably lithium-free, optical glass is useful in imaging, projection, telecommunications, optical communication and/or laser technology, particularly for making precise-pressed optical elements. It has a refractive index nd of 1.50 to 1.57, an Abbé number ?d of 61 to 70. It also has a low transformation temperature of about or below 400° C., good production and processing properties and crystallization resistance. It has a composition, in percent by weight, based on oxide content of P2O5, 40 to 60; Al2O3, 1 to 20; B2O3, 0 to <5; Na2O, 0 to 30; K2O, 0 to 30; Li2O, 0 to <1; ?M2O, >15 to 40; BaO, 1 to 20; ZnO, 1 to 20; SrO, 0 to 5; CaO, 0 to 5; MgO, 0 to 5; and ?MO, 5 to 25. In addition, it may contain standard refining agents, although it is preferably free of arsenic and fluorine.Type: GrantFiled: January 13, 2005Date of Patent: July 8, 2008Assignee: Schott AGInventors: Simone Monika Ritter, Ute Woelfel, Silke Wolff
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Patent number: 7371703Abstract: An optical glass wherein an amount of change in refractive index (?n: difference in refractive index between a state before radiation and a state after radiation) caused by radiation of laser beam at wavelength of 351 nm having average output power of 0.43 W, pulse repetition rate of 5 kHz and pulse width of 400 ns for one hour is 5 ppm or below is provided. The optical glass comprises a fluorine ingredient and/or a titanium oxide ingredient and/or an arsenic oxide ingredient. The optical glass suffers little change in refractive index by radiation of strong light having wavelengths of 300 nm to 400 nm such as ultraviolet laser.Type: GrantFiled: September 18, 2003Date of Patent: May 13, 2008Assignee: Kabushiki Kaisha OharaInventors: Akira Masumura, Muneo Nakahara, Satoru Matsumoto, Tatsuya Senoo
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Patent number: 7361632Abstract: A zinc-containing, water-soluble glass composition comprising from 41 to 54 mole % of P2O5, 10 to 30 mole % of alkali oxides, up to 5 mole % of SO3 and up to 25 mole % of ZnO.Type: GrantFiled: July 25, 2005Date of Patent: April 22, 2008Assignee: Reckitt Benckiser N.V.Inventor: Karlheinz Ulrich Gerhard Hahn
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Publication number: 20080085826Abstract: The present invention relates to lead and fluorine and preferably lithium free optical glasses for the application areas imaging, projection, telecommunications optical communications engineering, mobile drive and/or laser technology with a refractive index of from 1.60?nd?1.64 and an Abbe number of from 56??d?64, which glasses have a low transformation temperature, namely less than or equal to 590° C., preferably less than or equal to 585° C., more preferred less than or equal to 570° C., which glasses can still further be produced and handled easily and are stable to crystallization. The glasses according to the invention with the following composition (in weight-% based on the oxides) comprise the following components: P2O5 26-35 B2O3 10-15 Al2O3 5.5-10? BaO 25-37 SrO 0-6 CaO ?8-15 ZnO ?3-10 Bi2O3 0-8 Na2O 0-2 K2O 0-2 WO3 ?0-10 La2O3 0-2 Nb2O5 0-1 TiO2 ??0-<1 ?earth alkali oxides ?40 ?alkali oxides 0-2 common refining agents ??0-0.Type: ApplicationFiled: October 2, 2007Publication date: April 10, 2008Inventors: Simone Monika Ritter, Ute Woelfel
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Publication number: 20080039309Abstract: The lead-free optical glass can be used in the fields of imaging, sensor technology, microscopy, medical technology, digital projection, photolithography, laser technology, wafer/chip technology, as well as of telecommunications, optical communication engineering and optics/lighting in the automotive sector. It has a refractive index nd of 1.82?nd?2.00 and/or an Abbe number vd of 18?vd?28 with good chemical stability, excellent crystallization stability and the following composition, in wt. based on oxide content, of: P2O5 12-35 Nb2O5 30-50 Bi2O3 ?2-13 GeO2 0.1-7?? Li2O ?6 Na2O ?6 K2O ?6 Cs2O ?6 MgO ?6 CaO ?6 SrO ?6 BaO ???7-<17 ZnO ?6 TiO2 ?7 ZrO2 ?7 WO3 ?2-14 F ??6.Type: ApplicationFiled: August 8, 2007Publication date: February 14, 2008Inventors: Silke Wolff, Simone Monika Ritter, Ute Woelfel
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Publication number: 20080032879Abstract: An optical glass suitable for mold forming at a low temperature including, in percent by weight, 9-25 percent of P2O5, 1-20 percent of GeO2, 12-28 percent of Nb2O5, 1-7 percent of TiO2, 0-55 percent of Bi2O3, 0-38 percent of WO3, 0-3 percent of SiO2, 0-5 percent of B2O3, 0-2 percent of Al2O3, 0-5 percent of Li2O, 0-11 percent of Na2O, 0-5 percent of K2O, 0-3 percent of Ta2O5, 0-1 percent of Sb2O3, at most 13 percent of at least one R2O selected from the group consisting of Li2O, Na2O and K2O, and at most 15 percent of at least one XO selected from the group consisting of CaO, SrO, BaO and ZnO. The optical glass essentially contains no environmental and human harmful components, facilitates mass production and is stable against devitrification near its softening temperature.Type: ApplicationFiled: May 31, 2007Publication date: February 7, 2008Applicant: Asia Optical Co., IncInventors: Tsung-yuen Tsai, Hsiang-jen Shih
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Patent number: 7312169Abstract: The present invention provides a high refractive index, high dispersion optical glass for precision molding, being free from harmful materials causing environmental problems, such as lead oxide, etc., and having a low yield temperature, a refractive index (nd) of at least 1.83 and an Abbe number (?d) of at most 26.0 and further providing a low softening property as well as an improved mass production property with less coloration, which is represented in terms of for making up the glass, by the following chemical composition (wt %): P2O5 15 to 29% B2O3 ?0 to 2% GeO2 ?0 to 14% Sum of P2O5 + B2O3 + GeO2 20 to 35% Li2O ?0 to 5% Na2O ?3 to 14% K2O ?0 to 9% Sum of Li2O + Na2O + K2O ?5 to 15% Nb2O5 ?2 to less than 22% Bi2O3 34 to 60% WO3 ?0 to 5% BaO ?0 to 5% In2O3 ??0 to 7%.Type: GrantFiled: November 4, 2004Date of Patent: December 25, 2007Assignee: Sumita Optical Glass, Inc.Inventors: Yoshinori Yamamoto, Naruhito Sawanobori, Shinobu Nagahama
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Patent number: 7309670Abstract: The present invention relates to optical glass having a high refractive index, high dispersion, and a low glass transition temperature; a preform comprised of the optical glass for precision press-molding and a method of manufacturing the same; and an optical element comprised of the optical glass and a method of manufacturing the same.Type: GrantFiled: April 19, 2004Date of Patent: December 18, 2007Assignee: Hoya CorporationInventors: Yasuhiro Fujiwara, Xuelu Zou
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Patent number: 7306845Abstract: Nanoscale particles, particle coatings/particle arrays and corresponding consolidated materials are described based on an ability to vary the composition involving a wide range of metal and/or metalloid elements and corresponding compositions. In particular, metalloid oxides and metal-metalloid compositions are described in the form of improved nanoscale particles and coatings formed from the nanoscale particles. Compositions comprising rare earth metals and dopants/additives with rare earth metals are described. Complex compositions with a range of host compositions and dopants/additives can be formed using the approaches described herein. The particle coating can take the form of particle arrays that range from collections of disbursable primary particles to fused networks of primary particles forming channels that reflect the nanoscale of the primary particles. Suitable materials for optical applications are described along with some optical devices of interest.Type: GrantFiled: October 29, 2004Date of Patent: December 11, 2007Assignee: NeoPhotonics CorporationInventors: Craig R. Horne, Pierre J. DeMascarel, Christian C. Honeker, Benjamin Chaloner-Gill, Herman A. Lopez, Xiangxin Bi, Ronald J. Mosso, William E. McGovern, James T. Gardner, Sujeet Kumar, James A. Gilliam, Vince Pham, Eric Euvrard, Shivkumar Chiruvolu, Jesse Jur
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Publication number: 20070243991Abstract: A substantially alkaline resistant calcium-iron-phosphate (CFP) glass and methods of making and using thereof. In one application, the CFP glass is drawn into a fiber and dispersed in cement to produce glass fiber reinforced concrete (GFRC) articles having the high compressive strength of concrete with the high impact, flexural and tensile strength associated with glass fibers.Type: ApplicationFiled: March 30, 2007Publication date: October 18, 2007Inventors: Richard K. Brow, Signo T. Reis, Mariano Velez, Delbert E. Day
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Publication number: 20070225146Abstract: Optical glasses are described, which are useful for imaging, sensors, microscopy, medical technology, digital protection, photolithography, laser technology, wafer/chip technology, as well as telecommunication, optical communications engineering and optics/lighting in the automotive sector, with a refractive index of 1.80?nd?1.95 and an Abbe value from 19??d?28 with excellent chemical resistance and stability to crystallization. These optical glasses have a composition, in weight % based on oxide content, of: P2O5, 14-35; Nb2O5, 45-50; Li2O, 0-4; Na2O, 0-4; K2O, 0.5-5; BaO, 17-23; ZnO, 0.1-5; TiO2, 1-<5; ZrO2, 06; and Sb2O3, 0.1-2.Type: ApplicationFiled: March 16, 2007Publication date: September 27, 2007Inventors: Silke Wolff, Stefanie Hansen, Ute Woelfel
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Flat panel display spacer, method of manufacturing flat panel display spacer, and flat panel display
Patent number: 7245066Abstract: A flat panel display spacer has a sintered body containing A12O3, TiC, MgO, and TiO2, whereas the sintered body includes 35 to 55 wt % of MgO with respect to the total weight of A12O3, TiC, MgO, and TiO2.Type: GrantFiled: July 28, 2004Date of Patent: July 17, 2007Assignee: TDK CorporationInventors: Yukio Kawaguchi, Atsushi Hitomi, Kazumitsu Tanaka, Takao Matsumoto, Masahiro Itoh, Kenichi Jinguji, Tsutomu Koyanagi, Katsuyuki Kurachi -
Patent number: 7141525Abstract: The present invention provides a high refractive index, high dispersion optical glass for precision molding, being free from harmful materials causing environmental problems, such as lead oxide, etc., and having a low yield temperature (At), i.e. at most 580° C., a refractive index (nd) of at least 1.89 and an Abbe number (?d) of at most 23.0 and further providing a low softening property as well as an improved mass production property with less coloration, which is represented in terms of for making up the glass, by the following chemical composition (wt %): P2O5 3 to 20% B2O3 0 to 5% GeO2 more than 14 to 37% Sum of P2O5 + B2O3 + GeO2 24 to 43% Li2O 0 to 5% Na2O 0 to 8% K2O 0 to 10% Sum of Li2O + Na2O + K2O 1 to 10% Nb2O5 0 to 50% Bi2O3 12 to 67% BaO 0 to 5% WO3 0 to 12%.Type: GrantFiled: November 4, 2004Date of Patent: November 28, 2006Assignee: Sumita Optical Glass, Inc.Inventors: Yoshinori Yamamoto, Koichi Tsuchiya, Naruhito Sawanobori, Shinobu Nagahama
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Patent number: 7115536Abstract: A rare earth containing glass nominally based on the ternary P2O5—WO3—Na2O-Ln2O3 compositional space, with WO3>30-65 mole %, Na2O 15-35 mole %, P2O5 5-65 mole %, Ln2O3 (Ln=one or more cations selected from lanthanum or any of the rare earth oxides) up to the limit of solubility; with optional additives, MoO3 being a preferred additive, that can be employed alone or in combination at levels up to 15 mole %.Type: GrantFiled: March 5, 2003Date of Patent: October 3, 2006Assignee: Schott Glass Technologies, Inc.Inventors: Joseph Hayden, Sally Pucilowski, Bianca Schreder, Ulrich Peuchert, Ruediger Sprengard, Martin Letz
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Patent number: 7060640Abstract: An optical glass comprises, in mass percent, 15–35% of P2O5, 40–60% of Nb2O5, 0.5% to less than 15% of Na2O and 3% to less than 25% of BaO, has a ratio in mass % of (BaO+Nb2O5)/{(TiO2+WO3)×3+Bi2O3+Nb2O5}>1.0; is free of Pb and As; and has a refractive index (nd) within a range from 1.78 to 1.90 and an Abbe number (?d) within a range from 18 to 27.Type: GrantFiled: July 10, 2003Date of Patent: June 13, 2006Assignee: Kabushiki Kaisha OharaInventors: Michiko Ogino, Yoshio Mori, Masahiro Onozawa
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Patent number: 7033966Abstract: An optical glass which contains at least 20 mol % of TeO2 and has an internal transmittance of at least 80% in a thickness of 2 mm to a light having a wavelength of 405 nm and a refractive index of at least 1.85 to the same light, and which contains no alkali metal oxide or contains alkali metal oxides in a total amount of at most 15 mol %.Type: GrantFiled: May 19, 2004Date of Patent: April 25, 2006Assignee: Asahi Glass Company, LimitedInventors: Tomoyuki Kobayashi, Minoru Sekine, Naoki Sugimoto, Syuji Matsumoto
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Patent number: 7018566Abstract: The invention concerns novel compounds derived from La2Mo2O9 and their use as ion conductors.Type: GrantFiled: April 5, 2001Date of Patent: March 28, 2006Assignee: Centre National de la Recherche ScientifiqueInventors: François Goutenoire, Philippe Lacorre
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Patent number: 7005396Abstract: The present invention provides a composition for use in forming an enamel cover coat from which baked-on foods can be removed without the need for pyrolysis or highly alkaline cleaners. The enamel cover coat preferably exhibits no chipping or other surface defects subsequent to a 2.0 mm Plum Jam Test and an acid resistance of A or better according to ISO 2722. The composition according to the invention includes a glass component including at least a first glass frit comprising a low SiO2 glass frit. Preferably, the glass component includes a blend of the first glass frit and at least a second glass frit. Preferably, the first glass frit includes by weight from about 30% to about 45% P2O5, from about 20% to about 40% Al2O3, from about 15% to about 35% Li2O+Na2O+K2O, up to about 15% B2O3, up to about 15% MgO+CaO+SrO+BaO+ZnO, up to about 10% TiO2+ZrO2, and up to about 10% SiO2.Type: GrantFiled: June 25, 2001Date of Patent: February 28, 2006Assignee: Ferro France-S.A.R.L.Inventors: Sophie Espargillière, Andreas Schanné, Francois Roques
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Patent number: 7001858Abstract: Glass fiber which substantially has the following composition as represented by mol percentage and has a glass transition temperature higher than 300° C. and lower than 400° C.: Li2O+Na2O+K2O: 5 to 35%, P2O5: 20 to 27%, SO3: 3 to 20%, ZnO: 10 to 55%, MgO: 0 to 20%, ZnO+MgO: 10 to 55%, Al2O3: 1 to 5%, and B2O3: 8 to 20%.Type: GrantFiled: February 12, 2003Date of Patent: February 21, 2006Assignees: Asahi Glass Company, Limited, Asahi Fiber Glass Company, LimitedInventors: Hideki Nakagawa, Yoshiro Niino, Yoshinao Kobayashi
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Patent number: 6995101Abstract: An optical glass having a high refractive index and high dispersion characteristics suitable for application to precision press molding to precisely mold final products without requiring grinding or polishing. An optical glass can be prepared exhibiting a refractive index in the range of from 1.75 to 2.0, and an Abbé number in the range of from 20 to 28.5. Optical parts comprised of this glass; press-molding materials comprised of this glass; methods of manufacturing the same; and methods of manufacturing molded glass products employing these materials. A suitable optical glass is composed of the following in molar percent: 15–30% P2O5; 0.5–15% B2O3; 5–25% Nb2O5; 6–40% WO3; 4–45% of at least one of Li2O, Na2O or K2O; 1–5% K2O; 2–9% TiO2; and 0–30% (excluding 30%) of at least one RO selected from among BaO, ZnO, and SrO; with the total content of the above-stated components being equal to or more than 95 percent.Type: GrantFiled: June 29, 2001Date of Patent: February 7, 2006Assignee: Hoya CorporationInventors: Xuelu Zou, Hiromasa Tawarayama, Kazutaka Hayashi, Hiroshi Kawazoe
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Patent number: 6984261Abstract: The invention relates to uses of glasses and glass-ceramics in dental and orthodontic applications.Type: GrantFiled: February 5, 2003Date of Patent: January 10, 2006Assignee: 3M Innovative Properties CompanyInventors: Kevin M. Cummings, Jacqueline C. Rolf, Anatoly Z. Rosenflanz, Richard P. Rusin, Jerome E. Swanson
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Patent number: 6878765Abstract: A method for producing a component from a glass/polymer mixture where, a component is formed from a mixture of a thermoplastic with a processing temperature T1 and first glass particles with saturated surface bonds and a glass temperature T2<T1, at a temperature T3>T1. By melting the first glass particles, second glass particles are produced with surface bonds which can be saturated. The bonds are saturated by being bonded to the thermoplastic.Type: GrantFiled: December 13, 2000Date of Patent: April 12, 2005Assignee: Siemens AktiengesellschaftInventors: Robert Greiner, Angelo Polese
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Patent number: 6875714Abstract: An optical glass consists essentially, expressed in term of weight percent, of: P2O5: 20.0 to 30.0%, B2O3: 0.5 to 10.0%, Nb2O5: 5.0 to 50.0%, WO3: 15.0 to 27.0%, Bi2O3: 0.1 to 3.0%, ZnO: 1.0 to 7.0%, Li2O: 0 to 8.0%, Na2O: 0 to 15.0%, K2O: 0 to 15.0%, and Li2O+Na2O+K2O: 5.0 to 20.0%.Type: GrantFiled: April 25, 2003Date of Patent: April 5, 2005Assignee: Minolta Co., Ltd.Inventor: Manabu Izuki
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Patent number: 6849334Abstract: Nanoscale particles, particle coatings/particle arrays and corresponding consolidated materials are described based on an ability to vary the composition involving a wide range of metal and/or metalloid elements and corresponding compositions. In particular, metalloid oxides and metal-metalloid compositions are described in the form of improved nanoscale particles and coatings formed from the nanoscale particles. Compositions comprising rare earth metals and dopants/additives with rare earth metals are described. Complex compositions with a range of host compositions and dopants/additives can be formed using the approaches described herein. The particle coating can take the form of particle arrays that range from collections of disbursable primary particles to fused networks of primary particles forming channels that reflect the nanoscale of the primary particles. Suitable materials for optical applications are described along with some optical devices of interest.Type: GrantFiled: March 15, 2002Date of Patent: February 1, 2005Assignee: NeoPhotonics CorporationInventors: Craig R. Horne, Pierre J. DeMascarel, Christian C. Honeker, Benjamin Chaloner-Gill, Herman A. Lopez, Xiangxin Bi, Ronald J. Mosso, William E. McGovern, James T. Gardner, Sujeet Kumar, James A. Gilliam, Vince Pham, Eric Euvrard, Shivkumar Chiruvolu, Jesse Jur
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Patent number: 6841493Abstract: The present invention is directed to a glass composition comprising, based on mole %, 15-35% MO where M is selected from BaO, CaO, MgO, PbO, SrO and mixtures thereof, 30-60% TiO2, 10-30% B2O3, 1-7% P2O5, 0-3% Li2O and 2-16% Ln2O3 where Ln is selected from the group of rare earth elements and mixtures thereof. The invention is further directed to the glass composition incorporated in a thick film composition or a castable dielectric composition comprising a dispersion of finely divided solids comprising, based on solids: (a) 30-100 wt. % the glass composition; (b) 0-50 wt. % ceramic filler; both dispersed in a solution of (c) an organic polymeric binder; and (d) a volatile organic solvent. The invention is still further directed to the castable dielectric composition used in a method of forming a high K green tape by casting a thin layer of the castable dispersion onto a flexible sheet and heating the cast layer to remove the volatile organic solvent.Type: GrantFiled: March 17, 2003Date of Patent: January 11, 2005Assignee: E. I. du Pont de Nemours and CompanyInventors: Yong Cho, Kenneth Warren Hang
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Publication number: 20040266602Abstract: The present invention relates to optical glass having a high refractive index, high dispersion, and a low glass transition temperature; a preform comprised of the optical glass for precision press-molding and a method of manufacturing the same; and an optical element comprised of the optical glass and a method of manufacturing the same.Type: ApplicationFiled: April 19, 2004Publication date: December 30, 2004Applicant: HOYA CORPORATIONInventors: Yasuhiro Fujiwara, Xuelu Zou
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Publication number: 20040176236Abstract: A rare earth containing glass nominally based on the ternary P2O5 —WO3—Na2O—Ln2O3 compositional space, with WO3>30-65 mole %, Na2O 15-35 mole %, P2O5 5-65 mole %, Ln2O3 (Ln=one or more cations selected from lanthanum or any of the rare earth oxides) up to the limit of solubility; with optional additives, MoO3 being a preferred additive, that can be employed alone or in combination at levels up to 15 mole %.Type: ApplicationFiled: March 5, 2003Publication date: September 9, 2004Applicant: SCHOTT GLASS TECHNOLOGIES, INC.Inventors: Joseph Hayden, Sally Pucilowski, Bianca Schreder, Ulrich Peuchert, Ruediger Sprengard, Martin Letz
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Patent number: 6767854Abstract: The invention refers to a material which is chemically long-term stable in a neutral or slightly acid environment and which can be used both as bioactive bone replacement material, e.g. in the form of a coating applied onto metallic prosthesis sticks by thermal spraying, and as substrate material in biotechnology, e.g. in the form of a ceramic sheet. According to the invention, said material comprises 15-45% by weight CaO, 40-45% by weight P2O5, 10-40% by weight ZrO2 and fluoride, said material further comprises two crystalline phases being apatite and calcium zirconium phosphate, and a secondary glass phase. Said material has a very high chemical long-term stability, compared to known materials which can also be produced by means of a melting process.Type: GrantFiled: June 13, 2002Date of Patent: July 27, 2004Assignee: Bam Bundesanstalt fuer Materialforschung und PrufungInventors: Georg Berger, Ute Ploska
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Patent number: 6743743Abstract: Optical glasses and optical articles comprised of the optical glass are disclosed. One of which comprises, by means of weight percentages, more than 32 percent and not more than 45 percent P2O5, more than 0.5 percent and not more than 6 percent Li2O, more than 5 percent and not more than 22 percent Na2O, 6-30 percent Nb2O5, 0.5-10 percent B2O3, 0-35 percent WO3, 0-14 percent K2O, and 10-24 percent Na2O+K2O, and the total of all the above components is not less than 80 percent.Type: GrantFiled: January 29, 2002Date of Patent: June 1, 2004Assignee: Hoya CorporationInventor: Koichi Sato
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Patent number: 6656859Abstract: A family of tellurite glasses and optical components for telecommunication systems, the glasses consisting essentially of, as calculated in cation percent, 65-97% TeO2, and at least one additional oxide of an element having a valence greater than two and selected from the group consisting of Ta, Nb, W, Ti, La, Zr, Hf, Y, Gd, Lu, Sc, Al and Ga, that may contain a lanthanide oxide as a dopant, in particular erbium oxide, and that, when so doped, is characterized by a fluorescent emission spectrum having a relatively broad FWHM value.Type: GrantFiled: December 6, 2001Date of Patent: December 2, 2003Assignee: Corning IncorporatedInventors: Bruce G. Aitken, Adam J. G. Ellison, Randall E. Youngman
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Publication number: 20030220182Abstract: An optical glass consists essentially, expressed in term of weight percent, of: P2O5: 20.0 to 30.0%, B2O3: 0.5 to 10.0%, Nb2O5: 5.0 to 50.0%, WO3: 15.0 to 27.0%, Bi2O3: 0.1 to 3.0%, ZnO: 1.0 to 7.0%, Li2O: 0 to 8.0%, Na2O: 0 to 15.0%, K2O: 0 to 15.0%, and Li2O+Na2O+K2O: 5.0 to 20.0%.Type: ApplicationFiled: April 25, 2003Publication date: November 27, 2003Inventor: Manabu Izuki
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Patent number: 6566289Abstract: The present invention provides a composition for use in forming a white porcelain enamel coating on aluminized or galvanized steel. The composition according to the present invention includes a solids portion including a glass component and a white pigment. The glass component includes one or more glass frits including by weight from about 30% to 50% P2O5, from about 15% to about 30% Al2O3, from about 8% to about 40% X2O where X=Na and/or K, up to about 30% TiO2, up to about 12% B2O3, up to about 10% K2O, up to about 10% ZnO, up to about 8% SiO2, up to about 7% La2O3, up to about 5% Li2O, and up to about 15% F. The white pigment include TiO2.Type: GrantFiled: August 17, 2001Date of Patent: May 20, 2003Assignee: Ferro France - S.A.R.L.Inventors: Alain Aronica, Emmanuel Marinho, David Coutouly, Luc Allemeersch, Christophe Reb
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Patent number: 6528442Abstract: To provide an optically transparent film containing 0.01 to 20% by weight glass forming oxide consisting of Nb2O5, V2O5, B2O3, SiO2, and P2O6; 0.01 to 20% by weight Al2O3 or Ga2O3; and 0.01 to 5% by weight hard oxide of ZrO2 and TiO2 as required; balance being ZnO, and a sputtering target for forming such a film. This sputtering target reduces occurrence of particles during sputtering, decreases the number of interruption or discontinuance of sputtering to improve production efficiency, and forms a protective film for optical disks with large transmittance and low reflectance.Type: GrantFiled: December 7, 2000Date of Patent: March 4, 2003Assignee: Nikko Materials Company, LimitedInventors: Katsuo Kuwano, Hideo Takami
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Patent number: 6511931Abstract: The present invention provides a ground coat composition for use in forming an enamel layer on sheet steel that exhibits good spot acid resistance, a satin finish, good bond, and is easy-to-clean. The composition according to the invention includes a glass component that includes a blend of from about 40% to about 70% by weight of a first glass portion including one or more alkali aluminophosphate frits, up to about 30% by weight of a second glass portion including one or more zirconia-phosphate frits, and up to about 30% by weight of a third glass portion including one or more alkali borosilicate frits.Type: GrantFiled: July 16, 2001Date of Patent: January 28, 2003Assignee: Ferro CorporationInventor: Charles A. Baldwin
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Patent number: 6485622Abstract: Lithium ion conductive glass-ceramics comprise in mol %: P2O5 30-45% SiO2 0-15% GeO2 + TiO2 25-50% in which GeO2 0-50% TiO2 0-50% ZrO2 0-8% M2O3 0<-10% where M is an element or elements selected from the group consisting of In, Fe, Cr, Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Th, Dy, Ho, Er, Tm, Yb and Lu Al2O3 0-12% Ga2O3 0-12% Li2O 10-25% and contain Li1+X(M, Al, Ga)X(Ge1−YTiY)2−X(PO4)3 (where 0<X≦0.8 and 0≦Y≦1.0) as a predominant crystal phase. A solid electrolyte, an electric cell and a gas sensor utilizing these glass-ceramics are also provided.Type: GrantFiled: September 27, 1999Date of Patent: November 26, 2002Assignee: Kabushiki Kaisha OharaInventor: Jie Fu
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Patent number: 6432851Abstract: A durable low Tg Sb-stabilized Mo+W phosphate based glass composition exhibiting superior resistance to attack by boiling water, humidity and acids resulting from the addition of Sb to Mo+W phosphate based glass compositions. Specifically, the present invention discloses a glass composition comprising in mol % on the oxide basis, of 0-40% R2O where R includes the alkali metals (Li, Na, K, Rb or Cs) as well as Ag and Tl, 0-20% XO where X includes the alkaline earth metals (Mg, Ca, Sr or Ba) as well as Cu, Zn, Cd and Pb, 15-80% MoO3+WO3, 0.5-60% Sb2O3, and 10-40% P2O5. Additionally, the Sb-stabilized Mo+W phosphate based glass composition can contain a total of 0-5%, in mole percent (mol %) on the oxide basis, of glass forming oxides including, but not limited to, B2O3, Al2O3, SiO2, TeO2, Ga2O3, GeO2, transition metal and rare earth metal oxides, or mixtures thereof.Type: GrantFiled: May 31, 2000Date of Patent: August 13, 2002Assignee: Corning IncorporatedInventor: Bruce G. Aitken
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Publication number: 20020061809Abstract: The present invention provides a composition for use in forming a white porcelain enamel coating on aluminized or galvanized steel. The composition according to the present invention includes a solids portion including a glass component and a white pigment. The glass component includes one or more glass frits including by weight from about 30% to 50% P2O5, from about 15% to about 30% Al2O3, from about 8% to about 40% X2O where X=Na and/or K, up to about 30% TiO2, up to about 12% B2O3, up to about 10% K2O, up to about 10% ZnO, up to about 8% SiO2, up to about 7% La2O3, up to about 5% Li2O, and up to about 15% F. The white pigment include TiO2.Type: ApplicationFiled: August 17, 2001Publication date: May 23, 2002Applicant: Ferro France S.A.R.L.Inventors: Alain Aronica, Emmanuel Marinho, David Coutouly, Luc Allemeersch, Christophe Reb
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Patent number: 6376399Abstract: Alkali tungstate, molybdate and vanadate glasses, and telecommunications components embodying such glasses, the compositions of the glasses consisting essentially of 15-70 mol percent of at least one oxide selected from the group consisting of WO3, MoO3 and VO2.5, 0-35% CrO3, 0-15% UO3, the total WO3 plus MoO3 plus VO2.5 plus CrO3 plus UO3 being 50-70%, 20-50% R2O where R represents at least two elements selected from the group consisting of Li, Na, K, Rb, Cs, Ag and T1, and optionally containing 0-10% MO where M is selected from the groups of elements consisting of Ca, Ba, Sr, Mg, Cd, Pb, 0-5 % X2O3 where x is at least one element selected from the group consisting of Al, Ga, In and Bi, 0-5% of at least one transition metal oxide, 0-15% P2O5 and/or TeO2 and 0-5% of a rare earth oxide selected from the lanthanide series.Type: GrantFiled: January 24, 2000Date of Patent: April 23, 2002Assignee: Corning IncorporatedInventors: Bruce G. Aitken, Matthew J. Dejneka
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Publication number: 20020042337Abstract: An optical glass having a high refractive index and high dispersion characteristics that is suited to application to precision press molding to precisely mold the shape of final products for objectives not requiring grinding or polishing. An optical glass exhibiting a refractive index in the range of from 1.75 to 2.0, an Abbé number in the range of from 20 to 28.5. Optical parts comprised of this glass; press-molding materials comprised of this glass; methods of manufacturing the same; and methods of manufacturing molded glass products employing these materials.Type: ApplicationFiled: June 29, 2001Publication date: April 11, 2002Inventors: Xuelu Zou, Hiromasa Tawarayama, Kazutaka Hayashi, Hiroshi Kawazoe
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Patent number: 6355586Abstract: A low melting point glass consisting essentially of, as represented by mol % based on the following oxides: Mol % SnO 2 to 37.5, ZnO 5 to 73, P2O5 16 to 50, Li2O 0 to 9, Na2O 0 to 9, K2O 0 to 9, Al2O3 0 to 20, B2O3 0 to 30, SiO2 0 to 20, MgO 0 to 35, CaO 0 to 35, SrO 0 to 35, BaO 0 to 35, In2O3 0 to 10, WO3 0 to 10, wherein SnO+ZnO+P2O5+B2O3 is at least 76 mol %, Li2O+Na2O+K2O is from 0 to 9 mol %, MgO+CaO+SrO+BaO is from 0 to 35 mol %, and the molar ratio of SnO to ZnO is less than 1.Type: GrantFiled: January 31, 2000Date of Patent: March 12, 2002Assignee: Asahi Glass Company, LimitedInventors: Hiroshi Usui, Yasuko Dotani, Ryuichi Tanabe, Tsuneo Manabe
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Patent number: 6352950Abstract: A family of alkali-tungsten-tellurite glasses that consist essentially of, as calculated in mole percent, 10-90% TeO2, at least 5% W03 and at least 0.5% R2O where R is Li, Na, K, Cs, Tl and mixtures, that may contain a lanthanide oxide as a dopant, in particular erbium oxide, and that, when so doped, is characterized by a fluorescent emission spectrum having a relatively broad FWHM value.Type: GrantFiled: May 31, 2000Date of Patent: March 5, 2002Assignee: Corning IncorporatedInventors: Bruce G. Aitken, Adam J. G. Ellison
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Patent number: 6333282Abstract: The present invention provides an optical glass for precision molding, having excellent properties, i.e. yield temperature (At) of at most 550° C., refractive index (nd) of at least 1.83 and Abbe number (&ngr;d) of at most 26.0 and further providing a low softening property as well as an improved mass production property with less coloration, which is represented, in term of atoms for making up the glass, by the following chemical composition (wt %) P2O5 14.0 to 31.0% B2O3 0 to 5.0% GeO2 0 to 14.0% Sum of P2O5 + B2O3 + GeO2 14.0 to 35.0% Li2O 0 to 6.0% Na2O 2.5 to 14.0% Sum of Li2O + Na2O 2.5 to 15.0% Nb2O5 22.0 to 50.0% WO3 0 to 30.0% Bi2O3 5.0 to 36.0% BaO 0 to 22.0%.Type: GrantFiled: August 9, 2000Date of Patent: December 25, 2001Assignee: Sumita Optical Glass, Inc.Inventors: Koji Nakahata, Koichi Tsuchiya, Shinobu Nagahama
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Patent number: 6315881Abstract: A solid electric cell includes a case, a negative electrode, a positive electrode and a solid electrolyte. The negative electrode, positive electrode and solid electrolyte are disposed in the case in such a manner that the negative electrode opposes the positive electrode through the solid electrolyte. The solid electrolyte is made of an alkali ion conductive glass-ceramic having ion conductivity no less than 10−3S/cm at room temperature. A gas sensor includes a case, a negative electrode, a positive electrode, a solid electrolyte and a layer for which an electromotive force corresponding to the concentration of the gas is produced between the two electrodes. In the case, the negative electrode opposes the positive electrode through the solid electrolyte. The solid electrolyte is made of an alkali ion conductive glass-ceramic having ion conductivity no less than 10−3S/cm at room temperature.Type: GrantFiled: April 9, 1999Date of Patent: November 13, 2001Assignee: Kabushiki Kaisha OharaInventor: Jie Fu
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Patent number: 6309989Abstract: A tin-borophosphate glass of the present invention has main components of SnO, B2O3, and P2O5, consists essentially of, by mole % representation, 30-70% SnO, 5-30% B2O3, and 24-45% (24% exclusive) P2O5, and satisfies a condition of B2O3/P2O5≧0.20 by mole ratio.Type: GrantFiled: November 29, 1999Date of Patent: October 30, 2001Assignee: Nippon Electric Glass Co., Ltd.Inventor: Takemi Kikutani
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Patent number: 6306783Abstract: A tin borophosphate glass for use in sealing materials includes, by mole, 30 to 80% of SnO, 5 to 60% of B2O3, and 5 to 24% of P2O5 as main components. The glass is free of lead but is of equal quality to those of conventional lead-containing sealing glasses. The glass can provide a satisfactory sealing material.Type: GrantFiled: February 2, 2000Date of Patent: October 23, 2001Assignee: Nippon Electric Glass Co., Ltd.Inventor: Toshio Yamanaka
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Patent number: 6194333Abstract: A dielectric composition for a plasma display panel that is capable of satisfying the required characteristics of a dielectric applied to an barrier rib and a dielectric layer of a plasma display panel. The dielectric composition includes a parent glass of P2O5—PbO—K2O group and an oxide filler. The dielectric has relatively low sintering temperature and dielectric constant, a high reflectivity and a reduced amount of PbO component, so that it can minimize an environment contamination and reduce a weight of the device.Type: GrantFiled: April 27, 1999Date of Patent: February 27, 2001Assignee: LG Electronics Inc.Inventor: Byung Gil Ryu
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Patent number: 6156684Abstract: In a light polarization control element using a stress-optical coefficient glass, the stress-optical coefficient glass is substantially composed of a phosphorous acid glass containing 20 to 60 percent by weight of P.sub.2 O.sub.5 and 40 to 73 percent by weight of BaO and PbO.Type: GrantFiled: June 16, 1998Date of Patent: December 5, 2000Assignee: Hoya CorporationInventors: Kouichi Sato, Kazuo Tachiwana