And Zirconium, Titanium, Tantalum, Or Niobium Patents (Class 501/51)
  • Patent number: 8110515
    Abstract: A glass composition that simultaneously has a low temperature coefficient of refractive index and a good light transmittance, being suitable for use in environments of intense temperature change. There is provided an optical glass containing SiO2, B2O3 and La2O3, which has a temperature coefficient (20° to 40° C.) of relative refractive index (546.07 nm) of 10.0×10?6 (° C.?1) or below. Further, there is provided an optical glass mentioned above having a temperature coefficient (20° to 40° C.) of relative refractive index (546.07 nm) of 4.6×10?6 (° C.?1) or below. Still further, there is provided an optical glass mentioned above having an internal transmittance (?;10 mm) at 400 nm of 80% or higher.
    Type: Grant
    Filed: September 8, 2006
    Date of Patent: February 7, 2012
    Assignee: Ohara, Inc.
    Inventor: Koji Shimizu
  • Patent number: 8110513
    Abstract: A glass composition comprising: (A) TeO2 (50-95 mol %); (B) B2O3 (1-33 mol %); (C) ZnO (1-37 mol %); (D) Bi2O3 (1-18 mol %); (E) P2O5 (0-15 mol %); (F) R2O (0-13 mol %), where R represents at least one element selected from the group consisting of Li, Na, and K; (G) MO (0-13 mol %), where M represents at least one element selected from the group consisting of Mg, Ca, Sr, and Ba; (H) TiO2 (0-13 mol %); (I) Nb2O5 (0-10 mol %); (J) Ta2O5 (0-13 mol %); (K) L2O3 (0-11 mol %), where L represents at least one element selected from the group consisting of yttrium and lanthanoids; and (L) the total amount of P2O5, R2O, MO, TiO2, Nb2O5, Ta2O5, and L2O3 described in (E) to (K), respectively, is 0-15 mol %.
    Type: Grant
    Filed: June 24, 2008
    Date of Patent: February 7, 2012
    Assignee: Nikon Corporation
    Inventors: Motoi Ueda, Takashi Ozawa, Kiyoaki Shinohara
  • Publication number: 20120028785
    Abstract: The invention provides a novel optical glass which has a refractive index (nd) of 1.78 to 2.2 and an Abbe value (?d) of 16 to less than 40 and is suitable for precision mold press molding by virtue of its having a low glass transition temperature, namely, an optical glass which contains by mole in terms of oxides 25 to 60% B2O3, 2 to 45% (in total) TiO2 and Nb2O5 and 1 to 25% WO3 and has a refractive index (nd) of 1.78 to 2.2 and an Abbe value (?d) of 16 to less than 40. Further, the glass contains 5 to 35% La2O3 and 1 to 40% ZnO and has a glass transition temperature (Tg) of 700° C. or below. The optical glass is excellent in meltability, stability and devitrification resistance and has a high refractive index, high light-dispersive power and excellent precision press moldability.
    Type: Application
    Filed: September 30, 2011
    Publication date: February 2, 2012
    Applicant: OHARA INC.
    Inventor: Jie Fu
  • Patent number: 8080491
    Abstract: An optical glass having high refractive index and low dispersion properties. There is provided an optical glass having an Abbe number (?d) and a refractive index (nd) in a region indicated by a shape bound by connecting three points, A(53, 1.70), B(53, 1.87), and C(40, 1.87) with straight lines on an orthogonal xy-coordinate system with the x-axis designating the Abbe number and the y-axis designating the refractive index; and comprising no less than 25% and no more than 65% of a combination of a SiO2 component and a B2O3 component, no less than 20% and no more than 55% of a Ln2O3 component (Ln represents at least one species selected from the group consisting of La, Gd, Dy, Yb, and Lu), and a ratio of a La2O3 component to a Ln2O3 component being no more than 0.6, by mol % on the basis of oxides.
    Type: Grant
    Filed: October 10, 2008
    Date of Patent: December 20, 2011
    Assignee: Ohara Inc.
    Inventor: Jie Fu
  • Patent number: 8053384
    Abstract: A glass composition being suitable for precision mold press forming, having superior resistance to devitrification, having optical constants (a refractive index, an Abbe number, and the like) required for aspherical lenses, and a low glass transition temperature. There is provided an optical glass comprising no less than 5 mol % and no more than 60 mol % of a B2O3 component, and no less than 0.2 mol % and no more than 60 mol % of a TeO2 component, by mol % on the basis of oxides. Further, there is provided an optical glass mentioned above having optical constants with a refractive index (nd) of 1.80 to 2.20, and an Abbe number (?d) of 16 to 40. Still further, there is provided an optical glass mentioned above having a glass transition temperature (Tg) of no more than 680° C.
    Type: Grant
    Filed: April 2, 2008
    Date of Patent: November 8, 2011
    Assignee: Ohara Inc.
    Inventor: Jie Fu
  • Publication number: 20110257001
    Abstract: The present invention relates to an optical glass having a refractive index nd of 1.86 or higher and an Abbé number v(nu)d of 28 to 36; a preform for precision press molding and an optical element that are comprised of this glass; and a method for manufacturing the optical element.
    Type: Application
    Filed: February 25, 2011
    Publication date: October 20, 2011
    Applicant: HOYA CORPORATION
    Inventor: Tomoaki Negishi
  • Patent number: 8039408
    Abstract: The optical glass of the present invention has a refractive index nd of 1.70 or greater and an Abbé number of 50 or greater. Given as mole percentages, it comprises: B2O3 20 to 80 percent, SiO2 0 to 30 percent, Li2O 1 to 25 percent; ZnO 0 to 20 percent, La2O3 4 to 30 percent, Gd2O3 1 to 25 percent, Y2O3 0 to 20 percent, ZrO2 0 to 5 percent, MgO 0 to 25 percent, CaO 0 to 15 percent, SrO 0 to 10 percent, with the combined quantity of the above components being 97 percent or greater. The molar ratio of {ZnO/(La2O3+Gd2O3+Y2O3)} is 0.8 or less and the molar ratio of {(CaO +SrO+BaO)/(La2O3+Gd2O3+Y2O3)} is 0.8 or less. Ta2O5 may be incorporated as an optional component, with the molar ratio {(ZrO2+Ta2O5)/(La2O3+Gd2O3+Y2O3)}being 0.4 or less. The present invention further relates to a preform for precision press molding comprised of this glass, an optical element comprised of this glass, and methods of manufacturing the same.
    Type: Grant
    Filed: March 28, 2007
    Date of Patent: October 18, 2011
    Assignee: Hoya Corporation
    Inventor: Yasuhiro Fujiwara
  • Patent number: 8034733
    Abstract: An optical glass comprises, denoted as weight percentages, SiO2-2-22%, B2O3: 3-24%, ZnO:>8% and ?30%, CaO+BaO+ZnO: 10-50%, MgO: 0-3%, La2O3+Y2O3+Gd2O3+Yb2O3: 1-33%, TiO2: 2-20%, ZrO2: 0-10%, Nb2O5: 2-32%, Li2O: 0-5%, Na2O: 0-8%, K2O: 0-10%, WO3: 0-20%. The ratio by weight of La2O3 to the combined contents of La2O3, Y2O3, Gd2O3, and Yb2O3 (La2O3/(La2O3+Y2O3+Gd2O3+Yb2O3)) falls within a range of 0.7 to 1.
    Type: Grant
    Filed: March 20, 2007
    Date of Patent: October 11, 2011
    Assignee: Hoya Corporation
    Inventors: Yuta Kobayashi, Yoichi Hachitani
  • Patent number: 7998891
    Abstract: Optical glass having a refractive index (nd) of 1.85 or greater, and an Abbe number (?d) falling within the range of 10 to 30, which is suited for molding by precision mold press is provided. The optical glass is characterized by including B2O3+SiO2 in an amount of 3 to 60%, Bi2O3 in an amount of 25 to 80%, RO+Rn2O in an amount of 5 to 60% (wherein R represents one or more selected from a group consisting of Zn, Ba, Sr, Ca, and Mg; and Rn represents one or more selected from a group consisting of Li, Na, K, and Cs), with each component in the range expressed in oxide-based mole percentage, and is characterized in that transparency in the visible region is high, and that the transition point (Tg) is 480° C. or lower. The optical glass is characterized by having a spectral transmittance of 70% or greater at a wavelength of 600 nm for a thickness of 10 mm.
    Type: Grant
    Filed: April 27, 2006
    Date of Patent: August 16, 2011
    Assignee: Ohara Inc.
    Inventor: Jie Fu
  • Publication number: 20110160032
    Abstract: An object of the present invention is to provide optical glass having improved glass-devitrification resistance and moldability without causing reduction in refractive index, and also provide an optical element using the optical glass as a raw material. Specifically, the present invention provides an optical glass containing components of, by mol %: B2O3: over 60% through 75%; Bi2O3: 24% to 39%; La2O3: 7% or lower; Gd2O3: 7% or lower; and ZrO2: 7% or lower.
    Type: Application
    Filed: December 22, 2010
    Publication date: June 30, 2011
    Inventor: Yoshinori Yamamoto
  • Publication number: 20110136652
    Abstract: The optical glass has a refractive index nd of 1.945?nd?1.97, an Abbe number ?d of 33??d?36, and a composition with the following components in amounts expressed in % of their cations, with respect to the total number of cations in the composition: B3+, 35-46; La3+, 25-35; Ta5+, 6-14; W6+, 6-13; Zr4+, 1-7; Gd3+, 0-5; Nb5+, 0-4; Y+3, 0-4; Ba2+, 0-2; ? alkaline earth metal cations, 0-2, ? La3++Ta3++W6++Zr4++Gd3++Nb5++Y3+?50; and at least one fining agent, 0-0.3. Also a ratio of B3+ to La+3 is 1.1 to 1.6 and a ratio of B3+ to ? Si+4+B3+ is ?0.5. The glass is free of lead, arsenic, Ti4+, Th4+, Zn2+, F?, and Hf+4.
    Type: Application
    Filed: December 2, 2010
    Publication date: June 9, 2011
    Inventors: Simone Ritter, Ute Woelfel, Stefanie Hansen
  • Patent number: 7955998
    Abstract: A high-refractivity optical glass which has both a low-temperature softening property suitable for precision press-molding and glass stability suitable for hot-shaping of a preform, which contains, by mass %, 13 to 30% of B2O3, 0.1 to 4% of Li2O, 17 to 35% of ZnO, 15 to 45% of La2O3, 4 to 15% of Ta2O5 exclusive of 15%, 0 to 10% of ZrO2, 0 to 10% of Nb2O5 provided that Ta2O5/(Ta2O5+ZrO2+Nb2O5)>0.3, 0 to 20% of WO3 and 0 to 1% of Sb2O3 and which has a refractive index (nd) of 1.80 to 1.84 and an Abbe's number (?d) of 40.0 to 45.0.
    Type: Grant
    Filed: March 13, 2007
    Date of Patent: June 7, 2011
    Assignee: Hoya Corporation
    Inventors: Kazutaka Hayashi, Yasuhiro Fujiwara
  • Publication number: 20110124485
    Abstract: A glass composition being suitable for precision mold press forming, having superior resistance to devitrification, having optical constants (a refractive index, an Abbe number, and the like) required for aspherical lenses, and a low glass transition temperature. There is provided an optical glass comprising 5 mol % to 60 mol % of a B2O3 component, and 0.2 mol % to 60 mol % of a TeO2 component, by mol % on the basis of oxides. Further, there is provided an optical glass mentioned above having optical constants with a refractive index (nd) of 1.80 to 2.20, and an Abbe number (?d) of 16 to 40. Still further, there is provided an optical glass mentioned above having a glass transition temperature (Tg) of no more than 680° C.
    Type: Application
    Filed: January 19, 2011
    Publication date: May 26, 2011
    Applicant: OHARA INC.
    Inventor: Jie FU
  • Patent number: 7943540
    Abstract: An optical glass for precision molding having a high refractive index (nd) and a low yield temperature (At). The optical glass comprises, as glass components in wt %, 64 to 83% of Bi2O3; 4 to 17% of B2O3; 0 to 12% of GeO2 (wherein the total of B2O3 and GeO2 is 10 to 20%); 0 to 7% of La2O3; 0 to 7% of Gd2O3 (wherein the total of La2O3 and Gd2O3 is 1 to 13%); 0 to 4% of ZrO2; 0 to 5% of Ta2O5; 0 to 15% of ZnO; 0 to 2% of Sb2O3; and 0 to 1% of In2O3. The optical glass has optical constants, that is, a refractive index (nd) of 2.05 to 2.25 and an Abbe number (vd) of 15 to 22, and a yield temperature (At) of 510° C. or less.
    Type: Grant
    Filed: October 5, 2007
    Date of Patent: May 17, 2011
    Assignee: Sumita Optical Glass, Inc.
    Inventor: Yoshinori Yamamoto
  • Publication number: 20110105294
    Abstract: [Problems to be Solved] To provide a high-refractivity low-dispersion optical glass that enables the stable production of high-quality optical elements. [Means to Solve the Problems] An optical glass comprising, as essential components, 20 to 50% of B3+, 5 to 35% of La3+, 1 to 30% of Nb5+, 0.5 to 15% of Ta5+, and 11 to 40% of Zn2+, the total content of B3+ and Si4+ being 20 to 50%, the total content of La3+, Gd3+ and Y3+ being 5 to 35%, the cationic ratio of ((B3++Si4+)/(La3++Gd3++Y3+)) being from 1 to 5, the total content of Ti4+, Nb5+, Ta5+ and W6+ being 10 to 35%, the cationic ratio of ((Nb5++Ta5+)/(Ti4++Nb5++Ta5++W6+)) being from 0.7 to 1, the cationic ratio of ((B3++Si4+)/(Ti4++Nb5++Ta5++W6+)) being from 0.5 to 4, the cationic ratio of ((La3++Gd3++Y3+)/(Ti4++Nb5++Ta5++W6+)) being from 0.2 to 3, the cationic ratio of Zn2+/Zn2++Mg2++Ca2++Sr2++Ba2+) being from 0.8 to 1, the optical glass having a refractive index nd of 1.89 or more and an Abbe's number ?d of 27 to 37.
    Type: Application
    Filed: September 29, 2010
    Publication date: May 5, 2011
    Applicant: HOYA CORPORATION
    Inventors: Tomoaki NEGISHI, Yasuhiro Fujiwara
  • Patent number: 7932197
    Abstract: Provided is an optical glass having high-refractivity low-dispersion properties, having a low glass transition temperature and having the property of being softened at a low temperature so that a preform therefrom is precision press-moldable, and the optical glass comprises, as essential components, B2O3, La2O3, Gd2O3 and ZnO and has a refractive index (nd) of over 1.86, an Abbe's number (?d) of less than 35 and a glass transition temperature (Tg) of 630° C. or lower.
    Type: Grant
    Filed: October 8, 2009
    Date of Patent: April 26, 2011
    Assignee: Hoya Corporation
    Inventor: Kazutaka Hayashi
  • Patent number: 7910507
    Abstract: There is provided a glass ceramic material for plasma display, in which glass fine grains (A) having a softening point of 570-640° C. are in 40-70 wt %, and glass fine grains (B) having a softening point of 480-540° C. are in 30-60 wt %, the glass ceramic material for plasma display being characterized in that the glass fine grains (A) comprise 2-12 wt % of SiO2, 50-58 wt % of B2O3, 10-20 wt % of Al2O3, 0-6 wt % of ZnO, 0-2.8 wt % of Li2O, and 10-22 wt % of at least one selected from MgO, CaO, SrO and BaO and that refractive index of the glass fine grains (A) is 1.53-1.56.
    Type: Grant
    Filed: December 20, 2007
    Date of Patent: March 22, 2011
    Assignee: Central Glass Company, Limited
    Inventors: Kazuhiro Nishikawa, Koji Tominaga
  • Publication number: 20110065564
    Abstract: The invention provides a novel optical glass which has a refractive index (nd) of 1.78 to 2.2 and an Abbe value (?d) of 16 to less than 40 and is suitable for precision mold press molding by virtue of its having a low glass transition temperature, namely, an optical glass which contains by mole in terms of oxides 25 to 60% B2O3, 2 to 45% (in total) TiO2 and Nb2O5 and 1 to 25% WO3 and has a refractive index (nd) of 1.78 to 2.2 and an Abbe value (?d) of 16 to less than 40. Further, the glass contains 5 to 35% La2O3 and 1 to 40% ZnO and has a glass transition temperature (Tg) of 700° C. or below. The optical glass is excellent in meltability, stability and devitrification resistance and has a high refractive index, high light-dispersive power and excellent precision press moldability.
    Type: Application
    Filed: October 3, 2007
    Publication date: March 17, 2011
    Inventor: Jie Fu
  • Patent number: 7855158
    Abstract: Provided is an optical glass comprising, denoted as molar percentages: 10 to 20 percent SiO2, 5 to 40 percent B2O3, SiO2+B2O3=15 to 50 percent, 0 to 10 percent Li2O, 12 to 36 percent ZnO, where 3×Li2O+ZnO?18 percent, 5 to 30 percent La2O3, 0 to 20 percent Gd2O3, 0 to 10 percent Y2O3, La2O3+Gd2O3=10 to 30 percent, La2O3/SIGMA(?)RE2O3=0.67 to 0.95 (where SIGMA(?)RE2O3=La2O3+Gd2O3+Y2O3+Yb2O3+Sc2O3+Lu2O3), 0.5 to 10 percent ZrO2, 1 to 15 percent Ta2O5, 1 to 20 percent WO3, Ta2O5/WO3?2.5 (molar ratio), 0 to 8 percent Nb2O5, 0 to 8 percent TiO2; and having a refractive index nd of not less than 1.87 and an Abbé number nu(v)d of not less than 35 but less then 40. A method for manufacturing a preform for precision press molding by separating a glass melt gob from a glass melt obtained by mixing, heating, and melting glass starting materials, and forming a preform in a glass melt gob cooling step, said mixing, heating, and melting of glass starting materials is conducted so as to obtain the above optical glass.
    Type: Grant
    Filed: January 24, 2008
    Date of Patent: December 21, 2010
    Assignee: Hoya Corporation
    Inventor: Yasuhiro Fujiwara
  • Publication number: 20100255979
    Abstract: An optical Glass characterized by comprising, denoted as molar percentages: B2O3 5 to 45 percent; Li2O 0 to 3 percent; ZnO 10 to 40 percent; La2O3 5 to 30 percent; Gd2O3 0 to 20 percent; and at least one from among TiO2, Nb2O5, WO3, and Bi2O3; in that the total content X of Ti, Nb, W, and Bi, denoted as a cation percentage, is 3 to 35 percent; in that the Abbé number v(nu)d and refractive index nd fall within the range delimited by sequentially connecting with straight lines points A, B, C, D and A in FIG. 1; and in that the glass transition temperature Tg satisfies relation (1) below: Tg[° C.]?655° C.?5×X??(1). An optical Glass characterized by comprising, denoted as molar percentages: B2O5 5 to 45 percent; SiO2 0 to 6 percent (excluding 6 percent); Li2O, Na2O, K2O in total 0 to 3 percent; ZnO 10 to 40 percent; La2O3 5 to 30 percent; Gd2O3 0 to 20 percent; and ZrO2, TaO2, TiO2, Nb2O5, 12.
    Type: Application
    Filed: May 28, 2009
    Publication date: October 7, 2010
    Applicant: Hoya Corporation
    Inventor: Yasuhiro Fujiwara
  • Patent number: 7704904
    Abstract: An optical glass contains as glass ingredients, by weight: 0-8% SiO2; 34.5-46% B2O3; 2.6-6% Li2O; 21-38% ZnO; 0-40% La2O3; 0-35% Gd2O3; and 0-15% Y2O3, with the total content of La2O3+Gd2O3+Y2O3 accounting for 10-40%. The optical glass also has a predetermined index of refraction and a predetermined dispersion.
    Type: Grant
    Filed: January 22, 2008
    Date of Patent: April 27, 2010
    Assignee: Konica Minolta Opto, Inc.
    Inventor: Akio Oogaki
  • Publication number: 20100035744
    Abstract: Provided is an optical glass having high-refractivity low-dispersion properties, having a low glass transition temperature and having the property of being softened at a low temperature so that a preform therefrom is precision press-moldable, and the optical glass comprises, as essential components, B2O3, La2O3, Gd2O3 and ZnO and has a refractive index (nd) of over 1.86, an Abbe's number (vd) of less than 35 and a glass transition temperature (Tg) of 630° C. or lower.
    Type: Application
    Filed: October 8, 2009
    Publication date: February 11, 2010
    Applicant: HOYA CORPORATION
    Inventor: Kazutaka Hayashi
  • Patent number: 7655585
    Abstract: Provided is a precision press-molding optical glass that is not easily degraded in quality by the occurrence of an altered layer such as fogging or yellowing on a surface and that comprises B2O3, ZnO, La2O3 and ZrO2 and contains, by mol %, 0 to less than 0.5% of Li2O, 20 to 50% of B2O3, 0 to 20% of SiO2, 22 to 42% of ZnO, 5 to 24% of La2O3, 0 to 20% of Gd2O3, provided that the total content of La2O3 and Gd2O3 is 10 to 24%, 0.5 to 10% of ZrO2, 0 to 15% of Ta2O5, 0 to 20% of WO3, 0 to 15% of Nb2O5, 0 to 20% of TiO2, 0 to 10% of Bi2O3, 0 to 10% of GeO2, 0 to 10% of Ga2O3, 0 to 10% of Al2O3, 0 to 10% of BaO, 0 to 10% of Y2O3 and 0 to 10% of Yb2O3, the optical glass having an Abbe's number (?d) of at least 35 but less than 40.
    Type: Grant
    Filed: August 30, 2006
    Date of Patent: February 2, 2010
    Assignee: Hoya Corporation
    Inventor: Kazutaka Hayashi
  • Patent number: 7638449
    Abstract: This invention provides an optical glass including, by mass %: 30 to 40% of B2O3; 2.5 to 6% of Li2O; 10 to 17% of ZnO; 12 to 22% of La2O3; 15 to 25% of Gd2O3; 0 to 5% of SiO2; 0 to 5% of Bi2O3; 0 to 15% of Al2O3; 0 to 3% of ZrO2; 0 to 5% of WO3; 0 to 5% of Ta2O5; 0 to 3% of TiO2; 0 to 5% of Y2O3; and 0 to 5% of MgO+CaO+SrO+BaO.
    Type: Grant
    Filed: August 15, 2008
    Date of Patent: December 29, 2009
    Assignee: Asahi Glass Company, Limited
    Inventors: Kenji Imakita, Jun Sasai, Naoki Sugimoto
  • Patent number: 7638450
    Abstract: The lead-free, fluorine-free and arsenic-free optical glass, which is useful in mapping, projection, telecommunication, optical communication engineering, and mobile drive and laser technology, has a refractive index of 1.75?nd?1.83, an Abbe number of 34?Vd?44, and Tg?560° C. The glass is free of WO3 and TeO2and has a composition in percent by weight based on oxide content of: SiO2, 0.5-8; B2O3, 10-25; ZnO, 10-22; La2O3, 23-34; Ta2O5, >15-25; Nb2O5, 0.5-15; Al2O3, 0-2; and can include optional ingredients, e.g. alkali and/or alkaline-earth oxides. In addition, a sum of B2O3 and ZnO is 33 to 41% by weight and preferably a sum of La2O3+Ta2O5+Nb2O5+Y2O3+ZrO2 is greater than 50% by weight.
    Type: Grant
    Filed: April 27, 2006
    Date of Patent: December 29, 2009
    Assignee: Schott AG
    Inventors: Simone Monika Ritter, Ute Woelfel, Stefanie Hansen
  • Patent number: 7622409
    Abstract: Provided is an optical glass having high-refractivity low-dispersion properties, having a low glass transition temperature and having the property of being softened at a low temperature so that a preform therefrom is precision press-moldable, and the optical glass comprises, as essential components, B2O3, La2O3, Gd2O3 and ZnO and has a refractive index (nd) of over 1.86, an Abbe's number (vd) of less than 35 and a glass transition temperature (Tg) of 630° C. or lower.
    Type: Grant
    Filed: January 7, 2008
    Date of Patent: November 24, 2009
    Assignee: Hoya Corporation
    Inventor: Kazutaka Hayashi
  • Patent number: 7615507
    Abstract: An optical glass having a remarkably high refractive index and excellent stability can be give without being based on PbO, and the optical glass contains, as essential components, at least one oxide selected from La2O3, Gd2O3, Y2O3, Yb2O3, TiO2, Nb2O5 or WO3, at least one oxide selected from MgO, CaO, SrO or BaO and B2O3 and optionally containing SiO2, wherein on the basis of mass, the total content of B2O3 and SiO2 is from 1 to 25%, the ratio of (B2O3+SiO2)/(La2O3+Gd2O3+Y2O3+Yb2O3+TiO2+Nb2O5+WO3) is from 0.05 to 0.3 and the ratio of (MgO+CaO+SrO+BaO)/(La2O3+Gd2O3+Y2O3+Yb2O3+TiO2+Nb2O5+WO3) is from 0.1 to 0.4, the optical glass having a refractive index (nd) of 2.000 or more and an Abbe's number (vd) of 27 or less.
    Type: Grant
    Filed: July 10, 2006
    Date of Patent: November 10, 2009
    Assignee: Hoya Corporation
    Inventor: Michio Endo
  • Patent number: 7605099
    Abstract: The optical glass has an index of refraction (nd) greater than or equal to 1.70, an Abbé number (?d) greater than or equal to 35 and a density (?) less than or equal to 4.5 g/cm3. Optical elements made with this optical glass are especially desirable in optical data transfer applications, particularly in read-write devices with movable read-write heads. The glass compositions required to make optical glass with these properties are described.
    Type: Grant
    Filed: March 23, 2004
    Date of Patent: October 20, 2009
    Assignee: Schott AG
    Inventors: Silke Wolff, Ute Woelfel, Ulrich Siepe
  • Patent number: 7582580
    Abstract: The present invention provides an optical glass including, by mass %: 46 to 70 of B2O3; 3 to 10 of Li2O; 5 to 15 of Y2O3; 0 to 46 of SiO2: 0 to 20 of Al2O3: 0 to 40 of MgO+CaO+SrO+BaO; 0 to 30 of La2O3; and 0 to 10 of ZrO2+TiO2+Gd2O3.
    Type: Grant
    Filed: August 21, 2008
    Date of Patent: September 1, 2009
    Assignee: Asahi Glass Company, Limited
    Inventors: Hiroyuki Ohkawa, Jun Sasai, Naoki Sugimoto
  • Patent number: 7576020
    Abstract: Provided is an optical glass for precision press-molding is free from degradations in product quality caused by a surface altered layer such as fogging, browning, etc., and a precision press-molding preform and an optical element provided are formed of the above glass. The optical glass is a glass which contains B2O3, La2O3 and ZnO and is used as a glass material for precision press-molding, and contains, by mol %, 20 to 60% of B2O3, 0 to 20% of SiO2, 22 to 42% of ZnO, 5 to 24% of La2O3, 0 to 20% of Gd2O3, provided that the total content of La2O3 and Gd2O3 is 10 to 24%, 0 to 10% of ZrO2, 0 to 10% of Ta2O5, 0 to 10% of WO3, 0 to 10% of Nb2O5, 0 to 10% of TiO2, 0 to 10% of Bi2O3, 0 to 10% of GeO2, 0 to 10% of Ga2O3, 0 to 10% of Al2O3, 0 to 10% of BaO, 0 to 10% of Y2O3 and 0 to 10% of Yb2O3, has an Abbe's number (?d) of 40 or more and is substantially free of lithium.
    Type: Grant
    Filed: October 11, 2005
    Date of Patent: August 18, 2009
    Assignee: Hoya Corporation
    Inventor: Kazutaka Hayashi
  • Patent number: 7572747
    Abstract: An optical glass consisting essentially of B2O3 in an amount of 10-40 wt %, SiO2 in an amount less than or equal to 5 wt %, ZnO in an amount less than or equal to 15 wt %, SrO in an amount less than or equal to 9 wt %, ZrO2 in an amount less than or equal to 9 wt %, La2O3 in an amount of 15 to 45 wt %, BaF2 in an amount of 1 to 10 wt %, BaO in an amount less than or equal to 5 wt %, HfO2 in an amount of 0.1 to 7.5 wt %, Gd2O3 in an amount less than or equal to 16 wt %, CaO in an amount less than or equal to 7 wt %, ZrF4 in an amount less than or equal to 5 wt %, Na2O in an amount less than or equal to 2 wt % and Y2O3 in an amount less than or equal to 16 wt %. The optical glass has a glass transition temperature in a range of 500-670° C. and a refractive index (nd) in a range of 1.60 to 2.00.
    Type: Grant
    Filed: September 26, 2008
    Date of Patent: August 11, 2009
    Assignees: Alfred University, Kyocera Corporation
    Inventors: Alexis G. Clare, Tatsuji Furuse, Matthew Hall
  • Publication number: 20090197754
    Abstract: Provided is an optical glass having optical constants, a refractive index (nd) of more than 1.9 and an Abbe number (?d) of not more than 38, having a small partial dispersion ratio and capable of being produced from inexpensive materials. The optical glass has a partial dispersion ratio (?g, F) of at most 0.615, and contains, as indispensable ingredients, B203, La2O3, TiO2, Nb2O5 and Ta2O5, wherein the ratio, as % by mass, of TiO2/Nb2O5 is at most 0.26 and GeO2/Nb2O5 is at most 0.38. The optical glass contains, in terms of % by mass, the following ingredients: B2O3 ??5 to 22%, La2O3 ??15 to 50%, TiO2 0.01 to 15%, Nb2O5 ??5 to 40%, and Ta2O5 ?0.1 to 25%, and SiO2 0 to 10% and/or GeO2 0 to 10% and/or Al2O3 0 to 10% and/or Gd2O3 0 to 16% and/or ZrO2 0 to 15% and/or WO3 0 to 22% and/or Sb2O3 0 to 1%.
    Type: Application
    Filed: January 29, 2009
    Publication date: August 6, 2009
    Applicant: OHARA INC.
    Inventors: Susumu UEHARA, Kiyoyuki Momono
  • Patent number: 7563736
    Abstract: An optical glass which has an internal transmittance to a light having a wavelength of 400 nm being at least 90% as calculated in a thickness of 1 mm and which contains at least 25 mol % of B2O3 and from 0.1 to 20 mol % of TeO2. The above optical glass which contains La2O3. The above optical glass wherein the glass transition point ?650° C. and the refractive index at 633 nm?1.70. A process for producing an optical element made of the above optical glass, which comprises dropping the optical glass in a molten state from a flow outlet of a flow out pipe made of a platinum alloy to form a preform and subjecting it to precision press-molding.
    Type: Grant
    Filed: April 26, 2006
    Date of Patent: July 21, 2009
    Assignee: Asahi Glass Company, Limited
    Inventors: Tomoyuki Kobayashi, Jun Sasai, Syuji Matsumoto, Naoki Sugimoto
  • Patent number: 7524781
    Abstract: A non-lead optical glass consisting essentially of, as represented by mol %, from 45 to 75% of Bi2O3, from 12 to 45% of B2O3, from 1 to 20% of Ga2O3, from 1 to 20% of In2O3, from 0 to 20% of ZnO, from 0 to 15% of BaO, from 0 to 15% of SiO2+Al2O3+GeO2, from 0 to 15% of MgO+CaO+SrO, from 0 to 10% of SnO2+TeO2+TiO2+ZrO2+Ta2O3+Y2O3+WO3 and from 0 to 5% of CeO2, wherein Ga2O3+In2O3+ZnO?5%. An optical fiber comprising the above non-lead optical glass as a core.
    Type: Grant
    Filed: December 20, 2005
    Date of Patent: April 28, 2009
    Assignee: Asahi Glass Company, Limited
    Inventors: Tatsuo Nagashima, Naoki Sugimoto, Seiki Ohara, Tomoharu Hasegawa
  • Patent number: 7514381
    Abstract: To provide an optical glass which has a high transmittance and a high refractive index and shows little decrease in the transmitted light intensity when continuously irradiated with a blue-violet laser diode light, and which is less prone to a higher melting temperature and exhibits chemical durability being not low. An optical glass consisting essentially of, as represented by mol %, from 35 to 54% of TeO2, from 0 to 10% of GeO2, from 5 to 30% of B2O3, from 0 to 15% of Ga2O3, from 0 to 8% of Bi2O3, from 3 to 20% of ZnO, from 0 to 10% of MgO+CaO+SrO+BaO, from 1 to 10% of Y2O3+La2O3+Gd2O3, from 0 to 5% of Ta2O5+Nb2O5, from 0 to 1.8% of TiO2, and from 0 to 6% of Li2O+Na2O+K2O+Rb2O+Cs2O. A lens made of such an optical glass.
    Type: Grant
    Filed: December 26, 2006
    Date of Patent: April 7, 2009
    Assignee: Asahi Glass Company, Limited
    Inventors: Syuji Matsumoto, Jun Sasai, Naoki Sugimoto
  • Patent number: 7501369
    Abstract: An optical glass having high-refractivity and low-dispersion optical properties and having a low glass transition point so that a heat-treating furnace can be operated for a long period of time. The optical glass has a refractive index nd of at least 1.875, an Abbe's number ?d of at least 39.5 and a glass transition point Tg of 700° C. or lower, and contains at least one of La2O3, Gd2O3, Y2O3 or Yb2O3 and at least one of ZrO2, Ta2O5 or Nb2O5, with a weight ratio of the total content of La2O3, Gd2O3, Y2O3 and Yb2O3 to the total content of SiO2 and B2O3 of from 3.2 to 5 and the weight ratio of the total content of ZrO2, Ta2O5 and Nb2O5 to the total content of SiO2 and B2O3 is from 1.1 to 1.5.
    Type: Grant
    Filed: July 16, 2007
    Date of Patent: March 10, 2009
    Assignee: Hoya Corporation
    Inventor: Kazuo Tachiwana
  • Patent number: 7490485
    Abstract: An optical glass whose refractive index is high and whose coloring is decreased comprising, by weight %, 2 to 45% of B2O3, 0 to 30% of SiO2 provided that the content of B2O3>the content of SiO2, 10 to 50% of La2O3, 0 to 30% of TiO2, 0 to 15% of ZnO, 0 to 15% of ZrO2, 0 to 35% of Nb2O5, 0 to 35% of BaO, 0 to 5% of SrO, 0% or more but less than 8% of CaO, 0% or more but less than 13% of MgO, provided that the total content of BaO, SrO, CaO and MgO is 0 to 40%, 0 to 20% of Gd2O3, 0 to 15% of Y2O3, 0 to 18% of Ta2O5, 0% or more but less than 0.5% of WO3, 0% or more but less than 1.5% of a total of Na2O, K2O and Li2O, 0 to 10% of GeO2, 0 to 20% of Bi2O3, 0 to 10% of Yb2O3, 0 to 10% of Al2O3, 0% or more but less than 2% of Sb2O3 and 0 to 1% of SnO2.
    Type: Grant
    Filed: April 9, 2008
    Date of Patent: February 17, 2009
    Assignee: Hoya Corporation
    Inventor: Michio Endo
  • Patent number: 7491667
    Abstract: Provided are optical glasses having a refractive index (nd) of over 1.82 but not more than 1.86 and an Abbe's number (?d) of 30 to 39.5 and having the property of low-temperature softening that permits precision press-molding, one is an optical glass comprising B2O3, La2O5, Gd2O3 and ZnO as essential components, comprising Li2O and SiO2 as optional components, provided that the content of SiO2 is less than 2% by weight when Li2O is contained, having a refractive index (nd) of over 1.82 but not more than 1.86 and an Abbe's number (?d) of 30 to 39.5 and having a glass transition temperature (Tg) of 630° C. or lower, and the other is an optical glass comprising, by % by weight, 14 to 30% of B2O3, 10 to 40% of La2O3, 1 to 30% of Gd2O3 and 6 to 26% of ZnO as essential components, and comprising, as optional components, predetermined amounts of WO3, Ta2O5, Nb2O5, TiO2, SiO2, Li2O, Na2O, K2O, MgO, CaO, SrO, BaO, Y2O3, Yb2O3, ZrO2, Bi2O3 and Sb2O3 and having a refractive index (nd) of over 1.82 but not more than 1.
    Type: Grant
    Filed: March 17, 2005
    Date of Patent: February 17, 2009
    Assignee: Hoya Corporation
    Inventor: Kazutaka Hayashi
  • Publication number: 20090018006
    Abstract: A glass composition satisfying the following conditions (A) to (L), the conditions are: (A) a content ratio of TeO2 is in a range from 50 to 95 mol %; (B) a content ratio of B2O3 is in a range from 1 to 33 mol %; (C) a content ratio of ZnO is in a range from 1 to 37 mol %; (D) a content ratio of Bi2O3 is in a range from 1 to 18 mol %; (E) a content ratio of P2O5 is in a range from 0 to 15 mol %; (F) a content ratio of R2O (where R represents at least one element selected from the group consisting of Li, Na, and K) is in a range from 0 to 13 mol %; (G) a content ratio of MO (where M represents at least one element selected from the group consisting of Mg, Ca, Sr, and Ba) is in a range from 0 to 13 mol %; (H) a content ratio of TiO2 is in a range from 0 to 13 mol %; (I) a content ratio of Nb2O5 is in a range from 0 to 10 mol %; (J) a content ratio of Ta2O5 is in a range from 0 to 13 mol %; (K) a content ratio of L2O3 (where L represents at least one element selected from the group consisting of yttrium and lant
    Type: Application
    Filed: June 24, 2008
    Publication date: January 15, 2009
    Applicant: NIKON CORPORATION
    Inventors: Motoi Ueda, Takashi Ozawa, Kiyoaki Shinohara
  • Publication number: 20080318758
    Abstract: This invention provides an optical glass including, by mass %: 30 to 40% of B2O3; 2.5 to 6% of Li2O; 10 to 17% of ZnO; 12 to 22% of La2O3; 15 to 25% of Gd2O3; 0 to 5% of SiO2; 0 to 5% of Bi2O3; 0 to 15% of Al2O3; 0 to 3% of ZrO2; 0 to 5% of WO3; 0 to 5% of Ta2O5; 0 to 3% of TiO2; 0 to 5% of Y2O3; and 0 to 5% of MgO+CaO+SrO+BaO.
    Type: Application
    Filed: August 15, 2008
    Publication date: December 25, 2008
    Applicant: ASAHI GLASS COMPANY, LIMITED
    Inventors: Kenji IMAKITA, Jun Sasai, Naoki Sugimoto
  • Patent number: 7468338
    Abstract: A high-refractivity low-dispersion optical glass that gives press-molding preforms excellent in high-temperature shapability and suitable for precision press-molding, including an optical glass comprising B2O3, La2O3, Gd2O3 and ZnO as essential components, substantially containing none of lead and fluorine, having a refractive index (nd) of 1.72 to 1.83, an Abbe's number (?d) of 45 to 55 and a glass transition temperature (Tg) of 630° C. or lower and having a viscosity of at least 0.6 Pa·s at its liquidus temperature, and an optical glass comprising, by mol %, 45 to 65% of B2O3, 5 to 22% of La2O3, 1 to 20% of Gd2O3, provided that the total content of La2O3 and Gd2O3 is 14 to 30%, 5 to 30% of ZnO, 0 to 10% of SiO2, 0 to 6.5% of ZrO2 and 0 to 1% of Sb2O3, substantially containing none of lead and fluorine, and having a refractive index (nd) of 1.72 to 1.83 and an Abbe's number (?d) of 45 to 55.
    Type: Grant
    Filed: September 21, 2007
    Date of Patent: December 23, 2008
    Assignee: Hoya Corporation
    Inventors: Kazutaka Hayashi, Yasuhiro Fujiwara, Zou Xuelu
  • Publication number: 20080312063
    Abstract: The present invention provides an optical glass including, by mass %: 46 to 70 of B2O3; 3 to 10 of Li2O; 5 to 15 of Y2O3; 0 to 46 of SiO2: 0 to 20 of Al2O3: 0 to 40 of MgO+CaO+SrO+BaO; 0 to 30 of La2O3; and 0 to 10 of ZrO2+TiO2+Gd2O3.
    Type: Application
    Filed: August 21, 2008
    Publication date: December 18, 2008
    Applicant: ASAHI GLASS CO., LTD.
    Inventors: Hiroyuki OHKAWA, Jun Sasai, Naoki Sugimoto
  • Publication number: 20080207428
    Abstract: The present claimed invention intends to provide a responsive glass membrane for ion selective electrode glass and an ion selective electrode comprising the responsive glass membrane that produces a self-cleaning function when the ultraviolet rays are irradiated although no change is brought in a composition of a sample solution as being an object to be measured and that is low in electric resistance value and superior in responsivity under an ordinary measurement environment. The responsive glass membrane for ion selective electrode is made of the titanium-containing oxide glass that contains 20˜80 mol % of titanium dioxide and lithium oxide.
    Type: Application
    Filed: February 26, 2008
    Publication date: August 28, 2008
    Inventors: Yuji Nishio, Yasukazu Iwamoto, Tadanori Hashimoto
  • Publication number: 20080167172
    Abstract: Provided is an optical glass having high-refractivity low-dispersion properties, having a low glass transition temperature and having the property of being softened at a low temperature so that a preform therefrom is precision press-moldable, and the optical glass comprises, as essential components, B2O3, La2O3, Gd2O3 and ZnO and has a refractive index (nd) of over 1.86, an Abbe's number (vd) of less than 35 and a glass transition temperature (Tg) of 630° C. or lower.
    Type: Application
    Filed: January 7, 2008
    Publication date: July 10, 2008
    Applicant: HOYA CORPORATION
    Inventor: Kazutaka Hayashi
  • Publication number: 20080119345
    Abstract: A ceramic substrate composition is provided which can be co-fired with a low-melting metal and exhibits excellent dielectric characteristics at high frequencies, particularly tens of gigahertz. The ceramic substrate composition mainly contains a glass represented by aB2O3-bRe2O3-cZnO, wherein the molar ratios (a, b, and c) fall within a region defined in a ternary composition diagram by Point A (0.4, 0.595, 0.005), Point B (0.4, 0.25, 0.35), Point C (0.52, 0.01, 0.47), Point D (0.9, 0.005, 0.095), and Point E (0.9, 0.09, 0.01).
    Type: Application
    Filed: December 12, 2007
    Publication date: May 22, 2008
    Applicant: MURATA MANUFACTURING CO., LTD.
    Inventors: Takahiro Takada, Hirobumi Yamamoto, Keisuke Kageyama
  • Patent number: 7332453
    Abstract: Ceramics (including glasses and glass-ceramics) comprising nitrogen, and methods of making the same.
    Type: Grant
    Filed: July 29, 2004
    Date of Patent: February 19, 2008
    Assignee: 3M Innovative Properties Company
    Inventors: Anatoly Z. Rosenflanz, Berkan K. Endres, Thomas J. Anderson
  • Patent number: 7314841
    Abstract: A ceramic composition includes a glass composition and a filler including at least one of Al2O3 and TiO2, wherein the composition of the ceramic composition includes 0.15 to 0.55 mol of a, 0.45 to 0.85 mol of b, 0.01 to 0.2 mol of an oxide RO of an alkaline earth metal element R, and 0.1 to 0.4 mol of the filler, wherein a represents a molar quantity of an oxide Ln2O3 of a rare earth element Ln, b represents a molar quantity of boron oxide B2O3, and a+b=1 mol.
    Type: Grant
    Filed: May 14, 2004
    Date of Patent: January 1, 2008
    Assignee: Murata Manufacturing Co., Ltd.
    Inventor: Takahiro Takada
  • Patent number: 7297646
    Abstract: Ceramics comprising (i) at least one of Nb2O5 or Ta2O5 and (ii) at least two of (a) Al2O3, (b) REO, or (c) at least one of ZrO2 or HfO2. Embodiments of ceramics according to the present invention can be made, formed as, or converted into optical waveguides, glass beads, articles (e.g., plates), fibers, particles (e.g., abrasive particles), and thin coatings.
    Type: Grant
    Filed: September 25, 2006
    Date of Patent: November 20, 2007
    Assignee: 3M Innovative Properties Company
    Inventors: Anatoly Z. Rosenflanz, Craig R. Schardt
  • Publication number: 20070225148
    Abstract: A high-refractivity optical glass which has both a low-temperature softening property suitable for precision press-molding and glass stability suitable for hot-shaping of a preform, which contains, by mass %, 13 to 30% of B2O3, 0.1 to 4% of Li2O, 17 to 35% of ZnO, 15 to 45% of La2O3, 4 to 15% of Ta2O5 exclusive of 15%, 0 to 10% of ZrO2, 0 to 10% of Nb2O5 provided that Ta2O5/(Ta2O5+ZrO2+Nb2O5)>0.3, 0 to 20% of WO3 and 0 to 1% of Sb2O3 and which has a refractive index (nd) of 1.80 to 1.84 and an Abbe's number (vd) of 40.0 to 45.0.
    Type: Application
    Filed: March 13, 2007
    Publication date: September 27, 2007
    Inventors: Kazutaka Hayashi, Yasuhiro Fujiwara
  • Patent number: 7232779
    Abstract: Provided are optical glass exhibiting a refractive index (nd) in a range of 1.75 to 1.87, an Abbé number (?d) in a range of 80 to 45, and excellent low-temperature softening properties even when not incorporating Th2O5 as well as permitting a low production cost; a precision press molding preform and an optical element comprised of such glass; a method of manufacturing the preform; and a method of manufacturing the optical element. The optical glass comprises, in a molar percent, 30 to 45 percent of B2O3, 2 to 15 percent of SiO2, 10 to 20 percent of La2O3, 1 to 10 percent of TiO2, 10 to 30 percent of ZnO, 2 to 15 percent of Li2O, higher than 0 percent and 10 percent or less of WO3, 0 to 15 percent of Nb2O5, and 0 to 10 percent of ZrO2, wherein the total amount of the above-mentioned components is higher than 95 percent, the glass exhibits a refractive index (nd) in a range of 1.75 to 1.87, and an Abbé number (?d) in a range of 80 to 45.
    Type: Grant
    Filed: August 20, 2003
    Date of Patent: June 19, 2007
    Assignee: Hoya Corporation
    Inventors: Yoshiko Kasuga, Xuelu Zou