Fluorine Patents (Class 501/57)
  • Patent number: 11890833
    Abstract: A laminate glass-ceramic article is provided that includes: a core glass layer having a first coefficient of thermal expansion (CTE); and a plurality of clad glass-ceramic layers, each having a CTE that is lower than or equal to the first CTE of the core glass layer. A first of the clad glass-ceramic layers is laminated to a first surface of core glass layer and a second of the clad glass-ceramic layers is laminated to a second surface of the core glass layer. Further, a total thickness of the plurality of clad glass-ceramic layers is from about 0.05 mm to about 0.5 mm. In addition, each of the glass-ceramic layers includes: an alumino-boro-silicate glass, 0 mol %?MoO3?15 mol %, and 0 mol %?WO3?15 mol %, the WO3 (mol %) plus the MoO3 (mol %) is from 0.7 mol % to 19 mol %.
    Type: Grant
    Filed: May 2, 2022
    Date of Patent: February 6, 2024
    Assignee: CORNING INCORPORATED
    Inventors: Matthew John Dejneka, Jesse Kohl
  • Patent number: 11731901
    Abstract: The purpose of the present invention is to provide a chemically strengthened glass having excellent transparency and strength and being scratch resistant. The present invention pertains to a chemically strengthened glass that: has a compressive stress layer on the surface thereof; has a visible light transmittance of at least 70% when the thickness thereof is converted to 0.8 mm; has a surface compressive stress of at least 600 MPa; has a compressive stress depth of at least 80 ?m; and contains a ?-spodumene.
    Type: Grant
    Filed: January 21, 2020
    Date of Patent: August 22, 2023
    Assignee: AGC Inc.
    Inventors: Qing Li, Kenji Imakita, Akio Koike, Eriko Maeda
  • Patent number: 11476634
    Abstract: A rare earth-doped optical fiber comprises a fluorosilicate core surrounded by a silica cladding, where the fluorosilicate core comprises an alkaline-earth fluoro-alumino-silicate glass, such as a strontium fluoro-alumino-silicate glass. The rare earth-doped optical fiber may be useful as a high-power fiber laser and/or fiber amplifier. A method of making a rare earth-doped optical fiber comprises: inserting a powder mixture comprising YbF3, SrF2, and Al2O3 into a silica tube; after inserting the powder mixture, heating the silica tube to a temperature of at least about 2000° C., some or all of the powder mixture undergoing melting; drawing the silica tube to obtain a reduced-diameter fiber; and cooling the reduced-diameter fiber. Thus, a rare earth-doped optical fiber comprising a fluorosilicate core surrounded by a silica cladding is formed.
    Type: Grant
    Filed: May 7, 2019
    Date of Patent: October 18, 2022
    Assignees: THE BOARD OF TRUSTEES OF THE UNIVERSITY OF ILLINOIS, CLEMSON UNIVERSITY
    Inventors: Peter Dragic, John Ballato, Maxime Cavillon
  • Patent number: 11104608
    Abstract: Ion-exchanged glass ceramic articles described herein have a stress that decreases with increasing distance according to a substantially linear function from a depth of about 0.07 t to a depth of about 0.26 t from the outer surface of the ion-exchanged glass ceramic article from a compressive stress to a tensile stress. The stress transitions from the compressive stress to the tensile stress at a depth of from about 0.18 t to about 0.25 t from the outer surface of the ion-exchanged glass ceramic article. An absolute value of a maximum compressive stress at the outer surface of the ion-exchanged glass article is from 1.8 to 2.2 times an absolute value of a maximum central tension (CT) of the ion-exchanged glass article, and the glass ceramic article has a fracture toughness of 1 MPa?m or more as measured according to the double cantilever beam method.
    Type: Grant
    Filed: November 13, 2019
    Date of Patent: August 31, 2021
    Assignee: Corning Incorporated
    Inventors: Ryan Claude Andrews, Albert Joseph Fahey, Lisa Marie Noni, Rostislav Vatchev Roussev, Charlene Marie Smith, Ljerka Ukrainczyk, Shelby Kerin Wilson
  • Patent number: 10962502
    Abstract: A hydrogen detector for gas and fluid media is disclosed. The detector includes a selective membrane and a housing. Within the housing is a potential measuring unit and a ceramic sensing element made of a solid electrolyte. A standard electrode is located within a cavity of the ceramic sensing element and a porous platinum electrode is applied to an external layer of the ceramic sensing element. A potential measuring unit passes through a sealed lead-in at the upper end of the housing and is brought out to the standard electrode. The selective membrane, which is attached to a hole in the end of the lower bushing, is closed with a plug. The cavity limited by the inner surface of the lower bushing, the external part of the bottom of the ceramic sensing element and the inner surfaces of the selective membrane and the plug is leak-tight.
    Type: Grant
    Filed: November 16, 2015
    Date of Patent: March 30, 2021
    Assignee: JOINT STOCK COMPANY “AKME-ENGINEERING”
    Inventors: Petr Nikiforovich Martynov, Mi hail Efimovich Chernov, Alexsey Nikolaevich Storozhenko, Vasiliy Mikhaylovich Shelemet'Ev, Roman Petrovich Sadovnichiy
  • Patent number: 10703670
    Abstract: The invention relates to a process for producing alkali metal-rich aluminosilicate glasses having a content (in mol % based on oxide) of alkali metal oxides of 4-16 mol %, of Al2O3 of at least 4 mol % and of B2O3 of 0-4 mol %, wherein 0.15 mol % to 0.9 mol % of chloride(s) and at least one refining agent from the group of sulfate(s) (reported as SO3), CeO2 are added to the glass batch and wherein the sum total of refining agents added in the batch is 0.17 mol % to 1.3 mol %.
    Type: Grant
    Filed: February 21, 2018
    Date of Patent: July 7, 2020
    Assignee: SCHOTT AG
    Inventors: Christof Kass, Rainer Eichholz
  • Patent number: 10640416
    Abstract: The present invention relates to an alkali-free glass substrate, having a difference ?n between the maximum value and the minimum value of a refractive index at a cross-section of a glass sheet of 0.40×10?5 or less. According to the alkali-free glass substrate of the present invention, the polishing ability can be extremely improved and the polishing time is shortened, so that the production efficiency can be improved.
    Type: Grant
    Filed: March 27, 2018
    Date of Patent: May 5, 2020
    Assignee: AGC INC.
    Inventors: Kenta Saito, Daisuke Kobayashi
  • Patent number: 10421568
    Abstract: A horn and an anvil are moved toward and away from each other by axially reciprocating a driving rod and thereby reciprocatingly rotating a forked lever in a predetermined angle range. The horn and the anvil are moved toward and pressed against each other with a predetermined force with a bag mouth b held therebetween. A sensor detects the position of a second mounting block secured to the rear end of a sliding shaft of the anvil, thereby detecting the distance between respective pressing surfaces of the horn and the anvil, i.e. the thickness m of a portion of the bag mouth held between the pressing surfaces. When the thickness m is not less than a predetermined threshold value M, a vibrator is activated to perform sealing. When the thickness m is less than the threshold value M, no sealing is performed.
    Type: Grant
    Filed: October 10, 2017
    Date of Patent: September 24, 2019
    Assignee: Toyo Jidoki Co., Ltd
    Inventors: Kazunori Yamamoto, Yasuyuki Honda, Noriyuki Yamane
  • Patent number: 9701570
    Abstract: Opal glass compositions and glass articles comprising the same are disclosed. In one embodiment, a glass composition includes 55 mol. % to 70 mol. % SiO2 and 9 mol. % to 15 mol. % Al2O3 as glass network formers. The glass composition also includes 10 mol. % to 15 mol. % alkali oxide M2O, wherein M is at least one of Na and K. The glass composition also includes 2 mol. % to 8 mol. % divalent oxide RO, wherein R is at least one of Zn, Ca, and Mg. As an opalizing agent, the glass composition may also include 8.5 mol. % to 16 mol. % F?. The glass composition may also include 0 mol. % to 0.3 mol. % SnO2 as a fining agent and from about 0 mol. % to about 6 mol. % of colorant. The glass composition is free from As and compounds containing As.
    Type: Grant
    Filed: February 27, 2013
    Date of Patent: July 11, 2017
    Assignee: Corning Incorporated
    Inventors: John Christopher Mauro, Morten Mattrup Smedskjaer, Natesan Venkataraman
  • Patent number: 9650288
    Abstract: The present invention relates to an aqua blue glass composition having a base composition of a soda-lime-silica glass having as main coloring agents total iron, expressed as Fe2O3 in the range of 0.30 to 0.60% by weight with a ratio of ferrous (redox) in the range of 20 to 30; FeO in the range of 0.06 to 0.18% by weight; TiO2 in the range of 0.025 to 1.0% by weight; Co3O4 expressed in the range of 5 to 30% ppm; Se expressed in the range of 0.1 to 10 ppm; CuO in the range of 0 to 400 ppm; and Cr2O3 in the range of 10 to 20 ppm. The glass provides light transmittance, illuminant “A”, greater than 50%, a dominant wavelength (?) of 487 nm to 498 nm; a solar energy transmittance of less than or equal to 64.4%; an ultraviolet solar transmittance no more than 51.6%; and an excitation purity less than 12 for glass thicknesses from 4 to 12 mm.
    Type: Grant
    Filed: December 19, 2013
    Date of Patent: May 16, 2017
    Assignee: Vidrio Plano de Mexico, S.A. de C.V.
    Inventors: Jose Guadalupe Cid-Aguilar, Roberto Marcos Cabrera-Llanos, Jose Luis Tavares-Cortes
  • Patent number: 9470614
    Abstract: A chemically strengthened glass is disposed on a base, and an impacting object is dropped from above in a state where one surface of the chemically strengthened glass is in contact with an abrasive surface of a sandpaper containing an abrasive having a size of not smaller than a depth of a compressive stress layer.
    Type: Grant
    Filed: February 4, 2014
    Date of Patent: October 18, 2016
    Assignee: ASAHI GLASS COMPANY, LIMITED
    Inventors: Hiroyuki Okawa, Kazuhiko Yamanaka
  • Publication number: 20150045201
    Abstract: The present invention relates to a non-alkali glass having a strain point of 710° C. or higher, an average thermal expansion coefficient at from 50 to 300° C. of from 30×10?7 to 43×10?7/° C., a temperature T2 at which glass viscosity reaches 102 dPa·s of 1,710° C. or lower, a temperature T4 at which the glass viscosity reaches 104 dPa·s of 1,320° C. or lower, containing, indicated by percentage by mass on the basis of oxides, SiO2 58.5 to 67.5, Al2O3 18 to 24, B2O3 0 to 1.7, MgO 6.0 to 8.5, CaO 3.0 to 8.5, SrO 0.5 to 7.5, BaO 0 to 2.5 and ZrO2 0 to 4.0, containing Cl in an amount of from 0.15 to 0.35% by mass, F in an amount of from 0.01 to 0.15% by mass and SO3 in an amount of from 1 to 25 ppm and having a ?-OH value of the glass of from 0.15 to 0.45 mm?1, in which (MgO/40.3)+(CaO/56.1)+(SrO/103.6)+(BaO/153.3) is from 0.27 to 0.35, (MgO/40.3)/((MgO/40.3)+(CaO/56.1)+(SrO/103.6)+(BaO/153.3)) is 0.40 or more, (MgO/40.3)/((MgO/40.3)+(CaO/56.1)) is 0.40 or more, and (MgO/40.3)/((MgO/40.3)+(SrO/103.6)) is 0.
    Type: Application
    Filed: October 27, 2014
    Publication date: February 12, 2015
    Applicant: ASAHI GLASS COMPANY, LIMITED
    Inventors: Hirofumi TOKUNAGA, Shingo Urata, Akio Koike, Manabu Nishizawa, Takashi Enomoto, Tomoyuki Tsujimura
  • Publication number: 20150038315
    Abstract: To provide a method for producing chemically tempered glass, whereby frequency of replacement of the molten salt can be reduced. A method for producing chemically tempered glass, which comprises repeating ion exchange treatment of immersing glass in a molten salt, wherein the glass comprises, as represented by mole percentage, from 61 to 77% of SiO2, from 1 to 18% of Al2O3, from 3 to 15% of MgO, from 0 to 5% of CaO, from 0 to 4% of ZrO2, from 8 to 18% of Na2O and from 0 to 6% of K2O; SiO2+Al2O3 is from 65 to 85%; MgO+CaO is from 3 to 15%; and R calculated by the following formula by using contents of the respective components, is at least 0.66: R=0.029×SiO2+0.021×Al2O3+0.016×MgO?0.004×CaO+0.016×ZrO2+0.029×Na2O+0×K2O?2.
    Type: Application
    Filed: October 21, 2014
    Publication date: February 5, 2015
    Applicant: Asahi Glass Company, Limited
    Inventors: Jun Endo, Shusaku Akiba, Kazutaka Ono, Shigeki Sawamura
  • Publication number: 20150010739
    Abstract: Opal glass compositions and glass articles comprising the same are disclosed. In one embodiment, a glass composition includes 55 mol. % to 70 mol. % SiO2 and 9 mol. % to 15 mol. % Al2O3 as glass network formers. The glass composition also includes 10 mol. % to 15 mol. % alkali oxide M2O, wherein M is at least one of Na and K. The glass composition also includes 2 mol. % to 8 mol. % divalent oxide RO, wherein R is at least one of Zn, Ca, and Mg. As an opalizing agent, the glass composition may also include 8.5 mol. % to 16 mol. % F?. The glass composition may also include 0 mol. % to 0.3 mol. % SnO2 as a fining agent and from about 0 mol. % to about 6 mol. % of colorant. The glass composition is free from As and compounds containing As.
    Type: Application
    Filed: February 27, 2013
    Publication date: January 8, 2015
    Inventors: John Christopher Mauro, Morten Mattrup Smedskjaer, Natesan Venkataraman
  • Patent number: 8889575
    Abstract: Ion exchangeable glass articles are disclosed. In one embodiment, a glass article formed from alkali aluminosilicate glass which may include Ga2O3, Al2O3, Na2O, SiO2, B2O3, P2O5 and various combinations thereof. The glass article may generally include about X mol % of Ga2O3 and about Z mol % of Al2O3, wherein 0?X?20, 0?Z?25 and 10?(X+Z)?25. The glass article may also include from about 5 mol % to about 35 mol % Na2O, SiO2 may be present in an amount from about 40 mol % to about 70 mol % SiO2. The glass article may further include Y mol % B2O3 where Y is from 0 to about 10. The glass article may further include (10-Y) mol % of P2O5. Glass articles formed according to the present invention may be ion-exchange strengthened. In addition, the glass articles may have a low liquid CTE which enables the glass articles to be readily formed into complex shapes.
    Type: Grant
    Filed: May 31, 2011
    Date of Patent: November 18, 2014
    Assignee: Corning Incorporated
    Inventors: Heather Debra Boek, Mark Owen Weller, Randall Eugene Youngman
  • Patent number: 8846555
    Abstract: Disclosed are silica and fluoride doped lead-bismuth-gallium heavy metal oxide glasses for visible to mid-wave Infrared Radiation transmitting optics and preparation thereof.
    Type: Grant
    Filed: June 25, 2012
    Date of Patent: September 30, 2014
    Assignee: Schott Corporation
    Inventors: Simi George, Sally Pucilowski
  • Publication number: 20140155246
    Abstract: The present disclosure is directed to a doped silica-titania glass, DST glass, consisting essentially of 0.1 wt. % to 5 wt. % halogen, 50 ppm-wt. to 6 wt. % one or more oxides of Al, Ta and Nb, 3 wt. % to 10 wt. % TiO2 and the remainder SiO2. In an embodiment the halogen content can be in the range of 0.2 wt. % to 3 wt. % along with 50 ppm-wt. to 6 wt. % one or more oxides of Al, Ta and Nb, 3 wt. % to 10 wt. % TiO2 and the remainder SiO2. In an embodiment the DST glass has an OH concentration of less than 100 ppm. In another embodiment the OH concentration is less than 50 ppm. The DST glass has a fictive temperature Tf of less than 875° C. In an embodiment Tf is less than 825° C. In another embodiment Tf is less than 775° C.
    Type: Application
    Filed: March 15, 2013
    Publication date: June 5, 2014
    Applicant: CORNING INCORPORATED
    Inventors: Sezhian Annamalai, Carlos Alberto Duran, Kenneth Edward Hrdina
  • Publication number: 20130344312
    Abstract: Disclosed are silica and fluoride doped lead-bismuth-gallium heavy metal oxide glasses for visible to mid-wave Infrared Radiation transmitting optics and preparation thereof.
    Type: Application
    Filed: June 25, 2012
    Publication date: December 26, 2013
    Applicant: SCHOTT NORTH AMERICA, INC.
    Inventors: Simi GEORGE, Sally Pucilowski
  • Publication number: 20130296157
    Abstract: Described herein are alkali-free, boroalumino silicate glasses exhibiting desirable physical and chemical properties for use as substrates in flat panel display devices, such as, active matrix liquid crystal displays (AMLCDs) and active matrix organic light emitting diode displays (AMOLEDs). In accordance with certain of its aspects, the glasses possess good dimensional stability as a function of temperature. The glasses comprise in mol percent on an oxide basis: 70-74.5 SiO2, 10.5-13.5 AL2O3, 0-2.5 B2O3, 3-7 MgO, 3-7 CaO, 0-4 SrO, 1.5-6 BaO, 0-0.3 SnO2, 0-03 CeO2, 0-0.5 As2O3, 0-0.5 Sb2O3, 0.01-0.08 Fe2O3 and F+Cl+BrRO/Al2O31.7 and 0.2MgO/RO0.45, RO being the sum of MgO, BaO, SrO and CaO.
    Type: Application
    Filed: January 25, 2012
    Publication date: November 7, 2013
    Inventors: Adam J. Ellison, Timothy J. Kiczenski
  • Patent number: 8546283
    Abstract: The present invention relates to a substrate for EUV lithography optical member, comprising a silica glass containing TiO2, in which the substrate has two opposite surfaces, and the substrate has temperatures at which a coefficient of linear thermal expansion (CTE) is 0 ppb/° C. (Cross-Over Temperature: COT), and in which the two opposite surfaces have difference in the COTs of 5° C. or more.
    Type: Grant
    Filed: June 25, 2012
    Date of Patent: October 1, 2013
    Assignee: Asahi Glass Company, Limited
    Inventors: Junko Miyasaka, Akio Koike, Tomonori Ogawa
  • Publication number: 20130209751
    Abstract: An alkali aluminosilicate glass for 3D precision molding and thermal bending is provided. The glass has a working point lower than 1200° C. (104 dPas) and a transition temperature Tg lower than 610° C. The glass has, based on a sum of all the components in percentage by weight, 51-63% of Si02; 5-18% of Al203; 8-16% of Na20; 0-6% of K20; 3.5-10% of MgO; 0-5% of B203; 0-4.5% of Li20; 0-5% of ZnO; 0-8% of CaO; 0.1-2.5% of Zr02; 0.01-<0.2% of Ce02; 0-0.5% of F2; 0.01-0.5% of Sn02; 0-3% of BaO; 0-3% of SrO; 0-0.5% of Yb203; wherein the sum of Si02+Al203 is 63-81%, and the sum of CaO+MgO is 3.5-18%, and the ratio of Na20/(Li20+Na20+K20) is 0.4-1.5.
    Type: Application
    Filed: May 18, 2011
    Publication date: August 15, 2013
    Applicant: SCHOTT GLASS TECHNOLOGIES (SUZHOU) CO. LTD.
    Inventors: Guangjun Zhang, José Zimmer, He Feng, Gerhard Lautenschlaeger, Armin Vogl
  • Publication number: 20130059716
    Abstract: The invention relates to an alumino-silicate glass which has a thermal expansion coefficient in the range of 8 to 10×10?6/K in a temperature range of 20 to 300° C., a transformation temperature Tg in a range of 580° C. to 640° C., and a processing temperature VA in a range of 1065° C. to 1140° C. and which can therefore be used as an alternative for soda lime glasses. An object of the invention is also the use of the inventive glasses in applications where a high temperature stability of the glasses is advantageous, in particular as substrate glass, superstrate glass and/or cover glass in the field of semiconductor technology, preferably for Cd—Te or for CIS or CIGS photovoltaic applications and for other applications in solar technology.
    Type: Application
    Filed: February 29, 2012
    Publication date: March 7, 2013
    Inventors: Jörg H. Fechner, Franz Ott, Erhard Dick, Christof Kass
  • Publication number: 20130045855
    Abstract: The invention relates to red-dyed glass, comprising the components of a base glass, coloring additives, reductants, and stabilizers, wherein the coloring additives comprise copper oxides and neodymium oxides and wherein the reductants comprise tin oxides and wherein the stabilizers comprise antimony oxides, wherein the fraction of the copper oxides in the red-dyed glass is between 0.02 and 0.08 weight percent.
    Type: Application
    Filed: October 23, 2012
    Publication date: February 21, 2013
    Applicant: D. SWAROVSKI KG
    Inventor: D. Swarovski KG
  • Publication number: 20120318356
    Abstract: A photovoltaic cell, for example a thin-film photovoltaic cell, having a substrate glass made of aluminosilicate glass, has a glass composition which has SiO2 and Al2O3 as well as the alkaline oxide Na2O and the alkaline earth oxides CaO, MgO, and BaO, and optionally further components. The glass composition includes 10 to 16 wt.-% Na2O, >0 to <5 wt.-% CaO, and >1 to 10 wt.-% BaO, and the ratio of CaO:MgO is in the range of 0.5 to 1.7. The aluminosilicate glass used is crystallization stable because of the selected quotient of CaO/MgO and has a transformation temperature >580° C. and a processing temperature <1200° C. Therefore, it represents a more thermally stable alternative to soda-lime glass. The aluminosilicate glass is used as a substrate glass, superstrate glass, and/or cover glass for a photovoltaic cells, for example for thin-film photovoltaic cells, in particular those based on semiconductor composite material, such as CdTe, CIS, or CIGS.
    Type: Application
    Filed: July 27, 2012
    Publication date: December 20, 2012
    Inventors: Jörg Hinrich Fechner, Christof Kass, Franz Ott
  • Publication number: 20120308827
    Abstract: Ion exchangeable glass articles are disclosed. In one embodiment, a glass article formed from alkali aluminosilicate glass which may include Ga2O3, Al2O3, Na2O, SiO2, B2O3, P2O5 and various combinations thereof. The glass article may generally include about X mol % of Ga2O3 and about Z mol % of Al2O3, wherein 0?x?20, 0?z?25 and 10?(X+Z)?25. The glass article may also include from about 5 mol % to about 35 mol % Na2O, SiO2 may be present in an amount from about 40 mol % to about 70 mol % SiO2. The glass article may further include Y mol % B2O3 where Y is from 0 to about 10. The glass article may further include (10-Y) mol % of P2O5. Glass articles formed according to the present invention may be ion-exchange strengthened. In addition, the glass articles may have a low liquid CTE which enables the glass articles to be readily formed into complex shapes.
    Type: Application
    Filed: May 31, 2011
    Publication date: December 6, 2012
    Inventors: Heather Debra Boek, Mark Owen Weller, Randall Eugene Youngman
  • Publication number: 20120309607
    Abstract: The invention relates to glass-ceramics based on the lithium disilicate system which can be mechanically machined easily in an intermediate step of crystallisation and, after complete crystallisation, represent a very strong, highly-translucent and chemically-stable glass-ceramic. Likewise, the invention relates to a method for the production of these glass-ceramics. The glass-ceramics according to the invention are used as dental material.
    Type: Application
    Filed: December 23, 2010
    Publication date: December 6, 2012
    Applicants: FRAUNHOFER-GESELLSCHAFT ZUR FÖRDERUNG DER ANGEWANDTEN FORSCHUNG E.V., DEGUDENT GMBH, VITA ZAHNFABRIK H. RAUTER GMBH & CO. KG
    Inventors: Bernhard Durschang, Jorn Probst, Norbert Thiel, Joachim Bibus, Markus Vollmann, Udo Schusser
  • Publication number: 20120251743
    Abstract: A housing/enclosure/cover can include an ion-exchanged glass exhibiting the following attributes (1) radio, and microwave frequency transparency, as defined by a loss tangent of less than 0.03 and at a frequency range of between 15 MHz to 3.0 GHz; (2) infrared transparency; (3) a fracture toughness of greater than 0.6 MPa·m1/2; (4) a 4-point bend strength of greater than 350 MPa; (5) a Vickers hardness of at least 450 kgf/mm2 and a Vickers median/radial crack initiation threshold of at least 5 kgf; (6) a Young's Modulus ranging between about 50 to 100 GPa;; (7) a thermal conductivity of less than 2.0 W/m° C., and (9) and at least one of the following attributes: (i) a compressive surface layer having a depth of layer (DOL) greater and a compressive stress greater than 400 MPa, or, (ii) a central tension of more than 20 MPa.
    Type: Application
    Filed: May 15, 2012
    Publication date: October 4, 2012
    Inventors: Jaymin Amin, Matthew John Dejneka, Linda Ruth Pinckney, Katherine Rose Rossington, Robert Sabia
  • Patent number: 8268739
    Abstract: Zirconium-containing BaO- and PbO-free X-ray opaque glasses having a refractive index nd of about 1.57 to about 1.61 and a high X-ray opacity with an aluminum equivalent thickness of at least about 400% are provided. Such glasses are based on a SiO2—Al2O3—La2O3—ZrO2—Cs2O system with additions of Li2O, Na2O, ZnO and/or Ta2O5. Such glasses may be used, in particular, as dental glasses or as optical glasses.
    Type: Grant
    Filed: January 28, 2010
    Date of Patent: September 18, 2012
    Assignee: Schott AG
    Inventors: Simone Monika Ritter, Oliver Hochrein, Sabine Pichler-Wilhelm
  • Patent number: 8252708
    Abstract: A borosilicate glass composition suitable for manufacturing microreactor glass frits includes 12-22 mol % B2O3=12-22; 68-80 mol % SiO2; 3-8 mol % Al2O3, 1-8 mol % Li2O, and one of 0.5±0.1 mol % ZrO2 and 1.1±0.5 mol % F. After sintering a glass frit having the borosilicate glass composition, the glass frit has a surface crystalline layer of 30 ?m or less or is amorphous throughout.
    Type: Grant
    Filed: March 8, 2012
    Date of Patent: August 28, 2012
    Assignee: Corning Incorporated
    Inventors: Robert Michael Morena, Paulo Jorge Marques, Henry Edwin Hagy
  • Publication number: 20120094822
    Abstract: The present invention relates to a method of fabricating an improved lithium silicate glass ceramic and to that material for the manufacture of blocks for dental appliances using a CAD/CAM process and hot pressing system. The lithium silicate material has a chemical composition that is different from those reported in the prior art with 1 to 10% of germanium dioxide in final composition. The softening points are close to the crystallization final temperature of 800° C. indicating that the samples will support the temperature process without shape deformation.
    Type: Application
    Filed: December 8, 2011
    Publication date: April 19, 2012
    Inventor: Rodolfo Castillo
  • Patent number: 8156761
    Abstract: A mixed quartz powder contains quartz powder and two or more types of doping element in an amount of from 0.1 to 20 mass %. The aforementioned doped elements include a first dope element selected from the group consisting of N, C and F, and a second dope element selected from the group consisting of Mg, Ca, Sr, Ba, Sc, Y, Ti, Zr, Hf, the lanthanides and the actinides. The “quartz powder” is a powder of crystalline quartz or it is a powder of glassy SiO2 particles. It is made form natural occurring quartz or it is fabricated synthetically. The “quartz powder” may be doped. The compounding ratio of the total amount (M1) of the aforementioned first elements and the total amount (M2) of the aforementioned second elements as the ratio of the number of atoms (M1)/(M2) is preferably from 0.1 to 20. Al as well as the aforementioned doped elements is preferably included in a mixed quartz powder of this invention.
    Type: Grant
    Filed: February 8, 2011
    Date of Patent: April 17, 2012
    Assignees: Heraeus Quarzglas GmbH & Co. KG, Shin-Etsu Quartz Products Co., Ltd.
    Inventor: Tatsuhiro Sato
  • Patent number: 8133828
    Abstract: Glass-ceramic compositions exhibiting high reliability and tensile strength are described. The compositions can include crystal phases including roedderite and/or potassium fluorrichterite. The glass-ceramic compositions are bioactive, and can be used as components of a wide variety of biomedical devices such as dental restorations.
    Type: Grant
    Filed: May 13, 2009
    Date of Patent: March 13, 2012
    Assignee: The Ohio State University Research Foundation
    Inventors: Isabelle L. Denry, Julie A. Holloway
  • Patent number: 8093167
    Abstract: For providing glasses and glass-ceramics having properties suitable for use as a substrate of an information storage medium of next generation such as one for the perpendicular magnetic recording system without employing arsenic and antimony components which adversely affect human beings and the environment, there are provided glass-ceramics comprising SiO2, Li2O and Al2O3 on oxide basis, comprising lithium disilicate as a crystal phase, and comprising one or more elements selected from the group consisting of Sn, Ce, Mn, W, Ta, Bi, Nb, S, Cl and F.
    Type: Grant
    Filed: February 16, 2011
    Date of Patent: January 10, 2012
    Assignee: Ohara Inc.
    Inventors: Toshitaka Yagi, Naoyuki Goto
  • Patent number: 8048816
    Abstract: The invention relates to opaque, colored glass-ceramic articles and to the production of opaque, colored glass-ceramic articles which can be readily formed to a desired shape using standard metal-working tools. The glass-ceramic material used to make such articles contains mica crystals as the predominant phase. The desired color is obtained through the addition of a colorant system to the precursor glass. In a particular embodiment the invention is directed to a black glass-ceramic article, the black color being obtained by the addition of iron oxides in levels as high as 20 wt %, which can yield a glass-ceramic having an iron-rice mica phase and/or a glass ceramic having an iron-rich mica phase plus an iron oxide phase.
    Type: Grant
    Filed: April 20, 2009
    Date of Patent: November 1, 2011
    Assignee: Corning Incorporated
    Inventors: George Halsey Beall, Linda Ruth Pinckney, Steven Alvin Tietje
  • Publication number: 20110259053
    Abstract: Lithium silicate materials are described which can be easily processed by machining to dental products without undue wear of the tools and which subsequently can be converted into lithium silicate products showing high strength.
    Type: Application
    Filed: July 1, 2011
    Publication date: October 27, 2011
    Applicant: IVOCLAR VIVADENT AG
    Inventors: Elke Apel, Wolfram Höland, Marcel Schweiger, Christian van t'Hoen, Harald Bürke, Volker M. Rheinberger
  • Patent number: 7998892
    Abstract: The present invention provides a TiO2—SiO2 glass whose coefficient of linear thermal expansion upon irradiation with high EUV energy light is substantially zero, which is suitable as an optical member of an exposure tool for EUVL. The present invention relates to a TiO2-containing silica glass having a halogen content of 100 ppm or more; a fictive temperature of 1,100° C. or lower; an average coefficient of linear thermal expansion in the range of from 20 to 100° C. of 30 ppb/° C. or lower; a temperature width ?T, in which a coefficient of linear thermal expansion is 0±5 ppb/° C., of 5° C. or greater; and a temperature, at which a coefficient of linear thermal expansion is 0 ppb/° C., falling within the range of from 30 to 150° C.
    Type: Grant
    Filed: August 27, 2010
    Date of Patent: August 16, 2011
    Assignee: Asahi Glass Company, Limited
    Inventors: Akio Koike, Yasutomi Iwahashi, Shinya Kikugawa
  • Patent number: 7989378
    Abstract: The present invention is to provide a TiO2—SiO2 glass having suitable thermal expansion properties as an optical member of an exposure tool for EUVL. The present invention relates to a TiO2-containing silica glass having a temperature, at which a coefficient of thermal expansion is 0 ppb/° C., falling within the range of 23±4° C. and a temperature width, in which a coefficient of thermal expansion is 0±5 ppb/° C., of 5° C. or more.
    Type: Grant
    Filed: June 28, 2010
    Date of Patent: August 2, 2011
    Assignee: Asahi Glass Company, Limited
    Inventors: Akio Koike, Yasutomi Iwahashi, Shinya Kikugawa
  • Patent number: 7964294
    Abstract: An easy to clean and stain resistant coating for a cooking product includes an oxycarbofluoride coating. The oxycarbofluoride coating has a composition comprising at least one metal oxide, carbon and fluorine and can be applied to a substrate using a sol-gel process.
    Type: Grant
    Filed: July 8, 2008
    Date of Patent: June 21, 2011
    Assignee: General Electric Company
    Inventors: Venkat Subramaniam Venkataramani, Salil Mohan Joshi, Nagaveni Karkada, Sundeep Kumar
  • Patent number: 7964522
    Abstract: An F-doped silica glass, a process for making the glass, an optical member comprising the glass, and an optical system comprising such optical member. The glass material comprises 0.1-5000 ppm by weight of fluorine. The glass material according to certain embodiments of the present invention has low polarization-induced birefringence, low LIWFD and low induced absorption at 193 nm.
    Type: Grant
    Filed: August 14, 2007
    Date of Patent: June 21, 2011
    Assignee: Corning Incorporated
    Inventors: Lisa Anne Moore, Charlene Marie Smith
  • Publication number: 20110111944
    Abstract: The invention provides a crystallizable glass, a crystallized glass, and manufacturing methods thereof. The crystallizable glass can be crystallized in a short period of time, and can maintain its glass shape and its surface condition during a crystallization process. The crystallized glass has good mechanical strength, an adequate thermal expansion coefficient that allows the crystallized glass to be used as a construction material, less content of alkali-metal oxides, and good chemical durability. The MgO—Al2O3—SiO2-based crystallizable glass and crystallized glass contain, by mass percent, 55.0-65.0% SiO2, 8.0-14.0% Al2O3, 10.0-20.0% MgO, 1.5-6.0% CaO, 1.0-2.2% Li2O, 0.7-3.0% Na2O, 2.5-4.0% K2O, and 1.5-3.0% F.
    Type: Application
    Filed: October 25, 2010
    Publication date: May 12, 2011
    Applicant: Huzhou Ta Hsiang Glass Products Co., Ltd.,
    Inventors: Kuo-Chuan Hsu, Chao Qu
  • Publication number: 20110111260
    Abstract: A glass substrate for information recording medium, said glass substrate being composed of an aluminosilicate glass containing 60-75% by mass of SiO2, 5-18% by mass of Al2O3, 3-10% by mass of Li2O, 3-15% by mass of Na2O and 0.5-8% by mass of ZrO2 relative to the entire glass components. The glass substrate for information recording medium contains neither As (arsenic) nor Sb (antimony), while containing at least one substance selected from the group consisting of SO3 (sulfurous acid), F (fluorine), Cl (chlorine), Br (bromine) and I (iodine), as a refining agent. The molar ratio of the total amount of the refining agent to the amount of Al2O3 is within the range of 0.02-0.20.
    Type: Application
    Filed: July 3, 2009
    Publication date: May 12, 2011
    Applicant: Konica Minolta Opto, Inc.
    Inventor: Hideki Kawai
  • Publication number: 20110111161
    Abstract: A glass substrate for information recording medium, said glass substrate being composed of an alminosilicate glass containing 60-75% by mass of SiO2, 5-18% by mass of Al2O3, 3-10% by mass of Li2O, 3-15% by mass of Na2O and 0.5-8% by mass of ZrO2 relative to the entire glass components. The glass substrate for information recording medium contains neither As (arsenic) nor Sb (antimony), while containing at least one substance selected from the group consisting of SO3 (sulfurous acid), F (fluorine), Cl (chlorine), Br (bromine) and I (iodine), as a refining agent. The molar ratio of the total amount of the refining agent to the amount of ZrO2 is within the range of 0.05-0.50.
    Type: Application
    Filed: July 3, 2009
    Publication date: May 12, 2011
    Applicant: Konica Minolta Opto, Inc.
    Inventor: Hideki Kawai
  • Publication number: 20110098172
    Abstract: The invention discloses boron-free neutral glasses having the composition (in % by weight, based on oxide) 65-72 SiO2, 11-17 Al2O3, 0.1-8 Na2O, 3-8 MgO, 4-12 CaO and 0-10 ZnO, a ratio CaO/MgO of 1.4 to 1.6, and having a hydrolytic resistance in accordance with DIN ISO 719 in class 1 and an acid resistance in accordance with DIN 12116 and an alkali resistance in accordance with DIN ISO 695 at least in class 2.
    Type: Application
    Filed: October 25, 2010
    Publication date: April 28, 2011
    Inventor: Peter BRIX
  • Publication number: 20110053754
    Abstract: A glass composition useful in preparing fiberglass comprises 12 to 25 weight % CaO; 12 to 16 weight % Al2O3; 52 to 62 weight % SiO2; 0.05 to 0.8 Fe2O3; and greater than 2 up to about 8 weight % alkali metal oxide.
    Type: Application
    Filed: September 1, 2009
    Publication date: March 3, 2011
    Inventors: Jeffrey Shock, Elam Leed, Jonathan McCann
  • Publication number: 20110003122
    Abstract: A photovoltaic module having a fluoride-containing covering, substrate or superstrate glass is disclosed. The weight ratio X of the iron content to the fluorine content is preferably from 0.001 to 0.6. The glass to which fluoride has been added can be any glass suitable for photovoltaic modules, for example a soda-lime glass, a borosilicate glass or an aluminosilicate glass.
    Type: Application
    Filed: July 1, 2010
    Publication date: January 6, 2011
    Inventors: Oliver HOCHREIN, Axel Engel, Jochen Alkemper
  • Publication number: 20100184345
    Abstract: The invention relates to reinforcing glass yarns of which the composition comprises the following components within the limits defined below expressed in weight percent: SiO2 62-72% Al2O3 4-11% CaO 8-22% MgO 1-7% Na2O + K2O + Li2O 0-9% BaO + SrO 0-4% B2O3 0-4% F2 0-2% Other components: TiO2 + ZrO2 + 0-4% Fe2O3 (total iron) + P2O5 + MnO + Cr2O3 + MoO3 + ZnO + SO3 These yarns consist of an economical glass offering an excellent comprise between its mechanical properties represented by the specific Young's modulus and its drawing conditions. The invention also relates to the glass composition suitable for manufacturing said glass yarns, the basic structures of such yarns, in particular meshes, fabrics and mats, and the composites incorporating such yarns.
    Type: Application
    Filed: May 15, 2008
    Publication date: July 22, 2010
    Applicant: Saint-Gobain Technical Fabrics Europe
    Inventors: Jerome Lalande, Anne Berthereau
  • Patent number: 7687418
    Abstract: The X-ray opaque glass is characterized by a composition, in mol %, of SiO2, 75-98; Yb2O3, 0.1 to 40; and ZrO2, 0 to 40. Preferred embodiments of the glass are free of Al2O3 and B2O3. The glass is produced from the glass batch by melting at a temperature of at least 1500° C. in an iridium or iridium alloy vessel with the assistance of high-frequency radiation. In preferred embodiments of the glass production process at least one raw material ingredient is present in the batch as a nanoscale powder. The glass is useful in dental applications, optical applications, and biomedical applications, or for photovoltaics, or as a target material in PVD processes.
    Type: Grant
    Filed: December 28, 2004
    Date of Patent: March 30, 2010
    Assignee: Schott AG
    Inventors: Ulrich Peuchert, Uwe Kolberg, Joern Besinger
  • Publication number: 20090286666
    Abstract: Glass-ceramic compositions exhibiting high reliability and tensile strength are described. The compositions can include crystal phases including roedderite and/or potassium fluorrichterite. The glass-ceramic compositions are bioactive, and can be used as components of a wide variety of biomedical devices such as dental restorations.
    Type: Application
    Filed: May 13, 2009
    Publication date: November 19, 2009
    Applicant: THE OHIO STATE UNIVERSITY RESEARCH FOUNDATION
    Inventors: Isabelle L. Denry, Julie A. Holloway
  • Publication number: 20090286667
    Abstract: An optically detectable, floatable arsenic- and antimony-free, glazable lithium-aluminosilicate glass that can be prestressed and the glass ceramic converted therefrom are described. The glass or the glass ceramic has a composition (in % by weight based on oxide) of essentially SiO2 55-69, Al2O3 19-25, Li2O 3.2-5, Na2O 0-1.5, K2O 0-1.5, MgO 0-2.2, CaO 0-2.0, SrO 0-2.0, BaO 0-2.5, ZnO 0-<1.5, TiO2 1-3, ZrO2 1-2.5, 0.1-<1, ?TiO2+ZrO2+SnO2 2.5-5, P2O5 O-3, Nd2O3 0.01-0.6, CoO 0-0.005, F 0-1, B2O3 0-2.
    Type: Application
    Filed: February 26, 2009
    Publication date: November 19, 2009
    Inventors: Friedrich SIEBERS, Hans-Werner Beudt, Bernd Rudinger, Gerbard Lautenschlager, Klaus Schneider, Michael Jacquorie, Wolfgang Schmidbauer
  • Patent number: 7592063
    Abstract: For a substrate having fine convexoconcave patterns on its surface, the dimensions of the convexoconcave patterns in a vertical direction of a quartz glass substrate are controlled to be uniform with extreme accuracy and over the entire substrate surface. The quartz glass substrate is made to have a fictive temperature distribution of at most 40° C. and a halogen concentration of less than 400 ppm, and the etching rate of the surface of the quartz glass substrate is made uniform, whereby the dimensions of the convexoconcave patterns in a vertical direction of the quartz glass substrate are controlled to be uniform with good accuracy and over the entire substrate surface.
    Type: Grant
    Filed: September 5, 2006
    Date of Patent: September 22, 2009
    Assignee: Asahi Glass Company, Limited
    Inventors: Yoshiaki Ikuta, Shinya Kikugawa