And Lead Patents (Class 501/74)
  • Patent number: 5073524
    Abstract: Cerium-doped radiation-shielding glasses in the system of SiO.sub.2 -PbO-alkali metal oxides, with a high absorption coefficient for high-energy X-ray and/or gamma- and, respectively, neutron radiation which are resistant to discoloration and exhibit a discharge stability of >5.times.10.sup.8 rad, consist essentially of (in % by weight)______________________________________ SiO.sub.2 35-56 Na.sub.2 O K.sub.2 O 12-21 Cs.sub.2 O PbO.sub.2 24-46 CeO.sub.2 0.5-2.5 CuO + Fe.sub.2 0-0.05; ______________________________________for absorption of neutrons, the isotope Li.sup.6 can furthermore be onctained therein, and SiO.sub.2 can be substituted by B.sub.2 O.sub.3 and/or Gd.sub.2 O.sub.3 in an amount of up to 10% by weight and Gd.sub.2 O.sub.3 is present.
    Type: Grant
    Filed: June 6, 1990
    Date of Patent: December 17, 1991
    Assignee: Schott Glaswerke
    Inventor: Burkhard Speit
  • Patent number: 5043223
    Abstract: A multilayer ceramic substrate comprises plural conductive layers and insulation layer for insulating the plural conductive layers, and the insulation layer is made of an inorganic composition comprising at least one member selected from the group of Al.sub.2 O.sub.3 and ZrO.sub.2, SiO.sub.2, PbO, and at least one member selected from the group of BaO, CaO and ZnO in predetermined range. The multilayer ceramic substrate can be sintered at low temperature in the air and is splendid in a heat resistance, a solderability and resistance value of the insulation layer and furthermore, a microcrack is not caused in a laser trimming of a top resistance film.
    Type: Grant
    Filed: April 23, 1990
    Date of Patent: August 27, 1991
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Koichi Kumagai, Shinji Shimazaki
  • Patent number: 5034354
    Abstract: There is disclosed a family of alkali-free, lead silicate glasses having properties that make them particularly suitable for use in producing perforated plates for such applications as multichannel plates. In addition to lead oxide and silica, the glasses contain ZnO, BaO, CaO and, under certain circumstances, MgO.
    Type: Grant
    Filed: May 16, 1990
    Date of Patent: July 23, 1991
    Assignee: Corning Incorporated
    Inventor: Gerald J. Fine
  • Patent number: 5028567
    Abstract: A glass-ceramic obtained by heat treating a parent glass in which specific amounts of MgO and PbO are added to the SiO.sub.2 - Al.sub.2 O.sub.3 - ZnO - TiO.sub.2 system glass has a wide range of coefficients of thermal expansion and improved fineness in diameters of crystals and also improved chemical durability or thermal expansion curve.
    Type: Grant
    Filed: May 24, 1988
    Date of Patent: July 2, 1991
    Assignee: 501 Kabushiki Kaisha Ohara
    Inventors: Naoyuki Gotoh, Makoto Hayasaka
  • Patent number: 4996173
    Abstract: The optical glass of the present invention comprising SiO.sub.2, alkali metal oxides, P.sub.2 O.sub.5 and Nb.sub.2 O.sub.5 has optical properties of 1.70 or more in refractive index nd and 30 or less in Abbe's number .nu.d and is superior in devitrification resistance and stability.
    Type: Grant
    Filed: February 13, 1989
    Date of Patent: February 26, 1991
    Assignee: Hoya Corporation
    Inventor: Kazuo Tachiwana
  • Patent number: 4985376
    Abstract: A surface conductive paste composition to be applied to the surface of a green sheet for a ceramic substrate or to the surface of a ceramic substrate after being fired and to be then fired, the solid content of which has a composition comprising from 80 to 99.9% by weight of Au powder, from 0.1 to 20% by weight of crystallized glass frit and from 0 to 19.9% by weight of non-crystallized glass frit, provided that the total of the crystallized glass frit and the non-crystallized glass frit is at most 20% by weight, and which has a lead compound powder incorporated in an amount of from 0 to 5% by weight based on the total amount of said composition.
    Type: Grant
    Filed: January 19, 1990
    Date of Patent: January 15, 1991
    Assignee: Asahi Glass Company, Ltd.
    Inventors: Kazuo Sunahara, Tsuneo Ichimatsu, Yumiko Aoki
  • Patent number: 4983551
    Abstract: Glass consisting essentially of, in weight percent:______________________________________ SiO.sub.2 30-35% PbO 50-57% Cs.sub.2 O 2-10% .SIGMA.MgO + CaO + SrO + BaO 0-5% .SIGMA.Al.sub.2 O.sub.3 + ZrO.sub.2 + TiO.sub.2 + Nb.sub.2 O.sub.5 0.1-1%, ______________________________________wherein the ratio of Si or Pb, expressed as the molar ratio of SiO.sub.2 to PbO, is 2.0-2.4, and channel electron multipliers made therefrom.
    Type: Grant
    Filed: August 18, 1988
    Date of Patent: January 8, 1991
    Assignee: Galileo Electro-Optics Corp.
    Inventors: W. Bruce Feller, Lee M. Cook
  • Patent number: 4957883
    Abstract: An oxynitride glass, a process for preparing same and a fiber thereof, in the glass which has Si--M.sub.1 --M.sub.2 --O--N system and contains SiO.sub.2, Si.sub.3 N.sub.4 and M.sub.1 O in amounts which, as mole %, satisfy the following equations (a) and (b):(SiO.sub.2 +3Si.sub.3 N.sub.4 +M.sub.1 O) X 100 / (100+2Si.sub.3 N.sub.4)=65 to less than 100 (a)(SiO.sub.2 +3Si.sub.3 N.sub.4)/M.sub.1 O=0.7 to 2.3 (b)wherein M.sub.1 is Ca, or Ca and Mg; M.sub.2 is at least one of the metal selected from the group consisting of Al, Sr, La, Ba, Y, Ti, Zr, Ce, Na, K, Sb, B, Cr, Pb, V and Sn, said glass containing 0-40 mole% SiO.sub.2, 26-70 mole % CaO, 0-20 mole % MgO, and over O to not more than 22 at % M.sub.2.
    Type: Grant
    Filed: March 6, 1989
    Date of Patent: September 18, 1990
    Assignee: Shimadzu Corporation
    Inventors: Junya Kobayashi, Masaaki Oota, Katsuhiko Kada, Hiroyoshi Minakuchi
  • Patent number: 4949010
    Abstract: X-ray attenuating polycrystalline ceramic materials having at least 20 wt. percent cerium oxide are disclosed. In addition, the materials can include one or more X-ray attenuating substances selected from the group including compounds of strontium, zirconium, yttrium, niobium, molybdenum, neodymium and tungsten. The materials can be formed in strong, non-porous bodies such as cathode ray tube funnels.
    Type: Grant
    Filed: January 11, 1988
    Date of Patent: August 14, 1990
    Assignee: Tektronix, Inc.
    Inventors: Ronald O. Petersen, James L. McAlpin
  • Patent number: 4946622
    Abstract: There are described blue luminescent glasses having the following compositions(a) 0 to 90 mole % alkali metal oxide (sodium oxide, potassium oxide, lithium oxide), individually or several together, 0 to 90 mole % alkaline earth metal oxide (magnesium oxide, calcium oxide, strontium oxide, barium oxide), individually or several together, with the proviso that the magnesium oxide and/or calcium oxide can only be present in an amount of up to 25 mole % and at least 2 mole % of alkali metal oxide and/or alkaline earth metal oxide must be present(b)7 to 95 mole % silica0 to 70 mole % boron oxide (B.sub.2 O.sub.3)0 to 85 mole % aluminum oxide(c) 0.01 to 40 mole % lead oxide (PbO).
    Type: Grant
    Filed: February 6, 1989
    Date of Patent: August 7, 1990
    Assignee: Degussa Aktiengesellschaft
    Inventors: Akos Kiss, Peter Kleinschmit, Werner Volker, Gunter Halbritter
  • Patent number: 4945071
    Abstract: This invention presents a series of glasses which possess low softening points, high resistance to recrystallization and good durability in the presence of moisture. The glasses are contained within oxides of silver, vanadium, tellurium, and lead and have glass transition temperatures below 260.degree. C., and are useful in electronic applications such as die attach adhesives and sealing glasses.
    Type: Grant
    Filed: April 19, 1989
    Date of Patent: July 31, 1990
    Assignee: National Starch and Chemical Investment Holding Company
    Inventors: G. Delbert Friesen, Yun K. Shin, Lewis Hoffman, deceased
  • Patent number: 4874724
    Abstract: This invention is directed to the production of glass-ceramic articles exhibiting an apparent annealing point in excess of 400.degree. C. and excellent resistance to moisture attack, the articles consisting essentially, in mole percent, of:______________________________________ Li.sub.2 O 5-25 ZnO 35-50 Na.sub.2 O 0-15 Al.sub.2 O.sub.3 0.75-6 K.sub.2 O 0-10 P.sub.2 O.sub.5 29-37. Li.sub.2 O + Na.sub.2 O + K.sub.
    Type: Grant
    Filed: October 17, 1988
    Date of Patent: October 17, 1989
    Assignee: Corning Incorporated
    Inventors: George H. Beall, Joseph E. Pierson, Candace J. Quinn
  • Patent number: 4806268
    Abstract: There are described luminescent glasses having the following compositions(a) 0 to 80 mole % alkali metal oxide (sodium oxide, potassium oxide, lithium oxide), individually or several together, 0 to 30 mole % alkaline earth metal oxide (magnesium oxide, calcium oxide, strontium oxide, barium oxide), individually or several together, and at least 2 mole % of alkali metal oxide and/or alkaline earth metal oxide must be present(b)7 to 90 mole % silica1 to 50 mole % boron oxide (B.sub.2 O.sub.3)1 to 30 mole % aluminum oxide(c)0.1 to 5 mole % lead oxide (PbO)0.1 to 10 mole % vandium pentoxide (V.sub.2 O.sub.5).The glasses have white, yellow, or blue luminescence, depending on the PbO and V.sub.2 O.sub.5 content, at excitation with a wave length of 254 nm.
    Type: Grant
    Filed: March 9, 1988
    Date of Patent: February 21, 1989
    Assignee: Degussa Aktiengesellschaft
    Inventors: Akos Kiss, Peter Kleinschmit, Werner Volker, Gunter Halbritter
  • Patent number: 4804885
    Abstract: X-ray attenuating ceramic materials having at least one substance selected from the group including compounds of strontium, zirconium, yttrium, niobium, molybdenum, neodymium and tungsten are disclosed. A zinc compound can be used for fluxing and X-ray attenuation in certain ceramic materials. The materials can be formed into strong, non-porous bodies such as cathode ray tube funnels. Such materials include forsteritic porcelains manufactured from batches containing strontium zirconate. Other X-ray attenuating ceramics contain a mixture of X-ray attenuating substances, including a compound of barium.
    Type: Grant
    Filed: August 20, 1984
    Date of Patent: February 14, 1989
    Assignee: Tektronix, Inc.
    Inventors: Ronald O. Petersen, James L. McAlpin
  • Patent number: 4759965
    Abstract: A ceramic comprises therein two or more dielectric portions having different dielectric constants formed by filling of one or more vacant spaces provided within a dielectric porcelain, a semiconductor porcelain as a precursor of said dielectric porcelain or a molded product as a precursor of said semiconductor procelain with one or more kinds of materials capable of becoming to have different dielectric constants from said dielectric porcelain and subsequent calcination.
    Type: Grant
    Filed: August 4, 1986
    Date of Patent: July 26, 1988
    Assignee: Canon Kabushiki Kaisha
    Inventors: Keiichi Kato, Motoo Kumagai
  • Patent number: 4737475
    Abstract: A glass composition specially useful in the glass envelope of TV receiver tubes and which is of the lead silicate type is disclosed comprising in weight percent 30-65% SiO.sub.2, 20-40% PbO, 5-20% alkali metal oxides, 0-2% Al.sub.2 O.sub.3, 0-10% alkaline earth metal oxides, 0.2-2% Sb.sub.2 O.sub.3, and 0.1-0.5% CeO.sub.2. The improvement resides in employment of a novel refining system when the glass is formed which employs Sb.sub.2 O.sub.3, niter and CeO.sub.2 as the refining agents in particular weight proportions to reduce the seed count in the molten glass while also reducing thermal shock breakage when the solid glass product is thereafter thermally reworked.
    Type: Grant
    Filed: May 1, 1987
    Date of Patent: April 12, 1988
    Assignee: General Electric Company
    Inventors: George L. Thomas, Anup Sircar
  • Patent number: 4734389
    Abstract: A highly refractive optical glass (n.sub.d .gtoreq.1.83) with high dispersion (v.sub.d .ltoreq.25) and very good chemical stability at relatively low density (.delta..ltoreq.3.5 g/cm.sup.3) consists of (in weight percent) SiO.sub.2 19-25, Na.sub.2 O 7-10, K.sub.2 O 4-7, Cs.sub.2 O 0-12, Cao 0.5-2.0, BaO 9-15, TiO.sub.2 25-30, ZrO.sub.2 0-6, Nb.sub.2 O.sub.5 16-20, WO.sub.3 0-3, with Nb.sub.2 O.sub.5 :TiO.sub.2 =0.6-0.71.
    Type: Grant
    Filed: February 7, 1986
    Date of Patent: March 29, 1988
    Assignee: Schott Glaswerke
    Inventors: Danuta Grabowski, Ludwig Ross, Volkmar Geiler
  • Patent number: 4732875
    Abstract: To tellurite optical glass comprising TeO.sub.2, high valence components are added and may be a combination of La.sub.2 O.sub.3, at least one of B.sub.2 O.sub.3 and GeO.sub.2, and at least one of Ta.sub.2 O.sub.5 and Nb.sub.2 O.sub.5. The high valence components may include Y.sub.2 O.sub.3, Gd.sub.2 O.sub.3, and Yb.sub.2 O.sub.3. Amounts of TeO.sub.2 and La.sub.2 O.sub.3 are restricted to ranges between 10% and 80% and between 5% and 35%, respectively. A sum of B.sub.2 O.sub.3 and GeO.sub.2 must fall within a range between 1% and 30%, with an amount of GeO.sub.2 restricted between 0% and 22%. A total of La.sub.2 O.sub.3, Y.sub.2 O.sub.3, Gd.sub.2 O.sub.3, and Yb.sub.2 O.sub.3 must be between 5% and 50%. A sum of Ta.sub.2 O.sub.5 and Nb.sub.2 O.sub.5 should range from 1% to 26%, with individual amounts of Ta.sub.2 O.sub.5 and Nb.sub.2 O.sub.5 kept between 0% and 20% and between 0% and 26%, respectively.
    Type: Grant
    Filed: February 21, 1986
    Date of Patent: March 22, 1988
    Assignee: Hoya Corporation
    Inventor: Koji Sagara
  • Patent number: 4721690
    Abstract: High PbO-content glass in the optical range of flint and heavy flint glasses from the system SiO.sub.2 --PbO--M.sub.2 O wherein M.sub.2 O=alkali metal oxides, said glass having a minimum PbO content of 30 wt. % and a minimum M.sub.2 O content of 0.5 wt. %, are provided with enhanced chemical stability without loss of the desired optical position by replacing a portion of the SiO.sub.2 and PbO such that the glass contains 1.5-6 wt. % (TiO.sub.2 +ZrO.sub.2) and the ratio of TiO.sub.2 :ZrO.sub.2 is about 0.3-2.0.
    Type: Grant
    Filed: February 5, 1985
    Date of Patent: January 26, 1988
    Inventors: Ludwig Ross, Danuta Grabowski, Burkhard Speit, Volkmar Geiler
  • Patent number: 4677081
    Abstract: A glass composition specially useful in the glass envelope of TV receiver tubes and which is of the lead silicate type is disclosed comprising in weight percent 30-65% SiO.sub.2, 20-40% PbO, 5-20% alkali metal oxides, 0-2% Al.sub.2 O.sub.3, 0-10% alkaline earth metal oxides, 0.2-2% Sb.sub.2 O.sub.3, and 0.1-0.5% CeO.sub.2. The improvement resides in employment of a novel refining system when the glass is formed which employs Sb.sub.2 O.sub.3, niter and CeO.sub.2 as the refining agents in particular weight proportions to reduce the seed count in the molten glass while also reducing thermal shock breakage when the solid glass product is thereafter thermally reworked.
    Type: Grant
    Filed: October 7, 1985
    Date of Patent: June 30, 1987
    Assignee: General Electric Company
    Inventors: George L. Thomas, Anup Sircar
  • Patent number: 4609582
    Abstract: A dielectric glass and a glass ceramic obtained therefrom is provided for separating crossing conductors in multilayer thick-film circuits. The dielectric glass has a composition in mol. % between the limits of 10-25% ZnO, 7.5-25% PbO, 50-60% SiO.sub.2, and 7.5-12.5% Al.sub.2 O.sub.3. These compositions are particularly suitable for conductor patterns having silver because they are free from micropores.
    Type: Grant
    Filed: April 26, 1984
    Date of Patent: September 2, 1986
    Assignee: U.S. Philips Corporation
    Inventors: Hendrik J. M. Joormann, Alois J. M. Van Gorp
  • Patent number: 4567151
    Abstract: A thick film conductor composition comprising an admixture of finely divided particles of noble metal and inorganic binder dispersed in organic medium in which the inorganic binder consists essentially of a bismuth silicate glass and/or bismuth germanate glass, ZnO and optionally Bi.sub.2 O.sub.3.
    Type: Grant
    Filed: January 14, 1985
    Date of Patent: January 28, 1986
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Barry E. Taylor
  • Patent number: 4562162
    Abstract: A glass for multi-focal eyeglass having a refractive index (n.sub.d) of 1.67 to 1.73, an Abbe number (.nu..sub.d) of 33 or more, a coefficient of thermal expansion of 82 to 95.times.10.sup.-7 and a softening point of 560.degree. to 640.degree. C., comprising, in % by weight,32 to 40% SiO.sub.2 +B.sub.2 O.sub.3 +Al.sub.2 O.sub.3 ;22 to 40% SiO.sub.2 ;0 to 10% B.sub.2 O.sub.3 ;0 to 4% Al.sub.2 O.sub.3 ;4 to 10% Li.sub.2 O+Na.sub.2 O+K.sub.2 O;0 to 4% Li.sub.2 O;0 to 7% Na.sub.2 O;0 to 7% K.sub.2 O;30 to 47% PbO;3 to 24% BaO+SrO+CaO+MgO+ZnO;0 to 20% BaO;0 to 15% SrO;0 to 10% CaO;0 to 8% MgO;0 to 15% ZnO; and1 to 7% ZrO.sub.2 ;wherein a weight ratio of alkali metal oxides/PbO ranges from 0.1 to 0.3.
    Type: Grant
    Filed: October 26, 1984
    Date of Patent: December 31, 1985
    Assignee: Hoya Corporation
    Inventor: Hiroji Sagara
  • Patent number: 4532221
    Abstract: This invention is concerned with the preparation of thermally crystallizable enamels suitable for application to glass-ceramics, particularly glass-ceramics having coefficients of thermal expansion less than 15.times.10.sup.-7 /.degree.C. The enamels are capable of being fired to maturity simultaneously with the precursor glass body being crystallized to a glass-ceramic. The enamels consist essentially, expressed in weight percent on the oxide basis, of:SiO.sub.2 : 36-58Al.sub.2 O.sub.3 : 8.5-16CaO: 0.5-10PbO: 27-40K.sub.2 O: 0.
    Type: Grant
    Filed: February 21, 1984
    Date of Patent: July 30, 1985
    Assignee: Corning Glass Works
    Inventors: Pernette R. M. Barlier, Gerard R. Boury, Jean-Pierre Mazeau
  • Patent number: 4520115
    Abstract: These objects have been attained by providing highly absorbent lead containing alkali metal silicate glasses for cathode ray tube image screens, having a linear absorption coefficient .mu. of >30 cm.sup.-1 (0.6 .ANG.) and with a high resistance to discoloration by X-ray and electron radiation, comprises, in weight percent:______________________________________ SiO.sub.2 20-65% P.sub.2 O.sub.5 + B.sub.2 O.sub.3 + Al.sub.2 O.sub.3 0-30% Li.sub.2 O 0-5% Na.sub.2 O 0-10% K.sub.2 O 0-15% MgO + CaO + ZnO 0-15% SrO 0-20% BaO 0-40% PbO 5-60% ZrO.sub.2 0-10% CeO.sub.2 0.1-5% Other Components 0-20%.
    Type: Grant
    Filed: August 2, 1983
    Date of Patent: May 28, 1985
    Assignee: Schott Glaswerke
    Inventors: Burkhard Speit, Karl Mennemann, Georg Gliemeroth
  • Patent number: 4512791
    Abstract: First and second spaced members are hermetically sealed by a partially amorphous and partially crystalline insulating material. The insulating material is non-hygroscopic and is able to withstand forces of about 26,000 psi at about 700.degree. F. It may provide resistances of at least 10,000 megohms even when subjected to 500 volts AC or DC and to steam at about 212.degree. F. for three (3) days. A second insulating layer may be fused to the first insulating layer with essentially the same properties and composition as the first layer. However, the second layer may be more crystalline than the first layer to provide a mechanical and chemical barrier. The insulating materials may be formed from the oxides of lead, zinc, aluminum, silicon, cerium, lanthanum, cobalt, sodium, zirconium, bismuth and molybdenum. The oxides of lead, silicon, bismuth and sodium may be glass formers. The oxides of cerium, lanthanum and zirconium may form crystals. A mixture of the oxides may be heated to at least 2000.degree. F.
    Type: Grant
    Filed: May 2, 1984
    Date of Patent: April 23, 1985
    Inventor: James C. Kyle
  • Patent number: 4495298
    Abstract: A thallium-containing optical glass composition which comprises the following oxides in the indicated proportions in mole %: SiO.sub.2 35-80, Tl.sub.2 O 1-30, Tl.sub.2 O+R.sub.2 O (R being an alkali metal) 1-35, ZnO 0-35, GeO.sub.2 0-30, BaO 0-25, TiO.sub.2 0-20, MgO 0-20, B.sub.2 O.sub.3 0-less than 10, ZrO.sub.2 0-2, Al.sub.2 O.sub.3 0-8, SnO 0-5, CaO 0-10, SrO 0-10, PbO 0-10, La.sub.2 O.sub.3 0-5, Bi.sub.2 O.sub.3 0-8, and Ta.sub.2 O.sub.5 0-2, and satisfies the following relations:5.ltoreq.ZnO+GeO.sub.2 +BaO+TiO.sub.2 +MgO+B.sub.2 O.sub.3 .ltoreq.40,0.1.ltoreq.ZrO.sub.2 +Al.sub.2 O.sub.3 +SnO.ltoreq.8,and0.ltoreq.CaO+SrO+PbO+La.sub.2 O.sub.3 +Bi.sub.2 O.sub.3 +Ta.sub.2 O.sub.5 .ltoreq.10.
    Type: Grant
    Filed: May 11, 1982
    Date of Patent: January 22, 1985
    Assignee: Nippon Sheet Glass Co., Ltd.
    Inventors: Takasi Yamagishi, Yukio Noguchi
  • Patent number: 4483931
    Abstract: This invention is directed to the preparation of glasses in the PbO--Ga.sub.2 O.sub.3 field exhibiting good infrared transmitting characteristics out to wavelengths of 8 microns. The binary glasses consist essentially, by weight, of about 15-28% Ga.sub.2 O.sub.3 and 72-85% PbO. However, the preferred glasses contain up to 85% Bi.sub.2 O.sub.3 and consist essentially as included within the area generally encompassed by the curve in FIG. 2.
    Type: Grant
    Filed: March 21, 1983
    Date of Patent: November 20, 1984
    Assignee: Corning Glass Works
    Inventors: William H. Dumbaugh, Jr., Brian P. Tyndell
  • Patent number: 4476233
    Abstract: A phosphate optical glass comprises P.sub.2 O.sub.5 of 40-55 weight percents, R.sub.2 O of 20-40 weight percents (wherein R is an alkali metal or a mixture of alkali metals selected from the group consisting of Li, Na and K), TiO.sub.2 of 8-20 weight percents, WO.sub.3 of 1-12 weight percents (providing that the WO.sub.3 content be less than TiO.sub.2), As.sub.2 O.sub.3 of 0.1-4 weight percents, MgO of 0-7, CaO of 0-11, BaO of 0-12, ZnO of 0-12 PbO of 0-18, Nb.sub.2 O.sub.5 of 0-20, Ta.sub.2 O.sub.5 of 0-10, SiO.sub.2 of 0-3, ZrO.sub.2 of 0-3, La.sub.2 O.sub.3 of 0-3, Y.sub.2 O.sub.3 of 0-3 and F of 0-5.
    Type: Grant
    Filed: September 12, 1983
    Date of Patent: October 9, 1984
    Assignee: Nippon Kogaku K.K.
    Inventor: Hiroyuki Kodama
  • Patent number: 4472030
    Abstract: A cesium-containing optical glass comprising, by weight, 32-56% of SiO.sub.2, 6-25% of K.sub.2 O, 6-32% of Cs.sub.2 O, 0-30% of BaO, 0-2.5% of MgO, 5-34% of ZnO, 0-3% of ZrO.sub.2 and 0-5% of SnO.sub.2, provided that the total proportion of BaO, MgO and ZnO is 8-40% and the total proportion of ZrO.sub.2 and SnO.sub.2 is 0.2-6%. When this cesium-containing optical glass is treated in a molten bath containing potassium nitrate, the cesium ion in the glass is easily exchanged with a potassium ion and therefore, the cesium ion concentration gradually decreases radially outwardly from the central axis and the potassium ion concentration gradually increases in that direction. Thus, there is obtained a light converge-type lens in which the refractive index gradually decreases in the same direction.
    Type: Grant
    Filed: November 4, 1983
    Date of Patent: September 18, 1984
    Assignee: Nippon Sheet Glass Company, Limited
    Inventors: Masakiyo Tachibana, Yukio Noguchi, Noboru Akazawa
  • Patent number: 4461926
    Abstract: First and second spaced members are hermetically sealed by a partially amorphous and partially crystalline insulating material. The insulating material is non-hygroscopic and is able to withstand forces of about 26,000 psi at about 700.degree. F. It may provide resistances of at least 10,000 megohms even when subjected to 500 volts AC or DC and to steam at about 212.degree. F. for three (3) days. A second insulating layer may be fused to the first insulating layer with essentially the same properties and composition as the first layer. However, the second layer may be more crystalline than the first layer to provide a mechanical and chemical barrier. The insulating materials may be formed from the oxides of lead, zinc, aluminum, silicon, cerium, lanthanum, cobalt, sodium, zirconium, bismuth and molybdenum. The oxides of lead, silicon, bismuth and sodium may be glass formers. The oxides of cerium, lanthanum and zirconium may form crystals. A mixture of the oxides may be heated to at least 2000.degree. F.
    Type: Grant
    Filed: November 16, 1981
    Date of Patent: July 24, 1984
    Inventor: James C. Kyle
  • Patent number: 4395291
    Abstract: A lead additive containing a lead oxide and an alkaline silicate which is resistant to dusting, abrasion and segregation. The weight ratio of lead to alkaline silicate, calculated as PbO and SiO.sub.2, respectively, is greater than about 95:5; the moisture content is less than or equal to about 2%; and the density is less than about 5 g/cm.sup.3.The process for producing these additives involve forming a paste of the lead oxide and alkaline silicate, conditioning the paste to form granules and heat treating the granules.
    Type: Grant
    Filed: March 19, 1982
    Date of Patent: July 26, 1983
    Assignee: Societe Anonyme Societe Miniere et Metallurgique de Penarroya
    Inventors: Armand Limare, Bernard Razumowski, Claude Sindezingue
  • Patent number: 4391915
    Abstract: Optical components can be pressed with such a precision that grinding and polishing of the formed components is not necessary, from glasses containing 45-55 wt. % P.sub.2 O.sub.5, 3.5-9 wt. % Al.sub.2 O.sub.3, 5-20 wt. % K.sub.2 O, 0-3 wt. % Li.sub.2 O, 8-15% BaO, 4.5-9 wt. % ZnO, 0-6 wt. % MgO, 0-18 wt. % PbO, 0-1 wt. % SiO.sub.2, 0-3 wt. % B.sub.2 O.sub.3, 0-2 wt. % TiO.sub.2.
    Type: Grant
    Filed: December 7, 1981
    Date of Patent: July 5, 1983
    Assignee: U.S. Philips Corporation
    Inventors: Gertraud A. A. Meden-Piesslinger, Johannes H. P. Van de Heuvel
  • Patent number: 4351906
    Abstract: The present invention is drawn to glasses suitable for the fabrication of segments or buttons for multifocal ophthalmic lenses. The inventive glasses have refractive indices ranging between about 1.745-1.771, an Abbe number greater than 29 for a refractive index of 1.771 and greater than 31 for a refractive index of 1.745, a softening point between about 640.degree.-700.degree. C., a coefficient of thermal expansion (25.degree.-300.degree. C.) between about 90-98.times.10.sup.-7 /.degree.C., and satisfactory chemical durability. The glasses consist essentially, expressed in terms of weight percent on the oxide basis, of______________________________________ SiO.sub.2 28-32.5 Na.sub.2 O 2-9 K.sub.2 O 0-4 Li.sub.2 O 0-1 K.sub.2 O + Na.sub.2 O + Li.sub.2 O 4-10.5 BaO 0-22 La.sub.2 O.sub.3 0-20 BaO + La.sub.2 O.sub.3 14-22 PbO 28.5-34 ZnO 0-4 TiO.sub.2 0-9 ZrO.sub.2 2-6.5 Nb.sub.2 O.sub.5 0-10 TiO.sub.2 + Nb.sub.2 O.sub.5 4.5-12 ZrO.sub.2 + TiO.sub.2 + Nb.sub.2 O.sub.
    Type: Grant
    Filed: December 7, 1981
    Date of Patent: September 28, 1982
    Assignee: Corning Glass Works
    Inventors: Jean E. Boudot, Jean P. Mazeau, Andre C. Michaud
  • Patent number: 4342943
    Abstract: A glass composition is disclosed that is useful as a solder glass for sealing components together. However, the glass is also especially adapted for use as an electric resistance film for coating the inner neck or funnel portions of a cathode ray tube to reduce arcing. The glass composition includes primarily the oxides of vanadium and phosphorous with the preferred addition of either zinc oxide or lead oxide. Still other metal oxides may be optionally included such as oxides of barium, antimony, lithium, manganese, silicon, boron, molybdenum and mixtures thereof.
    Type: Grant
    Filed: October 17, 1979
    Date of Patent: August 3, 1982
    Assignee: Owens-Illinois, Inc.
    Inventor: Edward A. Weaver
  • Patent number: 4314031
    Abstract: Glass compositions in the tin-phosphorus-oxyfluoride composition system exhibiting very low glass transition temperatures and capable of being modified by the addition of selected constituents to exhibit excellent stability in a humid environment, are described.
    Type: Grant
    Filed: June 17, 1980
    Date of Patent: February 2, 1982
    Assignee: Corning Glass Works
    Inventors: Leon M. Sanford, Paul A. Tick
  • Patent number: 4302362
    Abstract: Thick film resistors, based on pyrochlore conductive phase, glass, and refractory fillers having a thermal expansion coefficient range of 40.times.10.sup.-7 -60.times.10.sup.-7 /.degree. C. and low solubility in the glass, are provided. Such thick film resistor pastes afford resistors having excellent stability to mechanical or thermal stresses.
    Type: Grant
    Filed: January 23, 1979
    Date of Patent: November 24, 1981
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Lewis C. Hoffman, Samuel J. Horowitz