And Lead Patents (Class 501/74)
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Patent number: 5073524Abstract: Cerium-doped radiation-shielding glasses in the system of SiO.sub.2 -PbO-alkali metal oxides, with a high absorption coefficient for high-energy X-ray and/or gamma- and, respectively, neutron radiation which are resistant to discoloration and exhibit a discharge stability of >5.times.10.sup.8 rad, consist essentially of (in % by weight)______________________________________ SiO.sub.2 35-56 Na.sub.2 O K.sub.2 O 12-21 Cs.sub.2 O PbO.sub.2 24-46 CeO.sub.2 0.5-2.5 CuO + Fe.sub.2 0-0.05; ______________________________________for absorption of neutrons, the isotope Li.sup.6 can furthermore be onctained therein, and SiO.sub.2 can be substituted by B.sub.2 O.sub.3 and/or Gd.sub.2 O.sub.3 in an amount of up to 10% by weight and Gd.sub.2 O.sub.3 is present.Type: GrantFiled: June 6, 1990Date of Patent: December 17, 1991Assignee: Schott GlaswerkeInventor: Burkhard Speit
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Patent number: 5043223Abstract: A multilayer ceramic substrate comprises plural conductive layers and insulation layer for insulating the plural conductive layers, and the insulation layer is made of an inorganic composition comprising at least one member selected from the group of Al.sub.2 O.sub.3 and ZrO.sub.2, SiO.sub.2, PbO, and at least one member selected from the group of BaO, CaO and ZnO in predetermined range. The multilayer ceramic substrate can be sintered at low temperature in the air and is splendid in a heat resistance, a solderability and resistance value of the insulation layer and furthermore, a microcrack is not caused in a laser trimming of a top resistance film.Type: GrantFiled: April 23, 1990Date of Patent: August 27, 1991Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Koichi Kumagai, Shinji Shimazaki
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Patent number: 5034354Abstract: There is disclosed a family of alkali-free, lead silicate glasses having properties that make them particularly suitable for use in producing perforated plates for such applications as multichannel plates. In addition to lead oxide and silica, the glasses contain ZnO, BaO, CaO and, under certain circumstances, MgO.Type: GrantFiled: May 16, 1990Date of Patent: July 23, 1991Assignee: Corning IncorporatedInventor: Gerald J. Fine
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Patent number: 5028567Abstract: A glass-ceramic obtained by heat treating a parent glass in which specific amounts of MgO and PbO are added to the SiO.sub.2 - Al.sub.2 O.sub.3 - ZnO - TiO.sub.2 system glass has a wide range of coefficients of thermal expansion and improved fineness in diameters of crystals and also improved chemical durability or thermal expansion curve.Type: GrantFiled: May 24, 1988Date of Patent: July 2, 1991Assignee: 501 Kabushiki Kaisha OharaInventors: Naoyuki Gotoh, Makoto Hayasaka
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Patent number: 4996173Abstract: The optical glass of the present invention comprising SiO.sub.2, alkali metal oxides, P.sub.2 O.sub.5 and Nb.sub.2 O.sub.5 has optical properties of 1.70 or more in refractive index nd and 30 or less in Abbe's number .nu.d and is superior in devitrification resistance and stability.Type: GrantFiled: February 13, 1989Date of Patent: February 26, 1991Assignee: Hoya CorporationInventor: Kazuo Tachiwana
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Patent number: 4985376Abstract: A surface conductive paste composition to be applied to the surface of a green sheet for a ceramic substrate or to the surface of a ceramic substrate after being fired and to be then fired, the solid content of which has a composition comprising from 80 to 99.9% by weight of Au powder, from 0.1 to 20% by weight of crystallized glass frit and from 0 to 19.9% by weight of non-crystallized glass frit, provided that the total of the crystallized glass frit and the non-crystallized glass frit is at most 20% by weight, and which has a lead compound powder incorporated in an amount of from 0 to 5% by weight based on the total amount of said composition.Type: GrantFiled: January 19, 1990Date of Patent: January 15, 1991Assignee: Asahi Glass Company, Ltd.Inventors: Kazuo Sunahara, Tsuneo Ichimatsu, Yumiko Aoki
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Patent number: 4983551Abstract: Glass consisting essentially of, in weight percent:______________________________________ SiO.sub.2 30-35% PbO 50-57% Cs.sub.2 O 2-10% .SIGMA.MgO + CaO + SrO + BaO 0-5% .SIGMA.Al.sub.2 O.sub.3 + ZrO.sub.2 + TiO.sub.2 + Nb.sub.2 O.sub.5 0.1-1%, ______________________________________wherein the ratio of Si or Pb, expressed as the molar ratio of SiO.sub.2 to PbO, is 2.0-2.4, and channel electron multipliers made therefrom.Type: GrantFiled: August 18, 1988Date of Patent: January 8, 1991Assignee: Galileo Electro-Optics Corp.Inventors: W. Bruce Feller, Lee M. Cook
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Patent number: 4957883Abstract: An oxynitride glass, a process for preparing same and a fiber thereof, in the glass which has Si--M.sub.1 --M.sub.2 --O--N system and contains SiO.sub.2, Si.sub.3 N.sub.4 and M.sub.1 O in amounts which, as mole %, satisfy the following equations (a) and (b):(SiO.sub.2 +3Si.sub.3 N.sub.4 +M.sub.1 O) X 100 / (100+2Si.sub.3 N.sub.4)=65 to less than 100 (a)(SiO.sub.2 +3Si.sub.3 N.sub.4)/M.sub.1 O=0.7 to 2.3 (b)wherein M.sub.1 is Ca, or Ca and Mg; M.sub.2 is at least one of the metal selected from the group consisting of Al, Sr, La, Ba, Y, Ti, Zr, Ce, Na, K, Sb, B, Cr, Pb, V and Sn, said glass containing 0-40 mole% SiO.sub.2, 26-70 mole % CaO, 0-20 mole % MgO, and over O to not more than 22 at % M.sub.2.Type: GrantFiled: March 6, 1989Date of Patent: September 18, 1990Assignee: Shimadzu CorporationInventors: Junya Kobayashi, Masaaki Oota, Katsuhiko Kada, Hiroyoshi Minakuchi
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Patent number: 4949010Abstract: X-ray attenuating polycrystalline ceramic materials having at least 20 wt. percent cerium oxide are disclosed. In addition, the materials can include one or more X-ray attenuating substances selected from the group including compounds of strontium, zirconium, yttrium, niobium, molybdenum, neodymium and tungsten. The materials can be formed in strong, non-porous bodies such as cathode ray tube funnels.Type: GrantFiled: January 11, 1988Date of Patent: August 14, 1990Assignee: Tektronix, Inc.Inventors: Ronald O. Petersen, James L. McAlpin
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Patent number: 4946622Abstract: There are described blue luminescent glasses having the following compositions(a) 0 to 90 mole % alkali metal oxide (sodium oxide, potassium oxide, lithium oxide), individually or several together, 0 to 90 mole % alkaline earth metal oxide (magnesium oxide, calcium oxide, strontium oxide, barium oxide), individually or several together, with the proviso that the magnesium oxide and/or calcium oxide can only be present in an amount of up to 25 mole % and at least 2 mole % of alkali metal oxide and/or alkaline earth metal oxide must be present(b)7 to 95 mole % silica0 to 70 mole % boron oxide (B.sub.2 O.sub.3)0 to 85 mole % aluminum oxide(c) 0.01 to 40 mole % lead oxide (PbO).Type: GrantFiled: February 6, 1989Date of Patent: August 7, 1990Assignee: Degussa AktiengesellschaftInventors: Akos Kiss, Peter Kleinschmit, Werner Volker, Gunter Halbritter
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Patent number: 4945071Abstract: This invention presents a series of glasses which possess low softening points, high resistance to recrystallization and good durability in the presence of moisture. The glasses are contained within oxides of silver, vanadium, tellurium, and lead and have glass transition temperatures below 260.degree. C., and are useful in electronic applications such as die attach adhesives and sealing glasses.Type: GrantFiled: April 19, 1989Date of Patent: July 31, 1990Assignee: National Starch and Chemical Investment Holding CompanyInventors: G. Delbert Friesen, Yun K. Shin, Lewis Hoffman, deceased
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Patent number: 4874724Abstract: This invention is directed to the production of glass-ceramic articles exhibiting an apparent annealing point in excess of 400.degree. C. and excellent resistance to moisture attack, the articles consisting essentially, in mole percent, of:______________________________________ Li.sub.2 O 5-25 ZnO 35-50 Na.sub.2 O 0-15 Al.sub.2 O.sub.3 0.75-6 K.sub.2 O 0-10 P.sub.2 O.sub.5 29-37. Li.sub.2 O + Na.sub.2 O + K.sub.Type: GrantFiled: October 17, 1988Date of Patent: October 17, 1989Assignee: Corning IncorporatedInventors: George H. Beall, Joseph E. Pierson, Candace J. Quinn
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Patent number: 4806268Abstract: There are described luminescent glasses having the following compositions(a) 0 to 80 mole % alkali metal oxide (sodium oxide, potassium oxide, lithium oxide), individually or several together, 0 to 30 mole % alkaline earth metal oxide (magnesium oxide, calcium oxide, strontium oxide, barium oxide), individually or several together, and at least 2 mole % of alkali metal oxide and/or alkaline earth metal oxide must be present(b)7 to 90 mole % silica1 to 50 mole % boron oxide (B.sub.2 O.sub.3)1 to 30 mole % aluminum oxide(c)0.1 to 5 mole % lead oxide (PbO)0.1 to 10 mole % vandium pentoxide (V.sub.2 O.sub.5).The glasses have white, yellow, or blue luminescence, depending on the PbO and V.sub.2 O.sub.5 content, at excitation with a wave length of 254 nm.Type: GrantFiled: March 9, 1988Date of Patent: February 21, 1989Assignee: Degussa AktiengesellschaftInventors: Akos Kiss, Peter Kleinschmit, Werner Volker, Gunter Halbritter
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Patent number: 4804885Abstract: X-ray attenuating ceramic materials having at least one substance selected from the group including compounds of strontium, zirconium, yttrium, niobium, molybdenum, neodymium and tungsten are disclosed. A zinc compound can be used for fluxing and X-ray attenuation in certain ceramic materials. The materials can be formed into strong, non-porous bodies such as cathode ray tube funnels. Such materials include forsteritic porcelains manufactured from batches containing strontium zirconate. Other X-ray attenuating ceramics contain a mixture of X-ray attenuating substances, including a compound of barium.Type: GrantFiled: August 20, 1984Date of Patent: February 14, 1989Assignee: Tektronix, Inc.Inventors: Ronald O. Petersen, James L. McAlpin
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Patent number: 4759965Abstract: A ceramic comprises therein two or more dielectric portions having different dielectric constants formed by filling of one or more vacant spaces provided within a dielectric porcelain, a semiconductor porcelain as a precursor of said dielectric porcelain or a molded product as a precursor of said semiconductor procelain with one or more kinds of materials capable of becoming to have different dielectric constants from said dielectric porcelain and subsequent calcination.Type: GrantFiled: August 4, 1986Date of Patent: July 26, 1988Assignee: Canon Kabushiki KaishaInventors: Keiichi Kato, Motoo Kumagai
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Patent number: 4737475Abstract: A glass composition specially useful in the glass envelope of TV receiver tubes and which is of the lead silicate type is disclosed comprising in weight percent 30-65% SiO.sub.2, 20-40% PbO, 5-20% alkali metal oxides, 0-2% Al.sub.2 O.sub.3, 0-10% alkaline earth metal oxides, 0.2-2% Sb.sub.2 O.sub.3, and 0.1-0.5% CeO.sub.2. The improvement resides in employment of a novel refining system when the glass is formed which employs Sb.sub.2 O.sub.3, niter and CeO.sub.2 as the refining agents in particular weight proportions to reduce the seed count in the molten glass while also reducing thermal shock breakage when the solid glass product is thereafter thermally reworked.Type: GrantFiled: May 1, 1987Date of Patent: April 12, 1988Assignee: General Electric CompanyInventors: George L. Thomas, Anup Sircar
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Patent number: 4734389Abstract: A highly refractive optical glass (n.sub.d .gtoreq.1.83) with high dispersion (v.sub.d .ltoreq.25) and very good chemical stability at relatively low density (.delta..ltoreq.3.5 g/cm.sup.3) consists of (in weight percent) SiO.sub.2 19-25, Na.sub.2 O 7-10, K.sub.2 O 4-7, Cs.sub.2 O 0-12, Cao 0.5-2.0, BaO 9-15, TiO.sub.2 25-30, ZrO.sub.2 0-6, Nb.sub.2 O.sub.5 16-20, WO.sub.3 0-3, with Nb.sub.2 O.sub.5 :TiO.sub.2 =0.6-0.71.Type: GrantFiled: February 7, 1986Date of Patent: March 29, 1988Assignee: Schott GlaswerkeInventors: Danuta Grabowski, Ludwig Ross, Volkmar Geiler
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Patent number: 4732875Abstract: To tellurite optical glass comprising TeO.sub.2, high valence components are added and may be a combination of La.sub.2 O.sub.3, at least one of B.sub.2 O.sub.3 and GeO.sub.2, and at least one of Ta.sub.2 O.sub.5 and Nb.sub.2 O.sub.5. The high valence components may include Y.sub.2 O.sub.3, Gd.sub.2 O.sub.3, and Yb.sub.2 O.sub.3. Amounts of TeO.sub.2 and La.sub.2 O.sub.3 are restricted to ranges between 10% and 80% and between 5% and 35%, respectively. A sum of B.sub.2 O.sub.3 and GeO.sub.2 must fall within a range between 1% and 30%, with an amount of GeO.sub.2 restricted between 0% and 22%. A total of La.sub.2 O.sub.3, Y.sub.2 O.sub.3, Gd.sub.2 O.sub.3, and Yb.sub.2 O.sub.3 must be between 5% and 50%. A sum of Ta.sub.2 O.sub.5 and Nb.sub.2 O.sub.5 should range from 1% to 26%, with individual amounts of Ta.sub.2 O.sub.5 and Nb.sub.2 O.sub.5 kept between 0% and 20% and between 0% and 26%, respectively.Type: GrantFiled: February 21, 1986Date of Patent: March 22, 1988Assignee: Hoya CorporationInventor: Koji Sagara
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Patent number: 4721690Abstract: High PbO-content glass in the optical range of flint and heavy flint glasses from the system SiO.sub.2 --PbO--M.sub.2 O wherein M.sub.2 O=alkali metal oxides, said glass having a minimum PbO content of 30 wt. % and a minimum M.sub.2 O content of 0.5 wt. %, are provided with enhanced chemical stability without loss of the desired optical position by replacing a portion of the SiO.sub.2 and PbO such that the glass contains 1.5-6 wt. % (TiO.sub.2 +ZrO.sub.2) and the ratio of TiO.sub.2 :ZrO.sub.2 is about 0.3-2.0.Type: GrantFiled: February 5, 1985Date of Patent: January 26, 1988Inventors: Ludwig Ross, Danuta Grabowski, Burkhard Speit, Volkmar Geiler
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Patent number: 4677081Abstract: A glass composition specially useful in the glass envelope of TV receiver tubes and which is of the lead silicate type is disclosed comprising in weight percent 30-65% SiO.sub.2, 20-40% PbO, 5-20% alkali metal oxides, 0-2% Al.sub.2 O.sub.3, 0-10% alkaline earth metal oxides, 0.2-2% Sb.sub.2 O.sub.3, and 0.1-0.5% CeO.sub.2. The improvement resides in employment of a novel refining system when the glass is formed which employs Sb.sub.2 O.sub.3, niter and CeO.sub.2 as the refining agents in particular weight proportions to reduce the seed count in the molten glass while also reducing thermal shock breakage when the solid glass product is thereafter thermally reworked.Type: GrantFiled: October 7, 1985Date of Patent: June 30, 1987Assignee: General Electric CompanyInventors: George L. Thomas, Anup Sircar
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Patent number: 4609582Abstract: A dielectric glass and a glass ceramic obtained therefrom is provided for separating crossing conductors in multilayer thick-film circuits. The dielectric glass has a composition in mol. % between the limits of 10-25% ZnO, 7.5-25% PbO, 50-60% SiO.sub.2, and 7.5-12.5% Al.sub.2 O.sub.3. These compositions are particularly suitable for conductor patterns having silver because they are free from micropores.Type: GrantFiled: April 26, 1984Date of Patent: September 2, 1986Assignee: U.S. Philips CorporationInventors: Hendrik J. M. Joormann, Alois J. M. Van Gorp
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Patent number: 4567151Abstract: A thick film conductor composition comprising an admixture of finely divided particles of noble metal and inorganic binder dispersed in organic medium in which the inorganic binder consists essentially of a bismuth silicate glass and/or bismuth germanate glass, ZnO and optionally Bi.sub.2 O.sub.3.Type: GrantFiled: January 14, 1985Date of Patent: January 28, 1986Assignee: E. I. Du Pont de Nemours and CompanyInventor: Barry E. Taylor
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Patent number: 4562162Abstract: A glass for multi-focal eyeglass having a refractive index (n.sub.d) of 1.67 to 1.73, an Abbe number (.nu..sub.d) of 33 or more, a coefficient of thermal expansion of 82 to 95.times.10.sup.-7 and a softening point of 560.degree. to 640.degree. C., comprising, in % by weight,32 to 40% SiO.sub.2 +B.sub.2 O.sub.3 +Al.sub.2 O.sub.3 ;22 to 40% SiO.sub.2 ;0 to 10% B.sub.2 O.sub.3 ;0 to 4% Al.sub.2 O.sub.3 ;4 to 10% Li.sub.2 O+Na.sub.2 O+K.sub.2 O;0 to 4% Li.sub.2 O;0 to 7% Na.sub.2 O;0 to 7% K.sub.2 O;30 to 47% PbO;3 to 24% BaO+SrO+CaO+MgO+ZnO;0 to 20% BaO;0 to 15% SrO;0 to 10% CaO;0 to 8% MgO;0 to 15% ZnO; and1 to 7% ZrO.sub.2 ;wherein a weight ratio of alkali metal oxides/PbO ranges from 0.1 to 0.3.Type: GrantFiled: October 26, 1984Date of Patent: December 31, 1985Assignee: Hoya CorporationInventor: Hiroji Sagara
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Patent number: 4532221Abstract: This invention is concerned with the preparation of thermally crystallizable enamels suitable for application to glass-ceramics, particularly glass-ceramics having coefficients of thermal expansion less than 15.times.10.sup.-7 /.degree.C. The enamels are capable of being fired to maturity simultaneously with the precursor glass body being crystallized to a glass-ceramic. The enamels consist essentially, expressed in weight percent on the oxide basis, of:SiO.sub.2 : 36-58Al.sub.2 O.sub.3 : 8.5-16CaO: 0.5-10PbO: 27-40K.sub.2 O: 0.Type: GrantFiled: February 21, 1984Date of Patent: July 30, 1985Assignee: Corning Glass WorksInventors: Pernette R. M. Barlier, Gerard R. Boury, Jean-Pierre Mazeau
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Patent number: 4520115Abstract: These objects have been attained by providing highly absorbent lead containing alkali metal silicate glasses for cathode ray tube image screens, having a linear absorption coefficient .mu. of >30 cm.sup.-1 (0.6 .ANG.) and with a high resistance to discoloration by X-ray and electron radiation, comprises, in weight percent:______________________________________ SiO.sub.2 20-65% P.sub.2 O.sub.5 + B.sub.2 O.sub.3 + Al.sub.2 O.sub.3 0-30% Li.sub.2 O 0-5% Na.sub.2 O 0-10% K.sub.2 O 0-15% MgO + CaO + ZnO 0-15% SrO 0-20% BaO 0-40% PbO 5-60% ZrO.sub.2 0-10% CeO.sub.2 0.1-5% Other Components 0-20%.Type: GrantFiled: August 2, 1983Date of Patent: May 28, 1985Assignee: Schott GlaswerkeInventors: Burkhard Speit, Karl Mennemann, Georg Gliemeroth
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Patent number: 4512791Abstract: First and second spaced members are hermetically sealed by a partially amorphous and partially crystalline insulating material. The insulating material is non-hygroscopic and is able to withstand forces of about 26,000 psi at about 700.degree. F. It may provide resistances of at least 10,000 megohms even when subjected to 500 volts AC or DC and to steam at about 212.degree. F. for three (3) days. A second insulating layer may be fused to the first insulating layer with essentially the same properties and composition as the first layer. However, the second layer may be more crystalline than the first layer to provide a mechanical and chemical barrier. The insulating materials may be formed from the oxides of lead, zinc, aluminum, silicon, cerium, lanthanum, cobalt, sodium, zirconium, bismuth and molybdenum. The oxides of lead, silicon, bismuth and sodium may be glass formers. The oxides of cerium, lanthanum and zirconium may form crystals. A mixture of the oxides may be heated to at least 2000.degree. F.Type: GrantFiled: May 2, 1984Date of Patent: April 23, 1985Inventor: James C. Kyle
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Patent number: 4495298Abstract: A thallium-containing optical glass composition which comprises the following oxides in the indicated proportions in mole %: SiO.sub.2 35-80, Tl.sub.2 O 1-30, Tl.sub.2 O+R.sub.2 O (R being an alkali metal) 1-35, ZnO 0-35, GeO.sub.2 0-30, BaO 0-25, TiO.sub.2 0-20, MgO 0-20, B.sub.2 O.sub.3 0-less than 10, ZrO.sub.2 0-2, Al.sub.2 O.sub.3 0-8, SnO 0-5, CaO 0-10, SrO 0-10, PbO 0-10, La.sub.2 O.sub.3 0-5, Bi.sub.2 O.sub.3 0-8, and Ta.sub.2 O.sub.5 0-2, and satisfies the following relations:5.ltoreq.ZnO+GeO.sub.2 +BaO+TiO.sub.2 +MgO+B.sub.2 O.sub.3 .ltoreq.40,0.1.ltoreq.ZrO.sub.2 +Al.sub.2 O.sub.3 +SnO.ltoreq.8,and0.ltoreq.CaO+SrO+PbO+La.sub.2 O.sub.3 +Bi.sub.2 O.sub.3 +Ta.sub.2 O.sub.5 .ltoreq.10.Type: GrantFiled: May 11, 1982Date of Patent: January 22, 1985Assignee: Nippon Sheet Glass Co., Ltd.Inventors: Takasi Yamagishi, Yukio Noguchi
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Patent number: 4483931Abstract: This invention is directed to the preparation of glasses in the PbO--Ga.sub.2 O.sub.3 field exhibiting good infrared transmitting characteristics out to wavelengths of 8 microns. The binary glasses consist essentially, by weight, of about 15-28% Ga.sub.2 O.sub.3 and 72-85% PbO. However, the preferred glasses contain up to 85% Bi.sub.2 O.sub.3 and consist essentially as included within the area generally encompassed by the curve in FIG. 2.Type: GrantFiled: March 21, 1983Date of Patent: November 20, 1984Assignee: Corning Glass WorksInventors: William H. Dumbaugh, Jr., Brian P. Tyndell
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Patent number: 4476233Abstract: A phosphate optical glass comprises P.sub.2 O.sub.5 of 40-55 weight percents, R.sub.2 O of 20-40 weight percents (wherein R is an alkali metal or a mixture of alkali metals selected from the group consisting of Li, Na and K), TiO.sub.2 of 8-20 weight percents, WO.sub.3 of 1-12 weight percents (providing that the WO.sub.3 content be less than TiO.sub.2), As.sub.2 O.sub.3 of 0.1-4 weight percents, MgO of 0-7, CaO of 0-11, BaO of 0-12, ZnO of 0-12 PbO of 0-18, Nb.sub.2 O.sub.5 of 0-20, Ta.sub.2 O.sub.5 of 0-10, SiO.sub.2 of 0-3, ZrO.sub.2 of 0-3, La.sub.2 O.sub.3 of 0-3, Y.sub.2 O.sub.3 of 0-3 and F of 0-5.Type: GrantFiled: September 12, 1983Date of Patent: October 9, 1984Assignee: Nippon Kogaku K.K.Inventor: Hiroyuki Kodama
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Patent number: 4472030Abstract: A cesium-containing optical glass comprising, by weight, 32-56% of SiO.sub.2, 6-25% of K.sub.2 O, 6-32% of Cs.sub.2 O, 0-30% of BaO, 0-2.5% of MgO, 5-34% of ZnO, 0-3% of ZrO.sub.2 and 0-5% of SnO.sub.2, provided that the total proportion of BaO, MgO and ZnO is 8-40% and the total proportion of ZrO.sub.2 and SnO.sub.2 is 0.2-6%. When this cesium-containing optical glass is treated in a molten bath containing potassium nitrate, the cesium ion in the glass is easily exchanged with a potassium ion and therefore, the cesium ion concentration gradually decreases radially outwardly from the central axis and the potassium ion concentration gradually increases in that direction. Thus, there is obtained a light converge-type lens in which the refractive index gradually decreases in the same direction.Type: GrantFiled: November 4, 1983Date of Patent: September 18, 1984Assignee: Nippon Sheet Glass Company, LimitedInventors: Masakiyo Tachibana, Yukio Noguchi, Noboru Akazawa
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Patent number: 4461926Abstract: First and second spaced members are hermetically sealed by a partially amorphous and partially crystalline insulating material. The insulating material is non-hygroscopic and is able to withstand forces of about 26,000 psi at about 700.degree. F. It may provide resistances of at least 10,000 megohms even when subjected to 500 volts AC or DC and to steam at about 212.degree. F. for three (3) days. A second insulating layer may be fused to the first insulating layer with essentially the same properties and composition as the first layer. However, the second layer may be more crystalline than the first layer to provide a mechanical and chemical barrier. The insulating materials may be formed from the oxides of lead, zinc, aluminum, silicon, cerium, lanthanum, cobalt, sodium, zirconium, bismuth and molybdenum. The oxides of lead, silicon, bismuth and sodium may be glass formers. The oxides of cerium, lanthanum and zirconium may form crystals. A mixture of the oxides may be heated to at least 2000.degree. F.Type: GrantFiled: November 16, 1981Date of Patent: July 24, 1984Inventor: James C. Kyle
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Patent number: 4395291Abstract: A lead additive containing a lead oxide and an alkaline silicate which is resistant to dusting, abrasion and segregation. The weight ratio of lead to alkaline silicate, calculated as PbO and SiO.sub.2, respectively, is greater than about 95:5; the moisture content is less than or equal to about 2%; and the density is less than about 5 g/cm.sup.3.The process for producing these additives involve forming a paste of the lead oxide and alkaline silicate, conditioning the paste to form granules and heat treating the granules.Type: GrantFiled: March 19, 1982Date of Patent: July 26, 1983Assignee: Societe Anonyme Societe Miniere et Metallurgique de PenarroyaInventors: Armand Limare, Bernard Razumowski, Claude Sindezingue
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Patent number: 4391915Abstract: Optical components can be pressed with such a precision that grinding and polishing of the formed components is not necessary, from glasses containing 45-55 wt. % P.sub.2 O.sub.5, 3.5-9 wt. % Al.sub.2 O.sub.3, 5-20 wt. % K.sub.2 O, 0-3 wt. % Li.sub.2 O, 8-15% BaO, 4.5-9 wt. % ZnO, 0-6 wt. % MgO, 0-18 wt. % PbO, 0-1 wt. % SiO.sub.2, 0-3 wt. % B.sub.2 O.sub.3, 0-2 wt. % TiO.sub.2.Type: GrantFiled: December 7, 1981Date of Patent: July 5, 1983Assignee: U.S. Philips CorporationInventors: Gertraud A. A. Meden-Piesslinger, Johannes H. P. Van de Heuvel
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Patent number: 4351906Abstract: The present invention is drawn to glasses suitable for the fabrication of segments or buttons for multifocal ophthalmic lenses. The inventive glasses have refractive indices ranging between about 1.745-1.771, an Abbe number greater than 29 for a refractive index of 1.771 and greater than 31 for a refractive index of 1.745, a softening point between about 640.degree.-700.degree. C., a coefficient of thermal expansion (25.degree.-300.degree. C.) between about 90-98.times.10.sup.-7 /.degree.C., and satisfactory chemical durability. The glasses consist essentially, expressed in terms of weight percent on the oxide basis, of______________________________________ SiO.sub.2 28-32.5 Na.sub.2 O 2-9 K.sub.2 O 0-4 Li.sub.2 O 0-1 K.sub.2 O + Na.sub.2 O + Li.sub.2 O 4-10.5 BaO 0-22 La.sub.2 O.sub.3 0-20 BaO + La.sub.2 O.sub.3 14-22 PbO 28.5-34 ZnO 0-4 TiO.sub.2 0-9 ZrO.sub.2 2-6.5 Nb.sub.2 O.sub.5 0-10 TiO.sub.2 + Nb.sub.2 O.sub.5 4.5-12 ZrO.sub.2 + TiO.sub.2 + Nb.sub.2 O.sub.Type: GrantFiled: December 7, 1981Date of Patent: September 28, 1982Assignee: Corning Glass WorksInventors: Jean E. Boudot, Jean P. Mazeau, Andre C. Michaud
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Patent number: 4342943Abstract: A glass composition is disclosed that is useful as a solder glass for sealing components together. However, the glass is also especially adapted for use as an electric resistance film for coating the inner neck or funnel portions of a cathode ray tube to reduce arcing. The glass composition includes primarily the oxides of vanadium and phosphorous with the preferred addition of either zinc oxide or lead oxide. Still other metal oxides may be optionally included such as oxides of barium, antimony, lithium, manganese, silicon, boron, molybdenum and mixtures thereof.Type: GrantFiled: October 17, 1979Date of Patent: August 3, 1982Assignee: Owens-Illinois, Inc.Inventor: Edward A. Weaver
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Patent number: 4314031Abstract: Glass compositions in the tin-phosphorus-oxyfluoride composition system exhibiting very low glass transition temperatures and capable of being modified by the addition of selected constituents to exhibit excellent stability in a humid environment, are described.Type: GrantFiled: June 17, 1980Date of Patent: February 2, 1982Assignee: Corning Glass WorksInventors: Leon M. Sanford, Paul A. Tick
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Patent number: 4302362Abstract: Thick film resistors, based on pyrochlore conductive phase, glass, and refractory fillers having a thermal expansion coefficient range of 40.times.10.sup.-7 -60.times.10.sup.-7 /.degree. C. and low solubility in the glass, are provided. Such thick film resistor pastes afford resistors having excellent stability to mechanical or thermal stresses.Type: GrantFiled: January 23, 1979Date of Patent: November 24, 1981Assignee: E. I. Du Pont de Nemours and CompanyInventors: Lewis C. Hoffman, Samuel J. Horowitz