And Zinc Or Zirconium Patents (Class 501/67)
  • Patent number: 6664203
    Abstract: The present invention can provide an alkali free glass containing as a refining agent, a tin oxide and at least one selected from the group consisting of a cerium oxide, a manganese oxide, a tungsten oxide, a tantalum oxide and a niobium oxide.
    Type: Grant
    Filed: December 21, 2001
    Date of Patent: December 16, 2003
    Assignee: Nippon Sheet Glass Co., Ltd.
    Inventors: Yukihito Nagashima, Yoshikazu Toshikiyo
  • Patent number: 6656861
    Abstract: Provided are glass compositions uniquely applicable for the preparation of ultrafine fibers for filtration and separation applications. The glasses meet all physical and chemical criteria, including that for biodissolution rate.
    Type: Grant
    Filed: November 2, 2000
    Date of Patent: December 2, 2003
    Assignee: Johns Manville International, Inc.
    Inventors: Jon Frederick Bauer, Foster Laverne Harding, Harry Hand Russell, III
  • Patent number: 6635592
    Abstract: A tungsten sealing glass for use in a fluorescent lamp has a composition of, by mass percent, 65-76% SiO2, 10-25% B2O3, 2-6% Al2O3, 0.5-5.8% MgO+CaO+SrO+BaO+ZnO, 3-8% Li2O+Na2O+K2O, 0.01-4% Fe2O3+CeO2, 0-10% TiO2+Sb2O3+PbO, and 0-2% ZrO2, where Na2O/(Na2O+K2O)≦0.6.
    Type: Grant
    Filed: July 27, 2001
    Date of Patent: October 21, 2003
    Assignee: Nippon Electric Glass Co., Ltd.
    Inventors: Hiroyuki Kosokabe, Koichi Hashimoto
  • Patent number: 6630417
    Abstract: The porcelain of the present invention comprises 5 to 70% by weight of a non-oxide ceramic filler and 30 to 95% by weight of a borosilicate glass having a glass transition temperature of 800° C. or lower, wherein a weight loss per unit surface area of said non-oxide ceramics is not more than 0.15 g/cm2 after dipping said non-oxide ceramic having purity of not less than 96% by weight for five minutes in a glass melt obtained by melting said borosilicate glass with heating at 1200° C. Since the porcelain composition can be fired at a low temperature together with a low-resistance metal, the resulting porcelain has a high thermal conductivity, a low dielectric constant, a high heat dissipation property and a reduced apparent signal delay in a high frequency signal and is suited for use as an insulating board in a wiring board.
    Type: Grant
    Filed: May 30, 2001
    Date of Patent: October 7, 2003
    Assignee: Kyocera Corporation
    Inventors: Shinya Kawai, Hiromi Iwachi, Yoshitake Terashi
  • Publication number: 20030181309
    Abstract: An alkaline-earth aluminosilicate glass having a composition (in % by weight, based on oxide) of SiO2>55 - 64; Al2O3 13 - 18; B2O3 0 - 5.5; M5O 0 - 7; CaO 5.5 - 14; SrO 0 - 8; BaO 6 - 17; ZrO2 0 - 2; CeO2 0 - 0.3; TiO2 0 - 0.5; CoO 0.01 - 0.035; Fe2O3 0.005 - 0.05; and NiO 0 - 0.
    Type: Application
    Filed: February 3, 2003
    Publication date: September 25, 2003
    Applicant: SCHOTT GLAS
    Inventors: Christian Kunert, Karin Naumann, Franz Ott, Ottmar Becker
  • Publication number: 20030148868
    Abstract: Objects of the present invention are:
    Type: Application
    Filed: June 27, 2002
    Publication date: August 7, 2003
    Inventors: Lionel Beunet, Sebastien Hyvart, Fabrice Minier, Sophie Peschiera, Christophe Remy
  • Patent number: 6589896
    Abstract: A lead- and arsenic-free borosilicate glass having an improved melting characteristic is described. The melting rate of the glass was improved dramatically by making the composition substantially free of MgO and CaO and adding 1.0 to 4.0 weight percent BaO. The improved melting characteristic yielded up to a ninety-nine percent reduction in the number of unmelted batch stones.
    Type: Grant
    Filed: June 6, 2002
    Date of Patent: July 8, 2003
    Assignee: Osram Sylvania Inc.
    Inventor: Richard C. Marlor
  • Publication number: 20030114292
    Abstract: The invention concerns an optical colored glass of the composition (in % in weight on oxide basis) SiO2 50-62; K2O 10-25; Na2O 0-14; Al2O3 0-2; B2O3 3-5; ZnO 13.5-37; F 0-1; TiO2 0-7; In2O30-2; Ga2O3 0-2; SO30-1; SeO20-1; C 0-1; MIMIIIY2II 0.1-3, whereby MI=Cu+ and/or Ag+ and/or MIII=In3+ and/or Ga3+ and/or Al3+ and/or YII═S2− and/or Se2− and at least 0.1% in weight of the oxide (M2O3) of the MIII, which is/are present in MIMIIIYII2, and with at least 0.2% in weight of the oxide, of the YII, which is/are present in MIMIIIYII2.
    Type: Application
    Filed: August 20, 2002
    Publication date: June 19, 2003
    Inventors: Uwe Kolberg, Ruediger Hentschel, Simone Ritter
  • Patent number: 6562523
    Abstract: A narrowly defined range of zinc silicate glass compositions is found to produce High Energy Beam Sensitive-glass (HEBS-glass) that possesses the essential properties of a true gray level mask which is necessary for the fabrication of general three dimensional microstructures with one optical exposure in a conventional photolithographic process. The essential properties are (1) A mask pattern or image is grainiless even when observed under optical microscope at 1000× or at higher magnifications. (2) The HEBS-glass is insensitive and/or inert to photons in the spectral ranges employed in photolithographic processes, and is also insensitive and/or inert to visible spectral range of light so that a HEBS-glass mask blank and a HEBS-glass mask are permanently stable under room lighting conditions. (3) The HEBS-glass is sufficiently sensitive to electron beam exposure, so that the cost of making a mask using an e-beam writer is affordable for many applications.
    Type: Grant
    Filed: February 18, 2000
    Date of Patent: May 13, 2003
    Assignee: Canyon Materials, Inc.
    Inventors: Che-Kuang Wu, Laurie Ann Wu
  • Publication number: 20030087745
    Abstract: The invention relates to a borosilicate glass of high chemicals resistance, having a composition (in % by weight, based on oxide) of SiO2 70-77; B2O3 6 -<11.5; Al2O3 4-8.5; Li2O 0-2; Na2O 4-9.5; K2O 0-5; with Li2O+Na2O+K2O 5-11; MgO 0-2; CaO 0-2; with MgO+CaO 0-3; ZrO2 0-<0.5; CeO2 0-1.
    Type: Application
    Filed: August 13, 2002
    Publication date: May 8, 2003
    Inventors: Ulrich Peuchert, Christian Kunert, Reiner Bartsch
  • Publication number: 20030087744
    Abstract: Panel glass, for a cathode ray tube, which has an SrO/(SrO+BaO) ratio of from 0.35 to 0.70, an X-ray absorption coefficient of 36.0 cm−1 or more at the wavelength of 0.6 angstrom, wherein Na2O/R2O, K2O/R2O and Li2O/R2O (R2O: Na2O+K2O+Li2O) molar ratios fall within a range surrounded by the points A (0, 0.2, 0.8), B (0.2, 0.2, 0.6), C (0.4, 0.6, 0), D (0.2, 0.8, 0) and E (0, 0.4, 0.6) in the ternary phase diagram as shown in FIG. 1.
    Type: Application
    Filed: October 23, 2002
    Publication date: May 8, 2003
    Inventors: Hiroshi Komori, Hiroki Yamazaki
  • Publication number: 20030087746
    Abstract: The invention concerns alkali-poor or alkali-free alkaline earth aluminum borosilicate glasses having the following composition (weight percent based on oxides) SiO2>55-70; B2O3 1-8; Al2O3 10-18; Na2O>1-5; K2O 0-4; with Na2O+K2O >1-5; MgO 0-5; CaO 3-<8; SrO 0.1-8; BaO 4.5-12; with MgO+CaO+SrO+BaO 10-25; SnO2 0-15; ZrO2 0-3; TiO2 0-2; ZnO 0-2. Said glasses can be used especially as substrates in thin layer photovoltaics, especially for CIS-based solar cells.
    Type: Application
    Filed: August 2, 2002
    Publication date: May 8, 2003
    Inventors: Simone Ritter, Ulrich Peuchert
  • Publication number: 20030078154
    Abstract: The lead-free glass tubing of the SiO2—B2O3—R2O—BaO—ZnO—TiO2 system has a composition, in percent by weight on an oxide basis, consisting essentially of: SiO2, 34 to 52; B2O3, 10 to 25; Al2O3, 0 to 25; Li2O, 2 to 6; Na2O, 4 to 10; K2O, 2 to 6; CaO, 0 to 4; BaO, 1 to 5; ZnO, 4 to 12; TiO2, 2 to 6, and at least one refining agent in an effective amount for refining. An encapsulated diode consisting of a diode encapsulated with this lead-free glass tubing is also disclosed.
    Type: Application
    Filed: October 10, 2002
    Publication date: April 24, 2003
    Inventors: Peter Brix, Helmar Vetter, Oliver Fritz
  • Publication number: 20030064874
    Abstract: The present invention provides a composition for use in forming an opaque porcelain enamel coating on a metal substrate. A porcelain enamel coating formed using a composition according to the invention readily adheres to metal substrates such as, for example, steel, that are degreased-only. Furthermore, such a porcelain enamel coating displays an acid resistance of A according to ISO 2722 and good easy-to-clean properties. The composition according to the invention includes a glass component including by weight from about 45% to about 55% SiO2, from about 8% to about 17% B2O3, from about 1.8% to about 17.7% SrO+BaO, from about 1.9% to about 10% Li2O, up to about 6% ZrO2, from about 2% to about 11% TiO2, from about 1.5% to about 6% K2O, from about 1% to about 4% MoO3, from about 0.3% to about 13% Na2O, up to about 2% NiO, up to about 3% Al2O3, up to about 2.9% MnO, up to about 0.8% CoO, up to about 3% MgO, up to about 5% CaO, and up to about 2% Sb2O3.
    Type: Application
    Filed: April 8, 2002
    Publication date: April 3, 2003
    Applicant: Ferro France - S.A.R.L.
    Inventors: Jean-Christophe Eckmann, Moha Ait Ali Oumoumene, Francois Roques
  • Publication number: 20030050173
    Abstract: A silicate based composition for optical glass used as a substrate for thin film optical interference filters having a stable transmission band center wavelength and bandwidth has a relatively high coefficient of thermal expansion, high Young's modulus and high optical transmittance in the near infrared (NIR) wavelength range of about 950 nm to about 1600 nm. The coefficient of thermal expansion of the glass composition is adjustable to particular values to result in minimal wavelength shift in filters made by depositing thin films of particular dielectric materials onto a substrate made of the glass, the composition being varied from a preferred baseline composition consisting of about 43.2% SiO2, 7% Al2O3, 12.7% CaO, 7.3% SrO, 7.8% Li2O, 13.2% Na2O, 8.0% K2O, 0.7% ZrO, and 0.1% Sb2O3, the baseline composition having a coefficient of thermal expansion of about 112×10−7/° C. over the temperature range of −30° C. to +70° C., a Young's modulus E of 88.
    Type: Application
    Filed: August 14, 2001
    Publication date: March 13, 2003
    Inventor: Jacob W. Lin
  • Patent number: 6521557
    Abstract: An aluminosilicate transparent glass has corrosion resistance in the form of mass loss of 4.0 mg or below per 1cm2 of the surface of a specimen upon holding the specimen for five hours in sodium hydroxide solution having concentration of 300 mg(L under test pressure of 50 MPa at 250° C. The glass has a coefficient of thermal expansion within a range from 35×10−7/° C. to 50×10−7/° C. within a temperature range from 100° C to 300° C. The glass has also powdered glass mass loss rate of 0.1% or below in terms of water resistance, acid resistance and alkali resistance.
    Type: Grant
    Filed: September 27, 2000
    Date of Patent: February 18, 2003
    Assignee: Kabushiki Kaisha Ohara
    Inventor: Hiroyuki Minamikawa
  • Patent number: 6517807
    Abstract: This invention relates to a process for producing zeolite-bound high silica zeolites and the use of the zeolite-bound high silica zeolite produced by the process for hydrocarbon conversion. The process is carried out by forming an extrudable paste comprising a mixture of high silica zeolite in the hydrogen form, water, silica, and optionally an extrusion aid, extruding the extrudable paste to form silica-bound high silica zeolite extrudates, and then converting the silica of the binder to a zeolite binder. The zeolite-bound high silica zeolite produced by the process comprises high silica zeolite crystals that are bound together by zeolite binder crystals. The zeolite-bound high silica zeolite finds particular application in hydrocarbon conversion processes, e.g., catalytic cracking, alkylation, disproportionation of toluene, isomerization, and transalkylation reactions.
    Type: Grant
    Filed: November 14, 2001
    Date of Patent: February 11, 2003
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Johannes P. Verduijn, Gary David Mohr
  • Patent number: 6514893
    Abstract: High-strength sinterable lithium disilicate glass ceramics are described which can be further processed in particular by pressing in the viscous state to shaped dental products.
    Type: Grant
    Filed: October 19, 1999
    Date of Patent: February 4, 2003
    Assignee: Ivoclar AG
    Inventors: Marcel Schweiger, Martin Frank, Volker Rheinberger, Wolfram Hoeland
  • Patent number: 6511932
    Abstract: A graded index lens is obtained by treating a raw glass material having a rod shape by ion exchange using silver to form a refractive index distribution in the radial direction of the rod, wherein the raw glass material comprises a glass composition of the following components: 15<Na2O≦30 mol %; 10<Al2O3≦25 mol %; 27.5≦SiO2≦55 mol %; 3≦B2O3≦18 mol %; 2.5≦MgO≦18 mol %; 0≦Ta2O5≦5 mol %; 0≦La2O3≦3 mol %; 0≦BaO≦3 mol %; and 0≦ZrO2≦3 mol %.
    Type: Grant
    Filed: December 1, 2000
    Date of Patent: January 28, 2003
    Assignee: Nippon Sheet Glass Co., Ltd.
    Inventors: Jun Yamaguchi, Shigeo Kittaka
  • Publication number: 20020193231
    Abstract: Provided are glass compositions uniquely applicable for the preparation of ultrafine fibers for filtration and separation applications. The glasses meet all physical and chemical criteria, including that for biodissolution rate.
    Type: Application
    Filed: March 14, 2002
    Publication date: December 19, 2002
    Inventor: Jon Frederick Bauer
  • Patent number: 6468933
    Abstract: An alkali-free glass essentially consists of, by weight percent, 40-70% SiO2, 6-25% Al2O3, 5-20% B2O3, 0-10% MgO, 0-15% CaO, 0-30% BaO, 0-10% SrO, 0-10% ZnO, 0.05-2% SnO2, and 0.005-1% Cl2, and substantially contains no alkali metal oxide.
    Type: Grant
    Filed: September 21, 1999
    Date of Patent: October 22, 2002
    Assignee: Nippon Electric Glass Co., Ltd.
    Inventors: Toshiharu Narita, Hiroki Yamazaki
  • Publication number: 20020151426
    Abstract: An alkali-free glass consists essentially of, in mass percent, 58-70% SiO2, 10-19% Al2O3, 6.5-15% B2O3, 0-2% MgO, 3-12% CaO, 0.1-5% BaO, 0-4% SrO, 0.1-6% BaO+SrO, 0-5% ZnO, 5-15% MgO+CaO+BaO+SrO+ZnO, 0-5% ZrO2, 0-5% TiO2, and 0-5% P2O5. The alkali-free glass contains substantially no alkali metal oxide and has a density of 2.45g/cm3 or less, an average coefficient of thermal expansion of 25×10−7/° C.-36×10−7/° C. within a temperature range between 30 and 380° C., and a strain point not lower than 640° C.
    Type: Application
    Filed: January 30, 2002
    Publication date: October 17, 2002
    Applicant: NIPPON ELECTRIC GLASS CO., LTD
    Inventors: Takashi Murata, Shinkichi Miwa
  • Patent number: 6465381
    Abstract: The invention relates to an alkali-free aluminoboro-silicate glass which has the following composition (in % by weight, based on oxide): SiO2 >60-65; B2O3 6.5-9.5; Al2O3 14-21; MgO 1-8; CaO 1-6; SrO 1-9; BaO 0.1-3.5; with MgO+CaO+SrO+BaO 8-16; ZrO2 0.1-1.5; SnO2 0.1-1; TiO2 0.1-1; CeO2 0.01-1. The glass is particularly suitable for use as a substrate glass in display technology.
    Type: Grant
    Filed: July 24, 2000
    Date of Patent: October 15, 2002
    Assignee: Schott Glas
    Inventors: Gerhard Lautenschläger, Klaus Schneider, Thomas Kloss, Andreas Sprenger
  • Publication number: 20020123420
    Abstract: The present invention can provide an alkali free glass containing as a refining agent, a tin oxide and at least one selected from the group consisting of a cerium oxide, a manganese oxide, a tungsten oxide, a tantalum oxide and a niobium oxide.
    Type: Application
    Filed: December 21, 2001
    Publication date: September 5, 2002
    Applicant: NIPPON SHEET GLASS CO., LTD.
    Inventors: Yukihito Nagashima, Yoshikazu Toshikiyo
  • Patent number: 6436858
    Abstract: The principal object of the present invention is organic lens molds, constituted wholly or in part of at least one specific inorganic glass, advantageously strengthened by a chemical tempering or a thermal tempering. Said glass has the following composition, expressed in percentages by weight: SiO2 56-66, Al2O3 2.5-10, B2O3 0.5-7, Li2O 0-3, Na2O 8-15, K2O 3-12, with Li2O+Na2O+K2O 12-20, ZnO 2-12, MgO 0-3, TiO2 0-0.5, ZrO2 1-9, CaO 0-1, BaO 0-2, SrO 0-2, with MgO+CaO+SrO+BaO 0-5, Cl 0-0.5, As2O3+sb2O3 0-1. The invention also deals with novel inorganic glasses which have the above composition with a single exception relative to the Al2O3 content: Al2O3 2.5-4.
    Type: Grant
    Filed: January 4, 2000
    Date of Patent: August 20, 2002
    Assignee: Corning S.A.
    Inventors: Pascale Laborde, Daniel L. G. Ricoult
  • Patent number: 6428614
    Abstract: Opaque porcelains for use with metal cores in the manufacture of PFM restorations. The porcelains exhibit a coefficient of thermal expansion (CTE) substantially equal to or slightly above the CTE of the metal to which it is applied. The porcelains exhibit a CTE equal to or up to about 1.5×10−6/° C. higher than the dental alloys to which they are applied as the opaque. The porcelains are fabricated from a mixture of two frit compositions. A high expansion, leucite containing frit is combined with a low melting glass frit to provide a porcelain having an expansion in the range of 16.9 to about 18×10−6/° C. in the temperature range of 25°-500° C.
    Type: Grant
    Filed: June 29, 2000
    Date of Patent: August 6, 2002
    Assignee: Jeneric/Pentron, Inc.
    Inventors: Dmitri Brodkin, Carlino Panzera, Paul Panzera
  • Patent number: 6420290
    Abstract: The object of the present invention is colorless inorganic glasses, as well as products manufactured from said glasses. Said glasses are of the type containing copper halides or copper cadmium halides and having a sharp optical absorption cutoff between 370 nm and 425 nm essentially having the composition below, expressed in cationic percentages: 23-73% SiO2 15-45% B2O3  0-24% Al2O3  0-12% Li2O  0-20% Na2O  0-12% K2O 0-5% CaO + BaO + SrO 0.125-1%    Cu2O 0-1% CdO 0-5% ZrO2 with   0-1.75% Cl 0.
    Type: Grant
    Filed: February 11, 2000
    Date of Patent: July 16, 2002
    Assignee: Corning S.A.
    Inventors: Yves A. H. Brocheton, Christophe Remy
  • Patent number: 6417124
    Abstract: The invention relates a alkali-free aluminoborosilicate glasses having the following composition (in % by weight, based on oxide): SiO2 50-70, B2O3 0.5-15, Al2O3 10-25, MgO 0-10, CaO 0-12, SrO 0-12, BaO 0-15, with MgO+CaO+SrO+BaO 8-26, ZnO 0-10, ZrO2 0-5, TiO2 0-5, SnO2 0-2, MoO3 0.05-2. The glasses are particularly suitable as substract glasses for display and photovoltaic applications.
    Type: Grant
    Filed: August 21, 2000
    Date of Patent: July 9, 2002
    Assignee: Schott Glas
    Inventors: Ulrich Peuchert, Thomas Pfeiffer, Peter Brix, Hildegard Roemer
  • Patent number: 6410633
    Abstract: An antibacterial glass is a ZnO—B2O3—SiO2 glass and includes 0-6 wt % Na2O. Typically, the antibacterial glass is used as an antibacterial agent which is filled into a resin.
    Type: Grant
    Filed: February 3, 2000
    Date of Patent: June 25, 2002
    Assignee: Nippon Electric Glass Co., Ltd.
    Inventors: Hajime Hikata, Kazuyoshi Shindo, Toshio Yamanaka
  • Patent number: 6402156
    Abstract: Glass-ceramic sealants for ceramic membrane reactors, ceramic membrane sealed to holders or substrates and methods of making seals between two ceramic materials or between a ceramic and a metal or metal alloy are provided. These sealants combine silicate glass-ceramic materials with selected metal oxides and, optionally, materials similar or identical to the materials being sealed, and employ thermal processing so that the resultant materials will have a thermal expansion coefficient that substantially matches the thermal expansion coefficients of the two materials. Surfaces of the ceramic sealant that are exposed to reactive atmospheres can be protected by providing a metal or metallic alloy layer over the ceramic seal.
    Type: Grant
    Filed: September 20, 1999
    Date of Patent: June 11, 2002
    Assignee: Eltron Research, Inc.
    Inventors: James B. Schutz, Thomas F. Barton
  • Publication number: 20020065187
    Abstract: The subject of the invention is a glass sheet intended to be thermally toughened, the matrix of which is of the silica-soda-lime type, having an expansion coefficient &agr; of greater than 100×10−7 K−1, a Young's modulus E of greater than 60 GPa and a thermal conductivity k of less than 0.9 W/m.K.
    Type: Application
    Filed: November 26, 2001
    Publication date: May 30, 2002
    Applicant: SAINT-GOBAIN GLASS FRANCE
    Inventors: Frederic Bordeaux, Lucas Duffrene
  • Patent number: 6391810
    Abstract: Lead- and barium-free crystal glass for the manual or machine production of high-grade glass objects with a refractive index higher than 1.52 and a density of at least 2.45 g/cc, wherein the crystal glass comprises the following components in weight percent. SiO2 59.0-71.0 TiO2 0.001-8.0  Al2O3 0.01-4.0  CaO  2.0-10.0 MgO 0.5-8.0 ZnO 0.01-11.0 K2O 0.08-11.0 Na2O  3.0-15.5 Sb2O3 or AS2O3 0.001-1.5  SrO 0.001-0.1  B2O3 0.01-3.0  Li2O 0.01-2.0  SO42− 0.0008-1.2   F− 0.008-0.2  as well as at least two components selected from the group consisting of Er2O3, Nd2O3, CeO2, CoO, Pr2O3, SeO, NiO and MnO and has a moisture content of 0.025 to 0.07% by weight.
    Type: Grant
    Filed: July 27, 2000
    Date of Patent: May 21, 2002
    Assignee: F. X. Nachtmann Bleikristallwerke GmbH
    Inventor: Armin Lenhart
  • Patent number: 6391809
    Abstract: The present invention is directed at a copper aluminosilicate glass, having coefficients of thermal expansion (CTEs) of between 20-82×10−7/° C. (over a range of 25-500° C.) and a softening points in the range of 660-1000° C., being suitable for use as a sealing glass, especially for borosilicate glass, and having a composition consisting essentially, in terms of weight percent on an oxide basis, of 35-68 SiO2, 3-25 Al2O3, 2-26 B2O3, 0-20 R2O, 1-30 RO, 2-33 CuO, 0-4 F, 0-10 MxOy, where R2O is an alkali oxide selected from the group consisting of Li2O, Na2O, and K2O, and RO is an alkaline earth oxide selected from the group consisting of CaO, MgO, ZnO, SrO, and BaO, and MxOy is a transition metal oxide selected from the group consisting of Co2O3, TiO2, NiO, MnO2, and Fe2O3.
    Type: Grant
    Filed: June 1, 2000
    Date of Patent: May 21, 2002
    Assignee: Corning Incorporated
    Inventor: Dianna M. Young
  • Publication number: 20020058578
    Abstract: A glass ceramic comprises a main crystal phase which comprises at least one selected from a group consisting of &bgr;-eucryptite (&bgr;-Li2O.Al2O3.2SiO2), &bgr;-eucryptite solid solution (&bgr;-Li2O.Al2O3.2SiO2 solid solution), &bgr;-quartz (&bgr;-SiO2), and &bgr;-quartz solid solution (&bgr;-SiO2 solid solution), wherein an average grain size of the main crystal phase is less than 5 &mgr;m, and a coefficient of thermal expansion thereof is −30×10−7 to −90×10−7/° C. in a temperature range of −40° C. to +160° C., and a hysteresis of the coefficient of thermal expansion is not more than 20 ppm.
    Type: Application
    Filed: November 29, 2000
    Publication date: May 16, 2002
    Applicant: Kabushiki Kaisha Ohara
    Inventor: Ayako Shindo
  • Patent number: 6387832
    Abstract: Transition metal NZP type compounds are synthesized. Examples of these compounds include MnZr4(PO4)6, FeZr4(PO4)6, CoZr4(PO4)6, NiZr4(PO4)6, and CuZr4(PO4)6. These compounds are synthesized by the Xerogel process. These transition metal NZP type compounds can be used as colorants in applications such as ceramic glazes where high thermal stability of the colorant is important.
    Type: Grant
    Filed: July 31, 2000
    Date of Patent: May 14, 2002
    Assignee: The Penn State Research Foundation
    Inventors: Sridhar Komarneni, William W. Gould
  • Patent number: 6376402
    Abstract: The glass or glass-ceramic has the following composition (in % by weight based on oxide content): SiO2, 25 to 50; B2O3, >5 to 16; Al2O3, 10 to 17; P2O5, 0 to 8; Li2O,5 to 15; Na2O, 0 to 10; K2O, 0 to 10; MgO, 10 to 30; CaO, 0 to 10; SrO, 0 to 8; ZnO, 0 to 8; TiO2, 0.1 to 10; ZrO2, 0 to 8; and at least one refining agent, in an amount as needed according to its purpose. The sum total amount of divalent metal oxides (RO) present is less or equal to than 45% by weight based on oxide content and the sum total amount of alkali metal oxides (R2O) present is less than or equal to 30% by weight based on oxide content. The glass or glass-ceramic material generally has elasticity modulus values (E)>90×103 N/mm2 and <125×103 N/mm2, specific elasticity modulus values (E/&rgr;)>30×105 N cm/g and <45×105 N cm/g and thermal expansion coefficient values (&agr;20/300)>7.0×10−6/K and <11.0×10−6/K.
    Type: Grant
    Filed: April 19, 2000
    Date of Patent: April 23, 2002
    Assignee: Schott Glas
    Inventors: Wolfgang Pannhorst, Ute Woelfel, Silke Wolff
  • Patent number: 6372155
    Abstract: The object of the present invention is to provide an oxide glass capable of exhibiting a long lasting afterglow and photostimulated phosphorescence, whereby energy can be accumulated by radiation excitation, for example, by &ggr;-rays, X-rays, UV-rays, etc. and light emission can be continued for a long time even after stopping the excitation. That is, the present invention relates to an oxide glass capable of exhibiting a long lasting afterglow and photostimulated luminescence, characterized by a constitutional composition comprising, at least, terbium oxide (Tb2O3) or manganese oxide (MnO), gallium oxide (Ga2O3) or aluminum oxide (Al2O3), alkali metal oxide or alkaline earth metal oxide and boron oxide (B2O3) or silicon oxide (SiO2) or zinc oxide (ZnO).
    Type: Grant
    Filed: November 30, 1999
    Date of Patent: April 16, 2002
    Assignee: Sumita Optical Glass, Inc.
    Inventors: Masaaki Yamazaki, Yoshinori Yamamoto, Naruhito Sawanobori, Shinobu Nagahama
  • Patent number: 6358873
    Abstract: A glass for tungsten halogen lamp glass envelopes, glass filter lenses, and glass filters consisting essentially in terms of weight percent on the oxide basis, of about 50-62% SiO2, 10-17% Al2O3, 0-6% B2O3, 3.6-10% CaO, 0-7.5% MgO, 0.1-0.3% SrO, 2.4-18% BaO, 0-1% ZnO, 1-8% Nd2O3. The glass exhibits the following physical properties: strain point between about 665° C. to about 750° C., coefficient of thermal expansion to the set point of between about 49-59×10−7/° C., liquidus temperature below 1320° C., viscosity at liquidus temperature greater than 2,000 poises, and transmission at 585 nm of between 5-60% for a 1.2 mm thickness. The lamp color temperature for a tungsten halogen lamp containing a glass envelope, a glass filter lens, or a glass filter prepared from the glass composition is increased from about 3 to 7% above a similar glass with no Nd2O3, and the total visible lumen loss is limited to less than about 10%.
    Type: Grant
    Filed: June 15, 2000
    Date of Patent: March 19, 2002
    Assignee: Corning Incorporatedc
    Inventor: Ronald L. Stewart
  • Publication number: 20020032117
    Abstract: An alkali-free aluminoborosilicate glass which has the following composition (in % by weight, based on oxide): silicon dioxide (SiO2)>58-65, boric oxide (B2O3)>6-10.5, aluminum oxide (Al2O3)>14-25, magnesium oxide (MgO) 0-<3, calcium oxide (CaO) 0-9, and barium oxide (BaO)>3-8, with magnesium oxide (MgO)+calcium oxide (CaO)+barium oxide (BaO) 8-18, and zinc oxide ( ZnO) 0-<2, and which is highly suitable for use as a substrate glass both in display technology and in thin-film photovoltaics.
    Type: Application
    Filed: January 11, 2001
    Publication date: March 14, 2002
    Inventors: Ulrich Peuchert, Peter Brix
  • Publication number: 20020023463
    Abstract: This invention relates to a flat float glass that can be prestressed or transformed into a glass ceramic with high quartz mixed crystals or keatite mixed crystals. To eliminate undesirable surface defects during floating and to achieve superior characteristics of the glass or of he glass ceramic, in particular with regard to a low coefficient of thermal expansion and high light transmittance, the glass has a concentration of less than 300 ppb Pt, less than 30 ppb Rh, less than 1.5 wt. % ZnO and less than 1 wt. % SnO2, and is refined during melting without the use of the conventional fining agents arsenic oxide and/or antimony oxide.
    Type: Application
    Filed: April 9, 2001
    Publication date: February 28, 2002
    Inventors: Friedrich Siebers, Peter Nass, Gerhard Lautenschlager, Otmar Becker
  • Patent number: 6346493
    Abstract: The present invention provides a new and improved lead-free and cadmium-free glass enamel composition that displays good flow at traditional glass enamel firing temperatures and upon firing produces an enamel finish that displays no cracking, good chemical resistance, good weatherability, and improved color values. The glass enamel composition of the present invention includes a glass component, an oxidizer, a pigment system, and optional vehicles and fillers. The presence of the oxidizer in the composition, which can be included as part of the glass component, as a separately added material, or both, improves the color values of the fired enamel as compared to enamels formed using similar glass enamel compositions having no oxidizer present.
    Type: Grant
    Filed: October 27, 1999
    Date of Patent: February 12, 2002
    Assignee: Ferro Corporation
    Inventors: Galina Kniajer, Jeffrey David Cosby, Ivan H. Joyce, Srinivasan Sridharan, John J. Maloney
  • Publication number: 20020013210
    Abstract: The invention relates to an alkali-free aluminoborosilicate glass having a coefficient of thermal expansion &agr;20/300 of between 2.8.10−6/K and 3.6.10−6/K, which has the following composition (in % by weight, based on oxide): silicon dioxide (SiO2)>58-65, boric oxide (B2O3)>6-11.5, aluminum oxide (Al2O3)>20-25, magnesium oxide (MgO) 4-<6.5, calcium oxide (CaO)>4.5-8, strontium oxide (SrO) 0-<4, barium oxide (BaO) 0.5-<5, with strontium oxide (SrO)+barium oxide (BaO)>3, zinc oxide (ZnO) 0-<2, and which is highly suitable for use as a substrate glass both in display technology and in thin-film photovoltaics.
    Type: Application
    Filed: January 11, 2001
    Publication date: January 31, 2002
    Inventors: Ulrich Peuchert, Peter Brix
  • Publication number: 20020010064
    Abstract: A SiO2-Al2O3-Li2O component-based glass material, which comprises, as basic components, SiO2: 60-63 wt %; Al2O3: 23-25 wt %; and Li2O: 4-5 wt % and, as modifying components, ZrO2: 1.5-2.5 wt %; TiO2: 0.5-2.5 wt %; MgO: 0.5-1.5 wt %; ZnO: 0.5-1.2 wt %; Na2O: 0.5-2.0 wt %; and K2O: 0.5-2.0 wt %, and further comprises any one of BaO: 0.5-1.0 wt, CaO: 1.0-2.0 wt %, and B2O3: 0.01-1.0 wt %. This can be reheat-formed in a glass state and has a low thermal expansion coefficient.
    Type: Application
    Filed: March 29, 2001
    Publication date: January 24, 2002
    Applicant: NGK Insulators, Ltd.
    Inventors: Takashi Ota, Kazutoshi Tohyama, Masashi Fukuyama, Akiyoshi Ide
  • Patent number: 6329310
    Abstract: The invention relates to an alkali-free aluminoborosilicate glass which has the following composition in % by weight, based on oxide: SiO2 60.5-69, B2O3 0.5-4.5, Al2O3 15-24, MgO 3-10, CaO 0-10, SrO 0.5-8, BaO 0.5-5.5, with MgO+CaO+SrO+BaO 8-19, SnO2 0.1-2, ZrO2 0-2, TiO2 0-2, CeO2 0-1, ZnO 0-<1, and which is highly suitable for use as substrate glass both in display technology and thin-film photovoltaics.
    Type: Grant
    Filed: April 12, 2000
    Date of Patent: December 11, 2001
    Assignee: Schott Glas
    Inventors: Ulrich Peuchert, Peter Brix
  • Patent number: 6316374
    Abstract: A dielectric ceramic composition which can be sintered at low temperature and has a low dielectric constant, high Q value, and favorable temperature-dependent characteristic of capacitance (TCC) in the high-frequency region, can be used in a ceramic electronic element. The dielectric ceramic composition comprises glass and at least one of an Si—Mg—Al—O ceramic and TiO2. Preferably, the compositional proportions of the three components based on wt. % represented by (glass, Si—Mg—Al—O ceramic, TiO2) fall within a polygon formed by connecting points A(100, 0, 0), B(30, 70, 0), and C(30, 0, 70) in the ternary diagram of the three components.
    Type: Grant
    Filed: February 26, 1999
    Date of Patent: November 13, 2001
    Assignee: Murata Manufacturing Co., Ltd.
    Inventor: Hiromichi Kawakami
  • Patent number: 6309990
    Abstract: A low-dielectric-constant glass fiber having a glass composition comprising, by % by weight, 45 to 60% of SiO2, 8 to 20% of Al2O3, 15 to 30% of B2O3, 0 to 5% of MgO, 5%, exclusive of 5%, to 12% of CaO, 0 to 1.0% of Li2O+Na2O+K2O, 0.5 to 5% of TiO2 and 0 to 2% of F2 is suitable for use for reinforcing a high-density printed wiring board required to have a low dielectric tangent and its peripheral members.
    Type: Grant
    Filed: April 14, 1999
    Date of Patent: October 30, 2001
    Assignees: Nitto Boseki Co., Ltd., Nitto Glass Fiber Mfg. Co., Ltd
    Inventors: Shinichi Tamura, Masahiro Mori
  • Publication number: 20010034294
    Abstract: The invention relates to an alkali-free aluminoborosilicate glass which has the following composition (in % by weight, based on oxide): silicon dioxide (SiO2)>58-65, boric oxide (B2O3)>6-10.5, aluminum oxide (Al2O3)>14-25, magnesium oxide (MgO) 0-<3, calcium oxide (CaO) 0-9, strontium oxide (SrO) 0.1-1.5, and barium oxide (BaO)>5-8.5, with strontium oxide (SrO)+barium oxide (BaO)<8.6, and with magnesium oxide (MgO)+calcium oxide (CaO)+strontium oxide (SrO)+barium oxide (BaO) 8-18; zinc oxide (ZnO) 0<2, and which is highly suitable for use as a substrate glass both in display technology and in thin-film photovoltaics.
    Type: Application
    Filed: January 11, 2001
    Publication date: October 25, 2001
    Inventors: Ulrich Peuchert, Peter Brix
  • Publication number: 20010034293
    Abstract: An alkali-free aluminoborosilicate glass having a coefficient of thermal expansion &agr;20/300 of between 2.8×10−6/K and 3.8×10−6/K, which has the following composition (in % by weight, based on oxide): silicon dioxide (SiO2)>58−65, boric oxide (B2O3)>6−11.5, magnesium oxide (MgO) 4−8, barium oxide (BaO) 0−<0.5, zinc oxide (ZnO) 0−2 and aluminum oxide (Al2O3)>14−25, calcium oxide (CaO) 0−8, strontium oxide (SrO) 2.6−<4, with barium oxide (BaO)+strontium oxide (SrO) >3, or aluminum oxide (Al2O3)>14−25, calcium oxide (CaO) 0−<2, strontium oxide (SrO)>0.5−<4, or aluminum oxide (Al2O3)>21−25, calcium oxide (CaO) 0−8, strontium oxide (SrO)>2.6−<8, with barium oxide (BaO)−strontium oxide (SrO)>3, and which is highly suitable for use as a substrate glass both in display technology and in thin-film photovoltaics.
    Type: Application
    Filed: January 11, 2001
    Publication date: October 25, 2001
    Inventors: Ulrich Peuchert, Peter Brix
  • Patent number: 6306784
    Abstract: Alkali silicate glasses are described which, in view of their good chemical stability and their optical properties and processing properties, are particularly suitable as a coating or veneering material for ceramic dental frameworks and hence for the production of all-ceramic dental restorations such as crowns or bridges.
    Type: Grant
    Filed: June 9, 2000
    Date of Patent: October 23, 2001
    Assignee: Ivoclar AG
    Inventors: Helga Drescher, Martin Frank, Volker Rheinberger, Wolfram Höland
  • Patent number: 6303528
    Abstract: The glasses used for making rigid disk substrates have the following composition (in % by weight based on oxides): SiO2, 40 to 50.8; Al2O3, 5 to 20; B2O3, 0 to 5; Li2O, 0 to 10; Na2O, 0 to 12, with the proviso that Li2O+Na2O, 5 to 12; K2O, 0 to 5; MgO, 0 to 20; CaO, 0 to 6, with the proviso that MgO+CaO, 4 to 20; SrO+BaO, 0 to 10; ZrO2, 0 to 5; TiO2,0 to 5; CeO2, 0 to 1; La2O3, 0 to 10; Fe2O3, 0 to 10; Nb2O5, 0 to 10; V2O5, 0 to 15, with the proviso that TiO2+ZrO2+La2O3+Fe2O3+Nb2O5+V2O5≧18.7; As2O3+Sb2O3+F. 0,1 to 1. These glasses also fulfill the following inequality formulae (1): (E/&rgr;)·+3,500 R>38.5 and 1000 R>1  (1), wherein R represents the relaxation rate of the glass and E/&rgr; represents specific elasticity modulus of the glass measured in GPA*cm3/g.
    Type: Grant
    Filed: May 19, 2000
    Date of Patent: October 16, 2001
    Assignee: Schott Glas
    Inventors: Burkhard Speit, Gerhard Westenberger