Fluorine Patents (Class 501/57)
-
Patent number: 11890833Abstract: A laminate glass-ceramic article is provided that includes: a core glass layer having a first coefficient of thermal expansion (CTE); and a plurality of clad glass-ceramic layers, each having a CTE that is lower than or equal to the first CTE of the core glass layer. A first of the clad glass-ceramic layers is laminated to a first surface of core glass layer and a second of the clad glass-ceramic layers is laminated to a second surface of the core glass layer. Further, a total thickness of the plurality of clad glass-ceramic layers is from about 0.05 mm to about 0.5 mm. In addition, each of the glass-ceramic layers includes: an alumino-boro-silicate glass, 0 mol %?MoO3?15 mol %, and 0 mol %?WO3?15 mol %, the WO3 (mol %) plus the MoO3 (mol %) is from 0.7 mol % to 19 mol %.Type: GrantFiled: May 2, 2022Date of Patent: February 6, 2024Assignee: CORNING INCORPORATEDInventors: Matthew John Dejneka, Jesse Kohl
-
Patent number: 11731901Abstract: The purpose of the present invention is to provide a chemically strengthened glass having excellent transparency and strength and being scratch resistant. The present invention pertains to a chemically strengthened glass that: has a compressive stress layer on the surface thereof; has a visible light transmittance of at least 70% when the thickness thereof is converted to 0.8 mm; has a surface compressive stress of at least 600 MPa; has a compressive stress depth of at least 80 ?m; and contains a ?-spodumene.Type: GrantFiled: January 21, 2020Date of Patent: August 22, 2023Assignee: AGC Inc.Inventors: Qing Li, Kenji Imakita, Akio Koike, Eriko Maeda
-
Patent number: 11476634Abstract: A rare earth-doped optical fiber comprises a fluorosilicate core surrounded by a silica cladding, where the fluorosilicate core comprises an alkaline-earth fluoro-alumino-silicate glass, such as a strontium fluoro-alumino-silicate glass. The rare earth-doped optical fiber may be useful as a high-power fiber laser and/or fiber amplifier. A method of making a rare earth-doped optical fiber comprises: inserting a powder mixture comprising YbF3, SrF2, and Al2O3 into a silica tube; after inserting the powder mixture, heating the silica tube to a temperature of at least about 2000° C., some or all of the powder mixture undergoing melting; drawing the silica tube to obtain a reduced-diameter fiber; and cooling the reduced-diameter fiber. Thus, a rare earth-doped optical fiber comprising a fluorosilicate core surrounded by a silica cladding is formed.Type: GrantFiled: May 7, 2019Date of Patent: October 18, 2022Assignees: THE BOARD OF TRUSTEES OF THE UNIVERSITY OF ILLINOIS, CLEMSON UNIVERSITYInventors: Peter Dragic, John Ballato, Maxime Cavillon
-
Patent number: 11104608Abstract: Ion-exchanged glass ceramic articles described herein have a stress that decreases with increasing distance according to a substantially linear function from a depth of about 0.07 t to a depth of about 0.26 t from the outer surface of the ion-exchanged glass ceramic article from a compressive stress to a tensile stress. The stress transitions from the compressive stress to the tensile stress at a depth of from about 0.18 t to about 0.25 t from the outer surface of the ion-exchanged glass ceramic article. An absolute value of a maximum compressive stress at the outer surface of the ion-exchanged glass article is from 1.8 to 2.2 times an absolute value of a maximum central tension (CT) of the ion-exchanged glass article, and the glass ceramic article has a fracture toughness of 1 MPa?m or more as measured according to the double cantilever beam method.Type: GrantFiled: November 13, 2019Date of Patent: August 31, 2021Assignee: Corning IncorporatedInventors: Ryan Claude Andrews, Albert Joseph Fahey, Lisa Marie Noni, Rostislav Vatchev Roussev, Charlene Marie Smith, Ljerka Ukrainczyk, Shelby Kerin Wilson
-
Patent number: 10962502Abstract: A hydrogen detector for gas and fluid media is disclosed. The detector includes a selective membrane and a housing. Within the housing is a potential measuring unit and a ceramic sensing element made of a solid electrolyte. A standard electrode is located within a cavity of the ceramic sensing element and a porous platinum electrode is applied to an external layer of the ceramic sensing element. A potential measuring unit passes through a sealed lead-in at the upper end of the housing and is brought out to the standard electrode. The selective membrane, which is attached to a hole in the end of the lower bushing, is closed with a plug. The cavity limited by the inner surface of the lower bushing, the external part of the bottom of the ceramic sensing element and the inner surfaces of the selective membrane and the plug is leak-tight.Type: GrantFiled: November 16, 2015Date of Patent: March 30, 2021Assignee: JOINT STOCK COMPANY “AKME-ENGINEERING”Inventors: Petr Nikiforovich Martynov, Mi hail Efimovich Chernov, Alexsey Nikolaevich Storozhenko, Vasiliy Mikhaylovich Shelemet'Ev, Roman Petrovich Sadovnichiy
-
Patent number: 10703670Abstract: The invention relates to a process for producing alkali metal-rich aluminosilicate glasses having a content (in mol % based on oxide) of alkali metal oxides of 4-16 mol %, of Al2O3 of at least 4 mol % and of B2O3 of 0-4 mol %, wherein 0.15 mol % to 0.9 mol % of chloride(s) and at least one refining agent from the group of sulfate(s) (reported as SO3), CeO2 are added to the glass batch and wherein the sum total of refining agents added in the batch is 0.17 mol % to 1.3 mol %.Type: GrantFiled: February 21, 2018Date of Patent: July 7, 2020Assignee: SCHOTT AGInventors: Christof Kass, Rainer Eichholz
-
Patent number: 10640416Abstract: The present invention relates to an alkali-free glass substrate, having a difference ?n between the maximum value and the minimum value of a refractive index at a cross-section of a glass sheet of 0.40×10?5 or less. According to the alkali-free glass substrate of the present invention, the polishing ability can be extremely improved and the polishing time is shortened, so that the production efficiency can be improved.Type: GrantFiled: March 27, 2018Date of Patent: May 5, 2020Assignee: AGC INC.Inventors: Kenta Saito, Daisuke Kobayashi
-
Patent number: 10421568Abstract: A horn and an anvil are moved toward and away from each other by axially reciprocating a driving rod and thereby reciprocatingly rotating a forked lever in a predetermined angle range. The horn and the anvil are moved toward and pressed against each other with a predetermined force with a bag mouth b held therebetween. A sensor detects the position of a second mounting block secured to the rear end of a sliding shaft of the anvil, thereby detecting the distance between respective pressing surfaces of the horn and the anvil, i.e. the thickness m of a portion of the bag mouth held between the pressing surfaces. When the thickness m is not less than a predetermined threshold value M, a vibrator is activated to perform sealing. When the thickness m is less than the threshold value M, no sealing is performed.Type: GrantFiled: October 10, 2017Date of Patent: September 24, 2019Assignee: Toyo Jidoki Co., LtdInventors: Kazunori Yamamoto, Yasuyuki Honda, Noriyuki Yamane
-
Patent number: 9701570Abstract: Opal glass compositions and glass articles comprising the same are disclosed. In one embodiment, a glass composition includes 55 mol. % to 70 mol. % SiO2 and 9 mol. % to 15 mol. % Al2O3 as glass network formers. The glass composition also includes 10 mol. % to 15 mol. % alkali oxide M2O, wherein M is at least one of Na and K. The glass composition also includes 2 mol. % to 8 mol. % divalent oxide RO, wherein R is at least one of Zn, Ca, and Mg. As an opalizing agent, the glass composition may also include 8.5 mol. % to 16 mol. % F?. The glass composition may also include 0 mol. % to 0.3 mol. % SnO2 as a fining agent and from about 0 mol. % to about 6 mol. % of colorant. The glass composition is free from As and compounds containing As.Type: GrantFiled: February 27, 2013Date of Patent: July 11, 2017Assignee: Corning IncorporatedInventors: John Christopher Mauro, Morten Mattrup Smedskjaer, Natesan Venkataraman
-
Patent number: 9650288Abstract: The present invention relates to an aqua blue glass composition having a base composition of a soda-lime-silica glass having as main coloring agents total iron, expressed as Fe2O3 in the range of 0.30 to 0.60% by weight with a ratio of ferrous (redox) in the range of 20 to 30; FeO in the range of 0.06 to 0.18% by weight; TiO2 in the range of 0.025 to 1.0% by weight; Co3O4 expressed in the range of 5 to 30% ppm; Se expressed in the range of 0.1 to 10 ppm; CuO in the range of 0 to 400 ppm; and Cr2O3 in the range of 10 to 20 ppm. The glass provides light transmittance, illuminant “A”, greater than 50%, a dominant wavelength (?) of 487 nm to 498 nm; a solar energy transmittance of less than or equal to 64.4%; an ultraviolet solar transmittance no more than 51.6%; and an excitation purity less than 12 for glass thicknesses from 4 to 12 mm.Type: GrantFiled: December 19, 2013Date of Patent: May 16, 2017Assignee: Vidrio Plano de Mexico, S.A. de C.V.Inventors: Jose Guadalupe Cid-Aguilar, Roberto Marcos Cabrera-Llanos, Jose Luis Tavares-Cortes
-
Patent number: 9470614Abstract: A chemically strengthened glass is disposed on a base, and an impacting object is dropped from above in a state where one surface of the chemically strengthened glass is in contact with an abrasive surface of a sandpaper containing an abrasive having a size of not smaller than a depth of a compressive stress layer.Type: GrantFiled: February 4, 2014Date of Patent: October 18, 2016Assignee: ASAHI GLASS COMPANY, LIMITEDInventors: Hiroyuki Okawa, Kazuhiko Yamanaka
-
Publication number: 20150045201Abstract: The present invention relates to a non-alkali glass having a strain point of 710° C. or higher, an average thermal expansion coefficient at from 50 to 300° C. of from 30×10?7 to 43×10?7/° C., a temperature T2 at which glass viscosity reaches 102 dPa·s of 1,710° C. or lower, a temperature T4 at which the glass viscosity reaches 104 dPa·s of 1,320° C. or lower, containing, indicated by percentage by mass on the basis of oxides, SiO2 58.5 to 67.5, Al2O3 18 to 24, B2O3 0 to 1.7, MgO 6.0 to 8.5, CaO 3.0 to 8.5, SrO 0.5 to 7.5, BaO 0 to 2.5 and ZrO2 0 to 4.0, containing Cl in an amount of from 0.15 to 0.35% by mass, F in an amount of from 0.01 to 0.15% by mass and SO3 in an amount of from 1 to 25 ppm and having a ?-OH value of the glass of from 0.15 to 0.45 mm?1, in which (MgO/40.3)+(CaO/56.1)+(SrO/103.6)+(BaO/153.3) is from 0.27 to 0.35, (MgO/40.3)/((MgO/40.3)+(CaO/56.1)+(SrO/103.6)+(BaO/153.3)) is 0.40 or more, (MgO/40.3)/((MgO/40.3)+(CaO/56.1)) is 0.40 or more, and (MgO/40.3)/((MgO/40.3)+(SrO/103.6)) is 0.Type: ApplicationFiled: October 27, 2014Publication date: February 12, 2015Applicant: ASAHI GLASS COMPANY, LIMITEDInventors: Hirofumi TOKUNAGA, Shingo Urata, Akio Koike, Manabu Nishizawa, Takashi Enomoto, Tomoyuki Tsujimura
-
Publication number: 20150038315Abstract: To provide a method for producing chemically tempered glass, whereby frequency of replacement of the molten salt can be reduced. A method for producing chemically tempered glass, which comprises repeating ion exchange treatment of immersing glass in a molten salt, wherein the glass comprises, as represented by mole percentage, from 61 to 77% of SiO2, from 1 to 18% of Al2O3, from 3 to 15% of MgO, from 0 to 5% of CaO, from 0 to 4% of ZrO2, from 8 to 18% of Na2O and from 0 to 6% of K2O; SiO2+Al2O3 is from 65 to 85%; MgO+CaO is from 3 to 15%; and R calculated by the following formula by using contents of the respective components, is at least 0.66: R=0.029×SiO2+0.021×Al2O3+0.016×MgO?0.004×CaO+0.016×ZrO2+0.029×Na2O+0×K2O?2.Type: ApplicationFiled: October 21, 2014Publication date: February 5, 2015Applicant: Asahi Glass Company, LimitedInventors: Jun Endo, Shusaku Akiba, Kazutaka Ono, Shigeki Sawamura
-
Publication number: 20150010739Abstract: Opal glass compositions and glass articles comprising the same are disclosed. In one embodiment, a glass composition includes 55 mol. % to 70 mol. % SiO2 and 9 mol. % to 15 mol. % Al2O3 as glass network formers. The glass composition also includes 10 mol. % to 15 mol. % alkali oxide M2O, wherein M is at least one of Na and K. The glass composition also includes 2 mol. % to 8 mol. % divalent oxide RO, wherein R is at least one of Zn, Ca, and Mg. As an opalizing agent, the glass composition may also include 8.5 mol. % to 16 mol. % F?. The glass composition may also include 0 mol. % to 0.3 mol. % SnO2 as a fining agent and from about 0 mol. % to about 6 mol. % of colorant. The glass composition is free from As and compounds containing As.Type: ApplicationFiled: February 27, 2013Publication date: January 8, 2015Inventors: John Christopher Mauro, Morten Mattrup Smedskjaer, Natesan Venkataraman
-
Patent number: 8889575Abstract: Ion exchangeable glass articles are disclosed. In one embodiment, a glass article formed from alkali aluminosilicate glass which may include Ga2O3, Al2O3, Na2O, SiO2, B2O3, P2O5 and various combinations thereof. The glass article may generally include about X mol % of Ga2O3 and about Z mol % of Al2O3, wherein 0?X?20, 0?Z?25 and 10?(X+Z)?25. The glass article may also include from about 5 mol % to about 35 mol % Na2O, SiO2 may be present in an amount from about 40 mol % to about 70 mol % SiO2. The glass article may further include Y mol % B2O3 where Y is from 0 to about 10. The glass article may further include (10-Y) mol % of P2O5. Glass articles formed according to the present invention may be ion-exchange strengthened. In addition, the glass articles may have a low liquid CTE which enables the glass articles to be readily formed into complex shapes.Type: GrantFiled: May 31, 2011Date of Patent: November 18, 2014Assignee: Corning IncorporatedInventors: Heather Debra Boek, Mark Owen Weller, Randall Eugene Youngman
-
Patent number: 8846555Abstract: Disclosed are silica and fluoride doped lead-bismuth-gallium heavy metal oxide glasses for visible to mid-wave Infrared Radiation transmitting optics and preparation thereof.Type: GrantFiled: June 25, 2012Date of Patent: September 30, 2014Assignee: Schott CorporationInventors: Simi George, Sally Pucilowski
-
Publication number: 20140155246Abstract: The present disclosure is directed to a doped silica-titania glass, DST glass, consisting essentially of 0.1 wt. % to 5 wt. % halogen, 50 ppm-wt. to 6 wt. % one or more oxides of Al, Ta and Nb, 3 wt. % to 10 wt. % TiO2 and the remainder SiO2. In an embodiment the halogen content can be in the range of 0.2 wt. % to 3 wt. % along with 50 ppm-wt. to 6 wt. % one or more oxides of Al, Ta and Nb, 3 wt. % to 10 wt. % TiO2 and the remainder SiO2. In an embodiment the DST glass has an OH concentration of less than 100 ppm. In another embodiment the OH concentration is less than 50 ppm. The DST glass has a fictive temperature Tf of less than 875° C. In an embodiment Tf is less than 825° C. In another embodiment Tf is less than 775° C.Type: ApplicationFiled: March 15, 2013Publication date: June 5, 2014Applicant: CORNING INCORPORATEDInventors: Sezhian Annamalai, Carlos Alberto Duran, Kenneth Edward Hrdina
-
Publication number: 20130344312Abstract: Disclosed are silica and fluoride doped lead-bismuth-gallium heavy metal oxide glasses for visible to mid-wave Infrared Radiation transmitting optics and preparation thereof.Type: ApplicationFiled: June 25, 2012Publication date: December 26, 2013Applicant: SCHOTT NORTH AMERICA, INC.Inventors: Simi GEORGE, Sally Pucilowski
-
Publication number: 20130296157Abstract: Described herein are alkali-free, boroalumino silicate glasses exhibiting desirable physical and chemical properties for use as substrates in flat panel display devices, such as, active matrix liquid crystal displays (AMLCDs) and active matrix organic light emitting diode displays (AMOLEDs). In accordance with certain of its aspects, the glasses possess good dimensional stability as a function of temperature. The glasses comprise in mol percent on an oxide basis: 70-74.5 SiO2, 10.5-13.5 AL2O3, 0-2.5 B2O3, 3-7 MgO, 3-7 CaO, 0-4 SrO, 1.5-6 BaO, 0-0.3 SnO2, 0-03 CeO2, 0-0.5 As2O3, 0-0.5 Sb2O3, 0.01-0.08 Fe2O3 and F+Cl+BrRO/Al2O31.7 and 0.2MgO/RO0.45, RO being the sum of MgO, BaO, SrO and CaO.Type: ApplicationFiled: January 25, 2012Publication date: November 7, 2013Inventors: Adam J. Ellison, Timothy J. Kiczenski
-
Patent number: 8546283Abstract: The present invention relates to a substrate for EUV lithography optical member, comprising a silica glass containing TiO2, in which the substrate has two opposite surfaces, and the substrate has temperatures at which a coefficient of linear thermal expansion (CTE) is 0 ppb/° C. (Cross-Over Temperature: COT), and in which the two opposite surfaces have difference in the COTs of 5° C. or more.Type: GrantFiled: June 25, 2012Date of Patent: October 1, 2013Assignee: Asahi Glass Company, LimitedInventors: Junko Miyasaka, Akio Koike, Tomonori Ogawa
-
Publication number: 20130209751Abstract: An alkali aluminosilicate glass for 3D precision molding and thermal bending is provided. The glass has a working point lower than 1200° C. (104 dPas) and a transition temperature Tg lower than 610° C. The glass has, based on a sum of all the components in percentage by weight, 51-63% of Si02; 5-18% of Al203; 8-16% of Na20; 0-6% of K20; 3.5-10% of MgO; 0-5% of B203; 0-4.5% of Li20; 0-5% of ZnO; 0-8% of CaO; 0.1-2.5% of Zr02; 0.01-<0.2% of Ce02; 0-0.5% of F2; 0.01-0.5% of Sn02; 0-3% of BaO; 0-3% of SrO; 0-0.5% of Yb203; wherein the sum of Si02+Al203 is 63-81%, and the sum of CaO+MgO is 3.5-18%, and the ratio of Na20/(Li20+Na20+K20) is 0.4-1.5.Type: ApplicationFiled: May 18, 2011Publication date: August 15, 2013Applicant: SCHOTT GLASS TECHNOLOGIES (SUZHOU) CO. LTD.Inventors: Guangjun Zhang, José Zimmer, He Feng, Gerhard Lautenschlaeger, Armin Vogl
-
Publication number: 20130059716Abstract: The invention relates to an alumino-silicate glass which has a thermal expansion coefficient in the range of 8 to 10×10?6/K in a temperature range of 20 to 300° C., a transformation temperature Tg in a range of 580° C. to 640° C., and a processing temperature VA in a range of 1065° C. to 1140° C. and which can therefore be used as an alternative for soda lime glasses. An object of the invention is also the use of the inventive glasses in applications where a high temperature stability of the glasses is advantageous, in particular as substrate glass, superstrate glass and/or cover glass in the field of semiconductor technology, preferably for Cd—Te or for CIS or CIGS photovoltaic applications and for other applications in solar technology.Type: ApplicationFiled: February 29, 2012Publication date: March 7, 2013Inventors: Jörg H. Fechner, Franz Ott, Erhard Dick, Christof Kass
-
Publication number: 20130045855Abstract: The invention relates to red-dyed glass, comprising the components of a base glass, coloring additives, reductants, and stabilizers, wherein the coloring additives comprise copper oxides and neodymium oxides and wherein the reductants comprise tin oxides and wherein the stabilizers comprise antimony oxides, wherein the fraction of the copper oxides in the red-dyed glass is between 0.02 and 0.08 weight percent.Type: ApplicationFiled: October 23, 2012Publication date: February 21, 2013Applicant: D. SWAROVSKI KGInventor: D. Swarovski KG
-
Publication number: 20120318356Abstract: A photovoltaic cell, for example a thin-film photovoltaic cell, having a substrate glass made of aluminosilicate glass, has a glass composition which has SiO2 and Al2O3 as well as the alkaline oxide Na2O and the alkaline earth oxides CaO, MgO, and BaO, and optionally further components. The glass composition includes 10 to 16 wt.-% Na2O, >0 to <5 wt.-% CaO, and >1 to 10 wt.-% BaO, and the ratio of CaO:MgO is in the range of 0.5 to 1.7. The aluminosilicate glass used is crystallization stable because of the selected quotient of CaO/MgO and has a transformation temperature >580° C. and a processing temperature <1200° C. Therefore, it represents a more thermally stable alternative to soda-lime glass. The aluminosilicate glass is used as a substrate glass, superstrate glass, and/or cover glass for a photovoltaic cells, for example for thin-film photovoltaic cells, in particular those based on semiconductor composite material, such as CdTe, CIS, or CIGS.Type: ApplicationFiled: July 27, 2012Publication date: December 20, 2012Inventors: Jörg Hinrich Fechner, Christof Kass, Franz Ott
-
Publication number: 20120308827Abstract: Ion exchangeable glass articles are disclosed. In one embodiment, a glass article formed from alkali aluminosilicate glass which may include Ga2O3, Al2O3, Na2O, SiO2, B2O3, P2O5 and various combinations thereof. The glass article may generally include about X mol % of Ga2O3 and about Z mol % of Al2O3, wherein 0?x?20, 0?z?25 and 10?(X+Z)?25. The glass article may also include from about 5 mol % to about 35 mol % Na2O, SiO2 may be present in an amount from about 40 mol % to about 70 mol % SiO2. The glass article may further include Y mol % B2O3 where Y is from 0 to about 10. The glass article may further include (10-Y) mol % of P2O5. Glass articles formed according to the present invention may be ion-exchange strengthened. In addition, the glass articles may have a low liquid CTE which enables the glass articles to be readily formed into complex shapes.Type: ApplicationFiled: May 31, 2011Publication date: December 6, 2012Inventors: Heather Debra Boek, Mark Owen Weller, Randall Eugene Youngman
-
Publication number: 20120309607Abstract: The invention relates to glass-ceramics based on the lithium disilicate system which can be mechanically machined easily in an intermediate step of crystallisation and, after complete crystallisation, represent a very strong, highly-translucent and chemically-stable glass-ceramic. Likewise, the invention relates to a method for the production of these glass-ceramics. The glass-ceramics according to the invention are used as dental material.Type: ApplicationFiled: December 23, 2010Publication date: December 6, 2012Applicants: FRAUNHOFER-GESELLSCHAFT ZUR FÖRDERUNG DER ANGEWANDTEN FORSCHUNG E.V., DEGUDENT GMBH, VITA ZAHNFABRIK H. RAUTER GMBH & CO. KGInventors: Bernhard Durschang, Jorn Probst, Norbert Thiel, Joachim Bibus, Markus Vollmann, Udo Schusser
-
Publication number: 20120251743Abstract: A housing/enclosure/cover can include an ion-exchanged glass exhibiting the following attributes (1) radio, and microwave frequency transparency, as defined by a loss tangent of less than 0.03 and at a frequency range of between 15 MHz to 3.0 GHz; (2) infrared transparency; (3) a fracture toughness of greater than 0.6 MPa·m1/2; (4) a 4-point bend strength of greater than 350 MPa; (5) a Vickers hardness of at least 450 kgf/mm2 and a Vickers median/radial crack initiation threshold of at least 5 kgf; (6) a Young's Modulus ranging between about 50 to 100 GPa;; (7) a thermal conductivity of less than 2.0 W/m° C., and (9) and at least one of the following attributes: (i) a compressive surface layer having a depth of layer (DOL) greater and a compressive stress greater than 400 MPa, or, (ii) a central tension of more than 20 MPa.Type: ApplicationFiled: May 15, 2012Publication date: October 4, 2012Inventors: Jaymin Amin, Matthew John Dejneka, Linda Ruth Pinckney, Katherine Rose Rossington, Robert Sabia
-
Patent number: 8268739Abstract: Zirconium-containing BaO- and PbO-free X-ray opaque glasses having a refractive index nd of about 1.57 to about 1.61 and a high X-ray opacity with an aluminum equivalent thickness of at least about 400% are provided. Such glasses are based on a SiO2—Al2O3—La2O3—ZrO2—Cs2O system with additions of Li2O, Na2O, ZnO and/or Ta2O5. Such glasses may be used, in particular, as dental glasses or as optical glasses.Type: GrantFiled: January 28, 2010Date of Patent: September 18, 2012Assignee: Schott AGInventors: Simone Monika Ritter, Oliver Hochrein, Sabine Pichler-Wilhelm
-
Patent number: 8252708Abstract: A borosilicate glass composition suitable for manufacturing microreactor glass frits includes 12-22 mol % B2O3=12-22; 68-80 mol % SiO2; 3-8 mol % Al2O3, 1-8 mol % Li2O, and one of 0.5±0.1 mol % ZrO2 and 1.1±0.5 mol % F. After sintering a glass frit having the borosilicate glass composition, the glass frit has a surface crystalline layer of 30 ?m or less or is amorphous throughout.Type: GrantFiled: March 8, 2012Date of Patent: August 28, 2012Assignee: Corning IncorporatedInventors: Robert Michael Morena, Paulo Jorge Marques, Henry Edwin Hagy
-
Publication number: 20120094822Abstract: The present invention relates to a method of fabricating an improved lithium silicate glass ceramic and to that material for the manufacture of blocks for dental appliances using a CAD/CAM process and hot pressing system. The lithium silicate material has a chemical composition that is different from those reported in the prior art with 1 to 10% of germanium dioxide in final composition. The softening points are close to the crystallization final temperature of 800° C. indicating that the samples will support the temperature process without shape deformation.Type: ApplicationFiled: December 8, 2011Publication date: April 19, 2012Inventor: Rodolfo Castillo
-
Patent number: 8156761Abstract: A mixed quartz powder contains quartz powder and two or more types of doping element in an amount of from 0.1 to 20 mass %. The aforementioned doped elements include a first dope element selected from the group consisting of N, C and F, and a second dope element selected from the group consisting of Mg, Ca, Sr, Ba, Sc, Y, Ti, Zr, Hf, the lanthanides and the actinides. The “quartz powder” is a powder of crystalline quartz or it is a powder of glassy SiO2 particles. It is made form natural occurring quartz or it is fabricated synthetically. The “quartz powder” may be doped. The compounding ratio of the total amount (M1) of the aforementioned first elements and the total amount (M2) of the aforementioned second elements as the ratio of the number of atoms (M1)/(M2) is preferably from 0.1 to 20. Al as well as the aforementioned doped elements is preferably included in a mixed quartz powder of this invention.Type: GrantFiled: February 8, 2011Date of Patent: April 17, 2012Assignees: Heraeus Quarzglas GmbH & Co. KG, Shin-Etsu Quartz Products Co., Ltd.Inventor: Tatsuhiro Sato
-
Patent number: 8133828Abstract: Glass-ceramic compositions exhibiting high reliability and tensile strength are described. The compositions can include crystal phases including roedderite and/or potassium fluorrichterite. The glass-ceramic compositions are bioactive, and can be used as components of a wide variety of biomedical devices such as dental restorations.Type: GrantFiled: May 13, 2009Date of Patent: March 13, 2012Assignee: The Ohio State University Research FoundationInventors: Isabelle L. Denry, Julie A. Holloway
-
Patent number: 8093167Abstract: For providing glasses and glass-ceramics having properties suitable for use as a substrate of an information storage medium of next generation such as one for the perpendicular magnetic recording system without employing arsenic and antimony components which adversely affect human beings and the environment, there are provided glass-ceramics comprising SiO2, Li2O and Al2O3 on oxide basis, comprising lithium disilicate as a crystal phase, and comprising one or more elements selected from the group consisting of Sn, Ce, Mn, W, Ta, Bi, Nb, S, Cl and F.Type: GrantFiled: February 16, 2011Date of Patent: January 10, 2012Assignee: Ohara Inc.Inventors: Toshitaka Yagi, Naoyuki Goto
-
Patent number: 8048816Abstract: The invention relates to opaque, colored glass-ceramic articles and to the production of opaque, colored glass-ceramic articles which can be readily formed to a desired shape using standard metal-working tools. The glass-ceramic material used to make such articles contains mica crystals as the predominant phase. The desired color is obtained through the addition of a colorant system to the precursor glass. In a particular embodiment the invention is directed to a black glass-ceramic article, the black color being obtained by the addition of iron oxides in levels as high as 20 wt %, which can yield a glass-ceramic having an iron-rice mica phase and/or a glass ceramic having an iron-rich mica phase plus an iron oxide phase.Type: GrantFiled: April 20, 2009Date of Patent: November 1, 2011Assignee: Corning IncorporatedInventors: George Halsey Beall, Linda Ruth Pinckney, Steven Alvin Tietje
-
Publication number: 20110259053Abstract: Lithium silicate materials are described which can be easily processed by machining to dental products without undue wear of the tools and which subsequently can be converted into lithium silicate products showing high strength.Type: ApplicationFiled: July 1, 2011Publication date: October 27, 2011Applicant: IVOCLAR VIVADENT AGInventors: Elke Apel, Wolfram Höland, Marcel Schweiger, Christian van t'Hoen, Harald Bürke, Volker M. Rheinberger
-
Patent number: 7998892Abstract: The present invention provides a TiO2—SiO2 glass whose coefficient of linear thermal expansion upon irradiation with high EUV energy light is substantially zero, which is suitable as an optical member of an exposure tool for EUVL. The present invention relates to a TiO2-containing silica glass having a halogen content of 100 ppm or more; a fictive temperature of 1,100° C. or lower; an average coefficient of linear thermal expansion in the range of from 20 to 100° C. of 30 ppb/° C. or lower; a temperature width ?T, in which a coefficient of linear thermal expansion is 0±5 ppb/° C., of 5° C. or greater; and a temperature, at which a coefficient of linear thermal expansion is 0 ppb/° C., falling within the range of from 30 to 150° C.Type: GrantFiled: August 27, 2010Date of Patent: August 16, 2011Assignee: Asahi Glass Company, LimitedInventors: Akio Koike, Yasutomi Iwahashi, Shinya Kikugawa
-
Patent number: 7989378Abstract: The present invention is to provide a TiO2—SiO2 glass having suitable thermal expansion properties as an optical member of an exposure tool for EUVL. The present invention relates to a TiO2-containing silica glass having a temperature, at which a coefficient of thermal expansion is 0 ppb/° C., falling within the range of 23±4° C. and a temperature width, in which a coefficient of thermal expansion is 0±5 ppb/° C., of 5° C. or more.Type: GrantFiled: June 28, 2010Date of Patent: August 2, 2011Assignee: Asahi Glass Company, LimitedInventors: Akio Koike, Yasutomi Iwahashi, Shinya Kikugawa
-
Patent number: 7964294Abstract: An easy to clean and stain resistant coating for a cooking product includes an oxycarbofluoride coating. The oxycarbofluoride coating has a composition comprising at least one metal oxide, carbon and fluorine and can be applied to a substrate using a sol-gel process.Type: GrantFiled: July 8, 2008Date of Patent: June 21, 2011Assignee: General Electric CompanyInventors: Venkat Subramaniam Venkataramani, Salil Mohan Joshi, Nagaveni Karkada, Sundeep Kumar
-
Patent number: 7964522Abstract: An F-doped silica glass, a process for making the glass, an optical member comprising the glass, and an optical system comprising such optical member. The glass material comprises 0.1-5000 ppm by weight of fluorine. The glass material according to certain embodiments of the present invention has low polarization-induced birefringence, low LIWFD and low induced absorption at 193 nm.Type: GrantFiled: August 14, 2007Date of Patent: June 21, 2011Assignee: Corning IncorporatedInventors: Lisa Anne Moore, Charlene Marie Smith
-
Publication number: 20110111944Abstract: The invention provides a crystallizable glass, a crystallized glass, and manufacturing methods thereof. The crystallizable glass can be crystallized in a short period of time, and can maintain its glass shape and its surface condition during a crystallization process. The crystallized glass has good mechanical strength, an adequate thermal expansion coefficient that allows the crystallized glass to be used as a construction material, less content of alkali-metal oxides, and good chemical durability. The MgO—Al2O3—SiO2-based crystallizable glass and crystallized glass contain, by mass percent, 55.0-65.0% SiO2, 8.0-14.0% Al2O3, 10.0-20.0% MgO, 1.5-6.0% CaO, 1.0-2.2% Li2O, 0.7-3.0% Na2O, 2.5-4.0% K2O, and 1.5-3.0% F.Type: ApplicationFiled: October 25, 2010Publication date: May 12, 2011Applicant: Huzhou Ta Hsiang Glass Products Co., Ltd.,Inventors: Kuo-Chuan Hsu, Chao Qu
-
Publication number: 20110111260Abstract: A glass substrate for information recording medium, said glass substrate being composed of an aluminosilicate glass containing 60-75% by mass of SiO2, 5-18% by mass of Al2O3, 3-10% by mass of Li2O, 3-15% by mass of Na2O and 0.5-8% by mass of ZrO2 relative to the entire glass components. The glass substrate for information recording medium contains neither As (arsenic) nor Sb (antimony), while containing at least one substance selected from the group consisting of SO3 (sulfurous acid), F (fluorine), Cl (chlorine), Br (bromine) and I (iodine), as a refining agent. The molar ratio of the total amount of the refining agent to the amount of Al2O3 is within the range of 0.02-0.20.Type: ApplicationFiled: July 3, 2009Publication date: May 12, 2011Applicant: Konica Minolta Opto, Inc.Inventor: Hideki Kawai
-
Publication number: 20110111161Abstract: A glass substrate for information recording medium, said glass substrate being composed of an alminosilicate glass containing 60-75% by mass of SiO2, 5-18% by mass of Al2O3, 3-10% by mass of Li2O, 3-15% by mass of Na2O and 0.5-8% by mass of ZrO2 relative to the entire glass components. The glass substrate for information recording medium contains neither As (arsenic) nor Sb (antimony), while containing at least one substance selected from the group consisting of SO3 (sulfurous acid), F (fluorine), Cl (chlorine), Br (bromine) and I (iodine), as a refining agent. The molar ratio of the total amount of the refining agent to the amount of ZrO2 is within the range of 0.05-0.50.Type: ApplicationFiled: July 3, 2009Publication date: May 12, 2011Applicant: Konica Minolta Opto, Inc.Inventor: Hideki Kawai
-
Publication number: 20110098172Abstract: The invention discloses boron-free neutral glasses having the composition (in % by weight, based on oxide) 65-72 SiO2, 11-17 Al2O3, 0.1-8 Na2O, 3-8 MgO, 4-12 CaO and 0-10 ZnO, a ratio CaO/MgO of 1.4 to 1.6, and having a hydrolytic resistance in accordance with DIN ISO 719 in class 1 and an acid resistance in accordance with DIN 12116 and an alkali resistance in accordance with DIN ISO 695 at least in class 2.Type: ApplicationFiled: October 25, 2010Publication date: April 28, 2011Inventor: Peter BRIX
-
Publication number: 20110053754Abstract: A glass composition useful in preparing fiberglass comprises 12 to 25 weight % CaO; 12 to 16 weight % Al2O3; 52 to 62 weight % SiO2; 0.05 to 0.8 Fe2O3; and greater than 2 up to about 8 weight % alkali metal oxide.Type: ApplicationFiled: September 1, 2009Publication date: March 3, 2011Inventors: Jeffrey Shock, Elam Leed, Jonathan McCann
-
Publication number: 20110003122Abstract: A photovoltaic module having a fluoride-containing covering, substrate or superstrate glass is disclosed. The weight ratio X of the iron content to the fluorine content is preferably from 0.001 to 0.6. The glass to which fluoride has been added can be any glass suitable for photovoltaic modules, for example a soda-lime glass, a borosilicate glass or an aluminosilicate glass.Type: ApplicationFiled: July 1, 2010Publication date: January 6, 2011Inventors: Oliver HOCHREIN, Axel Engel, Jochen Alkemper
-
Publication number: 20100184345Abstract: The invention relates to reinforcing glass yarns of which the composition comprises the following components within the limits defined below expressed in weight percent: SiO2 62-72% Al2O3 4-11% CaO 8-22% MgO 1-7% Na2O + K2O + Li2O 0-9% BaO + SrO 0-4% B2O3 0-4% F2 0-2% Other components: TiO2 + ZrO2 + 0-4% Fe2O3 (total iron) + P2O5 + MnO + Cr2O3 + MoO3 + ZnO + SO3 These yarns consist of an economical glass offering an excellent comprise between its mechanical properties represented by the specific Young's modulus and its drawing conditions. The invention also relates to the glass composition suitable for manufacturing said glass yarns, the basic structures of such yarns, in particular meshes, fabrics and mats, and the composites incorporating such yarns.Type: ApplicationFiled: May 15, 2008Publication date: July 22, 2010Applicant: Saint-Gobain Technical Fabrics EuropeInventors: Jerome Lalande, Anne Berthereau
-
Patent number: 7687418Abstract: The X-ray opaque glass is characterized by a composition, in mol %, of SiO2, 75-98; Yb2O3, 0.1 to 40; and ZrO2, 0 to 40. Preferred embodiments of the glass are free of Al2O3 and B2O3. The glass is produced from the glass batch by melting at a temperature of at least 1500° C. in an iridium or iridium alloy vessel with the assistance of high-frequency radiation. In preferred embodiments of the glass production process at least one raw material ingredient is present in the batch as a nanoscale powder. The glass is useful in dental applications, optical applications, and biomedical applications, or for photovoltaics, or as a target material in PVD processes.Type: GrantFiled: December 28, 2004Date of Patent: March 30, 2010Assignee: Schott AGInventors: Ulrich Peuchert, Uwe Kolberg, Joern Besinger
-
Publication number: 20090286666Abstract: Glass-ceramic compositions exhibiting high reliability and tensile strength are described. The compositions can include crystal phases including roedderite and/or potassium fluorrichterite. The glass-ceramic compositions are bioactive, and can be used as components of a wide variety of biomedical devices such as dental restorations.Type: ApplicationFiled: May 13, 2009Publication date: November 19, 2009Applicant: THE OHIO STATE UNIVERSITY RESEARCH FOUNDATIONInventors: Isabelle L. Denry, Julie A. Holloway
-
Publication number: 20090286667Abstract: An optically detectable, floatable arsenic- and antimony-free, glazable lithium-aluminosilicate glass that can be prestressed and the glass ceramic converted therefrom are described. The glass or the glass ceramic has a composition (in % by weight based on oxide) of essentially SiO2 55-69, Al2O3 19-25, Li2O 3.2-5, Na2O 0-1.5, K2O 0-1.5, MgO 0-2.2, CaO 0-2.0, SrO 0-2.0, BaO 0-2.5, ZnO 0-<1.5, TiO2 1-3, ZrO2 1-2.5, 0.1-<1, ?TiO2+ZrO2+SnO2 2.5-5, P2O5 O-3, Nd2O3 0.01-0.6, CoO 0-0.005, F 0-1, B2O3 0-2.Type: ApplicationFiled: February 26, 2009Publication date: November 19, 2009Inventors: Friedrich SIEBERS, Hans-Werner Beudt, Bernd Rudinger, Gerbard Lautenschlager, Klaus Schneider, Michael Jacquorie, Wolfgang Schmidbauer
-
Patent number: 7592063Abstract: For a substrate having fine convexoconcave patterns on its surface, the dimensions of the convexoconcave patterns in a vertical direction of a quartz glass substrate are controlled to be uniform with extreme accuracy and over the entire substrate surface. The quartz glass substrate is made to have a fictive temperature distribution of at most 40° C. and a halogen concentration of less than 400 ppm, and the etching rate of the surface of the quartz glass substrate is made uniform, whereby the dimensions of the convexoconcave patterns in a vertical direction of the quartz glass substrate are controlled to be uniform with good accuracy and over the entire substrate surface.Type: GrantFiled: September 5, 2006Date of Patent: September 22, 2009Assignee: Asahi Glass Company, LimitedInventors: Yoshiaki Ikuta, Shinya Kikugawa